CN109694520A - Flame-proof antibiotic PP fiberboard and preparation method thereof - Google Patents
Flame-proof antibiotic PP fiberboard and preparation method thereof Download PDFInfo
- Publication number
- CN109694520A CN109694520A CN201811617044.3A CN201811617044A CN109694520A CN 109694520 A CN109694520 A CN 109694520A CN 201811617044 A CN201811617044 A CN 201811617044A CN 109694520 A CN109694520 A CN 109694520A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame
- fiberboard
- proof antibiotic
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011094 fiberboard Substances 0.000 title claims abstract description 55
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 37
- 244000198134 Agave sisalana Species 0.000 claims description 33
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 24
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 23
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 23
- 239000012065 filter cake Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 19
- 230000001070 adhesive effect Effects 0.000 claims description 19
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- 229920000881 Modified starch Polymers 0.000 claims description 18
- 239000004368 Modified starch Substances 0.000 claims description 18
- 235000019426 modified starch Nutrition 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 238000000465 moulding Methods 0.000 claims description 15
- 238000010792 warming Methods 0.000 claims description 15
- 229920000877 Melamine resin Polymers 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 13
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 13
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 13
- 229960004011 methenamine Drugs 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000002604 ultrasonography Methods 0.000 claims description 12
- 150000005846 sugar alcohols Polymers 0.000 claims description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- WESVFLQWZCBKSK-UHFFFAOYSA-N (1,1,3-tribromo-2,2-dimethylpropyl) dihydrogen phosphate Chemical compound BrCC(C)(C)C(Br)(Br)OP(O)(O)=O WESVFLQWZCBKSK-UHFFFAOYSA-N 0.000 claims description 9
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- 239000013049 sediment Substances 0.000 claims description 8
- 229920001661 Chitosan Polymers 0.000 claims description 7
- MEXATBHBIYUJGT-UHFFFAOYSA-N NCCNCCC[SiH](OCC(OCC)(OCC)OCC)OCC Chemical compound NCCNCCC[SiH](OCC(OCC)(OCC)OCC)OCC MEXATBHBIYUJGT-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 239000005662 Paraffin oil Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- BHTJEPVNHUUIPV-UHFFFAOYSA-N pentanedial;hydrate Chemical compound O.O=CCCCC=O BHTJEPVNHUUIPV-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 claims 1
- 235000011624 Agave sisalana Nutrition 0.000 claims 1
- QQXLDOJGLXJCSE-UHFFFAOYSA-N N-methylnortropinone Natural products C1C(=O)CC2CCC1N2C QQXLDOJGLXJCSE-UHFFFAOYSA-N 0.000 claims 1
- QIZDQFOVGFDBKW-DHBOJHSNSA-N Pseudotropine Natural products OC1C[C@@H]2[N+](C)[C@H](C1)CC2 QIZDQFOVGFDBKW-DHBOJHSNSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- CYHOMWAPJJPNMW-JIGDXULJSA-N tropine Chemical compound C1[C@@H](O)C[C@H]2CC[C@@H]1N2C CYHOMWAPJJPNMW-JIGDXULJSA-N 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 238000005034 decoration Methods 0.000 abstract description 4
- 230000000845 anti-microbial effect Effects 0.000 abstract description 3
- 239000004035 construction material Substances 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 description 44
- 229920001155 polypropylene Polymers 0.000 description 44
- -1 Polypropylene Polymers 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000005119 centrifugation Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000007790 scraping Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 235000011609 Pinus massoniana Nutrition 0.000 description 2
- 241000018650 Pinus massoniana Species 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention discloses a kind of flame-proof antibiotic PP fiberboard and preparation method thereof, the flame-proof antibiotic PP fiberboard includes that the raw material of following weight parts is prepared: 60-100 parts PP, 10-30 parts ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 1-4 parts of odium stearate.Flame-proof antibiotic PP fiberboard of the invention has good anti-microbial property, fracture resistance, compressive property, stretches slight, Scratch Resistance energy, has good application prospect on construction material, automobile decoration piece, household, mechanical equipment component.
Description
Technical field
The present invention relates to a kind of PP fiberboard technical fields, more particularly to a kind of flame-proof antibiotic PP fiberboard and its preparation
Method.
Background technique
Polypropylene (PP) is the versatility plastic resin that a kind of source is wide, cheap, there is very extensive purposes.Its
Crystallinity is high, compound with regular structure, thus has excellent mechanical property.The absolute value of Mechanical Properties of PP is higher than polyethylene, but
Relatively low kind is still fallen in a plastic material.The biggish polypropylene of isotactic index tensile strength with higher, but with isotactic
The impact strength of the raising of index, material is declined, but is no longer changed after dropping to a certain numerical value.Temperature and loading speed pair
Polyacrylic toughness influences very big.When temperature is higher than glass transition temperature, impact failure is in ductile rupture, is lower than glass transition temperature
In brittle fracture, and impact value sharp fall.Improve loading speed, the temperature that ductile rupture can be made to change to brittle fracture
Degree rises.Polypropylene have excellent flexural fatigue resistance, product at normal temperature bent 106 times without damage.Fiberboard
Also known as density board, it is to apply Lauxite or other applicable adhesive using wood fibre or other plant cellulose fiber as raw material
Manufactured wood-based plate.Adhesive or additive can be applied in manufacturing process.It forms and contains isolated wood fibre in fiberboard
Or fibre bundle.The raw material of fiber is produced mainly from forest harvesting residue, such as branch, the tip of a branch, small dimension wood；And timber adds
Work residue, such as edges of boards, wood shavings, sawdust.Additionally produced using the waste material and other plant bar stem of chemistry of forest product processing
Fiber.Fiberboard has many advantages, such as that uniform in material, intensity difference is not small, easy to crack in length and breadth, widely used.It is fast with China's economy
The continuous improvement of speed development and Urbanization Rate, quality is stable, environmental protection grade is high, meets differentiated demand and has safety fire-retardant
The fibreboard product of function has a vast market space.The industries such as following China's real estate, furniture, interior decoration, packaging
Fast development and fast-growing Industry plantation raw material site be constructed and put into operation, the demand and export volume that drive fiberboard is steady
Increase, ratio of the fibreboard product in Wood-based Panel Production total amount will also greatly improve.PP fiberboard can overcome the disadvantages that polypropylene stretches
The low problem of intensity, while improving the load-bearing capacity of fiberboard.
Summary of the invention
The present invention provides a kind of flame-proof antibiotic PP fiberboards and preparation method thereof.The present invention adopts the following technical scheme:
A kind of flame-proof antibiotic PP fiberboard, the raw material including following weight parts are prepared: 60-100 parts PP, 10-30 parts
ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 1-4 parts of odium stearate.
A kind of flame-proof antibiotic PP fiberboard, the raw material including following weight parts are prepared: 60-100 parts PP, 10-30 parts
ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 1-4 parts of odium stearate, 2-10 parts of bondings
Agent.
A kind of flame-proof antibiotic PP fiberboard, the raw material including following weight parts are prepared: 60-100 parts PP, 10-30 parts
ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 3-12 parts of modified sisal fibers, 1-4 parts it is hard
Resin acid sodium, 2-10 part adhesive.
According to flame-proof antibiotic PP fiberboard described in any of the above item, the antioxidant is antioxidant 1010, irgasfos 168
One of or it is a variety of.
According to flame-proof antibiotic PP fiberboard described in any of the above item, the fire retardant is three (tribromo neopentyl) phosphates
And magnesium hydroxide, the mass ratio of three (tribromo neopentyl) phosphate and magnesium hydroxide are 3:1.
According to flame-proof antibiotic PP fiberboard described in any of the above item, the antibacterial agent is zinc oxide, one in titanium oxide
Kind is a variety of.
According to flame-proof antibiotic PP fiberboard described in any of the above item, described adhesive includes melamine polyalcohol, modified pine
Botany bar gum, modified starch, methenamine, the quality of the melamine polyalcohol, modified rosin resin, modified starch, methenamine
Than for (3-5): (3-5): (3-5): 1, preferably 5:5:3:1.
By selecting suitable adhesive component, its preferred ratio range is constantly regulate, obtained adhesive can effectively increase
The associativity of strong PP and fiber, improve PP fiberboard mechanical property, hardness, surface abrasion resistance.
Adhesive the preparation method is as follows: by melamine polyalcohol, modified rosin resin, modified starch, methenamine mix
Afterwards, it is heated to 80-100 DEG C, is that 200-500 turns/min stirring 2-5 hours in 80-100 DEG C, revolving speed, natural cooling is bonded
Agent.
Modified rosin resin described in adhesive the preparation method is as follows: 20-60g rosin be added flask in, be heated to 80-
110 DEG C, temperature is maintained to melt completely at 80-110 DEG C to rosin, 0.5-1.5g phenol, 0.2-0.8g mass fraction is then added
Formalin, 0.02-0.08g methenamine for 37%, continue 80-110 DEG C reaction 2-5 hours, addition 0.02-
0.08g zinc oxide, 2-8g glycerol, are warming up to 240-270 DEG C, 240-270 DEG C heat preservation 5-10 hours, natural cooling is changed
Property rosin resin.
Modified starch described in adhesive the preparation method is as follows: 5-12g starch, 15-30g water are mixed after stir it is equal
It is even, starch emulsion is obtained, 1-5g sodium metaperiodate is added into starch emulsion, is uniformly mixed, then uses 0.5-1.5mol/L
Salt acid for adjusting pH is then warming up to 35-45 DEG C to 1-3, turns in 35-45 DEG C, 100-400/min stirs 1-5 hours, then with
5000-7000 turns/centrifugation of min revolving speed 20-50 minutes, sediment separate out, after sediment 80-120g water washing, in 35-45
DEG C, absolute pressure be 0.01-0.03MPa condition dry 16-28 hours, obtain modified starch.
According to flame-proof antibiotic PP fiberboard described in any of the above item, the modified sisal fiber the preparation method is as follows:
The modified sisal fiber the preparation method is as follows: sisal fiber crushed 300 meshes by (1), it is spare；By 8-15g diatomite
It is added in 1000-2000g water, ultrasonic frequency is 20-60kHz, power is 200-800W condition ultrasound 30-60 minutes, obtains
To diatomite dispersion liquids, 8-16g polyvinyl alcohol, 10-30g chitosan are added into diatomite dispersion liquid, is heated to 60-80 DEG C,
It is that 200-600 turns/min stirring 0.5-1.5 hours in 60-80 DEG C, revolving speed, 80-120g sisal fiber is then added, continues to exist
60-80 DEG C, revolving speed be 200-600 turn/min stir 20-60 minute, cross 800 meshes, by filter cake be added 1200-1800g mass divide
Number is in 2% glutaraldehyde water solution, addition 3-8g ethyl acetate is warming up to 55-65 DEG C, in 55-65 DEG C, revolving speed 200-
600 turns/min stir 20-60 minute, cross 800 meshes, by filter cake absolute pressure be 0.01-0.02MPa, 45-55 DEG C of dryings
18-26 hours；(2) filter cake after drying is added in 800-1500g paraffin oil, is 20-60kHz, function in ultrasonic frequency
Rate be 200-800W condition ultrasound 30-60 minute, cross 800 meshes, by filter cake be added 500-1000g mass fraction for 75% to
In 90% ethanol water, 0.1-0.5mol silane coupling agent is added, is warming up to 55-65 DEG C, is in 55-65 DEG C, revolving speed
200-600 turns/min stirring 18-26 hours, is then turned/centrifugation of min revolving speed 25-45 minutes with 5000-8000, takes centrifugation
Object is 0.01-0.02MPa, 45-55 DEG C 18-26 hours dry in absolute pressure, obtains modified sisal fiber；The silane is even
Joining agent is 4- aminopropyltriethoxy dimethoxysilane and/or N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane.It is preferred that
Ground, the silane coupling agent are 4- aminopropyltriethoxy dimethoxysilane and N-2- aminoethyl -3- aminopropyltriethoxy diethoxy
Silane, the quality of the 4- aminopropyltriethoxy dimethoxysilane and N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane
Than for (1-3): (1-3).
Modified sisal fiber not only can the tensile strength of reinforced polypropylene plate, fracture resistance, load-bearing, also act as absorption volatilization
The effect of property organic matter.
The present invention also provides a kind of preparation method of flame-proof antibiotic PP fiberboard, include the following steps: to weigh by weight
Each raw material mixes each raw material, turns/min stirring 20-60 minutes in 25-30 DEG C, 200-500, then heats to 110-130 DEG C,
110-130 DEG C melting 20-50 minutes, be then pressed and molded on vulcanizing press, shed pressure, natural cooling is hindered
Fire antibacterial PP fiberboard.
Preferably, the preparation method of the flame-proof antibiotic PP fiberboard, includes the following steps: to weigh each original by weight
Material, each raw material is mixed, and is turned/min stirring 20-60 minutes in 25-30 DEG C, 200-500, is then heated to 110-130 DEG C,
110-130 DEG C melting 20-50 minutes, be then pressed and molded on vulcanizing press, first time molding temperature be 150-180 DEG C,
Molding pressure is 20-50MPa, and clamp time is 10-30 minutes, and second of molding temperature is 145-175 DEG C, and molding pressure is
Then etc. 15-30MPa, clamp time are 5-15 minute, and temperature are down to 65-95 DEG C and shed pressure, and natural cooling obtains fire-retardant resist
Bacterium PP fiberboard.
Flame-proof antibiotic PP fiberboard of the invention has good anti-microbial property, fracture resistance, compressive property, stretches gently
Degree, Scratch Resistance energy, have good application prospect on construction material, automobile decoration piece, household, mechanical equipment component.
On the basis of common knowledge of the art, above-mentioned each optimum condition, can be each preferably to get the present invention in any combination
Embodiment.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.In the following examples, the experimental methods for specific conditions are not specified, according to conventional methods and conditions, or according to quotient
The selection of product specification.
Part material used is described below in embodiment:
PP, Sinopec Beijing Yanshan Mountain branch company, trade mark K8303.
ABS, Qimei Industry Co., Ltd., model PA-757.
Sisal fiber, length 2mm, 100-120 μm of diameter, bundle fiber ultimate strength: 880N, percentage of impurity: 2.5%, resurgence
Rate: 13%.Longzhou strength Ma Ye Co., Ltd provides.
4- aminopropyltriethoxy dimethoxysilane, CAS:3663-44-3.Nanjing Neng De new material technology Co., Ltd.
N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane, CAS:70240-34-5.It Nanjing can moral new material technology
Co., Ltd.
Three (tribromo neopentyl) phosphates, CAS:19186-97-1.
Melamine polyalcohol, Jiangsu Changshun Group Co., Ltd, model: EDS-5083L.
Rosin, the oil flowed out inside pine tree trunk at watery, become a kind of day of blocks of solid through high temperature melting after dry and hard
Right resin.It is specifically used in the embodiment of the present invention to be derived from masson pine (scientific name: Pinus massoniana Lamb.)
Rosin.
Starch meets GB12309-90 primary standard using industrial cornstarch.
Sodium metaperiodate, molecular formula: NaIO4。
Diatomite, 325 mesh of partial size.
Polyvinyl alcohol, Anhui Wanwei New High-tech Materials Co., Ltd, model PVA 17-99 (L).
Chitosan, deacetylated Du≤90%, viscosity (10g/L, 20 DEG C): 100mPas, the auspicious fine chemistry industry of Zhengzhou section are limited
Company.
Paraffin oil, CAS:8012-95-1, Wuxi Yong Zhen industrial oil company.
The present invention is further illustrated below by the mode of embodiment.
Embodiment 1
A kind of flame-proof antibiotic PP fiberboard, the raw material including following weight parts are prepared: 80 parts of PP, 15 parts of ABS, 5 parts
Fire retardant, 1.5 parts of antioxidants, 0.01 part of antibacterial agent, 8 parts of modified sisal fibers, 2 parts of odium stearate, 5 parts of adhesives.
The fire retardant be three (tribromo neopentyl) phosphates and magnesium hydroxide, three (tribromo neopentyl) phosphate and
The mass ratio of magnesium hydroxide is 3:1.The antioxidant is antioxidant 1010.The antibacterial agent is titanium oxide.
Described adhesive includes melamine polyalcohol, modified rosin resin, modified starch, methenamine, and the melamine is polynary
Alcohol, modified rosin resin, modified starch, methenamine mass ratio be 5:5:3:1.Described adhesive the preparation method is as follows:
After melamine polyalcohol, modified rosin resin, modified starch, methenamine are mixed, 95 DEG C are heated to, in 95 DEG C, revolving speed 300
Turn/min stirring 3 hours, natural cooling obtains adhesive.The modified rosin resin the preparation method is as follows: 40g rosin adds
Enter in flask, be heated to 100 DEG C, temperature is maintained to melt completely at 100 DEG C to rosin, 0.8g phenol, 0.5g mass is then added
Formalin, 0.05g methenamine of the score for 37%, continue to react 4 hours at 100 DEG C, 0.05g zinc oxide, 5g are added
Glycerol is warming up to 265 DEG C, keeps the temperature 8 hours at 265 DEG C, natural cooling obtains modified rosin resin.The system of the modified starch
Preparation Method is as follows: stirring evenly after 8g starch, 20g water are mixed, obtains starch emulsion, 3g periodic acid is added into starch emulsion
Sodium is uniformly mixed, and is then then warming up to 40 DEG C to 1.5 with 1mol/L salt acid for adjusting pH, stirred in 40 DEG C, 200 turns/min
It mixes 3 hours, then with 5000 turns/min revolving speed centrifugation 40 minutes, sediment separate out, after sediment 100g water washing, 40
DEG C, absolute pressure be 0.01MPa condition dry 24 hours, obtain modified starch.
The modified sisal fiber the preparation method is as follows: sisal fiber crushed 300 meshes by (1), it is spare；By 10g
Diatomite is added in 1500g water, ultrasonic frequency is 40kHz, power is 500W condition ultrasound 50 minutes, obtains diatomite point
Dispersion liquid, into diatomite dispersion liquid be added 10g polyvinyl alcohol, 15g chitosan, be heated to 75 DEG C, 75 DEG C, revolving speed be 300 turns/
Min is stirred 1 hour, and 100g sisal fiber is then added, and is continued in 75 DEG C, revolving speed to be that 300 turns/min is stirred 40 minutes, is crossed 800
Mesh filter cake is added in the glutaraldehyde water solution that 1500g mass fraction is 2%, and 5g ethyl acetate is added, is warming up to 60 DEG C,
60 DEG C, revolving speed be 300 turns/min stir 40 minutes, cross 800 meshes, by filter cake absolute pressure be 0.01MPa, 50 DEG C of dryings
24 hours；(2) filter cake after drying is added in 1000g paraffin oil, ultrasonic frequency is 40kHz, power is 500W item
Part ultrasound 50 minutes, crosses 800 meshes, filter cake is added in the ethanol water that 800g mass fraction is 85%, and 0.2mol is added
Silane coupling agent is warming up to 60 DEG C, 60 DEG C, revolving speed be 300 turns/min stir 24 hours, then with 5000 turns/min revolving speed from
The heart 30 minutes, take centrifugal sediment, absolute pressure be 0.01MPa, 50 DEG C drying 24 hours, obtain be modified sisal fiber.Institute
State silane coupling agent be 4- aminopropyltriethoxy dimethoxysilane and N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane,
The mass ratio of the 4- aminopropyltriethoxy dimethoxysilane and N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane is 1:
1。
The flame-proof antibiotic PP fiberboard the preparation method is as follows: weigh each raw material by weight, each raw material is mixed,
28 DEG C, 400 turns/min stirring 30 minutes, then heat to 120 DEG C, melt 40 minutes at 120 DEG C, then on vulcanizing press
Compression molding, first time molding temperature are 175 DEG C, molding pressure 40MPa, and clamp time is 15 minutes, second of molding temperature
Then etc. degree is 170 DEG C, molding pressure 25MPa, and clamp time is 10 minutes, and temperature are down to 80 DEG C and shed pressure, naturally cold
But, flame-proof antibiotic PP fiberboard is obtained.
Embodiment 2
Substantially the same manner as Example 1, difference is only that, in the present embodiment 2, described adhesive include melamine polyalcohol,
Modified rosin resin, modified starch, methenamine, the melamine polyalcohol, modified rosin resin, modified starch, methenamine
Mass ratio be 3:5:5:1.The modified rosin resin, the preparation method of modified starch are same as Example 1.
Embodiment 3
Substantially the same manner as Example 1, difference is only that, in the present embodiment 3, described adhesive include melamine polyalcohol,
Modified rosin resin, modified starch, methenamine, the melamine polyalcohol, modified rosin resin, modified starch, methenamine
Mass ratio be 5:3:5:1.The modified rosin resin, the preparation method of modified starch are same as Example 1.
Embodiment 4
Substantially the same manner as Example 1, difference is only that: in the present embodiment 4, the preparation method of the modified sisal fiber is such as
Under: (1) sisal fiber is crushed into 300 meshes, it is spare；10g diatomite is added in 1500g water, is in ultrasonic frequency
40kHz, power are 500W condition ultrasound 50 minutes, obtain diatomite dispersion liquid, 10g polyethylene is added into diatomite dispersion liquid
Alcohol, 15g chitosan, are heated to 75 DEG C, are that 300 turns/min is stirred 1 hour in 75 DEG C, revolving speed, 100g sisal fiber is then added,
Continue in 75 DEG C, revolving speed to be that 300 turns/min is stirred 40 minutes, cross 800 meshes, it is 2% that 1500g mass fraction, which is added, in filter cake
In glutaraldehyde water solution, 5g ethyl acetate is added, is warming up to 60 DEG C, is that 300 turns/min is stirred 40 minutes in 60 DEG C, revolving speed, mistake
800 meshes, by filter cake absolute pressure be 0.01MPa, 50 DEG C drying 24 hours；(2) filter cake after drying is added to 1000g
In paraffin oil, ultrasonic frequency is 40kHz, power is 500W condition ultrasound 50 minutes, filter cake is added 800 meshes excessively
In the ethanol water that 800g mass fraction is 85%, 0.2mol silane coupling agent is added, 60 DEG C are warming up to, in 60 DEG C, revolving speed
Centrifugal sediment is taken, in absolute pressure then with 5000 turns/min revolving speed centrifugation 30 minutes for 300 turns/min stirring 24 hours
For 0.01MPa, 50 DEG C drying 24 hours, obtain modified sisal fiber.The silane coupling agent is only 4- aminopropyltriethoxy two
Methoxy silane.
Embodiment 5
Substantially the same manner as Example 1, difference is only that: in the present embodiment 5, the preparation method of the modified sisal fiber is such as
Under: (1) sisal fiber is crushed into 300 meshes, it is spare；10g diatomite is added in 1500g water, is in ultrasonic frequency
40kHz, power are 500W condition ultrasound 50 minutes, obtain diatomite dispersion liquid, 10g polyethylene is added into diatomite dispersion liquid
Alcohol, 15g chitosan, are heated to 75 DEG C, are that 300 turns/min is stirred 1 hour in 75 DEG C, revolving speed, 100g sisal fiber is then added,
Continue in 75 DEG C, revolving speed to be that 300 turns/min is stirred 40 minutes, cross 800 meshes, it is 2% that 1500g mass fraction, which is added, in filter cake
In glutaraldehyde water solution, 5g ethyl acetate is added, is warming up to 60 DEG C, is that 300 turns/min is stirred 40 minutes in 60 DEG C, revolving speed, mistake
800 meshes, by filter cake absolute pressure be 0.01MPa, 50 DEG C drying 24 hours；(2) filter cake after drying is added to 1000g
In paraffin oil, ultrasonic frequency is 40kHz, power is 500W condition ultrasound 50 minutes, filter cake is added 800 meshes excessively
In the ethanol water that 800g mass fraction is 85%, 0.2mol silane coupling agent is added, 60 DEG C are warming up to, in 60 DEG C, revolving speed
Centrifugal sediment is taken, in absolute pressure then with 5000 turns/min revolving speed centrifugation 30 minutes for 300 turns/min stirring 24 hours
For 0.01MPa, 50 DEG C drying 24 hours, obtain modified sisal fiber.The silane coupling agent is only N-2- aminoethyl -3- ammonia
Hydroxypropyl methyl diethoxy silane.
Comparative example 1
Substantially the same manner as Example 1, difference is only that: in this comparative example 1, the preparation method of the modified sisal fiber is such as
Under: sisal fiber be crushed into 300 meshes, it is spare；By 10g diatomite be added 1500g water in, ultrasonic frequency be 40kHz,
Power is 500W condition ultrasound 50 minutes, obtains diatomite dispersion liquid, 10g polyvinyl alcohol, 15g are added into diatomite dispersion liquid
Chitosan is heated to 75 DEG C, is that 300 turns/min is stirred 1 hour in 75 DEG C, revolving speed, 100g sisal fiber is then added, continues
75 DEG C, revolving speed be 300 turns/min stir 40 minutes, cross 800 meshes, by filter cake be added 1500g mass fraction be 2% glutaraldehyde
In aqueous solution, 5g ethyl acetate is added, is warming up to 60 DEG C, is that 300 turns/min is stirred 40 minutes in 60 DEG C, revolving speed, crosses 800 mesh
Sieve, by filter cake absolute pressure is 0.01MPa, 50 DEG C of drying 24 hours to get modification sisal fiber.
Comparative example 2
A kind of flame-proof antibiotic PP fiberboard, the raw material including following weight parts are prepared: 80 parts of PP, 15 parts of ABS, 5 parts
Fire retardant, 1.5 parts of antioxidants, 0.01 part of antibacterial agent, 8 parts of modified sisal fibers, 2 parts of odium stearate.
The fire retardant be three (tribromo neopentyl) phosphates and magnesium hydroxide, three (tribromo neopentyl) phosphate and
The mass ratio of magnesium hydroxide is 3:1.The antioxidant is antioxidant 1010.The antibacterial agent is titanium oxide.
The preparation method of the modified sisal fiber is same as Example 1.
The flame-proof antibiotic PP fiberboard the preparation method is as follows: weigh each raw material by weight, each raw material is mixed,
28 DEG C, 400 turns/min stirring 30 minutes, then heat to 120 DEG C, melt 40 minutes at 120 DEG C, then on vulcanizing press
Compression molding, first time molding temperature are 175 DEG C, molding pressure 40MPa, and clamp time is 15 minutes, second of molding temperature
Then etc. degree is 170 DEG C, molding pressure 25MPa, and clamp time is 10 minutes, and temperature are down to 80 DEG C and shed pressure, naturally cold
But, flame-proof antibiotic PP fiberboard is obtained.
Test case
Flame-proof antibiotic PP fiberboard is subjected to following tests:
(1), TVOC burst size is tested: being tested according to VDA277 standard.
(2), tensile strength is tested: being tested according to GB/T1447-2005.
(3), scraping and wiping resistance performance is tested: by flame-proof antibiotic PP fiberboard (long 60mm, width 60mm, with a thickness of 3mm) according to
GMW14688 tests scraping and wiping resistance performance, load 10N.
Table 1:TVOC burst size test result table
| TVOC burst size/(ugCg-1) | |
| Embodiment 1 | 20.4 |
| Embodiment 2 | 21.6 |
| Embodiment 3 | 22.4 |
| Embodiment 4 | 26.8 |
| Embodiment 5 | 27.2 |
| Comparative example 1 | 32.6 |
Table 2: tensile strength and scraping and wiping resistance performance test result table
| Tensile strength/MPa | △L | |
| Embodiment 1 | 47 | 1.15 |
| Embodiment 2 | 45 | 1.19 |
| Embodiment 3 | 44 | 1.21 |
| Embodiment 4 | 42 | 1.30 |
| Embodiment 5 | 43 | 1.27 |
| Comparative example 1 | 46 | 1.21 |
| Comparative example 2 | 39 | 1.25 |
Flame-proof antibiotic PP fiberboard of the invention has good anti-microbial property, fracture resistance, compressive property, stretches gently
Degree, Scratch Resistance energy, have good application prospect on construction material, automobile decoration piece, household, mechanical equipment component.It is fire-retardant anti-
The modification sisal fiber added in bacterium PP fiberboard not only enhances the tensile strength and scraping and wiping resistance performance of fiberboard, also has and inhales
The function of attached volatile organic matter reduces the smell of fiberboard.The adhesive added in flame-proof antibiotic PP fiberboard makes fiberboard
Close structure, compacting improve load-bearing, the tension, fracture resistance of fiberboard.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without
It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be within the scope of protection determined by the claims.
Claims (10)
1. a kind of flame-proof antibiotic PP fiberboard, which is characterized in that the raw material including following weight parts is prepared: 60-100 parts
PP, 10-30 parts of ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 1-4 parts of odium stearate.
2. a kind of flame-proof antibiotic PP fiberboard, which is characterized in that the raw material including following weight parts is prepared: 60-100 parts
PP, 10-30 parts of ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 1-4 parts of odium stearate, 2-
10 parts of adhesives.
3. a kind of flame-proof antibiotic PP fiberboard, which is characterized in that the raw material including following weight parts is prepared: 60-100 parts
PP, 10-30 parts of ABS, 2-6 parts of fire retardants, 0.5-2 parts of antioxidants, 0.005-0.02 parts of antibacterial agents, 3-12 parts of modified sisal hemps are fine
Dimension, 1-4 parts of odium stearate, 2-10 parts of adhesives.
4. flame-proof antibiotic PP fiberboard according to any one of claim 1-3, which is characterized in that the antioxidant is anti-
One of oxygen agent 1010, irgasfos 168 are a variety of.
5. flame-proof antibiotic PP fiberboard according to any one of claim 1-3, which is characterized in that the fire retardant is three
The mass ratio of (tribromo neopentyl) phosphate and magnesium hydroxide, three (tribromo neopentyl) phosphate and magnesium hydroxide is 3:1.
6. flame-proof antibiotic PP fiberboard according to any one of claim 1-3, which is characterized in that the antibacterial agent is oxygen
Change one of zinc, titanium oxide or a variety of.
7. flame-proof antibiotic PP fiberboard according to claim 2 or 3, which is characterized in that described adhesive includes that melamine is more
First alcohol, modified rosin resin, modified starch, methenamine, the melamine polyalcohol, modified rosin resin, modified starch, Wu Luo
The mass ratio of tropine is (3-5): (3-5): (3-5): 1.
8. flame-proof antibiotic PP fiberboard according to claim 3, which is characterized in that the preparation side of the modified sisal fiber
Method is as follows: (1) sisal fiber is crushed into 300 meshes, it is spare；8-15g diatomite is added in 1000-2000g water, in ultrasound
Wave frequency rate is 20-60kHz, power is 200-800W condition ultrasound 30-60 minutes, obtains diatomite dispersion liquid, to diatomite point
In dispersion liquid be added 8-16g polyvinyl alcohol, 10-30g chitosan, be heated to 60-80 DEG C, 60-80 DEG C, revolving speed be 200-600 turn/
Min is stirred 0.5-1.5 hours, and 80-120g sisal fiber is then added, and continues in 60-80 DEG C, revolving speed to be that 200-600 turns/min
800 meshes are crossed in stirring 20-60 minutes, filter cake are added in the glutaraldehyde water solution that 1200-1800g mass fraction is 2%, are added
Enter 3-8g ethyl acetate, be warming up to 55-65 DEG C, is that 200-600 turns/min stirring 20-60 minutes in 55-65 DEG C, revolving speed, crosses 800
Mesh, filter cake is 18-26 hours dry for 0.01-0.02MPa, 45-55 DEG C in absolute pressure；(2) filter cake after drying is added
Enter into 800-1500g paraffin oil, ultrasonic frequency is 20-60kHz, power is 200-800W condition ultrasound 30-60 minutes,
800 meshes are crossed, filter cake are added in the ethanol water that 500-1000g mass fraction is 75% to 90%, 0.1- is added
0.5mol silane coupling agent, is warming up to 55-65 DEG C, is 200-600 turns/min stirring 18-26 hours in 55-65 DEG C, revolving speed, so
Afterwards with 5000-8000 turn/min revolving speed be centrifuged 25-45 minute, take centrifugal sediment, absolute pressure be 0.01-0.02MPa,
45-55 DEG C 18-26 hours dry, obtains modified sisal fiber；The silane coupling agent is 4- aminopropyltriethoxy dimethoxy silicon
Alkane and/or N-2- aminoethyl -3- aminopropyltriethoxy diethoxy silane.
9. the preparation method of flame-proof antibiotic PP fiberboard according to claim 1 to 8, which is characterized in that including
Following step: weighing each raw material by weight, and each raw material is mixed, and turns/20-60 points of min stirring in 25-30 DEG C, 200-500
Clock then heats to 110-130 DEG C, 110-130 DEG C melting 20-50 minutes, be then pressed and molded, unload on vulcanizing press
Pressure is gone, natural cooling obtains flame-proof antibiotic PP fiberboard.
10. the preparation method of flame-proof antibiotic PP fiberboard according to claim 9, which is characterized in that include the following steps:
Each raw material is weighed by weight, each raw material is mixed, and is turned/min stirring 20-60 minutes in 25-30 DEG C, 200-500, is then heated up
To 110-130 DEG C, 110-130 DEG C melting 20-50 minutes, be then pressed and molded on vulcanizing press, for the first time be molded temperature
Degree is 150-180 DEG C, molding pressure 20-50MPa, and clamp time is 10-30 minutes, and second of molding temperature is 145-175
DEG C, then etc. molding pressure 15-30MPa, clamp time is 5-15 minutes, and temperature are down to 65-95 DEG C and shed pressure, naturally cold
But, flame-proof antibiotic PP fiberboard is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811617044.3A CN109694520A (en) | 2018-12-28 | 2018-12-28 | Flame-proof antibiotic PP fiberboard and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811617044.3A CN109694520A (en) | 2018-12-28 | 2018-12-28 | Flame-proof antibiotic PP fiberboard and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109694520A true CN109694520A (en) | 2019-04-30 |
Family
ID=66232241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811617044.3A Pending CN109694520A (en) | 2018-12-28 | 2018-12-28 | Flame-proof antibiotic PP fiberboard and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109694520A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121813A (en) * | 2007-08-02 | 2008-02-13 | 同济大学 | Full-degradation natural fibre/polylactic acid composite material and preparation method thereof |
| HK1208486A1 (en) * | 2015-05-27 | 2016-03-04 | Dongguan Kidsme Ind Ltd | A high wear-resistance and environmental educational toys and its manufacturing method |
| CN105566807A (en) * | 2016-01-29 | 2016-05-11 | 宁波远欣石化有限公司 | Heat-resistant stable plastic plate and preparation method thereof |
| CN108641191A (en) * | 2018-05-31 | 2018-10-12 | 占夏青 | antibacterial flame retardant plastic |
-
2018
- 2018-12-28 CN CN201811617044.3A patent/CN109694520A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121813A (en) * | 2007-08-02 | 2008-02-13 | 同济大学 | Full-degradation natural fibre/polylactic acid composite material and preparation method thereof |
| HK1208486A1 (en) * | 2015-05-27 | 2016-03-04 | Dongguan Kidsme Ind Ltd | A high wear-resistance and environmental educational toys and its manufacturing method |
| CN105566807A (en) * | 2016-01-29 | 2016-05-11 | 宁波远欣石化有限公司 | Heat-resistant stable plastic plate and preparation method thereof |
| CN108641191A (en) * | 2018-05-31 | 2018-10-12 | 占夏青 | antibacterial flame retardant plastic |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Labidi et al. | All-cellulose composites from alfa and wood fibers | |
| Huang et al. | Characterization of kraft lignin fractions obtained by sequential ultrafiltration and their potential application as a biobased component in blends with polyethylene | |
| Asasutjarit et al. | Materials and mechanical properties of pretreated coir-based green composites | |
| Kumar et al. | Studies on mechanical, thermal and dynamic mechanical properties of untreated (raw) and treated coconut sheath fiber reinforced epoxy composites | |
| Ashori et al. | Evaluation of Calotropis gigantea as a promising raw material for fiber-reinforced composite | |
| Espinach et al. | Flexural properties of fully biodegradable alpha-grass fibers reinforced starch-based thermoplastics | |
| Basta et al. | Performance assessment of deashed and dewaxed rice straw on improving the quality of RS-based composites | |
| Penjumras et al. | Mechanical properties and water absorption behaviour of durian rind cellulose reinforced poly (lactic acid) biocomposites | |
| Ogunsile et al. | Utilization of banana stalk fiber as reinforcement in low density polyethylene composite | |
| CN107779165B (en) | Manufacturing process of formaldehyde-free fiberboard | |
| CA2962611A1 (en) | Adhesive compositions comprising type-ii cellulose | |
| KR101457470B1 (en) | Paper with high dry strength containing hemicellulose and producing method thereof | |
| Asyraf et al. | Mechanical properties of sugar palm lignocellulosic fibre reinforced polymer composites: A review | |
| CN105150343A (en) | High-density fiberboard with absorption performance enhanced by adding modified paper sludge and preparation method thereof | |
| Sreenivasan et al. | Recent developments of kenaf fibre reinforced thermoset composites | |
| EP2888272A1 (en) | A method for recovering low molecular weight lignin from a filtrate | |
| Agu et al. | Physicochemical properties of lignocellulosic biofibres from South Eastern Nigeria: their suitability for biocomposite technology | |
| US20190119851A1 (en) | Lignocellulosic composites prepared with aqueous alkaline and urea solutions in cold temperatures systems and methods | |
| CN111823351A (en) | Preparation method of high-strength non-adhesive shaving board | |
| CN103406967A (en) | Method for preparing formaldehyde-free artificial board on basis of lignin adhesive | |
| CN101967295B (en) | Wood plastic starch composite material and preparation method thereof | |
| CN109694520A (en) | Flame-proof antibiotic PP fiberboard and preparation method thereof | |
| CN101134335A (en) | Method of producing biological degradation corn stalk fiber board with bionic structure | |
| CN101805461A (en) | Bio-based composite material and preparation method and application thereof | |
| Biao et al. | Preparation of nanocellulose with cation–exchange resin catalysed hydrolysis |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190430 |