CN109647189A - One kind being based on light-catalysed VOC waste gas treatment equipment - Google Patents

One kind being based on light-catalysed VOC waste gas treatment equipment Download PDF

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Publication number
CN109647189A
CN109647189A CN201910070104.2A CN201910070104A CN109647189A CN 109647189 A CN109647189 A CN 109647189A CN 201910070104 A CN201910070104 A CN 201910070104A CN 109647189 A CN109647189 A CN 109647189A
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CN
China
Prior art keywords
light
catalysed
waste gas
gas treatment
treatment equipment
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910070104.2A
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Chinese (zh)
Inventor
熊金强
黄邦武
徐哲
陈璐
黄浩
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Fujian Enthusiastic Environmental Protection Technology Co Ltd
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Fujian Enthusiastic Environmental Protection Technology Co Ltd
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Priority to CN201910070104.2A priority Critical patent/CN109647189A/en
Publication of CN109647189A publication Critical patent/CN109647189A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20723Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention provides one kind based on light-catalysed VOC waste gas treatment equipment, including apparatus body, and the one lateral air outlet side of air inlet of the apparatus body has been sequentially arranged lipid phase absorbing unit, inducing catalysis disproportionation unit and photocatalysis unit;The lipid phase absorbing unit includes the atomizing humidifier that corresponding gas is arranged by air duct upper and lower ends, which extracts scavenging solution from fluid reservoir, and water filter is equipped with above corresponding fluid reservoir, and the moisture of water filter absorption flows into fluid reservoir;Photocatalysis unit includes the non-woven fabrics coated with photocatalyst material, and several light sources that corresponding non-woven fabrics each section is set gradually.The invention reasonable structural arrangement, can be first by VOC exhaust gas solution compatible with lipid phase object, and the exhaust gas utilization photocatalyst for mixing water phase later is catalyzed reaction.Whole reaction efficiency is increased substantially, and then reaches discharge standard rapidly and efficiently.

Description

One kind being based on light-catalysed VOC waste gas treatment equipment
Technical field
The invention belongs to waste gas treatment equipment technical field, is based on light-catalysed VOC exhaust gas more particularly, to one kind Processing equipment.
Background technique
The common processing VOC emission technology of tradition has recovery technology and destruction technology, and recovery technology includes adsorption technology, absorbs Technology etc..Although adsorption technology can be used for recycling the control of the industrial gas emissions such as VOC exhaust gas and the Adsorption Concentration of high concentration, There is also some technological difficulties to need to break through for VOC exhaust gas adsorbent material, and operating cost is higher, is also easy to produce secondary pollution.And it sells Ruining technology mainly has flame combustion, biological oxidation etc., but VOC Exhaust gas species are various, and distinct, technical process is many and diverse, single Treatment process can not be able to satisfy all VOC waste gas pollution control and treatments.
Summary of the invention
In view of this, the invention is intended to overcome above-mentioned defect existing in the prior art, propose that one kind is urged based on light The VOC waste gas treatment equipment of change.
In order to achieve the above objectives, the technical solution of the invention is achieved in that
One kind is based on light-catalysed VOC waste gas treatment equipment, including apparatus body, one side of air inlet of the apparatus body to Air outlet side has been sequentially arranged lipid phase absorbing unit, inducing catalysis disproportionation unit and photocatalysis unit;
The lipid phase absorbing unit includes the atomizing humidifier that corresponding gas is arranged by air duct upper and lower ends, this adds by spraying Wet device extracts scavenging solution from fluid reservoir, and water filter is equipped with above corresponding fluid reservoir, and the moisture of water filter absorption flows into liquid storage Tank;The water filter includes biomimetic features filter core;
The inducing catalysis disproportionation unit includes the inducing catalysis disproportionation filter that water filter rear end is arranged in, which urges Changing disproportionation filter includes several hollow balls being distributed on carrier and carrier;The carrier surface and each hollow sphere Internal outer wall surface is coated with catalyst coat;Water replanishing device is equipped with above the corresponding carrier;
The photocatalysis unit includes the non-woven fabrics coated with photocatalyst material, and corresponding non-woven fabrics each section is successively set Several light sources set.
Further, the non-woven fabrics is arranged in V-shape fold.
Further, the light source uses ultraviolet light source.
Further, the catalyst coat uses vanadium series catalyst.
Further, the first seal plate is equipped with close to air inlet side in atomizing humidifier on apparatus body.
Further, the second seal plate is equipped with far from air inlet side in water filter on the apparatus body;Apparatus body On the second seal plate close to air inlet side be equipped with communicated with fluid reservoir first cross liquid mouth.
Further, third sealing is equipped with close to air outlet side in inducing catalysis disproportionation filter on the apparatus body Plate;It is equipped with second communicated with fluid reservoir close to air inlet side in third seal plate on apparatus body and crosses liquid mouth.
Further, the biomimetic features filter core includes the filter core carrier of multi-cavity structure, and the filter core carries intracorporal cavity Quantity is incremented by from the top of carrier to middle part in geometric multiple, and is successively decreased to the lower part in geometric multiple by the middle part of the carrier, respectively Be filled with spiral packing part in a cavity, each spiral packing part towards random distribution.
Further, spiral packing part upper end is big, lower end is small, and screw pitch is between 2mm-20mm.
Compared with the existing technology, the invention has the advantage that
The invention reasonable structural arrangement can mix later the exhaust gas of water phase first by VOC exhaust gas solution compatible with lipid phase object It is catalyzed and is reacted using photocatalyst.Whole reaction efficiency is increased substantially, and then reaches discharge standard rapidly and efficiently.
Detailed description of the invention
The attached drawing for constituting a part of the invention is used to provide to further understand the invention, present invention wound The illustrative embodiments and their description made are used to explain the present invention creation, do not constitute the improper restriction to the invention.? In attached drawing:
Fig. 1 is the structural schematic diagram of the invention;
Fig. 2 is the structural schematic diagram of biomimetic features filter core in the invention embodiment;
Fig. 3 is the enlarged drawing of structure at A in Fig. 2;
Fig. 4 is the structural schematic diagram of hollow ball in the invention embodiment.
In figure:
1- air inlet;2- air outlet;3- atomizing humidifier;4- fluid reservoir;5- water filter;6- inducing catalysis disproportionation filtering Device;7- venthole;8- hollow ball;9- water replanishing device;10- non-woven fabrics;11- light source;The first seal plate of 12-;The second sealing of 13- Plate;14- first crosses liquid mouth;15- third seal plate;16- second crosses liquid mouth;17- filter core carrier;18- spiral packing part;19- Filter assemblies;20- framework;21- retainer.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the invention can To be combined with each other.
In the description of the invention, it is to be understood that term " center ", " longitudinal direction ", " transverse direction ", "upper", "lower", The orientation or positional relationship of the instructions such as "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is It is based on the orientation or positional relationship shown in the drawings, is merely for convenience of description the invention and simplifies description, rather than indicate Or imply that signified device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore cannot understand For the limitation to the invention.In addition, term " first ", " second " etc. are used for description purposes only, and should not be understood as indicating Or it implies relative importance or implicitly indicates the quantity of indicated technical characteristic." first ", " second " etc. are defined as a result, Feature can explicitly or implicitly include one or more of the features.In the description of the invention, unless separately It is described, the meaning of " plurality " is two or more.
In the description of the invention, it should be noted that unless otherwise clearly defined and limited, term " peace Dress ", " connected ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integrally Connection;It can be mechanical connection, be also possible to be electrically connected;Can be directly connected, can also indirectly connected through an intermediary, It can be the connection inside two elements.For the ordinary skill in the art, on being understood by concrete condition State concrete meaning of the term in the invention.
Below with reference to embodiment come the present invention will be described in detail create.
One kind being based on light-catalysed VOC waste gas treatment equipment, as shown in Figures 1 to 4, including apparatus body, the apparatus body 1 one lateral air outlet of air inlet, 2 side be sequentially arranged lipid phase absorbing unit, inducing catalysis disproportionation unit and photocatalysis list Member;
The lipid phase absorbing unit includes the atomizing humidifier 3 that corresponding gas is arranged by air duct upper and lower ends, this is spraying Humidifier extracts scavenging solution from fluid reservoir 4, and water filter 5 is equipped with above corresponding fluid reservoir, and the moisture of water filter absorption flows into Fluid reservoir;The water filter includes biomimetic features filter core;Filter assemblies 19 are equipped in fluid reservoir, specifically, filter assemblies can be with Including activated charcoal strainer, impurity particle in effective adsorption cleaning liquid avoids the nozzle of blocking atomizing humidifier;
The inducing catalysis disproportionation unit includes the inducing catalysis disproportionation filter 6 that water filter rear end is arranged in, the induction Catalytic disproportionation filter includes several hollow balls 8 being distributed on carrier and carrier;The carrier surface and each sky Outer wall surface is coated with catalyst coat in bulbus cordis body;Water replanishing device 9 is equipped at corresponding carrier;It is pointed out that this hair The attached drawing of bright creation is only schematic diagram, and water replanishing device is not necessarily necessarily placed above carrier, is also possible to side coil arrangement, root Suitable installation site is selected according to actual condition;
The photocatalysis unit includes the non-woven fabrics 10 coated with photocatalyst material, and corresponding non-woven fabrics each section is successively Several light sources 11 being arranged.
It should be noted that exhaust gas has certain temperature when entering system, and relative humidity and cleanser are uneven, can lead Cause, which has cleanser to be sprayed rear portion water, to be evaporated, and therefore, it is necessary to water is continuously replenished to fluid reservoir.Above-mentioned water replanishing device with Structure between fluid reservoir can may include being loaded with only using the box structure that draws water similar to squat type closestool, water replanishing device Change liquid sealant supplement cylinder, in fluid reservoir be equipped with floating ball, when fluid reservoir water level decreasing to a certain extent, floating ball loss of buoyance support, Can by lever open water compensating valve, from water replanishing device sealant supplement cylinder into fluid reservoir after-purification liquid, fill the water of fluid reservoir Foot.Atomizing humidifier can use the structure similar with humidifier on the market, realize the atomization to cleanser.Specifically , cleanser can use water phase and lipid phase mixture, certainly, also can achieve the effect of certain purification absorption only with water phase Fruit.
Be dissolved VOC waste gas component with before photocatalyst interfacial contact, in advance catalysis generate most easily lured by photocatalyst The aerosol receptor of catalytic decomposition is led, particularly, spraying and form droplets particles very tiny, catalyst and VOC waste gas reaction Surface catalysis disproportionation occurs, forms liquid particles object, suspends in air, therefore generates aerosol receptor, specific surface area is got over Greatly, the content of dissolved oxygen is higher, and the oxygen atom in water is made constantly to be disproportionated into active oxonium ion, and easier and photocatalyst material exists It is oxidized cartalytic decomposition effect under the action of light, VOC is decomposed into water and carbon dioxide.
The gas-phase space formed by spraying in air is mixed by catalysis state, so that the cartalytic decomposition effect of photocatalyst It is stably and controllable.It is friendly to be catalyzed reaction interface, not carbon distribution, that is, do not generate other harmful side products after photocatalyst reaction and participate in anti- It is easy to react between the reactant answered, photocatalyst generates carbon dioxide gas after decomposing VOC oxidation, by carbon band It walks, and unoxidized VOC particle can be pushed open and not cause to accumulate, interface has certain self-regeneration mechanism, so that catalysis drop Solution VOC exhaust-gas treatment ability greatly improves.
The VOC gas of feeding are coated with the hollow sphere of catalysis material by surface, to VOC exhaust gas in aqueous environment boundary condition The lower a series of disproportionated reaction of completion (collide with catalyst interface, and the mistake of liquid particles is converted to by gas particles by VOC exhaust gas Journey), this is a kind of process being catalyzed in advance to the progress of VOC gas.VOC exhaust gas mixing gas phase water phase and photocatalyst phase after catalysis Carry out catalysis oxidation is more advantageous to after contact.So that whole reaction efficiency can be increased substantially to 12.5%-76%.
Preferably, the non-woven fabrics arranges that surface area is big, can improve light-catalyzed reaction to greatest extent in V-shape fold Efficiency.In general, the light source uses ultraviolet light source.As photocatalyst catalysis material is adhered on the non-woven fabrics of carrier, light is touched Matchmaker's catalysis material obtains huge specific surface area in same space volume, so that VOC exhaust gas and photocatalyst carry out sufficiently Contact improves the probability of happening of catalysis reaction.The exhaust gas decomposed is discharged into air by air outlet.
Above-mentioned catalyst can be used vanadium system oxidation reduction catalyst in sncr and preferably adopt in an alternative embodiment With 2.6% molybdenum, 7% titanium, the surface chemistry sedimentary facies and its oxide of the synthesis of 8%-11% nickel.
Preferably, the first seal plate 12, energy are equipped with close to air inlet side in atomizing humidifier on the apparatus body Enough avoid scavenging solution excessive.
Preferably, the second seal plate 13 is equipped with far from air inlet side in water filter on the apparatus body;It is described to set It is equipped with first communicated with fluid reservoir close to air inlet side in the second seal plate on standby ontology and crosses liquid mouth 14.In addition, described set Third seal plate 15 is equipped with close to air outlet side in inducing catalysis disproportionation filter on standby ontology;In third on apparatus body Seal plate is equipped with second communicated with fluid reservoir close to air inlet side and crosses liquid mouth 16, scavenging solution can be recycled to storage as far as possible Flow container.
In an alternative embodiment, the biomimetic features filter core includes the filter core carrier 17 of multi-cavity structure, described Filter core carries intracorporal number of cavities (or cavity volume size) and is incremented by from the top of carrier to middle part in geometric multiple, and by the load The middle part of body is successively decreased in geometric multiple to the lower part, and spiral packing part 18, each spiral packing part are filled in each cavity Towards random distribution.Preferably, spiral packing part upper end is big, lower end is small, and screw pitch is between 2mm-20mm.Specifically, Filter core carrier may include external framework 20 and internal retainer 21, and retainer is equipped with several ventholes 7.
It should be noted that non-equant conveyor screw changes at random, so that reaction medium system is in a kind of adaptive flat Weighing apparatus state, when local conveyor screw interface since catalysis reaction carries out too fast generation reaction product accumulation, then, water filter exists always The steam adulterated in absorption exhaust gas, when condensation vapor is after helix packing element the preceding paragraph time, with continuing to build up for water droplet Molding, reactant accumulation in short-term can change cross section of fluid channel, change flow velocity, accelerate the movement of deposit, avoid blocking, in this way Operating mode be similar to human lung's structure working principle.Therefore, the biomimetic features filter core in the invention is very sharp In rinsing, dirt being discharged, the deposition blocking of fine particle is avoided.
Equally, inducing catalysis disproportionation filter can also use above-mentioned biomimetic features, and carrier also uses multi-cavity structure Filter core carrier, the filter core carries intracorporal number of cavities (or cavity volume size) from the top of carrier to middle part in geometry times Number is incremented by, and is successively decreased to the lower part in geometric multiple by the middle part of the carrier, is filled in each cavity several described hollow Sphere corresponds to different directions on hollow ball equipped with several openings.Gas phase after inducing catalysis is disproportionated obtains huge ratio Surface area, then the reaction rate of oxygenolysis is accelerated after contacting with the photocatalyst under light action.
The invention reasonable structural arrangement can mix later the exhaust gas of water phase first by VOC exhaust gas solution compatible with lipid phase object It is catalyzed and is reacted using photocatalyst.Whole reaction efficiency is increased substantially, and then reaches discharge standard rapidly and efficiently.
The foregoing is merely the preferred embodiments of the invention, are not intended to limit the invention creation, all at this Within the spirit and principle of innovation and creation, any modification, equivalent replacement, improvement and so on should be included in the invention Protection scope within.

Claims (9)

1. one kind is based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: including apparatus body, the apparatus body into One lateral air outlet side of air port has been sequentially arranged lipid phase absorbing unit, inducing catalysis disproportionation unit and photocatalysis unit;
The lipid phase absorbing unit includes the atomizing humidifier that corresponding gas is arranged by air duct upper and lower ends, the atomizing humidifier Scavenging solution is extracted from fluid reservoir, water filter is equipped with above corresponding fluid reservoir, and the moisture of water filter absorption flows into fluid reservoir;Institute Stating water filter includes biomimetic features filter core;
The inducing catalysis disproportionation unit includes the inducing catalysis disproportionation filter that water filter rear end is arranged in, the inducing catalysis discrimination Changing filter includes several hollow balls being distributed on carrier and carrier;In the carrier surface and each hollow ball Outer wall surface is coated with catalyst coat, is equipped with water replanishing device above the corresponding carrier;
The photocatalysis unit includes the non-woven fabrics coated with photocatalyst material, and corresponds to what non-woven fabrics each section was set gradually Several light sources.
2. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the nonwoven Cloth is arranged in V-shape fold.
3. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the light source Using ultraviolet light source.
4. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the catalysis Agent coating uses vanadium series catalyst.
5. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the equipment The first seal plate is equipped with close to air inlet side in atomizing humidifier on ontology.
6. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the equipment The second seal plate is equipped with far from air inlet side in water filter on ontology;On the apparatus body the second seal plate close into Air port side is equipped with first communicated with fluid reservoir and crosses liquid mouth.
7. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the equipment Third seal plate is equipped with close to air outlet side in inducing catalysis disproportionation filter on ontology;In third sealing on apparatus body Plate is equipped with second communicated with fluid reservoir close to air inlet side and crosses liquid mouth.
8. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: described bionical Filter core includes the filter core carrier of multi-cavity structure, and the filter core carries intracorporal number of cavities from the top of carrier and is in middle part Geometric multiple are incremented by, and are successively decreased to the lower part in geometric multiple by the middle part of the carrier, are filled with spiral shape in each cavity and fill out Materials and parts, each spiral packing part towards random distribution.
9. according to claim 1 a kind of based on light-catalysed VOC waste gas treatment equipment, it is characterised in that: the spiral Shape packing element upper end is big, lower end is small, and screw pitch is between 2mm-20mm.
CN201910070104.2A 2019-01-24 2019-01-24 One kind being based on light-catalysed VOC waste gas treatment equipment Pending CN109647189A (en)

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Application Number Priority Date Filing Date Title
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451388A (en) * 1994-01-21 1995-09-19 Engelhard Corporation Catalytic method and device for controlling VOC. CO and halogenated organic emissions
CN1552457A (en) * 2003-05-23 2004-12-08 彭云龙 Nanometer optical catalyst air sterilizing purifier
CN103212291A (en) * 2013-04-27 2013-07-24 重庆大学 V-shaped folded-plate photocatalytic reactor
CN206046044U (en) * 2016-09-09 2017-03-29 天津雾净环保科技有限公司 A kind of bionical gas reaction device of lung and its model topology structure
CN106693938A (en) * 2017-01-25 2017-05-24 华东理工大学 VOC Fenton degradation activated carbon oxidation regeneration method and device
CN106823798A (en) * 2017-03-07 2017-06-13 浙江工业大学 A kind of ultrasonic synergistic ultraviolet light cleaning organic waste gas device and processing method
CN106914113A (en) * 2017-03-06 2017-07-04 常州大学 A kind of chlorobenzene exhaust-gas treatment tank
CN108211577A (en) * 2018-02-01 2018-06-29 华北水利水电大学 A kind of atmospheric haze controlling device
CN208194072U (en) * 2018-01-31 2018-12-07 杭州路成环保科技有限公司 A kind of photochemical catalytic oxidation absorption system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451388A (en) * 1994-01-21 1995-09-19 Engelhard Corporation Catalytic method and device for controlling VOC. CO and halogenated organic emissions
CN1552457A (en) * 2003-05-23 2004-12-08 彭云龙 Nanometer optical catalyst air sterilizing purifier
CN103212291A (en) * 2013-04-27 2013-07-24 重庆大学 V-shaped folded-plate photocatalytic reactor
CN206046044U (en) * 2016-09-09 2017-03-29 天津雾净环保科技有限公司 A kind of bionical gas reaction device of lung and its model topology structure
CN106693938A (en) * 2017-01-25 2017-05-24 华东理工大学 VOC Fenton degradation activated carbon oxidation regeneration method and device
CN106914113A (en) * 2017-03-06 2017-07-04 常州大学 A kind of chlorobenzene exhaust-gas treatment tank
CN106823798A (en) * 2017-03-07 2017-06-13 浙江工业大学 A kind of ultrasonic synergistic ultraviolet light cleaning organic waste gas device and processing method
CN208194072U (en) * 2018-01-31 2018-12-07 杭州路成环保科技有限公司 A kind of photochemical catalytic oxidation absorption system
CN108211577A (en) * 2018-02-01 2018-06-29 华北水利水电大学 A kind of atmospheric haze controlling device

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