CN109686935A - Application of the hydroascorbic acid as lithium ion battery organic cathode material - Google Patents
Application of the hydroascorbic acid as lithium ion battery organic cathode material Download PDFInfo
- Publication number
- CN109686935A CN109686935A CN201811540119.2A CN201811540119A CN109686935A CN 109686935 A CN109686935 A CN 109686935A CN 201811540119 A CN201811540119 A CN 201811540119A CN 109686935 A CN109686935 A CN 109686935A
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- CN
- China
- Prior art keywords
- lithium ion
- ion battery
- hydroascorbic acid
- electrode
- cathode material
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 32
- 239000002253 acid Substances 0.000 title claims abstract description 17
- 239000010406 cathode material Substances 0.000 title claims abstract description 12
- 239000011149 active material Substances 0.000 claims abstract description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 239000007773 negative electrode material Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002033 PVDF binder Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006230 acetylene black Substances 0.000 claims description 2
- 239000012300 argon atmosphere Substances 0.000 claims description 2
- 239000011889 copper foil Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 2
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims 1
- 229930003268 Vitamin C Natural products 0.000 claims 1
- 235000019154 vitamin C Nutrition 0.000 claims 1
- 239000011718 vitamin C Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000010189 synthetic method Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 239000007772 electrode material Substances 0.000 description 4
- 229910001290 LiPF6 Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical group OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910003307 Ni-Cd Inorganic materials 0.000 description 1
- 229910018502 Ni—H Inorganic materials 0.000 description 1
- 238000000627 alternating current impedance spectroscopy Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 propylene carbonate Ester Chemical class 0.000 description 1
- 238000011076 safety test Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Application of the hydroascorbic acid as lithium ion battery organic cathode material, belong to battery material field, the lithium ion battery organic cathode material uses active material of the hydroascorbic acid as negative electrode of lithium ion battery, the active material theoretical specific capacity height, abundant raw materials, at low cost, easy design are processed, and the synthetic method of the active material is simple, technology controlling and process is good, and production cost is low, and energy large-scale application is in industrialized production.
Description
Technical field
The invention belongs to battery material fields, and in particular, to a kind of lithium ion battery organic cathode material, more particularly to
Hydroascorbic acid is as lithium ion battery organic cathode material.
Background technique
With the rapid development of economy, exhaustive exploitation causes resource scarcity, the problems such as energy waste, environmental pollution, which becomes, works as
The focus of modern social concerns, high, energy density and power density are big with operating voltage for lithium ion battery, have extended cycle life, have
There are higher energy to weight ratio, energy volume ratio；, single-lithium-battery cell voltage is 3.6V, is equal to 3 ni-Cd or nickel-hydrogen chargeable cell
Series voltage, self discharge is small to store for a long time, this is battery superiority most outstanding, memory-less effect.Lithium battery is not
There are the so-called memory effects of nickel-cadmium cell, so the service life is long without electric discharge before lithium battery charging.Under normal running conditions, lithium
Battery charging/discharging cycle-index is much larger than 500 times, can be with quick charge.Lithium battery can usually use 0.5~1 times of capacity
Electric current charging, foreshortens to the charging time 1~2 hour, can be arbitrarily used in parallel；Due to being free of the weight such as cadmium, lead, mercury in battery
Metallic element, no pollution to the environment are the present age state-of-the-art green batteries, and the operating voltage of single battery is up to 3.6-3.9V,
It is 3 times of Ni-Cd, Ni-H battery, has a safety feature, nuisanceless, memory-less effect.Traditional lithium ion battery material is based on high
Expensive, non-renewable transition metal inorganic matter, compared with traditional lithium ion battery, organic electrode materials have raw material rich
Rich, the advantages that resource is renewable, at low cost.Therefore large-scale electric energy storage requirements are met, can be realized green sustainable development
Exhibition, it is necessary to develop new type lithium ion battery organic electrode materials.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of lithium ion battery negative material, the lithium ion battery is organic
Negative electrode material uses active material of the hydroascorbic acid composite material as lithium ion battery negative material, is able to ascend material
Safety and stability test, and the synthetic method of the active material is simple, and technology controlling and process is good, and production cost is low, can be big
Sizable application is in industrialized production.
The technical solution adopted by the present invention to solve the technical problems is.
Application of the hydroascorbic acid as lithium ion battery organic cathode material active material.
Lithium ion battery organic cathode material, the active material of the negative electrode material are hydroascorbic acid, and the dehydrogenation is anti-
The chemical composition C of bad hematic acid6H6O6。
Lithium ion battery organic cathode material, the active material of the negative electrode material are hydroascorbic acid, and the dehydrogenation is anti-
Bad hematic acid group is C6H6O6, chemical structural formula:
The reaction potential of the lithium ion battery negative material is 0.8V.
Lithium ion battery comprising hydroascorbic acid cell negative electrode material.
A kind of lithium ion battery, which is characterized in that C6H6O6Electrode slice is working electrode, and lithium metal is to electrode, glass fibers
Dimension is diaphragm.
The electrolyte solute that battery uses is LiPF6, solution concentration 1mol/L.
The beneficial effects of the present invention are:
1, according to current lithium ion battery status analysis, it is confined to graphite to the negative electrode material exploitation inertial thinking of lithium ion
And metal oxide field, the present invention develop a kind of organic cathode material, have widened grinding for ion cathode material lithium exploitation
Study carefully field and research direction.It is used in lithium ion battery for inexpensive industrial Organic Ingredients and case is provided, play resource
It makes full use of.
2, the hydroascorbic acid negative electrode material developed of the present invention, has that synthetic method is simple, production cost is low, technique control
Good this kind of lithium ion battery material of property processed is nontoxic, will not generate any harm to environment, have large-scale development space.
3, the hydroascorbic acid negative electrode material that the present invention develops can be prepared using the raw material of industry of rich reserves, and
And specific discharge capacity with higher.
Detailed description of the invention:
Fig. 1 is C6H6O6The infrared spectrogram of powder
Fig. 2 is C6H6O6The AC impedance spectroscopy of lithium ion battery
Fig. 3 is C6H6O6The constant current charge-discharge diagram of lithium ion battery electrode material:
Fig. 4 is C6H6O6The cycle performance figure of lithium ion battery electrode material
Fig. 5 is lithium ion battery structure schematic diagram.
1 anode cover, 2 lithium piece, 3 diaphragm, 4 negative electrode tab, 5 negative electrode casing
Specific embodiment
Below with reference to examples and drawings, the present invention is described in further detail, but embodiments of the present invention are not
It is limited to this.
Embodiment 1
Weigh the C of 140mg6H6O6Powder, 40mg acetylene black be added agate mortar in, grind 10 minutes, add dissolved with
The N-Methyl pyrrolidone solution 1ml (concentration 20mg/ml) of PVDF binder continues grinding 30 minutes, is then applied to copper foil
Upper preparation C6H6O6Electrode slice.By the electrode slice of preparation argon atmosphere glove box (MIKROUNA Universal 2440 |
750, water, oxygen are less than assembled battery in 0.5ppm), C6H6O6Electrode slice is working electrode, and lithium metal is to electrode, glass fibre
For diaphragm.The electrolyte solute that battery uses is LiPF6, solvent is (EC/PC 1:1 (w/w)), solution concentration 1mol/L.It will
The button cell of preparation uses the new prestige NEWARE battery detection equipment (CT- of new Weir polyelectron equipment Co., Ltd, Shenzhen
3008W) Lai Jinhang charge-discharge test.When it is 100mA/g that voltage range, which is 0.1-3V current density, reaction potential is 0.8V, first
Secondary specific discharge capacity is 600mAh/g, charge specific capacity 233.0mAh/g.Wherein EC is ethylene carbonate, and PC is propylene carbonate
Ester.
Claims (4)
1. application of the hydroascorbic acid as lithium ion battery organic cathode material active material, wherein the dehydrogenation Vitamin C
The chemical composition C of acidoHoOo, chemical structural formula:
2. a kind of lithium ion battery comprising hydroascorbic acid cell negative electrode material.
3. a kind of preparation method of lithium ion battery, which is characterized in that weigh the C of 140mgoHoOoPowder, 40mg acetylene black are added
It in agate mortar, grinds 10 minutes, adds the N-Methyl pyrrolidone solution dissolved with PVDF binder, continue 30 points of grinding
Then clock is applied on copper foil and prepares CoHoOoElectrode slice；By the assembled battery in the glove box of argon atmosphere of the electrode slice of preparation,
CoHoOoElectrode slice is working electrode, and lithium metal is to electrode, and glass fibre is diaphragm.
4. a kind of lithium ion battery comprising hydroascorbic acid cell negative electrode material, which is characterized in that when voltage range is
Reaction potential is 0.8V when 0.1-3V current density is 100mA/g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811540119.2A CN109686935B (en) | 2018-12-17 | 2018-12-17 | Application of dehydroascorbic acid as lithium ion battery organic negative electrode material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811540119.2A CN109686935B (en) | 2018-12-17 | 2018-12-17 | Application of dehydroascorbic acid as lithium ion battery organic negative electrode material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109686935A true CN109686935A (en) | 2019-04-26 |
| CN109686935B CN109686935B (en) | 2023-11-24 |
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|---|---|---|---|
| CN201811540119.2A Active CN109686935B (en) | 2018-12-17 | 2018-12-17 | Application of dehydroascorbic acid as lithium ion battery organic negative electrode material |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011095152A (en) * | 2009-10-30 | 2011-05-12 | Ritsumeikan | Method and device for electrochemical analysis of body fluid |
| CN104882608A (en) * | 2015-05-06 | 2015-09-02 | 江南大学 | Preparation method of N-doped 3D graphene/graphite lithium ion battery negative material |
| CN108107150A (en) * | 2017-12-19 | 2018-06-01 | 云南大学 | A kind of redox active method of preferred electrochemical process evaluation electrocatalysis material |
| CN108123143A (en) * | 2017-12-19 | 2018-06-05 | 大连理工大学 | A kind of method of direct ascorbic acid fuel-cell single-cell performance boost |
| CN209169309U (en) * | 2018-12-17 | 2019-07-26 | 北京工业大学 | A kind of lithium ion battery |
-
2018
- 2018-12-17 CN CN201811540119.2A patent/CN109686935B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011095152A (en) * | 2009-10-30 | 2011-05-12 | Ritsumeikan | Method and device for electrochemical analysis of body fluid |
| CN104882608A (en) * | 2015-05-06 | 2015-09-02 | 江南大学 | Preparation method of N-doped 3D graphene/graphite lithium ion battery negative material |
| CN108107150A (en) * | 2017-12-19 | 2018-06-01 | 云南大学 | A kind of redox active method of preferred electrochemical process evaluation electrocatalysis material |
| CN108123143A (en) * | 2017-12-19 | 2018-06-05 | 大连理工大学 | A kind of method of direct ascorbic acid fuel-cell single-cell performance boost |
| CN209169309U (en) * | 2018-12-17 | 2019-07-26 | 北京工业大学 | A kind of lithium ion battery |
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| Publication number | Publication date |
|---|---|
| CN109686935B (en) | 2023-11-24 |
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