CN109665544A - Lamellar zeolite and preparation method - Google Patents
Lamellar zeolite and preparation method Download PDFInfo
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- CN109665544A CN109665544A CN201710966120.0A CN201710966120A CN109665544A CN 109665544 A CN109665544 A CN 109665544A CN 201710966120 A CN201710966120 A CN 201710966120A CN 109665544 A CN109665544 A CN 109665544A
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- lamellar zeolite
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
Abstract
The present invention relates to a kind of lamellar zeolite material and preparation method, the technical issues of mainly solving the novel lamellar molecular screen material being not directed in the prior art.The present invention is by providing a kind of new lamellar zeolite material, the chemical composition comprising following molar ratio: 1SiO2: (0~0.1) Al2O3: (0.1~0.3) Q:(1~10) H2O, wherein template Q is the technical solution of a kind of gemini quaternary ammonium salt or quaternary amine alkali, preferably solves above-mentioned technical problem, obtains new lamellar zeolite material, can be used for Industrial Catalysis field.
Description
Technical field
The present invention relates to a kind of lamellar zeolite and preparation methods, belong to Zeolite synthesis technical field.
Background technique
Zeolite molecular sieve is due to unique duct shape selectivity, unique solid acid property and excellent ion exchange
Property, thus it is very widely used, it is adsorbing, separate and be catalyzed etc. has all shown their huge business application valences
Value.Such as in petroleum refining and chemical field, the application of Y zeolite brings the leather of a jumping to petroleum catalytic cracking technology
Life, and other molecular sieve catalysts, such as ZSM-5 zeolite, modenite, β zeolite, MCM-22 zeolite, SAPO-34 molecular sieve etc.
Using also give cracking, reformation, isomerization, aromatic disproportion and alkylation, methanol conversion etc. important petroleum refining and chemical industry skill
Art brings substantive breakthrough.In view of important function of the molecular sieve in many industrial circles, for new in document and patent
The research of molecular sieve and the research of novel synthesis are all very rich always.
Mainly there are two aspects in the source of molecular sieve, first is that obtaining from nature mineral, second is that by artificial synthesized
Method obtains, some molecular sieves can be obtained by both approach, but some molecular sieves can only be obtained by one of both.
But in petroleum refining and chemical field, most of molecular sieve catalyst is obtained by artificial synthesized method.
Common molecular sieve artificial synthesis is hydrothermal synthesis method, such as ZSM-5[US 3702886], ZSM-11[US 3709979],
ZSM-23【US 4076842】,ZSM-35【US 4016245】,Zeolite beta【US 3308069】,SAPO-34【US
4440871],MCM-22[US 4954325].It the use of hydro-thermal method synthesis zeolite is usually to first pass through silicon source compound, aluminium
The reactions such as source compound, alkali, template and water obtain starting sol, and then the colloidal sol is by the hydro-thermal reaction under enclosed system
Obtain the molecular sieve product of crystallization.
Domestic and foreign scholars by research discovery zeolite molecular sieve catalytic performance usually with its pattern and cellular structure feature
There is direct, close relationship, the shape characteristic for controlling molecular sieve has its application in terms of catalysis reaction and absorption
Highly important meaning.Lamellar zeolite has unique appearance structure, biggish specific surface area and stronger acid activity
Position shows excellent catalysis and absorption property in the field that macromolecular participates in.Currently, domestic and foreign scholars pass through unremitting effort,
The lamellar zeolite of various topological structures is developed: the lamellar zeolite with MWW topological structure, such as MCM-22[US
4954325], MCM-56[Chemical Journal of Chinese Universities, 2001,22,1898-1900] and ITQ-2[Microporous and
Mesoporous Materials,2000,38,301-309]；Lamellar zeolite with FER topological structure, such as ITQ-6[days
With chemical industry, 2011,41,250-252]；Lamellar zeolite [Journal and the with MFI topological structure
American Chemical Society, 2010,132,4169-4177] etc..
Lamellar zeolite is with its unique morphological structure, in catalytic cracking, hydro carbons alkylation, aromatisation and alkene
The fields such as isomerization are widely used, it is anticipated that have more lamellar zeolite materials urgently to be invented.The present invention
Provide a kind of lamellar zeolite and preparation method thereof having not been reported.
Summary of the invention
The first technical problem to be solved by the present invention is to provide a kind of new layer molecule being not directed in the prior art
Sieve.
The second technical problem to be solved by the present invention is to provide the corresponding stratiform of one of one kind and solution technical problem
The preparation method of molecular sieve.
One of to solve above-mentioned technical problem, the technical solution adopted by the present invention are as follows: a kind of lamellar zeolite, comprising as follows
The chemical composition of molar ratio: 1SiO2: (0~0.1) Al2O3: (0.01~0.4) Q:(1~10) H2O, wherein Q is a kind of Shuangzi season
Ammonium salt or quaternary amine alkali, structure are indicated by following general molecular formula:
Wherein R1For C1~C10Alkyl, C6~C10Aryl in any one；R2For H, halogen atom and C1~C6
At least one of alkyl, n takes 1~4 integer, and X is selected from halide ion or hydroxide ion.
In above-mentioned technical proposal, the lamellar zeolite preferably comprises X ray diffracting data as follows:
In above-mentioned technical proposal, the R1Preferably C1~C10Alkyl；The R2Preferably H, halogen atom and C1
~C6At least one of alkyl；The X preferably is selected from OH—。
To solve above-mentioned technical problem two, The technical solution adopted by the invention is as follows: a kind of solution above-mentioned technical problem
One of described in technical solution any lamellar zeolite preparation method, comprising the following steps:
A) according to 1SiO2: (0~0.1) Al2O3: (0.01~1) template Q:(20~200) H2The initial molar of O matches,
Silicon source, silicon source, alkaline matter, template and deionized water are uniformly mixed to get mixture；
B) mixture is transferred in reaction kettle, hydrothermal crystallizing 20~200 hours at 95~200 DEG C, gained produces
Object is washed and is dried, and lamellar zeolite material is obtained.
Above-mentioned to prepare in lamellar zeolite technical solution, silicon source is preferably selected from silica solution, solid silicone, gas-phase silica,
At least one of amorphous silica or organic silicone grease；The preferred self-alumina of silicon source, aluminium isopropoxide, aluminium hydroxide are intended thin
At least one of diaspore.
In above-mentioned technical proposal, the initial molar proportion of the mixture is preferably 1SiO2: (0~0.08) Al2O3:
(0.01~0.6) template Q:(20~140) H2O；For mixture preferably at 100~180 DEG C, hydro-thermal is brilliant in the step (b)
Change 20~160 hours.
Using technical solution of the present invention, above-mentioned lamellar zeolite crystallinity is high, and template is included between molecular sieve, can
It is used as the carrier of catalyst or the precursor as pillared composite achieves preferable technology with good application prospect
Effect.
Detailed description of the invention
Fig. 1 is X-ray diffraction (XRD) figure for the lamellar zeolite that embodiment 1 obtains.
Fig. 2 is the SEM electron microscopic picture for the lamellar zeolite that embodiment 1 obtains.
The present invention will be further described below by way of examples, but the protection scope being not intended to limit the present invention.
Specific embodiment
[embodiment 1]
By 40% silica solution, aluminium hydroxide, template Q1 and water 1SiO in molar ratio2:0.05Al2O3:0.2Q1:
80H2O be uniformly mixed, by said mixture move into reaction kettle in 170 DEG C crystallization 120 hours, after reaction by washing,
After drying, lamellar zeolite is obtained.Q1 dependency structure is shown in Table 1.
[embodiment 2]
By 40% silica solution, aluminium oxide, template Q2 and water 1SiO in molar ratio2:0.15Q2:100H2O mixing is equal
It is even, by said mixture move into reaction kettle in 150 DEG C crystallization 100 hours, after reaction after washing, drying, obtain
Lamellar zeolite.Template Q2 dependency structure is shown in Table 1.
[embodiment 3]
By white carbon black, aluminium oxide, template Q3 and water 1SiO in molar ratio2:0.01Al2O3:0.2Q3:100H2O is mixed
Close uniformly, by said mixture move into reaction kettle in 150 DEG C crystallization 120 hours, after reaction after washing, drying,
Obtain lamellar zeolite.Template Q3 dependency structure is shown in Table 1.
[embodiment 4]
By 40% silica solution, aluminium oxide, template Q3 and water 1SiO in molar ratio2:0.06Al2O3:0.3Q3:
120H2O be uniformly mixed, by said mixture move into reaction kettle in 170 DEG C crystallization 120 hours, after reaction by washing,
After drying, lamellar zeolite is obtained.Template Q3 dependency structure is shown in Table 1.
[embodiment 5]
By 40% silica solution, aluminium oxide, template Q4 and water 1SiO in molar ratio2:0.04Al2O3:0.6Q4:
150H2O be uniformly mixed, by said mixture move into reaction kettle in 160 DEG C crystallization 120 hours, after reaction by washing,
After drying, lamellar zeolite is obtained.Template Q4 dependency structure is shown in Table 1.
Template used dose of structure of 1 embodiment of table
Claims (10)
1. a kind of lamellar zeolite, the chemical composition comprising following molar ratio: 1SiO2: (0~0.1) Al2O3: (0.01~0.4)
Q:(1~10) H2O, wherein template Q is a kind of gemini quaternary ammonium salt or quaternary amine alkali, and structure is indicated by following general molecular formula:
Wherein R1For C1~C10Alkyl, C6~C10Aryl in any one；R2For H, halogen atom and C1~C6Hydrocarbon
At least one of base, n take 1~4 integer, and X is selected from halide ion or hydroxide ion.
2. lamellar zeolite according to claim 1, it is characterised in that the lamellar zeolite includes X as follows
Ray diffraction data:
3. lamellar zeolite according to claim 1, it is characterised in that the R1For C1~C10Alkyl.
4. lamellar zeolite according to claim 1, it is characterised in that the R2For H, halogen atom and C1~C6's
At least one of alkyl.
5. lamellar zeolite according to claim 1, it is characterised in that the X is selected from OH—。
6. the preparation method of lamellar zeolite described in Claims 1 to 5, comprises the following steps:
A) according to 1SiO2: (0~0.1) Al2O3: (0.01~1) Q:(20~200) H2The initial molar of O matches, by silicon source, aluminium
Source, template and deionized water are uniformly mixed to get mixture；
B) mixture is transferred in reaction kettle, hydrothermal crystallizing 20~200 hours at 95~200 DEG C, products therefrom into
Row washing and drying, obtain lamellar zeolite material.
7. the preparation method of lamellar zeolite according to claim 6, it is characterised in that the silicon source is selected from silica solution, Gu
Body silica gel, gas-phase silica, at least one of amorphous silica or organic silicone grease.
8. the preparation method of lamellar zeolite according to claim 6, it is characterised in that source of aluminium be selected from aluminium oxide,
Aluminium isopropoxide, aluminium hydroxide, at least one of boehmite.
9. the preparation method of lamellar zeolite according to claim 6, it is characterised in that the initial molar of the mixture
Proportion is 1SiO2: (0~0.08) Al2O3: (0.01~0.6) template Q:(20~140) H2O。
10. the preparation method of lamellar zeolite according to claim 6, it is characterised in that the mixture is 100~180
At DEG C, hydrothermal crystallizing 20~160 hours.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011134925A1 (en) * | 2010-04-28 | 2011-11-03 | F. Hoffmann-La Roche Ag | Spiroindolinone pyrrolidines |
| CN103626202A (en) * | 2012-08-21 | 2014-03-12 | 巩雁军 | Method for preparing catalyst used for methanol/dimethyl ether high selectivity propylene preparation |
| CN105983440A (en) * | 2015-04-02 | 2016-10-05 | 大连海鑫化工有限公司 | Composite nanometer thin layer molecular sieve and preparation method and application |
| CN106587102A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Synthetic method of ZSM-12 type zeolite molecular sieve |
| CN106588816A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Gemini quaternary ammonium salt or quaternary ammonium salt compound and preparation method |
-
2017
- 2017-10-17 CN CN201710966120.0A patent/CN109665544B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011134925A1 (en) * | 2010-04-28 | 2011-11-03 | F. Hoffmann-La Roche Ag | Spiroindolinone pyrrolidines |
| CN103626202A (en) * | 2012-08-21 | 2014-03-12 | 巩雁军 | Method for preparing catalyst used for methanol/dimethyl ether high selectivity propylene preparation |
| CN105983440A (en) * | 2015-04-02 | 2016-10-05 | 大连海鑫化工有限公司 | Composite nanometer thin layer molecular sieve and preparation method and application |
| CN106587102A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Synthetic method of ZSM-12 type zeolite molecular sieve |
| CN106588816A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Gemini quaternary ammonium salt or quaternary ammonium salt compound and preparation method |
Non-Patent Citations (1)
| Title |
|---|
| MUHAMMAD JAWWAD SAIF, ET AL.: "Antimicrobial Activities of Novel Bis-Piperidinium Compounds.", 《POLISH JOURNAL OF MICROBIOLOGY》 * |
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