CN109642185A - Fabrid care composition comprising glycerol ester copolymer - Google Patents

Abstract

The present invention relates to clean fabric and/or treatment compositions and the methods for making and using them.Such clean fabric and/or treatment compositions include the species of the glycerol ester copolymer with required viscosity and lubricity.Therefore, such glycerol ester copolymer provides improved softening performance and property prepared.

Description

Fabrid care composition comprising glycerol ester copolymer

Technical field

The present invention relates to clean fabric and/or treatment compositions and the methods for making and using them.

Background technique

Softening agent is commonly used to softening fabrics.Regrettably, current softening agent have multiple defects, including high cost, Narrow preparation PH window, lower than required stability and/or softening performance.In order to make great efforts to reduce such defect, new softening agent is also In continual exploitation.Regrettably, even if such softening agent newly developed still has one or more such defects.Application People recognizes that aforementioned drawback should be attributed to one or more of following factors: ester bond (for the β ester bond of quaternary ammonium group in molecule) Hydrolytic instability lead to pH intolerance, the high charge density of quaternary ammonium head-group cause salt intolerance and/or with yin Ionic material such as anionic surfactant is incompatible, and the mistake high molecular weight for polymerizeing softening agent makes it be difficult to handle and dispose. Therefore need cleaning and/or treatment compositions comprising following material: may act as soften active material, but not with current softening Active material defect level having the same.Applicants have recognized that glycerol ester copolymer can be used as such softening active material and It can lead to the performance gain cooperateed with when in conjunction with certain fabrics and household care ingredient.

Although without being bound by theory, applicant thinks uncharged property of glycerol ester copolymer and/or lower Oligomeric degree cause do not have aforementioned drawback.Therefore glycerol ester copolymer is tolerance salt and pH and is more easily handled and locates It sets, but still there is the softening power at least equally good with softening agent optimal at present.Therefore, comprising such glycerol ester copolymer Preparation can have wide pH range and/or salt level and be still stable.In addition, the salt of such preparation, anion and/or PH tolerance allows formulator to use Multiple components, including the still not available ingredient for formulator so far.In addition, Obtain the performance gain of collaboration, for example, when glycerol ester copolymer and cationic softener, cationic surfactant and/or When cationic polymer combines, there are unexpected flexibility performance gains；When glycerol ester copolymer and anionic surface are living Property agent combination when, obtain the enhancing of unexpected phase stability；When such glycerol ester copolymer is combined with water-soluble solid carrier When, it obtains unexpected glycerol ester copolymer deposition and increases；By being gathered with comprising glycerol ester copolymer and brightening agent, soil dispersion After the compositions-treated fabric for closing object, dope dye, dye transfer inhibitor and/or detergency enzymes and their mixture, obtain Obtaining unexpected fabric whiteness improves；Finally, by the combination comprising glycerol ester copolymer and fragrance and/or perfume delivery systems Object obtains unexpected depositing perfume and product stability gain.

Applicants have recognized that the problem of commercially available glycerol ester copolymer, is the rheological characteristic of such material, because Such rheological characteristic causes to sprawl a certain range on the fabric, and the first kind material of the fabric is insufficient and the second class excessive material is spread Exhibition.Therefore, the commercially available material of two classes all shows insufficient lubrication.The invention discloses with the sweet of correct rheological characteristic The pattern of grease copolymer.Such glycerol ester copolymer provides the softening performance expected and property prepared.

Regrettably, need to oxidation and enzyme chemical stability in terms of and machinability in terms of further change It is kind, it is produced because the viscosity of above-mentioned glycerol ester copolymer limits to be used to prepare by the fabric nursing that this class glycerol ester copolymer is prepared The efficiency of the method for product.Applicants have recognized that the source of viscosity problem is the fatty acid chain length distribution of glycerol ester copolymer.This Outside, the glycerol ester copolymer of the conventional metathesis derived from unsaturated polyol ester includes to lead to unfavorable smell in finished product Impurity.Applicants have recognized that this smell is caused by short-chain olefin double decomposition by-product, it is difficult to from derived from unsaturated polynary It is removed in the glycerol ester copolymer of the metathesis of alcohol ester.Therefore, applicant passes through alkylene and metathesized unsaturated polyol ester Problems are solved to form new glycerol ester copolymer.Therefore, reduce fatty acid chain length, but still profit needed for providing is provided The molecular weight of slip, and also reduce the short-chain olefin in Fabrid care composition and eliminate smell.Applicant discloses Such improved glycerol ester copolymer and wherein include the glycerol ester copolymer product.

Summary of the invention

The present invention relates to clean fabric and/or treatment compositions and the methods for making and using them.This kind fabric is clear Clean and/or treatment compositions include the species of the glycerol ester copolymer with required viscosity and lubricity.Therefore, such glyceride Copolymer unexpectedly provides improved softening performance and property prepared.

Specific embodiment

Definition

As used herein, term " natural oil ", " natural material " or " natural oil raw material " refer to come derived from plant or animal The oil in source.Unless otherwise specified, term " natural oil " includes natural oil derivatives.Unless otherwise specified, the term Also include modified plant or animal origin (for example, plant or animal origin through gene modification), and by fermentation or Enzymatic method generates or the derivative of modification.The example of natural oil include but is not limited to vegetable oil, algae oil, fish oil, tallow, Tall oil, derivatives of these oil, combination any in these oil etc..The representative non-limiting example of vegetable oil includes low It is erucic acid rapeseed oil (canola oil), high erucic acid rapeseed oil, coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, red Caul-fat, sesame oil, soybean oil, sunflower oil, linseed oil, palm-kernel oil, tung oil, Jatropha oil, canola, penny cress Oil, shepherd's purse indigo plant seed oil, cannabis oil and castor oil.The representative non-limiting example of animal tallow includes lard, tallow, poultry rouge Fat, butter fat and fish oil.Tall oil is the byproduct of wood pulp manufacture.In some embodiments, natural oil or natural oil are former Material includes one or more unsaturated glycerides (for example, unsaturated triglyceride).In some such embodiments, natural oil Comprising at least 50 weight % or at least 60 weight % of the total weight based on the natural oil or at least 70 weight % or at least One kind of 80 weight % or at least 90 weight % or at least 95 weight % or at least 97 weight % or at least 99 weight % or A variety of unsaturated triglycerides.

Term " natural oil glyceride " refers to the glyceride of the fatty acid derived from natural oil.Such glyceride includes monoacyl Glyceride, diacylglycerol ester and triacylglyceride (triglycerides).In some embodiments, natural oil glyceride is sweet Oily three esters.Similarly, term " unsaturated natural oil glyceride " refers to natural oil glyceride, wherein in its fatty acid residue extremely Few one contains degree of unsaturation.For example, the glyceride of oleic acid is unsaturated natural oil glyceride.Term " unsaturated alkenyl day Right oil glyceride " refer to by with sorting olefine (as given a definition) metathesis reaction derived from the natural oil glyceride of unsaturation (as defined above).In some cases, Olefination process shortens one or more fatty acid chains in compound.For example, 9- The glyceride of decylenic acid is the natural oil glyceride of unsaturated alkenyl.Similarly, butylene is (for example, utilize 1- butylene and/or 2- Butylene) canola oil is natural oil glyceride, it is modified to include some short chain unsaturation C by double decomposition_10-15Ester group.

Term " natural oil derivatives " refers to its derivative from natural oil.It is used to form these natural oil derivatives Method may include addition, neutralization, high alkalinity, saponification, transesterification, interesterification, esterification, amidation, hydrogenation, isomerization, Oxidation, alkanisation, acylation, vulcanization, sulfonation, rearrangement, reduction, fermentation, pyrolysis, hydrolysis, liquefaction, anaerobic digestion, hydro-thermal process, gasification One of or a variety of or two or more in them combinations.The example of their natural derivative may include carboxylic acid, Natural gum, phosphatide, soap stock, acidification soap stock, distillate or distillate sludge, fatty acid, aliphatic ester and their hydroxyl replace Modification, including unsaturated polyol ester.In some embodiments, natural oil derivatives may include having about 5 to about 30 Carbon atom, the unsaturated carboxylic acid in hydrocarbon (alkene) chain with one or more carbon-to-carbon double bonds.Natural oil derivatives also may include From unsaturated fat dialkylaminobenzoic acid (such as methyl) ester of the glyceride of natural oil.For example, natural oil derivatives can be source In the fatty acid methyl ester (" FAME ") of the glyceride of natural oil.In some embodiments, raw material includes canola oil or soybean Oil, as a non-limiting example, including refining, decoloration and the oil (i.e. RBD soybean oil) being deodorized.

As used herein, term " unsaturated polyol ester " refers to the compound with two or more hydroxyl groups, Wherein at least one of hydroxyl group is the form of ester, and wherein the ester have include at least one carbon-to-carbon double bond Organic group.

Term " oligomeric glyceride fraction " be comprising two or more, up to 20 in one aspect, in another party Face is up to the part of 10 structural units, and the structural unit is via olefin metathesis by natural oil glyceride and/or alkenyl Change natural oil glyceride to be formed.

Term " free hydrocarbon " refers in C_2-30Any one of insatiable hunger and/or saturated straight chain, branch or cyclic hydrocarbon in range Or combination.

Term " metathesis monomers " refers to the single entity of the product as olefin metathesis reaction, and it includes have one Or the compound molecule of multiple carbon-to-carbon double bonds, the compound molecule is via one or more carbon-of the same intramolecular Carbon double bond experience alkylidene unit exchange (intramolecular double decomposition) and/or with include the another of one or more carbon-to-carbon double bonds Compound molecule such as alkene experience alkylidene unit exchanges (intermolecular double decomposition).In some embodiments, which is Refer to that triglycerides or other unsaturated polyol esters, not yet experience alkylidene unit are exchanged but are included at the position " ω-n " and have There is at least one C of carbon-to-carbon double bond_4-17Ester, wherein n=0,1,2,3,4,5 or 6 and wherein ester moiety has at least n+3 Carbon atom.

Term " double decomposition dimer " refer to it is as metathesis reaction as a result, two of them reactant compound (it can It is identical or different and respectively there are one or more carbon-to-carbon double bonds) via one or more of each reactant compound Carbon-to-carbon double bond and the product of metathesis reaction being bonded together.

Term " double decomposition trimer " refers to as one or more metathesis reactions as a result, two of them or more Three molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the trimer include three binding groups derived from reactant compound.

Term " double decomposition tetramer " refers to as one or more metathesis reactions as a result, two of them or more Four molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the tetramer include four binding groups derived from reactant compound.

Term " double decomposition pentamer " refers to as one or more metathesis reactions as a result, two of them or more Five molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the pentamer include five binding groups derived from reactant compound.

Term " double decomposition hexamer " refers to as one or more metathesis reactions as a result, two of them or more Six molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the hexamer include six binding groups derived from reactant compound.

Term " double decomposition haptamer " refers to as one or more metathesis reactions as a result, two of them or more Seven molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the haptamer include seven binding groups derived from reactant compound.

Term " double decomposition octamer " refers to as one or more metathesis reactions as a result, two of them or more Eight molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the octamer include eight binding groups derived from reactant compound.

Term " double decomposition nonamer " refers to as one or more metathesis reactions as a result, two of them or more Nine molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, the nonamer include nine binding groups derived from reactant compound.

Term " ten polymers of double decomposition " refers to as one or more metathesis reactions as a result, two of them or more Ten molecules in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) are via each One or more carbon-to-carbon double bonds in a reactant compound and the production of one or more metathesis reactions being bonded together Object, ten polymers include ten binding groups derived from reactant compound.

Term " metathesis oligomers " refers to as one or more metathesis reactions as a result, two of them or more Two or more points in reactant compound (it may be the same or different and respectively has one or more carbon-to-carbon double bonds) Sub (for example, 2 to about 10 or 2 to about 4) key via one or more carbon-to-carbon double bonds in each reactant compound The product for the one or more metathesis reactions being combined, the oligomer include several derived from reactant compound (for example, 2 to about 10 or 2 to about 4) binding groups.In some embodiments, term " metathesis oligomers " may include Metathesis reaction, (it may be the same or different and respectively has one or more two of them or more reactant compound Carbon-to-carbon double bond) in be bonded in via one or more carbon-to-carbon double bonds in each reactant compound more than ten molecules Metathesis reaction together, the oligomer include to be more than ten binding groups derived from reactant compound.

As used herein, " double decomposition " refers to olefin metathesis.As used herein, " metathesis catalyst " includes catalysis alkene Any catalyst or catalyst system of hydrocarbon metathesis reaction.

As used herein, " double decomposition " and " double decomposition ", which refers to, reacts raw material with shape in the presence of metathesis catalyst At " metathesis product " comprising new olefinic compounds, i.e. " double decomposition " compound.Double decomposition is not limited to any specific type Olefin metathesis, and can refer to cross metathesis (that is, altogether double decomposition), self-metathesis, ring-opening methathesis, ring-opening methathesis It polymerize (" ROMP "), ring closing metathesis (" RCM ") and acyclic diene double decomposition (" ADMET ").In some embodiments, Double decomposition refers in the presence of metathesis catalyst, and (itself is multiple for the two kinds of triglycerides reaction for making to be present in natural material Decompose), wherein every kind of triglycerides has unsaturated carbon-to-carbon double bond, so that the new blend of alkene and ester is formed, it is described new mixed Closing object may include triglycerides dimer.This quasi-glycerol three-ester dimer can have more than one ethylene linkage, therefore higher oligomeric Object can also be formed.These higher oligomers may include one of the following or a variety of: metathesis monomers, double decomposition dimer, multiple Decompose that trimer, double decomposition tetramer, (such as double decomposition six is poly- for double decomposition pentamer and more advanced metathesis oligomers Object, double decomposition object, double decomposition haptamer, double decomposition octamer, double decomposition nonamer, ten polymers of double decomposition and compare double decomposition The more advanced oligomer of ten polymers and more than).In addition, double decomposition, which can be, instigates alkene all in some other embodiments If the triglycerides in ethylene, and the natural material at least one unsaturated carbon-to-carbon double bond reacts, to form new alkene Hydrocarbon molecule and new ester molecule (cross metathesis).

As used herein, term " alkylene natural polyols ester and/or alkylene synthesize polyol ester " refer to by it is natural and/ Or synthesize polyol ester and C_2-14Alkene, preferably C_2-6Alkene, more preferably C_3-4Alkene and their mixture and isomery The standby product of body metathetical.

As used herein, " alkene " or " a variety of alkene " refers to the compound at least one unsaturated carbon-to-carbon double bond. In certain embodiments, term " alkene " refers to one group of unsaturated carbon-carbon double bond compound with different carbon chain lengths.It removes Non- otherwise indicated, otherwise term " alkene " or " a variety of alkene " cover " the how unsaturated alkene with more than one carbon-to-carbon double bond Hydrocarbon " or " polyolefin ".As used herein, term " single unsaturated olefin " or " monoolefine ", which refer to, only has a carbon-to-carbon double bond Compound.Compound with end carbon-to-carbon double bond is referred to alternatively as " terminal olefin " or " alpha-olefin ", however has non-end The alkene of carbon-to-carbon double bond is referred to alternatively as " internal olefin ".In some embodiments, alpha-olefin is terminal olefin, for end Hold the alkene (such as giving a definition) of carbon-to-carbon double bond.Additional carbon-to-carbon double bond may be present.

Carbon atom number in any group or compound can be indicated by following term: " C_z", refer to z carbon atom Compound group；" C_x-y", refer to group or compound comprising x to y (including end value) a carbon atom.For example, “C_1-6Alkyl " indicate have 1 to 6 carbon atom alkyl chain, and e.g., including but be not limited to methyl, ethyl, n-propyl, Isopropyl, isobutyl group, normal-butyl, sec-butyl, tert-butyl, isopentyl, n-pentyl, neopentyl and n-hexyl.Show as another Example, " C_4-10Alkene " refers to the olefin hydrocarbon molecules with 4 to 10 carbon atoms, and e.g., including but it is not limited to 1- butylene, 2- fourth Alkene, isobutene, 1- amylene, 1- hexene, 3- hexene, 1- heptene, 3- heptene, 1- octene, 4- octene, 1- nonene, 4- nonene and 1- Decene.

As used herein, term " short-chain olefin " or " short-chain olefin " refer in C_2-14In range, or in C_2-12In range, Or in C_2-10In range or in C_2-8Any one of unsaturated straight chain, branch or cyclic hydrocarbon in range or combination.Such alkene Hydrocarbon includes alpha-olefin, wherein unsaturated carbon-carbon bond is present in an end of compound.Such alkene further includes diene or three Alkene.Such alkene further includes internal olefin.In C_2-6The example of short-chain olefin in range includes but is not limited to ethylene, propylene, 1- Butylene, 2- butylene, isobutene, 1- amylene, 2- amylene, 2- methyl-l- butylene, 2- methyl-2-butene, 3- methyl-l- butylene, ring Amylene, 1,4- pentadiene, 1- hexene, 2- hexene, 3- hexene, 2- methyl-l- amylene, 3- methyl-l- amylene, 4- methyl-l- penta Alkene, 2- methyl -2- amylene, 3- methyl -2- amylene, 4- methyl -2- amylene, 2- methyl -3- amylene and cyclohexene.In C_7-9Model The non-limiting example of short-chain olefin in enclosing includes 1,4- heptadiene, 1- heptene, 3,6- nonadiene, 3- nonene, 1,4,7- pungent Triolefin.In some embodiments, it is preferred that the mixture includes C using the mixture of alkene_4-10Straight chain and branch in range Chain low molecular weight olefins.In some embodiments, straight chain and branch C are preferably used₄The mixture of alkene is (that is, following object The combination of matter: 1- butylene, 2- butylene, and/or isobutene).In other embodiments, C can be used_11-14Higher range.

As used herein, " alkyl " refers to the linear chain or branched chain saturated hydrocarbons with 1 to 30 carbon atom, optionally by Replace, as further described herein, wherein allowing multiple degree of substitution.As used herein, the example of " alkyl " includes but unlimited In methyl, ethyl, n-propyl, isopropyl, isobutyl group, normal-butyl, sec-butyl, tert-butyl, isopentyl, n-pentyl, neopentyl, just Hexyl and 2- ethylhexyl.Carbon atom number in alkyl group is by phrase " C_x-yAlkyl " indicate, refer to comprising x to y (including Including end value) alkyl group of a carbon atom, as herein defined.Therefore, " C_1-6Alkyl " indicates there is 1 to 6 carbon atom Alkyl chain, and e.g., including but be not limited to methyl, ethyl, n-propyl, isopropyl, isobutyl group, normal-butyl, sec-butyl, uncle Butyl, isopentyl, n-pentyl, neopentyl and n-hexyl.In some cases, " alkyl " group can be divalent, this In the case of, the group is alternatively referred to as " alkylidene " group.

As used herein, " alkenyl " refers to 2 to 30 carbon atoms and has the straight of one or more carbon-to-carbon double bonds Chain or branch non-aromatic hydrocarbons, the carbon-to-carbon double bond are optionally substituted, as further described herein, wherein allowing multiple Degree of substitution.As used herein, the example of " alkenyl " includes but is not limited to vinyl, 2- acrylic, 2- cyclobutenyl and 3- cyclobutenyl. Carbon atom number in alkenyl group is by phrase " C_x-yAlkenyl " indicates, refers to comprising x to y (including end value) a carbon atom Alkenyl group, as herein defined.Therefore, " C_2-6Alkenyl " indicates the alkenylene chain with 2 to 6 carbon atoms, and example Such as, including but not limited to vinyl, 2- acrylic, 2- cyclobutenyl and 3- cyclobutenyl.In some cases, " alkenyl " group can be with For divalent, in this case, the group is alternatively referred to as " alkenylene " group.

As used herein, " direct key " refers to that wherein identified part is not present in structure, and connected by it The embodiment that key between other parts replaces.For example, if specification or claim list A-D-E, and D is determined Justice is direct key, then resulting structure is A-E.

As used herein, " substitution " refers to the one or more hydrogen for replacing specified portions with one or more of substituent groups Atom, unless otherwise stated, allowing multiple degree of substitution, precondition is that the substitution leads to stabilization or chemically feasible Compound.Stable compound or chemically feasible compound are that moisture or other chemical reactivity conditions wherein are being not present In the case where, about -80 DEG C to about+40 DEG C at a temperature of kept at least one week when, chemical combination that chemical structure not substantially changes Object.As used herein, phrase " one or more ... to replace " or " replacing one or many ... ", refer to based on available bonding position Points, the substitution radix of radix is replaced equal to one to maximum possible, and precondition is to meet aforementioned stable and chemistry is feasible Property condition.

As used herein, term " polyol " means to contain at least two the organic material of hydroxylic moiety.

As used herein, term " C_10-14Unsaturated fatty acid ester " means to include 10,11,12,13 or 14 carbon atoms Aliphatic ester, wherein the aliphatic ester chain has at least one carbon-to-carbon double bond.

Under some cases of this paper, " cable architecture " method of use describes organic compound, and wherein chemical bond is indicated by line, Wherein carbon atom is not explicitly labeled, and does not show completely wherein and the hydrogen atom of carbon covalent bonding (or c h bond).For example, root According to the convention, formulaIndicate n-propane.Under some cases of this paper, zigzag key can have two for showing compound Any one of kind or more isomers.For example, structureIt can refer to (E) -2- butylene or (Z) -2- butylene.It is drawing It is also such about referring to when which kind of isomers is indefinite alkene structures.For example, CH₃- CH=CH-CH₃It may refer to (E) -2- Butylene or (Z) -2- butylene.

As used herein, representative various functional groups will be understood as with hyphen or dash (-) or asterisk There is tie point at the functional group of (*).In other words, in-CH₂CH₂CH₃In the case where, it should be understood that the tie point is most left The CH of side₂Group.If listing the group without asterisk or dash, tie point is referred to by the ordinary meaning of listed group Show.

As used herein, polyatom divalent species are from left to right read.For example, if specification or claim recitation A-D-E and D are defined as-OC (O)-, then the substituted resulting group of D is A-OC (O)-E rather than A-C (O) O-E.

As used herein, unless otherwise stated, term " fabric " care composition " it include that can be used for by washing, floating It washes or cleans during drying and/or the composition of softening fabrics, such composition include more function of graininess or powder type Energy or " heavy duty detergent " detergent, especially detergent；The multifunctional detergent of liquid, gel or paste-like, it is especially so-called Heavy duty liquid type；Liquid fine fabric detergents, those of especially high bubbling type；Including for family and mechanism use Various tablets, graininess, unit dosage forms；Cleaning rod, automobile or carpet cleaner, fabric conditioning product (including softening agent and/ Or freshener, can be liquid, solid and/or drying agent chip form)；And cleaning adjuvant, such as such as bleaching additive and " decontamination Stick " or pretreatment type product with substrate, such as dryer paper.All such products that can be applied can be canonical form, dense Contracting form or even highly enriched form, in some aspects, such product can even is that non-aqueous.

As used herein, term " solid " includes particle, powder, bar, bead, pastille and tablet form.

As used herein, it when in claim, is understood to refer to including the article of "one" and "an" It is one or more to be claimed or described substance.

As used herein, the terms "include", "comprise" and " containing " are it is intended that unrestricted.

Unless otherwise specified, all components or composition level be the active part with regard to the component or composition and Speech, and do not include the impurity being likely to be present in the commercially available source of such component or composition, such as residual solvent Or by-product.

Unless otherwise specified, all percentages and ratio are calculated by weight.Unless otherwise specified, all hundred Divide than being based on total composition calculating with ratio, precondition is the percentage summation of respective mixtures/formula all the components It is no more than or less than 100%.

It should be appreciated that include each lower numerical limitation through each greatest measure limit that this specification provides, as The lower numerical limitation clearly writes out herein.The each minimum value limit provided through this specification will include it is each compared with High numerical limitation, as the high value limit is clearly write out herein.The each numberical range provided through this specification It will include each narrower numberical range fallen within the scope of the bigger numerical, as the narrower numberical range is all herein In clearly write out.

Composition, product, application method and processed product

Section (a) to (vv)

The invention discloses following composition, application method and through treatment articles:

(a) a kind of composition, the composition includes:

A) it is selected from following material:

(i) the first glycerol ester copolymer, it includes the total weights about 3% based on the first glycerol ester copolymer to about 30%, about 3% to the about 25% or C of about 5% to about 20%_10-14Unsaturated fatty acid ester；In one aspect, described first is sweet Grease copolymer is comprising the total weight about 3% to about 30%, about 3% to about 25% based on the first glycerol ester copolymer or about The C of 3% to about 20%_10-13Unsaturated fatty acid ester；In one aspect, the first glycerol ester copolymer includes sweet based on first The total weight of grease copolymer about 0.1% to about 30%, about 0.1% to about 25% or about 0.2% to about 20% or about The C of 0.5% to about 15%_10-11Unsaturated fatty acid ester；

(ii) with the second glycerol ester copolymer of formula (I):

Wherein:

Each R in second glycerol ester copolymer¹、R²、R³、R⁴And R⁵Independently selected from oligomeric glyceride fraction, C_1-24Alkane Base, the wherein substituent group are the substituted C of the part one or more-OH_1-24Alkyl, C_2-24Alkenyl or in which the substitution Base is the substituted C of the part one or more-OH_2-24Alkenyl；And/or it is wherein each in the following combination of each section It is a to be covalently attached each independently:

R¹And R³,

R²And R⁵,

R¹With adjacent R⁴,

R²With adjacent R⁴,

R³With adjacent R⁴,

R⁵With adjacent R⁴, or

Any two adjacent R⁴

So that the part of the covalent linkage forms alkenylene moieties；

Each X in the second glycerol ester copolymer¹And X²Independently selected from C_1-32Alkylidene, the wherein substituent group For the substituted C of the part one or more-OH_1-32Alkylidene, C_2-32Alkenylene or in which the substituent group are one or more The substituted C of a part-OH_2-32Alkenylene；

G¹、G²And G³In two be-CH₂, and G¹、G²And G³In one be direct key；

For the independent repetitive unit of each of repetitive unit with index n, G⁴、G⁵And G⁶In two be-CH₂, And G⁴、G⁵And G⁶One be direct key, and the G of each individually repetitive unit⁴、G⁵And G⁶Value it is heavy independently selected from other G in multiple unit⁴、G⁵And G⁶Value；

G⁷、G⁸And G⁹In two be-CH₂, and G⁷、G⁸And G⁹In one be direct key；

The integer that n is 3 to 250；

Precondition is for each in the second glycerol ester copolymer, R¹、R²、R³And R⁵At least one of, And/or at least one R in an independent repetitive unit of the repetitive unit with index n⁴It is selected from: 8- nonenyl；8- Decene base；8- undecenyl；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；8,11- oleatridecadiene base；8,11- ten Four carbon dialkylenes；8,11- pentadecane dialkylene；8,11,14- pentadecane trialkenyl；16 carbon trialkenyl of 8,11,14-；8,11, 18 carbon trialkenyl of 14-；9- methyl -8- decene base；9- methyl -8- undecenyl；10- methyl -8- undecenyl；12- Methyl -8,11- oleatridecadiene base；14 carbon dialkylene of 12- methyl -8,11-；14 carbon dialkylene of 13- methyl -8,11-； 16 carbon trialkenyl of 15- methyl -8,11,14-；17 carbon trialkenyl of 15- methyl -8,11,14-；16- methyl -8,11,14- ten Seven carbon trialkenyls；12- tridecylene base；12- tetradecene base；12- pentadecane alkenyl；12- hexadecene base；13- methyl- 12- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- methyl-1 2- pentadecane alkenyl；In one aspect, described Two glycerol ester copolymers include total weight about 3% to about 30% based on the second glycerol ester copolymer, about 3% to about 25%, Or the C of about 5% to about 20%_9-13Alkenyl part；In one aspect, the second glycerol ester copolymer includes to be based on the second glycerol The total weight of ester copolymer about 3% to about 30%, about 3% to about 25% or the C of about 3% to about 20%_9-12Alkenyl part； In one aspect, the second glycerol ester copolymer includes the total weight about 0.1% based on the second glycerol ester copolymer to about 30%, about 0.1% to about 25%, about 0.2% to the about 20% or C of about 0.5% to about 15%_9-10Alkenyl part；And

(iii) optionally, third glycerol ester copolymer, the third glycerol ester copolymer are deposited included in metathesis catalyst Under, the structural unit formed is reacted by one or more compounds, the compound is in the compound with following formula Each:

Formula (IIa):

Formula (IIb):

Wherein,

Each R¹¹、R¹²And R¹³It independently is C_1-24Alkyl, wherein substituent group are being substituted for the part one or more-OH C_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, precondition It is R¹¹、R¹²And R¹³At least one of be C_2-24Alkenyl or in which substituent group are the substituted of the part one or more-OH C_2-24Alkenyl；And

Each R²¹、R²²And R²³It independently is C_1-24Alkyl, wherein substituent group are being substituted for the part one or more-OH C_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, precondition It is R²¹、R²²And R²³At least one of be 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic；8,11- ten Two carbon dialkylenes；8,11- oleatridecadiene base；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- 15 Carbon trialkenyl；16 carbon trialkenyl of 8,11,14-；18 carbon trialkenyl of 8,11,14-；9- methyl -8- decene base；9- methyl -8- Undecenyl；10- methyl -8- undecenyl；12- methyl -8,11- oleatridecadiene base；14 carbon of 12- methyl -8,11- Dialkylene；14 carbon dialkylene of 13- methyl -8,11-；16 carbon trialkenyl of 15- methyl -8,11,14-；Methyl -8,11 15-, 17 carbon trialkenyl of 14-；17 carbon trialkenyl of 16- methyl -8,11,14-；12- tridecylene base；12- tetradecene base；12- Pentadecane alkenyl；12- hexadecene base；13- methyl-1 2- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- first Base -12- pentadecane alkenyl；

The structural unit wherein formed by the monomeric compound that formula (IIa) is indicated and the monomer chemical combination indicated by formula (IIb) The quantity ratio for the structural unit that object is formed is no more than 10:1；And

(iv) their mixture；And

B) be selected from following material: fabric softener active, fabric care benefit agents, anionic surfactant are clear Except agent, delivery enhancer, fragrance, perfume delivery systems, structural agent, soil dispersion polymer, brightening agent, dope dye, dyestuff Transfer inhibitor, builder, surfactant, enzyme, in one aspect, detergency enzymes and their mixture, and optionally Carrier, in one aspect, the composition have the pH of about 2 to about 12,

The composition is Fabrid care composition.

(b) composition according to section (a), wherein the first, second, and third glycerol ester copolymer has about 4, 000g/mol to about 150,000g/mol, about 5,000g/mol to about 130,000g/mol, about 6,000g/mol to about 100, 000g/mol, about 7,000g/mol are to about 50,000g/mol, about 8,000g/mol to about 30,000g/mol, about 8,000g/mol To the weight average molecular weight of about 20,000g/mol.

(c) composition according to section (a) to (b), wherein the first, second, and third glycerol ester copolymer passes through Method preparation including double decomposition；In one aspect, the method includes making two kinds in the presence of metathesis catalyst Or more monomer reaction, as a part of reaction mixture, wherein by formula (IIa) indicate monomeric compound with by formula (IIb) indicate monomeric compound weight and weight ratio be no more than 10:1, be no more than 9:1, be no more than 8:1, be no more than 7:1, No more than 6:1, be no more than 5:1, be no more than 4:1, be no more than 3:1, be no more than 2:1 or be no more than 1:1；In one aspect, described Metathesis catalyst is organic ruthenium compound, organic osmium compound, organotungsten compounds or organic molybdenum.

(d) composition according to section (a) to (c), wherein for the second glycerol ester copolymer, R¹、R²、R³、R⁴ Or R⁵At least one of be C_9-13Alkenyl, in one aspect, R¹、R²、R³、R⁴Or R⁵At least one of be C_9-12Alkenyl, another On the one hand, R¹、R²、R³、R⁴Or R⁵At least one of be C_9-10Alkenyl.

(e) composition according to section (a) to (d), wherein for the third glycerol ester copolymer, R¹¹、R¹²、R¹³、 R²¹、R²²Or R²³At least one of be C_9-13Alkenyl, in one aspect, R¹¹、R¹²、R¹³、R²¹、R²²Or R²³At least one of For C_9-12Alkenyl, on the other hand, R¹¹、R¹²、R¹³、R²¹、R²²Or R²³At least one of be C_9-10Alkenyl.

(f) composition according to section (a) to (e), wherein the G of the second glycerol ester copolymer¹And G²Partially be- CH₂And G³For direct key.

(g) composition according to any one of section (a) to (e), wherein the G of the second glycerol ester copolymer¹And G³ Part is-CH₂And G²For direct key.

(h) composition according to any one of section (a) to (e), wherein the G of the second glycerol ester copolymer²And G³ Part is-CH₂And G¹For direct key.

(I) composition according to section (a) to (h), wherein for the second glycerol ester copolymer, G⁴And G⁵In at least One is-CH₂And G⁶For direct key.

(i) composition according to any one of section (a) to (h), wherein for the second glycerol ester copolymer, G⁴And G⁶ At least one of be-CH₂And G⁵For direct key.

(k) composition according to any one of section (a) to (h), wherein for the second glycerol ester copolymer, G⁵And G⁶ At least one of be-CH₂And G⁴For direct key.

(l) composition according to any one of section (a) to (k), wherein for the second glycerol ester copolymer, G⁷And G⁸ At least one of be-CH₂And G⁹For direct key.

(m) composition according to section (a) to (k), wherein for the second glycerol ester copolymer, G⁷And G⁹In at least One is-CH₂And G⁸For direct key.

(n) composition according to section (a) to (k), wherein for the second glycerol ester copolymer, G⁸And G⁹In at least One is-CH₂And G⁷For direct key.

(o) composition according to any one of section (a) to (n), wherein for the second glycerol ester copolymer, often A X¹Independently selected from-(CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、- (CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₁₁- CH=CH- (CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、- (CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-。

(p) composition according to any one of section (a) to (m), wherein for the second glycerol ester copolymer, often A X²Independently selected from-(CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、- (CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₁₁- CH=CH- (CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、- (CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-。

(q) composition according to any one of section (a) to (p), wherein for the second glycerol ester copolymer, R¹ For C_1-24Alkyl or C_2-24Alkenyl；In one aspect, R¹It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon of 8- Alkenyl, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8, 11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene Base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl, on the other hand, R¹It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- Dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11,14- 16 carbon trialkenyls, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(r) composition according to any one of section (a) to (q), wherein for the second glycerol ester copolymer, R² For C_1-24Alkyl or C_2-24Alkenyl；In one aspect, R²It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon of 8- Alkenyl, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8, 11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene Base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；On the other hand, R²It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- Dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11,14- 16 carbon trialkenyls, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(s) composition according to any one of section (a) to (r), wherein for the second glycerol ester copolymer, R³ For C_1-24Alkyl or C_2-24Alkenyl；In one aspect, R³It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon of 8- Alkenyl, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8, 11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene Base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；On the other hand, R³It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- Dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11,14- 16 carbon trialkenyls, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(t) composition according to any one of section (a) to (s), wherein for the second glycerol ester copolymer, often A R⁴Independently selected from C_1-24Alkyl and C_2-24Alkenyl；In one aspect, each R⁴Independently selected from: 8- nonenyl, 8- decene Base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 diene of 8,11- Base, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon of 8,11,14- Trialkenyl, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- Oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, methyl -8 15-, 16 carbon trialkenyl of 11,14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；On the other hand, each R⁴Independently selected from: 8- Nonenyl, 8- decene base, 8- undecenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon two of 8,11- Alkenyl, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(u) composition according to any one of section (a) to (t), wherein for the second glycerol ester copolymer, R⁵ For C_1-24Alkyl or C_2-24Alkenyl；In one aspect, R⁵It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon of 8- Alkenyl, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8, 11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene Base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；On the other hand, R⁵It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- Dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11,14- 16 carbon trialkenyls, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(v) composition according to any one of section (a) to (u), wherein for the second glycerol ester copolymer, n be 3 to 250,5 to 180,6 to 140,8 to 70,9 to 40 or 9 to 26 integer.

(w) composition according to section (a) to (c), wherein for the third glycerol ester copolymer, R¹¹、R¹²And R¹³ It is each independently selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 17 carbon dialkylene of 8,11- and 17 carbon of 8,11,14- Trialkenyl.

(x) composition according to section (a) to (c) and (w), wherein for the third glycerol ester copolymer, R²¹、 R²²And R²³In two independently selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 17 carbon dialkylene of 8,11- and 8, 17 carbon trialkenyl of 11,14-；And wherein, R²¹、R²²And R²³In one be selected from: 8- nonenyl, 8- decene base, 11 carbon of 8- Alkenyl, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- 15 Carbon dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- first Base -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene Base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon of 15- methyl -8,11,14- Trialkenyl, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- ten Five carbene bases and 14- methyl-1 2- pentadecane alkenyl；In one aspect, R²¹、R²²And R²³In one be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8, 11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- 15 Carbene base.

(y) composition according to section (a) to (c) and (w), wherein for the third glycerol ester copolymer, R²¹、 R²²And R²³In one be selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 17 carbon dialkylene of 8,11- and 8,11,14- 17 carbon trialkenyls；And wherein, R²¹、R²²And R²³In two independently selected from 8- nonenyl, 8- decene base, 11 carbon of 8- Alkenyl, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- 15 Carbon dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- first Base -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene Base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon of 15- methyl -8,11,14- Trialkenyl, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- ten Five carbene bases and 14- methyl-1 2- pentadecane alkenyl；In one aspect, R²¹、R²²And R²³In two independently selected from 8- nonyl Alkenyl, 8- decene base, 8- undecenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon diene of 8,11- Base, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(z) a kind of composition comprising glycerol ester copolymer, the glycerol ester copolymer include by following substance reaction shape At structural unit:

A) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride and unsaturated alkenyl natural oil are sweet Grease；

B) in the presence of metathesis catalyst, at least unsaturated synthesis polyol ester and unsaturated alkenyl natural oil are sweet Grease；

C) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride is combined to polynary with unsaturated alkenyl Alcohol ester；

D) in the presence of metathesis catalyst, at least unsaturated synthesis polyol ester and unsaturated alkenyl are combined to polynary Alcohol ester；

D) in the presence of metathesis catalyst, at least unsaturated alkenyl is combined to polyol ester and unsaturated alkenyl chemical combination At polyol ester；

F) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride of alkenyl and unsaturated alkenyl day Right oil glyceride；

The composition is Fabrid care composition.

In one aspect, the glycerol ester copolymer includes C_10-14Unsaturated fatty acid ester,

In one aspect, the catalyst is selected from organic ruthenium compound, organic osmium compound, organotungsten compounds, organic Molybdenum compound and their mixture.

In one aspect, the natural oil glyceride of unsaturated alkenyl is by there are metathesis catalyst, no It is saturated natural oil glyceride to be formed with reacting for short-chain olefin, in one aspect, the catalyst is selected from organic ruthenium compound, has Machine osmium compound, organotungsten compounds, organic molybdenum and their mixture, in one aspect, short-chain olefin is selected from Ethylene, propylene, 1- butylene, 2- butylene, isobutene, 1- amylene, 2- amylene, 1- hexene, 2- hexene, 3- hexene and theirs is mixed Object is closed, in one aspect, short-chain olefin is selected from ethylene, propylene, 1- butylene and 2- butylene and their mixture, at one Aspect, the unsaturated natural oil glyceride of alkenyl have the natural lower molecular weight of oil glyceride more unsaturated than second；

In one aspect, the unsaturated natural oil glyceride derives from natural oil；In one aspect, it derives from vegetable oil, move Object fat and/or algae oil；In one aspect, Abyssinia's oil, almond oil, apricot oil, apricot kernel oil, Morocco's nut are derived from Oil, avocado oil, babassu oil, monkey-bread tree oil, black ennel oil, currant oil, borage oil, shepherd's purse indigo plant seed oil, rapeseed oil, mustard Caul-fat, castor oil, cherry-kernel oil, coconut oil, corn oil, cottonseed oil, blue dragonfly oil, evening primrose oil, linseed oil, grape seed oil, Grapefruit seed oil, hazelnut oil, hemp-seed oil, Jatropha oil, jojoba oil, Hawaii macadamia nut oil, linseed oil, Queensland nut Oily, white awns flower seed oil, veepa oil, olive oil, palm oil, palm-kernel oil, persic oil, peanut oil, pecan oil, is held back oil ben Blue rape oil, Purple Perilla Seed Oil, pistachio oil, granada seed oil, pongam oil, pumpkin seed oil, raspberry seed oil, red palm oil, rice Oil extracted from rice husks, safflower oil, hippophae rhamnoides fruit oil, sesame seed oil, shea butter, sunflower oil, soybean oil, smokes careless soya-bean oil, paulownia at rose hip oil Oil, walnut oil, wheat-germ oil, high oleoyl soybean oil, high oleoyl sunflower oil, high oleoyl safflower oil, high erucic acid rape seed oil, And their mixture；

In one aspect, the synthesis polyol ester, which is derived from, is selected from following material: ethylene glycol, glycerol, gathers at propylene glycol Glycerol, polyethylene glycol, polypropylene glycol, poly- (tetramethylene ether) glycol, pentaerythrite, dipentaerythritol, tripentaerythritol, three hydroxyls Methylpropane, neopentyl glycol, sugar (for example, sucrose) and their mixture；

In one aspect, glycerol ester copolymer have 4,000g/mol to 150,000g/mol, 5,000g/mol extremely 130,000g/mol, 6,000g/mol to 100,000g/mol, 7,000g/mol to 50,000g/mol, 8,000g/mol to 30, Weight average molecular weight within the scope of 000g/mol or 8,000g/mol to 20,000g/mol.

(aa) composition according to section (z), wherein short-chain olefin is ethylene

(bb) composition according to section (z), wherein short-chain olefin is propylene.

(cc) composition according to section (z), wherein short-chain olefin is 1- butylene.

(dd) composition according to section (z), wherein short-chain olefin is 2- butylene.

(ee) composition according to section (a) to (c), wherein the first glycerol ester copolymer is derived from natural polynary Alcohol ester and/or synthesis polyol ester, in one aspect, the natural polyols ester be selected from vegetable oil, animal tallow, algae oil with And their mixture；And the synthesis polyol ester, which is derived from, is selected from following material: ethylene glycol, glycerol, gathers at propylene glycol Glycerol, polyethylene glycol, polypropylene glycol, poly- (tetramethylene ether) glycol, pentaerythrite, dipentaerythritol, tripentaerythritol, three hydroxyls Methylpropane, neopentyl glycol, sugar (for example, sucrose) and their mixture.

(ff) composition according to any one of section (a) to (ee), the composition include to be based on total composition weight Meter about 0.1% to about 50%, about 0.5% to about 30% or about 1% to about 20% glycerol ester copolymer, the glyceride are total Polymers is selected from the first glycerol ester copolymer, the second glycerol ester copolymer, third glycerol ester copolymer and their mixing Object.

(gg) composition according to any one of section (a) to (ff), the composition include one in following item Or it is multinomial:

A) about 0.01% to about 50%, about 0.01% to about 30% or about 0.1% to about 20% fabric softener Active material；

B) about 0.001% to about 15%, about 0.05% to about 10% or about 0.05% to the about 5% anion table Face activating agent scavenger；

C) about 0.01% to about 10%, about 0.05% to about 5% or about 0.05% to about 3% delivery enhancer；

D) about 0.005% to about 30%, about 0.01% to about 20% or about 0.02% to about 10% fragrance；

E) about 0.005% to about 30%, about 0.01% to about 20% or about 0.02% to about 10% fragrance delivering System；

F) about 0.01% to about 20%, about 0.1% to about 10% or about 0.1% to about 5% soil dispersion polymerization Object；

G) about 0.001% to about 10%, about 0.005% to about 5% or about 0.01% to about 2% brightening agent；

H) about 0.0001% to about 10%, about 0.01% to about 2% or about 0.05% to about 1% dope dye；

I) about 0.0001% to about 10%, about 0.01% to about 2% or about 0.05% to about 1% dyestuff transfer Inhibitor；

J) about 0.01% to about 10%, about 0.01% to about 5% or about 0.05% to about 2% enzyme, a side Face, the enzyme are detergency enzymes；

K) about 0.01% to about 20%, about 0.1% to about 10% or about 0.1% to about 5% structural agent；

L) about 0.05% to about 20%, about 0.1% to about 15% or about 0.2% to about 7% fabric care benefit Agent；

If m) composition is powder laundry detergent, the composition includes about 0.1% to about 80% institute Builder is stated, and on the other hand, if the composition is liquid laundry detergent, the composition includes about 0.1% to about 20% builder；

N) carrier of about 0.1% to about 99%；And

O) their mixture.

(hh) composition according to any one of section (a) to (gg), in which:

A) fabric softener active includes cationic fabric softener, and in one aspect, the cation is soft Agent is selected from: the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid；Double-(2- hydroxypropyl)-dimethyl methyl The isomers of the ester of ammonium sulfate and fatty acid, preferably double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate aliphatic ester are more excellent Selection of land, the fatty acid are the C that can have tallow or plant origin₁₂-C₂₂Fatty acid can be saturated or unsaturated, and/ It or can be substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl ammonium chloride propane, N, the bis- (stearoyl ketos of N- Base ethyl)-N, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, the bis- (tristearin of N- Trimethylammonium)-N- (2- ethoxy)-N- methylammonium-methosulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- dimethyl Methylsulfuric acid ammonium, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, the bis- (palmityl -2- hydroxypropyls of N- Base)-N, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1,2- bis- are (stearic Acyloxy) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two tallow dimethyl ammonium chlorides, two mustard dimethyl Methylsulfuric acid ammonium, 1- methyl-1-stearoyl amido ethyl-2- stearyl methylsulfuric acid imidazoline, 1- tallow amidoethyl second Base -2- tallow acyl imidazoline, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and their mixture；

B) the anionic surfactant scavenger includes water-soluble cationic and/or amphoteric ion scavenger chemical combination Object；In one aspect, the anionic surfactant scavenger is selected from monoalkyl ammonium quat and its amine precursor, dialkyl group Quaternary ammonium compound and its amine precursor, poly quaternary ammonium compound and its amine precursor, polymeric amine and their mixture；

C) delivery enhancer include be selected from following material: charge density be about 0.05 milliequivalent/gram to about 23 milli Equivalent/the cationic polymer of gram polymer, charge density are about 0.05 milliequivalent/gram to about 23 milliequivalents/gram polymer Amphoteric polymer, charge density are about 0.05 milliequivalent/gram to about 23 milliequivalents/gram protein protein and theirs is mixed Close object；

D) perfume delivery systems be selected from polymer assisted delivery (PAD) system, molecule-assisted delivery (MAD) system, Cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic carrier (ZIC) system and their mixing Object；

E) the soil dispersion polymer is selected from the homopolymerization composition copolymer or three of ethylenically unsaturated monomers anionic monomer Membered copolymer, in one aspect, the anionic monomer are selected from acrylic acid, methacrylic acid, methyl methacrylate, clothing health Acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, Vinyl sulfonic acid, styrene sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt, their derivative and combination, alkane Oxygroup polyamine, in one aspect, alkoxylate polyethylene imine and their mixture；

F) brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, biphenyl, and five yuan Heterocycle, such as triazole, pyrazoline, oxazole, imidazoles, hexa-member heterocycle, such as cumarin, naphthalene amino acid, s-triazine and theirs is mixed Close object；

G) dope dye includes to be selected from following part: acridine, anthraquinone, such as polycyclic quinone, azine, azo, such as Monoazo, bisazo, trisazo-, four azos, polyazo, pre-metallization azo, two furans of benzo and benzodifuranone, class is recklessly Radish element, cumarin, Hua Jing, half flower cyanines of diaza, diphenyl-methane, formazan, half flower cyanines, indigoid, methane, naphthalimide, naphthoquinones, Nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, styryl, triarylmethane, triphenylmenthane, xanthene and it Mixture；

H) dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide pllymers, N- The copolymer of the copolymer of vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol or Their mixture；

I) bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Light drift White dose；Bleaching enzymes；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source and their mixture；

J) detergency enzymes be selected from hemicellulase, peroxidase, protease, cellulase, zytase, lipase, Phosphatidase, esterase, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, lignoenzyme, Pullulanase, tannase, pentosanase, Mai Laning enzyme (malanases), 1,4 beta-glucanase, arabinosidase, hyaluronic acid Enzyme, chondroitinase, laccase, amylase and their mixture；

K) structural agent be selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, guar gum, pectin, Xanthan gum, modified cellulose, microcrystalline cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic salts, at one Aspect, the inorganic salts are selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and their mixing Object, clay, homopolymer and copolymer comprising cationic monomer, the cationic monomer are selected from methacrylic acid N, N- dialkyl group Aminoalkyl ester, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- Dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- bis- Alkylaminoalkyl, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized acrylic acid N, N- dioxane Base aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl methyl-prop Acrylamide and their mixture, it is in one aspect, described when the composition is liquid laundry detergent composition Structural agent includes rilanit special；In one aspect, when the composition is rinse added fabric reinforcing agent, the structural agent Including quaternized acrylic acid N, the straight chain and/or cross-linked homopolymer and copolymer of N- dialkyl aminoalkyl ester；

L) fabric care benefit agents be selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, polyisobutene, Polyolefin and their mixture；

M) builder is selected from phosphate, water-soluble non-phosphorus organic washing-assisting detergent, alkali metal, ammonium and the poly- second of substituted ammonium Hydrochlorate, carboxylate, polycarboxylate, polyhydroxy sulfonate, in one aspect, the builder are selected from ethylenediamine tetra-acetic acid, secondary nitrogen Base triacetic acid, oxygen union II succinic acid, mellitic acid, benzene polycarboxylic acid, the sodium salt of citric acid, sylvite, lithium salts, ammonium salt and substitution ammonium Salt；Oxygen union II succinate, ether carboxylate, tartrate monosuccinic acid salt, tartaric acid disuccinate, silicate, aluminosilicate, Borate, carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, zeolite and their mixture；

N) surfactant be selected from anionic surfactant, nonionic surfactant, amphoteric surfactant, Cationic surfactant, zwitterionic surfactant and their mixture；

O) carrier is selected from water, 1,2-PD, hexylene glycol, ethyl alcohol, isopropanol, glycerol, C₁-C₄Alkanolamine, salt, Sugar, polyalkylene oxide, such as polyethylene oxide；Polyethylene glycol；Polypropylene oxide and their mixture.

(II) composition according to any one of section (a) to (hh), in which:

A) fabric softener active is selected from: double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid Ester；The isomers of the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid, preferably double-(2- hydroxypropyl)-two Methylammonium-methosulfate aliphatic ester, it is highly preferred that the fatty acid is the C that can have tallow or plant origin₁₂-C₂₂Fat Acid can be saturated or unsaturated, and/or can be substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl Ammonium chloride propane, N, bis- (stearoyl-oxy the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, bis- (stearoyl-oxy ethyl)-N- (2- the ethoxy)-N- methylammonium-methosulfates, N of N-, N- are bis- (hard Acyl -2- hydroxypropyl)-N, N- dimethyl ammonium methyl sulfate, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl methyl sulphur Sour ammonium, N, bis- (palmityl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1,2- bis- (stearoyl-oxy) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two (hard) tallow dimethyl ammonium chloride, two mustard dimethyl ammonium methyl sulfates, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and it Mixture；

B) the anionic surfactant scavenger is selected from the amine of monoalkyl ammonium quat, monoalkyl ammonium quat Precursor, the amine precursor of dialkyl quaternary compound and dialkyl quaternary compound, poly quaternary ammonium compound, poly quaternary ammonium compound Amine precursor and their mixture, in one aspect, the anionic surfactant scavenger is selected from: N-C₆To C₁₈Alkane Base-N, N, N- leptodactyline, N-C₆To C₁₈Alkyl-N- hydroxyethyl-N, N- dimethyl ammonium, N-C₆To C₁₈Alkyl-N, N- Dihydroxy ethyl-N- methyl ammonium salt, N-C₆To C₁₈Alkyl-N- benzyl-N, N- dimethyl ammonium, N, bis--C of N-₆To two-C₁₂Alkane Base-N, N- dimethyl ammonium, N, bis--C of N-₆To two-C₁₂Alkyl N- hydroxyethyl N- methyl ammonium salt, N-C₆To C₁₈Alkyl N- alkyl Hexyl-N, N- dimethyl ammonium；

C) delivery enhancer be selected from cationic polysaccharide, polyethyleneimine and its derivative, Polyamide amine and by Homopolymer, bipolymer and terpolymer made of one or more cationic monomers and optional second comonomer, it is described Cationic monomer is selected from methacrylic acid N, N- dialkyl aminoalkyl ester, methacrylic acid N, N- dialkyl aminoalkyl methyl Ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl first Base acrylamide, quaternized methacrylic acid N, N- dialkyl aminoalkyl ester, quaternized methacrylic acid N, N- dialkyl amino Base alkyl methacrylate ester, quaternized acrylic acid N, N- dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkyl aminoalkyl acryloyl Amine, quaternary ammonium N, N- dialkyl aminoalkyl Methacrylamide, vinylamine and its derivative, allylamine and its derivative, second Alkenyl imidazoles, quatemized vinylimidazol and poly (dially dialkyl) ammonium chloride and their combination, the second comonomer choosing From: acrylamide, N, N- dialkylacrylamides, Methacrylamide, N, N- dialkyl methacrylamides, acrylic acid C₁- C₁₂Arrcostab, acrylic acid C₁-C₁₂Hydroxy alkyl ester, polyacrylic acid alkylidene diol ester, methacrylic acid C₁-C₁₂Arrcostab, methyl Acrylic acid C₁-C₁₂Hydroxy alkyl ester, polymethylacrylic acid alkylidene diol ester, vinyl acetate, vinyl alcohol, vinyl formamide, Vinyl acetamide, vinyl alkyl ethers, vinylpyridine, vinyl pyrrolidone, vinyl imidazole and derivative, propylene Acid, methacrylic acid, methyl methacrylate, itaconic acid, fumaric acid, 3- allyl oxygroup -2- hydroxyl -1- propane sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamido propyl methylsulphur Sour (AMPS) and its salt and their combination；In one aspect, when the composition is rinse added fabric reinforcing agent, The polymer includes the quaternized acrylic acid N of straight chain and/or crosslinking, N- dialkyl aminoalkyl ester, when the composition is When liquid laundry detergent, the delivery enhancer includes cationic polysaccharide, Polyquaternium-10, polyquaternium -7, polyquaternary amine Salt -6 is selected from diallyldimethylammonium chloride, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternized N, N- bis- The homopolymer or copolymer of alkylaminoalkyl group Methacrylamide, vinylamine and their mixture；

D) the soil dispersion polymer is selected from alkoxylate polyethylene imine, acrylic acid, methacrylic acid, methyl-prop E pioic acid methyl ester, itaconic acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and Its salt, maleic acid, vinyl sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt homopolymer or copolymer, they Derivative and their mixture；

E) brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, biphenyl, five yuan Heterocycle, such as triazole and their mixture；

F) dope dye is selected from direct purple dye, for example, directly purple dye 9,35,48,51,66 and 99；It is directly blue Dyestuff, for example, directly indigo plant dyestuff 1,71,80 and 279；Acid red dye, for example, acid red dye 17,73,52,88 and 150； Acid purple dye, for example, acid purple dye 15,17,24,43,49 and 50；Acid blue dye, for example, acid blue dye 15,17, 25,29,40,45,75,80,83,90 and 113；Acid black dye, for example, acid black dye 1；Basic purple dye, for example, alkaline Purple dye 1,3,4,10 and 35；Basic dye, for example, basic dye 3,16,22,47,66,75 and 159；Disperse dyes or Solvent dye and their mixture, in one aspect, the dope dye is selected from: acid violet 17, acid blue 80, acid violet 50, directly indigo plant 71, directly purple 51, directly indigo plant 1, acid red 88, azogeramine 50, acid blue 29, Acid blue 113 and they Mixture；

G) bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Light drift White dose, peroxygen source, hydrogen peroxide, perborate and percarbonate or their mixture；

H) enzyme is selected from hemicellulase, peroxidase, protease, cellulase, zytase, lipase, phosphatide Enzyme, esterase, cutinase, pectase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, laccase, amylase and their mixing Object, in one aspect, the enzyme are detergency enzymes；

I) surfactant is selected from alkyl sulfate, alkyl ethoxy sulfate, linear alkylbenzene sulfonate (LAS), α-alkene Sulfonated hydrocarbon, ethoxylated alcohol, ethoxylated alkylphenol, fatty acid, soap and their mixture.

J) fabric care benefit agents are selected from dimethyl silicone polymer, polyether silicon, cationic silicone, amino silicone Oxygen alkane and their mixture.

(jj) composition according to any one of section (a) to (II), the composition includes:

A) fabric softener active is selected from cationic fabric softener, in one aspect, the cation softening Agent is selected from: the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid；Double-(2- hydroxypropyl)-dimethyl methyl sulphur The isomers of the ester of sour ammonium and fatty acid, preferably double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate aliphatic ester, more preferably Ground, the fatty acid are the C that can have tallow or plant origin₁₂-C₂₂Fatty acid can be saturated or unsaturated, and/or It can be substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl ammonium chloride propane, N, the bis- (stearoyl-oxies of N- Ethyl)-N, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, the bis- (stearoyls of N- Oxygroup ethyl)-N- (2- ethoxy)-N- methylammonium-methosulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- dimethyl methyl Base ammonium sulfate, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, the bis- (palmityl -2- hydroxypropyls of N- Base)-N, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1,2- bis- are (stearic Acyloxy) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two (hard) tallow dimethyl ammonium chlorides, two mustard two Methylammonium-methosulfate, 1- methyl-1-stearoyl amido ethyl-2- stearyl methylsulfuric acid imidazoline, 1- tallow amide Base ethyl -2- tallow acyl imidazoline, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and their mixture；

B) carrier,

C) optionally, anionic surfactant scavenger is selected from water-soluble cationic and/or amphoteric ion scavenger Compound；In one aspect, the anionic surfactant scavenger is selected from monoalkyl ammonium quat and its amine precursor, two Alkyl quaternary ammonium compound and its amine precursor, poly quaternary ammonium compound and its amine precursor, polymeric amine and their mixture；

D) optionally, delivery enhancer is selected from: charge density is about 0.05 milliequivalent/gram to about 23 milliequivalents/gram poly- Close the cationic polymer of object, charge density is about 0.05 milliequivalent/gram polymerize to the both sexes of about 23 milliequivalents/gram polymer Object, charge density are about 0.05 milliequivalent/gram to about 23 milliequivalents/gram protein protein and their mixture；

E) optionally, dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide polymerization Object, the copolymer of n-vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol are total to Polymers or their mixture；

F) optionally, structural agent is selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, Guar It is glue, pectin, xanthan gum, modified cellulose, microcrystalline cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic Salt (in one aspect, the inorganic salts be selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and it Mixture), clay, (cationic monomer is selected from methacrylic acid for the homopolymer comprising cationic monomer and copolymer N, N- dialkyl aminoalkyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- dialkyl aminoalkyl ester, quaternized propylene Sour N, N- dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl amido Alkyl methacrylamides) and their mixture, in one aspect, when the composition is liquid laundry detergent group When closing object, the structural agent includes rilanit special；In one aspect, when the composition is rinse added fabric reinforcing agent When, the structural agent includes quaternized acrylic acid N, the straight chain and/or cross-linked homopolymer of N- dialkyl aminoalkyl ester and copolymerization Object；And

G) optionally, fabric care benefit agents selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, gather Isobutene, polyolefin and their mixture；And

H) optionally fragrance；And

I) optionally, perfume delivery systems, in one aspect, the perfume delivery systems are selected from polymer assisted delivery (PAD) system, molecule-assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and Inorganic carrier (ZIC) system；In one aspect, the PMC of two or more types；

The composition has the pH of about 2 to about 7, or the pH of about 2 to about 5.

(kk) composition according to any one of section (a) to (II), the composition includes:

A) surfactant, selected from anionic surfactant, nonionic surfactant, amphoteric surfactant, Cationic surfactant, zwitterionic surfactant and their mixture；

B) carrier；

C) optionally, builder, selected from phosphate, water-soluble non-phosphorus organic washing-assisting detergent, alkali metal, ammonium and substituted The poly- acetate of ammonium, carboxylate, polycarboxylate, polyhydroxy sulfonate, in one aspect, the builder are selected from ethylenediamine tetrem Acid, nitrilotriacetic acid, oxygen union II succinic acid, mellitic acid, benzene polycarboxylic acid, the sodium salt of citric acid, sylvite, lithium salts, ammonium salt and Substituted ammonium salt；Oxygen union II succinate, ether carboxylate, tartrate monosuccinic acid salt, tartaric acid disuccinate, silicate, aluminium Silicate, borate, carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, zeolite and their mixing Object；

D) optionally, soil dispersion polymer, the homopolymer selected from ethylenically unsaturated monomers anionic monomer are copolymerized Object or terpolymer, in one aspect, the anionic monomer be selected from acrylic acid, methacrylic acid, itaconic acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, vinyl sulfonic acid, Styrene sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt, their derivative and their mixture, alcoxyl Base polyamine (being in one aspect alkoxylate polyethylene imine) and their mixture；

E) optionally, delivery enhancer, it includes be selected from following material: charge density is about 0.05 milliequivalent/gram extremely The about 23 milliequivalents/cationic polymer of gram polymer, charge density are about 0.05 milliequivalent/gram to about 23 milliequivalents/gram poly- Close the amphoteric polymer of object, charge density be about 0.05 milliequivalent/gram to about 23 milliequivalents/gram protein protein and it Mixture；

F) optionally, brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, connection Benzene, five-ring heterocycles, such as triazole, pyrazoline, oxazole, imidazoles, hexa-member heterocycle, such as cumarin, naphthalene amino acid, s-triazine, and Their mixture；

G) optionally, dope dye, it includes be selected from following part: acridine, anthraquinone (including polycyclic quinone), azine, Azo (such as monoazo, bisazo, trisazo-, four azos, polyazo, including pre-metallization azo), two furans of benzo and benzene And half flower cyanines of two furanones, carotenoid, cumarin, Hua Jing, diaza, diphenyl-methane, formazan, half flower cyanines, indigoid, first Alkane, naphthalimide, naphthoquinones, nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, styryl, triarylmethane, three Phenylmethane, xanthene and their mixture；

H) optionally, dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide polymerization Object, the copolymer of n-vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol are total to Polymers or their mixture；

I) optionally, bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach synergy Agent；Optical white；Bleaching enzymes；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source and their mixture；

J) optionally, detergency enzymes, selected from hemicellulase, peroxidase, protease, cellulase, zytase, It is lipase, phosphatidase, esterase, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, wooden It is plain enzyme, Pullulanase, tannase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, arabinosidase, hyaluronidase, soft Ossein enzyme, laccase, amylase and their mixture；

K) structural agent, selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, guar gum, pectin, Xanthan gum, modified cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic salts (in one aspect, the nothing Machine salt be selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and their mixture), clay, packet (cationic monomer is selected from methacrylic acid N, N- dialkyl aminoalkyl to the homopolymer and copolymer of cation monomer Ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl first Base acrylamide, quaternized methacrylic acid N, N- dialkyl aminoalkyl ester, quaternized acrylic acid N, N- dialkyl amido alkane Base ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl Methacrylamide), And their mixture, in one aspect, when the composition is liquid laundry detergent composition, the structural agent packet Include rilanit special；In one aspect, when the composition is rinse added fabric reinforcing agent, the structural agent includes quaternary ammonium Change acrylic acid N, the straight chain and/or cross-linked homopolymer and copolymer of N- dialkyl aminoalkyl ester；

L) optionally, fabric care benefit agents selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, gather Isobutene, polyolefin and their mixture；And

M) optionally fragrance；

N) optionally, perfume delivery systems, in one aspect, the perfume delivery systems are selected from polymer assisted delivery (PAD) system, molecule-assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and Inorganic carrier (ZIC) system；In one aspect, the PMC of two or more types；

The composition has the pH of about 4 to about 12, or the pH of about 5 to about 9.

(ll) composition according to any one of section (a) to (II), the composition includes:

A) carrier of about 49 to about 99%, the carrier are selected from polyethylene glycol, salt, polysaccharide and sugar；In one aspect, molecule Amount is polyethylene glycol of the about 2000Da to about 20,000Da, and molecular weight is polyethylene glycol of about 3, the 000Da to about 12,000Da, or Person's molecular weight is polyethylene glycol of the about 6,000Da to about 10,000Da；

B) optionally, fabric care benefit agents, in one aspect, siloxanes；

C) optionally fragrance；

D) optionally perfume delivery systems；

E) optionally delivery enhancer.

(mm) composition according to any one of section (a) to (II), the composition includes:

A) fabric softener, fragrance and delivery enhancer；Or

B) fabric softener, fragrance and perfume delivery systems；Or

C) dope dye and surfactant；Or

D) it is less than 10% total water, total water is free water and the summation for combining water；Or

E) fabric softener, fabric care benefit agents and delivery enhancer；Or

G) fabric care benefit agents, anionic surfactant scavenger and delivery enhancer；

Or

H) perfume delivery systems, in one aspect, the perfume delivery systems are selected from polymer assisted delivery (PAD) body System, molecule-assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and without airborne Body (ZIC) system；In one aspect, the PMC of two or more types.

(nn) composition according to any one of section (a) to (jj), the composition include lotion, gel network or Lamellar phase, in one aspect, the composition include vesica.

(oo) composition according to any one of section (a) to (II), the composition are crystal, bead or pastille Form, in one aspect, the composition include to be based on general composition weight meter about 0.1% to about 50%, and about 0.5% to about 30%, the glycerol ester copolymer of about 5% to about 30%, the glycerol ester copolymer is selected from the first glycerol ester copolymer, the Two glycerol ester copolymers, third glycerol ester copolymer and their mixture, in one aspect, the bead have shape, The shape is circle, diamond shape, dome shape or the semicircle with planar base portion.

(pp) a kind of product, the product include composition and water solubility according to any one of section (a) to (oo) Film, in one aspect, the film include polyvinyl alcohol, and in one aspect, the film surrounds the composition, in one aspect, The product includes two or more chambers surrounded by the film, and wherein at least one of described chamber includes institute State composition.

(qq) a kind of product, the product include the composition according to any one of section (a) to (II), the product For the form of dryer paper.

(rr) a kind of fabric, extremely with the composition according to any one of section (a) to (oo) and/or according to section (pp) Any one of (qq) the product processing described in.

(ss) a kind of method of processing and/or clean textile, which comprises

A) optionally wash and/or rinse the fabric；

B) make the fabric and the composition according to any one of section (a) to (oo), (uu) and (vv) and/or according to Product into contact described in any one of section (pp) to (qq)；

C) optionally wash and/or rinse the fabric；And

D) optionally it is passively or actively the dry fabric.

(tt) composition according to any one of section (a) to (oo), wherein the first glycerol ester copolymer and institute State the second glycerol ester copolymer with the poidometer based on glycerol ester copolymer about 0% to about 5%, about 0.1% to about 5%, about 0.1% to about 4%, about 0.1 to about 3% or about 0.1% to about 1% free hydrocarbon content.

(uu) composition according to any one of section (a) to (oo), wherein the third glycerol ester copolymer has Poidometer based on glycerol ester copolymer about 0% to about 5%, about 0.1% to about 5%, about 0.1% to about 4%, about 0.1 is to about 3% or about 0.1% to about 1% free hydrocarbon content.

(vv) composition according to any one of section (a) to (c) and (w), wherein total for the third glyceride Polymers, R²¹、R²²And R²³It is each independently selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 8, 12 carbon diene of 11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- ten Five carbon trialkenyls, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- methyl - 8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, 12- methyl -8,11- 14 Carbon dialkylene, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, methyl -8,11 15-, 17 carbon trialkenyl of 14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene base, 12- ten Five carbene bases, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl- 12- pentadecane alkenyl；In one aspect, R²¹、R²²And R²³It is each independently selected from: 8- nonenyl, 8- decene base, 11 carbon of 8- Alkenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane triolefin Base, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

Section (a2) to (vv2)

The invention discloses following composition, application method and through treatment articles:

(a2) a kind of composition, the composition includes:

A) it is selected from following material:

(i) the first glycerol ester copolymer, it is excellent it includes the total weight 3% to 30% based on the first glycerol ester copolymer Selection of land 3% to 25%, more preferably 5% to 20%% C_10-14Unsaturated fatty acid ester；Preferably, first glyceride is total Polymers include the total weight 3% to 30% based on the first glycerol ester copolymer, preferably 3% to 25%, more preferably 3% to 20%% C_10-13Unsaturated fatty acid ester；It is highly preferred that the first glycerol ester copolymer includes total based on the first glyceride The total weight 0.1% to 30% of polymers, preferably 0.1% to 25%, more preferably 0.2% to 20%, most preferably 0.5% To 15% C_10-11Unsaturated fatty acid ester；

(ii) with the second glycerol ester copolymer of formula (I):

Wherein:

Each R in second glycerol ester copolymer¹、R²、R³、R⁴And R⁵Independently selected from oligomeric glyceride fraction, C_1-24Alkane Base, the wherein substituent group are the substituted C of the part one or more-OH_1-24Alkyl, C_2-24Alkenyl or in which the substitution Base is the substituted C of the part one or more-OH_2-24Alkenyl；And/or it is wherein each in the following combination of each section It is a to be covalently attached each independently:

R¹And R³,

R²And R⁵,

R¹With adjacent R⁴,

R²With adjacent R⁴,

R³With adjacent R⁴,

R⁵With adjacent R⁴, or

Any two adjacent R⁴

So that the part of the covalent linkage forms alkenylene moieties；

Each X in the second glycerol ester copolymer¹And X²Independently selected from C_1-32Alkylidene, the wherein substituent group For the substituted C of the part one or more-OH_1-32Alkylidene, C_2-32Alkenylene or in which the substituent group are one or more The substituted C of a part-OH_2-32Alkenylene；

G¹、G²And G³In two be-CH₂, and G¹、G²And G³In one be direct key；

For the independent repetitive unit of each of repetitive unit with index n, G⁴、G⁵And G⁶In two be-CH₂, And G⁴、G⁵And G⁶One be direct key, and the G of each individually repetitive unit⁴、G⁵And G⁶Value it is heavy independently selected from other G in multiple unit⁴、G⁵And G⁶Value；

G⁷、G⁸And G⁹In two be-CH₂, and G⁷、G⁸And G⁹In one be direct key；

The integer that n is 3 to 250；

Precondition is for each in the second glycerol ester copolymer, R¹、R²、R³And R⁵At least one of, And/or at least one R in an independent repetitive unit of the repetitive unit with index n⁴It is selected from: 8- nonenyl；8- Decene base；8- undecenyl；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；8,11- oleatridecadiene base；8,11- ten Four carbon dialkylenes；8,11- pentadecane dialkylene；8,11,14- pentadecane trialkenyl；16 carbon trialkenyl of 8,11,14-；8,11, 18 carbon trialkenyl of 14-；9- methyl -8- decene base；9- methyl -8- undecenyl；10- methyl -8- undecenyl；12- Methyl -8,11- oleatridecadiene base；14 carbon dialkylene of 12- methyl -8,11-；14 carbon dialkylene of 13- methyl -8,11-； 16 carbon trialkenyl of 15- methyl -8,11,14-；17 carbon trialkenyl of 15- methyl -8,11,14-；16- methyl -8,11,14- ten Seven carbon trialkenyls；12- tridecylene base；12- tetradecene base；12- pentadecane alkenyl；12- hexadecene base；13- methyl- 12- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- methyl-1 2- pentadecane alkenyl；Preferably, described second is sweet Grease copolymer include the total weight 3% to 30% based on the second glycerol ester copolymer, preferably 3% to 25%, more preferably The C on ground 5% to 20%_9-13Alkenyl part；Preferably, the second glycerol ester copolymer includes to be based on the second glycerol ester copolymer Total weight 3% to 30%, preferably 3% to 25%, more preferably 3% to 20% C_9-12Alkenyl part；It is highly preferred that The second glycerol ester copolymer include the total weight 0.1% to 30% based on the second glycerol ester copolymer, preferably 0.1% To 25%, more preferably 0.2% to 20%, most preferably 0.5% to 15% C_9-10Alkenyl part；And

(iii) optionally, third glycerol ester copolymer, the third glycerol ester copolymer are deposited included in metathesis catalyst Under, the structural unit formed is reacted by one or more compounds, the compound is in the compound with following formula Each:

Formula (IIa):

Formula (IIb):

Wherein,

Each R¹¹、R¹²And R¹³It independently is C_1-24Alkyl, wherein substituent group are being substituted for the part one or more-OH C_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, precondition It is R¹¹、R¹²And R¹³At least one of be C_2-24Alkenyl or in which substituent group are the substituted of the part one or more-OH C_2-24Alkenyl；And

Each R²¹、R²²And R²³It independently is C_1-24Alkyl, wherein substituent group are being substituted for the part one or more-OH C_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, precondition It is R²¹、R²²And R²³At least one of be 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic；8,11- ten Two carbon dialkylenes；8,11- oleatridecadiene base；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- 15 Carbon trialkenyl；16 carbon trialkenyl of 8,11,14-；18 carbon trialkenyl of 8,11,14-；9- methyl -8- decene base；9- methyl -8- Undecenyl；10- methyl -8- undecenyl；12- methyl -8,11- oleatridecadiene base；14 carbon of 12- methyl -8,11- Dialkylene；14 carbon dialkylene of 13- methyl -8,11-；16 carbon trialkenyl of 15- methyl -8,11,14-；Methyl -8,11 15-, 17 carbon trialkenyl of 14-；17 carbon trialkenyl of 16- methyl -8,11,14-；12- tridecylene base；12- tetradecene base；12- Pentadecane alkenyl；12- hexadecene base；13- methyl-1 2- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- first Base -12- pentadecane alkenyl；

The structural unit wherein formed by the monomeric compound that formula (IIa) is indicated and the monomer chemical combination indicated by formula (IIb) The quantity ratio for the structural unit that object is formed is no more than 10:1；And

(iv) their mixture；And

B) be selected from following material: fabric softener active, fabric care benefit agents, anionic surfactant are clear Except agent, delivery enhancer, fragrance, perfume delivery systems, structural agent, soil dispersion polymer, brightening agent, dope dye, dyestuff Transfer inhibitor, builder, surfactant, enzyme, preferably detergency enzymes and their mixture, and optionally carrier, Preferably, the composition has 2 to 12 pH,

The composition is Fabrid care composition.

(b2) composition according to section (a2), wherein the first, second, and third glycerol ester copolymer has 4, 000g/mol to 150,000g/mol, preferably 5,000g/mol to 130,000g/mol, more preferably 6,000g/mol extremely 100,000g/mol, more preferably 7,000g/mol to 50,000g/mol, more preferably 8,000g/mol to 30,000g/mol, The most preferably weight average molecular weight of 8,000g/mol to 20,000g/mol.

(c2) composition according to section (a2) to (b2), wherein the first, second, and third glycerol ester copolymer It is prepared by the method including double decomposition；Preferably, the method includes making two kinds in the presence of metathesis catalyst Or more monomer reaction, as a part of reaction mixture, wherein by formula (IIa) indicate monomeric compound with by formula (IIb) weight with weight ratio of the monomeric compound indicated are no more than 10:1, are preferably no more than 9:1, are so more preferable that be no more than 8:1, no more than 7:1, no more than 6:1, no more than 5:1, no more than 4:1, No more than 3:1, no more than 2:1, most preferably it is no more than 1:1；Preferably, the metathesis catalyst For organic ruthenium compound, organic osmium compound, organotungsten compounds or organic molybdenum.

(d2) composition according to section (a2) to (c2), wherein for the second glycerol ester copolymer, R¹、R²、 R³、R⁴Or R⁵At least one of be C_9-13Alkenyl, preferably C_9-12Alkenyl, more preferably C_9-10Alkenyl.

(e2) composition according to section (a2) to (d2), wherein for the third glycerol ester copolymer, R¹¹、R¹²、 R¹³、R²¹、R²²Or R²³At least one of be C_9-13Alkenyl, preferably C_9-12Alkenyl, more preferably C_9-10Alkenyl.

(f2) composition according to section (a2) to (e2), wherein the G of the second glycerol ester copolymer¹And G²Part For-CH₂And G³For direct key.

(g2) composition according to any one of section (a2) to (e2), wherein the G of the second glycerol ester copolymer¹ And G³Part is-CH₂And G²For direct key.

(h2) composition according to any one of section (a2) to (e2), wherein the G of the second glycerol ester copolymer² And G³Part is-CH₂And G¹For direct key.

(i2) composition according to section (a2) to (h2), wherein for the second glycerol ester copolymer, G⁴And G⁵In extremely Few one is-CH₂And G⁶For direct key.

(j2) composition according to any one of section (a2) to (h2), wherein for the second glycerol ester copolymer, G⁴ And G⁶At least one of be-CH₂And G⁵For direct key.

(k2) composition according to any one of section (a2) to (h2), wherein for the second glycerol ester copolymer, G⁵ And G⁶At least one of be-CH₂And G⁴For direct key.

(l2) composition according to any one of section (a2) to (k2), wherein for the second glycerol ester copolymer, G⁷ And G⁸At least one of be-CH₂And G⁹For direct key.

(m2) composition according to section (a2) to (k2), wherein for the second glycerol ester copolymer, G⁷And G⁹In extremely Few one is-CH₂And G⁸For direct key.

(n2) composition according to section (a2) to (k2), wherein for the second glycerol ester copolymer, G⁸And G⁹In extremely Few one is-CH₂And G⁷For direct key.

(o2) composition according to any one of section (a2) to (n2), wherein being copolymerized for second glyceride Object, each X¹Independently selected from-(CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、- (CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₁₁- CH=CH- (CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、- (CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-。

(p2) composition according to any one of section (a2) to (m2), wherein being copolymerized for second glyceride Object, each X²Independently selected from-(CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、- (CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₁₁- CH=CH- (CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁-CH =CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、- (CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-。

(q2) composition according to any one of section (a2) to (p2), wherein being copolymerized for second glyceride Object, R¹For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R¹It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- 12 Carbene base, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane diene Base, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, the 9- methyl -8- last of the ten Heavenly stems Alkenyl, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, 12- first 14 carbon dialkylene of base -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 15- methyl -8,11,16 carbon trialkenyl of 14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- ten Four carbene bases, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R¹Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8, 16 carbon trialkenyl of 11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(r2) composition according to any one of section (a2) to (q2), wherein being copolymerized for second glyceride Object, R²For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R²It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- 12 Carbene base, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane diene Base, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyls, 8,11,14- ten eight carbon trialkenyls, the 9- methyl -8- last of the ten Heavenly stems Alkenyl, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, 12- first 14 carbon dialkylene of base -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- ten Four carbene bases, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R²Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8, 16 carbon trialkenyl of 11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(s2) composition according to any one of section (a2) to (r2), wherein being copolymerized for second glyceride Object, R³For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R³It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- 12 Carbene base, 8,11-, 12 carbon dialkylene, 8,11- oleatridecadiene base, 8,11-, 14 carbon dialkylene, 8,11- pentadecane diene Base, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyls, 8,11,14- ten eight carbon trialkenyls, the 9- methyl -8- last of the ten Heavenly stems Alkenyl, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, 12- first 14 carbon dialkylene of base -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- ten Four carbene bases, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R³Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8, 16 carbon trialkenyl of 11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(t2) composition according to any one of section (a2) to (s2), wherein being copolymerized for second glyceride Object, each R⁴Independently selected from C_1-24Alkyl and C_2-24Alkenyl；Preferably, each R⁴Independently selected from: 8- nonenyl, 8- decene Base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 diene of 8,11- Base, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon of 8,11,14- Trialkenyl, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- Oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, methyl -8 15-, 16 carbon trialkenyl of 11,14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that each R⁴Independently selected from: 8- nonyl Alkenyl, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon two of 8,11- Alkenyl, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(u2) composition according to any one of section (a2) to (t2), wherein being copolymerized for second glyceride Object, R⁵For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R⁵It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- 12 Carbene base, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane diene Base, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, the 9- methyl -8- last of the ten Heavenly stems Alkenyl, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, 12- first 14 carbon dialkylene of base -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- ten Four carbene bases, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R⁵Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8, 16 carbon trialkenyl of 11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

(v2) composition according to any one of section (a2) to (u2), wherein for the second glycerol ester copolymer, n is 3 to 250, preferably 5 to 180, more preferably 6 to 140, more preferably 8 to 70, more preferably 9 to 40, most preferably 9 to 26 Integer.

(w2) composition according to section (a2) to (c2), wherein for the third glycerol ester copolymer, R¹¹、R¹² And R¹³It is each independently selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 17 carbon dialkylene of 8,11- and 8,11,14- ten Seven carbon trialkenyls.

(x2) composition according to section (a2) to (c2) and (w2), wherein for the third glycerol ester copolymer, R²¹、R²²And R²³In two independently selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 17 carbon dialkylene of 8,11- and 17 carbon trialkenyl of 8,11,14-；And wherein, R²¹、R²²And R²³In one be selected from: 8- nonenyl, 8- decene base, 8- 11 Carbene base, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- ten Five carbon dialkylenes, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- Methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 13 carbon two of 12- methyl -8,11- Alkenyl, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 15- methyl -8,11,14- 16 Carbon trialkenyl, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene Base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl- 12- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R²¹、R²²And R²³In one be selected from: 8- nonene Base, 8- decene base, 8- undecenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyl, 12- tridecylene base, 12- tetradecene base and 12- ten Five carbene bases.

(y2) composition according to section (a2) to (c2) and (w2), wherein for the third glycerol ester copolymer, R²¹、R²²And R²³In one be selected from 15 alkenyls, 17 alkenyls, 17 alkenyl of 8-, 8,11-, 17 carbon dialkylene and 8,11, 17 carbon trialkenyl of 14-；And wherein, R²¹、R²²And R²³In two independently selected from 8- nonenyl, 8- decene base, 8- ten One carbene base, 8- dodecenyl succinic, 8,11-, 12 carbon diene, 8,11- oleatridecadiene base, 8,11-, 14 dialkylene, 8,11- Pentadecane dialkylene, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyls, 8,11,14- ten eight carbon trialkenyls, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 13 carbon of 12- methyl -8,11- Dialkylene, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 15- methyl -8,11,14- ten Six carbon trialkenyls, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- 13 Alkenyl, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl- 12- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R²¹、R²²And R²³In two independently selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon of 8,11- Dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base, With 12- pentadecane alkenyl.

(z2) a kind of composition, it includes glycerol ester copolymers, preferably include C_10-14The glycerol of unsaturated fatty acid ester Ester copolymer, it includes the structural units for having following substance reaction to be formed:

A) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride and unsaturated alkenyl natural oil are sweet Grease；

B) in the presence of metathesis catalyst, at least unsaturated synthesis polyol ester and unsaturated alkenyl natural oil are sweet Grease；

C) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride is combined to polynary with unsaturated alkenyl Alcohol ester；

D) in the presence of metathesis catalyst, at least unsaturated synthesis polyol ester and unsaturated alkenyl are combined to polynary Alcohol ester；

D) in the presence of metathesis catalyst, at least unsaturated alkenyl is combined to polyol ester and unsaturated alkenyl chemical combination At polyol ester；

F) in the presence of metathesis catalyst, at least unsaturated natural oil glyceride of alkenyl and unsaturated alkenyl day Right oil glyceride；

The composition is Fabrid care composition.

Preferably, the catalyst is selected from organic ruthenium compound, organic osmium compound, organotungsten compounds, organic-molybdenum Close object and their mixture；

Preferably, the natural oil glyceride of unsaturated alkenyl is unsaturated by there are metathesis catalyst Natural oil glyceride to be formed with reacting for short-chain olefin, it is preferable that the catalyst is selected from organic ruthenium compound, organic osmium chemical combination Object, organotungsten compounds, organic molybdenum and their mixture, preferably short-chain olefin are selected from ethylene, propylene, 1- fourth Alkene, 2- butylene, isobutene, 1- amylene, 2- amylene, 1- hexene, 2- hexene, 3- hexene and their mixture, it is preferably short Olefine is selected from ethylene, propylene, 1- butylene and 2- butylene and their mixture, preferably unsaturated alkenyl natural oil Glyceride has the natural lower molecular weight of oil glyceride more unsaturated than second；

Preferably, the unsaturated natural oil glyceride derives from natural oil；Preferably, derive from vegetable oil, animal tallow and/ Or algae oil；It is highly preferred that derive from Abyssinia's oil, almond oil, apricot oil, apricot kernel oil, argan oil, avocado oil, Babassu oil, monkey-bread tree oil, black ennel oil, currant oil, borage oil, shepherd's purse indigo plant seed oil, rapeseed oil, canola oil, castor-oil plant Oil, cherry-kernel oil, coconut oil, corn oil, cottonseed oil, blue dragonfly oil, evening primrose oil, linseed oil, grape seed oil, grapefruit seed Oil, hazelnut oil, hemp-seed oil, Jatropha oil, jojoba oil, Hawaii macadamia nut oil, linseed oil, macadimia nut oil, Bai Manghua Seed oil, oil ben, veepa oil, olive oil, palm oil, palm-kernel oil, persic oil, peanut oil, pecan oil, penny cress oil, purple Perilla oil, pistachio oil, granada seed oil, pongam oil, pumpkin seed oil, raspberry seed oil, red palm oil, rice bran oil, rose Fruit oil, safflower oil, hippophae rhamnoides fruit oil, sesame seed oil, shea butter, sunflower oil, soybean oil, smoke careless soya-bean oil, tung oil, walnut oil, Wheat-germ oil, high oleoyl soybean oil, high oleoyl sunflower oil, high oleoyl safflower oil, high erucic acid rape seed oil and they Mixture；

Preferably, the synthesis polyol ester be derived from be selected from following material: ethylene glycol, propylene glycol, glycerol, gather it is sweet Oil, polyethylene glycol, polypropylene glycol, poly- (tetramethylene ether) glycol, pentaerythrite, dipentaerythritol, tripentaerythritol, three hydroxyl first Base propane, neopentyl glycol, sugar, preferably sucrose and their mixture；

Preferably, the glycerol ester copolymer has in 4,000g/mol to 150,000g/mol, preferably 5,000g/ Mol to 130,000g/mol, more preferably 6,000g/mol to 100,000g/mol, more preferably 7,000g/mol to 50, 000g/mol, more preferably 8,000g/mol to 30,000g/mol, most preferably 8,000g/mol to 20,000g/mol range Interior weight average molecular weight.

(aa2) composition according to section (z2), wherein the short-chain olefin is ethylene

(bb2) composition according to section (z2), wherein the short-chain olefin is propylene.

(cc2) composition according to section (z2), wherein the short-chain olefin is 1- butylene.

(dd2) composition according to section (z2), wherein the short-chain olefin is 2- butylene.

(ee2) composition according to section (a2) to (c2), wherein the first glycerol ester copolymer is derived from natural Polyol ester and/or synthesis polyol ester, it is preferable that the natural polyols ester be selected from vegetable oil, animal tallow, algae oil with And their mixture；And the synthesis polyol ester, which is derived from, is selected from following material: ethylene glycol, glycerol, gathers at propylene glycol Glycerol, polyethylene glycol, polypropylene glycol, poly- (tetramethylene ether) glycol, pentaerythrite, dipentaerythritol, tripentaerythritol, three hydroxyls Methylpropane, neopentyl glycol, sugar, preferably sucrose and their mixture.

(ff2) composition according to any one of section (a) to (ee), the composition include to be based on total composition weight Meter 0.1% to 50%, preferably 0.5% to 30%, more preferably 1% to 20% glycerol ester copolymer, the glyceride are total Polymers is selected from the first glycerol ester copolymer, the second glycerol ester copolymer, third glycerol ester copolymer and their mixing Object.

(gg2) composition according to any one of section (a2) to (ff2), the composition include one in following item Item is multinomial:

A) 0.01% to 50%, preferably 0.01% to 30%, more preferably 0.1% to 20% fabric softener Active material；

B) 0.001% to 15%, preferably 0.05% to 10%, more preferably 0.05% to the 5% anion table Face activating agent scavenger；

C) 0.01% to 10%, preferably 0.05% to 5%, more preferably 0.05% to 3% delivery enhancer；

D) 0.005% to 30%, preferably 0.01% to 20%, more preferably 0.02% to 10% fragrance；

E) 0.005% to 30%, preferably 0.01% to 20%, more preferably 0.02% to 10% fragrance delivering System；

F) 0.01% to 20%, preferably 0.1 to 10%, more preferably 0.1% to 5% soil dispersion polymerization Object；

G) 0.001% to 10%, preferably 0.005 to 5%, more preferably 0.01% to 2% brightening agent；

H) 0.0001% to 10%, preferably 0.01% to 2%, more preferably 0.05% to 1% dope dye；

I) 0.0001% to 10%, preferably 0.01% to 2%, more preferably 0.05% to 1% dyestuff transfer Inhibitor；

J) 0.01% to 10%, preferably 0.01% to 5%, more preferably 0.05% to 2% enzyme, it is preferable that The enzyme is detergency enzymes；

K) 0.01% to 20%, 0.1% to 10% or 0.1% to 5% the structural agent；

L) 0.05% to 20%, preferably 0.1% to 15%, more preferably 0.2% to 7% fabric care benefit Agent；

If m) composition is powder laundry detergent, the composition includes to help described in 0.1% to 80% Lotion, and if the composition is liquid laundry detergent, the composition includes to help to wash described in 0.1% to 20% Agent；

N) 0.1% to 99% carrier；And

O) their mixture.

(hh2) composition according to any one of section (a2) to (gg2), in which:

A) fabric softener active includes cationic fabric softener, it is preferable that the cationic softener It is selected from: the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid；Double-(2- hydroxypropyl)-dimethyl methylsulfuric acid The isomers of the ester of ammonium and fatty acid, preferably double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate aliphatic ester, it is highly preferred that The fatty acid is the C that can have tallow or plant origin₁₂-C₂₂Fatty acid, can be to be saturated or unsaturated, and/or can be with To be substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl ammonium chloride propane, N, bis- (the stearoyl-oxy second of N- Base)-N, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, the bis- (stearoyl ketos of N- Base ethyl)-N- (2- ethoxy)-N- methylammonium-methosulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- dimethyl methyl Ammonium sulfate, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, N- bis- (palmityl -2- hydroxypropyls) - N, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, bis- (stearoyl keto of 1,2- Base) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two tallow dimethyl ammonium chlorides, two mustard dimethyl methyl Ammonium sulfate, 1- methyl-1-stearoyl amido ethyl-2- stearyl methylsulfuric acid imidazoline, 1- tallow amido ethyl-2- Tallow acyl imidazoline, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and their mixture；

B) the anionic surfactant scavenger includes water-soluble cationic and/or amphoteric ion scavenger chemical combination Object；Preferably, the anionic surfactant scavenger is selected from monoalkyl ammonium quat and its amine precursor, dialkyl quats Compound and its amine precursor, poly quaternary ammonium compound and its amine precursor, polymeric amine and their mixture；

C) delivery enhancer include be selected from following material: charge density be 0.05 milliequivalent/gram to 23 milliequivalents/ The cationic polymer of gram polymer, charge density are 0.05 milliequivalent/gram polymerize to the both sexes of 23 milliequivalents/gram polymer Object, charge density are 0.05 milliequivalent/gram to 23 milliequivalents/gram protein protein and their mixture；

D) perfume delivery systems be selected from polymer assisted delivery (PAD) system, molecule-assisted delivery (MAD) system, Cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic carrier (ZIC) system and their mixing Object；

E) the soil dispersion polymer is selected from the homopolymerization composition copolymer or three of ethylenically unsaturated monomers anionic monomer Membered copolymer, it is preferable that the anionic monomer is selected from acrylic acid, methacrylic acid, methyl methacrylate, itaconic acid, richness Horse acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, vinyl Sulfonic acid, styrene sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt, their derivative, alkoxylated polyamines are excellent Selection of land, alkoxylate polyethylene imine and their mixture；

F) brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, biphenyl, and five yuan Heterocycle, preferably triazole, pyrazoline, oxazole, imidazoles, hexa-member heterocycle, preferably cumarin, naphthalene amino acid, s-triazine and they Mixture；

G) dope dye includes to be selected from following part: acridine, anthraquinone, preferably polycyclic quinone, azine, azo are excellent Selection of land monoazo, bisazo, trisazo-, four azos, polyazo, pre-metallization azo, two furans of benzo and benzodifuranone, Carotenoid, cumarin, Hua Jing, half flower cyanines of diaza, diphenyl-methane, formazan, half flower cyanines, indigoid, methane, naphthalimide, Naphthoquinones, nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, styryl, triarylmethane, triphenylmenthane, xanthene with And their mixture；

H) dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide pllymers, N- The copolymer of the copolymer of vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol or Their mixture；

I) bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Light drift White dose；Bleaching enzymes；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source and their mixture；

J) detergency enzymes be selected from hemicellulase, peroxidase, protease, cellulase, zytase, lipase, Phosphatidase, esterase, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, lignoenzyme, Pullulanase, tannase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, arabinosidase, hyaluronidase, chondroitin Enzyme, laccase, amylase and their mixture；

K) structural agent be selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, guar gum, pectin, Xanthan gum, modified cellulose, microcrystalline cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic salts, preferably Ground, the inorganic salts are selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and their mixture, Clay, homopolymer and copolymer comprising cationic monomer, the cationic monomer are selected from methacrylic acid N, N- dialkyl amino Base Arrcostab, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- bis- Alkylaminoalkyl group acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- dioxane Base aminoalkyl ester, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized acrylic acid N, N- dialkyl group Aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl metering system Amide and their mixture, it is preferable that when the composition is liquid laundry detergent composition, the structural agent Including rilanit special；Preferably, when the composition is rinse added fabric reinforcing agent, the structural agent includes quaternized The straight chain and/or cross-linked homopolymer and copolymer of acrylic acid N, N- dialkyl aminoalkyl ester；

L) fabric care benefit agents be selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, polyisobutene, Polyolefin and their mixture；

M) builder is selected from phosphate, water-soluble non-phosphorus organic washing-assisting detergent, alkali metal, ammonium and the poly- second of substituted ammonium Hydrochlorate, carboxylate, polycarboxylate, polyhydroxy sulfonate, it is preferable that the builder is selected from ethylenediamine tetra-acetic acid, nitrilo- three Acetic acid, oxygen union II succinic acid, mellitic acid, benzene polycarboxylic acid, the sodium of citric acid, potassium, lithium, ammonium and substituted ammonium salt, oxygen union II Succinate, ether carboxylate, tartrate monosuccinic acid salt, tartaric acid disuccinate, silicate, aluminosilicate, borate, carbon Hydrochlorate, bicarbonate, sesquicarbonate, tetraborate decahydrate, zeolite and their mixture；

N) surfactant be selected from anionic surfactant, nonionic surfactant, amphoteric surfactant, Cationic surfactant, zwitterionic surfactant and their mixture；

O) carrier is selected from water, 1,2-PD, hexylene glycol, ethyl alcohol, isopropanol, glycerol, C₁-C₄Alkanolamine, salt, Sugar, polyalkylene oxide, such as polyethylene oxide；Polyethylene glycol；Polypropylene oxide and their mixture.

(ii2) composition according to any one of section (a2) to (hh2), in which:

A) fabric softener active is selected from: double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid Ester；The isomers of the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid, preferably double-(2- hydroxypropyl)-two Methylammonium-methosulfate aliphatic ester, it is highly preferred that the fatty acid is the C that can have tallow or plant origin₁₂-C₂₂Fat Acid can be saturated or unsaturated, and/or can be substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl Ammonium chloride propane, N, bis- (stearoyl-oxy the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, bis- (stearoyl-oxy ethyl)-N- (2- the ethoxy)-N- methylammonium-methosulfates, N of N-, N- are bis- (hard Acyl -2- hydroxypropyl)-N, N- dimethyl ammonium methyl sulfate, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl methyl sulphur Sour ammonium, N, bis- (palmityl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1,2- bis- (stearoyl-oxy) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two (hard) tallow dimethyl ammonium chloride, two mustard dimethyl ammonium methyl sulfates, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and it Mixture；

B) the anionic surfactant scavenger is selected from the amine of monoalkyl ammonium quat, monoalkyl ammonium quat Precursor, the amine precursor of dialkyl quaternary compound and dialkyl quaternary compound, poly quaternary ammonium compound, poly quaternary ammonium compound Amine precursor and their mixture, it is preferable that the anionic surfactant scavenger is selected from: N-C₆To C₁₈Alkyl- N, N, N- leptodactyline, N-C₆To C₁₈Alkyl-N- hydroxyethyl-N, N- dimethyl ammonium, N-C₆To C₁₈Alkyl-N, N- dihydroxy Base ethyl-N-methyl ammonium salt, N-C₆To C₁₈Alkyl-N- benzyl-N, N- dimethyl ammonium, N, bis--C of N-₆To two-C₁₂Alkyl-N, N- dimethyl ammonium, N, bis--C of N-₆To two-C₁₂Alkyl N- hydroxyethyl N- methyl ammonium salt, N-C₆To C₁₈Alkyl N- alkyl hexyl- N, N- dimethyl ammonium；

C) delivery enhancer be selected from cationic polysaccharide, polyethyleneimine and its derivative, Polyamide amine and by Homopolymer, bipolymer and terpolymer made of one or more cationic monomers and optional second comonomer, it is described Cationic monomer is selected from methacrylic acid N, N- dialkyl aminoalkyl ester, methacrylic acid N, N- dialkyl aminoalkyl methyl Ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl first Base acrylamide, quaternized methacrylic acid N, N- dialkyl aminoalkyl ester, quaternized methacrylic acid N, N- dialkyl amino Base alkyl methacrylate ester, quaternized acrylic acid N, N- dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkyl aminoalkyl acryloyl Amine, quaternary ammonium N, N- dialkyl aminoalkyl Methacrylamide, vinylamine and its derivative, allylamine and its derivative, second Alkenyl imidazoles, quatemized vinylimidazol and poly (dially dialkyl) ammonium chloride and their combination, the second comonomer choosing From: acrylamide, N, N- dialkylacrylamides, Methacrylamide, N, N- dialkyl methacrylamides, acrylic acid C₁- C₁₂Arrcostab, acrylic acid C₁-C₁₂Hydroxy alkyl ester, polyacrylic acid alkylidene diol ester, methacrylic acid C₁-C₁₂Arrcostab, methyl Acrylic acid C₁-C₁₂Hydroxy alkyl ester, polymethylacrylic acid alkylidene diol ester, vinyl acetate, vinyl alcohol, vinyl formamide, Vinyl acetamide, vinyl alkyl ethers, vinylpyridine, vinyl pyrrolidone, vinyl imidazole and derivative, propylene Acid, methacrylic acid, methyl methacrylate, itaconic acid, fumaric acid, 3- allyl oxygroup -2- hydroxyl -1- propane sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamido propyl methylsulphur Sour (AMPS) and its salt and their combination；It is highly preferred that when the composition is rinse added fabric reinforcing agent, institute State the quaternized acrylic acid N that polymer includes straight chain and/or crosslinking, N- dialkyl aminoalkyl ester, when the composition is liquid When body laundry detergent compositions, the delivery enhancer includes cationic polysaccharide, Polyquaternium-10, polyquaternium -7, polyquaternium - 6, diallyldimethylammonium chloride, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternized N, N- dioxane are selected from The homopolymer or copolymer of base aminoalkyl methacrylamides, vinylamine and their mixture；

D) the soil dispersion polymer is selected from alkoxylate polyethylene imine, acrylic acid, methacrylic acid, methyl-prop E pioic acid methyl ester, itaconic acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and Its salt, maleic acid, vinyl sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt homopolymer or copolymer, they Derivative and combination；

E) brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, biphenyl, five yuan Heterocycle such as triazole and their mixture；

F) dope dye is selected from direct purple dye, preferably direct purple dye 9,35,48,51,66 and 99；It is directly blue Dyestuff, preferably directly blue dyestuff 1,71,80 and 279；Acid red dye, preferably 17,73,52,88 and of acid red dye 150；Acid purple dye, preferably acid purple dye 15,17,24,43,49 and 50；Acid blue dye, preferably acid blue dye 15,17,25,29,40,45,75,80,83,90 and 113；Acid black dye, preferably acid black dye 1；Basic purple dye, it is excellent Selection of land basic purple dye 1,3,4,10 and 35；Basic dye, preferably basic dye 3,16,22,47,66,75 and 159； Disperse dyes or solvent dye and their mixture, it is highly preferred that the dope dye is selected from: acid violet 17, acid blue 80, acid violet 50, directly indigo plant 71, directly purple 51, directly indigo plant 1, acid red 88, azogeramine 50, acid blue 29, Acid blue 113 with And their mixture；

G) bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Light drift White dose, peroxygen source, hydrogen peroxide, perborate and percarbonate or their mixture；

H) enzyme is selected from hemicellulase, peroxidase, protease, cellulase, zytase, lipase, phosphatide Enzyme, esterase, cutinase, pectase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, laccase, amylase and their mixing Object, it is preferable that the enzyme is detergency enzymes；

I) surfactant is selected from alkyl sulfate, alkyl ethoxy sulfate, linear alkylbenzene sulfonate (LAS), α-alkene Sulfonated hydrocarbon, ethoxylated alcohol, ethoxylated alkylphenol, fatty acid, soap and their mixture.

J) fabric care benefit agents are selected from dimethyl silicone polymer, polyether silicon, cationic silicone, amino silicone Oxygen alkane and their mixture.

(jj2) composition according to any one of section (a2) to (II2), the composition includes:

A) fabric softener active is selected from cationic fabric softener, it is preferable that the cationic softener choosing From: the ester of double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate and fatty acid；Double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate With the isomers of the ester of fatty acid, preferably double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate aliphatic ester, it is highly preferred that institute Stating fatty acid is the C that can have tallow or plant origin₁₂-C₂₂Fatty acid can be saturated or unsaturated, and/or can be It is substituted or unsubstituted, 1,2- bis- (acyloxy) -3- trimethyl ammonium chloride propane, N, N- bis- (stearoyl-oxy ethyls) - N, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, N, bis- (the stearoyl-oxy second of N- Base)-N- (2- ethoxy)-N- methylammonium-methosulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- dimethyl methylsulfuric acid Ammonium, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, N- bis- (palmityl -2- hydroxypropyl)-N, N- Dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1,2- bis- (stearoyl-oxy) - 3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two (hard) tallow dimethyl ammonium chlorides, two mustard dimethyl methyl Ammonium sulfate, 1- methyl-1-stearoyl amido ethyl-2- stearyl methylsulfuric acid imidazoline, 1- tallow amido ethyl-2- Tallow acyl imidazoline, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and their mixture；

B) carrier,

C) optionally, anionic surfactant scavenger is selected from water-soluble cationic and/or amphoteric ion scavenger Compound；Preferably, the anionic surfactant scavenger is selected from monoalkyl ammonium quat and its amine precursor, dialkyl group Quaternary ammonium compound and its amine precursor, poly quaternary ammonium compound and its amine precursor, polymeric amine and their mixture；

D) optionally, delivery enhancer is selected from: charge density is 0.05 milliequivalent/gram to 23 milliequivalents/gram polymer Cationic polymer, charge density be 0.05 milliequivalent/gram close to 23 milliequivalents/gram polymer amphoteric polymer, charge Degree is 0.05 milliequivalent/gram to 23 milliequivalents/gram protein protein and their mixture；

E) optionally, dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide polymerization Object, the copolymer of n-vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol are total to Polymers or their mixture；

F) optionally, structural agent is selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, Guar Glue, pectin, xanthan gum, modified cellulose, microcrystalline cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin are inorganic Salt, it is preferable that the inorganic salts be selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and they Mixture, clay, homopolymer and copolymer comprising cationic monomer, the cationic monomer are selected from methacrylic acid N, N- bis- Alkylaminoalkyl, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- dialkyl aminoalkyl ester, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized acrylic acid N, N- Dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl first Base acrylamide and their mixture, it is preferable that described when the composition is liquid laundry detergent composition Structural agent includes rilanit special；Preferably, when the composition is rinse added fabric reinforcing agent, the structural agent includes Quaternized acrylic acid N, the straight chain and/or cross-linked homopolymer and copolymer of N- dialkyl aminoalkyl ester；And

G) optionally, fabric care benefit agents selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, gather Isobutene, polyolefin and their mixture；And

H) optionally fragrance；And

I) optionally, perfume delivery systems, it is preferable that the perfume delivery systems are selected from polymer assisted delivery (PAD) System, molecule-assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic Carrier (ZIC) system；The preferably PMC of two or more types；

The composition has 2 to 7 pH, preferably 2 to 5 pH.

(kk2) composition according to any one of section (a2) to (II2), the composition includes:

A) surfactant, selected from anionic surfactant, nonionic surfactant, amphoteric surfactant, Cationic surfactant, zwitterionic surfactant and their mixture；

B) carrier；

C) optionally, builder, selected from phosphate, water-soluble non-phosphorus organic washing-assisting detergent, alkali metal, ammonium and substituted The poly- acetate of ammonium, carboxylate, polycarboxylate, polyhydroxy sulfonate, it is preferable that the builder is selected from ethylenediamine tetra-acetic acid, secondary Nitrilotriacetic acid, oxygen union II succinic acid, mellitic acid, benzene polycarboxylic acid, the sodium salt of citric acid, sylvite, lithium salts, ammonium salt and substitution ammonium Salt；Oxygen union II succinate, ether carboxylate, tartrate monosuccinic acid salt, tartaric acid disuccinate, silicate, aluminosilicate, Borate, carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, zeolite and their mixture；

D) optionally, soil dispersion polymer, the homopolymer selected from ethylenically unsaturated monomers anionic monomer are copolymerized Object or terpolymer, it is preferable that the anionic monomer is selected from acrylic acid, methacrylic acid, methyl methacrylate, clothing health Acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, Vinyl sulfonic acid, styrene sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt, their derivative, alkoxylate Polyamine, it is preferable that alkoxylate polyethylene imine and their mixture；

E) optionally, delivery enhancer is selected from: charge density is 0.05 milliequivalent/gram to 23 milliequivalents/gram polymer Cationic polymer, charge density be 0.05 milliequivalent/gram close to 23 milliequivalents/gram polymer amphoteric polymer, charge Degree is 0.05 milliequivalent/gram to 23 milliequivalents/gram protein protein and their mixture；

F) optionally, brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, connection Benzene, five-ring heterocycles, preferably triazole, pyrazoline, oxazole, imidazoles, hexa-member heterocycle, preferably cumarin, naphthalene amino acid, s-triazine, And their mixture；

G) optionally, dope dye, it includes selected from following part: acridine, anthraquinone, preferably polycyclic quinone, and azine is even Nitrogen, preferably monoazo, bisazo, trisazo-, four azos, polyazo, two furan of pre-metallization azo, two furans of benzo and benzo It mutters ketone, carotenoid, cumarin, Hua Jing, half flower cyanines of diaza, diphenyl-methane, formazan, half flower cyanines, indigoid, methane, naphthoyl Imines, naphthoquinones, nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, styryl, triarylmethane, triphenylmenthane, Xanthene and their mixture；

H) optionally, dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide polymerization Object, the copolymer of n-vinyl pyrrolidone and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol are total to Polymers or their mixture；

I) optionally, bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach synergy Agent；Optical white；Bleaching enzymes；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source and their mixture；

J) optionally, detergency enzymes, selected from hemicellulase, peroxidase, protease, cellulase, zytase, It is lipase, phosphatidase, esterase, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, wooden It is plain enzyme, Pullulanase, tannase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, arabinosidase, hyaluronidase, soft Ossein enzyme, laccase, amylase and their mixture；

K) optionally, structural agent is selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, Guar Glue, pectin, xanthan gum, modified cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic salts, it is preferable that institute State inorganic salts be selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and their mixture, clay, Homopolymer and copolymer comprising cationic monomer, the cationic monomer are selected from methacrylic acid N, N- dialkyl aminoalkyl Ester, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkyl amino Base alkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- dialkyl amido Arrcostab, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized acrylic acid N, N- dialkyl amido alkane Base ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl Methacrylamide, with And their mixture, it is preferable that when the composition is liquid laundry detergent composition, the structural agent includes hydrogenation Castor oil；Preferably, when the composition is rinse added fabric reinforcing agent, the structural agent includes quaternized acrylic acid N, The straight chain and/or cross-linked homopolymer and copolymer of N- dialkyl aminoalkyl ester；

L) optionally, fabric care benefit agents selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, gather Isobutene, polyolefin and their mixture；And

M) optionally fragrance；

N) optionally, perfume delivery systems, it is preferable that the perfume delivery systems are selected from polymer assisted delivery (PAD) System, molecule-assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic Carrier (ZIC) system；The preferably PMC of two or more types；

The composition has 4 to 12 pH, more preferably 5 to 9 pH.

(ll2) composition according to any one of section (a2) to (II2), the composition includes:

A) 49 to 99% carrier, the carrier are selected from polyethylene glycol, salt, polysaccharide and sugar；Preferably molecular weight is The polyethylene glycol of 2000Da to 20,000Da, more preferably molecular weight are the polyethylene glycol of 3,000Da to 12,000Da, and most Preferably molecular weight be 6,000Da to 10,000Da polyethylene glycol；

B) optionally, fabric care benefit agents, preferably siloxanes；

C) optionally fragrance；

D) optionally perfume delivery systems；

E) optionally delivery enhancer.

(mm2) composition according to any one of section (a2) to (II2), the composition includes:

A) fabric softener, fragrance and delivery enhancer；Or

B) fabric softener, fragrance and perfume delivery systems；Or

C) dope dye and surfactant；Or

D) it is less than 10% total water, total water is free water and the summation for combining water；Or

E) fabric softener, fabric care benefit agents and delivery enhancer；Or

G) fabric care benefit agents, anionic surfactant scavenger and delivery enhancer；

Or

H) perfume delivery systems, it is preferable that the perfume delivery systems are selected from polymer assisted delivery (PAD) system, divide Sub- assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic carrier (ZIC) system；The preferably PMC of two or more types；

(nn2) composition according to any one of section (a2) to (jj2), the composition include lotion, gel net Network or lamellar phase, it is preferable that the composition includes vesica.

(oo2) composition according to section (a2) to any one of (II2) and (ll2), the composition are crystal, pearl The form of grain or pastille, it is preferable that the composition includes to be based on general composition weight meter 0.1% to 50%, and preferably 0.5% To 30%, more preferably 5% to 30% triglycerides copolymer, it is selected from the first glycerol ester copolymer, the second glycerol Ester copolymer, third glycerol ester copolymer and their mixture, it is preferable that the bead has shape, and the shape is Circle, diamond shape, dome shape or the semicircle with planar base portion.

(pp2) a kind of product, the product include the composition according to any one of section (a2) to (oo2) and water-soluble Property film, it is preferable that the film includes polyvinyl alcohol, it is preferable that the film surrounds the composition, it is highly preferred that the product Comprising two or more chambers surrounded by the film, and wherein, at least one of described chamber includes the combination Object.

(qq2) a kind of product, the product includes the composition according to any one of section (a2) to (II2), described Product is the form of dryer paper.

(rr2) a kind of fabric, with the composition according to any one of section (a2) to (oo2) and/or according to section The processing of product described in any one of (pp2) to (qq2).

(ss2) a kind of method of processing and/or clean textile, which comprises

A) optionally wash and/or rinse the fabric；

B) make the fabric and the composition according to any one of section (a2) to (oo2), (uu2) and (vv2) and/or The product into contact according to any one of section (pp2) to (qq2)；

C) optionally wash and/or rinse the fabric；And

D) optionally it is passively or actively the dry fabric.

(tt2) composition according to any one of section (a2) to (oo2), wherein the first glycerol ester copolymer and Second glycerol ester copolymer have the poidometer 0% to 5% based on glycerol ester copolymer, preferably 0.1% to 5%, more preferably Ground 0.1% to 4%, more preferably 0.1% to 3%, most preferably 0.1% to 1% free hydrocarbon content.

(uu2) composition according to any one of section (a2) to (oo2), wherein the third glycerol ester copolymer has There are the poidometer 0% to 5% based on glycerol ester copolymer, preferably 0.1% to 5%, more preferably 0.1% to 4%, more preferably Ground 0.1% to 3%, most preferably 0.1% to 1% free hydrocarbon content.

(vv2) composition according to section (a2) to any one of (c2) and (w2), wherein for the third glycerol Ester copolymer, R²¹、R²²And R²³It is each independently selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecylene Base, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11, 14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- Methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 12- tetradecene Base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；Preferably, R²¹、R²²And R²³It is each independently selected from: 8- nonenyl, 8- decene base, 8- ten One carbene base, 8,11- dodecenyl succinic, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane three Alkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

The method for preparing composition

Composition of the invention can be formulated into any suitable form, and any side by being selected by formulator Method preparation, non-limiting example are described in U.S.5, and in 879,584, the document is herein incorporated by reference.For example, glycerol Ester copolymer directly can be mixed to form finished product with the other compositions of composition without pre-emulsification and/or premixing.Alternatively, Can by glycerol ester copolymer and surfactant or emulsifier, solvent, suitable auxiliary agent and/or any other suitably at grouping It closes, to prepare lotion before with blend.

It may include continuously stirred tank reactor (CSTR), homogenizer, turbine type for the suitable equipment in presently disclosed method Blender, recirculation pump, arm mixer, plough coulter type shear mixer, ribbon blender, vertical axis granulator and rotating cylinder mixing Device (both this can configure in (when that can obtain) for batch technology configuration and continuous processing), sprayer dryer and extruder.This Class equipment be available from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Kentucky, U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minnesota, U.S.A.), Arde Barinco (New Jersey, U.S.A.).

Glycerol ester oligomer

In one aspect, present disclose provides the glycerol ester copolymers indicated by formula (I):

Wherein, each R¹、R²、R³、R⁴And R⁵Independently selected from oligomeric glyceride fraction, C_1-24Alkyl, the wherein substitution Base is the substituted C of the part one or more-OH_1-24Alkyl, C_2-24Alkenyl or in which the substituent group are one or more- The substituted C of the part OH_2-24Alkenyl；And/or each of following combination of each section can each independently covalently Connection: R¹And R³、R²And R⁵、R¹With adjacent R⁴、R²With adjacent R⁴、R³With adjacent R⁴、R⁵With adjacent R⁴Or any two Adjacent R⁴, so that the part being covalently attached forms alkenylene moieties；Each X¹And X²Independently selected from C_1-32Alkylidene, wherein The substituent group is the substituted C of the part one or more-OH_1-32Alkylidene, C_2-32Alkenylene or in which the substituent group For the substituted C of the part one or more-OH_2-32Alkenylene；G¹、G²And G³In two be-CH₂, and G¹、G²And G³In One be direct key；For the independent repetitive unit of each of repetitive unit with index n, G⁴、G⁵And G⁶In two For-CH₂, and G⁴、G⁵And G⁶One be direct key, and the G of each individually repetitive unit⁴、G⁵And G⁶Value independently select From G in other repetitive units⁴、G⁵And G⁶Value；G⁷、G⁸And G⁹In two be-CH₂, and G⁷、G⁸And G⁹In one be straight Connect key；And the integer that n is 3 to 250；Precondition is for each in the second glycerol ester copolymer, R¹、R²、R³ And R⁵At least one of, and/or at least one R in an independent repetitive unit of the repetitive unit with index n⁴ It is selected from: 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；8,11- 13 Carbon dialkylene；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- pentadecane trialkenyl；8,11,14- ten Six carbon trialkenyls；18 carbon trialkenyl of 8,11,14-；9- methyl -8- decene base；9- methyl -8- undecenyl；10- methyl- 8- undecenyl；12- methyl -8,11- oleatridecadiene base；14 carbon dialkylene of 12- methyl -8,11-；Methyl -8 13-, 14 carbon dialkylene of 11-；16 carbon trialkenyl of 15- methyl -8,11,14-；17 carbon trialkenyl of 15- methyl -8,11,14-；16- 17 carbon trialkenyl of methyl -8,11,14-；12- tridecylene base；12- tetradecene base；12- pentadecane alkenyl；16 carbon of 12- Alkenyl；13- methyl-1 2- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- methyl-1 2- pentadecane alkenyl.

G¹、G²And G³There can be any suitable value.In some embodiments, G¹And G²For-CH₂And G³It is direct Key.In some other embodiments, G¹And G³For-CH₂And G²For direct key.In some other embodiments, G²And G³ For-CH₂And G¹For direct key.

In each case, G⁴、G⁵And G⁶Independently there is any suitable value.In any one of foregoing embodiments institute In some embodiments stated, at least one situation, G⁴And G⁵For-CH₂And G⁶For direct key.In foregoing embodiments Any one of described in some other embodiments in, at least one situation, G⁴And G⁶For-CH₂And G⁵For direct key. In some other embodiments described in any one of foregoing embodiments, at least one situation, G⁵And G⁶For-CH₂- And G⁴For direct key.

G⁷、G⁸And G⁹There can be any suitable value.Some embodiments described in any one of foregoing embodiments In, G⁷And G⁸For-CH₂And G⁹For direct key.In some other embodiments described in any one of foregoing embodiments, G⁷And G⁹For-CH₂And G⁸For direct key.In some other embodiments described in any one of foregoing embodiments, G⁸With G⁹For-CH₂And G⁷For direct key.

X¹There can be any suitable value.In some embodiments described in any one of foregoing embodiments, X¹For- (CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、-(CH₂)₂₅-、-(CH₂)₂₈-、- (CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₁₁- CH= CH-(CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁- CH=CH-CH₂- CH=CH- CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、-(CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-.In some such embodiments, X¹For-(CH₂)₁₆-、-(CH₂)₁₈-、- (CH₂)₁₉-、-(CH₂)₂₂-、-(CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- (CH₂)₉-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.? In some such embodiments, X¹For-(CH₂)₁₆-、-(CH₂)₁₉-、-(CH₂)₂₂-、-(CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇-CH =CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH= CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.In some other such embodiments In, X¹For-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- (CH₂)₉-、- (CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.In some other such embodiments, X¹For- (CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、 Or-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-。

X²There can be any suitable value.In some embodiments described in any one of foregoing embodiments, X²For- (CH₂)₁₆-、-(CH₂)₁₈-、-(CH₂)₁₉-、-(CH₂)₂₀-、-(CH₂)₂₂-、-(CH₂)₂₄-、-(CH₂)₂₅-、-(CH₂)₂₈-、- (CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₁₁- CH= CH-(CH₂)₁₁-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₁₁-、-(CH₂)₁₁- CH=CH-CH₂- CH=CH- CH₂- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇、-(CH₂)₇- CH=CH- (CH₂)₉、-(CH₂)₁₁- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH- (CH₂)₁₁-.In some embodiments, X²For-(CH₂)₁₆-、-(CH₂)₁₈-、- (CH₂)₁₉-、-(CH₂)₂₂-、-(CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- (CH₂)₉-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.? In some such embodiments, X²For-(CH₂)₁₆-、-(CH₂)₁₉-、-(CH₂)₂₂-、-(CH₂)₂₅-、-(CH₂)₂₈-、-(CH₂)₇-CH =CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH= CH-(CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH= CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.In some other such embodiments In, X²For-(CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₉- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH- (CH₂)₉-、- (CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、- (CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇Or-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-.In some other such embodiments, X²For- (CH₂)₇- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH= CH-CH₂- CH=CH- (CH₂)₇-、-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-、 Or-(CH₂)₇- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH-CH₂- CH=CH- (CH₂)₇-。

R¹There can be any suitable value.In the above-described embodiment in described in any item some embodiments, R¹For C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R¹For undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R¹For pentadecyl or heptadecyl. In the above-described embodiment in described in any item some embodiments, R¹For C_2-24Alkenyl or C_9-24Alkenyl.In some such realities It applies in scheme, R¹For 8- heptadecene base, 10- heptadecene base, 12- heneicosene base, 17 carbon dialkylene of 8,11-, 8, 17 carbon trialkenyl of 11,14-, 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- dodecenyl succinic, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 9- methyl -8- decene base, 9- first Base -8- undecenyl, 10- methyl -8- undecenyl, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl, 14- methyl-1 2- pentadecane alkenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon two of 8,11- Alkenyl, 8,11- pentadecane dialkylene, 12- methyl -8,11- oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon of 15- methyl -8,11,14- Trialkenyl, 17 carbon trialkenyl of 16- methyl -8,11,14-, 8,11,14- pentadecane trialkenyl, 16 carbon triolefin of 8,11,14- 18 carbon trialkenyl of base, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.In some other such embodiments, R¹ For 8- heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some In addition in such embodiment, R¹For 17 carbon triolefin of 8- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14- Base.In some such embodiments, R¹For 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- ten Two carbene bases, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 12- tridecylene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon three of 8,11,14- 18 carbon trialkenyl of alkenyl or 8,11,14-.In some other such embodiments, R¹For 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon diene of 8,11- Base, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon of 8,11,14- 18 carbon trialkenyl of trialkenyl or 8,11,14-.In some other such embodiments, R¹For 8- nonenyl, 11 carbon of 8- Alkenyl, 12 carbon dialkylene of 8,11-, 14 carbon dialkylene of 8,11- or 8,11,14- pentadecane trialkenyl.In some embodiments In, R¹For oligomeric glyceride fraction.

R²There can be any suitable value.In the above-described embodiment in described in any item some embodiments, R²For C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R²For undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R²For pentadecyl or heptadecyl. In the above-described embodiment in some embodiments of any one, R²For C_2-24Alkenyl or C_9-24Alkenyl.In some such embodiment party In case, R²For 8- heptadecene base, 10- heptadecene base, 12- heneicosene base, 17 carbon dialkylene of 8,11-, 8,11, 17 carbon trialkenyl of 14-, 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- dodecenyl succinic, 12- Tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 9- methyl -8- decene base, 9- methyl - 8- undecenyl, 10- methyl -8- undecenyl, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkene Base, 14- methyl-1 2- pentadecane alkenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon diene of 8,11- Base, 8,11- pentadecane dialkylene, 12- methyl -8,11- oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 13- 14 carbon dialkylene of methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon three of 15- methyl -8,11,14- Alkenyl, 17 carbon trialkenyl of 16- methyl -8,11,14-, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 17 carbon trialkenyl of 8,11,14- or 8,11,14-.In some other such embodiments, R²For 8- Heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some other Such embodiment in, R²For 8- heptadecene base, 8,11-, 17 carbon dialkylene or 8,11,14- ten seven carbon trialkenyls.? In some such embodiments, R²For 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 12 carbon of 8- Alkenyl, 8,11-, 12 carbon dialkylene, 8,11- oleatridecadiene base, 8,11-, 14 carbon dialkylene, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyls, 8,11,14- ten seven carbon trialkenyls or 8,11,14- ten eight Carbon trialkenyl.In some other such embodiments, R²For 8- nonenyl, 8- decene base, 8- undecenyl, 8- 12 Carbene base, 8,11-, 12 carbon dialkylene, 8,11- oleatridecadiene base, 12- tridecylene, 8,11-, 14 carbon dialkylene, 8, 11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon triolefin of 8,11,14- 18 carbon trialkenyl of base or 8,11,14-.In some other such embodiments, R²For 8- nonenyl, 8- endecatylene Base, 12 carbon dialkylene of 8,11-, 14 carbon dialkylene of 8,11- or 8,11,14- pentadecane trialkenyl.In some embodiments In, R²For oligomeric glyceride fraction.

R³There can be any suitable value.In the above-described embodiment in described in any item some embodiments, R³For C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R³For undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R³For pentadecyl or heptadecyl. In the above-described embodiment in described in any item some embodiments, R³For C_2-24Alkenyl or C_9-24Alkenyl.In some such realities It applies in scheme, R³For 8- heptadecene base, 10- heptadecene base, 12- heneicosene base, 17 carbon dialkylene of 8,11-, 8, 17 carbon trialkenyl of 11,14-, 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- dodecenyl succinic, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 9- methyl -8- decene base, 9- first Base -8- undecenyl, 10- methyl -8- undecenyl, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl, 14- methyl-1 2- pentadecane alkenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon two of 8,11- Alkenyl, 8,11- pentadecane dialkylene, 12- methyl -8,11- oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon of 15- methyl -8,11,14- Trialkenyl, 17 carbon trialkenyl of 16- methyl -8,11,14-, 8,11,14- pentadecane trialkenyl, 16 carbon triolefin of 8,11,14- 18 carbon trialkenyl of base, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.In some other such embodiments, R³ For 8- heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some In addition in such embodiment, R³For 17 carbon triolefin of 8- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14- Base.In some such embodiments, R³For 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- ten Two carbene bases, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane two Alkenyl, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon trialkenyl of 8,11,14- or 8,11,14- 18 carbon trialkenyls.In some other such embodiments, R³For 8- nonenyl, 8- decene base, 8- undecenyl, 8- Dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 12- tridecylene, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon three of 8,11,14- 18 carbon trialkenyl of alkenyl or 8,11,14-.In some other such embodiments, R³For 8- nonenyl, 8- endecatylene Base, 8,11-, 12 carbon dialkylene, 8,11-, 14 carbon dialkylene or 8,11,14- pentadecane trialkenyls.In some embodiments In, R³For oligomeric glyceride fraction.

In the case of its, R⁴There can be any suitable value.In the above-described embodiment described in any item one In a little embodiments, at least one situation, R⁴For C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl. In some such embodiments, at least one situation, R⁴For undecyl, tridecyl, pentadecyl or heptadecane Base.In some such embodiments, at least one situation, R⁴For pentadecyl or heptadecyl.In above-mentioned embodiment party In some embodiments described in any one of case, at least one situation, R⁴For C_2-24Alkenyl or C_9-24Alkenyl.Some In such embodiment, at least one situation, R⁴For 8- heptadecene base, 10- heptadecene base, 12- heneicosene, 17 carbon dialkylene of 8,11-, 17 carbon trialkenyl of 8,11,14-, 8- nonenyl, 8- decene base, 8- undecenyl, 10- 11 Carbene base, 8- dodecenyl succinic, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 13- methyl-1 2- tetradecene Base, 13- methyl-1 2- pentadecane alkenyl, 14- methyl-1 2- pentadecane alkenyl, 8,11-, 12 carbon dialkylene, 8,11-, 13 carbon Dialkylene, 8,11-, 14 carbon dialkylene, 8,11- pentadecane dialkylene, 12- methyl -8,11- oleatridecadiene base, 12- methyl - 14 carbon dialkylene of 8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- 17 carbon trialkenyl of methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 8,11,14- pentadecane trialkenyl, 18 carbon trialkenyl of 16 carbon trialkenyl of 8,11,14-, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.Some other In such embodiment, at least one situation, R⁴For 8- heptadecene base, 10- heptadecene base, 17 carbon two of 8,11- 17 carbon trialkenyl of alkenyl or 8,11,14-.In some other such embodiments, at least one situation, R⁴For 17 carbon trialkenyl of 8- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.In some such embodiments, In at least one situation, R⁴For 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 12- tridecylene base, 14 carbon dialkylene of 8,11-, 8,11- 15 Carbon dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon trialkenyl of 8,11,14- or 8, 18 carbon trialkenyl of 11,14-.In some other such embodiments, at least one situation, R⁴For 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 8,11- 14 carbon dialkylenes, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 8, 18 carbon trialkenyl of 17 carbon trialkenyl of 11,14- or 8,11,14-.In some other such embodiments, at least one In the case of kind, R⁴For 8- nonenyl, 8- undecenyl, 12 carbon dialkylene of 8,11-, 14 carbon dialkylene of 8,11- or 8,11, 14- pentadecane trialkenyl.In some embodiments, at least one situation, R⁴For oligomeric glyceride fraction.

R⁵There can be any suitable value.In the above-described embodiment in described in any item some embodiments, R⁵For C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R⁵For undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R⁵For pentadecyl or heptadecyl. In the above-described embodiment in described in any item some embodiments, R⁵For C_2-24Alkenyl or C_9-24Alkenyl.In some such realities It applies in scheme, R⁵For 8- heptadecene base, 10- heptadecene base, 12- heneicosene base, 8,11-, 17 carbon dialkylene, 8, 17 carbon trialkenyl of 11,14-, 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- dodecenyl succinic, 12- tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 9- methyl -8- decene base, 9- first Base -8- undecenyl, 10- methyl -8- undecenyl, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane Alkenyl, 14- methyl-1 2- pentadecane alkenyl, 8,11-, 12 carbon dialkylene, 8,11- oleatridecadiene base, 8,11-, 14 carbon two Alkenyl, 8,11- pentadecane dialkylene, 12- methyl -8,11- oleatridecadiene base, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon of 15- methyl -8,11,14- Trialkenyl, 17 carbon trialkenyl of 16- methyl -8,11,14-, 8,11,14- pentadecane trialkenyl, 16 carbon triolefin of 8,11,14- 18 carbon trialkenyl of base, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.In some other such embodiments, R⁵ For 8- heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some In addition in such embodiment, R⁵For 17 carbon triolefin of 8- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14- Base.In some such embodiments, R⁵For 8- nonenyl, 8- decene base, 8- undecenyl, 10- undecenyl, 8- ten Two carbene bases, 12 carbon dialkylene of 8,11-, 12- tridecylene base, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon three of 8,11,14- 18 carbon trialkenyl of alkenyl or 8,11,14-.In some other such embodiments, R⁵For 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon diene of 8,11- Base, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyls, 8,11,14- ten six carbon trialkenyls, 8,11,14- ten seven carbon Trialkenyl or 8,11,14- ten eight carbon trialkenyls.In some other such embodiments, R⁵For 8- nonenyl, 11 carbon of 8- Alkenyl, 12 carbon dialkylene of 8,11-, 14 carbon dialkylene of 8,11- or 8,11,14- pentadecane trialkenyl.In some embodiments In, R⁵For oligomeric glyceride fraction.

Variable n can have any suitable value.In the above-described embodiment in described in any item some embodiments, n For 3 to 250 or 5 to 180 or 6 to 140 or 8 to 70 or 9 to 40 or 9 to 26 integer.In some other embodiments In, n be 3 to 35 or 5 to 30 or 7 to 25 or 10 to 20 integer.

In the above-described embodiment in described in any item some embodiments, glycerol ester polymer only includes following chemical combination Object, wherein R¹、R²、R³And R⁵At least one of or R⁴At least one situation be selected from: 8- nonenyl；8- decene base；8- 11 Carbene base；10- undecenyl, 12- tridecylenic ester；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；13 carbon two of 8,11- Alkenyl；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- pentadecane trialkenyl；16 carbon of 8,11,14- Trialkenyl；17 carbon trialkenyl of 8,11,14-；And 18 carbon trialkenyl of 8,11,14-.Any one institute in the above-described embodiment In some other embodiments stated, glycerol ester polymer only includes following compound, wherein R¹、R²、R³And R⁵In at least one A or R⁴At least one situation be selected from: 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic；8,11- ten Two carbon dialkylenes；8,11- oleatridecadiene base；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- 15 Carbon trialkenyl；16 carbon trialkenyl of 8,11,14-；17 carbon trialkenyl of 8,11,14-；And 18 carbon trialkenyl of 8,11,14-. In the above-described embodiment in described in any item some other embodiments, glycerol ester polymer only includes following compound, Wherein R¹、R²、R³And R⁵At least one of or R⁴At least one situation be selected from: 8- nonenyl；8- undecenyl；8,11- 12 carbon diene；14 carbon dialkylene of 8,11-；Or 8,11,14- pentadecane trialkenyl.Any one institute in the above-described embodiment In some embodiments stated, glycerol ester polymer only includes following compound, wherein R¹、R²、R³And R⁵At least one of, Or R⁴At least one situation be selected from: 8- nonenyl；8- decene base；8- undecenyl；10- undecenyl；13 carbon of 12- Alkenyl；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；8,11- oleatridecadiene base；14 carbon dialkylene of 8,11-；8,11- Pentadecane dialkylene；8,11,14- pentadecane trialkenyl；And 16 carbon trialkenyl of 8,11,14-.Appoint in the above-described embodiment In some other embodiments described in one, glycerol ester polymer only includes following compound, wherein R¹、R²、R³And R⁵In At least one or R⁴At least one situation be selected from: 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic； 12 carbon dialkylene of 8,11-；8,11- oleatridecadiene base；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylenes；8,11, 14- pentadecane trialkenyl；And 8,11,14- ten six carbon trialkenyls.It is described in any item some other in the above-described embodiment Embodiment, the glycerol ester polymer only include following compound, wherein R¹、R²、R³And R⁵At least one of or R⁴Extremely A kind of few situation is C_2-15Alkenyl or C_2-14Alkenyl or C_5-14Alkenyl or C_2-13Alkenyl or C_2-12Alkenyl or C_5-12Alkenyl.

On the other hand, glycerol ester copolymer is included in the presence of metathesis catalyst by two or more monomer reactions And the structural unit formed, described two or more monomers include the monomeric compound indicated by formula (IIa):

And the monomeric compound indicated by formula (IIb):

Wherein, each R¹¹、R¹²And R¹³It independently is C_1-24Alkyl, wherein substituent group are the quilt of the part one or more-OH Substituted C_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, premise Condition is R¹¹、R¹²And R¹³At least one of be C_2-24Alkenyl or in which substituent group are being substituted for the part one or more-OH C_2-24Alkenyl；Each R²¹、R²²And R²³It independently is C_1-24Alkyl, wherein substituent group are being taken for the part one or more-OH The C in generation_1-24Alkyl, C_2-24Alkenyl or in which substituent group are the substituted C of the part one or more-OH_2-24Alkenyl, premise item Part is R²¹、R²²And R²³At least one of be 8- nonenyl；8- decene base；8- undecenyl；8- dodecenyl succinic；8,11- 12 carbon dialkylenes；8,11- oleatridecadiene bases；14 carbon dialkylene of 8,11-；8,11- pentadecane dialkylene；8,11,14- ten Five carbon trialkenyls；16 carbon trialkenyl of 8,11,14-；18 carbon trialkenyl of 8,11,14-；9- methyl -8- decene base；9- methyl- 8- undecenyl；10- methyl -8- undecenyl；12- methyl -8,11- oleatridecadiene base；12- methyl -8,11- 14 Carbon dialkylene；14 carbon dialkylene of 13- methyl -8,11-；16 carbon trialkenyl of 15- methyl -8,11,14-；Methyl -8,11 15-, 17 carbon trialkenyl of 14-；17 carbon trialkenyl of 16- methyl -8,11,14-；12- tridecylene base；12- tetradecene base；12- Pentadecane alkenyl；12- hexadecene base；13- methyl-1 2- tetradecene base；13- methyl-1 2- pentadecane alkenyl；With 14- first Base -12- pentadecane alkenyl.

Variable R¹¹、R¹²And R¹³There can be any suitable value.In some embodiments, R¹¹、R¹²And R¹³It independently is C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R¹¹、R¹²And R¹³Solely It is on the spot undecyl, tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R¹¹、R¹² And R¹³It independently is pentadecyl or heptadecyl.In the above-described embodiment in described in any item some embodiments, R¹¹、R¹²And R¹³It independently is C_2-24Alkenyl or C_9-24Alkenyl or C_11-24Alkenyl or C_13-24Alkenyl or C_15-24Alkenyl.Some In such embodiment, R¹¹、R¹²And R¹³It independently is 8- heptadecene base, 10- heptadecene base, 17 carbon diene of 8,11- 17 carbon trialkenyl of base or 8,11,14-.In some other such embodiments, R¹¹、R¹²And R¹³It independently is 8- 17 17 carbon trialkenyl of carbene base, 17 carbon dialkylene of 8,11- or 8,11,14-.

Variable R²¹、R²²And R²³There can be any suitable value.Some implementations described in any one of foregoing embodiments In scheme, R²¹、R²²And R²³In zero, one or two independently be C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R²¹、R²²And R²³In zero, one or two independently be undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R²¹、R²²And R²³In zero, one It is a or two independently are pentadecyl or heptadecyl.Described in any item some embodiments in the above-described embodiment In, R²¹、R²²And R²³In zero, one or two independently be C_2-24Alkenyl or C_9-24Alkenyl or C_11-24Alkenyl or C_13-24 Alkenyl or C_15-24Alkenyl.In some such embodiments, R²¹、R²²And R²³In zero, one or two independently be 8- Heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some other Such embodiment in, R²¹、R²²And R²³In zero, one or two independently be 8- heptadecene base, 8,11- 17 17 carbon trialkenyl of carbon dialkylene or 8,11,14-.

In some other embodiments described in any one of foregoing embodiments, R²¹、R²²And R²³In one, two It is a or three independently are C_2-15Alkenyl or C_2-14Alkenyl, C_5-14Alkenyl or C_2-13Alkenyl or C_2-12Alkenyl or C_5-12Alkenyl. In some such embodiments, R²¹、R²²And R²³In one, two or three independently be 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon diene of 8,11-, 8,11- oleatridecadiene base, 14 dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon three of 8,11,14- Alkenyl, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- ten Three carbon dialkylenes, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, methyl -8,11 15-, 16 carbon trialkenyl of 14-, 15- methyl -8,11,17 carbon trialkenyl of 14-, 16- methyl -8,11,17 carbon trialkenyl of 14-, 12- Tridecylene base, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- Methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl, 10- undecenyl, 17 carbon trialkenyl of 8,11,14- Or 18 carbon trialkenyl of 8,11,14-.In some other such embodiments, R²¹、R²²And R²³In one, two or three It is a independently to be 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- Oleatridecadiene base, 8,11-, 14 carbon dialkylene, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyls, 8,11, 18 carbon trialkenyl of 16 carbon trialkenyl of 14-, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.In some other such realities It applies in scheme, R²¹、R²²And R²³In one, two or three independently be 8- nonenyl, 8- undecenyl, 8,11- 12 Carbon dialkylene, 14 carbon dialkylene of 8,11- or 8,11,14- pentadecane trialkenyl.

Glycerol ester copolymer disclosed herein can have any suitable molecular weight.In the above-described embodiment any one Some embodiments in, glycerol ester copolymer have in 4,000g/mol to 150,000g/mol or 5,000g/mol is extremely 130,000g/mol or 6,000g/mol to 100,000g/mol or 7,000g/mol to 50,000g/mol or 8,000g/ Weight average molecular weight within the scope of mol to 30,000g/mol or 8,000g/mol to 20,000g/mol.

In some embodiments, glycerol ester copolymer has 2,000g/mol to 150,000g/mol or 3,000g/ The number-average molecular weight (Mn) of mol to 30,000g/mol or 4,000g/mol to 20,000g/mol.

The structural unit that glycerol ester copolymer disclosed herein can have the monomeric compound indicated by formula (IIa) to be formed Any suitable ratio of the structural unit formed with the monomeric compound indicated by formula (IIb).It is any in the above-described embodiment In the above-mentioned some embodiments of item, indicated by the structural unit that the monomeric compound that formula (IIa) is indicated is formed with by formula (IIb) The quantity ratio of structural unit that is formed of monomeric compound be no more than 10:1 or or no more than 9:1 or no more than 8:1 be no more than 7:1 is no more than 6:1 or is no more than 5:1 or is no more than 4:1 or is no more than 3:1 or is no more than 2:1 or is no more than 1:1. Glycerol ester copolymer disclosed herein may include not added by what the monomeric compound that formula (IIa) or formula (IIb) indicate was formed Structural unit, the structure list including but not limited to formed by other unsaturated polyol esters (unsaturated diol, triol etc.) Member.

Or in some other embodiments described in any one of foregoing embodiments, in depositing for metathesis catalyst Under, make two or more monomer reactions, as a part of reaction mixture, wherein the singulation indicated by formula (IIa) Conjunction object and the weight of the monomeric compound indicated by formula (IIb) or no more than 10:1 or no more than 9:1 are no more than with weight ratio 8:1 or be no more than 7:1 or be no more than 6:1 or be no more than 5:1 or be no more than 4:1 or be no more than 3:1 or be no more than 2:1, Or it is no more than 1:1.In some embodiments, described anti-other than the monomeric compound that formula (IIa) and formula (IIb) indicate Answering mixture also includes additional monomer compound.

Any suitable metathesis catalyst can be used, as described in greater detail below.Appoint in the above-described embodiment In one some embodiment, metathesis catalyst is organic ruthenium compound, organic osmium compound, organotungsten compounds or has Machine molybdenum compound.

On the other hand, present disclose provides glycerol ester copolymers, and it includes answered by two or more monomers first The structural unit for reacting and being formed in the presence of decomposition catalyst；Wherein first monomer is unsaturated natural oil glyceride, And the second comonomer is the natural oil glyceride of unsaturated alkenyl.On the other hand, present disclose provides glyceride copolymerization Object, it includes the structural units for being reacted in the presence of the first metathesis catalyst by two or more monomers and being formed；Its Described in the first monomer be unsaturated synthesis polyol ester, and the second comonomer is unsaturated alkenyl natural oil glycerol Ester.On the other hand, present disclose provides glycerol ester copolymers, and it includes urged by two or more monomers in the first double decomposition The structural unit for reacting and being formed in the presence of agent；Wherein first monomer is unsaturated natural oil glyceride, and institute It states second comonomer and is combined to polyol ester for unsaturated alkenyl.On the other hand, present disclose provides glycerol ester copolymer, packets Containing the structural unit for being reacted in the presence of the first metathesis catalyst by two or more monomers and being formed；Wherein described One monomer is unsaturated synthesis polyol ester, and the second comonomer is that unsaturated alkenyl is combined to polyol ester.Another Aspect, present disclose provides glycerol ester copolymers, and it includes the depositing in the first metathesis catalyst by two or more monomers In the structural unit that lower reaction is formed；Wherein first monomer is combined to polyol ester for the first unsaturated alkenyl, and The second comonomer is that the second unsaturated alkenyl is combined to polyol ester.On the other hand, present disclose provides glyceride copolymerization Object, it includes the structural units for being reacted in the presence of the first double decomposition object by two or more monomers and being formed；Wherein institute Stating the first monomer is the first natural oil glyceride of unsaturated alkenyl, and the second comonomer is the second unsaturated alkenyl day Right oil glyceride.On the other hand, present disclose provides glycerol ester copolymer, it includes by two or more monomers first The structural unit for reacting and being formed in the presence of double decomposition object；Wherein first monomer is unsaturated alkenyl natural oil glycerol Ester, and the second comonomer is that unsaturated alkenyl is combined to polyol ester.

In some embodiments, the natural oil glyceride of unsaturated alkenyl by the second unsaturated natural oil glyceride with it is short Reaction of olefine in the presence of the second metathesis catalyst is formed.In some such embodiments, unsaturated alkenyl Natural oil glyceride has than the second low molecular weight of unsaturated natural oil glyceride.According to the embodiment above, it can be used and appoint What suitable short-chain olefin.In some embodiments, short-chain olefin C_2-8Alkene or C_2-6Alkene.In some such embodiment party In case, short-chain olefin is ethylene, propylene, 1- butylene, 2- butylene, isobutene, 1- amylene, 2- amylene, 1- hexene, 2- hexene or 3- Hexene.In some other such embodiments, short-chain olefin is ethylene, propylene, 1- butylene, 2- butylene or isobutene.? In some embodiments, short-chain olefin is ethylene.In some embodiments, short-chain olefin is propylene.In some embodiments In, short-chain olefin is 1- butylene.In some embodiments, short-chain olefin is 2- butylene.It is short in some other embodiments Olefine is branch short-chain olefin.The non-limiting example of such short alkene of branch includes but is not limited to isobutene, 3- methyl-1- Butylene, 3- Methyl-1-pentene and 4-methyl-1-pentene.

Unsaturated natural oil glyceride is available from any suitable natural oil sources.Described in any one of foregoing embodiments Some embodiments in, unsaturated natural oil glyceride derives from synthetic oil, natural oil (for example, vegetable oil, algae oil, bacterium And/or the oil and animal tallow of originated from fungus), these combination etc..In some embodiments, the natural oil, which derives from, plants Object oil, such as seed oil.The recyclable vegetable oil utilized can also be used.In some other embodiments, vegetable oil is Abyssinia's oil, almond oil, apricot oil, apricot kernel oil, argan oil, avocado oil, babassu oil, monkey-bread tree are oily, black Ennel oil, currant oil, borage oil, shepherd's purse indigo plant seed oil, rapeseed oil, canola (canola) oil, castor oil, cherry Persic oil, coconut oil, corn oil, cottonseed oil, blue dragonfly oil, evening primrose oil, linseed oil, grape seed oil, grapefruit seed oil, fibert It is oil, hemp-seed oil, Jatropha oil, jojoba oil, Hawaii macadamia nut oil, linseed oil, macadimia nut oil, white awns flower seed oil, peppery Wood oil, mustard oil, veepa oil, olive oil, palm oil, palm-kernel oil, persic oil, peanut oil, pecan oil, penny cress oil, purple Perilla oil, pistachio oil, granada seed oil, pongam oil, pumpkin seed oil, raspberry seed oil, red palm oil, rice bran oil, rose Fruit oil, safflower oil, hippophae rhamnoides fruit oil, sesame seed oil, shea butter, sunflower oil, soybean oil, smoke careless soya-bean oil, tung oil, walnut oil, Wheat-germ oil, high oleoyl soybean oil, high oleoyl sunflower oil, high oleoyl safflower oil, high erucic acid rape seed oil and they Mixture.In some embodiments, vegetable oil is palm oil.In some embodiments, vegetable oil is soybean oil.Some In embodiment, vegetable oil is canola oil.In some embodiments, the representative non-limiting example of animal tallow includes pig Oil, tallow, chicken fat, butter fat, fish oil, fat of Oromaius norvaehollandeae, combination of these oil etc..In some embodiments, the generation of synthetic oil Table non-limiting example includes tall oil, for the by-product of wood pulp manufacture.In some embodiments, natural oil is smart Refining, decoloration and/or deodorization.

The natural oil of type described herein is usually made of the triglycerides of fatty acid.These fatty acid can be saturation, list Insatiable hunger and/or how unsaturated and be included in C₈To C₃₀Different chain length in range.The most common fatty acid includes such as laurel Sour (dodecanoic acid), myristic acid (tetradecanoic acid), palmitinic acid (hexadecanoic acid), stearic acid (octadecanoid acid), arachidic acid (20 Alkanoic acid) and the saturated fatty acids such as lignoceric acid (tetracosanoic acid)；Unsaturated acids includes such as palmitoleic acid (C₁₆Acid) and oleic acid (C₁₈ Acid) etc. fatty acid；Polyunsaturated acid includes such as linoleic acid (two unsaturation C₁₈Acid), linolenic acid (three unsaturation C₁₈Acid) and flower Raw tetraenoic acid (four unsubstituted C₂₀Acid) etc. fatty acid.Natural oil is further by randomly positioned at three of trifunctional glycerol molecule The ester of these fatty acid on site is constituted.Different natural oil is giving these fatty acid with different ratios Natural oil in, ranges of these acid will also depend on the place of such as plant or plant growth, plant or crop maturity, The factor of weather during Growing season or the like.Therefore, any given natural oil is difficult to have specific or unique structure, phase Instead, structure is typically based on certain assembly averages.For example, it is the stearic acid of about 15:24:50:11, oil that soybean oil, which includes ratio, The mixture of sour, linoleic acid plus linolenic acid predominantly C16 and C18 acid groups, and the average double key number of each triglycerides For 4.4-4.7.One method of quantitative number of double bonds is iodine number (IV), is defined as gram of the iodine reacted with 100 grams of oil Number.Therefore, for soybean oil, the range of average Iodine Number is 120 to 140.Soybean oil can include about 95 weight % or more (example Such as, 99 weight % or more) fatty acid triglycerides.Main fatty acid in the polyol ester of soybean oil includes saturated fat Acid is palmitinic acid (hexadecylic acid) and stearic acid (stearic acid) and unsaturated fatty acid as a non-limiting example, as One non-limiting example is oleic acid (9- octadecenoic acid), linoleic acid (9,12 octadecadienoic acid) and linolenic acid (9,12, 15- octatecatrienoic acid).

In an exemplary embodiment, vegetable oil is canola oil, such as the canola oil for refining, decolourizing and be deodorized (i.e. RBD canola oil).Canola oil is generally comprise about 95 weight % or more (for example, 99 weight % or more) fatty acid sweet The unsaturated glycerine polyol ester of oily three esters.Main fatty acid in the polyol ester of canola oil include saturated fatty acid (such as Palmitinic acid (hexadecylic acid) and stearic acid (stearic acid)) and unsaturated fatty acid (such as oleic acid (9- octadecenoic acid), linoleic acid (9,12 octadecadienoic acid) and linolenic acid (9,12,15- octatecatrienoic acid)).Canola oil is the unsaturated plant of height Oil, and many in its triglycerides molecule has at least two unsaturated fatty acids (i.e. polyunsaturated triglyceride).

In some embodiments, unsaturated alkenyl is combined to polyol ester and synthesizes polyol ester and short alkene by unsaturation Reaction of hydrocarbon in the presence of the second metathesis catalyst is formed.In some such embodiments, unsaturated alkenyl is combined to Polyol ester has the lower molecular weight of synthesis polyol ester more unsaturated than second.According to the embodiment above, can be used any Suitable short-chain olefin.In some embodiments, short-chain olefin C_2-8Alkene or C_2-6Alkene.In some such embodiments In, short-chain olefin be ethylene, propylene, 1- butylene, 2- butylene, isobutene, 1- amylene, 2- amylene, 1- hexene, 2- hexene or 3- oneself Alkene.In some other such embodiments, short-chain olefin is ethylene, propylene, 1- butylene, 2- butylene or isobutene.One In a little embodiments, short-chain olefin is ethylene.In some embodiments, short-chain olefin is propylene.In some embodiments, Short-chain olefin is 1- butylene.In some embodiments, short-chain olefin is 2- butylene.In some other embodiments, short chain Alkene is branch short-chain olefin.The non-limiting example of such short alkene of branch includes but is not limited to isobutene, 3- methyl-1-fourth Alkene, 3- Methyl-1-pentene and 4-methyl-1-pentene.

Unsaturation synthesis polyol ester includes ester, such as derived from ethylene glycol or propylene glycol, polyethylene glycol, polypropylene glycol or Those of poly- (tetramethylene ether) glycol；Ester, such as derived from pentaerythrite, dipentaerythritol, tripentaerythritol, trihydroxy methyl Those of propane or neopentyl glycol；Or sugar ester, such asSugar ester is such asIncluding one or more classes The ester group of metathesis exchange reaction can occur at most eight for the sucrose Polyester of type.Sucrose Polyester is derived from natural next Source, and therefore can produce positive environment influence using sucrose Polyester.Sucrose Polyester is polyester material, around sucrose main chain Chain length, saturation degree and derivative variable with multiple the position of substitution and aliphatic chain.Such sucrose Polyester can have greater than about 5 Esterification degree (" IBAR ").In one embodiment, sucrose Polyester can have the IBAR of about 5 to about 8.In another embodiment party In case, sucrose Polyester has the IBAR of about 5-7, and in another embodiment, and sucrose Polyester has about 6 IBAR.? In another embodiment, sucrose Polyester has about 8 IBAR.Since sucrose Polyester is derived from natural origin, it is thus possible to deposit Distribution and chain length in IBAR.For example, the sucrose Polyester that IBAR is 6 has containing the IBAR mainly with about 6 with some About 5 IBAR and it is some with about 7 IBAR mixture.In addition, such sucrose Polyester can have the insatiable hunger of about 3 to about 140 With degree or iodine number (" IV ").In another embodiment, sucrose Polyester can have the IV of about 10 to about 120.In another reality It applies in scheme, sucrose Polyester can have about 20 to 100 IV.In addition, such sucrose Polyester has about C_12-20Chain length, but it is unlimited In these chain lengths.

The non-limiting example of applicable sucrose Polyester includes1618S、1618U、1618H、Sefa Soyate IMF 40、Sefa Soyate LP426、2275、C1695、C18:0 95、C1495、1618H B6、1618S B6、1618U B6、Sefa Cottonate、C1295、Sefa C895、Sefa C1095、1618S B4.5, it is all to be purchased from The Procter and Gamble Co. (Cincinnati, Ohio).

Other examples of suitable unsaturated polyol ester may include but be not limited to sorbitol ester, maltose alcohol ester, dehydration Ester derived from ester derived from sorbitol ester, maltodextrin, the ester of xylitol, polyglycerol ester and other sugar.

Glycerol ester copolymer disclosed herein can have any suitable molecular weight.In the above-described embodiment any one Some embodiments in, glycerol ester copolymer have in 4,000g/mol to 150,000g/mol or 5,000g/mol is extremely 130,000g/mol or 6,000g/mol to 100,000g/mol or 7,000g/mol to 50,000g/mol or 8,000g/ Weight average molecular weight within the scope of mol to 30,000g/mol or 8,000g/mol to 20,000g/mol.

In some embodiments, glycerol ester copolymer has 2,000g/mol to 150,000g/mol or 3,000g/ The number-average molecular weight (Mn) of mol to 30,000g/mol or 4,000g/mol to 20,000g/mol.

Glycerol ester copolymer disclosed herein can have the structural unit formed by the first monomer and by second comonomer shape At structural unit any suitable ratio.In the above-described embodiment in the above-mentioned some embodiments of any one, by first The quantity ratio of the structural unit that monomer is formed and the structural unit formed by second comonomer be no more than 10:1 or no more than 9:1 or Or no more than 8:1 or no more than 7:1 or no more than 6:1 or no more than 5:1 or no more than 4:1 or no more than 3:1 do not surpass It crosses 2:1 or is no more than 1:1.Glycerol ester copolymer disclosed herein may include not formed by the first monomer or second comonomer Additional structure units, the knot including but not limited to formed by other unsaturated polyol esters (unsaturated diol, triol etc.) Structure unit.

Alternatively, in some other embodiments described in any one of foregoing embodiments, as reaction mixture A part metathesis catalyst in the presence of, make two or more monomer reactions, wherein in the reaction mixture The weight of first monomer and second comonomer and weight ratio are no more than 10:1 or are no more than 9:1 or are no more than 8:1 or are no more than 7: 1 or be no more than 6:1 or be no more than 5:1 or be no more than 4:1 or be no more than 3:1 or be no more than 2:1 or be no more than 1:1.? In some embodiments, other than the first monomer and second comonomer, the reaction mixture also includes additional monomer compound.

Any suitable metathesis catalyst can be employed as the first metathesis catalyst or the second metathesis catalyst, as follows Text is described in more detail.In the above-described embodiment in some embodiments of any one, the first metathesis catalyst and second is answered Decomposition catalyst is organic ruthenium compound, organic osmium compound, organotungsten compounds or organic molybdenum.

Also contemplate product of the additional glycerol ester copolymer as synthetic method disclosed herein and synthesis example.

Synthetic method

At the 5th aspect, present disclose provides the methods for forming glycerol ester copolymer compositions, which comprises (a) Reaction mixture is provided, the reaction mixture includes metathesis catalyst and the monomeric compound by formula (IIIa) expression:

And the monomeric compound that formula is indicated by (IIIb):

Wherein R³¹、R³²And R³³It independently is C_1-24Alkyl or C_2-24Alkenyl, wherein each is optionally replaced by-OH primary Or repeatedly, precondition is R³¹、R³²And R³³At least one of be C_2-24Alkenyl is optionally replaced by-OH primary or more It is secondary；And R⁴¹、R⁴²And R⁴³It independently is C_1-24Alkyl or C_2-24Alkenyl, wherein each is optionally replaced by-OH primary or more Secondary, precondition is R⁴¹、R⁴²And R⁴³At least one of be 8- nonenyl, 8- decene base, 8- undecenyl, 12 carbon of 8- Alkenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 17 carbon trialkenyl of 8,11,14- or 8,11,14- 18 Carbon trialkenyl；And (b) in the presence of metathesis catalyst, make by formula (IIIa) monomeric compound indicated and by formula (IIIb) monomeric compound indicated is reacted to form glyceride polymer composition.

Variable R³¹、R³²And R³³There can be any suitable value.In some embodiments, R³¹、R³²And R³³It independently is C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R³¹、R³²And R³³Solely It is on the spot undecyl, tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R³¹、R³² And R³³It independently is pentadecyl or heptadecyl.In the above-described embodiment in described in any item some embodiments, R³¹、R³²And R³³It independently is C_2-24Alkenyl or C_9-24Alkenyl or C_11-24Alkenyl or C_13-24Alkenyl or C_15-24Alkenyl.Some In such embodiment, R³¹、R³²And R³³It independently is 8- heptadecene base, 10- heptadecene base, 17 carbon diene of 8,11- 17 carbon trialkenyl of base or 8,11,14-.In some other such embodiments, R³¹、R³²And R³³It independently is 8- 17 17 carbon trialkenyl of carbene base, 17 carbon dialkylene of 8,11- or 8,11,14-.

Variable R⁴¹、R⁴²And R⁴³There can be any suitable value.Some implementations described in any one of foregoing embodiments In scheme, R⁴¹、R⁴²And R⁴³In zero, one or two independently be C_1-24Alkyl or C_11-24Alkyl or C_13-24Alkyl or C_15-24Alkyl.In some such embodiments, R⁴¹、R⁴²And R⁴³In zero, one or two independently be undecyl, Tridecyl, pentadecyl or heptadecyl.In some other such embodiments, R⁴¹、R⁴²And R⁴³In zero, one It is a or two independently are pentadecyl or heptadecyl.Described in any item some embodiments in the above-described embodiment In, R⁴¹、R⁴²And R⁴³In zero, one or two independently be C_2-24Alkenyl or C_9-24Alkenyl or C_11-24Alkenyl or C_13-24 Alkenyl or C_15-24Alkenyl.In some such embodiments, R⁴¹、R⁴²And R⁴³In zero, one or two independently be 8- Heptadecene base, 17 carbon trialkenyl of 10- heptadecene base, 17 carbon dialkylene of 8,11- or 8,11,14-.Some other Such embodiment in, R⁴¹、R⁴²And R⁴³In zero, one or two independently be 8- heptadecene base, 8,11- 17 17 carbon trialkenyl of carbon dialkylene or 8,11,14-.

In some other embodiments described in any one of foregoing embodiments, R⁴¹、R⁴²And R⁴³In one, two It is a or three independently are C_2-15Alkenyl or C_2-14Alkenyl or C_2-13Alkenyl or C_2-12Alkenyl or C_5-12Alkenyl.Some such In embodiment, R⁴¹、R⁴²And R⁴³In one, two or three independently be 8- nonenyl, 8- decene base, 8- endecatylene Base, 10- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon of 8,11- Dialkylene, 8,11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 8,11,14- ten 18 carbon trialkenyl of seven carbon trialkenyls or 8,11,14-.In some other such embodiments, R⁴¹、R⁴²And R⁴³In one It is a, two or three independently be 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon of 8,11- Dialkylene, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11,14- pentadecane three Alkenyl, 18 carbon trialkenyl of 16 carbon trialkenyl of 8,11,14-, 17 carbon trialkenyl of 8,11,14- or 8,11,14-.Some another In outer such embodiment, R⁴¹、R⁴²And R⁴³In one, two or three independently be 8- nonenyl, 8- endecatylene Base, 12 carbon dialkylene of 8,11-, 14 carbon dialkylene of 8,11- or 8,11,14- pentadecane trialkenyl.

The glycerol ester copolymer formed by method disclosed herein can have any suitable molecular weight.In above-mentioned implementation In some embodiments of any of scheme, glycerol ester copolymer has in 4,000g/mol to 150,000g/mol or 5, 000g/mol to 130,000g/mol or 6,000g/mol to 100,000g/mol or 7,000g/mol to 50,000g/mol, Or the weight average molecular weight within the scope of 8,000g/mol to 30,000g/mol or 8,000g/mol to 20,000g/mol.

The glycerol ester copolymer formed by method disclosed herein can have the monomeric compound indicated by formula (IIIa) Any suitable ratio for the structural unit that the structural unit of formation is formed with the monomeric compound indicated by formula (IIIb).Above-mentioned In the above-mentioned some embodiments of any one of embodiment, the structural unit that is formed of monomeric compound that is indicated by formula (IIIa) The quantity ratio of the structural unit formed with the monomeric compound indicated by formula (IIIb) is no more than 10:1 or no more than 9:1 or not Or more than 8:1 or no more than 7:1 or no more than 6:1 or no more than 5:1 or no more than 4:1 or no more than 3:1 be no more than 2:1 is no more than 1:1.Glycerol ester copolymer disclosed herein may include not by formula (IIIa) or the singulation of formula (IIIb) Close the additional structure units that object is formed.

Or in some other embodiments described in any one of foregoing embodiments, as reaction mixture In the presence of the metathesis catalyst of a part, make two or more monomer reactions, wherein the monomer indicated by formula (IIIa) The weight of compound and the monomeric compound indicated by formula (IIIb) or no more than 10:1 or no more than 9:1 do not surpass with weight ratio It crosses 8:1 or is no more than 7:1 or is no more than 6:1 or is no more than 5:1 or is no more than 4:1 or is no more than 3:1 or is no more than 2: 1 or be no more than 1:1.In some embodiments, described anti-other than the monomeric compound of formula (IIIa) and formula (IIIb) Answering mixture also includes additional monomer compound.

Any suitable metathesis catalyst can be used, as described in greater detail below.Appoint in the above-described embodiment In one some embodiment, metathesis catalyst is organic ruthenium compound, organic osmium compound, organotungsten compounds or has Machine molybdenum compound.

Method disclosed herein may include the additional chemical and physical treatment of gained glycerol ester copolymer.For example, one In a little embodiments, resulting glycerol ester copolymer is subjected to hydrogenating completely or partially, such as diene selective hydration.In addition, In some embodiments, unused metathesis catalyst and/or metathesis catalyst residue are recycled.In aforementioned implementation In some embodiments of any one of scheme, resulting glycerol ester polymer is subjected to causing the method for isomerization, such as alkene Isomerization.

On the other hand, present disclose provides the methods for forming glycerol ester copolymer, which comprises (a) provides anti- Mixture is answered, the reaction mixture includes the first metathesis catalyst and the natural oil glyceride of unsaturated alkenyl；And (b) in the presence of first metathesis catalyst, keep the unsaturated natural oil glyceride and unsaturated alkenyl natural Oil glyceride is reacted in the presence of the first metathesis catalyst to form the glycerol ester copolymer.

In some embodiments, the natural oil glyceride of unsaturated alkenyl by the second unsaturated natural oil glyceride with it is short Reaction of olefine in the presence of the second metathesis catalyst is formed.In some such embodiments, unsaturated alkenyl Natural oil glyceride has than the second low molecular weight of unsaturated natural oil glyceride.According to the embodiment above, it can be used and appoint What suitable short-chain olefin.In some embodiments, short-chain olefin C_2-14Alkene, C_2-12Alkene, C_2-10Alkene, C_2-8Alkene Hydrocarbon, C_2-6Alkene or C_2-4Alkene.In some such embodiments, short-chain olefin may include at least one of following: second Alkene, propylene, 1- butylene, 2- butylene, isobutene, 1- amylene, 2- amylene, 1- hexene, 2- hexene, 3- hexene, cyclohexene, 2- first Base -1- butylene, 2- methyl-2-butene, 3-methyl-1-butene, cyclopentene, 2- Methyl-1-pentene, 3- Methyl-1-pentene, 4- first Base -1- amylene, 2- methyl -2- amylene, 3- methyl -2- amylene, 4- methyl -2- amylene or 4,4 dimethyl -2- amylenes.Some In addition in such embodiment, short-chain olefin is ethylene, propylene, 1- butylene, 2- butylene or isobutene.In some embodiment party In case, short-chain olefin is ethylene.In some embodiments, short-chain olefin is propylene.In some embodiments, short-chain olefin For 1- butylene.In some embodiments, short-chain olefin is 2- butylene.

As described above, the mixture of various linear chain or branched chain low molecular weight olefins can be used in the reaction, it is expected Metathesis product distribution.?

In one embodiment, the mixture of butylene (1- butylene, 2- butylene and optionally isobutene) can be used as low molecule Alkene is measured, so that low cost, commercially available raw material are provided, rather than a kind of purifying source of specific butylene.Such low cost Mixed butenes feedstock usually uses normal butane and/or iso-butane to dilute.

First unsaturated natural oil glyceride and the second unsaturated natural oil glyceride are available from any suitable natural oil Source.In some embodiments of any one of foregoing embodiments, the unsaturated natural oil glyceride of the first or second, which derives from, plants Object oil, such as seed oil.In some embodiments, vegetable oil is rapeseed oil, canola oil (erucic acid rape seed oil), coconut Oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, soybean oil, sunflower oil, linseed oil, Palm-kernel oil, tung oil, Jatropha oil, mustard oil, penny cress oil, shepherd's purse indigo plant seed oil or castor oil.In some embodiments, it plants Object oil is palm oil.In some embodiments, vegetable oil is soybean oil.In some embodiments, vegetable oil is canola oil.

The glycerol ester copolymer formed by method disclosed herein can have any suitable molecular weight.In above-mentioned implementation In some embodiments of any of scheme, glycerol ester copolymer has in 4,000g/mol to 150,000g/mol or 5, 000g/mol to 130,000g/mol or 6,000g/mol to 100,000g/mol or 7,000g/mol to 50,000g/mol, Or the weight average molecular weight within the scope of 8,000g/mol to 30,000g/mol or 8,000g/mol to 20,000g/mol.

In some embodiments, glycerol ester copolymer has 2,000g/mol to 150,000g/mol or 3,000g/ The number-average molecular weight (Mn) of mol to 30,000g/mol or 4,000g/mol to 20,000g/mol.

The glycerol ester copolymer formed by method disclosed herein can have the structural unit that is formed by the first monomer with By any suitable ratio for the structural unit that second comonomer is formed.The above-mentioned some embodiment party of any one in the above-described embodiment In case, the quantity ratio of the structural unit that is formed by the first monomer and the structural unit formed by second comonomer no more than 10:1 or Or no more than 9:1 or no more than 8:1 or no more than 7:1 or no more than 6:1 or no more than 5:1 or no more than 4:1 do not surpass It crosses 3:1 or is no more than 2:1 or is no more than 1:1.Glycerol ester copolymer disclosed herein may include not by the first monomer or The additional structure units that two monomers are formed.

Alternatively, in some other embodiments described in any one of foregoing embodiments, as reaction mixture A part metathesis catalyst in the presence of, make two or more monomer reactions, wherein in the reaction mixture The weight of first monomer and second comonomer and weight ratio are no more than 10:1 or are no more than 9:1 or are no more than 8:1 or are no more than 7: 1 or be no more than 6:1 or be no more than 5:1 or be no more than 4:1 or be no more than 3:1 or be no more than 2:1 or be no more than 1:1.? In some embodiments, other than the first monomer and second comonomer, the reaction mixture also includes additional monomer compound.

Any suitable metathesis catalyst can be employed as the first metathesis catalyst or the second metathesis catalyst, as follows Text is described in more detail.In the above-described embodiment in some embodiments of any one, the first metathesis catalyst and second is answered Decomposition catalyst is organic ruthenium compound, organic osmium compound, organotungsten compounds or organic molybdenum.

Method disclosed herein may include the additional chemical and physical treatment of gained glycerol ester copolymer.For example, one In a little embodiments, resulting glycerol ester copolymer is subjected to hydrogenating completely or partially, such as diene selective hydration.

Derived from renewable resource

In certain embodiments, the compound for any of aspect disclosed herein or embodiment can derive From renewable resource, such as derived from various natural oils or their derivative.Any suitable method is used to can by this class Regenerated resources prepare these compounds.

Olefin metathesis, which is provided, is converted to the possible mode of one of alkene and ester for certain natural oil raw materials, described Alkene and ester can be used in a variety of applications, or can further chemical modification and use in numerous applications.In some embodiment party In case, composition (or component of composition) can be formed by renewable raw materials, such as pass through natural oil and/or their fatty acid Or the renewable raw materials that the metathesis reaction of aliphatic ester derivatives is formed.When the compound comprising carbon-to-carbon double bond is in double decomposition When undergoing metathesis reaction in the presence of catalyst, the fracture of some or all of original carbon-to-carbon double bond, and formed newly Carbon-to-carbon double bond.The product of such anti-object of double decomposition includes carbon-to-carbon double bond at different locations, and can provide has with chemistry The unsaturated organic compound of characteristic.

The natural oil of wide scope or their derivative can be used for such metathesis reaction.The example packet of suitable natural oil Include but be not limited to vegetable oil, algae oil, fish oil, tallow, tall oil, derivatives of these oil, group any in these oil Close etc..The representative non-limiting example of vegetable oil include Canola Oil (canola oil), high erucic acid rapeseed oil, coconut oil, Corn oil, cottonseed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, soybean oil, sunflower oil, linseed oil, palm fibre Palmitic acid benevolence oil, tung oil, Jatropha oil, canola, penny cress oil, shepherd's purse indigo plant seed oil, cannabis oil and castor oil.The generation of animal tallow Table non-limiting example includes lard, tallow, poultry fat, butter fat and fish oil.Tall oil is the by-product of wood pulp manufacture Product.In some embodiments, natural oil or natural oil raw material include one or more unsaturated glycerides (for example, unsaturated Triglycerides).In some such embodiments, natural oil raw material include the total weight based on the natural oil raw material at least 50 weight % or at least 60 weight % or at least 70 weight % or at least 80 weight % or at least 90 weight % or at least 95 One or more unsaturated triglycerides of weight % or at least 97 weight % or at least 99 weight %.

Natural oil may include canola oil or soybean oil, and the soybean oil for such as refining, decolourizing and be deodorized is (that is, RBD soybean Oil).Soybean oil generally comprises the sweet of about 95 weight percent (weight %) or more (for example, 99 weight % or more) fatty acid Oily three esters.Main fatty acid in the polyol ester of soybean oil includes but is not limited to saturated fatty acid, such as palmitinic acid (16 Acid) and stearic acid (stearic acid) and unsaturated fatty acid, such as oleic acid (9- octadecenoic acid), linoleic acid (9,12- ten eight Carbon dienoic acid) and linolenic acid (9,12,15- octatecatrienoic acid).

Such natural oil or derivatives thereof includes the ester of various unsaturated fatty acids, such as triglycerides.Such fatty acid Characteristic and concentration according to oily source, and it is different in some cases according to type.In some embodiments, day So one or more esters of the oil comprising oleic acid, linoleic acid, linolenic acid or any combination of them.When such aliphatic ester double decomposition When, form noval chemical compound.For example, using certain short-chain olefins such as ethylene, propylene or 1- butylene, and natural oil in double decomposition In the embodiment of ester including oleic acid, a certain amount of 1- decene and 1- decylenic acid (or their ester) are formed in the product.

In some embodiments, the natural oil can undergo various preprocessing process, and the preprocessing process can help In them for the practicability in certain metathesis reactions.Available preprocess method is described in U.S. Patent Application Publication 2011/0113679, in 2014/0275595 and 2014/0275681, all three patents are herein incorporated by reference, such as With being fully expounded herein.

In certain embodiments, before metathesis reaction, can to natural oil and/or unsaturated polyol ester raw material into Row is processed so that natural oil is more suitable for subsequent metathesis reaction.In one embodiment, natural oil and/or unsaturation are polynary The processing of alcohol ester include remove can the active catalyst poison of potential reduction metathesis catalyst, such as peroxide.For subtracting The natural oil of few catalyst poison and/or the non-limiting example of unsaturated polyol ester material processing are included in PCT/ It is described in US2008/09604, PCT/US2008/09635 and U.S. Patent Application Serial Number 12/672,651 and 12/672,652 Those of, it is incorporated by reference and is incorporated herein.In certain embodiments, natural oil and/or unsaturated polyol ester are former Material is heat-treated by following process: the temperature higher than 100 DEG C is heated the raw material to when oxygen is not present, and in the temperature The lower time for keeping being enough to reduce catalyst poison in raw material.In other embodiments, temperature is between about 100 DEG C and 300 DEG C Between, between about 120 DEG C and 250 DEG C, between about 150 DEG C and 210 DEG C, or between about 190 DEG C and 200 DEG C. In one embodiment, it is realized by being bubbled natural oil and/or unsaturated polyol ester raw material with nitrogen there is no oxygen, Wherein nitrogen is pumped into feedstock processing container with the pressure of about 10atm (150psig).

In certain embodiments, under conditions of being enough to reduce catalyst poison in raw material, pass through catalyst poison Chemical reaction is chemically treated natural oil and/or unsaturated polyol ester raw material.In certain embodiments, reducing agent is used Or cation-inorganic base compositions-treated raw material.The non-limiting example of reducing agent includes disulfate, boron hydride, phosphine, sulphur Thiosulfate and their combination.

In certain embodiments, natural oil and/or unsaturated polyol ester raw material are handled to remove with adsorbent Remove catalyst poison.In one embodiment, raw material is handled with the combination of hot method and adsorbent method.Another In a embodiment, chemically raw material is handled with the combination of adsorbent method.In another embodiment, locate Reason is related to part hydrogenation treatment, to change the anti-of natural oil and/or unsaturated polyol ester raw material using metathesis catalyst Ying Xing.When discussing various metathesis catalysts, the Additional non-limiting example of feedstock processing has been also described below.

In some embodiments, after carrying out any optional pretreatment to natural oil raw material, in metathesis reaction React natural oil raw material in the presence of metathesis catalyst.In some other embodiments, in metathesis reaction In device, in the presence of metathesis catalyst, make beta-unsaturated esters (for example, unsaturated glyceride, such as unsaturated triglyceride) Reaction.These beta-unsaturated esters can be the component of natural oil raw material, or can derive from other sources, for example, from early stage The ester generated in the metathesis reaction of progress.

In some embodiments, winterization is carried out to natural oil.Winterization refers to following procedure: (1) removing wax and other non- What components of triglycerides, the naturally occurring high melting point triglyceride of (2) removing, and (3) removing were formed during part hydrogenates High melting point triglyceride.Winterization can by including for example being realized with known method including controllable rate cooling oil, thus The component of higher melt to be removed from the oil is caused to crystallize.Then the high melting point component of crystallization is removed from the oil by filtering, To obtain winterized oil.Winterization soybean oil can be from Cargill, and Incorporated (Minneapolis, Minn.) is commercially available.

The double decomposition of the condition and reactor design of such metathesis reaction and suitable catalyst reference alkene ester is such as It is described below.The discussion is herein incorporated by reference, as fully expounding herein.

Olefin metathesis

In some embodiments, one of unsaturated monomer or a variety of can be spread out by metathesized natural oil or natural oil It is prepared by biology.Term " double decomposition " or " double decomposition " can refer to a variety of different reactions comprising but be not limited to cross metathesis, Self-metathesis, ring-opening methathesis, ring opening metathesis polymerization (" ROMP "), ring closing metathesis (" RCM ") and acyclic diene subdivision It solves (" ADMET ").Any suitable metathesis reaction can be used, depend on desired product or product mixtures.

In some embodiments, after carrying out any optional pretreatment to natural oil raw material, in metathesis reaction React natural oil raw material in the presence of metathesis catalyst.In some other embodiments, in metathesis reaction In device, in the presence of metathesis catalyst, make beta-unsaturated esters (for example, unsaturated glyceride, such as unsaturated triglyceride) Reaction.These beta-unsaturated esters can be the component of natural oil raw material, or can derive from other sources, for example, from early stage The ester generated in the metathesis reaction of progress.In certain embodiments, in the presence of metathesis catalyst, natural oil or not Saturated ester can be reacted with itself experience metathesis.

In some embodiments, double decomposition, which is included in the presence of metathesis catalyst, keeps natural oil raw material (or another Beta-unsaturated esters) reaction.In some such embodiments, double decomposition is included in the presence of metathesis catalyst, makes natural oil One of raw material or a variety of unsaturated glycerides (such as unsaturated triglyceride) reaction.In some embodiments, insatiable hunger It include one of oleic acid, linoleic acid, linoleic acid or their combination or a variety of esters with glyceride.In some other embodiments In, unsaturated glyceride is the product of part hydrogenation and/or the double decomposition (as described above) of another unsaturated glyceride.

In some embodiments, unsaturated polyol ester is partially hydrogenated before double decomposition.For example, in some implementations In scheme, unsaturated polyol ester is partially hydrogenated, to realize about before making partially hydrogenated polyol ester be subjected to double decomposition 120 or smaller iodine number (IV).

Metathesis process can be enough to generate desired metathesis product it is any under the conditions of carry out.For example, art technology Stoichiometry, atmosphere, solvent, temperature and pressure may be selected to generate desired product and keep undesirable by-product minimum in personnel Change.In some embodiments, metathesis process can carry out under an inert atmosphere.Similarly, it is supplied in reagent as gas In embodiment, inert gas diluent can be used in the air-flow.In such implementation is raised difficult questions, inert atmosphere or inert gas are dilute Releasing agent is usually inert gas, it is intended that gas is not interacted with metathesis catalyst to prevent to be catalyzed on significance degree.Example Such as, the non-limiting example of inert gas includes helium, neon, argon gas, methane and nitrogen, be used alone or use each other with And it is used together with other inert gases.

The reactor design of metathesis reaction can change depending on various factors, and the factor includes but is not limited to react rule Mould, reaction condition (heat, pressure etc.), the characteristic of catalyst, the characteristic and raw materials used property of the substance reacted in reactor Matter.Suitable reactor can be designed by those skilled in the art according to correlative factor, and be incorporated into refining process, all As disclosed herein those.

Generally occur there are one or more metathesis catalysts in metathesis reaction disclosed herein. Any suitable metathesis catalyst can be used in such method.Metathesis catalyst in the reaction may include that catalysed metathesis is anti- Any catalyst or catalyst system answered.It can be used alone or be applied in combination with one or more additional catalysts any known Or it is expected that exploitation metathesis catalyst.The example of metathesis catalyst and process conditions is described in US 2011/0160472, It is herein incorporated by reference, unlike with any inconsistent disclosure or definition in this specification the case where Under, it should be subject to this disclosure or definition.The many metathesis catalyst mesh being described in US 2011/0160472 Preceding be purchased from adds Materia, Inc. (Pasadena, Calif.).

In some embodiments, metathesis catalyst includes Grubbs type olefin metathesis catalyst and/or is spread out by it Raw entity.In some embodiments, metathesis catalyst include first generation Grubbs type olefin metathesis catalyst and/or Entity as derived from it.In some embodiments, metathesis catalyst includes the catalysis of second generation Grubbs type olefin metathesis Agent and/or entity as derived from it.In some embodiments, metathesis catalyst includes first generation Hoveyda-Grubbs type Olefin metathesis catalyst and/or entity as derived from it.In some embodiments, metathesis catalyst includes the second generation Hoveyda-Grubbs type olefin metathesis catalyst and/or entity as derived from it.In some embodiments, double decomposition is urged Agent includes the one or more ruthenium Cabbeen metathesis catalysts sold by Materia, Inc. (Pasadena, California) And/or one or more entities derived from such catalyst.What teaching content used according to the present invention derives from Materia, Inc. representative metathesis catalyst includes but is not limited to those of following product number and their combination sale: being produced Product number C823 (catalog number (Cat.No.) 172222-30-9), product number C848 (catalog number (Cat.No.) 246047-72-3), product number C601 (mesh Record 203714-71-0), product number C627 (catalog number (Cat.No.) 301224-40-8), product number C571 (catalog number (Cat.No.) 927429- 61-6), product number C598 (catalog number (Cat.No.) 802912-44-3), product number C793 (catalog number (Cat.No.) 927429-60-5), product are compiled Number C801 (catalog number (Cat.No.) 194659-03-9), product number C827 (catalog number (Cat.No.) 253688-91-4), product number C884 (catalog number (Cat.No.) 900169-53-1), product number C833 (catalog number (Cat.No.) 1020085-61-3), product number C859 (catalog number (Cat.No.) 832146-68- 6), product number C711 (catalog number (Cat.No.) 635679-24-2), product number C933 (catalog number (Cat.No.) 373640-75-6).

In some embodiments, the metathesis catalyst includes molybdenum and/or tungsten carbene complex and/or derives since then The entity of class complex compound.In some embodiments, metathesis catalyst include Schrock type olefin metathesis catalyst and/ Or entity as derived from it.In some embodiments, metathesis catalyst include molybdenum high oxidation state alkylidene complex and/ Or especially derivative entity.In some embodiments, metathesis catalyst include tungsten high oxidation state alkylidene complex and/ Or especially derivative entity.In some embodiments, metathesis catalyst includes molybdenum (VI).In some embodiments, multiple Decomposition catalyst includes tungsten (VI).In some embodiments, the metathesis catalyst include such as one in following documents or The alkylidene complex containing molybdenum and/or tungsten of type described in more persons: (a) Angew.Chem.Int. edits Engl., and 2003, 42,4592-4633；(b) Chem.Rev., 2002,102,145-179；And/or (c) Chem.Rev., 2009,109,3211- 3226, each of described document, which is incorporated by reference, to be incorporated herein, unlike with it is any in this specification In the case where inconsistent disclosure or definition, it should be subject to this disclosure or definition.

Suitable homogeneous metathesis catalyst includes transition metal halide or oxo halide (for example, WOCl₄Or WCl₆) With alkanisation co-catalyst (Me₄) or the combination of alkylidene (or carbene) complex of transition metal (especially Ru or W) Sn.This It a bit include the first generation and second generation Grubbs catalyst, Grubbs-Hoveyda catalyst etc..Suitable alkylidene catalyst tool There is general formula structure: M [X¹X²L¹L²(L³)_n]=C_m=C (R¹)R²

Wherein M is the 8th group 4 transition metal, L¹、L²And L³For neutral electron donor ligand, n is 0 (so that L³It may not deposit ) or 1, m 0,1 or 2, X¹And X²For anion ligand, and R¹And R²Independently selected from H, alkyl, substituted alkyl, contain Hetero atom alkyl, substituted alkyl containing hetero atom and functional group.X¹、X²、L¹、L²、L³、R¹And R²In any two or More kinds of any one of cyclic groups and these groups of being formed could attach to carrier.

First-generation Grubbs catalyst belongs to this kind of classification, wherein m=n=0 and to n, X¹、X²、L¹、L²、L³、R¹And R² Specific choice is made, is such as described in U.S. Patent Application Publication 2010/0145086, all metathesis catalysis are related to The teaching content of agent is herein incorporated by reference.

Second generation Grubbs catalyst also has an above-mentioned general formula, but L¹For carbene ligands, the wherein carbon of carbene and N, O, S Or P atom flanks, and preferably flanks with two N atoms.In general, carbene ligands are a part of cyclic group.Suitable second It is also seen in the patent disclosure of ' 086 for the example of Grubbs catalyst.

In another kind of suitable alkylidene catalyst, L¹For matching by force in such as first generation and second generation Grubbs catalyst Position neutral electron donor, and L²And L³To match in the weak coordinating neutral electron donor for the heterocyclic group form being optionally substituted Body.Therefore, L²And L³For pyridine, pyrimidine, pyrroles, quinoline, thiophene etc..

In another kind of suitable alkylidene catalyst, a pair of of substituent group is used to form two-or tridentate ligand, such as double It sees, dialkanyl oxide or alkyldiketonate.Grubbs-Hoveyda catalyst is the subset of such catalyst, wherein L²And R² Connection.In general, neutral oxygen or nitrogen are coordinated to metal, while being also keyed to carbon (it is α-, β-or γ-relative to the carbon of carbene), To provide bidentate ligand.The example of suitable Grubbs-Hoveyda catalyst is seen in the patent disclosure of ' 086.

Some examples of workable suitable catalyst are provided only with flowering structure:

Solid-supported catalyst can be used for metathesis process.Solid-supported catalyst is the system comprising catalyst and carrier, is urged Agent and carrier associate.Exemplary association between catalyst and carrier can by catalyst or its any part and carrier or its Chemical bond or weak interaction (for example, hydrogen bond, donor-acceptor interaction) between any part and occur.Carrier is intended to wrap Include any material suitable for supported catalyst.In general, solid-supported catalyst acts on liquid phase or vapor-phase reactant and product Solid-phase catalyst.Exemplary carrier is polymer, silica or aluminium oxide.Such solid-supported catalyst can be used for flowing over Journey.Solid-supported catalyst can simplify the purifying of product and the recycling of catalyst, so that recycling catalyst may be facilitated more.

The selected metathesis catalyst of any available quantity is used equally for the process.For example, unsaturated polyol ester with The molar ratio of catalyst can be in the range of about 5:1 be to about 10,000,000:1 or about 50:1 to 500,000:1.In some implementations In scheme, metathesis catalyst/starting composition double bond of about 1ppm to about 20ppm or about 2ppm to about 15ppm amount is used (i.e. in terms of moles/mole).

In some embodiments, metathesis reaction is urged by the system comprising both transition metal and nontransition metal component Change.Most active and most number catalyst systems is derived from the 6th race and the 8th group 4 transition metal, such as tungsten, molybdenum and ruthenium.

In certain embodiments, before carrying out metathesis reaction, metathesis catalyst is dissolved in solvent.At certain In a little such embodiments, selected solvent can be selected as to be substantially inert relative to metathesis catalyst.For example, substantially Inert solvent includes but is not limited to: aromatic hydrocarbons, benzene,toluene,xylene etc.；Halogenated aryl hydrocarbon, such as chlorobenzene and dichloro-benzenes；Rouge Race's solvent, including pentane, hexane, heptane, hexamethylene etc.；And chloralkane, methylene chloride, chloroform, dichloroethanes etc.. In some embodiments, solvent includes toluene.

In other embodiments, before carrying out metathesis reaction, metathesis catalyst is insoluble in solvent.On the contrary, For example, catalyst can be with natural oil or beta-unsaturated esters pulp, wherein natural oil or beta-unsaturated esters are in a liquid state.Under these conditions, When separating solvent, can from the method elimination solvent (such as toluene) and eliminate downstream olefin loss.In other embodiment party In case, metathesis catalyst can be added in natural oil or beta-unsaturated esters (for example, as spiral in (rather than pulp) in solid form Conveyer charging).

In certain embodiments, ligand can be added in metathesis reaction mixture.In many realities using ligand It applies in scheme, ligand is chosen to make the molecule of catalyst stabilization, and therefore can provide the conversion number of raising for catalyst.? Under some cases, reaction selectivity and product distribution is can be changed in ligand.The example of workable ligand includes Lewis base ligands, Such as, but not limited to: trialkyl phosphine, such as tricyclohexyl phosphine and tributylphosphine；Triaryl phosphine, such as triphenylphosphine；Diaryl alkane Base phosphine, such as diphenylcyclohexyl phosphine；Pyridine, such as 2,6- lutidines, 2,4,6- trimethylpyridines；And other Louis This basic ligands, such as phosphine oxide and single oxygen Asia phosphonium salt.During double decomposition, the addition for improving catalyst life also may be present Agent.

In some cases, metathesis reaction temperature can be rate control variable, and wherein temperature is selected for can connect The rate received provides desired product.In certain embodiments, metathesis reaction temperature be greater than about -40 DEG C, greater than about -20 DEG C, Greater than about 0 DEG C or greater than about 10 DEG C.In certain embodiments, metathesis reaction temperature is below about 200 DEG C or below about 150 DEG C or be below about 120 DEG C.In some embodiments, metathesis reaction temperature is between about 0 DEG C and about 150 DEG C, or between Between about 10 DEG C and about 120 DEG C.

Metathesis reaction can be run under any desired pressure.General it is desired that maintaining high enough to making cross metathesis Reagent is held in the gross pressure in solution.Therefore, as the molecular weight of cross metathesis reagent increases, low pressure range usually subtracts It is small, the reason is that the boiling point of cross metathesis reagent increases.Gross pressure can be selected as greater than about 0.1 atmospheric pressure (10kPa), In some embodiments, greater than about 0.3 atmospheric pressure (30kPa) or greater than about 1 atmospheric pressure (100kPa).In general, reaction pressure Power no more than about 70 atmospheric pressure (7000kPa), in some embodiments, no more than about 30 atmospheric pressure (3000kPa).With In the non-restrictive illustrative pressure limit of metathesis reaction be about 1 atmospheric pressure (100kPa) to about 30 atmospheric pressure (3000kPa).In certain embodiments, it may be desirable to run metathesis reaction under reduced atmosphere.Decompression or true can be used Empty condition removes alkene (because its generate in metathesis reaction), to drive double decomposition lesser towards volatility is formed Product direction balance.For the self-metathesis of natural oil, as metathesis reaction carries out, decompression can be used for removing C₁₂Or more The alkene of lightweight, including but not limited to hexene, nonene and dodecylene and by-product, including but not limited to cyclohexadiene and Benzene.The removing of these species can be used as the side for driving reaction to carry out towards the direction for forming diglyceride group and crosslinking triglycerides Formula.

In some embodiments, after double decomposition occurs, metathesis catalyst is removed from products therefrom.It removes A kind of method of catalyst is to handle metathesis product with adsorbent bed.The representative adsorbent used for content according to this teaching Including but not limited to carbon, silica, silica-alumina, aluminium oxide, clay, magnesium silicate (such as Magnesols), with Synthetic silica adsorbent that trade name TRISYL is sold by W.R.Grace&Co., diatomite, polystyrene, macropore (MP) Resin etc. and their mixture.In one embodiment, the adsorbent is clay bed.Clay bed will adsorb subdivision Catalyst is solved, and after filtration step, metathesis product can be sent to separative unit and be used to be further processed.Separative unit It may include distillation unit.In some embodiments, distillation can be carried out for example by steam stripping metathesis product.Distillation can By being in a reservoir bubbled mixture, usually it is stirred, is may include typical distillation filling (for example, random or structuring) Column in make mixture and air flow contacts, be evaporated in vacuo, or in evaporator such as scraped film evaporator evaporate light materials come It completes.In general, steam stripping will carry out under reduced pressure and at a temperature in the range of about 100 DEG C to 250 DEG C.Temperature may depend on Such as vacuum level used, wherein high vacuum allows lower temperature, and allows the more effective and complete of volatile matter Separation.

In another embodiment, adsorbent is water-soluble phosphine reagent, such as tris hydroxymethyl phosphine (THMP).THMP can be with Relative to catalyst, the ratio equal at least about 1:1,5:1,10:1,25:1 or 50:1 molar ratio is added.Known liquid-can be passed through Liquid extracts mechanism, decants water phase in organic phase, catalyst is separated with water-soluble phosphine.In other embodiments, catalyst point From including washing or extracting the mixture (for example, specifically (but be not only) wherein reagent at least portion with polar solvent Ground is divided to be dissolved in the embodiment in polar solvent).The representative polar solvent that teaching content uses according to the present invention includes but not It is limited to water, alcohol (such as methanol, ethyl alcohol etc.), ethylene glycol, glycerol, DMF, multifunctional polar compound comprising but be not limited to gather Ethylene glycol and/or glyme, ionic liquid etc. and their combination.In some embodiments, mixture water is extracted It takes.In some embodiments, when phosphite ester at least partly hydrolyzable (for example, in some embodiments, will have low The phosphite ester of molecular weight comprising but it is not limited to phosphorous acid front three base ester, phosphorous acid triethyl group ester and their combination) As reagent, mixture, which is washed with water, can be converted to phosphite ester corresponding acid.In other embodiments, metathesis product It can be contacted with reactant to deactivate or extracting catalyst.

It can be straight chain or cricoid internal olefin compounds that metathesis reaction, which is also resulted in and to be formed,.If double decomposition polyol ester It is hydrogenated completely or partially, then straight chain and cyclic olefin will usually be completely or partially converted into corresponding saturated straight chain and ring-type Hydrocarbon.Straight chain/cyclic olefin and saturated straight chain/cyclic hydrocarbon can be retained in double decomposition polyol ester, or can be used a kind of or more Kind of known steam stripping technique removes from double decomposition polyol ester or partially removes them, it is known that steam stripping technique include but unlimited In Wiping film evaporation, falling film evaporation, rotary evaporation, steam stripping, vacuum distillation etc..

Multiple continuous metathesis reaction steps can be used.For example, glyceride copolymer products can be made in the following way It is standby: to react unsaturated polyol ester in the presence of metathesis catalyst, to form the first glyceride copolymer products.Then The first glyceride copolymer products can be made to react in self-metathesis reaction, to form another double decomposition glycerol ester copolymer Product.Alternatively, the first glyceride copolymer products can be made to react in cross-metathesis with unsaturated polyol ester, with Form another glyceride copolymer products.In addition in alternative form, transesterification product, alkene and/or ester can be in double decompositions Further double decomposition in the presence of catalyst.Such multiple and/or sequence metathesis reaction can execute repeatedly on demand, and at least One or many, this depends on processing/composition requirement as understood by those skilled in the art.As used herein, " glyceride is total Copolymer products " may include the product for having been subjected to a double decomposition and/or multiple double decomposition.These processes can be used to form double decomposition Dimer, double decomposition trimer, double decomposition tetramer, double decomposition pentamer and more advanced metathesis oligomers are (such as multiple Decompose hexamer, double decomposition haptamer, double decomposition octamer, double decomposition nonamer, ten polymers of double decomposition and than double decomposition ten The more advanced oligomer of polymers).These processes can be repeated as many times as desired (such as 2 to about 50 times or 2 to about 30 times or 2 To about 10 times or 2 to about 5 times or 2 to about 4 times or 2 times or 3 times), it may include such as 2 to about 100 bonding bases to provide Group or 2 to about 50 or 2 to about 30 or 2 to about 10 or 2 to about 8 or 2 to about 6 binding groups or 2 to about 4 bonding bases The desired metathesis oligomers or polymer of group or 2 to about 3 binding groups.In certain embodiments, it is expected that using by As the unsaturated polyol ester of reactant or the blend of unsaturated polyol ester and C in metathesis reaction_2-14Alkene, More preferably C_2-6Alkene, more preferably C₄The glycerol that the cross metathesis of alkene and their mixture and isomers generates Ester copolymer product prepares another glyceride copolymer products.It alternatively, can will be by unsaturated polyol ester or unsaturation The blend and C of polyol ester_2-14Alkene, preferably C_2-6Alkene, more preferably C₄Alkene and their mixture and isomery The metathesis product that the cross metathesis of body generates is combined with the blend of unsaturated polyol ester or unsaturated polyol ester, and And further double decomposition is to generate another glyceride copolymer products.

In some embodiments, glycerol ester copolymer can be hydrogenated (for example, hydrogenation completely or partially), to change It is apt to the stability of oil or changes its viscosity or other characteristics.For hydrogenating the representative art of unsaturated polyol ester in this field In be known and have been discussed herein.

In other embodiments, glycerol ester copolymer can be used as and one or more fabric care benefit agents and/or knit The blend that object softens active material uses.

Hydrogenation:

In some embodiments, unsaturated polyol ester is partially hydrogenated before it is subjected to metathesis reaction.Insatiable hunger Part hydrogenation with polyol ester reduces the number of double bonds that can be used for subsequent metathesis reaction.In some embodiments, will Unsaturated polyol ester double decomposition hydrogenates glycerol ester copolymer (for example, part to form glycerol ester copolymer, and then Or completely hydrogenated) to form hydrogenating glycerol ester copolymer.

Hydrogenation can be carried out according to any known method for hydrogenating such as vegetable oil containing double bond compound.In some implementations In scheme, to unsaturated polyol ester, natural in the presence of having utilized hydrogen electronation to be the Raney nickel of the state of activation Oil or glycerol ester copolymer are hydrogenated.Carry Ni hydrogenation catalysts commercial example include with trade name " NYSOFACT ", " NYSOSEL " and " NI 5248D " (derive from Englehard Corporation, Iselin, N.H.) those of buys.It is additional Carrying Ni hydrogenation catalysts includes with trade name " PRICAT 9910 ", " PRICAT 9920 ", " PRICAT9908 ", " PRICAT 9936 " is those of commercially available (derived from Johnson Matthey Catalysts, Ward Hill, Mass.).

In some embodiments, hydrogenation catalyst includes such as nickel, copper, palladium, platinum, molybdenum, iron, ruthenium, osmium, rhodium or iridium.? The combination of metal can be used.Available catalyst can be heterogeneous or homogeneous.In some embodiments, catalyst is to carry nickel Catalyst or sponge ni-type catalyst.

In some embodiments, hydrogenation catalyst include be arranged on carrier by hydrogen electronation for activation shape The nickel (that is, reduced nickel) of state.In some embodiments, carrier includes porous silica (for example, diatomite (kieselguhr), diatomite (infusorial), diatomite (diatomaceous) or silicon earth (siliceous )) or aluminium oxide earth.Catalyst is characterized in that higher nickel surface area/g nickel.

In some embodiments, by the particle of nickel-loaded catalyst be scattered in comprising hardening triacylglycerol, edible oil or In the protection medium of tallow.In an exemplary embodiment, nickel-loaded catalyst is dispersed with the level of about 22 weight % nickel In protection medium.

Hydrogenation can be intermittent or carries out in a continuous process and can be part hydrogenation or completely hydrogenated.At representative In method of having a rest, the headspace of the reaction vessel of stirring is vacuumized, and reaction vessel is made to be packed into material (example to be hydrogenated Such as, RBD soybean oil or the RBD soybean oil of double decomposition).Then desired temperature is heated the material to.In general, temperature is at about 50 DEG C To 350 DEG C, in the range of for example, about 100 DEG C to 300 DEG C or about 150 DEG C to 250 DEG C.Desired temperature can be for example with Hydrogen Vapor Pressure And change.In general, higher gas pressure will need lower temperature.In a separate container, hydrogenation catalyst is weighed into mixed It closes in container and is beaten it in a small amount of material (for example, RBD soybean oil or RBD soybean oil of double decomposition) to be hydrogenated.When When material to be hydrogenated reaches desired temperature, the slurries of hydrogenation catalyst are added in reaction vessel.Then by hydrogen pump Enter in reaction vessel to realize desired H₂Gas pressure.In general, H₂Gas pressure is in about 15psig to 3000psig or example In the range of such as from about 15psig to 150psig.As gas pressure increases, it may be necessary to more dedicated high voltage processing equipment.? Under the conditions of these, hydrogenation starts and temperature is allowed to increase to desired hydrogenation temperature (for example, about 120 DEG C to 200 DEG C), should Temperature with the cooling reaction mass of cooling coil for example, by being maintained.When reaching desired degree of hydrogenation, make reaction mass It is cooled to desired filtration temperature.

The amount of hydrogenation catalyst is selected generally according to Multiple factors, type including hydrogenation catalyst for example used, The amount of hydrogenation catalyst used, the degree of unsaturation of material to be hydrogenated, desired hydrogenation rate, desired degree of hydrogenation (example Such as, as surveyed by iodine number (IV)), the purity of reagent and H₂Gas pressure.In some embodiments, hydrogenation catalyst with About 10 weight % or less, for example, about 5 weight % or less or about 1 weight % or less amount use.

After hydrogenation, known technology (such as passing through filtering) can be used to remove hydrogenating catalytic from hydrogenated product Agent.In some embodiments, hydrogenation catalyst using plate frame filter such as can from Sparkler Filters, Inc., Conroe Tex is those of commercially available to be removed.In some embodiments, filtering is executed by means of pressure or vacuum.To change Kind strainability, can be used filtration adjuvant.Filtration adjuvant can be directly appended in metathesis product or can be applied it to Filter.The representative example of filtration adjuvant includes diatomite, silica, aluminium oxide and carbon.In general, filtration adjuvant is with about 10 Weight % or less, for example, about 5 weight % or less or about 1 weight % or less amount use.Other filtering skills also can be used Art and filtration adjuvant remove hydrogenation catalyst used.In other embodiments, using being strained after centrifugation to product Analysis is to remove hydrogenation catalyst.

Potential processing aid and/or impurity

Unsaturated polyol ester known to those skilled in the art, those of is specifically derived or is synthesized by natural source and include The microcomponent of wide scope and impurity.These may include tocopherol, carrotene, free fatty acid, dissociative glycerin, sterol, sulphur For glucoside, phosphatide, peroxide, aldehyde and other oxidation products etc..It is present in impurity in the natural oil of wide scope and anti- Product is answered to be described in " Bailey ' s Industrial Oil and Fat Products ", the 5th edition, Y.H.Hui is edited, Wiley (1996) and references cited therein；" Lipid Analysis in Oil and Fats ", R.J.Hamilton is edited, Chapman Hall (1998) and references cited therein；And " Flavor Chemistry of Fats and Oils ", D.B.Min and T.H.Smouse are edited, American Oil Chemists In Society (1985) and references cited therein.

It is claimed and glyceride described in this specification it will be appreciated by those skilled in the art that preparing claims Any one of these methods of copolymer can lead to final glycerol ester copolymer and claims are claimed and this explanation There are impurity in composition/consumer goods described in book, this is for using glycerol ester copolymer.These non-limiting example packets Metathesis catalyst is included, it includes metal as described herein and ligands；Solid-based catalysis agent carrier includes silica or oxidation Aluminium；Oily pretreating agent comprising reducing agent, cationic inorganic alkali composition and adsorbent；The structure generated by oily Grape berry； Processing aid comprising solvent such as aromatic hydrocarbon, halogenated aryl hydrocarbon, aliphatic solvents and chloralkane；Aliphatic olefin comprising oneself Alkane, nonene, dodecylene and cyclohexadiene；Catalyst agent for killing and/or catalyst remover comprising adsorbent is such as viscous Soil, carbon, silica, silica-alumina, aluminium oxide, clay, magnesium silicate, synthetic silica, diatomite, polyphenyl second Alkene, macropore (MP) resin or water-soluble phosphine reagent such as tris hydroxymethyl phosphine (THMP)；Polar solvent comprising water, alcohol (such as Methanol, ethyl alcohol etc.), ethylene glycol, glycerol, DMF, multifunctional polar compound comprising but be not limited to polyethylene glycol and/or glycol Dimethyl ether or ionic liquid；Phosphite ester hydrolysising by-product；Hydrogenation catalyst comprising metal and ligand as described herein；Gu Loadization hydrogenation catalyst carrier comprising porous silica or aluminium oxide；Protection activates and/or removes hydrogenation catalyst Auxiliary agent；And/or water.

It is claimed and the glycerol ester copolymer described in the present specification may include following processing aid And/or impurity:

Table 1:Potential processing aid and/or impurity in glycerol ester copolymer

Table 2:The potential processing aid and/or impurity in the consumer goods generated by glycerol ester copolymer

Present specification provide content under, due to using glycerol ester copolymer, be claimed and this Following processing aid and/or impurity can be introduced or generated during the storage of composition and/or the consumer goods described in the specification:

Consumer products promoter material

Composition disclosed in this invention may include additional adjunct ingredients, comprising: bleach-activating, is passed surfactant Send reinforcing agent, builder, chelating agent, dye transfer inhibitor, dispersing agent, enzyme and enzyme stabilizers, catalytic metal complexes, polymerization Object dispersing agent, clay and dirt removal/anti-redeposition agents, brightening agent, foam inhibitor, dyestuff, additional fragrance and fragrance deliver body System, structure elasticizing agent, fabric softener active, fabric care benefit agents, anionic surfactant scavenger, carrier, Hydrotropic agent, processing aid, structural agent, anti-agglomerating, coating, formaldehyde scavenger and/or pigment.The composition of applicant Other embodiments do not include one of following promoter material or a variety of: bleach-activating, surfactant, delivering enhancing Agent, builder, chelating agent, dye transfer inhibitor, dispersing agent, enzyme and enzyme stabilizers, catalytic metal complexes, polymer dispersion Agent, clay and dirt removal/anti-redeposition agents, brightening agent, foam inhibitor, dyestuff, additional fragrance and perfume delivery systems, structure Elasticator, fabric softener active, fabric care benefit agents, anionic surfactant scavenger, carrier, hydrotropic Agent, processing aid, structural agent, anti-agglomerating, coating, formaldehyde scavenger and/or pigment.The clear property of these annexing ingredients and Its levels of incorporation will depend on the property of the physical form and operation applied by it of composition.However, when in the presence of a kind of or When a variety of auxiliary agents, such one or more auxiliary agents can exist as detailed below.It is the non-limiting of suitable additional adjuvants below List.

Delivery enhancer: composition may include the delivery enhancer of about 0.01% to about 10% based on the composition.Such as this Used in text, such term refers to any polymerization of the deposition significantly increased on fabric care benefit agents to fabric in washing process The combination of object or polymer.Preferably, delivery enhancer can be cation or amphoteric polymer.The cationic charge of polymer is close Degree about 0.05 milliequivalent/gram to about 23 milliequivalents/gram in the range of.Can by by the net charges of each repetitive unit divided by The molecular weight of the repetitive unit, calculates charge density.In an aspect, charge density from about 0.05 milliequivalent/gram become Change to about 8 milliequivalents/gram.Positive charge can be located on the main chain of polymer or on the side chain of polymer.For containing amine monomers Polymer, charge density depend on carrier pH.For these polymer, charge density can be measured at pH 7.Deposition The non-limiting example of reinforcing agent is polysaccharide, protein and the synthetic polymer of cation or both sexes.Cationic polysaccharide includes sun Ion fiber element derivative, cationic guar derivative, chitosan and derivative and cationic starch.Sun from Sub- polysaccharide has about 50,000 to about 2,000,000, preferably about 100,000 to about 1,500,000 molecular weight.Suitable cation Polysaccharide includes cation cellulose ether, especially cationic hydroxyethyl cellulose and cationic hydroxypropylcellulose.Cationic hydroxyl The example of alkylcellulose includes those of entitled Polyquaternium10 of INCI, such as with trade name Ucare Those of Polymer JR 30M, 400 JR, JR 125, LR 400 and the sale of 400 polymer of LK；Polyquaternium 67, such as with Those of trade name Softcat SK TM sale, it is all these by Amerchol Corporation (Edgewater, NJ) It is commercially available；And polyquaternium 4, such as by trade name Celquat H200 and Celquat L-200 purchased from National Starch Those of and Chemical Company (Bridgewater, NJ).Other suitable polysaccharide include using glycidyl C₁₂- C₂₂Alkyl dimethyl ammonium chloride quaternized hydroxyethyl cellulose or hydroxypropyl cellulose.This saccharoidal example includes having The polymer of INCI title polyquaternium 24, such as Amerchol Corporation (Edgewater, NJ) is with trade name Those of sale of Quaternium LM 200.Cationic starch, which refers to, to be chemically modified to provide and have in pH3 aqueous solution The starch of the starch of net positive charge.This chemical modification includes but is not limited to that amino and/or ammonium are added in starch molecule. The non-limiting example of these ammoniums may include substituent group, such as trimethyl hydroxypropyl ammonium chloride, dimethyl stearyl hydroxypropyl Ammonium chloride or dimethyl dodecyl base hydroxypropyl ammonium chloride.Starch source before chemical modification can be selected from a variety of sources, including block Stem, beans, cereal and cereal.The non-limiting example of the starch in this source may include cornstarch, wheaten starch, paddy shallow lake Powder, waxy corn starch, oat starch, tapioca, waxy barley, waxy rice starch, seitan rice starch, glutinous rice Starch, amylopectin, potato starch, tapioca, oat starch, sago starch, sweet tea rice starch or their mixing Object.The non-limiting example of cationic starch includes cationic maize starch, cation cassava starch, cationic potato shallow lake Powder or their mixture.Cationic starch may include amylase, amylopectin or maltodextrin.Cationic starch can wrap Include one or more additional modifications.For example, these modifications may include crosslinking, stability reaction, phosphorylation, hydrolysis work With, crosslinking.Stability reaction may include alkylation and esterification.Cationic starch suitable for the present composition can be with commodity NameIt is commercially available from Cerestar, and with trade name2A is commercially available from National Starch and Chemical Company.Cationic galactomannan includes cation guar gum or cationic locust bean gum.Cationic melon The example of your glue is the quaternary ammonium derivative of hydroxypropyl guar gum, such as with trade name Jaguar C13 and Jaguar Excel by Rhodia, Inc. (Cranbury, NJ) are sold and are sold by Aqualon (Wilmington, DE) with trade name N-Hance Those.

In an aspect, it can be used synthetic cationic polymers as delivery enhancer.The molecular weight of these polymer It can be within the scope of about 2,000 to about 5,000,000 kD.Synthetic polymer includes the synthesis addition polymers with general formula structure

Wherein each R¹¹Hydrogen, C can independently be₁-C₁₂Alkyl, substituted or unsubstituted phenyl, be substituted or not by Substituted benzyl ,-OR_eOr-C (O) OR_e, wherein R_eIt can be selected from hydrogen, C₁-C₂₄Alkyl and their combination.In one aspect, R¹¹It can be hydrogen, C₁-C₄Alkyl or-OR_eOr-C (O) OR_e

Wherein each R¹²It can be independently selected from hydrogen, hydroxyl, halogen, C₁-C₁₂Alkyl ,-OR_e, it is substituted or unsubstituted Phenyl, substituted or unsubstituted benzyl, carbocylic radical, heterocycle and their combination.In an aspect, R¹²It is optional From hydrogen, C₁-C₄Alkyl and their combination.

Each Z can independently be hydrogen, halogen；Linear chain or branched chain C₁-C₃₀Alkyl, nitrilo-, N (R¹³)₂-C(O)N(R¹³)₂；- NHCHO (formamide)；-OR¹³、-O(CH₂)_nN(R¹³)₂、-O(CH₂)_nN⁺(R¹³)₃X^–、-C(O)OR¹⁴；-C(O)N-(R¹³)₂；-C (O)O(CH₂)_nN(R¹³)₂、-C(O)O(CH₂)_nN⁺(R¹³)₃X、-OCO(CH₂)_nN(R¹³)₂、-OCO(CH₂)_nN⁺(R¹³)₃X^-、-C(O) NH(CH₂)_nN(R¹³)₂、-C(O)NH(CH₂)_nN⁺(R¹³)₃X^-、-(CH₂)_nN(R¹³)₂、-(CH2)_nN⁺(R¹³)₃X^-,

Each R¹³It can be independently selected from hydrogen, C₁-C₂₄Alkyl, C₂-C₈Hydroxyalkyl, benzyl, substituted benzyl and they Combination；

Each R¹⁴It can be independently selected from hydrogen, C₁-C₂₄Alkyl,

Wherein m is 0 to 1,000, and R¹⁵It can be independently selected from hydrogen, C_l-C₆Alkyl and their combination；

And their combination.

X can be water soluble anion, and wherein n can be about 1 to about 6.

Z be further selected from the non-aromatic azacyclo- comprising quaternary ammonium ion, the heterocycle comprising N- oxide portions, one of them or The heterocycle comprising aromatics nitrogen that multiple or nitrogen-atoms can be quaternized；Wherein at least one nitrogen comprising aromatics nitrogen can aoxidize for N- The heterocycle of object；And their combination.The non-limiting example of addition polymerizable monomers comprising heterocycle Z unit includes 1- ethylene Base -2-Pyrrolidone, 1- vinyl imidazole, quatemized vinylimidazol, 2- vinyl -1,3- dioxolane, 4- ethylene Base -1- cyclohexene -1,2- epoxides and 2- vinylpyridine, 2- vinylpyridine N-oxide, 4-vinylpridine, 4-vinylpridine N- oxide.

Can be made can be for-NHCHO unit (formyl the non-limiting example of the Z unit of cationic charge is formed in situ Amine).Formulator can prepare polymer or copolymer comprising formyl amine unit, some of then to hydrolyze to form vinylamine etc. Valence object.

The polymer or copolymer also may include one or more cyclic polymer units derived from ring polycondensation monomer.Ring The example of shape polymerized monomer is dimethyldiallylammonium.

Suitable copolymer can be made of one or more cationic monomers, and the cationic monomer is selected from: metering system Sour N, N- dialkyl aminoalkyl ester, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl amino Base Arrcostab, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methyl Acrylic acid N, N- dialkyl aminoalkyl ester, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized third Olefin(e) acid N, N- dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl amino Base alkyl methacrylamides, vinylamine and its derivative, allylamine and its derivative, vinyl imidazole, quartenized vinyl base Imidazoles and poly (dially dialkyl) ammonium chloride and their combination, the second comonomer are selected from: acrylamide, N, N- dioxane Base acrylamide, Methacrylamide, N, N- dialkyl methacrylamides, acrylic acid C₁-C₁₂Arrcostab, acrylic acid C₁-C₁₂ Hydroxy alkyl ester, polyacrylic acid alkylidene diol ester, methacrylic acid C₁-C₁₂Arrcostab, methacrylic acid C₁-C₁₂Hydroxy alkyl ester, Polymethylacrylic acid alkylidene diol ester, vinyl acetate, vinyl alcohol, vinyl formamide, vinyl acetamide, vinyl alkane Base ether, vinylpyridine, vinyl pyrrolidone, vinyl imidazole and derivative, acrylic acid, methacrylic acid, metering system Sour methyl esters, itaconic acid, fumaric acid, 3- allyl oxygroup -2- hydroxyl -1- propane sulfonic acid (HAPS) and its salt, allyl sulphonic acid and Its salt, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamido propyl methanesulfonic acid (AMPS) and its salt and they Combination.Polymer may optionally be crosslinking.Suitable cross-linking monomer include ethylene glycol diacrylate, divinylbenzene and Butadiene.

In an aspect, synthetic polymer is poly- (acrylamide-co-diallyldimethylammonium chloride), poly- (third Acrylamide-methacryiamidopropyl trimethyl ammonium chloride), poly- (acrylamide-co-methacrylic acid N, N- diformazan ammonia Base ethyl ester), poly- (acrylamide-co-acrylic acid N, N- dimethylaminoethyl), poly- (hydroxy-ethyl acrylate-copolymerization-methyl-prop Olefin(e) acid dimethylaminoethyl), poly- (hydroxypropyl acrylate-copolymerization-dimethylaminoethyl methacrylate), poly- (acrylic acid hydroxypropyl Ester-copolymerization-methacryiamidopropyl trimethyl ammonium chloride), poly- (acrylamide-co-diallyidimethylammonium chloride Ammonium-copolymerization-acrylic acid), poly- (acrylamide-methacryiamidopropyl trimethyl ammonium chloride-copolymerization-acrylic acid).It is other The example of suitable synthetic polymer is polyquaternium -1, polyquaternium -5, polyquaternium -6, polyquaternium -7, polyquaternium - 8, polyquaternium -11, polyquaternium -14, Merquat 280, polyquaternium -28, polyquaternium -30, polyquaternium -32 and poly- Quaternary ammonium salt -33.

Other cationic polymers include polyvinylamine and its derivative and Polyamide amine-epoxychloropropane (PAE) tree Rouge.In an aspect, polythene derivative can be for the amide derivative of the trade name Lupasol SK polyethyleneimine sold Object.It further include alkoxylate polyethylene imine；Alkyl polyethylene imine and quaternized polyethyleneimine.These polymer are retouched It is set forth in by L.L.Chan, in the wet-strength resins and their application of TAPPI Press (1994) editors.By relative to polycyclic The size exclusion chromatography and RI of oxidative ethane reference substance measure, and the weight average molecular weight of the polymer is typically about 10,000 To about 5,000,000, or about 100,000 to about 200,000, or about 200,000 to about 1,500,000 dalton.The shifting used Dynamic is mutually 20% methanol in Waters Linear Ultrahdyrogel chromatographic column in 0.4M MEA, 0.1M NaNO₃, 3% Solution in acetic acid, 2 series connection.Chromatographic column and detector are maintained at 40 DEG C.Flow rate set is 0.5mL/min.

On the other hand, deposition aid may include poly- (acryloyl amine-n-dimethyl amino ethyl acrylate) and its season Ammonium derivative.In this regard, the deposition aid can be for trade nameBy BTC Specialty Those of Chemicals (BASF Group, Florham Park, N.J.) sale.In one embodiment, deposition aid is Cationic acrylamide acidic group homopolymer is sold with trade name Rheovis CDE by CIBA.

Surfactant: product of the invention can include about the surfactant of 0.11 weight % to 80 weight %.One A aspect, such composition can include about the surfactant of 5 weight % to 50 weight %.Surfactant used can be yin Ionic type, nonionic type, amphoteric ion type, amphoteric type or cation type, or may include the compatible of these types Mixture.

If fabric care product is laundry detergent compositions, anion and nonionic surfactant are generallyd use.It is another Aspect generallys use cationic surfactant if fabric care product is fabric softener.

Available anionic surfactant itself can be several different type.For example, higher fatty acids is water-soluble Property salt (i.e. " soap ") is available anionic surfactant in confectionery composition.This includes alkali metal soap, such as comprising about 8 to about 24 carbon atoms, or even about 12 to about 18 carbon atoms higher fatty acids sodium salt, sylvite, ammonium salt and alkanol ammonium salt.Soap It can be made by the Directly saponification of fat and oil, or be made by the neutralization of free fatty acid.Especially useful is derivative From the sodium salt and sylvite of coconut oil and the mixture of the fatty acid of tallow, that is, the soda soap or potash soap of tallow and coconut oil.

Available anionic surfactant include the water soluble salt of organic reaction of Salmon-Saxl product, especially alkali metal, ammonium and Alkylol ammonium (e.g., monoethanolamine or triethanol ammonium) salt, the reaction product have comprising about 10 in its molecular structure to about The alkyl and sulfonic group or sulfate group of 20 carbon atoms.(moieties of aryl group are included in term " alkyl ".) The example of such synthetic surfactant is alkyl sulfate and alkyl alkoxy sulfate, especially by sulfated higher alcohols (C₈-C₁₈Those of a carbon atom) obtain.

Other available anionic surfactants of this paper include: in fatty acid group comprising about 6 to 20 carbon atoms simultaneously And include α-sulfonated fatty acid ester water soluble salt of about 1 to 10 carbon atom in ester group；It include about 2 to 9 in carboxyl groups The water soluble salt of 2- acyloxy alkane -1- sulfonic acid in a carbon atom and paraffin section comprising about 9 to about 23 carbon atoms；Packet The water soluble salt of alkene sulfonic acid ester containing about 12 to 24 carbon atoms；And in alkyl group comprising about 1 to 3 carbon atom and It include β-alkyloxy alkane sulfonates of about 8 to 20 carbon atoms in paraffin section.

In another embodiment, anionic surfactant can include: C₁₁-C₁₈Alkylbenzene sulfonate surface-active Agent；C₁₀-C₂₀Alkyl sulfate surfactant；The C that average degree of alkoxylation is 1 to 30₁₀-C₁₈Alkyl alkoxy sulfate table Face activating agent, wherein alkoxy includes C₁-C₄Chain and their mixture；The alkyl sulfate surfactant of mid-chain branched； The alkyl alkoxy sulfate surfactant for the mid-chain branched that average degree of alkoxylation is 1 to 30, wherein alkoxy includes C₁- C₄Chain and their mixture；The C that average degree of alkoxylation is 1 to 5₁₀-C₁₈Alkyl alkoxy carboxylates；C₁₂-C₂₀Methyl esters sulphur Acid salt surfactant；C₁₀-C₁₈Alpha-alkene sulfonate surfactant；C₆-C₂₀Sulfosuccinate surfactant；And Their mixture.

Other than anionic surfactant, Fabrid care composition of the invention also may include non-ionic surface active Agent.Composition of the invention may include based on the weight of composition at most about 30%, or about 0.01% to about 20%, or The nonionic surfactant of about 0.1% to about 10%.In one embodiment, nonionic surfactant may include ethoxy Base nonionic surfactant.

It is formula R (OC suitable for this paper₂H₄) n OH the pure and mild ethoxylated alkylphenol of ethoxylation, wherein R be selected from comprising The aliphatic hydrocarbon group of about 8 to about 20 carbon atoms and wherein alkyl group include the alkyl phenyl base of about 8 to about 12 carbon atoms Group, and the average value of n is about 5 to about 15.Material can also be the pure and mild propoxylated alkylphenols of propoxylation, and can make With the mixture of this propoxylation and ethoxylation material.In addition, such material can be propenoxylated and ethoxylation 's.

Suitable nonionic surfactant is formula R¹(OC₂H₄)_nThose of OH, wherein R¹For C₁₀-C₁₆Alkyl group or C₈–C₁₂Alkyl phenyl group, and n is 3 to about 80.In one aspect, especially useful material is C₉-C₁₅Alcohol and every mol of alcohol The condensation product of about 5 to about 20 moles of ethylene oxide.

Other suitable nonionic surfactants include polyhydroxy fatty acid amide (such as N- methyl N -1- deoxy-glucose base Coconut oleoyl amine and N- methyl N -1- deoxyglucityl oleamide) and alkyl polysaccharide.

Fabrid care composition of the invention may include based on the weight of composition at most about 30%, or about 0.01% to About 20%, or the cationic surfactant of about 0.1% to about 20%.For purposes of the present invention, cationic surface is living Property agent include can deliver those of fabric care benefit.The non-limiting example packet of available cationic surfactant It includes: fatty amine；Quaternary surfactant；With imidazoline quaternary ammonium salt substance.

In some embodiments, available cationic surfactant has following general formula (IV):

Wherein:

(a)R₁And R₂It is each independently selected from: C₁–C₄Alkyl；C₁–C₄Hydroxy alkyl；Benzyl；--(C_nH_2nO)_xH, in which:

I.x has the value of about 2 to about 5；

Ii.n has the value of about 1-4；

(b)R₃And R₄Respectively are as follows:

i.C₈–C₂₂Alkyl；Or

ii.R₃For C₈-C₂₂Alkyl and R₄It is selected from: C₁-C₁₀Alkyl；C₁–C₁₀Hydroxy alkyl；Benzyl；--(C_nH_2nO)_xH, In:

1.x has 2 to 5 value；And

2.n has the value of 1-4；And

(c) X is anion.

Fabric softener active: composition of the invention may include by weight of the composition at most about 30% or about 0.01% to about 20%, again or about 0.1% to about 20% fabric softener active.Liquid fabric care Composition, such as fabric softening compositions are (such asOr LENOR^TMContained in those) it is living comprising fabric-softening Property substance.A kind of fabric softener active includes cationic surfactant.

The example of cationic surfactant includes quaternary ammonium compound.Exemplary quaternary ammonium compound includes that alkylation is quaternized Close object, ring or cyclic quaternary ammonium compound, aromatic quaternary ammonium compounds, two quaternary ammonium compounds, alkoxylated quaternized conjunction object, amide groups Amine quaternary ammonium compound, ester quaternary ammonium compound and their mixture.Finally fabric softening compositions (being suitable for retail) will include Based on the weight of the final composition about 1.5% to about 50% or about 1.5% to about 30% or about 3% to about 25% or The fabric-softening active material of about 3 to about 15%.In one embodiment, fabric softening compositions are that so-called rinsing is additional Composition.In such embodiment, the composition is substantially free of detersive surfactant, or substantially free of anion Surfactant.In another embodiment, the pH of fabric softening compositions is about pH 3 to about 9.In another embodiment party In case, the pH of fabric softening compositions is about pH 2 to about 3.Usable acid such as hydrochloric acid or formic acid adjust the pH.

In another embodiment, the fabric-softening active material is DEEDMAC (such as two butter acyl ethyl alcohol esters two Ammonio methacrylate).DEEDMAC refers to list and difatty acid ethyl alcohol ester dimethyl quaternary ammonium, straight chain fatty acid, methyl ester and/or Triglycerides (such as derived from animal and/or plant fat and oil, such as butter, palm oil) and methyl diethanolamine form an ester And diester compound, the reaction product for then using alkylating agent quaternized.

In one aspect, fabric softener active is double-(2- ethoxy)-alkyl dimethyl ammonium chloride aliphatic ester, The average chain length of fatty acid part is 16 to 20 carbon atoms, preferably 16 to 18 carbon atoms, and to free fatty acid meter The iodine number (IV) of calculating is 15 to 25 or 18 to 22, or about 19 to about 21 or their combination.Iodine number is according to ISO 3961 Consumed iodine number in grams is reacted in method measurement with the double bond of 100g fatty acid.

In some aspects, fabric-softening active material includes the compound of structure 5:

Wherein R¹⁸And R¹⁹It is each independently C₁₅-C₁₇, and wherein C₁₅-C₁₇It is insatiable hunger and/or saturation, branch or straight It is chain, substituted or unsubstituted.

In some respects, fabric-softening active material includes double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate fatty acid Ester has 1.85 to 1.99 fatty acid part and the molar ratio of amine moiety, the fatty acid part of 16 to 18 carbon atoms The iodine number of average chain length and the fatty acid part to free fatty acid calculated 0.5 to 60.

In some respects, the fabric-softening active material includes the compound of following formula as main active substances

{R_4-m-N⁺-[(CH₂)_n-Y-R¹]_m}A^- (Structure 6)

Wherein each R substituent is hydrogen, short chain C₁-C₆, preferably C₁-C₃Alkyl or hydroxyalkyl such as methyl, ethyl, third Base, ethoxy etc., poly- (C_2-3-Alkoxy) (preferably polyethoxy), benzyl or their mixture；Each m is 2 or 3；Often A n is 1 to about 4, preferably 2；Each Y is-O- (O) C- ,-C (O)-O- ,-NR-C (O)-or-C (O)-NR-；Each R¹In The sum of carbon is C₁₂-C₂₂, preferably C₁₄-C₂₀, when Y is-O- (O) C- or-NR-C (O)-, the sum of described carbon adds one, and each R¹For alkyl or substituted alkyl, and A^-It can be the compatible anion of any softening agent, preferably chloride ion, bromide ion, first Sulfate radical, etherosulfuric acid root, sulfate radical and nitrate anion, more preferably chloride ion or methyl-sulfuric acid root；

In some respects, fabric-softening active material has general formula:

[R₃N⁺CH₂CH(YR¹)(CH₂YR¹)]A^-

Wherein each Y, R, R¹There is meaning same as above with A-.Such compound includes having those of the formula:

[CH₃]₃N⁽⁺⁾[CH₂CH(CH₂O(O)CR¹)O(O)CR¹]C1^(-) (Structure 7)

Wherein each R is methyl or ethyl group, and preferably, each R¹In C₁₅To C₁₉In the range of.Such as this paper institute With may include existing monoesters when being appointed as diester.

The example of preferred DEQA (2) is " propyl " with formula 1,2- bis- (acyloxy) -3- thmethylpropyl ammonium chloride Ester quaternary ammonium fabric softener active.

In some respects, fabric-softening active material has following formula:

[R_4-m-N⁺-R¹ _m]A^- (Structure 8)

Wherein each R, R¹There is meaning same as above with A-.

In some respects, fabric-softening active material has following formula:

Wherein each R, R¹There is definition given above with A-；Each R²For C_1-6Alkylidene group, preferably ethylidene Group；And G is oxygen atom or-NR- group；

In some respects, fabric-softening active material has following formula:

Wherein R¹、R²It is as defined above with G.

In some respects, fabric-softening active material is the fatty acid and two alkylene triamines that such as molecular proportion is about 2:1 Condensation reaction products, the reaction product include following formula compound:

R¹-C(O)-NH-R²-NH-R³-NH-C(O)-R¹ (Structure 11)

Wherein R¹、R²As defined above, and each R³For C_1-6Alkylidene group, preferably ethylene group, and its In can by be added alkylating agent for example dimethyl suflfate optionally by reaction product it is quaternized.

In some respects, preferred fabric-softening active material has following formula:

[R¹-C(O)-NR-R²-N(R)₂-R³-NR-C(O)-R¹]⁺A^- (Structure 12) wherein R, R¹、R²、R³And A^-Institute as above Definition；

In some respects, fabric-softening active material is the fatty acid and hydroxyalkyl Alkylenediamine that molecular proportion is about 2:1 Reaction product, the reaction product include following formula compound:

R¹-C(O)-NH-R²-N(R³OH)-C(O)-R¹ (Structure 13)

Wherein R¹、R²And R³As defined above；

In some respects, fabric-softening active material has following formula:

Wherein R, R¹、R²And A^-As defined above.

On the other hand, fabric softener active can have following formula (structure 15)；

Wherein:

X₁It may include C_2-3Alkyl group includes ethyl group in one aspect；

X₂And X₃It can independently include C_1-6The alkyl or alkenyl group of linear chain or branched chain includes methyl, second in one aspect Base or isopropyl group；

R₁And R₂It can independently include C_8-22The alkyl or alkenyl group of linear chain or branched chain；

It is characterized by:

A and B is in one aspect-O- (C independently selected from-O- (C=O)-,-(C=O)-O- or their mixture =O)-.

The non-limiting example of structure 6 is N, bis- (steroyl oxyethyl)-N, the N- alkyl dimethyl ammonium chlorides of N-, N, the bis- (oxen of N- Oily acyloxyethyl)-N, N- alkyl dimethyl ammonium chloride, N, bis- (steroyl oxyethyl)-N- (2- the ethoxy)-N- methyl formate sulfuric acid of N- Ammonium.

The non-limiting example of structure 7 is 1,2- bis- (stearoyl-oxy) -3- thmethylpropyl ammonium chloride.

The non-limiting example of structure 8 is two alkylidene dimethyl ammoniums, such as two mustard alkyl dimethyl ammonium chlorides, two (hard) oxen Rouge alkyl dimethyl ammonium chloride, two mustard dimethyl ammonium methyl sulfates.The two commercially available alkylidenes two that can be used in the present invention The example of methyl ammonium salt is with trade name472 derive from the two oleyl dimethyl chlorinations of Evonik Corporation Ammonium and the two hard tallow dimethyl ammonium chlorides that Akzo Nobel is derived from trade name Arquad 2HT75.

The non-limiting example of structure 9 is with trade nameThe 1- commercially available from Witco Corporation Methyl-1-stearoyl amido ethyl-2- stearoyl imidazoline methosulfate, wherein R¹For acyclic aliphatic C₁₅-C₁₇Hydrocarbyl group, R²For ethylene group, G is NH group, R⁵For methyl group, and A^-For formate anion.

The non-limiting example of structure 10 is 1- butter amido-ethyl -2- butter acyl imidazoline, wherein R¹For no ring grease Race C₁₅-C₁₇Hydrocarbyl group, R²For ethylene group, and G is NH group.

The non-limiting example of structure 11 is the reaction product of the fatty acid that molecular proportion is about 2:1 and diethylenetriamines, The mixture of reaction products includes N, N "-dialkyl group diethylenetriamines with following formula:

R¹-C(O)-NH-CH₂CH₂-NH-CH₂CH₂-NH-C(O)-R¹

Wherein R¹- C (O) is the commercially available fatty acid of plant or animal origin (as being purchased from Henkel Corporation's223LL or7021) alkyl group, and R²And R³For divalent ethylene Group.

The non-limiting example of structure 12 is the softening agent based on two fatty acyl amido amine with following formula:

[R¹-C(O)-NH-CH₂CH₂-N(CH₃)(CH₂CH₂OH)-CH₂CH₂-NH-C(O)-R¹]⁺CH₃SO₄ ^-Wherein R¹-C(O) For alkyl group, such as can be with trade name222LT is commercially available from Witco Corporation.

The example of structure 12 is the reaction product of the fatty acid that molecular proportion is about 2:1 and N-2- ethoxy ethylene diamine, The mixture of reaction products includes the compound of following formula:

R¹-C(O)-NH-CH₂CH₂-N(CH₂CH₂OH)-C(O)-R¹

Wherein R¹- C (O) is from the commercially available fatty acid of plant or animal origin (as being purchased from Henkel Corporation's223LL or7021) alkyl group.

The example of structure 14 is the diquaternary ammonium compound with following formula:

Wherein R¹Derived from fatty acid, and the compound is purchased from Witco Company.

The non-limiting example of fabric-softening active material comprising structure 15 is dialkylimidazolium quinoline diester compound, Described in compound be N- (2- the ethoxy) -1,2- ethylenediamine being esterified with fatty acid or N- (2- hydroxyisopropyl) -1,2- second The reaction product of diamines and glycolic, wherein the fatty acid is (hydrogenation) tallow acid, PALM FATTY ACID, hydrogenated palm rouge Fat acid, oleic acid, Fatty Acid in Rapeseed, hydrogenation Fatty Acid in Rapeseed or above-mentioned mixture.

It should be appreciated that the combination of above-disclosed softener active is suitable for the present invention.

It should be understood that above-disclosed some softening active materials can be biodegradable into various ingredients, including but not limited to choline, rouge Fat acid, hydroxyalkyl ammonium salt and ammonium compounds.

Contain in nitrogen salt in cation herein, anion A^-It is the compatible anion of any softening agent, electroneutral is provided.Most Commonly, for providing the anion of electroneutral from strong acid, especially halogen ion in these salt, as chloride ion, bromine from Son or iodide ion.However, other anion can be used, such as methyl-sulfuric acid root, etherosulfuric acid root, acetate, formate, sulfate radical, carbon Acid group etc..Chloride ion and methyl-sulfuric acid root are herein preferably as anion A.Anion can also with but less preferably with double electricity Lotus, in this case, A^-Represent half of group.

Fabric care benefit agents

The compositions disclosed herein may include fabric care benefit agents.As used herein, " fabric care benefit agents " are Refer to water-dispersible or water insoluble active ingredient, and the detergent ingredients to clothes and fabric especially cotton clothing object and can be knitted Object provides fabric care benefit, such as fabric-softening, color protection, reduces pilling/fluffing, wear-resistant, crease-resistant, lasting fragrance Etc..

100g/L, preferably less than 10g/L are typically below in distilled water at 25 DEG C of these fabric care benefit agents Solubility.It is believed that the solubility of fabric care benefit agents is greater than 10g/L, it will be remained dissolved in wash liquid, from Without depositing on fabric.

The example that can be used for the water-insoluble fabric care benefit agents of this paper includes dispersibility polyolefin, polymer latex Cream, organosiloxane, fragrance or other active microcapsules and their mixture.Fabric care benefit agents can be lotion, glue The form of the forms such as cream, dispersion, suspension, micella, preferably microemulsion, swollen micelles or latex.As such, they can have The wide particle size range of about 1nm to 100um, preferably about 5nm to 10um.Conventional method can be used to determine for the granularity of microemulsion, such as Use Leeds&Northrup Microtrac UPA classifier.

Emulsifier, dispersing agent and suspending agent can be used.Emulsifier, dispersing agent or flotation reagents and fabric care benefit agents Weight ratio is about 1:100 to about 1:2.Preferably, the weight ratio is in the range of about 1:50 to 1:5.Suitable for preparing polymer cream Liquid or any surfactant of polymer latex emulsion polymerization can be used to prepare water-insoluble fabric care benefit of the invention Agent.Suitable surfactant include anionic surfactant, cationic surfactant and nonionic surfactant or Their mixture.

Siloxanes

Suitable organosiloxane includes but is not limited to (a) nonfunctionalized siloxanes, such as dimethyl silicone polymer (PDMS)； (b) functionalized silicone, such as has the siloxanes of one or more functional groups, and the functional group is selected from consisting of the following Group: amino, amide groups, alkoxy, alkyl, phenyl, polyethers, acrylate, silylation, mercapto propyl, carboxylate, sulfate radical, phosphorus Acid group, quaternized nitrogen and their combination.

In a typical implementation, have at 25 DEG C in about 10CSt to about 2 suitable for the organosiloxane of this paper, Viscosity in 000,000CSt (centistoke) range.In other embodiments, suitable organosiloxane has about at 25 DEG C The viscosity of 10 to about 800,000 centistokes.

(a) dimethyl silicone polymer (PDMS) has been described in " Cosmetics and Toiletries ".They can be Straight chain, branch, cricoid, grafting or crosslinking or cricoid structure.In some embodiments, detergent composition packet PDMS containing the viscosity at 25 DEG C with about 100CSt to about 700,000CSt.

(b) illustrative functionalized silicone includes but is not limited to that amino silicone, amide radical siloxane, siloxanes are poly- Ether, alkylsiloxane, phenyl siloxane and season siloxanes.

Functionalized silicone is suitable for the invention with following general formula:

Wherein

M is 4 to 50,000, preferably 10 to 20,000；

K is 1 to 25,000, preferably 3 to 12,000.

Each R is H or C₁-C₈Alkyl or aryl, preferably C₁-C₄Alkyl, and more preferably methyl；

X is the linking group with following formula:

i)-(CH₂)_p, wherein p is 2 to 6, preferably 2 to 3；

ii)

Wherein q is 0 to 4, preferably 1 to 2；

iii)

Q has following formula:

i)-NH₂、-NH–(CH₂)_r–NH₂, wherein r is 1 to 4, preferably 2 to 3；Or

ii)-(O–CHR₂–CH₂)_s- Z, wherein s is 1 to 100, preferably 3 to 30；Wherein R₂For H or C₁-C₃Alkyl, preferably Ground H or CH₃；And Z is selected from-OR₃、-OC(O)R₃、-CO-R₄–COOH、-SO₃、–PO(OH)₂And their mixture；In addition, Wherein R₃For H, C₁-C₂₆Alkyl or substituted alkyl, C₆-C₂₆Aryl or substituted aryl, C₇-C₂₆Alkylaryl is taken The alkylaryl in generation, it is preferable that R₃For H, methyl, ethyl, propyl or benzyl；R₄For-CH₂Or-CH₂CH₂Group；And

iii)

iv)

Wherein n is 1 to 4, preferably 2 to 3；R₅For C1-C4 alkyl, preferably methyl.

The another kind of organosiloxane that can be used for this paper includes the modified poly-epoxy alkane polysiloxanes with following general formula:

Wherein Q is NH₂Or-NHCH₂CH₂NH₂；R is H or C₁-C₆Alkyl；R is 0 to 1000；M is 4 to 40,000；N be 3 to 35,000；And p and q is the integer independently selected from 2 to 30.

As r=0, the non-limiting example of such polysiloxanes containing polyalkylene oxide is to derive from GE Silicones (Wilton, CT's)L-7622、L-7602、L-7604、L-7500、TLC；Derived from Noveon Inc.'s (Cleveland, OH)SW-12 andDW-18 Siloxanes；And derive from DowThe DC-5097 of (Midland, MI),Other example is WithDerive from Shin Etsu Silicones (Tokyo, Japan).

As r=1 to 1000, the non-limiting example of such organosiloxane is to derive from Noveon, Inc. (Cleveland, OH's)A21 andA-23；Derived from Dow Corning Toray Ltd. (Japan) 'sWith derived from Shin Etsu Corporation (Tokyo, Japan)

The organosiloxane that third class can be used for this paper is the modified poly-epoxy alkane polysiloxanes with following general formula:

Wherein m is 4 to 40,000；N is 3 to 35,000；And p and q is the integer independently selected from 2 to 30；Z is selected from

i.Wherein R₇For C1-C24 alkyl group；

ii.Wherein R₄For CH₂Or CH₂CH₂；

iii.-SO₃

iv.

v.

Wherein R₈For C1-C22 alkyl, and A- is anion appropriate, preferably Cl^-；

vi.

Wherein R₈For C1-C22 alkyl, and A^-For anion appropriate, preferably Cl^-。

Another kind of siloxanes is cationic silicone.These are usually made and making diamines and epoxide reaction.This It a bit can be with trade namePrime、HSSD、A-858 is commercially available (to be purchased from GE Silicones)。

On the other hand, functional silicone polymer may include siloxanes-carbamate.In one aspect, silicon oxygen It includes polysiloxanes (such as the α, ω-two of hydroxy functional group or amine functional group that the synthesis of alkane-carbamate, which includes in its end of the chain, Hydroxyalkyl dimethyl silicone polymer or α, ω-Diaminoalkyl dimethyl silicone polymer or alpha-amido, ω-hydroxyalkyl poly dimethyl Siloxanes) it is reacted with the conventional polycondensation between diisocyanate.It on the other hand, include hydroxyalkyl-functional or ammonia in its end of the chain The organopolysiloxane oligomer of base alkyl functional group can mix in compatible solvents with organic diol or diamines coupling agent.It is described Mixture then can be with di-isocyanate reaction.Siloxanes-carbamate can be with trade name SLM-21200 from Wacker Silicones is commercially available.

One embodiment of the present composition includes organosiloxane lotion, and it includes (usually negative in emulsifier Ionic surface active agent) in the presence of be dispersed in organosiloxane in suitable carrier (usually water).

In another embodiment, organosiloxane is the form of microemulsion.Organosiloxane microemulsion can have Average particle size within the scope of about 1nm to about 150nm, or about 10nm to about 100nm, or about 20nm to about 50nm.Microemulsion is than normal The macro lotion (average particle size is about 1-20 microns) of rule is stablized, and when mixing in product, and products obtained therefrom has preferred clear Clear appearance.Importantly, the emulsifier in composition is dilute when the composition is in typical aqueous cleaning environment It releases, so that microemulsion is no longer kept, and organosiloxane coalesces to form the significant of the average particle size with greater than about 1 micron Bigger drop.It is water-insoluble due to selected organosiloxane or there is limited solubility in water, they will be from It is isolated in wash liquid, to obtain more effective deposition on the fabric, and enhances fabric care benefit.One In a typical immersion wash environment, the composition and excessive water are mixed to form wash liquid, usually have 10:1 extremely Water within the scope of 400:1: the weight ratio of composition.

One typical embodiments of composition include by weight of the composition about 0.01% to about in the carrier 10% organosiloxane and a effective amount of emulsifier." effective quantity " of emulsifier, which refers to, to be enough to generate in carrier, preferably water The amount of organosiloxane microemulsion.In some embodiments, the amount of emulsifier be in every 100 parts by weight organosiloxane about In the range of 5 to about 75 parts, or about 25 to about 60 parts.

The microemulsion generally comprises based on the weight of the microemulsion about 10% to about 70%, or about 25% to about 60% Dispersion organosiloxane；Include based on the weight of the microemulsion about 0.1% to about 30%, or the yin of about 1% to about 20% Ionic surface active agent；Optionally include based on the weight of the microemulsion about 0% to about 3%, or about 0.1% to about 20% it is non- Ionic surface active agent；And surplus is water and optional other carriers.(institute is public above for selected organic siloxane polymer The all that opened does not include PDMS and cationic silicone) suitably form microemulsion；These organosiloxanes are sometimes referred to as " self-emulsifying siloxane ".Emulsifier especially anionic surfactant can be added to help the organosilicon oxygen formed in composition Alkane microemulsion.Optionally, it can be used as washing assisant to provide the nonionic surfactant of decontamination beneficial effect and can also help In the formation and stabilization of microemulsion.In a typical embodiment, the amount of emulsifier is by weight of the composition About 0.05% to about 15%.

Dispersible polyolefinAll dispersible polyolefin for providing fabric care benefit can be employed as combination of the present invention Fabric care benefit agents in object.The polyolefin can be the form of wax, lotion, dispersion or suspension.It can be used for this paper's The example of polyolefin is discussed below.

Polyolefin can be polyethylene, polypropylene, polyisoprene, polyisobutene and copolymer and their combination.It is poly- Alkene can at least partly be modified comprising various functional groups, such as carboxyl, alkylamide, sulfonic acid or amide groups.At one In embodiment, the polyolefin is at least partly carboxy-modified, or is in other words oxidized.

It, can be by using emulsifier, using dispersibility polyolefin as being dispersed in water-bearing media for ease of preparing Polyolefin suspension or lotion introduce.When using lotion, the emulsifier can be any suitable emulsifier, including yin Ion, cation or nonionic surfactant or their mixture.Substantially any suitable surfactant can be employed as Emulsifier of the invention.By using described dispersible poly- to disperse with the emulsifier or suspending agent of 1:100 to about 1:2 ratio Alkene.Preferably, the ratio is in the range of about 1:50 to 1:5.

The polyolefin suspension or lotion may include by weight about 1% to about 60%, or about 10% to about 55%, Or the polyolefin of about 20% to about 50%.

Suitable polyethylene wax can be commercially available from supplier including but not limited to below: Honeywell (the poly- second of A-C Alkene), Clariant (Velustrol lotion) and BASF (LUWAX).

Polymer emulsionPolymer emulsion is usually prepared by emulsion polymerisation process comprising one or more monomers, one Kind or numerous emulsifiers, initiator and those skilled in the art known to other components.Be provided with fabric nursing The polymer emulsion of beneficial effect can be employed as water-insoluble fabric care benefit agents of the invention.Suitable polymer emulsion Non-limiting example includes the monomer for producing polymer emulsion, such as: (1) 100% or pure acrylic acid butyl ester；(2) have The butyl acrylate and butadiene mixture of at least 20% (weight monomer ratio) butyl acrylate；(3) butyl acrylate and small In other monomers other than butadiene of 20% (weight monomer ratio)；(4) there is C6 or greater than the third of C6 alkyl carbon chain Olefin(e) acid Arrcostab；(5) there is C6 or greater than the alkyl acrylate of C6 alkyl carbon chain and less than 50% (weight monomer ratio) Other monomers；(6) Third monomer being added in above-mentioned monomer system (less than the monomer ratio of 20 weight %)；And (7) it Combination.

It is about -120 DEG C to about that the polymer emulsion for being suitable for this paper fabric care benefit agents, which includes glass transition temperature, 120 DEG C, and those of preferably about -80 DEG C to about 60 DEG C.Suitable emulsifier includes anionic surfactant, cation Surfactant, nonionic surfactant and amphoteric surfactant.Suitable initiator includes all suitable for polymer The initiator of the emulsion polymerization effect of latex.The granularity of polymer emulsion can be about 1nm to about 10 μm, and be preferably from about 10nm to about 1 μm.

Oiliness sugar derivatives

For purposes of the present invention, oiliness sugar derivatives includes that can deliver those of fabric care benefit.Oiliness sugar Two kinds of general types in derivative are the liquid or soft solid derivative of following substance: cyclic polyols are (hereinafter referred to as "CEP")；Or reduced sugar (RSE)；It is esterified and/or is etherified by 35% to 100% hydroxyl in CEP or RSE and obtained.Gained Derivative CPE or RSE have and at least two or more be attached separately to C₈To C₂₂Its ester of alkyl or alkenyl chain or Ether.Usual CPE and RSE has 3 or more esters or ether or their combination.

In some embodiments, two or more of CPE or RSE ester or ether can be attached separately to C₈To C₂₂Alkane Base or alkenyl chain.C₈To C₂₂Alkyl or alkenyl chain can be linear chain or branched chain.In some embodiments, about 40% to About 100% hydroxyl group is esterification or etherificate.In some embodiments, the hydroxyl group of about 50% to about 100% is It is esterified or is etherified.

In the present case, term cyclic polyols include the carbohydrate of form of ownership.In some embodiments, CPE and RSE is derived from monosaccharide and disaccharides.The non-limiting example of available monosaccharide includes: xylose；Arabinose；Galactolipin；Fruit Sugar；And glucose.It can be sorbitan with a non-limiting example of sugar.The non-limiting example of available disaccharides It include: sucrose；Lactose；Maltose；And cellobiose.

In some embodiments, CPE or RSE has 4 or more esters or ether.If ring-type CPE is disaccharides, Disaccharides can have three or more esters or ether.In some embodiments, using the sugarcane with 4 or more ester groups Sugar ester；These can be with trade nameFrom The Procter and Gamble Co. (Cincinnati, Ohio) quotient Purchase obtains.If cyclic polyols are reduced sugar, it may be advantageous that the ring of CPE has an ether, preferably in C₁Position It sets；Remaining hydroxyl is esterified with alkyl group.

Polyglycerol ester

All polyglycerol esters (PGE) for providing fabric care benefit can be used as the fabric nursing in the present composition Beneficial agent.Polyglycerol ester is suitable for the invention with following general formula:

Wherein each R has about 10 to about 22 carbon independently selected from the aliphatic ester part comprising carbochain, the carbochain The carbon chain lengths of atom；H；And their combination；Wherein n can be about 1.5 to about 6；Wherein the average esterification % of PGE can be about 20% to about 100%；And wherein PGE can be saturated or unsaturated, or may include their combination.It is commercially available Exemplary PGE include derive from BASFPGO 31K、PGO 104K；Derived from Abitec Corp.'sMPGO、ET；Derived from Danisco'sPGE 382、PGE 55、PGE 60；Derived from Evonik Industries's14、PC 31、 GO 33、GI 34。

Anionic surfactant scavenger

The composition may include anionic surfactant scavenger.Surfactant scavenger is preferably water solubility Cation and/or amphoteric ion scavenger compounds.Cation and the amphoteric ion scavenger compounds that can be used for this paper are usual With quaternized nitrogen-atoms or amine groups.Suitable anionic surfactant scavenger includes but is not limited to monoalkyl quaternary ammonium Compound and its amine precursor, dialkyl quaternary compound and its amine precursor, polymeric amine, poly quaternary ammonium compound and its amine precursor.

BuilderComposition may also comprise about the builder of 0.1 weight % to 80 weight %.The composition one of liquid form As include about 1 weight % to 10 weight % builder component.The composition of particle form generally comprises about 1 weight % to 50 weights Measure the builder component of %.Detergent builders are well known in the art, and may include for example phosphate and it is various it is organic and Inorganic non-phosphorus builder.The water-soluble non-phosphorus organic washing-assisting detergent that can be used for this paper includes various alkali metal, ammonium and substituted ammonium Poly- acetate, carboxylate, polycarboxylate and polyhydroxy sulfonate.The example of poly- acetate builder and polycarboxylate builders is Ethylenediamine tetra-acetic acid, nitrilotriacetic acid, oxygen union II succinic acid, mellitic acid, polycarboxylic acid benzene and citric acid sodium, potassium, lithium, ammonium With substituted ammonium salt.Other polycarboxylate builders are oxygen union II succinate and ether carboxylate lotion-aid combination, the ether Carboxylate builder's composition includes the combination of tartaric acid one succinate and tartaric acid disuccinate.For liquid detergent In builder include citric acid.Suitable nonphosphorus, inorganic builders include silicate, alumino-silicate, borate and carbonate, Such as sodium carbonate and potassium carbonate, sodium bicarbonate and saleratus, concentrated crystal soda and sesquialter potassium carbonate, sodium tetraborate decahydrate and ten Water dipotassium tetraborate and SiO₂Weight ratio with alkali metal oxide is about 0.5 to about 4.0 or the silicic acid of about 1.0 to about 2.4 Sodium and potassium silicate.Also available is alumino-silicate, including zeolite.

Dispersing agentComposition can include about the dispersing agent of 0.1 weight % to about 10 weight %.Suitable water-soluble organic material Material is equal polyacids or co-polymeric acids or their salt, and wherein polybasic carboxylic acid may include at least two being separated by no more than two carbon originals The carboxyl of son.Dispersing agent can also be the alkoxy derivative and/or quaternized derivative of polyamine.

EnzymeComposition may include the detergent enzyme of one or more offer clean-up performances and/or fabric care benefit. The example for being suitable for enzyme includes hemicellulase, peroxidase, protease, cellulase, zytase, lipase, phosphatidase, ester Enzyme, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, ligninase, Pullulanase, tan Sour enzyme, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, arabinosidase, hyaluronidase, chondroitinase, laccase, He Dian Powder enzyme or their mixture.Typical combination can use enzyme such as protease, lipase, cutinase and/or cellulase to be conventional The mixture combined with amylase.Enzyme can be used according to the level that their fields are proposed, such as such as according to supplier The horizontal use that Novozymes and Genencor is recommended.Typical level in composition is about 0.0001% to about 5%.When There are when enzyme, they can be with extremely low level for example, about 0.001% or lower use；Or it can be by them with higher horizontal example Such as from about 0.1% and higher in dusty clothes detergent formulations.According to some consumers to the inclined of " abiotic " detergent Love, composition can be containing enzyme and/or without enzyme.

Dye transfer inhibitorComposition also may include by weight of the composition about 0.0001%, about 0.01%, About 0.05% to about 10%, to about 2% or even to about 1% one or more dye transfer inhibitors, such as polyvinyl pyrrole Pyrrolidone polymer, polyamine N-oxide pllymers, n-vinyl pyrrolidone and N- vinyl imidazole copolymer, polyethylene Base oxazolidone and polyvinyl imidazol or their mixture.

Chelating agentComposition may include the chelating agent for being less than about 5% or about 0.01% to about 3%, such as citrate；Contain The without phosphorus aminocarboxylate of nitrogen, such as EDDS, EDTA and DTPA；Amino phosphonates, such as diethylenetriamine pentamethylene phosphine Acid and ethylenediamine tetramethylene phosphonic acid；Nitrogen-free phosphonate, such as HEDP；And the chelating of nitrogenous or oxygen without phosphorus no carboxylate radical Those of agent, such as with the general category compound of certain macrocyclic N-ligands, such as become known in bleaching catalyst system.

Brightening agentComposition also may include brightening agent (also known as " Optical Bleaching Agent ") and may include showing fluorescence Any compound, including the compound for absorbing ultraviolet light and being re-emitted in the form of " blue " visible light.Available brightening agent Non-limiting example include: talan or 4,4'- diaminobenzil, biphenyl, five-ring heterocycles (such as triazole, pyrazoles Quinoline, oxazole, imidazoles etc.) or hexa-member heterocycle (cumarin, naphthalene amino acid, s- triazine etc.) derivative.Usable cationic brightener, Anionic brightener, nonionic brightening agent, both sexes brightening agent and amphoteric ion brightening agent.Suitable brightening agent includes can be with commodity NameBy the city Ciba Specialty Chemicals Corporation (High Point, NC) Those of sell.

Bleach systemsBleach systems suitable for this paper include one or more bleaching agents.Suitable bleaching agent Non-limiting example includes catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Optical white；Bleaching Enzyme；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source, including perborate and/or percarbonate and they Combination.Suitable bleach-activating includes can fully hydrolyzed ester and can fully hydrolyzed acid imide, such as tetra acetyl ethylene diamine, pungent Acyl caprolactam, benzoyloxybenzenesulfonic acid ester, Nonanoyloxybenzenesulfonate, benzoyl valerolactam, dodecane acyl-oxygen Base benzene sulfonate.Other bleaching agents include the metal complex of transition metal with the ligand with specified stability constant.

Structural agentComposition may include one or more structural agents and thickener.Any a suitable level of structure can be used Agent；Exemplary horizontal include based on the weight of composition about 0.01% to about 20%, about 0.1% to about 10% or about 0.1% to About 3%.The non-limiting example of structural agent suitable for this paper includes the hydroxyl stabilizer of crystallization, trihydroxy glycerol stearate Ester, hydrogenated oil and fat or their modification and their combination.In some respects, the hydroxyl stabilizer of crystallization can be insoluble for water Property waxy substance, including fatty acid, aliphatic ester or fat soap.In other aspects, the hydroxyl stabilizer of crystallization can be castor-oil plant The derivative of oil, such as rilanit special derivative, such as castor wax.The hydroxyl stabilizer of commercially available crystallization includes(deriving from Rheox, Inc).Other structures agent includes thickening structural agent, such as natural gum and other similar polysaccharide, Such as the thickener and rheologic additive of gellan gum, carrageenan and other known type.Exemplary structure agent packet in such Include gum type polymer (such as xanthan gum), polyvinyl alcohol and its derivative, cellulose and its derivates (including cellulose ether and Cellulose esters), tamarind gum (for example including xyloglucan polymer), guar gum, locust bean gum is (in some respects, comprising half Newborn mannosan polymer) and other industrial gummy and polymer.

Structure agent material may also include the material for the delivery of particles comprising beneficial agent that is added to sufficiently suspend, described to pass Send that particle includes polysaccharide, gellan gum, starch, derivatization starch, carrageenan, guar gum, pectin, xanthan gum and theirs is mixed Close object；Modified cellulose, such as hydrocellulose acetic acid esters, hydroxypropyl cellulose, methylcellulose and their mixing Object；Modified protein such as gelatin；Hydrogenation and unhydrided polyolefin and their mixture；Inorganic salts, such as magnesium chloride, Calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate；Clay, such as synthetic hectorite clay, POLARGEL NF and it Mixture；The polysaccharide combined with inorganic salts；Quaternized polymeric materials, such as polyetheramine, alkyl trimethyl ammonium chloride, two Two tallow ammonium chloride of ester；Imidazoles；Non-ionic polymers with the pKa less than 6.0, such as polyethyleneimine, polyethyleneimine Ethoxylate；Polyurethane.Such material is available from CP Kelco Corp. (San Diego, California, USA)； Degussa AG (Dusseldorf, Germany)；BASF AG (Ludwigshafen, Germany)；Rhodia Corp. (Cranbury, New Jersey, USA)；Baker Hughes Corp. (Houston, Texas, USA)；Hercules Corp. (Wilmington, Delaware, USA)；Agrium Inc. (Calgary, Alberta, Canada), ISP (New Jersey, U.S.A.).Structural agent may also include comprising homopolymer and copolymer selected from following cationic monomer: methyl-prop Olefin(e) acid N, N- dialkyl aminoalkyl ester, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl group Aminoalkyl ester, N, N- dialkylaminoalkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized first Base acrylic acid N, N- dialkyl aminoalkyl ester, quaternized acrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized propylene Sour N, N- dialkyl aminoalkyl ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl amido Alkyl methacrylamides.

Fragrance: optional perfume composition may include selected from following component

(1) fragrance microcapsule or the fragrance microcapsule of moisture-activated, the spice composition comprising fragrance carrier and encapsulating, Described in fragrance carrier can be selected from cyclodextrin, starch capsules, porous carrier microcapsules and their mixture；And its The spice composition of middle encapsulating may include low volatility fragrance component, high volatile fragrance component and their mixture；

(2) fragrance before；

(3) the low fragrance component of odor detection threshold, wherein the low fragrance component content of the odor detection threshold is by pure The total weight of spice composition is smaller than about 25%；And

(4) their mixture；And

Porous carrier microcapsules-spice composition a part can be also absorbed on porous carrier such as zeolite or clay And/or be absorbed into the porous carrier, to form fragrance porous carrier microcapsules, to reduce multipurpose fabric-conditioning compositions The amount of middle free spice.

Preceding fragrance --- spice composition also may include preceding fragrance.Preceding fragrance may include discharged because of such as simple hydrolysis or The non-volatile materials of spices material are converted to, or can be the preceding fragrance (such as declined by pH and triggered) of pH change triggers, or can For the preceding fragrance or light-triggered preceding fragrance of enzyme r e lease.According to selected preceding fragrance, preceding fragrance can express different release speed Rate.

Perfume delivery systems

As disclosed, the beneficial effect of fragrance disclosed herein can be further by using perfume delivery systems to apply Increased with such fragrance.Suitable perfume delivery systems, the method for preparing perfume delivery systems and such fragrance delivering body The non-limiting example of the application of system is disclosed in USPA2007/0275866A1.Such perfume delivery systems include:

Polymer assisted delivery (PAD): the fragrance delivery technique delivers spices material using polymer material.It is some to show Example is typical agglomerate, water solubility or part aqueous to insoluble electrification or neutral polymer, liquid crystal, heat fusing object, water Gel, the plastics filled with fragrance, microcapsules, nano rubber latex and micron latex, polymer film-forming agent and polymer absorbing agent, polymerization Object adsorbent etc..PAD includes but is not limited to:

Matrix system: aromatic is dissolved or dispersed in polymer substrate or particle.1) fragrance can be formulated into for example It is distributed in polymer before in product or 2) during or after preparing product, is added separately to polymer.Although known permitted Other triggering factors of more controllable fragrance releases, but the diffusion in fragrance auto polymerization object is common trigger mechanism, so that Fragrance can be discharged from the polymer matrix plastidome for depositing or being applied on required surface (position) with certain rate, or be mentioned The high rate.Absorb and/or be adsorbed onto be among or on polymer beads, film, solution etc. the technology aspect.Example is The nano particle or micron particles being made of organic material (for example, latex).Suitable particle includes miscellaneous material, packet Include but be not limited to polyacetals, polyacrylate, polyacrylic, polyacrylonitrile, polyamide, poly(aryl ether ketone), polybutadiene, poly- fourth Alkene, polybutylene terephthalate (PBT), polychlorobutadiene, polyethylene, polyethylene terephthalate, poly terephthalic acid are sub- Two methylene ester of cyclohexyl, polycarbonate, polychlorobutadiene, polyhydroxyalkanoatefrom, polyketone, polyester, polyetherimide, polyethers Sulfone, haloflex, polyimides, polyisoprene, polylactic acid, polymethylpentene, polyphenylene oxide, polyphenylene sulfide, poly- adjacent benzene two Formamide, polypropylene, polystyrene, polysulfones, polyvinyl acetate, polyvinyl chloride and be based on acrylonitrile-butadiene, acetic acid Cellulose, ethane-acetic acid ethyenyl ester, ethylene-vinyl alcohol, styrene-butadiene, vinyl polymer or altogether Polymers and their mixture.

" standard " system refers to " those of preloading ", it is intended to keep preloading fragrance and polymer associate, until fragrance discharges One or more moment.This quasi polymer may also suppress neat product odor, and provide strong and/or sustained beneficial effect, This depends on flavor release rate.It preferably balances between following about one of such system challenge to obtain: 1) producing Stability (keeping fragrance until you need it on the inside of carrier) and 2 in product) in due course release is (during use or from drying Position).Storage obtains the stability and is even more important with during the aging of product in product.Water comprising surfactant For base product such as heavy duty liquid laundry detergent, which is particularly evident.It, can when being incorporated into water based product Many " standard " matrix systems effectively obtained become " balance " system.It can choose " balance " system or " storage " system, With diffusional stability in acceptable product and the available trigger mechanism (such as friction) for release." balance " system is The fragrance and polymer are in it wherein can be added alone the product, and the balance between fragrance and polymer is mutual Effect causes the beneficial effect on one or more consumer touch-points (relative to the delivery technique for not having polymer auxiliary Free spice) those of system.The polymer can preload fragrance；However, part or all of fragrance may be store in product It is spread during hiding, reaches balance, the balance includes required spice material (PRM) and polymer associate.It is carried with post-consumer polymer Fragrance reaches surface, and is usually discharged via fragrance diffusion.Such equilibrium system polymer is reduced using potential The odour intensity (usually even more so for preloading standards system) of net product.The deposition of this quasi polymer is used to " flat " and releases It puts feature and the increased shelf-life is provided.As described above, such shelf-life will be by inhibiting initial strength to obtain, and can make Formulator is able to use more influences or low odor detection threshold (ODT) or low Kovats index (KI) PRM to obtain FMOT Beneficial effect is without too strong or distortion initial strength.Importantly, fragrance release occurs in administration time section, to influence Desired one or more customer touch point.Matrix system also includes hot-melt adhesive and fragrance plastics.In addition, hydrophobic Modified polysaccharide can be incorporated into hair incense products, to improve depositing perfume and/or adjust fragrance release.All such matrix bodies System, including such as polysaccharide and nanoemulsions can with other PDT, including other PAD systems, such as fragrance microcapsule (PMC) form PAD storing body tying is closed.

Siloxanes also can be used as the example of the polymer of PDT, and can be similar to polymer assisted delivery " matrix body The mode of system " provides hair fragrant beneficial effect.Such PDT is referred to as silicone-assisted delivery (SAD).Silicon oxygen can be preloaded with fragrance Alkane, or equilibrium system is used them as, as described in PAD.The example of siloxanes includes dimethyl silicone polymer and poly- alkyl Dimethyl siloxane.Other examples include having those of amine functional group, can be used for providing with amine assisted delivery (AAD) and/ Or polymer assisted delivery (PAD) and/or the relevant beneficial effect of amine reaction product (ARP).

Reservoir system: reservoir system is also known as core-shell type technology or in which aromatic can be used as protective shell Fragrance releases the control the technology of film package.Material on the inside of microcapsules be referred to as core, it is internal mutually or filler, and wall sometimes by Referred to as shell, coating or film.Particle or pressure-sensitive capsule or microcapsules are the examples of the technology.Microcapsules of the invention are by working procedures It is formed, which includes but is not limited to coating, extrusion, spray drying, interfacial polymerization, in-situ polymerization and matrix polymerisations.It is possible Shell material differs widely in their stability to water.Among most stable is the material based on polyoxymethylene urea (PMU), Certain PRM even longer a period of time can be kept in aqueous solution (or product).Such system includes but is not limited to urea-formaldehyde And/or melamine-formaldehyde.The microcapsules based on gelatin can be prepared, so that they are rapidly or slowly soluble in water, this depends on In such as degree of cross linking.It can get many other capsule wall materials, and the fragrance diffusion stability observed is different.It is not bound by opinion Constraint, after for example depositing on the surface, fragrance from the rate of release in capsule be usually fragrance diffusional stability in product Reverse order.Thus, for example urea-formaldehyde and melamine-formaldehyde microcapsules usually require be not dispersal events or except expand The releasing mechanism other than release is dissipated, such as being crushed capsule and improving the mechanical force (example of fragrance (aromatic) rate of release Such as friction, pressure, shear stress).Other trigger mechanisms include melting, dissolution, hydrolysis or other chemical reactions, electromagnetic radiation Deng.The use for preloading microcapsules needs to discharge (on position) into ratio appropriate when product internal stability and use and/or on surface Rate, and properly select PRM.Microcapsules based on urea-formaldehyde and/or melamine-formaldehyde be it is more stable, especially exist In the group water solution of weakly acidic pH.These materials may need the trigger mechanism that rubs, and the friction trigger mechanism may not be suitable for All products applications.Other microencapsulation materials (such as gelatin) may be unstable in water based product, and in product The beneficial effect (controlling relative to free spice) of decrease may be even provided when aging.Scraping raw fragrant technology is the another of PAD A example.

In one aspect, the fragrance delivery technique may include the fragrance of encapsulating, is such as at least partly surrounded by with wall material Beneficial agent and the encapsulated perfume formed.The accelerant may include selected from following material: fragrance, such as 3- (4- tert-butyl-phenyl)- 2 methyl propanal, 3- (4- tert-butyl-phenyl)-propionic aldehyde, 3- (4- isopropyl phenyl) -2 methyl propanal, 3- (3,4- methylene two Oxygen phenyl) -2 methyl propanal and 2,6- dimethyl -5- heptenal, α-damascone, β-damascone, the big horse of δ-dihydro Ketone, beta -damascenone, 6,7- dihydro -1,1, -4 (5H)-indone of 2,3,3- pentamethyl, methyl -7,3- dihydro -2H-1,5- benzene And dioxane hept- 3- ketone, 2- [2- (4- methyl -3- cyclohexenyl group -1- base) propyl] pentamethylene -2- ketone, 2- sec-butyl hexamethylene Ketone and β-dihydro ionone, linalool, Ethyl linalool, tetrahydrolialool and dihydromyrcenol.Suitable spices material can Derived from Mount Olive, Givaudan Corp., South Brunswick, the New Jersey, USA of New Jersey, USA International Flavors&Fragrances Corp. or Naarden, the Quest Corp. of Netherlands.? On one side, microcapsule wall material can include: melamine, siloxanes, silica, polystyrene, polyureas, gathers polyacrylamide Urethane, the material based on polyacrylate, gelatin, maleic anhydride of styrene, polyamide and their mixture.At one Aspect, the melamine wall material may include with the melamine of formaldehyde crosslinking, with melamine-dimethoxy-ethanol of formaldehyde crosslinking and Their mixture.In one aspect, the polystyrene wall material may include the polystyrene with divinyl benzene crosslinked.? On one side, the polyureas wall material may include urea and their mixing with the urea of formaldehyde crosslinking and glutaraldehyde cross-linking Object.In one aspect, the material based on polyacrylate may include by methyl methacrylate/dimethylaminoethyl acrylate methyl base Polyacrylate that amino methyl is formed, the polyacrylate formed by amine acrylate and/or methacrylate and strong acid, The polyacrylate that is formed by carboxylic acid acrylates and/or methacrylate monomers and highly basic, by amine acrylate and/or first Polyacrylate that base acrylate monomer and carboxylic acid acrylates and/or carboxylic acid methyl acrylate monomer are formed and it Mixture.In one aspect, encapsulated perfume can be coated with deposition aid, cationic polymer, non-ionic polymers, yin from Sub- polymer or their mixture.Suitable polymer can be selected from polyvinyl formal, part of hydroxyl polyvinyl formal, Polyvinylamine, polyethyleneimine, ethoxylated polyethylene imines, polyvinyl alcohol, polyacrylate and their combination.? On one side, the encapsulated perfume of one or more types can be used, such as respectively with the two kinds of packet of different beneficial agents Seal fragrance and/or machined parameters.

Molecule-assisted delivery (MAD): non-polymer material or molecule can also be used to improve the delivering of fragrance.It is not bound by opinion Constraint, fragrance can with organic material noncovalent interaction, so as to cause depositing and/or discharging variation.Such organic material Non-limiting example include but is not limited to hydrophobic material such as organic oil, wax, mineral oil, vaseline, fatty acid or ester, sugar, Surfactant, liposome and even other spice materials (spice oil) and natural oil (including body soil and/or other Dirt).Perfume fixative is another example.In one aspect, non-polymer material or molecule have greater than about 2 CLogP

Cyclodextrin (CD): the technical method improves the delivering of fragrance using cricoid oligosaccharide or cyclodextrin.Usual shape At fragrance and cyclodextrin (CD) compound.Such compound can it is pre-formed, be formed in situ or shape on the position or in position At.Without being bound by theory, dehydration can be used for making balance mobile to CD- fragrance compound, especially other auxiliary elements (such as Surfactant) be not to exist with high concentration, not with fragrance compete cyclodextrin vestibule the case where.If time point later occur with Water contact improves water content, then may obtain strong beneficial effect.In addition, cyclodextrin can be improved flavor confect personnel selection The flexibility of PRM.Cyclodextrin can preload fragrance, or be added separately to fragrance, with obtain desired spice stability, deposition or Discharge beneficial effect.

Starch encapsulated temper (SEA): it can be for example, by ingredient be added such as using starch encapsulated temper (SEA) technology Liquid perfume is converted into solid by starch, adjusts the characteristic of the fragrance.The beneficial effect includes improving product storage The fragrance retention of period, especially under non-aqueous condition.After contacting water, it is body to can trigger fragrance.Also it can get in essence The beneficial effect at other true moment, because the starch allows product configuration personnel selection PRM or PRM concentration, the concentration It cannot usually be used in the presence of no SEA.Another technology example includes using other organic and inorganic materials Such as silica, fragrance is converted to solid from liquid.

Zeolite and inorganic carrier (ZIC): the technology is related to delivering fragrance using porous zeolite or other inorganic material. The zeolite for being loaded with fragrance can be used together with or without auxiliary element, and the auxiliary element is loaded with the boiling of fragrance for such as coating Stone (PLZ) with its fragrance release characteristics during changing product storage period or use, or changes its self-desiccation position release fragrance Characteristic.Silica is another form of ZIC.Another example of suitable inorganic carrier includes inorganic tubule, Described in fragrance or other active materials be comprised in receive-or the lumen of micro--tubule in.Be loaded with fragrance inorganic tubule (or carry Have the tubule or PLT of fragrance) it is preferably minerals nanometer or micron tubule, such as halloysite or halloysite and other nothings The mixture of machine material (including other clays).The PLT technology can include also additional in the inside and or outside of the tubule Ingredient be deposited on the purpose at desired position, or the fragrance for controlling load for improving the diffusional stability in product Rate of release.Monomer material and/or polymer material, including starch encapsulated object, can be used to cladding, filling, cover or with Other modes encapsulate the PLT.

In one aspect, it discloses selected from following perfume delivery systems: polymer assisted delivery (PAD) system, molecule Assisted delivery (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite inorganic carrier (ZIC) body System, wherein the perfume delivery systems may include the fragrance for being disclosed in this specification, such as selected from being disclosed in described in this specification The fragrance of the various fragrance of fragrance chapters and sections.

In one aspect, polymer assisted delivery (PAD) system is disclosed, wherein the polymer assisted delivery (PAD) System may include polymer assisted delivery (PAD) storage system, and the storage system may include the fragrance for being disclosed in this specification, Such as the fragrance selected from the various fragrance for being disclosed in fragrance chapters and sections described in this specification.

In the one aspect of the polymer assisted delivery (PAD) storage system, polymer assisted delivery (PAD) storage The system of depositing may include fragrance delivery of particles, and the fragrance delivery of particles may include sheathing material and core material, the sheathing material The core material is encapsulated, the core material may include the fragrance for being disclosed in this specification, such as selected from being disclosed in this specification institute The fragrance of the various fragrance of fragrance chapters and sections is stated, and the shell includes to be selected from following material: polyethylene；Polyamide；Polyphenyl Ethylene；Polyisoprene；Polycarbonate；Polyester；Polyacrylate；Aminoplast, in one aspect, the aminoplast can wrap Containing polyureas, polyurethane, and/or polyureaurethane, in one aspect, the polyureas includes polyoxymethylene urea and/or melamino-formaldehyde Resin；Polyolefin；Polysaccharide, in one aspect alginates and/or chitosan；Gelatin；Lac；Epoxy resin；Vinyl Polymer；Water insoluble inorganic substance；Siloxanes；And their mixture.

In the one aspect of the polymer assisted delivery (PAD) storage system, the shell may include melamine first Aldehyde and/or the melamino-formaldehyde of crosslinking.

In the one aspect of the polymer assisted delivery (PAD) storage system, the shell can be by water-soluble cationic Polymer peridium, the cationic polymer are selected from: polysaccharide, cationic modified starch and cation-modified guar gum, poly- silicon oxygen Alkane, dimethyldiallylammonium polyhalide, dimethyldiallylammonium polychloride and vinyl pyrrolidone copolymer, Acrylamide, imidazoles, imidazolinium halides and imidazolium halides and polyvinylamine and its with N- vinyl formamide Copolymer.

In the one aspect of the polymer assisted delivery (PAD) storage system, the coating for being coated with the shell may include Cationic polymer and anionic polymer.

In the one aspect of the polymer assisted delivery (PAD) storage system, wherein the cationic polymer can wrap Include hydroxy ethyl cellulose；And the anionic polymer may include carboxymethyl cellulose.

In one aspect, polymer assisted delivery (PAD) the storage system is fragrance microcapsule.

Stench reduces technologyAny stench technology can be used, including covering stench, inhibiting the perception of stench or by appointing What his mechanism is operated to form the technology of the one or more stenches less obvious to consumer.A kind of such technology is retouched in detail It is set forth in USPA series number 2016/0090555A1.USPA series number 2016/0090555A1, which is taught, following stench can be used to subtract Few material is to inhibit stench: total about 0.00025% to about 0.5%, preferably about 0.0025% to about 0.1%, more preferably About 0.005% to about 0.075%, most preferably one or more stenches of about 0.01% to about 0.05% reduce material, preferably 1 to about 20 kind of stench reduces material, and more preferably 1 to about 15 kind of stench reduces material, and most preferably 1 to about 10 kind of stench is reduced Material, the stench, which reduces each in material, has at least 0.5, preferably 0.5 to 10, more preferably 1 to 10, most preferably 1 to 5 MORV, and preferably, the stench reduces each in material and all has general MORV, and the whole stench is reduced Material has less than 3, and more preferably less than about 2.5, even more preferably less than about 2, and still more preferably less than about 1, and And most preferably 0 barrier index, and/or the barrier index of average 3 to about 0.001.Preferably, the stench reduces material tool Have less than 3, preferably less than 2, even more preferably less than 1, and most preferably 0 fragrant fidelity index and/or average out to 3 to About 0.001 fragrant fidelity index.In one aspect, the weight ratio of the number of malodor reduction composition and fragrance number is about 1: 20,000 to about 3000:1, preferably about 1:10,000 to about 1,000:1, more preferably 5,000:1 to about 500:1, and most Preferably about 1:15 to about 1:1.

Fabric hueing agentComposition may include fabric hueing agent (sometimes referred to as Toner, blueing agent or whitening agent).It adjusts Toner usually provides blue or violet hue to fabric.Toner can be used singly or in combination, to generate specific adjust It color tone and/or mixes colours different fabric type.This can be for example by mixing red and blue-green dyestuff to generate blue Or violet hue provides.Toner can be selected from the dyestuff of any known chemical classes, including but not limited to acridine, Anthraquinones (including polycyclic quinone), azine, azo (for example, monoazo, bisazo, trisazo-, four azos, polyazo) including pre-metal Change azo, half flower cyanines of two furans of benzo and benzodifuranone, carotenoid, cumarin, Hua Jing, diaza, diphenyl-methane, Formazan, half flower cyanines, indigoid, methane, naphthalimide, naphthoquinones, nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, benzene Vinyl, triarylmethane, triphenylmenthane, xanthene and their mixture.Suitable fabric hueing agent includes dyestuff, dye Material-clay conjugates and organic pigment and inorganic pigment.Suitable dyestuff includes small molecule dyes and polymeric dye.It closes Suitable small molecule dyes include selected from following small molecule dyes: belong to it is acid, directly, the activity of alkalinity, activity or hydrolysis, The dyestuff of the color index (C.I.) of solvent or disperse dyes classification, such as it is classified as blue, purple, red, green or black dyestuff, and And desired tone is provided either individually or in combination.On the other hand, suitable small molecule dyes include being selected from Colour Index The small molecule dyes of the lower column number of (Society of Dyers and Colourists, Bradford, UK): directly purple dye Material such as 9,35,48,51,66 and 99, directly indigo plant dyestuff such as 1,71,80 and 279, acid red dye such as 17,73,52,88 and 150, Acid purple dye such as 15,17,24,43,49 and 50, acid blue dye such as 15,17,25,29,40,45,75,80,83,90 and 113, acid black dye such as 1, basic purple dye such as 1,3,4,10,19,35,38 and 48, basic dye such as 3,16,22,47, 65,66,67,71,75 and 159, dispersion or solvent dye and their mixture.On the other hand, suitable small molecule dye Material includes selected from following small molecule dyes: C.I. number acid violet 17, acid blue 80, acid violet 50, directly indigo plant 71, directly purple 51, directly blue 1, acid red 88, azogeramine 50, acid blue 29, Acid blue 113 or their mixture.

Polymeric dyeSuitable polymeric dye includes selected from following polymeric dye: (sometimes comprising covalent bonding Referred to as be conjugated) chromogen polymer (dye-polymer conjugate) (such as with the chromogen being copolymerized in main polymer chain The polymer of body) and their mixture.

On the other hand, suitable polymeric dye includes selected from following polymeric dye: with trade name(Milliken, Spartanburg, South Carolina, USA) sale fabric-entity colorant, by extremely The dye-polymer conjugate that a kind of few reactive dye and polymer are formed, the polymer are selected from the polymerization comprising following part Object, the part are selected from hydroxylic moiety, primary amine moiety, secondary amine moieties, thiol moiety and their mixture.On the other hand, Suitable polymeric dye includes selected from following polymeric dye:Violet CT, is covalently bound to activity The carboxymethyl cellulose (CMC) of blue, reactive violet or active red dye such as with the CMC of C.I. active blue 19 conjugation (by Megazyme, Wicklow, Ireland with ProductName AZO-CM-CELLULOSE, product code S-ACMC sale), alkoxylate Triphenyl-methane polymeric colorant, alkoxylated thiophene polymeric colorant and their mixture.

A part that toner can be used as reaction mixture is impregnated in detergent composition, which is to pass through The result of one or more optionally purification step organic synthetic dye molecules.Such reaction mixture generally comprises dye molecule certainly Body, and additionally may include the by-product of unreacted raw material and/or organic synthesis approach.

Above-mentioned fabrics toner (any mixture that fabric hueing agent can be used) can be applied in combination.

CoatingIn one aspect of the invention, manufacture includes the delivery of particles of beneficial agent, and is then applied with additional materials Cover the delivery of particles.The non-limiting example of coating material includes but is not limited to be selected from following material: poly- (methyl) acrylic acid Ester, poly- (ethylene-maleic acid), polyamine, wax, polyvinylpyrrolidone, polyvinylpyrrolidone copolymer, polyvinyl Pyrrolidones-ethyl acrylate, polyvinylpyrrolidone-vinyl acrylate, polyvinylpyrrolidone methacrylic acid Ester, polyvinylpyrrolidone/vinyl acetate, polyvinyl acetal, polyvinyl butyral, polysiloxanes, poly- (propylene Maleic anhydride), it is maleic anhydride derivative, the copolymer of maleic anhydride derivative, polyvinyl alcohol, styrene-butadiene latex, bright Glue, gum arabic, carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose, other modifications cellulose, Mosanom, chitosan, casein, pectin, the starch of modification, polyvinyl acetal, polyvinyl butyral, polyvinyl first Base ether/maleic anhydride, polyvinylpyrrolidone and its copolymer, poly- (vinyl pyrrolidone/methacryiamidopropyl Trimethyl ammonium chloride), polyvinylpyrrolidone/vinyl acetate, polyvinylpyrrolidone/dimethylaminoethyl Ethyl ester, polyvinylamine, polyvinyl formamide, polyallylamine and polyvinylamine, polyvinyl formamide and polyallyl The copolymer of amine and their mixture.Such material be available from CP Kelco Corp. (San Diego, California, USA)；Degussa AG (Dusseldorf, Germany)；BASF AG (Ludwigshafen, Germany)； Rhodia Corp. (Cranbury, New Jersey, USA)；Baker Hughes Corp. (Houston, Texas, USA)； Hercules Corp. (Wilmington, Delaware, USA)；Agrium Inc. (Calgary, Alberta, Canada)； ISP (New Jersey, U.S.A.).

Formaldehyde scavengerIn one aspect, the delivery of particles comprising beneficial agent can be combined with formaldehyde scavenger.A side Face, such delivery of particles comprising beneficial agent may include the delivery of particles comprising beneficial agent in the present invention.Suitable formaldehyde is clear Except agent includes selected from following material: sodium hydrogensulfite, melamine, urea, ethylene urea, cysteine, cysteamine, lysine, Glycine, serine, carnosine, histidine, glutathione, 3,4- diaminobenzoic acid, allantoin, glycoluril, anthranilic acid, anthranilic acid Methyl esters, 4-aminobenzoic acid methyl esters, ethyl acetoacetate, acetyl acetamide, malonamide, ascorbic acid, 1,3- dihydroxy third Ketone dimer, oxamides, benzoguanamine, pyroglutamic acid, pyrogallol, gallicin, progallin A, does not have biuret Propyl galate, triethanolamine, succinamide, thiabendazole, benzotriazole, triazole, indoline, sulfanilic acid, oxamides, mountain Pears alcohol, glucose, cellulose, poly- (vinyl alcohol), poly- (vinyl formamide) of partial hydrolysis, poly- (vinylamine), poly- (ethylene is sub- Amine), poly- (oxidation enamine), poly- (vinyl alcohol)-co-poly (vinylamine), poly- (4- aminostyryl), poly- (1- lysine), shell Glycan, hexylene glycol, ethylenediamine-N, N '-bisacetoacet amine, N- (2- ethylhexyl) acetyl acetamide, 2- benzoyl acetyl Acetamide, N- (3- phenyl propyl) acetyl acetamide, lilial, helional, melonal, (2,4- dimethylcyclohexenes -3- Base) formaldehyde, 5,5- dimethyl-hydroresorcinol, 2,4- dimethyl -3- cyclohexene formaldehyde, the evil of 2,2- dimethyl -1,3- two Alkane -4,6- diketone, 2 pentanone, dibutylamine, trien, ammonium hydroxide, benzylamine, hydroxycitronellol, cyclohexanone, 2- fourth Ketone, pentanedione, dehydroactic acid or their mixture.These formaldehyde scavengers are available from Sigma/Aldrich/Fluka (St.Louis, Missouri., U.S.A.) or PolySciences, Inc. (Warrington, Pennsylvania, U.S.A.)。

In one aspect, such formaldehyde scavenger can be with consumer products for example comprising the liquid clothing containing benefit agent delivery particle The combination of object detergent product, the scavenger are selected from: sodium hydrogensulfite, melamine, urea, ethylene urea, cysteine, half Guang Amine, lysine, glycine, serine, carnosine, histidine, glutathione, 3,4- diaminobenzoic acid, allantoin, glycoluril, ammonia Anisic acid, artificial neroli oil, 4-aminobenzoic acid methyl esters, ethyl acetoacetate, acetyl acetamide, malonamide, ascorbic acid, C3H6O3 dimer, oxamides, benzoguanamine, pyroglutamic acid, pyrogallol, gallicin, does not have biuret Infanticide acetoacetic ester, propylgallate, triethanolamine, succinamide, thiabendazole, benzotriazole, triazole, indoline, sulphur Amino acid, oxamides, sorbierite, glucose, cellulose, poly- (vinyl alcohol), partially hydrogenated poly- (vinyl formamide), poly- (second Enamine), poly- (aziridine), poly- (oxyalkylene hydroxylamine), poly- (vinyl alcohol)-co-poly (vinylamine), poly- (4- aminobenzene second Alkene), poly- (1- lysine), chitosan, hexylene glycol, ethylenediamine-N, N '-bisacetoacet amine, N- (2- ethylhexyl) acetyl second Amide, 2- benzoyl acetyl acetamide, N- (3- phenyl propyl) acetyl acetamide, lilial, helional, melonal, (2,4- dimethylcyclohexenes -3- base) formaldehyde, 5,5- dimethyl-hydroresorcinol, 2,4- dimethyl -3- hexahydrobenzaldehyde, 2,2- dimethyl -1,3- dioxanes -4,6- diketone, 2 pentanone, dibutylamine, trien, ammonium hydroxide, benzyl amine, Hydroxycitronellol, cyclohexanone, 2- butanone, pentanedione, dehydroactic acid and their mixture, and to be washed by liquid laundry About 0.003 weight % of agent product total weight to about 0.20 weight %, about 0.03 weight % are to about 0.20 weight % or even about The content and the liquid laundry detergent product mix of 0.06 weight % to about 0.14 weight %.

CarrierComposition generally comprises carrier.In certain aspects, carrier can be only water or for the mixed of organic solvent and water Close object.In certain aspects, organic solvent includes 1,2-PD, ethyl alcohol, isopropanol, glycerol and their mixture.Also Other lower alcohols, C can be used₁-C₄Alkanolamine such as monoethanolamine and triethanolamine.Suitable carrier includes but is not limited to: Salt, sugar, polyvinyl alcohol (PVA), modified PVA；Polyvinylpyrrolidone；PVA copolymer, such as PVA/ polyvinylpyrrolidone Ketone and PVA/ polyvinylamine；The polyvinyl acetate of partial hydrolysis；Polyalkylene oxide, such as ethylene oxide；Polyethylene glycol；Polycyclic oxygen Propane, acrylamide；Acrylic acid；Cellulose, alkylcellulose, such as methylcellulose, ethyl cellulose and propyl cellulose； Cellulose ether；Cellulose esters；Cellulose amides；Polybasic carboxylic acid and salt；Polyaminoacid or peptide；Polyamide；Polyacrylamide；Malaysia Acid/acrylic acid copolymer；Polysaccharide, the starch including starch, modification；Gelatin；Alginates；Portugal's xylan, other hemicelluloses Polysaccharide, including xylan, glucuronoxylan, araboxylan, mannosan, glucomannans and galactolipin Portugal sweet dew Glycan；Natural gum, such as pectin, xanthan gum, carrageenan, locust bean gum, gum arabic, bassora gum；And they Combination.In one embodiment, polymer includes: polyacrylate, especially sulfonated polyacrylates and water soluble propene Acid ester copolymer；And alkylhydroxycellulose, such as methylcellulose, sodium carboxymethylcellulose, modification carboxymethyl cellulose Element, dextrin, ethyl cellulose, propyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, maltodextrin, poly- methyl Acrylate.In addition to carrier provided above, the copolymer of such polymer material also acts as carrier.Load may not be present Carrier may not be present in body, such as the composition of anhydrous solid form, but more typically with about 0.1% to about 99%, about 10% There are carriers for level in about 95% or about 25% to about 90% range.

Application method and processed product

The compositions disclosed herein can be used for cleaning and/or handling fabric.In general, making at least part and the Shen of fabric Please person composition embodiment (in a pure form or being diluted in liquid such as wash liquid) contact, then optionally Wash and/or rinse the fabric.

For the present invention, washing includes but is not limited to scouring and mechanical stirring.Fabric may include it is most of can be Any fabric for washing or handling under normal consumer use condition.May include disclosed composition liquid can have about 3 to About 12 pH.Such composition is usually used with the concentration of about 500ppm in solution to about 15,000ppm.When cleaning solvent is water When, for water temperature usually in the range of about 5 DEG C to about 90 DEG C, and when the fabric includes fabric, the ratio of water and fabric is usual It is about 1:1 to about 30:1.

In one aspect, the invention discloses what is handled with any embodiment of any composition disclosed herein to knit Object.

Test method

Molecular weight distribution

Weight average molecular weight (M_w) value measures as follows.Molecular weight analyte is examined equipped with autosampler, post case and refractive index It surveys in the Agilent 1260HPLC system of device and measures.Operating system is OpenLAB CDS ChemStation Workstation(A.01.03).Data storage and analysis are, the GPC/SECs of ChemStation offline using Cirrus GPC Software, version 3 .4 are carried out.Chromatography column condition is given in Table 3.When being calculated, as a result using with known molecular amount Polystyrene reference sample calibration.M_wThe measurement of value changes 5% or less.It is analyzed using the mobile mutually measurement molecular weight of chloroform.

Table 3

Table 4 shows the molecular weight and retention time of polystyrene standard.

Table 4

Iodine number

Another aspect of the present invention provides the method for the iodine number of measurement glycerol ester copolymer.Use AOCS official method Cd 1-25 measures iodine number, and is modified as follows: carbon tetrachloride solvent being replaced with chloroform (25ml), will accurately check sample (oleic acid 99%, Sigma-Aldrich；IV=89.86 ± 2.00cg/g) it is added in sample sets, and when measurement glyceride is total When the free hydrocarbon content of polymers, the IV reported has been directed to the small contribution from alkene identified and has been modified.

The gas chromatographic analysis of fatty acid residue in glycerol ester copolymer

After being atmospherically distilled to alkene lower than 1 weight %, pass through institute in gas chromatographic analysis embodiment 4,5,6 and 7 The final glyceride oligomer product stated, and as following procedure oligomer product transesterification by obtained by methyl ester.

0.10 ± 0.01g of sample is weighed in 20mL scintillation vial.Sodium methoxide is 1% molten in methanol (1.0mL) Liquid is transferred in bottle by pipette, and bottle is covered.The bottle of capping is placed in sample oscillator, and in 250rpm It shakes at 60 DEG C until sample substantially uniformity and clarification.It will take out in sample therefrom oscillator, then added by pipette Then 5ml saline solution adds 5ml ethyl acetate.By bottle vortex mixed one minute to be thoroughly mixed solution.Make mixed solution It stands until two separate.Top layer (ethyl acetate) (1mL) is transferred in bottle for gas chromatographic analysis.Based on selected Group grouping, normalization composition, is shown in Table 9 as unit of weight %.

Using equipped with Agilent DB-WAXETR column (122-7332E, 30m × 250um × 0.25um film thickness) and fire 6850 instrument of Agilent of flame ionization detector collects data from gas chromatography.Method and condition used is as described below: GC Analysis of the method " Fast_FAME.M " for all samples in embodiment 1 to 7.

C in glycerol ester copolymer_10-14The weight percent of unsaturated fatty acid ester is by will obtain in above-mentioned analysis All C₁₀、C₁₁、C₁₂、C₁₃And C₁₄The weight percent phase Calais of unsaturated fatty acid ester calculates.In glycerol ester copolymer C_10-13The weight percent of unsaturated fatty acid ester passes through all C for will obtaining in above-mentioned analysis₁₀、C₁₁、C₁₂And C₁₃It is unsaturated The weight percent phase Calais of aliphatic ester calculates.C in glycerol ester copolymer_10-11The weight percent of unsaturated fatty acid ester Pass through all C that will be obtained in above-mentioned analysis₁₀And C₁₁The weight percent phase Calais of unsaturated fatty acid ester calculates.

Free hydrocarbon content

Another aspect of the present invention provides the method for the free hydrocarbon content of measurement glycerol ester copolymer.This method combines Gas chromatography/mass spectrography (GC/MS) confirms the identification of free hydrocarbon homologue, and combines the gas using flame ion detection Phase chromatography (GC/FID) quantifies free hydrocarbon present in glycerol ester copolymer.

Sample preparation: sample to be analyzed is generally by diluting (such as 400:1) simultaneously in methanolizing KOH (such as 0.1N) It is heated in closed container and carries out transesterification, until the reaction is complete (i.e. 90 DEG C continue 30 minutes), then cooled to room temperature.So Sample solution can be handled with the methanol solution of 15% boron trifluoride afterwards, and be heated in closed container again, until the reaction is complete (continuing 30 minutes at 60 DEG C), to be acidified (methyl orange-red) simultaneously and any free acid being present in sample that methylates. After allowing to be cooled to room temperature, by addition saturation NaCl aqueous solution come quenching reaction.Then organic extraction solvent is such as wrapped The hexamethylene of internal standard containing known level (such as 150ppm dimethyl adipate) is added in bottle and is sufficiently mixed.Layer separation Afterwards, a part of organic phase is transferred in the bottle for being suitable for injection into gas chromatograph.It is molten that the sample extraction is analyzed by GC/MS Liquid, be compared with reference spectrum with confirm with the identification at the matched peak of hydrocarbon retention time, and then respond with standard FID because Son is compared through GC/FID the concentration for calculating hydrocarbon, fatty acid and fat diacid.

Be generally observed hydrocarbon compound (that is, 1- laurylene, 1- tridecylene, 1-tetradecylene, ten pentaene of 1-, 1- hexadecylene, 17 alkene of 1-, 1- octadecene, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, heptadecane and octadecane) it is known Concentration (such as each 50ppm) hydrocarbon standard specimen by be diluted in for extract in the identical containing the internal standard solvent of example reaction mixture come Preparation.The hydrocarbon standard specimen is analyzed to generate retention time and reference spectra by GC/MS, and guarantor is then generated by GC/FID Stay time and response factor.

GC/MS: it is set using equipped with shunting/Splitless injecting samples mouth Agilent 7890GC with EI+ ionization mode The Waters QuattroMicroGC mass spectrograph set executes Qualitative Identification to observed peak.With 1.4mL/ minutes helium Nonpolarity DB1-HT column (15m × 0.25mm × 0.1um df) is installed in carrier gas.In individual operation, by 1uL hydrocarbon standard specimen and sample Product extract solution is injected into 300 DEG C of injection ports with the split ratio of 25:1.Baking oven is kept for 1 minute at 40 DEG C, then with 15 DEG C/minute The speed of clock is warming up to 325 DEG C of final temperature, is kept for 10 minutes, and such total run time is 30 minutes.Transmission line is maintained at 330 DEG C, and the temperature in the source EI is 230 DEG C.Ionization energy is set in 70eV, and scanning range is 35-550m/z.

GC/FID: the Agilent 7890GC equipped with shunting/Splitless injecting samples mouth and flame ionization detector is used Carry out quantitative analysis.Nonpolarity DB1-HT column (5m × 0.25mm × 0.1um df) is installed with the helium carrier gas of 1.4mL/min.? Individually in operation, 1uL hydrocarbon standard specimen and sample extraction object solution are injected into 330 DEG C of injection ports with the split ratio of 100:1.Baking oven It is kept for 0.5 minute at 40 DEG C, 380 DEG C of final temperature is then warming up to 40 DEG C/min of speed, kept for 3 minutes, it is total in this way Runing time is 12 minutes.FID is maintained at 380 DEG C, and hydrogen flow rate is 40mL/ minutes, and air velocity is 450mL/ minutes. Make-up gas is the helium of 25mL/ minutes flow velocitys.Calibration is created in Chemstation Data Analysis Software using hydrocarbon standard specimen Table, including known concentration is to generate response factor.These response factors are applied to the correspondence peak in sample chromatogram figure, to calculate Free hydrocarbon total amount present in each sample.

Embodiment

Although specific embodiments of the present invention have had been illustrated and described, to those skilled in the art It is readily apparent that a number of other change and modification can be made without departing from the spirit and scope of the present invention.Therefore, It is intended to all such change and modification for covering in appended claims and belonging in the scope of the invention.

The non-limiting example of product formulation disclosed in this specification is summarized below.

Embodiment 1- is reacted with cyclobutenyl canola oil (BCO): the influence of BCO content

Experimental provision is by the three neck round bottom group equipped with magnetic stirring bar, diaphragm dome and the outlet to vacuum system At.Outside heating is provided by silicone oil bath.Diaphragm is for adding metathesis catalyst and extracting sample.Vacuum system by TEFLON diaphragm pump and pressure controller composition.

According to method described in United States Patent (USP) 8,957,268, pass through cross metathesis canola oil (Wesson) and 1- Butylene (the 1- butylene of the C=C double bond 1mol in every mole of oil) prepares cyclobutenyl canola (BCO).By BCO and mustard Oily (Wesson) is mixed and is fitted into 500mL round-bottomed flask.Oil mixture is purged about 15 minutes with nitrogen (Airgas, UHP).It will Reaction flask is heated to about 70 DEG C and is evacuated to required pressure (see below: 200 or 450 support absolute pressures).C827 is answered Decomposition catalyst (10mg/mL；Materia, Inc., Pasadena, California, USA) toluene (Sigma-Aldrich, The catalyst content for realizing 100ppmwt is added in oil mixture in anhydrous 99.8%) solution.Reaction is maintained at 70 DEG C, simultaneously Dynamic vacuum is kept under desired pressure and continues 2 hours.The small sample that reaction mixture is removed by syringe, uses ethyl Vinyl ethers (Sigma-Aldrich) is quenched, and as gpc analysis with the weight average molecular weight of glycerol ester oligomer obtained by measuring (Mw)。

Table 5 shows the equal M of gained weight of 13 kinds of differential responses_w, wherein the percentage of BCO increases.The BCO percentage of record It is weight percent of the BCO relative to the total weight (BCO and canola oil) of oil.Weight average molecular weight is recorded as unit of g/mol.

Table 5

Embodiment 2- is reacted with cyclobutenyl canola oil (BCO): the influence in reaction time

Using with those identical equipment described in embodiment 1 and program, by 50 weights of weight %/50 of BCO and canola oil It measures % mixture to react four hours, while dynamic vacuum being maintained under 200 or 450 supports (absolute pressure), wherein adopting per hour Collect sample.Table 6 shows weight average molecular weight (M as time goes by_w).Molecular weight (Mw) is recorded as unit of g/mol.

Table 6

The cross metathesis of embodiment 3- canola oil and cyclobutenyl palm oil (BPO): the influence of feedstock composition

Using with device and method identical those of described in embodiment 1, make the mixing of BPO (Wilmar) and palm oil Object reacts two hours.Table 7 show two hours after molecular weight (Mw).Molecular weight (Mw) is recorded as unit of g/mol.

Table 7

Embodiment 4- canola oil metathesis (comparative example)

Using identical equipment, (the difference is that two-stage rotary vane pump is used in experiment, the experiment is more exhausted than less than 10 supports It is run under the dynamic vacuum of pressure and under program described in embodiment 1, canola oil reacts two hours.Table 8 is shown two hours Molecular weight (M afterwards_w).Molecular weight (M_w) recorded as unit of g/mol.

Table 8

Absolute pressure (support)	100g grades of (Mw)	1kg grades of (Mw)
			450	11,700	-
200	12,300	-
			75	12,600	-
8	14,500	13,600
			3.2	-	15,100
2.5	-	15,900

A part (473g) of the product of the 1kg experiment run under comfortable 2.5 supports in the future heptane (BDH, laboratory examination Agent, 500mL) dilution.It adds Magnesol-600-R (Dallas Group of Am., 10g), and gained mixture is existed It is stirred at ambient temperature under nitrogen 30 minutes.Magnesol-600-R is removed by vacuum filter.It adds fresh Magnesol-600-R (10g), and gained mixture is stirred 30 minutes at ambient temperature under a nitrogen.Heptane passes through rotation Turn evaporation to remove.Alkene is removed in 1L three neck round bottom by vacuum distillation, and the three neck round bottom is equipped with short distance Still head；It is cooled to 5 DEG C of condenser；20mL round-bottomed flask cooler with dry ice/isopropanol；Magnetic stirring bar；And survey The thermometer of quantity of fluid temperature and vapor (steam) temperature.Heating is covered by resistance heating to be provided.Vacuum by two-stage rotary-vane vaccum pump Lai Offer removes most of olefin material by gradually increasing heat input.For the initial part of distillation, kept in system Minimum nitrogen purging.Final pressure is about 0.1 support absolute pressure, and final fluid temperature is 192 DEG C.Olefin(e) centent is less than 1 matter Measure %.The sample of final product is subjected to transesterification and is analyzed by GC with determination fatty acid residue as described above.Referring to table 9 (hereafter).

Embodiment 5- is removed using catalyst and alkene strips, the canola oil and cyclobutenyl canola oil of a kilogramme-scale (BCO) cross metathesis

Using with identical metathesis process and equipment described in embodiment 1, make the 1kg mixture (50 of BCO and canola oil The weight % of weight %/50) reaction two hours.Catalyst is removed to handle by THMP and be completed.THMP processing passes through following composition: adding Add the aqueous solution of 1M tri- (methylol) phosphine (THMP, 1.0M, 50mol THMP/mol C827), it is small to stir 2 at ambient temperature When, and then washed in separatory funnel with water (2 × 100mL).It is logical to be filled with identical program described in embodiment 4 and distillation It sets and removes olefin by-products and traces of residual water from product, the difference is that being purged without using nitrogen.Final pressure is about 0.2 support Absolute pressure, final fluid temperature are 195 DEG C.Olefin(e) centent is less than 1 mass %, and the M of glycerol ester oligomer_wIt is 16, 700g/mol.The sample of final product is subjected to transesterification and is analyzed by GCWith determination fatty acid residue as described above.Ginseng It was shown in Table for 9 (hereafter).

Embodiment 6- is removed using catalyst and alkene strips, the soybean oil and cyclobutenyl soybean oil of two kilogramme-scales (BCO) cross metathesis

Using identical program and device described in embodiment 1 is similar to, the difference is that being burnt using 3L flask instead of 500mL Bottle keeps the 1kg of butylene soybean oil and soybean oil (Costco), 50/50 weight % mixed using 100ppm wt C827 catalyst Object is closed to react about four hours.Additional 40ppm catalyst is added, and after about two hours or more, is quenched with ethyl vinyl ether It goes out reaction.By the distillation sequence and equipment similar with described in embodiment 5, olefin by-products are removed from 265g Product samples With the water of traces of residual.Final pressure is about 0.1 support absolute pressure, and final fluid temperature is 195 DEG C.Olefin(e) centent is less than 1 matter Measure %.The sample of final product is subjected to transesterification and is analyzed by GC with determination fatty acid residue as described above.Referring to table 9 (hereafter).

Embodiment 7- is removed using catalyst and alkene strips, the canola oil and cyclobutenyl canola oil of 12 kilogramme-scales (BCO) cross metathesis

The embodiment carries out in 5 gallons of stainless steel reactors (Par), the reactor equipped with impeller, for no sky The port of gas catalyst addition, and for sampling Strahman valve.Before proceeding, reactor assembly is purged completely with nitrogen.

BCO (6.16kg) is prepared by being similar to program used in embodiment 1, and it is mixed with canola oil (6.12kg) Merge and is fitted into reactor.Oil mixture is stirred with 200rpm, while being blown with the rate of 0.5SCFM with nitrogen by dip tub It sweeps about 30 minutes and leads to.Reactor is evacuated to 200 supports (absolute vacuum) and is heated to 70 DEG C.By C827 metathesis catalyst (1.0g, Materia, Inc., Pasadena, California, USA) is suspended in canola oil (50mL) and oil mixture is added In.Reaction is kept for four hours under 70 DEG C and 200 supports.By the C827 catalysis of additional addition being suspended in canola oil (50mL) Agent (0.25g) is added in reaction.After other two hours, reactor is backfilled with nitrogen.

Catalyst removal carries out in 5 gallons of jacketed glass reactors, and the reactor is arranged equipped with blender, bottom Water valve and port for adding reagent.It is packed into the 0.12M aqueous solution (0.31kg) of THMP into glass reactor and is preheated to About 90 DEG C.Thick metathesis reaction product is transferred to glass reactor at 70 DEG C, and mixture is stirred at about 80-90 DEG C Mix (150rpm) 20 minutes.Following washing procedure is carried out twice.Deionized water (1.9kg, 60 DEG C at) is heated to 80- In 90 DEG C of reactor, and resulting mixture is stirred into (100rpm) 20 minutes.Stop blender and makes reactor content It is settled 16 hours under 80-90 DEG C of steady temperature.Bottom aqueous layer is carefully discharged.After second is washed, by washed product It is cooling, it is then discharged in container.

Washed product is divided into two parts to remove alkene and residual water, this uses similar described in embodiment 5 Distillation sequence and equipment carry out.Final distillation pressure is about 0.1 support absolute pressure, and final fluid temperature is about 190 DEG C.? After distillation, two parts are reconfigured.The small sample of recombinant products is subjected to transesterification and is analyzed by GC to determine as above The fatty acid residue.Referring to table 9 (hereafter).

After being atmospherically distilled to alkene lower than 1 weight %, is analyzed in embodiment 4,5,6 and 7 and produced by the above method Fatty acid residue in raw final glyceride oligomer product.Calculate C_10-14Unsaturated fatty acid ester, C_10-13Unsaturated fat Acid esters and C_10-11Unsaturated fatty acid ester is simultaneously reported in Table 10 below.

Table 9

Table 10

The diene selective hydration of embodiment 8-crude glycerol ester polymer

In 600mL Parr reactor, before reactions, wash via toluene by the thick double decomposition of 170g from embodiment 6 Product, 170g n-decane (Sigma-Aldrich, anhydrous, >=99%) and 9908 (Johnson of 0.60g PRICAT Matthey Catalysts)；The Triglycerides of saturation remove, and use N₂And then use H₂Respectively purging 15 minutes, then exist 100psig H₂It reacts at 160 DEG C under (Airgas, UHP), while being stirred using gas dispersion impeller with 1000rpm.Monitor H₂ Pressure, and when reactor is reduced to about 70psig, reactor is refilled to 100psig.After six hours, it will react cold But it is lower than 50 DEG C, and with nitrogen replacing hydrogen.By reaction mixture by diatomite vacuum filter to remove catalyst solid. By the distillation sequence and equipment similar with described in embodiment 5, olefin by-products and positive decene are removed from product.It is final to steam Evaporating pressure is about 0.1 support absolute pressure, and final fluid temperature is 195 DEG C.Olefin(e) centent is less than 1 mass %.It will finally produce The sample of object and methanol transesterification, and analyzed by GC.C18 fatty acid methyl ester (C18:2 adds C18:3) of how unsaturated contains Amount 3.88% reducing to 1.13% from raw material, and C21:2 diester is reduced from 6.40% in raw material to 3.72%.

Embodiment 9: liquid fabric reinforcing agent

By being mixed together to the ingredient being shown below to prepare fabric softener composition:

¹N, N- bis- (alkyloyloxyethyl ethyl)-N, N- alkyl dimethyl ammonium chloride, wherein alkyl is mainly made of C16-C18 alkyl chain, IV value is about 20, is purchased from Evonik

²Bis- [ethyl (tallow acid ester)] -2- hydroxyethyl ammonium methylsulfuric acid methyl esters, are purchased from Stepan

³N, N- bis- (alkyloyloxyethyl ethyl)-N, N- alkyl dimethyl ammonium chloride, wherein alkyl is made of C16-C18 alkyl chain, IV value It is about 52, is purchased from Evonik

⁴The reaction product of fatty acid and methyl diethanolamine, it is quaternized by chloromethanes, the N that molar ratio is 2.5:1 is obtained, N- bis- (tallowoyl base ethyl)-N, N- alkyl dimethyl ammonium chloride and N- (tallowoyl base ethyl) N- ethoxy-N, N- dimethyl The mixture of ammonium chloride is purchased from Evonik Corporation, Hopewell, VA.

⁵Low-molecular-weight alcohol, such as ethyl alcohol or isopropanol

⁶Cationic polyacrylamide polymer, such as acrylamide/[2- (acrylamido) ethyl] trimethyl ammonium chloride The copolymer of (quaternized dimethylaminoethyl acrylate), by trade name Rheovis CDX purchased from BASF, AG, Ludwigshafen。

⁷Trade name2280 dimercaptodimethyl ammonium chloride or with trade nameHTL8-MS is derived from Hydrogenated tallow alkyl (2- ethylhexyl) dimethyl methyl ammonium sulfate of AkzoNobel

⁸Fragrance microcapsule is purchased from ex Appleton Papers, Inc.

⁹Propoxylation amino-functional organic siloxane polymer, as described in United States Patent (USP) 8748646

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Embodiment 10

For hand-washing or the granular laundry detergent composition of washing machine (usually top-loaded formula washing machine).

(1) optionally.

(2) it is purchased from Appleton Paper (Appleton, WI)

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Embodiment 11

Commonly used in the granular laundry detergent composition of preceding loaded type automatic washing machine.

(1) optionally.

(2) it is purchased from Appleton Paper (Appleton, WI)

Typical pH is about 10.

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Embodiment 12: heavy duty liquid laundry detergent composition

(1) optionally.

(2) it is purchased from Appleton Paper (Appleton, WI)

(3) BASF, Ludwigshafen are purchased from

(4) by trade name Polymer PK or LR400 purchased from Dow Chemicals

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Embodiment 13: units dosage composition

* it is based on overall cleaning and/or treatment compositions poidometer, amounts to the water no more than 12%

(1) it is purchased from Appleton Paper (Appleton, WI)

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Embodiment 14: clothes washing lozenge composition

(5) it is purchased from Appleton Paper (Appleton, WI)

(6) BASF, Ludwigshafen are purchased from

(7) by trade name Polymer PK or LR400 purchased from Dow Chemicals

By conventional equipment known to persons of ordinary skill in the art, ingredient is merged and mixed.

Raw material and explanation for composition embodiment

LAS is to be supplied by Stepan (Northfield, Illinois, USA) or Huntsman Corp. with C₉-C₁₅ The linear alkylbenzene sulfonate (LAS) of average aliphatic carbon chain lengths (HLAS is sour form).

C_12-14Dimethyl hydroxyethyl ammonium chloride is supplied by Clariant GmbH (Germany).

AE3S is C_12-15Alkyl ethoxy (3) sulfate is supplied by Stepan (Northfield, Illinois, USA)

AE7 is C_12-15Alcohol ethoxylate, average degree of ethoxylation 7, by Huntsman (Salt Lake City, Utah, USA) supply

AES is C_10-18Alkyl ethoxy sulfate is supplied by Shell Chemicals.

AE9 is C_12-13Alcohol ethoxylate, average degree of ethoxylation 9, by Huntsman (Salt Lake City, Utah, USA) supply

HSAS or HC_16-17HSAS is the primary alkyl sulphates of mid-chain branched, the average carbon number with about 16-17.

Sodium tripolyphosphate is supplied by Rhodia (Paris, France)

Wessalith CS is supplied by Industrial Zeolite (UK) Ltd (Grays, Essex, UK)

1.6R silicate is supplied by Koma (Nestemica, Czech Republic)

Sodium carbonate is supplied by Solvay (Houston, Texas, USA)

The polyacrylate that molecular weight is 4500 is supplied by BASF (Ludwigshafen, Germany)

Carboxymethyl cellulose is supplied by CP Kelco (Arnhem, Netherlands)V

Suitable chelating agent is the diethylidene for example supplied by Dow Chemical (Midland, Michigan, USA) Four triamine pentaacetic acids (DTPA), or the hydroxyl supplied by Solutia (St Louis, Missouri, USA Bagsvaerd, Denmark) Ethane bisphosphonates (HEDP)

Celluclean^TM、 WithIt is the product of Novozymes (Bagsvaerd, Denmark).

Protease can be supplied by Genencor International (Palo Alto, California, USA) (for example, Purafect) or by Novozymes (Bagsvaerd, Denmark) supply (for example,)。

Fluorescent whitening agent 1 isAMS, fluorescent whitening agent 2 areCBS-X, sulfonation phthalocyanine phthalocyanine zinc and directly Purple 9 areViolet BN-Z, they by Ciba Specialty Chemicals (Basel, Switzerland it) supplies

SODIUM PERCARBONATE is supplied by Solvay (Houston, Texas, USA)

Sodium perborate is supplied by Degussa (Hanau, Germany)

NOBS is the nonanoyloxybenzene sulfonate supplied by Future Fuels (Batesville, USA).

TAED is tetra acetyl ethylene diamine, with trade nameBy Clariant GmbH (Sulzbach, Germany it) supplies.

S-ACMC is the carboxymethyl cellulose with C.I. active blue 19 conjugation, with ProductName AZO-CM-CELLULOSE (product code S-ACMC) is sold by Megazyme (Wicklow, Ireland).

Detergent is supplied by Rhodia (Paris, France)PF

Acrylic acid/maleic acid molecular weight is 70,000, and acrylic acid radical and the ratio of maleate are 70: 30, it is supplied by BASF (Ludwigshafen, Germany)

The sodium salt of ethylenediamine-N, N'- disuccinic acid, (S, S) isomers (EDDS) by Octel (Ellesmere Port, UK it) supplies

Hydroxyl ethane bisphosphonates (HEDP) are supplied by Dow Corning (Midland, Michigan, USA)

Foam inhibitor agglomerate is supplied by Dow Corning (Midland, Michigan, USA)

C_12-14Dimethyl amine is supplied by Procter&Gamble Chemicals (Cincinnati, USA)

Random graft copolymer is the polyethylene oxide copolymer of polyvinyl acetate grafting, with polyethylene oxide master Chain and multiple polyvinyl acetate ester side chains.The molecular weight of the polyethylene oxide main chain is about 6000, and polyethylene oxide with The weight ratio of polyvinyl acetate is about 40:60, and every 50 ethylene oxide units have no more than 1 grafting site.

Ethoxylated polyethylene imines are the polyethyleneimine (MW=that each-NH has 20 ethoxylate groups 600)。

Cationic cellulose polymer be LK400 derived from Amerchol Corporation (Edgewater NJ), LR400 and/or JR30M.

Note: all enzyme contents are represented as proenzyme material %.

Embodiment 15

The embodiment of free flowing granule product comprising glycerol ester copolymer according to the present invention.

(1)PEG

(2) clay

(3) urea

(4) polysaccharide, most starches, unmodified starch, starch derivatives, the modified starch of acid and kappa carrageenan

(5) zeolite

(6) starch/zeolite-SEA

(7) metal oxide-non-limiting example-TiO2, ZnO, MnO

(8) metallic catalyst

(9) opacifier

(10) Appvion, Appleton, WI are purchased from.

Composition by being formulated offer above is by combining such components according to the preparation method provided in this specification And it is made.

Dimension disclosed herein and value are not understood as being strictly limited to cited exact numerical.On the contrary, unless in addition It indicates, otherwise each such dimension is intended to indicate that described value and the range functionally equivalent around the value.For example, being disclosed as The dimension of " 40mm " is intended to indicate that " about 40mm ".

The relevant portion of cited All Files is herein incorporated by reference in a specific embodiment of the invention； The reference of any file is not construed as to recognize that it is the prior art for the present invention.When term in this document Any meaning or definition with any meaning of same term in file incorporated by reference or define mutually conflict when, should Obey the meaning or definition for assigning the term in this document.

Although specific embodiments of the present invention have had been illustrated and described, to those skilled in the art It is readily apparent that a number of other change and modification can be made without departing from the spirit and scope of the present invention.Therefore, It is intended to all such change and modification for covering in appended claims and belonging in the scope of the invention.

Claims (16)

1. a kind of composition, the composition includes:

A) it is selected from following material:

(i) the first glycerol ester copolymer, it includes the total weights 3% to 30% based on the first glycerol ester copolymer, preferably 3% to 25%, more preferably 5% to 20% C_10-14Unsaturated fatty acid ester；Preferably, the first glycerol ester copolymer packet Containing the total weight 3% to 30% based on the first glycerol ester copolymer, preferably 3% to 25%, more preferably 3% to 20% C_10-13Unsaturated fatty acid ester；It is highly preferred that the first glycerol ester copolymer includes based on the total of the first glycerol ester copolymer Poidometer 0.1% to 30%, preferably 0.1% to 25%, more preferably 0.2% to 20%, most preferably 0.5% to 15% C_10-11Unsaturated fatty acid ester；

(ii) with the second glycerol ester copolymer of formula (I):

Wherein:

Each R in second glycerol ester copolymer¹、R²、R³、R⁴And R⁵Independently selected from: oligomeric glyceride fraction, C_1-24Alkyl, Wherein substituent group is the substituted C of the part one or more-OH_1-24Alkyl, C_2-24Alkenyl or in which substituent group be one or The substituted C of multiple parts-OH_2-24Alkenyl；And/or wherein each of following combination of each section can respectively solely On the spot it is covalently attached:

R¹And R³,

R²And R⁵,

R¹With adjacent R⁴,

R²With adjacent R⁴,

R³With adjacent R⁴,

R⁵With adjacent R⁴, or

Any two adjacent R⁴

So that the part of the covalent linkage forms alkenylene moieties；

Each X in the second glycerol ester copolymer¹And X²Independently selected from: C_1-32Alkylidene, wherein substituent group be one or The substituted C of multiple parts-OH_1-32Alkylidene, C_2-32Alkenylene or in which substituent group are the quilt of the part one or more-OH Substituted C_2-32Alkenylene；

G¹、G²And G³In two be-CH₂, and G¹、G²And G³In one be direct key；

For the independent repetitive unit of each of repetitive unit with index n, G⁴、G⁵And G⁶In two be-CH₂, and G⁴、G⁵And G⁶In one be direct key, and the value G of each individually repetitive unit⁴、G⁵And G⁶It is repeated independently selected from other single G in member⁴、G⁵And G⁶Value；

G⁷、G⁸And G⁹In two be-CH₂, and G⁷、G⁸And G⁹In one be direct key；

The integer that n is 3 to 250；

Precondition is for each in the second glycerol ester copolymer, R¹、R²、R³And R⁵At least one of, and/or At least one R in the independent repetitive unit of one of the repetitive unit with index n⁴It is selected from: 8- nonenyl；8- decene Base；8- undecenyl；8- dodecenyl succinic；12 carbon dialkylene of 8,11-；8,11- oleatridecadiene base；14 carbon of 8,11- Dialkylene；8,11- pentadecane dialkylene；8,11,14- pentadecane trialkenyl；16 carbon trialkenyl of 8,11,14-；8,11,14- ten Eight carbon trialkenyls；9- methyl -8- decene base；9- methyl -8- undecenyl；10- methyl -8- undecenyl；12- methyl- 8,11- oleatridecadiene base；14 carbon dialkylene of 12- methyl -8,11-；14 carbon dialkylene of 13- methyl -8,11-；15- first 16 carbon trialkenyl of base -8,11,14-；17 carbon trialkenyl of 15- methyl -8,11,14-；17 carbon three of 16- methyl -8,11,14- Alkenyl；12- tridecylene base；12- tetradecene base；12- pentadecane alkenyl；12- hexadecene base；13- methyl-1 2- 14 Carbene base；13- methyl-1 2- pentadecane alkenyl；With 14- methyl-1 2- pentadecane alkenyl；Preferably, second glyceride is total Polymers include the total weight 3% to 30% based on the second glycerol ester copolymer, preferably 3% to 25%, more preferably 5% to 20% C_9-13Alkenyl part；Preferably, the second glycerol ester copolymer includes the gross weight based on the second glycerol ester copolymer Meter 3% to 30%, preferably 3% to 25%, more preferably 3% to 20% C_9-12Alkenyl part；It is highly preferred that described Two glycerol ester copolymers include the total weight 0.1% to 30% based on the second glycerol ester copolymer, preferably 0.1% to 25%, more preferably 0.2% to 20%, most preferably 0.5% to 15% C_9-10Alkenyl part；And

(iii) their mixture；

Preferably, first copolymer and second copolymer have 4,000g/mol to 150,000g/mol, preferably 5,000g/mol to 130,000g/mol, more preferably 6,000g/mol to 100,000g/mol, more preferably 7,000g/mol To 50,000g/mol, more preferably 8,000g/mol to 30,000g/mol, most preferably 8,000g/mol to 20,000g/mol Weight average molecular weight, and the composition is preferably included based on general composition weight meter 0.1% to 50%, preferably 0.5% to 30%, more preferably 1% to 20% glycerol ester copolymer, the glycerol ester copolymer is selected from first glycerol Ester copolymer, the second glycerol ester copolymer and their mixture；And

B it) is selected from following material: fabric softener active, fabric care benefit agents, anionic surfactant is removed Agent, delivery enhancer, fragrance, perfume delivery systems, structural agent, soil dispersion polymer, brightening agent, dope dye, dyestuff turn Inhibitor, builder, surfactant, enzyme, preferably detergency enzymes and their mixture, and optionally carrier are moved, it is excellent Selection of land, the composition have 2 to 12 pH；

The composition is Fabrid care composition.

2. composition according to claim 1, wherein for the second glycerol ester copolymer, R¹、R²、R³、R⁴Or R⁵In At least one be C_9-13Alkenyl, preferably C_9-12Alkenyl, more preferably C_9-10Alkenyl.

3. composition according to any one of the preceding claims, wherein for the second glycerol ester copolymer, R¹For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R¹Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11, 14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- Methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 14 carbon of 12- Alkenyl, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl, With 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R¹It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- 12 carbon dialkylenes, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11, 16 carbon trialkenyl of 14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

4. composition according to any one of the preceding claims, wherein for the second glycerol ester copolymer, R²For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R²Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11, 14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- Methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 14 carbon of 12- Alkenyl, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl, With 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R²It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- 12 carbon dialkylenes, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11, 16 carbon trialkenyl of 14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

5. composition according to any one of the preceding claims, wherein for the second glycerol ester copolymer, R³For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R³Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11, 14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- Methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 14 carbon of 12- Alkenyl, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl, With 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R³It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- 12 carbon dialkylenes, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11, 16 carbon trialkenyl of 14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

6. composition according to any one of the preceding claims, wherein for the second glycerol ester copolymer, each R⁴ Independently selected from C_1-24Alkyl and C_2-24Alkenyl；Preferably, each R⁴Independently selected from: 8- nonenyl, 8- decene base, 8- 11 Carbene base, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8, 11- pentadecane dialkylene, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon triolefin of 8,11,14- Base, 9- methyl -8- decene base, 9- methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- 13 Carbon dialkylene, 14 carbon dialkylene of 12- methyl -8,11-, 14 carbon dialkylene of 13- methyl -8,11-, 15- methyl -8,11,14- 16 carbon trialkenyls, 17 carbon trialkenyl of 15- methyl -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- ten Three carbene bases, 12- tetradecene base, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- Methyl-1 2- pentadecane alkenyl and 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that each R⁴Independently selected from: 8- nonene Base, 8- decene base, 8- undecenyl, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon diene of 8,11- Base, 8,11,14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

7. composition according to any one of the preceding claims, wherein for the second glycerol ester copolymer, R⁵For C_1-24Alkyl or C_2-24Alkenyl；Preferably, R⁵Be selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8- dodecenyl succinic, 12 carbon dialkylene of 8,11-, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11- pentadecane dialkylene, 8,11, 14- pentadecane trialkenyl, 16 carbon trialkenyl of 8,11,14-, 18 carbon trialkenyl of 8,11,14-, 9- methyl -8- decene base, 9- Methyl -8- undecenyl, 10- methyl -8- undecenyl, 12- methyl -8,11- oleatridecadiene base, methyl -8 12-, 14 carbon dialkylene of 11-, 14 carbon dialkylene of 13- methyl -8,11-, 16 carbon trialkenyl of 15- methyl -8,11,14-, 15- first 17 carbon trialkenyl of base -8,11,14-, 17 carbon trialkenyl of 16- methyl -8,11,14-, 12- tridecylene base, 14 carbon of 12- Alkenyl, 12- pentadecane alkenyl, 12- hexadecene base, 13- methyl-1 2- tetradecene base, 13- methyl-1 2- pentadecane alkenyl, With 14- methyl-1 2- pentadecane alkenyl；It is highly preferred that R⁵It is selected from: 8- nonenyl, 8- decene base, 8- undecenyl, 8,11- 12 carbon dialkylenes, 8,11- oleatridecadiene base, 14 carbon dialkylene of 8,11-, 8,11,14- pentadecane trialkenyl, 8,11, 16 carbon trialkenyl of 14-, 12- tridecylene base, 12- tetradecene base and 12- pentadecane alkenyl.

8. composition according to any one of the preceding claims, the composition includes one or more in following item :

A) 0.01% to 50%, preferably 0.01% to 30%, more preferably 0.1% to 20% fabric softener activity Substance；

B) 0.001% to 15%, preferably 0.05% to 10%, more preferably 0.05% to 5% anionic surface is living Property agent scavenger；

C) 0.01% to 10%, preferably 0.05% to 5%, more preferably 0.05% to 3% delivery enhancer；

D) 0.005% to 30%, preferably 0.01% to 20%, more preferably 0.02% to 10% fragrance；

E) 0.005% to 30%, preferably 0.01% to 20%, more preferably 0.02% to 10% fragrance delivers body System；

F) 0.01% to 20%, preferably 0.1 to 10%, more preferably 0.1% to the 5% soil dispersion polymer；

G) 0.001% to 10%, preferably 0.005 to 5%, more preferably 0.01% to 2% brightening agent；

H) 0.0001% to 10%, preferably 0.01% to 2%, more preferably 0.05% to 1% dope dye；

I) 0.0001% to 10%, preferably 0.01% to 2%, more preferably 0.05% to the 1% dyestuff metastasis suppressor Agent；

J) 0.01% to 10%, preferably 0.01% to 5%, more preferably 0.05% to 2% enzyme, it is preferable that described Enzyme is detergency enzymes；

K) 0.01% to 20%, 0.1% to 10% or 0.1% to 5% the structural agent；

L) 0.05% to 20%, preferably 0.1% to 15%, more preferably 0.2% to 7% fabric care benefit agents；

If m) composition is powder laundry detergent, the composition includes 0.1% to 80% builder, And if the composition is liquid laundry detergent, the composition includes 0.1% to 20% builder；

N) 0.1% to 99% carrier；And

O) their mixture.

9. composition according to any one of the preceding claims, in which:

A) fabric softener active includes cationic fabric softener, it is preferable that the cationic softener is selected from Double-(2- hydroxypropyl)-dimethyl ammonium methyl sulfate aliphatic ester, 1,2- bis- (acyloxy) -3- trimethyl ammonium chloride propane, N, N- Bis- (stearoyl-oxy ethyl)-N, N- alkyl dimethyl ammonium chloride, N, bis- (tallowoyl base the ethyl)-N of N-, N- alkyl dimethyl ammonium chloride, Bis- (stearoyl-oxy ethyl)-N- (2- the ethoxy)-N- methylammonium-methosulfates, N of N, N-, N- bis- (stearoyl -2- hydroxypropyls) - N, N- dimethyl ammonium methyl sulfate, N, bis- (tallow acyl -2- the hydroxypropyl)-N of N-, N- dimethyl ammonium methyl sulfate, N, the bis- (palms of N- Acyl -2- hydroxypropyl)-N, N- dimethyl ammonium methyl sulfate, N, bis- (stearoyl -2- the hydroxypropyl)-N of N-, N- alkyl dimethyl ammonium chloride, 1, 2- bis- (stearoyl-oxy) -3- trimethyl ammonium chloride propane, two mustard alkyl dimethyl ammonium chlorides, two tallow dimethyl ammonium chlorides, two Mustard dimethyl ammonium methyl sulfate, 1- methyl-1-stearoyl amido ethyl-2- stearyl methylsulfuric acid imidazoline, 1- ox Rouge amido-ethyl -2- tallow acyl imidazoline, two palm ethyl-hydroxyethyl methylsulfuric acid ammoniums and their mixture；

B) the anionic surfactant scavenger includes water-soluble cationic and/or amphoteric ion scavenger compounds；It is excellent Selection of land, the anionic surfactant scavenger are selected from monoalkyl ammonium quat and its amine precursor, dialkyl quats chemical combination Object and its amine precursor, poly quaternary ammonium compound and its amine precursor, polymeric amine and their mixture；

C) delivery enhancer includes to be selected from following material: charge density is 0.05 milliequivalent/gram to 23 milliequivalents/gram poly- Close the cationic polymer of object, charge density is 0.05 milliequivalent/gram to 23 milliequivalents/gram polymer amphoteric polymer, electricity Lotus density is 0.05 milliequivalent/gram to 23 milliequivalents/gram protein protein and their mixture；

D) perfume delivery systems are selected from polymer assisted delivery (PAD) system, molecule-assisted delivery (MAD) system, ring paste Smart (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic carrier (ZIC) system and their mixture；

E) the soil dispersion polymer is selected from the homopolymerization composition copolymer of ethylenically unsaturated monomers anionic monomer or ternary is total to Polymers, it is preferable that the anionic monomer be selected from acrylic acid, methacrylic acid, methyl methacrylate, itaconic acid, fumaric acid, 3- allyloxy -2- hydroxyl -1- propane-sulfonic acid (HAPS) and its salt, allyl sulphonic acid and its salt, maleic acid, vinyl sulfonic acid, Styrene sulfonic acid, acrylamide propyl Loprazolam (AMPS) and its salt, their derivative and combination, alkoxylated polyamines, In one aspect, alkoxylate polyethylene imine and their mixture；

F) brightening agent is selected from following derivative: talan or 4,4'- diaminobenzil, biphenyl, five-ring heterocycles, Preferably triazole, pyrazoline, oxazole, imidazoles, hexa-member heterocycle, preferably cumarin, naphthalene amino acid, s-triazine and theirs is mixed Close object；

G) dope dye includes to be selected from following part: acridine, anthraquinone, preferably polycyclic quinone, azine, azo, preferably Monoazo, bisazo, trisazo-, four azos, polyazo, pre-metallization azo, two furans of benzo and benzodifuranone, class is recklessly Radish element, cumarin, Hua Jing, half flower cyanines of diaza, diphenyl-methane, formazan, half flower cyanines, indigoid, methane, naphthalimide, naphthoquinones, Nitro and nitroso, oxazines, phthalocyanine, pyrazoles, talan, styryl, triarylmethane, triphenylmenthane, xanthene and it Mixture；

H) dye transfer inhibitor is selected from polyvinylpyrrolidonepolymers polymers, polyamine N-oxide pllymers, N- ethylene The copolymer of the copolymer of base pyrrolidones and N- vinyl imidazole, polyvinyl oxazolidone and polyvinyl imidazol or they Mixture；

I) bleaching agent is selected from catalytic metal complexes；Activated peroxygen source；Bleach-activating；Bleach boosters；Optical white； Bleaching enzymes；Radical initiator；H₂O₂；Hypohalite beaches；Peroxygen source and their mixture；

J) detergency enzymes are selected from hemicellulase, peroxidase, protease, cellulase, zytase, lipase, phosphatide Enzyme, esterase, cutinase, pectase, keratanase, reductase, oxidizing ferment, phenol oxidase, lipoxygenase, lignoenzyme, Pu Lu Blue enzyme, tannase, pentosanase, Mai Laning enzyme, 1,4 beta-glucanase, arabinosidase, hyaluronidase, chondroitinase, paint Enzyme, amylase and their mixture；

K) structural agent is selected from rilanit special, gellan gum, starch, derivatized starch, carrageenan, guar gum, pectin, xanthan Glue, modified cellulose, microcrystalline cellulose, modified protein, hydrogenated polyolefins, non-hydrogenated polyolefin, inorganic salts, it is preferable that institute State inorganic salts be selected from magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminium chloride, potassium permanganate and their mixture, clay, Homopolymer and copolymer comprising cationic monomer, the cationic monomer are selected from methacrylic acid N, N- dialkyl aminoalkyl Ester, methacrylic acid N, N- dialkyl aminoalkyl methyl ester, acrylic acid N, N- dialkyl aminoalkyl ester, N, N- dialkyl amino Base alkyl acrylamide, N, N- dialkyl aminoalkyl Methacrylamide, quaternized methacrylic acid N, N- dialkyl amido Arrcostab, quaternized methacrylic acid N, N- dialkyl aminoalkyl methyl ester, quaternized acrylic acid N, N- dialkyl amido alkane Base ester, quaternary ammonium N, N- dialkylaminoalkyl acrylamide, quaternary ammonium N, N- dialkyl aminoalkyl Methacrylamide, with And their mixture, it is preferable that when the composition is liquid laundry detergent composition, the structural agent includes hydrogenation Castor oil；Preferably, when the composition is rinse added fabric reinforcing agent, the structural agent includes quaternized acrylic acid N, N- dialkyl aminoalkyl ester and/or quaternized methacrylic acid N, the straight chain of N- dialkyl aminoalkyl ester and/or crosslinking are equal Polymers and/or copolymer；

1) fabric care benefit agents are selected from polyglycerol ester, oiliness sugar derivatives, wax emulsion, siloxanes, polyisobutene, polyene Hydrocarbon and their mixture；

M) builder is selected from phosphate, water-soluble non-phosphorus organic washing-assisting detergent, alkali metal, ammonium and the poly- acetic acid of substituted ammonium Salt, carboxylate, polycarboxylate, polyhydroxy sulfonate, it is preferable that the builder is selected from ethylenediamine tetra-acetic acid, three second of nitrilo- Acid, oxygen union II succinic acid, mellitic acid, benzene polycarboxylic acid, the sodium salt of citric acid, sylvite, lithium salts, ammonium salt and substituted ammonium salt, Oxygen union II succinate, ether carboxylate, tartrate monosuccinic acid salt, tartaric acid disuccinate, silicate, aluminosilicate, boron Hydrochlorate, carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, zeolite and their mixture；

N) surfactant be selected from anionic surfactant, nonionic surfactant, amphoteric surfactant, sun from Sub- surfactant, zwitterionic surfactant and their mixture；

O) carrier is selected from water, 1,2-PD, hexylene glycol, ethyl alcohol, isopropanol, glycerol, C₁-C₄Alkanolamine, salt, sugar gather Alkylene oxide, preferably polyethylene oxide；Polyethylene glycol；Polypropylene oxide and their mixture.

10. the composition includes according to claim 1 to composition described in 9:

A) 49 to 99% carrier, the carrier are selected from polyethylene glycol, salt, polysaccharide and sugar；Preferably molecular weight be 2000Da extremely 20,000Da polyethylene glycol, more preferably molecular weight are the polyethylene glycol of 3,000Da to 12,000Da, and most preferably divide The polyethylene glycol that son amount is 6,000Da to 10,000Da；

B) optionally, fabric care benefit agents, preferably siloxanes；

C) optionally fragrance；

D) optionally perfume delivery systems；

E) optionally delivery enhancer.

11. composition according to any one of claim 1 to 9, the composition includes:

A) fabric softener, fragrance and delivery enhancer；Or

B) fabric softener, fragrance and perfume delivery systems；Or

C) dope dye and surfactant；Or

D) it is less than 10% total water, total water is free water and the summation for combining water；Or

E) fabric softener, fabric care benefit agents and delivery enhancer；Or

G) fabric care benefit agents, anionic surfactant scavenger and delivery enhancer；Or

H) perfume delivery systems, it is preferable that it is auxiliary that the perfume delivery systems are selected from polymer assisted delivery (PAD) system, molecule Help delivering (MAD) system, cyclodextrin (CD) system, starch encapsulated temper (SEA) system, zeolite and inorganic carrier (ZIC) body System；The preferably PMC of two or more seed types.

12. composition according to any one of claim 1 to 10, the composition is the shape of crystal, bead or pastille Formula, it is preferable that the composition includes to be based on general composition weight meter 0.1% to 50%, and preferably 0.5% to 30%, it is more excellent The glycerol ester copolymer of selection of land 5% to 30%, the glycerol ester copolymer are selected from the first glycerol ester copolymer, the second glycerol Ester copolymer and their mixture, it is preferable that the bead has shape, and the shape is circle, diamond shape, vault Push up shape or the semicircle with planar base portion.

13. a kind of product, the product includes composition according to any one of claim 1 to 9, and the product is to dry The form of dry machine paper.

14. a kind of fabric, the fabric to composition described in 12 and/or according to claim 13 institute according to claim 1 The product processing stated.

15. a kind of method of processing and/or clean textile, which comprises

A) optionally wash and/or rinse the fabric；

B) make the fabric and according to claim 1 to composition described in 12 and/or product according to claim 13 Contact；

C) optionally wash and/or rinse the fabric；And

D) optionally it is passively or actively the dry fabric.

16. composition according to any one of claim 1 to 12, wherein the first glycerol ester copolymer and described Two glycerol ester copolymers have the poidometer 0% to 5% based on glycerol ester copolymer, preferably 0.1% to 5%, more preferably 0.1% to 4%, more preferably 0.1% to 3%, most preferably 0.1% to 1% free hydrocarbon content.