CN109650519A - Packaged type Supercritical water oxidation treatment device - Google Patents
Packaged type Supercritical water oxidation treatment device Download PDFInfo
- Publication number
- CN109650519A CN109650519A CN201910097359.8A CN201910097359A CN109650519A CN 109650519 A CN109650519 A CN 109650519A CN 201910097359 A CN201910097359 A CN 201910097359A CN 109650519 A CN109650519 A CN 109650519A
- Authority
- CN
- China
- Prior art keywords
- reactor
- delivery pump
- cooler
- supercritical water
- cabin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009284 supercritical water oxidation Methods 0.000 title claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 41
- 230000001681 protective effect Effects 0.000 claims abstract description 33
- 239000007791 liquid phase Substances 0.000 claims abstract description 22
- 238000010438 heat treatment Methods 0.000 claims abstract description 21
- 238000001816 cooling Methods 0.000 claims abstract description 20
- 238000000926 separation method Methods 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims description 20
- 238000005192 partition Methods 0.000 claims description 11
- 239000000084 colloidal system Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 238000013461 design Methods 0.000 abstract description 4
- 238000002955 isolation Methods 0.000 abstract description 3
- 239000000498 cooling water Substances 0.000 description 7
- 108010066278 cabin-4 Proteins 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 230000032258 transport Effects 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010808 liquid waste Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910001119 inconels 625 Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
The invention discloses a kind of packaged type Supercritical water oxidation treatment devices, including moveable charging cabin, reaction cabin and operational window, it is provided with connector on charging cabin, reaction cabin and operational window, charging cabin, reaction cabin pass through piping connection between operational window;It is provided with high-pressure delivery pump and liquid phase delivery pump in charging cabin, reactor, cooler and cooling separation are provided in reaction warehouse, reactor outer sheath is equipped with heating furnace, operates in storehouse and is provided with control cabinet;High-pressure delivery pump and liquid phase delivery pump are connected with the entrance of reactor, and the outlet of reactor is connected with cooler, and cooler is connected with cooling separation;Control cabinet can control the switch of high-pressure delivery pump, liquid phase delivery pump, reactor, cooler and cooling separation.The present invention is ingenious in design, divides equipment using shelter, facilitates the transport of equipment, and the isolation of equipment is carried out using protective housing, improves the safety of equipment.
Description
Technical field
The present invention relates at a kind of Supercritical water oxidation treatment device more particularly to a kind of packaged type supercritical water oxidation
Manage device.
Background technique
Supercritical water oxidation (Supercritical Water Oxidation, abbreviation SCWO) technology is a kind of can be achieved
A variety of debirs are carried out with the technology of deep oxidation processing.The principle of supercritical Water Oxidation Technology is with supercritical water for reaction
Organic matter complete oxidation is clean H by homogeneous oxidation reaction by medium2O、CO2And N2Equal substances, S, P etc. are converted into
Highest price salt stabilizes, and heavy metal oxidation stable solid phase is present in ash content.Since supercritical water is equal to organic matter and oxygen
It is fabulous solvent, therefore the oxidation of organic matter can carry out in oxygen-enriched homogeneous phase, there is no because needing Xiang Wenzhuan for reaction
The limitation for moving and generating.Meanwhile 400~600 DEG C of high reaction temperature also accelerates reaction speed, it can be in reaction in several seconds
In, that is, it can reach 99% or more destructive rate.In addition, supercritical water oxidation is to a certain extent and simple burned
Journey is similar, and a large amount of heat is released in oxidation process.
Although supercritical water oxidation method has lot of advantages, the operating condition of high temperature and pressure is undoubtedly to the group of equipment
It is filled with and transports and propose strict requirements.When transport, package unit require to break and in adaptable packing case into
Row transport, also needs assembly and adjustment, increases the workload of assembler and consume a large amount of time after arriving at the destination.
Summary of the invention
The present invention provides a kind of packaged type Supercritical water oxidation treatment devices, have the effect of convenient transportation.Specifically
Technical solution is as follows:
A kind of packaged type Supercritical water oxidation treatment device includes moveable charging cabin, reaction cabin and operational window,
It is provided with connector on charging cabin, reaction cabin and operational window, charging cabin, reaction cabin pass through piping connection between operational window;
It is provided with high-pressure delivery pump and liquid phase delivery pump in charging cabin, reactor, cooler and refrigerated separation are provided in reaction warehouse
System, reactor outer sheath are equipped with heating furnace, operate in storehouse and are provided with control cabinet;High-pressure delivery pump and liquid phase delivery pump with react
The entrance of device is connected, and the outlet of reactor is connected with cooler, and cooler is connected with cooling separation;The controllable height of control cabinet
Press the switch of delivery pump, liquid phase delivery pump, reactor, cooler and cooling separation.
Further, the first protective housing and the second protective housing are provided in reaction cabin, the first protective housing is set with the second protective housing
It is equipped with connector, the first protective housing is connected with the second protective housing by pipeline, and reactor and cooler are accommodated in the first protective housing
Interior, cooling separation is accommodated in the second protective housing.
Further, it is provided with camera in charging cabin, the first protective housing and the second protective housing, monitoring is provided in operational window
Device, monitor are connected with the camera in charging cabin, the first protective housing and the second protective housing.
Further, partition is provided in operational window, one end of partition and the bulkhead of operational window are fixedly linked, and the other end is formed
Personnel channel;The side of partition is arranged in control cabinet, between the other side of partition and the bulkhead formation operation of operational window.
Further, reaction system further includes preheating furnace, and preheating furnace is positioned close to one end of reactor inlet, and heating furnace is set
Set one end in reactor close to outlet.
Further, the first temperature tube is provided between preheating furnace and heating furnace, the first temperature tube is connected with reactor, heating
The second temperature tube is provided on furnace, the outlet of cooler is provided with third temperature tube;Reactor outlet is additionally provided with pressure gauge.
Further, instrument board is provided in operation room, be provided on instrument board pressure display unit, the first temperature indicator,
Second temperature display, third temperature indicator;Pressure display unit is connected with pressure gauge, the first temperature indicator and the first thermometric
Pipe is connected, and second temperature display is connected with the second temperature tube, and third temperature indicator is connected with third temperature tube.
Further, colloid mill and dissolvers are additionally provided in charging cabin, colloid mill is connected with dissolvers, dissolvers and liquid phase
Delivery pump is connected.
Further, check valve is provided between high-pressure delivery pump and reaction system, between liquid phase delivery pump and reaction system
It is also equipped with check valve.
Further, cooling separation includes spiral cooler, and the entrance of spiral cooler is connected with counterbalance valve, and spiral is cold
The outlet of condenser is connected with gas-liquid separator, and the exhaust outlet of gas-liquid separator is connected with accumulator tank, the leakage fluid dram of gas-liquid separator
It is connected with sample tap.
The present invention is ingenious in design, divides equipment using shelter, facilitates the transport of equipment, greatly reduce and tear open
Unload and assembly equipment needed for workload, saved the time, meanwhile, using protective housing carry out equipment isolation, improve and set
Standby safety ensure that the safety of operator.
Detailed description of the invention
Fig. 1 is the overall schematic of packaged type Supercritical water oxidation treatment device of the invention;
Fig. 2 is the partial schematic diagram of the reaction system of packaged type Supercritical water oxidation treatment device of the invention;
Fig. 3 is the process that packaged type Supercritical water oxidation treatment device of the invention handles waste oil or organic liquid waste
Figure;
Fig. 4 is the flow chart that packaged type Supercritical water oxidation treatment device of the invention handles resin.
Specific embodiment
In order to be best understood from the purpose of the present invention, function and specific design scheme, with reference to the accompanying drawing, to the present invention
Packaged type Supercritical water oxidation treatment device be described in further detail.
As shown in Figure 1, packaged type Supercritical water oxidation treatment device of the invention include moveable charging cabin 4, it is anti-
Answer cabin 5 and operational window 6, be provided with connector on charging cabin 4, reaction cabin 5 and operational window 6, operational window 6 respectively with charging
Cabin 4 is connected with reaction cabin 5 by pipeline.It is equipped with feed system 1 in charging cabin 4, reaction system 2 is equipped in reaction cabin 5, grasps
Make to be equipped with operation control system 3 in cabin 6.
Specifically, being provided with feed system 1 in charging cabin 4, feed system 1 includes dioxygen sink 11,11 He of dioxygen sink
High-pressure delivery pump 12 is connected, and high-pressure delivery pump 12 is connected with reaction system 2;Feed system 1 further includes liquid phase delivery pump 13, liquid phase
Delivery pump 13 is connected with reaction system 2.Preferably, feed system 1 further includes colloid mill 14 and dissolvers 15, colloid mill 14 with it is molten
It solves device 15 to be connected, dissolvers 15 is connected with liquid phase delivery pump 13.It is worth noting that, high-pressure delivery pump 12 and reaction system 2 it
Between be provided with check valve, check valve is also equipped between liquid phase delivery pump 13 and reaction system 2, to prevent supercritical water high-temperature stream
Body flows back into feed system 1.
Reaction system 2 is provided in reaction cabin 5, as shown in Fig. 2, reaction system 2 includes reactor 21, reactor 21 is pipe
Road formula reactor, material Inconel625, the entrance of reactor are connected with the first valve 23, the first valve 23 and high-pressure delivery
Pump 12 is connected with liquid phase delivery pump 13, and the outlet of reactor is connected with the entrance of cooler 22.The outlet and back pressure of cooler 22
Valve 24 is connected, and counterbalance valve 24 is connected with cooling separation.The high pressure of counterbalance valve 24 and check valve to guarantee inside reactor.
21 outer sheath of reactor is equipped with preheating furnace 71 and heating furnace 72, and preheating furnace 71 is positioned close to 21 entrance of reactor
One end, heating furnace 72 are arranged in reactor 21 close to one end of outlet, the first survey are provided between preheating furnace 71 and heating furnace 72
Warm pipe 81, the first temperature tube 81 is connected with reactor 21, for detecting the temperature of 21 internal liquid of reactor;It is set on heating furnace 72
It is equipped with the second temperature tube 82, the second temperature tube 82 is used to detect the temperature of heating furnace 72.The preheating furnace 71 of the present embodiment and heating
Furnace 72 is opposite opened tubular heater, using infrared heating, it is preferred that the power of preheating furnace 71 is less than the power of heating furnace, this
The preheating furnace of embodiment uses 2kw opposite opened tubular heater, and heating furnace 72 uses 4kw opposite opened tubular heater, to reach
To the purpose of power saving, save the cost.
Preferably, pressure gauge 25 is additionally provided between the first valve 23 and reactor 21, pressure gauge 25 is anti-for detecting
Answer the pressure inside system 2.
The cooler 22 of the present embodiment is straight pipe condensation device, and the liquid after 22 pairs of cooler reactions cools down, cooler
Cooling water inlet be connected with cooling water pump.It is provided with third temperature tube 83 between the outlet and counterbalance valve 24 of cooler 22, the
Three temperature tubes 83 are used to detect the temperature of the liquid after cooling of cooler 22.
Cooling separation includes spiral cooler 26, and the entrance of spiral cooler 26 is connected with counterbalance valve 24, and spiral is cold
The outlet of condenser 26 is connected with gas-liquid separator 27, and the cooling water inlet of spiral cooler 26 is connected with cooling water pump, gas-liquid point
Exhaust outlet from device 27 is connected with accumulator tank 28, and the leakage fluid dram of gas-liquid separator 27 is connected with sample tap, and sample tap takes liquid
Sample is simultaneously monitored effluent pH value, and sample is analyzed with COD analyzer and TOC analyzer, anti-by COD value/TOC value
Feedback regulates and controls reaction.
As shown in figure 3, reactor 21 and cooler 22 are mounted in the first protective housing 91, cooling separation is mounted on
In two protective housings 92.First protective housing 91 and the second protective housing 92 are arranged in reaction cabin 5, and the first protective housing 91 and second is anti-
Connector is provided on protecting box 92, the first protective housing 91 is connected with the second protective housing 92 by pipeline, when reactor 21 is endangered
When dangerous, the safety of cooling separation equipment can protect, reduce loss, while can also protect the safety of operator.
Operation control system 3 is provided in operational window 6, operation control system 3 includes control cabinet 31, instrument board 32 and monitoring
Device 33.Battery main switch, high-pressure delivery switch pump, liquid phase conveying switch pump, colloid mill switch, dissolution are provided on control cabinet 31
Device switch, preheating furnace switch, heating furnace switch, cooling water pump switch.High-pressure delivery switch pump is connected with high-pressure delivery pump 12, liquid
Mutually conveying switch pump is connected with liquid phase delivery pump 13, and colloid mill switch is connected with colloid mill 14, dissolvers switch and dissolvers 15
It is connected, preheating furnace switch is connected with preheating furnace 71, and heating furnace switch is connected with heating furnace 72, cooling water pump switch and cooling water pump
It is connected.
Pressure display unit, the first temperature indicator, second temperature display, third temperature display are provided on instrument board 32
Device.Pressure display unit is connected with pressure gauge 25, and the first temperature indicator is connected with the first temperature tube 81, second temperature display with
Second temperature tube 82 is connected, and third temperature indicator is connected with third temperature tube 83.Monitor 33 is connected with camera, camera
It is separately positioned in charging cabin 4, the first protective housing 91 and the second protective housing 92.It can real-time monitoring by above-mentioned instrument and camera
The operating status of equipment of the invention.Preferably, as shown in Figure 1, being provided with partition in operational window 6, one end of partition and operation
The bulkhead in cabin 6 is fixedly linked, and the other end forms personnel channel;Partition is arranged in control cabinet 31, instrument board 32 and monitor 33
34 between the bulkhead formation operation of side, the other side and operational window 6.Operation room 34 is additionally provided in operational window 6, operator is grasping
Make the control that operation room 34 in cabin 6 carries out supercritical water oxidation equipment, it is ensured that the safety of operator, avoid because
Reaction occurs accident and causes casualties.
As shown in figure 3, the present invention is when handling organic liquid waste or waste oil, hydrogen peroxide is delivered to reaction by high-pressure delivery pump
In device, meanwhile, organic liquid waste or waste oil are delivered in reactor by liquid phase delivery pump and heat simultaneously oxygenolysis, after reaction
Liquid through straight pipe condensation device carry out it is cooling after further cooled down through spiral cooler again, liquid after cooling enters gas-liquid
Separator carries out gas-liquid separation, finally enters in accumulator tank.
As shown in figure 4, the present invention is when handling resin, hydrogen peroxide is delivered in reactor by high-pressure delivery pump, resin
It grinds by colloid mill, is dissolved using dissolvers, be delivered in reactor finally by liquid phase delivery pump and heat simultaneously oxygen
Change and decompose, the liquid after reaction is further cooled down through spiral cooler again after straight pipe condensation device carries out cooling, after cooling
Liquid enter gas-liquid separator carry out gas-liquid separation, finally enter in accumulator tank.
The present invention is ingenious in design, divides equipment using shelter, facilitates the transport of equipment, greatly reduce and tear open
Unload and assembly equipment needed for workload, saved the time, meanwhile, using protective housing carry out equipment isolation, improve and set
Standby safety ensure that the safety of operator.
The present invention is further described by specific embodiment above, it should be understood that, here specifically
Description, should not be construed as the restriction for the essence of the present invention with range, and one of ordinary skilled in the art is reading this explanation
The various modifications made after book to above-described embodiment belong to the range that the present invention is protected.
Claims (10)
1. a kind of packaged type Supercritical water oxidation treatment device, which is characterized in that including moveable charging cabin, reaction cabin with
And operational window, it is provided with connector on charging cabin, reaction cabin and operational window, charging cabin, reaction cabin pass through between operational window
Piping connection;High-pressure delivery pump and liquid phase delivery pump are provided in charging cabin, be provided in reaction warehouse reactor, cooler and
Cooling separation, reactor outer sheath are equipped with heating furnace, operate in storehouse and are provided with control cabinet;High-pressure delivery pump and liquid phase conveying
Pump is connected with the entrance of reactor, and the outlet of reactor is connected with cooler, and cooler is connected with cooling separation;Control cabinet
It can control the switch of high-pressure delivery pump, liquid phase delivery pump, reactor, cooler and cooling separation.
2. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that be provided in reaction cabin
First protective housing and the second protective housing, the first protective housing and the second protective housing are provided with connector, and the first protective housing and second prevent
Protecting box is connected by pipeline, and reactor and cooler are accommodated in the first protective housing, and cooling separation is accommodated in the second protection
In case.
3. packaged type Supercritical water oxidation treatment device as claimed in claim 2, which is characterized in that charging cabin, first prevent
It is provided with camera in protecting box and the second protective housing, monitor, monitor and charging cabin, the first protective housing are provided in operational window
It is connected with the camera in the second protective housing.
4. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that be provided in operational window
Partition, one end of partition and the bulkhead of operational window are fixedly linked, and the other end forms personnel channel;The one of partition is arranged in control cabinet
Side, between the other side of partition and the bulkhead formation operation of operational window.
5. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that reaction system further includes
Preheating furnace, preheating furnace are positioned close to one end of reactor inlet, and heating furnace is positioned close to one end of reactor outlet.
6. packaged type Supercritical water oxidation treatment device as claimed in claim 5, which is characterized in that preheating furnace and heating furnace
Between be provided with the first temperature tube, the first temperature tube is connected with reactor, the second temperature tube is provided on heating furnace, cooler
Outlet is provided with third temperature tube;Reactor outlet is additionally provided with pressure gauge.
7. packaged type Supercritical water oxidation treatment device as claimed in claim 6, which is characterized in that be provided in operation room
Instrument board is provided with pressure display unit, the first temperature indicator, second temperature display, third temperature indicator on instrument board;
Pressure display unit is connected with pressure gauge, and the first temperature indicator is connected with the first temperature tube, and second temperature display and second is surveyed
Warm Guan Xianglian, third temperature indicator are connected with third temperature tube.
8. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that also set up in charging cabin
There are colloid mill and dissolvers, colloid mill is connected with dissolvers, and dissolvers is connected with liquid phase delivery pump.
9. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that high-pressure delivery pump and anti-
It answers and is provided with check valve between system, be also equipped with check valve between liquid phase delivery pump and reaction system.
10. packaged type Supercritical water oxidation treatment device as described in claim 1, which is characterized in that cooling separation
Including spiral cooler, the entrance of spiral cooler is connected with counterbalance valve, and the outlet of spiral cooler is connected with gas-liquid separator,
The exhaust outlet of gas-liquid separator is connected with accumulator tank, and the leakage fluid dram of gas-liquid separator is connected with sample tap.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910097359.8A CN109650519A (en) | 2019-01-30 | 2019-01-30 | Packaged type Supercritical water oxidation treatment device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910097359.8A CN109650519A (en) | 2019-01-30 | 2019-01-30 | Packaged type Supercritical water oxidation treatment device |
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Publication Number | Publication Date |
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CN109650519A true CN109650519A (en) | 2019-04-19 |
Family
ID=66122594
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CN201910097359.8A Pending CN109650519A (en) | 2019-01-30 | 2019-01-30 | Packaged type Supercritical water oxidation treatment device |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN205953631U (en) * | 2016-08-18 | 2017-02-15 | 新奥科技发展有限公司 | Supercritical water oxidation's sled dress device |
CN205999106U (en) * | 2016-06-28 | 2017-03-08 | 新奥科技发展有限公司 | A kind of supercritical water oxidation treatment system |
CN209651956U (en) * | 2019-01-30 | 2019-11-19 | 北京国原新技术有限公司 | Packaged type Supercritical water oxidation treatment device |
-
2019
- 2019-01-30 CN CN201910097359.8A patent/CN109650519A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN205999106U (en) * | 2016-06-28 | 2017-03-08 | 新奥科技发展有限公司 | A kind of supercritical water oxidation treatment system |
CN205953631U (en) * | 2016-08-18 | 2017-02-15 | 新奥科技发展有限公司 | Supercritical water oxidation's sled dress device |
CN209651956U (en) * | 2019-01-30 | 2019-11-19 | 北京国原新技术有限公司 | Packaged type Supercritical water oxidation treatment device |
Non-Patent Citations (1)
Title |
---|
廖传华等: "《超临界流体与环境治理》", vol. 1, 中国石化出版社, pages: 131 - 132 * |
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