CN109678217B - High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material - Google Patents
High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material Download PDFInfo
- Publication number
- CN109678217B CN109678217B CN201811538465.7A CN201811538465A CN109678217B CN 109678217 B CN109678217 B CN 109678217B CN 201811538465 A CN201811538465 A CN 201811538465A CN 109678217 B CN109678217 B CN 109678217B
- Authority
- CN
- China
- Prior art keywords
- solution
- concentration
- tap density
- mol
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention relates to Ni with high tap density0.8Co0.1Mn0.1(OH)2The preparation method of the material comprises the following concrete implementation steps: preparing nickel sulfate, cobalt sulfate and manganese sulfate into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, diluting strong ammonia water into a solution b with the concentration of 3-5 mol/L, diluting the strong ammonia water into a solution c with the concentration of 5-8 mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; ascorbic acid is dissolved in water to form a solution e. Then, the solution b and the solution e were poured into a 20L reactor as a base solution. Nitrogen was introduced into the reactor as a protective gas. Setting the temperature at 55 ℃, setting the stirring speed at 800r/min, and controlling the pH value between 10 and 11. Obtaining crude Ni after 50h of reaction0.8Co0.1Mn0.1(OH)2A material. Heat treating the crude product in an atmosphere furnace to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material. The method has the advantages of simple and safe process and low cost, and the obtained nickel-cobalt-manganese hydroxide precursor material has uniform particle distribution, excellent microstructure and better electrochemical performance.
Description
Technical Field
The invention relates to the technical field of lithium ion battery materials, in particular to Ni with high tap density0.8Co0.1Mn0.1(OH)2Method for producing material, Ni produced by the method0.8Co0.1Mn0.1(OH)2Materials and uses thereof.
Background
The increasing environmental pollution problem forces people to abandon the use of three traditional fossil fuels. The consumption of fossil fuels by automobiles is immeasurable every year, and the number of automobiles per year is increasing. The emergence of lithium-ion batteries will reverse this situation. New energy vehicles using lithium ion batteries are being sought by people. The endurance of the energy storage equipment of the new energy automobile directly influences the endurance of the new energy automobile.
At present, the energy storage device of the new energy automobile uses a lithium ion battery. The lithium ion battery is composed of anode materials, cathode materials, a diaphragm, electrolyte, a shell and other key materials. Therefore, the quality of the performance of the positive electrode material directly affects the quality of the battery performance.
The first generation of positive electrode material is mainly lithium cobaltate, which has good cycle stability and high gram volume. But cobalt is expensive as an important strategic resource, and the cost of large-scale commercial use is too high. In recent years, nickel-cobalt-manganese ternary cathode materials have attracted great attention. The ternary material has high gram capacity, good cycle stability and high voltage platform, and the price of nickel salt and manganese salt is less than one tenth of that of cobalt salt. Wherein the higher the nickel content in the ternary material, the higher the gram capacity; meanwhile, the lower the content of manganese, the more unstable the structure, so the 811 type nickel-cobalt-manganese ternary cathode material has the most application value.
The key technology for preparing the 811 type nickel-cobalt-manganese ternary cathode material is to prepare a precursor Ni0.8Co0.1Mn0.1(OH)2A material. The main methods for preparing the precursor at present comprise a solid phase method, a ball milling method, a Sol-gel method and coprecipitationStarch methods, and the like. The optimal preparation method is a first-push coprecipitation method, and the precursor prepared by the coprecipitation method is good in uniformity, high in sphericity and controllable in appearance. However, the co-precipitation method has many control factors, such as: the pH value, the reaction temperature, the concentration of the salt solution, the concentration of ammonia, the concentration of alkali, the flow rate of the salt solution, the flow rate of ammonia, the flow rate of alkali and the like all influence the shape and the tap density of the precursor. The precursors reported in the literature at present are unsatisfactory in two important indexes, namely morphology and tap density. Therefore, we propose a high tap density of Ni0.8Co0.1Mn0.1(OH)2A method for preparing the material.
Disclosure of Invention
In order to solve the problems of poor sphericity, low tap density and the like of a 811 type ternary cathode material precursor material, the invention provides Ni with high tap density0.8Co0.1Mn0.1(OH)2Method for producing material, Ni produced by the method0.8Co0.1Mn0.1(OH)2Materials and uses thereof.
The invention provides Ni with high tap density0.8Co0.1Mn0.1(OH)2The preparation method of the material comprises the steps of preparing nickel sulfate, cobalt sulfate and manganese sulfate into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, diluting industrial strong ammonia water into a solution b with the concentration of 3-5 mol/L, diluting industrial strong ammonia water into a solution c with the concentration of 5-8 mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; an appropriate amount of ascorbic acid was dissolved in water to form a solution e. Then pouring the solution b and the solution e into a 25L reaction kettle as a base solution, wherein the stirring speed is set to be 200r/min, and the temperature of the reaction kettle is set to be 40-60 ℃. Introducing nitrogen into the reaction kettle as protective gas to ensure Mn2+Not oxidized, and the flow rate of nitrogen gas is preferably set to 100 mL/min. When the temperature is increased to the set temperature, the stirring speed is increased to 800r/min, the solution a starts to be pumped, and the adding speed is set to 3 mL/min; then immediately pumping in the solution c, and setting the adding rate to be 2 mL/min; finally, the pH value is controlled by controlling the addition amount of the solution dBetween 10 and 13. Taking out the solution after reacting for 50h, filtering, vacuum drying at 80-120 ℃ for 24-48h, and sieving with a 100-mesh sieve to obtain crude Ni0.8Co0.1Mn0.1(OH)2A material. The crude product is thermally insulated for 2 to 15 hours in a blast drying oven at the temperature of 120 ℃ and 250 ℃ to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material.
The invention also provides Ni0.8Co0.1Mn0.1(OH)2Material passing through the above-mentioned Ni of high tap density0.8Co0.1Mn0.1(OH)2The preparation method of the material.
The invention also provides the Ni0.8Co0.1Mn0.1(OH)2Application of material, in particular spherical Ni with high tap density0.8Co0.1Mn0.1(OH)2The material can be used as a precursor of a ternary cathode material, and Ni is added0.8Co0.1Mn0.1(OH)2The 811 type ternary cathode material with excellent electrochemical performance can be obtained by mixing the material with a lithium source and then sintering at high temperature. Wherein the sintering step is as follows: the precursor material and a lithium source are uniformly mixed according to the molar ratio of lithium metal of 1: 1.02-1: 1.2, and the mixed powder is subjected to heat treatment at 700-900 ℃ for 10-20h, wet treatment, coating secondary sintering and the like to obtain the high-performance 811 type ternary cathode material.
Further, the lithium source is one or two of lithium carbonate, lithium hydroxide monohydrate, lithium acetate and lithium nitrate.
Further, the molar ratio of lithium metal in the precursor to the lithium source during the high-temperature calcination process is set to be 1: 1.04-1: 1.10.
Further, the heat treatment temperature in the high-temperature calcination process is 700-850 ℃.
Further, the heat preservation time of the high-temperature calcination process is set to be 10-15 h.
Compared with the prior art, the invention has the beneficial effects that:
the invention adopts a coprecipitation method to prepare the nickel hydroxide cobalt manganese precursor material with high tap density. The shape and tap density of the catalyst are controlled by adjusting the temperature, pH value, salt concentration, ammonia water concentration, alkali concentration, salt flow rate, ammonia water flow rate and alkali flow rate in the reaction process. The precursor material with high tap density directly influences the energy density of the sintered ternary cathode material.
Ni prepared by the invention0.8Co0.1Mn0.1(OH)2The material is pure phase, has uniform particle size distribution, high tap density and spherical morphology. Vibrating for 200 times per minute, and the tap density of the precursor material can reach 2.4g/cm after 3000 times of oscillation test3. After the lithium source is mixed, the high-nickel ternary cathode material is subjected to primary calcination, wet treatment, coating secondary calcination and the like to obtain the high-nickel ternary cathode material with excellent electrochemical performance (optimal electrochemical data is selected): the specific discharge capacity under 0.1C is as high as 205.6.mAh g-1The first coulombic efficiency is as high as 90.33%, the capacity retention rate after 800 cycles under a 3.0-4.2V and 1C/1C charge-discharge system is 94%, and the cycle performance is excellent.
Drawings
Fig. 1 and 2 are X-ray diffraction patterns of samples of example 1 and example 2, respectively. Wherein the abscissa is 2 theta/°, and theta is a diffraction angle;
FIGS. 3 and 4 are scanning electron microscope images at 3 Ktimes for samples of example 1 and example 2, respectively;
FIGS. 5 and 6 are full cell cycle performance curves for the finished ternary cathode materials of examples 1 and 2, respectively;
FIG. 7 shows Ni of the present application0.8Co0.1Mn0.1(OH)2Schematic of the preparation method of the material.
Detailed Description
The invention relates to Ni with high tap density0.8Co0.1Mn0.1(OH)2The preparation method of the material is implemented by the following steps:
as shown in figure 7, nickel sulfate, cobalt sulfate and manganese sulfate are prepared into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, industrial strong ammonia water is diluted into a solution b with the concentration of 3-5 mol/L, and the industrial strong ammonia water is dilutedReleasing the solution c with the concentration of 5-8 mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; an appropriate amount of ascorbic acid was dissolved in water to form a solution e. Then pouring the solution b and the solution e into a 25L reaction kettle as a base solution, wherein the stirring speed is set to be 200r/min, and the temperature of the reaction kettle is set to be 40-60 ℃. Introducing nitrogen into the reaction kettle as protective gas to ensure Mn2+Not oxidized, and the flow rate of nitrogen gas is preferably set to 100 mL/min. When the temperature is increased to the set temperature, the stirring speed is increased to 800r/min, the solution a starts to be pumped, and the adding speed is set to 3 mL/min; then immediately pumping in the solution c, and setting the adding rate to be 2 mL/min; finally, the pH value is controlled between 10 and 13 by controlling the addition amount of the solution d. Taking out the solution after reacting for 50h, filtering, vacuum drying at 80-120 ℃ for 24-48h, and sieving with a 100-mesh sieve to obtain crude Ni0.8Co0.1Mn0.1(OH)2A material. The crude product is thermally insulated for 2 to 15 hours in a blast drying oven at the temperature of 120 ℃ and 250 ℃ to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material.
Example 1 high tap Density of Ni0.8Co0.1Mn0.1(OH)2Preparation of the Material
Preparing nickel sulfate, cobalt sulfate and manganese sulfate into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, diluting industrial strong ammonia water into a solution b with the concentration of 4mol/L, diluting industrial strong ammonia water into a solution c with the concentration of 5mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; an appropriate amount of ascorbic acid was dissolved in water to form a solution e. Then the solution b and the solution e are poured into a 25L reaction kettle as a base solution, the stirring speed is set to be 200r/min, and the temperature of the reaction kettle is set to be 60 ℃. Nitrogen gas was introduced into the reaction vessel as a protective gas, and the flow rate of nitrogen gas was set to preferably 100 mL/min. When the temperature is increased to the set temperature, the stirring speed is increased to 800r/min, the solution a starts to be pumped, and the adding speed is set to 3 mL/min; then immediately pumping in the solution c, and setting the adding rate to be 2 mL/min; finally, the pH value is controlled to be 11 by controlling the addition amount of the solution d. Taking out the solution after reacting for 50h, filtering, vacuum drying at 80 ℃ for 24h, and sieving with a 100-mesh sieve to obtain coarse powderProduct Ni0.8Co0.1Mn0.1(OH)2A material. Keeping the temperature of the crude product in a blast drying oven at 120 ℃ for 10h to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material.
Performance testing and characterization
FIG. 1 is an XRD pattern of a sample of example 1, and a diffraction peak is consistent with a diffraction peak of standard card JCPDS (14-117), and has a typical layered structure characteristic of a ternary cathode material. Diffraction peaks in the figure are sharp, which indicates that the crystal form of the sample is relatively complete. The absence of impurity peaks indicates a very high purity of the material.
The table shows the results of atomic emission spectroscopy analysis of the samples of example 1, and analysis of the data shows that the elemental ratios of the samples of example are substantially consistent with those of the samples of example at the beginning of the design. The reliability of this process is more pronounced.
TABLE EXAMPLE 1ICP test
FIG. 3 is an SEM image of a sample of example 1. Obviously, the samples of the examples have high sphericity and good homogeneity, with a particle size of substantially around 10 microns. The tap density is as high as 2.29g/cm3After mixing the lithium source, the electrochemical properties of the high-nickel ternary cathode material after the treatments such as primary sintering, wet processing, coating secondary sintering and the like are shown in fig. 5: the discharge specific capacity under 0.1C is up to 203.6.mAh g-1The first coulombic efficiency is 89.70%, the capacity retention rate after 500 cycles under a 3.0-4.2V and 1C/1C charge-discharge system is 95%, and the cycle performance is excellent.
Example 2 high tap Density of Ni0.8Co0.1Mn0.1(OH)2Preparation of the Material
Preparing nickel sulfate, cobalt sulfate and manganese sulfate into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, diluting industrial strong ammonia water into a solution b with the concentration of 5mol/L, diluting industrial strong ammonia water into a solution c with the concentration of 7mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; mixing the right amount ofAscorbic acid dissolves in water to form a solution e. Then the solution b and the solution e are poured into a 25L reaction kettle as a base solution, the stirring speed is set to be 200r/min, and the temperature of the reaction kettle is set to be 50 ℃. Nitrogen gas was introduced into the reaction vessel as a protective gas, and the flow rate of nitrogen gas was set to preferably 100 mL/min. When the temperature is increased to the set temperature, the stirring speed is increased to 800r/min, the solution a starts to be pumped, and the adding speed is set to 3 mL/min; then immediately pumping in the solution c, and setting the adding rate to be 2 mL/min; finally, the pH value is controlled to be 11 by controlling the addition amount of the solution d. Taking out the solution after reacting for 50h, filtering, vacuum drying at 120 ℃ for 24h, and sieving by a 100-mesh sieve to obtain a crude product Ni0.8Co0.1Mn0.1(OH)2A material. Keeping the temperature of the crude product in a blast drying oven at 200 ℃ for 10h to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material.
Performance testing and characterization
FIG. 2 is the XRD pattern of the sample of example 1, and the diffraction peak is consistent with the diffraction peak of standard card JCPDS (14-117), and has the characteristic of a typical layered structure of a ternary cathode material. Diffraction peaks in the figure are sharp, which indicates that the crystal form of the sample is relatively complete. The absence of impurity peaks indicates a very high purity of the material.
And the second table shows the detection results of the atomic emission spectrometer of the samples in the embodiment, and analysis data can find that the element proportion of the samples in the embodiment is basically consistent with that of the samples in the embodiment at the beginning of design. The reliability of this process is more pronounced.
TABLE II EXAMPLE 2ICP test
FIG. 4 is an SEM image of a sample of example 2. Obviously, the samples of the examples have high sphericity and good homogeneity, with a particle size of substantially around 10 microns. The tap density is as high as 2.33g/cm3After mixing the lithium source, the electrochemical properties of the high-nickel ternary cathode material after the treatments such as primary sintering, wet processing, coating secondary sintering and the like are shown in fig. 6: the discharge specific capacity at 0.1C is up to 204.6mA h g-1The first coulombic efficiency is as high as 90.12%, the capacity retention rate after 500 cycles under a charging and discharging system of 3.0-4.2V and 1C/1C is 95%, and the cycle performance is excellent.
Claims (1)
1. High tap density Ni0.8Co0.1Mn0.1(OH)2The preparation method of the material is characterized by comprising the following steps:
step 1: preparing nickel sulfate, cobalt sulfate and manganese sulfate into a solution a with the concentration of 2mol/L according to the molar ratio of 8:1:1, diluting industrial strong ammonia water into a solution b with the concentration of 3-5 mol/L, diluting industrial strong ammonia water into a solution c with the concentration of 5-8 mol/L, and preparing sodium hydroxide into a solution d with the concentration of 3 mol/L; dissolving a proper amount of ascorbic acid in water to form a solution e;
step 2: pouring the solution b and the solution e into a 25L reaction kettle in sequence to be used as base solution, wherein the stirring speed is set to be 200r/min, and the temperature of the reaction kettle is set to be 55 ℃; introducing nitrogen into the reaction kettle as protective gas to ensure Mn2+Not oxidized, wherein the flow rate of nitrogen gas is set to 100 mL/min;
and step 3: when the temperature is increased to 40-60 ℃, the stirring speed is increased to 800r/min, the solution a is pumped in, and the adding speed is set to 3 mL/min; then immediately pumping in the solution c, and setting the adding rate to be 2 mL/min; finally, controlling the pH value to be between 10 and 13 by controlling the addition amount of the solution d;
and 4, step 4: taking out the solution after reacting for 50h, filtering, vacuum drying for 24-48h at 80-120 ℃, and then sieving by a 100-mesh sieve to obtain a crude product Ni0.8Co0.1Mn0.1(OH)2A material;
and 5: the crude product is thermally insulated for 2 to 15 hours in a blast drying oven at the temperature of 120 ℃ and 250 ℃ to obtain Ni with high tap density0.8Co0.1Mn0.1(OH)2A material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811538465.7A CN109678217B (en) | 2018-12-16 | 2018-12-16 | High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811538465.7A CN109678217B (en) | 2018-12-16 | 2018-12-16 | High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109678217A CN109678217A (en) | 2019-04-26 |
| CN109678217B true CN109678217B (en) | 2021-12-31 |
Family
ID=66187774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811538465.7A Active CN109678217B (en) | 2018-12-16 | 2018-12-16 | High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109678217B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112191212B (en) * | 2020-12-02 | 2021-02-26 | 河南科隆新能源股份有限公司 | Reaction kettle and method for preparing precursor of lithium ion battery anode material |
| CN114655998A (en) * | 2022-03-01 | 2022-06-24 | 西安理工大学 | Preparation method of high-nickel ternary positive electrode precursor |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1622371A (en) * | 2004-12-30 | 2005-06-01 | 清华大学 | Process for preparing high density spherical nickel-cobalt lithium manganate as anode material of lithium ion cell |
| CN101269849A (en) * | 2008-03-05 | 2008-09-24 | 广州融捷材料科技有限公司 | High-density spherical lithium nickel cobalt manganese oxygen and method for preparing the same |
| CN101662025A (en) * | 2009-09-21 | 2010-03-03 | 昆明理工大学 | Lithium ion battery anode active material and preparing method thereof |
| CN103482711A (en) * | 2013-09-06 | 2014-01-01 | 大连瑞源动力有限公司 | Ultrasonic assisted method for preparing precursor of ternary positive material of lithium ion battery |
| CN104852038A (en) * | 2015-04-08 | 2015-08-19 | 中国科学院长春应用化学研究所 | Preparation method of high-capacity quickly-chargeable/dischargeable lithium ion battery ternary anode material |
| CN105375020A (en) * | 2015-11-28 | 2016-03-02 | 中信大锰矿业有限责任公司大新锰矿分公司 | Preparation method of spherical lithium nickel cobalt manganese oxide precursor mixture |
| CN106058237A (en) * | 2016-07-07 | 2016-10-26 | 成都翔羽科技有限公司 | Method for continuously preparing nanoflower lithium ion battery layered anode material and reaction kettle thereof |
| CN106602004A (en) * | 2015-10-19 | 2017-04-26 | 河南科隆新能源股份有限公司 | High-safety power lithium ion secondary battery composite positive material and preparation method thereof |
| CN106745336A (en) * | 2016-12-28 | 2017-05-31 | 杉杉能源（宁夏）有限公司 | A kind of precursor of nickel-cobalt-lithium-manganese-oxide of nanometer sheet reunion second particle and preparation method thereof |
| CN107324405A (en) * | 2017-07-07 | 2017-11-07 | 金驰能源材料有限公司 | A kind of lithium nickel cobalt manganese oxide precursor and preparation method thereof and the lithium ion battery prepared by the presoma |
| CN107342417A (en) * | 2016-12-28 | 2017-11-10 | 杉杉能源（宁夏）有限公司 | A kind of high ni-type precursor of nickel-cobalt-lithium-manganese-oxide with specific morphology and preparation method thereof |
| CN107742720A (en) * | 2017-10-17 | 2018-02-27 | 哈尔滨工业大学（威海） | A kind of preparation method of ternary cathode material of lithium ion battery presoma |
| CN108264096A (en) * | 2016-12-30 | 2018-07-10 | 北京当升材料科技股份有限公司 | A kind of preparation method of high density little particle nickel cobalt manganese hydroxide |
| CN108365216A (en) * | 2018-04-18 | 2018-08-03 | 西南石油大学 | The novel nickelic tertiary cathode material of one kind and preparation |
| CN108807968A (en) * | 2018-08-09 | 2018-11-13 | 中国恩菲工程技术有限公司 | Nickel-cobalt-manganese ternary persursor material and its synthetic method |
| CN108987682A (en) * | 2017-06-02 | 2018-12-11 | 杉杉能源（宁夏）有限公司 | It can prevent the preparation method of the Ni-based persursor material of richness of breakage of particles |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107611383B (en) * | 2017-08-25 | 2020-05-19 | 浙江华友钴业股份有限公司 | Preparation method of nickel-cobalt-manganese ternary precursor with low sulfur and high tap density |
-
2018
- 2018-12-16 CN CN201811538465.7A patent/CN109678217B/en active Active
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1622371A (en) * | 2004-12-30 | 2005-06-01 | 清华大学 | Process for preparing high density spherical nickel-cobalt lithium manganate as anode material of lithium ion cell |
| CN101269849A (en) * | 2008-03-05 | 2008-09-24 | 广州融捷材料科技有限公司 | High-density spherical lithium nickel cobalt manganese oxygen and method for preparing the same |
| CN101662025A (en) * | 2009-09-21 | 2010-03-03 | 昆明理工大学 | Lithium ion battery anode active material and preparing method thereof |
| CN103482711A (en) * | 2013-09-06 | 2014-01-01 | 大连瑞源动力有限公司 | Ultrasonic assisted method for preparing precursor of ternary positive material of lithium ion battery |
| CN104852038A (en) * | 2015-04-08 | 2015-08-19 | 中国科学院长春应用化学研究所 | Preparation method of high-capacity quickly-chargeable/dischargeable lithium ion battery ternary anode material |
| CN106602004A (en) * | 2015-10-19 | 2017-04-26 | 河南科隆新能源股份有限公司 | High-safety power lithium ion secondary battery composite positive material and preparation method thereof |
| CN105375020A (en) * | 2015-11-28 | 2016-03-02 | 中信大锰矿业有限责任公司大新锰矿分公司 | Preparation method of spherical lithium nickel cobalt manganese oxide precursor mixture |
| CN106058237A (en) * | 2016-07-07 | 2016-10-26 | 成都翔羽科技有限公司 | Method for continuously preparing nanoflower lithium ion battery layered anode material and reaction kettle thereof |
| CN106745336A (en) * | 2016-12-28 | 2017-05-31 | 杉杉能源（宁夏）有限公司 | A kind of precursor of nickel-cobalt-lithium-manganese-oxide of nanometer sheet reunion second particle and preparation method thereof |
| CN107342417A (en) * | 2016-12-28 | 2017-11-10 | 杉杉能源（宁夏）有限公司 | A kind of high ni-type precursor of nickel-cobalt-lithium-manganese-oxide with specific morphology and preparation method thereof |
| CN108264096A (en) * | 2016-12-30 | 2018-07-10 | 北京当升材料科技股份有限公司 | A kind of preparation method of high density little particle nickel cobalt manganese hydroxide |
| CN108987682A (en) * | 2017-06-02 | 2018-12-11 | 杉杉能源（宁夏）有限公司 | It can prevent the preparation method of the Ni-based persursor material of richness of breakage of particles |
| CN107324405A (en) * | 2017-07-07 | 2017-11-07 | 金驰能源材料有限公司 | A kind of lithium nickel cobalt manganese oxide precursor and preparation method thereof and the lithium ion battery prepared by the presoma |
| CN107742720A (en) * | 2017-10-17 | 2018-02-27 | 哈尔滨工业大学（威海） | A kind of preparation method of ternary cathode material of lithium ion battery presoma |
| CN108365216A (en) * | 2018-04-18 | 2018-08-03 | 西南石油大学 | The novel nickelic tertiary cathode material of one kind and preparation |
| CN108807968A (en) * | 2018-08-09 | 2018-11-13 | 中国恩菲工程技术有限公司 | Nickel-cobalt-manganese ternary persursor material and its synthetic method |
Non-Patent Citations (1)
| Title |
|---|
| 高容量镍基正极材料LiNi0.8Co0.1Mn0.1O2的制备与改性研究;彭弯弯;《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》;20180715;C042-645 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109678217A (en) | 2019-04-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110518220B (en) | Nickel-cobalt-manganese-aluminum quaternary positive electrode material with high nickel gradient and preparation method thereof | |
| CN114920306B (en) | Positive electrode material precursor, positive electrode material, preparation method of positive electrode material precursor and sodium ion battery | |
| CN102074679B (en) | Method for preparing spherical aluminum-doped nickel lithium carbonate for lithium ion battery positive electrode material | |
| CN106910887B (en) | Lithium-rich manganese-based positive electrode material, preparation method thereof and lithium ion battery containing positive electrode material | |
| CN109778301A (en) | The preparation of one type monocrystalline lithium-rich oxide material and application | |
| CN105304893A (en) | Preparation method of lithium ion battery anode active material lithium nickel manganese oxide | |
| CN103715424A (en) | Core-shell structured cathode material and preparation method thereof | |
| CN113620354A (en) | Surface-coated lithium ion battery anode material precursor and preparation method thereof | |
| CN110540254A (en) | Boron-magnesium co-doped gradient nickel cobalt lithium manganate positive electrode material and preparation method thereof | |
| CN113540436A (en) | Tungsten ion doped high nickel gradient ternary positive electrode material and preparation method thereof | |
| WO2015039490A1 (en) | Lithium-rich anode material and preparation method thereof | |
| CN113644272B (en) | Cerium-bismuth composite oxide doped lithium ion battery positive electrode material and preparation method thereof | |
| CN113603154A (en) | High-voltage nickel-cobalt-manganese ternary precursor and preparation method thereof | |
| CN112310391B (en) | Positive electrode material precursor, positive electrode material and preparation method thereof, lithium ion battery positive electrode, lithium ion battery and electric equipment | |
| CN112811477A (en) | Method for controlling synthesis of single crystal ternary cathode material through precursor | |
| CN108365216A (en) | The novel nickelic tertiary cathode material of one kind and preparation | |
| CN113690430A (en) | Lithium-rich manganese-based positive electrode material for realizing accurate lithium preparation and preparation method and application thereof | |
| CN111342008A (en) | Potassium fluoride doped lithium-rich manganese-based material and preparation method and application thereof | |
| CN114162881A (en) | Preparation method of anion in-situ doped high-nickel ternary cathode material | |
| CN114804230B (en) | NCA positive electrode material precursor with core-shell structure, and preparation method and application thereof | |
| CN109678217B (en) | High tap density Ni0.8Co0.1Mn0.1(OH)2Preparation method and application of material | |
| CN106684350B (en) | Preparation method of high-voltage positive electrode material lithium nickel manganese oxide | |
| CN112582587A (en) | Core-shell structure high-nickel cathode material with single crystal as core and preparation method thereof | |
| CN110690444A (en) | High-nickel ternary cathode material with layered porous structure, and preparation method and application thereof | |
| CN112952056B (en) | Lithium-rich manganese-based composite cathode material and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 312300 No. 5 Weiqi East Road, Hangzhou Bay Economic and Technological Development Zone, Shangyu District, Shaoxing City, Zhejiang Province Applicant after: Zhejiang Haichuang lithium battery technology Co.,Ltd. Address before: 312300 No. 5 Weiqi East Road, Hangzhou Bay Economic and Technological Development Zone, Shangyu District, Shaoxing City, Zhejiang Province Applicant before: ZHEJIANG MEIDU HAICHUANG LITHIUM ELECTRICITY TECHNOLOGY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |