Gas burning rate test device
Technical field
The present invention relates to a kind of gas burning rate test devices.
Background technique
The flammability classification of gas chemicals mainly passes through explosion limit (upper explosion limit, lower explosion limit), gas pressure at present
Two kinds of parameters of power are classified, the burn rate of gas as gas and the characterization parameter of oxygen mixture after-combustion characteristic more
It can reflect the risk of gas chemicals, therefore the parameter is introduced in the dangerous nature classification of gas chemicals.The United Nations
" global chemicals homogeneous classification and labeling system " using gas burn rate as judge the combustible important parameter of gas it
One, but there is no the design and research and development of such gas burn rate test equipment on the market at present, the invention patent is test gas
Burn rate provides a kind of quickly and effectively test device, can quickly and effectively test the burn rate of gas, and tested
Cheng Zhiguan, data acquisition are simple, quick.
Summary of the invention
The technical problem to be solved by the present invention is to there is no gas burning rate test device in the prior art, mention
For a kind of new gas burning rate test device.The device is intuitive with experimentation, data acquisition is simple, quickly
The advantages of.
To solve the above problems, The technical solution adopted by the invention is as follows: a kind of gas burning rate test device, mainly
Including testing tube, mixing vessel, ignition system and gas handling system, mixing vessel connects with air feed tank, and container bottom is set
There is magnetic agitation, shell of tank is equipped with plus surveys layer, and container top is equipped with pressure test amount device and vacuum pump, magnetic agitation peace
Mounted in the bottom of mixing vessel, purge gas pipeline one end is connected with mixing vessel, and the other end is connected with the tube inlet of testing tube,
Tube inlet is connected by quenching screen with testing tube, and quenching screen is mounted on the both ends of testing tube, testing tube outlet shielded by quenching and
Polyvinyl chloride pipe be connected, the polyvinyl chloride pipe other end is connected with gas expansion tank, the outlet of testing tube communicated with atmosphere or with gas
The connection of body processing system, testing tube tail end install ignition system and damping hole.
In above-mentioned technical proposal, it is preferable that testing tube must have scale, and minimum scale cannot be greater than 1mm.
In above-mentioned technical proposal, it is preferable that the shell of mixing vessel is equipped with heating layer.
In above-mentioned technical proposal, it is preferable that quenching screen cannot be with HF and NH3It reacts.
In above-mentioned technical proposal, it is preferable that testing tube is fixed in vertical support, and is located at below ignition system.
In above-mentioned technical proposal, it is preferable that testing tube is glass material.
In above-mentioned technical proposal, it is preferable that the upper end of testing tube is connected with mixture container.
In above-mentioned technical proposal, it is preferable that the electrode of ignition system uses tungsten material, and electrode is fixed to use polytetrafluoroethylene (PTFE)
Plug.
In above-mentioned technical proposal, it is preferable that the diameter of damping hole is 9mm~11mm.
In above-mentioned technical proposal, it is preferable that gas handling system is containing the collecting tank for neutralizing solution, and gas expansion tank goes out
Mouth pipeline deeply contains in the collecting tank for neutralizing solution.
In above-mentioned technical proposal, it is preferable that testing tube axial direction is equipped at least one temperature-measuring element.
In above-mentioned technical proposal, it is preferable that be equipped with hood or washer at the top of collecting tank.
This patent provides a kind of gas burning rate test device, for testing after gas chemicals and oxygen mix in pipe
Interior burn rate, for assessing the flammability of gas chemicals, with experimentation, intuitive, test result was acquired
Simple, the quick advantage of journey, achieves preferable technical effect.
Detailed description of the invention
Fig. 1 is testboard schematic diagram.
In Fig. 1:
1 mixing vessel, 2 magnetic agitation
3 purge gas pipeline, 4 tube inlet
5 quenching 6 testing tubes of screen
7 electrode, 8 mounting hole
9 quenching 10 polyvinyl chloride pipes of screen
11 incendiary source, 12 gas expansion tank
13 contain the collecting tank for neutralizing solution
A air feed tank b pressure measurement
The outlet of c vacuum pump d pipe
E temperature measures f incendiary source
G hood h heating layer
Fig. 2 is testing tube schematic diagram.
In Fig. 2: 1, equipment is fixedly mounted;2, electrode tube;3, pipe end entrance
Fig. 3 is schematic diagram at pipe lower end ignitor and damping hole
In Fig. 3: 1, nut;2, polyfluortetraethylene pipe;3, quenching screen;4, polytetrafluoroethylene (PTFE) mounting hole;5, polytetrafluoroethylene (PTFE)
Plug;6, testing tube;7,1 mm dia electrode;8, power supply.
Fig. 4 is the schematic diagram of vertical tube Flame Propagation.
In Fig. 4: 1, the direction of flame propagation;2, unburned mixture;3, flame front;4, flame front is displaced; 5,
Unburned gas;6, incendiary source
The present invention will be further described below by way of examples, but is not limited only to the present embodiment.
Specific embodiment
[embodiment 1]
A kind of gas burning rate test device, as shown in Figure 1, mainly include testing tube, mixing vessel, ignition system with
And gas handling system, mixing vessel connect with air feed tank, container bottom is equipped with magnetic agitation, and shell of tank is equipped with heating layer,
Container top is equipped with pressure test amount device and vacuum pump, and magnetic agitation is mounted on the bottom of mixing vessel, purge gas pipeline
One end is connected with mixing vessel, and the other end is connected with the tube inlet of testing tube, and tube inlet is connected by quenching screen with testing tube,
Quenching screen is mounted on the both ends of testing tube, and testing tube outlet is connected by quenching screen with polyvinyl chloride pipe, and polyvinyl chloride pipe is another
End is connected with gas expansion tank, and the outlet of testing tube is communicated with atmosphere or connect with gas handling system, the installation of testing tube tail end
Ignition system and damping hole.
(1) mixing vessel 1.Mixture container is used for hybrid test gas.Mixing vessel connects with air feed tank a, container bottom
Portion is equipped with magnetic agitation 2, and shell of tank is equipped with heating layer h, and container top is equipped with pressure test amount device b, temperature measuring device
E and vacuum pump c.
(2) magnetic agitation 2.Magnetic agitation is mounted on the bottom of mixing vessel.
(3) purge gas pipeline 3.3 one end of purge gas pipeline is connected with mixing vessel, and one end and the pipe of testing tube 6 enter
Mouth 4 is connected.
(4) tube inlet 4.Tube inlet 4 is connected by quenching peaceful screen sliding barrier 5 with testing tube 6.
(5) quenching screen 5 and 9.Quenching screen is mounted on the both ends of pipe, and quenching screen cannot react with HF and NH3, in order to avoid
Adverse effect is generated to ambient enviroment.Quenching screen should be equipped with the mesh of certain size.The quenching screen distance of HCs should about 2
Millimeter quenches screen distance and reduces if burn rate declines.
(6) testing tube 6
The design of testing tube should can make flame propagation reduce interference, especially ignition phase or flame propagation as far as possible
First stage.The discharge of close gas and processing system that ignition system, quenching system and damping hole should design as far as possible
System.The convenience that the outlet (bottom) of pipe should design is connect with gas treatment and exhaust system.Pipe should be fixed on vertical support
On, and below ignition system, to prevent fixed support interferences flame propagation (sub-cooled) or generate shadow to flame image
It rings.
1. size
Testing tube is glass material, 1.2 meters long, and inside diameter is 40 millimeters, has scale, and minimum scale cannot be greater than
1mm.The setting of this diameter is because will increase quenching effect in narrow pipe, and have better flame stabilization to propagate
Environment, if the loss of tube wall is lesser, but will increase unstability using larger-diameter pipe.40 millimeters of selection straight
Diameter most convenient is used to test the burn rate lower than 40cm/s.It is able to bear the atmospheric pressure of 100kPa or more, although over-voltage
The case where it is very limited, the bottom of pipe be opening.
2. installing
The pipe is placed on a vertical position, from convection effects before the flame to reduce possible deformation, and ensures
One more symmetrical shape.In this position, light a fire in the lower end of pipe, flame upwardly propagates.
3. the tail end of pipe
The tail end of pipe is communicated with atmosphere.Tail end installation ignition system and damping hole, usable nut fix the system.By
It can contain in combustion product and be corrosive or the harmful constituent of toxicity, such as hydrogen fluoride, hydrogen chloride, ammonia, therefore in pipe
Tail end installs a gas aftertreatment system.If using gas after-treatment system, which does not allow over-voltage, combustion product
It can freely escape from pipe, and be expanded in a tank greater than 100 liters.
The upper end of pipe is connected with mixture container, and after coming out from mixing vessel, mixed gas enters in pipe, and from bottom of the tube
Out.Nut stationary exit system can be used.Before the root of igniting and flame starts propagation, the tail end of pipe is closing
's.
4. pipe type of glass
Most of flame emission spectrums assume within the distance of 250nm and 600nm.Excessive loss in order to prevent, therefore
It is recommended that selection quartz glass, borosilicate glass.
(7) electrode 7
Electrode uses tungsten material, diameter 1mm.The distance between electrode is 6.4mm.Electrode is fixed to use polytetrafluoroethylene (PTFE)
Plug.
In order to ensure burning condition, especially near the lower propagation limit and the higher propagation limit, electrode should be again clear
Reason, to remove any deposit.
(8) replaceable damping hole 8
Rate of flame propagation and the shape of flame are related with the component of combustible substance and mixture.At bottom opening
The hole of insertion calibration adjusts existing diameter, for reducing the unstability of flame and preventing acoustic effect, before adjusting flame
Cutting edge of a knife or a sword shape forms a good flame front shape.The diameter of the damping hole of the pipe of 40 millimeters of internal diameters can be 9mm~
11mm.It only needs to use damping hole when burn rate is too fast and mixture concentration is big.
(10) polyvinyl chloride pipe 10
(11) incendiary source 11
Incendiary source can influence combustion limits or even flame combustion mechanism.Spark ignition is via many researchers'
Analysis and processing arrange, electrode type (such as flange electrode), material and size, gap distance, spark duration and breakdown
The influence of voltage and these minimum ignition energies.
1. Source Type of lighting a fire
The incendiary source is that there are two the spark ignition sources of electrode for band.
2. installing
Igniting occurs in the bottom of pipe, therefore electrode is fixed on the opposite direction of axis, on the upper surface in commutative hole
At 5mm~10mm.
(12) gas expansion tank 12
The expansion drum being connected between gas handling system and the outlet end of pipe, to simulate constant pressure exaggerated conditions.Extraction fan
Combustion product discharge in pipe is arrived into absorbing liquid by gas expansion tank, then remaining clean gas is arranged by exhaust outlet
Out.
(13) there is the collecting tank 13 for neutralizing solution
The combustion product of previous trial should be all thoroughly removed after test every time, and guarantees that combustion product will not be to work people
Member and environment generate adverse effect.Therefore suitable vent gas treatment mode should be selected, burnt especially for halogenated hydrocarbons
After can generate hydrogen fluoride or hydrogen chloride etc., should be neutralized as early as possible, reduce corrosion to instrument and equipment.
(14) material requirement: all components of all component, link member and experimental bench should resistance to gas attack, such as
Ammonia and copper can react, and other oxidation reactions etc..Stainless steel or other corrosion-resistant materials can be used.
A. air feed tank
One end is connected in mixing vessel, for providing various gases.
B. pressure measurement
Installation on the mixing vessel, measures the pressure of mixing vessel.
C. vacuum pump
It installs on the mixing vessel, for vacuumizing.
D. pipe exports
On the mixing vessel, the gas to be tested mixed is exported from pipe enters test via purge gas pipeline for installation
Pipe.
G. hood
It is mounted on the end of exhaust treatment system, for tail gas to be discharged.
H. heating layer
It is mounted on mixture container outer layer, settable different heating temperature, with the gas burning tested under different temperatures
Rate.
[specific implementation method]
1) experiment should check following items before starting
1. using dry air or nitrogen purging test system;
2. checking inter-electrode gap distance and whether in centre;
3. selecting suitable exit duct diameter.
2) mixture container and all connecting tubes and testing tube first have to be evacuated to 10Pa or less.
3) mixed gas is filled into mixing vessel according to corresponding intrinsic standoff ratio.It should be incited somebody to action when often filling a kind of new gas
Junction vacuumizes.Magnetic agitation should when starting to fill opening, and turned off after at least 5 minutes after filling.
4) mixing vessel layer heating temperature is set.
5) mixed gas is from mixing vessel, by testing tube, then from the outlet end of pipe, is discharged by hood.At least
It is recycled using 13 times of pipe volume of gas of test.
Once mixed gas completes circulation in pipe, mixing vessel should be separated from pipe, to prevent in stop combustion mixing vessel
Gas.
6) upper end of pipe should be first shut off, and the bottom end then closed is closed immediately, to prevent the gas of electrode zone from occurring
Any dilution or variation.
7) it waits 5~10 seconds, so that the gas in pipe is static.
8) lower end should gently open, and any disturbance or concentration variation occurs to avoid ignition zone, then lights a fire.Igniting
Before, camera is opened, image is recorded, for calculating flame propagation velocity and its surface area.Firing time interval should be designed as
0.3 ±0.05s.This time is certified as the time for being most suitable for testing combustion limits.
9) after flame propagation, in the upper end hardening of pipe, combustion product is by nitrogen or air circulation lead-in tube.If
There is harmful products of combustion, suitable exhaust treatment system should be used.Hydrogen fluoride in HFCs or HCFCs combustion product or
Person's hydrogen chloride etc. is contacted with water generates corrosion to pipeline after a test, becomes opaque white.According to pipeline cleaning degree
Difference, the probability of generation are about 30~50%.Therefore, pipeline should be cleared up using dry nitrogen as early as possible after the end of the test.
10) result calculates.The flame that record video camera is continuously shot, the rate of gas burning are that flame front is displaced and sends out
The ratio of the time of raw displacement.
The gaseous mixture of certain hydrogen and nitrogen tests its burn rate, and specific implementation process is as follows:
1) experiment should check following items before starting
1. using dry air or nitrogen purging test system;
2. checking inter-electrode gap distance and whether in centre;
3. selecting suitable exit duct diameter.
2) mixture container and all connecting tubes and testing tube are evacuated to 10Pa or less first;
3) magnetic agitation is opened when starting to fill, and mixed gas is filled into mixing vessel according to corresponding intrinsic standoff ratio.
Junction should be vacuumized when often filling a kind of new gas, and be turned off after at least 5 minutes after filling;
4) setting mixing vessel heating temperature is 25 DEG C.
5) mixed gas is from mixing vessel, by testing tube, then from the outlet end of pipe, is discharged by hood.At least
It is recycled using 13 times of pipe volume of gas of test;
6) mixed gas completes circulation in pipe, and mixing vessel is separated from pipe, to prevent the gas in stop combustion mixing vessel
Body;
7) upper end of pipe should be first shut off, and the bottom end then closed is closed immediately, to prevent the gas of electrode zone from occurring
Any dilution or variation;
8) it waits 5~10 seconds, so that the gas in pipe is static;
9) lower end is gently opened, any disturbance or concentration variation occurs to avoid ignition zone, then lights a fire.Igniting
Before, camera is opened, image is recorded.Firing time interval should be designed as 0.3 ± 0.05s.This time is certified as being most suitable for
Test the time of combustion limits.
10) after flame propagation, in the upper end hardening of pipe, combustion product is by nitrogen or air circulation lead-in tube.?
After the test pipeline should be cleared up using dry nitrogen as early as possible.
11) result calculates
The rate of gas burning is the ratio for the time that flame front is displaced and is subjected to displacement, and is computed, the mixed gas
Burn rate be 15cm/s.
[embodiment 2]
Using the device of embodiment 1, the gaseous mixture of certain carbon monoxide and helium is tested its burn rate, was embodied
Journey is as follows:
The gaseous mixture of certain hydrogen and nitrogen tests its burn rate, and specific implementation process is as follows:
1) experiment should check following items before starting
1. using dry air or nitrogen purging test system;
2. checking inter-electrode gap distance and whether in centre;
3. selecting suitable exit duct diameter.
2) mixture container and all connecting tubes and testing tube are evacuated to 10Pa or less first;
3) magnetic agitation is opened when starting to fill, and mixed gas is filled into mixing vessel according to corresponding intrinsic standoff ratio.
Junction should be vacuumized when often filling a kind of new gas, and be turned off after at least 5 minutes after filling;
4) mixed gas is from mixing vessel, by testing tube, then from the outlet end of pipe, is discharged by hood.At least
It is recycled using 13 times of pipe volume of gas of test;
5) setting mixing vessel heating temperature is 35 DEG C.
6) mixed gas completes circulation in pipe, and mixing vessel is separated from pipe, to prevent the gas in stop combustion mixing vessel
Body;
7) upper end of pipe should be first shut off, and the bottom end then closed is closed immediately, to prevent the gas of electrode zone from occurring
Any dilution or variation;
8) it waits 5~10 seconds, so that the gas in pipe is static;
9) lower end is gently opened, any disturbance or concentration variation occurs to avoid ignition zone, then lights a fire.Igniting
Before, camera is opened, image is recorded.Firing time interval should be designed as 0.3 ± 0.05s.This time is certified as being most suitable for
Test the time of combustion limits.
10) after flame propagation, in the upper end hardening of pipe, combustion product is by nitrogen or air circulation lead-in tube.?
After the test pipeline should be cleared up using dry nitrogen as early as possible.
11) result calculates
The rate of gas burning is the ratio for the time that flame front is displaced and is subjected to displacement, and is computed, the mixed gas
Burn rate be 12cm/s.