CN109632682A - The two-parameter fast qualitative screening detector of animality novel trench oil - Google Patents

The two-parameter fast qualitative screening detector of animality novel trench oil Download PDF

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Publication number
CN109632682A
CN109632682A CN201910123317.7A CN201910123317A CN109632682A CN 109632682 A CN109632682 A CN 109632682A CN 201910123317 A CN201910123317 A CN 201910123317A CN 109632682 A CN109632682 A CN 109632682A
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chip
oil
detector
animality
novel trench
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罗舒
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/02Investigating or analyzing materials by the use of thermal means by investigating changes of state or changes of phase; by investigating sintering
    • G01N25/04Investigating or analyzing materials by the use of thermal means by investigating changes of state or changes of phase; by investigating sintering of melting point; of freezing point; of softening point

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
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  • Pathology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Fats And Perfumes (AREA)

Abstract

To solve the deficiencies in the prior art, this patent provides the two-parameter fast qualitative screening detector of animality novel trench oil, including Switching Power Supply U1, DC-DC chip U2 and U3, temperature detection chip U4, temp probe PT100, main control chip U5, solid-state relay U6, heater HEATER, display screen LCD, triode Q1, ultraviolet-ray diode UV-LED, UV detector U7;Switching Power Supply U1 connection DC-DC chip U2 and U3, the U2 connection of DC-DC chip temperature detection chip U4 and main control chip U5, DC-DC chip U3 connection display screen LCD and UV detector U7, main control chip U5 is separately connected temperature detection chip U4, display screen LCD, solid-state relay U6, UV detector U7, triode Q1 connection ultraviolet-ray diode UV-LED, solid-state relay U6 connection heater HEATER, temp probe PT100 connection temperature detection chip U4.This instrument detection parameters are the fusing point and ultraviolet absorbance of novel trench oil, much more convenient than spectral detection, are relatively suitble to public security, and industrial and commercial, quality inspection carries out on-site law-enforcing primary dcreening operation, are especially suitable for the primary dcreening operation detection of novel trench oil incorporation edible oil.

Description

The two-parameter fast qualitative screening detector of animality novel trench oil
Technical field
This instrument relates generally to novel trench oil detector, and in particular to the two-parameter fast qualitative of animality novel trench oil Screening detector.
Background technique
Novel trench oil refers to part oil refining workshop by Animal Skin inferior, expired, corrupt, meat, internal organ by processing The grease produced after refinement.It is identical in appearance as regular oil product after the finishing such as decoloration, deodorizing, high temperature tanning, Finally be made into butter, food, chafing dish bottom flavorings etc. enters field of food to these novel trenchs oil.It is so-called new, mainly It is different from the gutter oil made of kitchen garbage that we were understood in the past, no matter which kind of gutter oil can all cause human body very greatly Harm.
Saturated fatty acid, trans-fatty acid, cholesterol in novel trench oil are apparently higher than normal edible oil and fat, through often eating It is caused huge harm with to human body cardiovascular and cerebrovascular, gutter oil can be mixed into detergent ingredients (detergent alkylate sulphur during collection Sour sodium), neopelex is a kind of oleophylic and hydrophilic moderate toxicity substance, has carcinogenesis.
Novel trench oil is in underground and cement wall (containing the microelements such as As, Pb, Cd), the sewage of underground, waste and old iron The contacts such as putrefactions, the rubbish of life, the various bacteria toxin such as bucket, fruit and vegetables, can gradually occur hydrolysis, oxidation, condensation, Polymerization, color such as deepen at a series of variations, generate peroxide, multiring aromatic hydrocarbon substance, low molecule decomposition product (such as ferment, ketone Deng) etc..
Novel trench oil container containing generally uses non-edible plastic, under sunlight irradiation, toxic oligomer, list Body, plasticizer, high-molecular compound and heavy metal can dissolve in grease, seriously endanger digestion and nervous system.
Rotten residue can generate mycotoxin secondary metabolic product during its growth and breeding containing a large amount of moulds, Such as aflatoxin, sickle mycete toxin biotoxin, the toxicity of aflatoxins are 100 times of arsenic, aflatoxin quilt International cancer research institution, the World Health Organization (International Agency for Research on Cancer, WHO/ IARC it) is classified as I class carcinogenic substance, to the very harmful of human body.
Currently, novel trench oil component quantitative measurement technology mainly have infra-red sepectrometry, chromatography, isotope method of comparison, Fluorescent spectrometry, nuclear magnetic resonance method etc., can in quantitative detection oil samples allogenic material content, but above-mentioned instrument price is very Valuableness, and professional technician is needed to operate.
It is very rare that developed country's novel trench oil passes into edible oil case, because they take from source More effective measures, such as Japanese government's high price recycling gutter oil, are made biodiesel, it is useless that special recovery point recycling is arranged in Britain Oil is focused on, and is provided at Britain's environment, food and Rural Affairs, from October 31st, 2004, food and drink place was cooked Waste oil is adjusted no longer to be used as animal feed, food production oil and original cooking oil can continue to serve as animal feed, appoint It will be illegal if who eats the cooked waste oil feeding animals of onstage before starting on a long aria.China's grease usage amount is big, and cycling and reutilization is insufficient, leads It causes gutter oil illegally to recycle, returns to dining table after refined.
In terms of S&T papers:
Wu Jun " Study on Preparation that gutter oil methyl esters produces biological aviation kerosine catalyst " Beijing University of Chemical Technology .2018.
Each of Wang Hua " gutter oil pretreatment and a step add hydrogen aviation kerosine experimental study " Kunming University of Science and Technology .2018.
Su Lin (Dona SOULIYATHAI) " combustion characteristics in industrial furnace of gutter oil and its biodiesel and its Sunykatuib analysis " Yunnan Normal University .2018.
Yu Huimei " technique, characterization and the flotation performance research that waste cooking oil the prepares fatty acid collecting agent " Beijing science and technology University, university .2018.
Fan Hui " the gutter oil properties study based on multispectral technology Yu optical chromatography method " Kunming University of Science and Technology .2018。
Shi Yaxin " the gutter oil detection technique research based on animal sources genetic analysis " Xi'an Technological University .2017.
Each of Wang Hua " gutter oil detection method optimizing research " Xibei Univ. of Agricultural & Forest Science & Technology .2016.
Wang Li " combustion characteristics and its sunykatuib analysis of gutter oil and its biodiesel in the industrial furnace " Shaoyang institute .2015。
Wang Tongzhen " foundation of edible oil fatty acid profile and its application in gutter oil detection " Kunming University of Science and Technology .2018。
Tian Qili " gutter oil identification and Optical characteristics based on terahertz time-domain spectroscopic technology " Guangdong Industrial University .2015.
Wang Jieni " the improved research of gutter oil biodiesel lower-temperature fluidity " Shanghai Institute Of Technology .2015.
Ye Qin " the edible oil adulteration analyte research based on FTIR technology " Zhejiang Polytechnical University .2015.
Wang Xiaole " quickly detects the new side of gutter oil based on activated carbon fibre-solid phase micro-extraction technique and GC-MS combination Method " Shanghai Communications University .2015.
Du Weizhao is " for identifying the soybean oil substrate standard substance of gutter oil and grinding for olive oil substrate standard substance System " Beijing University of Chemical Technology .2015.
It is big that Wang Rongrong " detects based on the gutter oil of three-dimensional fluorescence spectrum technology and dynamic light scattering technique and study " Chongqing Learn .2013.
Wang Pan " research and design of gutter oil detection spectrometer " Wuhan Polytechnic University .2013.
Shi Jing " the gutter oil detection method research based on raman scattering spectrum " Changchun University of Science and Technology .2014.
Wang Yongwei " gutter oil based on dielectric spectra technology detects research " He'nan University of Technology .2012.
Li Zhixing " bad edible oil electro-optical characteristic detection technique research is mixed under multiple activation " He'nan University of Technology .2013.
Zhang Shaomin " gutter oil comprehensive utilization " University Of Science and Technology of the Inner Mongol .2012.
Yang Pei " the binary channels gutter oil detection method based on DSP digital Lock-in Amplifier " Shenyang University of Technology .2013.
Li Shiyan " detection and analysis of used edible oil and identification method research " Zhejiang Prov Industrial And Commercial University .2012.
Zhu Rui " edible oil mixes the research of gutter oil detection method and device " Kunming University of Science and Technology .2010.
Huang Fang " metal ion in flame atomic absorption spectrometry gutter oil " " Nanjing Xiaozhuang College's journal " .2018.
Wu Zhenpeng;Zhao Xinchao;The red of Jian's English " optimizing research of remaining meal gutter oil de-alkali additives " " Chinese oil " .2018。
Xie Tingyi " applied analysis of the spectral technique in gutter oil detection " " food safety guide " .2018.
Hu Xiaohui;Wang Lei;Yao Shuai;Xiao Bing " the gutter oil recognition methods based on gas sensor array " " observing and controlling skill Art " .2017.
Jian's English is red;Fan Ningwei;Xin Bingjing;Wei Wei;" remaining meal gutter oil comprehensive utilization pretreatment technology is ground Wang Hong Study carefully " " scientific and technical innovation and application " .2017.
Song Jiayu;Chen Jindong;Liu Wenjie;Zhou Jingyang;" oil fatty acid fingerprint base constructs and in edible oil and fat Jiang great Feng Gutter oil classification is applied in identifying " " Chinese public health " .2017.
Shi Shengda;Chen Fengying;Liu Xingwei;Liu Mingxuan;Liu Kaiqian " the gutter oil frequency tester based on 555 oscillators " " electronic production " .2017.
Lin Chao " utilization of the gutter oil Fast Detection Technique in foods supervision " " food safety guide " .2017.
Zhang Peiqiang;Zhang Jin;Fan Zhinan;Wang Bin;Tong little Fan " second dervative Fourier transform infrared spectroscopy differential plant oil And gutter oil " " Chinese oil " .2017.
Chen Lihua;Hao Delan;Zhu Chuchu;Rong Yuzhi;Li Bin " the analysis and identification technique study of gutter oil " " food work Industry " .2017.
Zhang Gaoqi;Tao Xiankun;Wang Chen;Zhao Chuntao;Tan Wenying " Preparation of biodiesel from waste oils decolorising agent and is urged The selection of agent " " Chemical Industry in Guangzhou " .2017.
Peng Yuanhuai;Lu Meiying;Li Haiyan " research of lipase hydrolysis preparing fatty acid by illegal cooking oil " " grain and oil Rouge " .2017.
Yang Xiaoqin;Yellow elementary wave;Zheng Yunwu;Liu Can;" ion-exchange resin catalyzed gutter oil synthesizes green plasticization to Ai Xiaolu The research of agent " " Chinese oil " .2017.
Hu Xinyu " the gutter oil assay based on electrical conductivity method " " technology of Internet of things " .2017.
Zhang Hui;Mao Rungan;Zheng Jihuan;Luo Xudong " transmission of gutter oil EO-1 hyperion tests and analyzes " " grain and grease " .2017。
Liu Honghua;Wu Haiyun;Shang Youshan;Chen Wenjiang " piezoelectric biological sensor quickly identifies gutter oil research " " agriculture Technical service business " .2017.
Song Chongfu;Tian Zhimei;Yang Haicheng;Xia Juan;" swill-cooked dirty oil rapid detecting method based on conductance measurement is ground Liu Xin Study carefully " " Chemical Industry in Guangzhou " .2017.
Wu Chunying;Egression;Valley wind;Wei Wei " aflatoxin and BaP in measurement gutter oil " " food industry " .2017。
Ji Xiaofeng;Chen Huarui " innovation and application of the colloidal gold in gutter oil quickly detects " " chemical education " .2016.
Hu Ruibin;Cao Kezhong;Quan Yan;Lu Zhe;Li Shangze " swill-cooked dirty oil rapid detecting method research and development " " science and technology wound Newly with application " .2016.
Song Chongfu;Wang Jie;Tian Zhimei;Yellow Deccan;Xu Huajie " identifying gutter oil and edible oil with acid value determination method " " place State institute journal " .2016.
Liu Hailong " progress of gutter oil detection method " " Shandong chemical industry " .2016.
Chen Minghui;Fan Yunping;Li Hao;Zheng Gang " application study of the fluorescence lifetime analysis method in gutter oil identification " " laser biology journal " .2016.
In terms of domestic patent:
The Xiong Huanhuan of generation sheet (Tianjin) Environmental Technology AS;Yang Jiao cloud;Hu Chunping;The Chinese utility model of Shen Wang application is special Sharp " a kind of gutter oil heating kettle ", number of patent application 201820150548, Authorization Notice No. CN207313558U.
The Li Guanghuang of Shenzhen Saiyi Science And Technology Development Co., Ltd;Luo Hui;Du Lijuan;Deep state is secret;Zhong Zhiwei;Chen Yang;Flood It is auspicious it is dry applied Chinese utility model patent " it is a kind of based on electronic nose detection gutter oil device ", number of patent application 201721150540, Authorization Notice No. CN207366488U.
A kind of Feng Xuemin application of Chongqing Three Gorges Professional School Chinese utility model patent " gutter oil on-site test dress Set ", number of patent application 201721098887, Authorization Notice No. CN207379969U.
The Wang Weiming of Zhejiang Vocational College of Commerce has applied for a kind of Chinese utility model patent " computer digitlization Gutter oil detects display device ", number of patent application 201720552171, Authorization Notice No. CN206710411U.
The Shi Shengda of Nanchang University of aviation;Chen Fengying;Liu Kaiqian;Liu Xingwei;Liu Mingxuan;Yang Zhihao application is Chinese practical New patent " gutter oil detector ", number of patent application 201720409285, Authorization Notice No. CN206696222U.
The clock woods application Chinese invention patent of thanking of eco-friendly power source Co., Ltd is initiated in Yangzhou, and " a kind of trench grease removes in batches Miscellaneous metering and the miscellaneous isolated method of water ", number of patent application 201811328026, application publication number CN109161446A.
The graduate Yuan Hui of Xinjiang Uygur Autonomous Regions's product quality supervision and inspection;Long Zerong;Deer is firm;Li Manjiang application Chinese invention patent " with the measuring method for adulterating gutter oil in vegetable oil ", number of patent application 201811095362, Shen Qing Publication Number CN108872449A.
Rectifying for Zhejiang Wang Neng Eco Science Technology Co., Ltd is refined;Liu Xiang is rung;Zhang Chuanyong;Ding Xiaoming application Chinese invention patent " a kind of environment-friendly treatment method of gutter oil ", number of patent application 201810967212, application publication number CN109207268A.
It is winged that Shanxi public affairs pansophy examines appointing for Science and Technology Ltd.;Feng Bin;Liu Qinghua;Liu Bin application Chinese invention patent " one Plant the immuno-chromatographic test paper strip and preparation method thereof for detecting capsaicine in gutter oil ", number of patent application 201810865376, Application publication number CN108982862A.
The Tao Yulun of Anhui University of Science and Technology;Cao Zhen space application Chinese invention patent is " a kind of to be detected using polyaniline chip The method for refining gutter oil ", number of patent application 201810829535, application publication number CN109187706A.
The beam of Shengzhou promise Mick Import and Export Co., Ltd. is lofty and steep to have applied for a kind of Chinese invention patent " portable gutter oil Extraction element ", number of patent application 201810792285, application publication number CN108865443A.
The Li Rongwei of Suzhou Jing Rui Environmental Protection Technology Co., Ltd;Wang Zhongyong application Chinese invention patent " gutter oil oil-containing Rate accurate quantification method ", number of patent application 201810647943, application publication number CN109115650A.
Zhang Junxia;A kind of Wang Zehua application Chinese invention patent " dress that fuel oil is prepared with gutter oil and animal tallow Set and preparation method ", number of patent application 201810588949, application publication number CN108774552A.
The Lu Panfang of Shandong Agricultural University;Open school;Liu Yanlu;It opens the people and has applied for that Chinese invention patent is " a kind of to utilize trench The high molecular slow-release fertilizer of oil synthesis ", number of patent application 201810555964, application publication number CN108821846A.
A kind of Wang Yongxing application of the automobile-used biogas Co., Ltd in Hainan Chengmai Divine Land Chinese invention patent " gutter oil moisture Detection method ", number of patent application 201810498397, application publication number CN108760562A.
The Liu Weiye application of Fuyang City Changhai environmental protection equipment Science and Technology Ltd. Chinese invention patent " multi-functional gutter oil Purify oil refining device ", number of patent application 201810498369, application publication number CN109055017A.
Model Yongqing of Lang Kun Biotechnology Co., Ltd, Shenzhen;Chen Jianxiang;Yang Youqiang;Yuan Yidong;Su Yuehua;Li Shuai; Wang Siyang application Chinese invention patent " a kind of gutter oil screening machine ", number of patent application 201820773820, application publication number CN208406287U。
The Chinese invention patent of the Wang Shaoxiong application with new material Science and Technology Ltd. is praised in Ningbo, and " one kind is mentioned containing gutter oil Take the biomass-based surfactant and preparation method thereof of object ", number of patent application 201810118392, application publication number CN108277118A。
The Wang Pengfei of Nantong Jin Li oil prodution industry Co., Ltd;" one kind is for ground for Dai Yuanying application Chinese invention patent The rectifying column of ditch oil processing ", number of patent application 201810113721, application publication number CN108192729A.
The Yang Jiao cloud of generation sheet (Tianjin) Environmental Technology AS;Xiong Huanhuan;Shen Wang;Hu Chunping application Chinese invention is special Sharp " a kind of gutter oil equipment for separating liquid from solid ", number of patent application 201820154986, application publication number CN207307381U.
Liu Yinxi;Zhao Liping application Chinese invention patent " a kind of gutter oil deodorization degradation treating agent and its preparation side Method ", number of patent application 201711275655, application publication number CN108042970A.
Wide environmental protection technology research institute (Nanjing) Co., Ltd;Wide environmental science and technology (China) Co., Ltd;Wide environmental protection Institute for Research and Technology (Shenzhen) Co., Ltd;The Lu Yufeng of wide environmental protection technology equipment (Changzhou) Co., Ltd;Liao Xiaocong;Department is red It is red;Height has applied for Chinese invention patent " for handling the method and system of gutter oil ", number of patent application with expensive 201711047420, application publication number CN107777819A.
The Li Guanghuang of Shenzhen Saiyi Science And Technology Development Co., Ltd;Luo Hui;Du Lijuan;Zhu Penghui;Liu Bo;Li Yaojun;Korea Spro Zhong Liang application Chinese invention patent " a kind of device and detection method based near infrared spectrum detection gutter oil ", patent application Numbers 201710808763, application publication number CN107831134A.
Zhou Minghao application Chinese invention patent " a kind of swill-cooked dirty oil detecting system based on LIF technology ", number of patent application 201710804242, application publication number CN107449763A.
The Yu Yingtao of the Maritime Affairs University Of Dalian;Li Jie;Opening fine jade application Chinese invention patent, " gutter oil low amounts blends edible oil Efficient lossless discrimination method ", number of patent application 201710317526, application publication number CN107091827A.
The Xu Shuping of Jilin University;Xu Weiqing;Liu Zhigang;Geng Yi character used in proper names and in rendering some foreign names;Zhao Bing;Liu Xiangyuan;Sun Dan application Chinese invention Patent " a method of gutter oil is identified using Raman spectroscopy ", number of patent application 201710332843, application publication number CN107144558A。
The Ma Yan of the just bright detection Co., Ltd in Zhejiang;Xu Xiaoyang;Huang Ling;Yao Xiaoping;Wu Bowen;It learns kure;Tang Wenhua;Perhaps Wei Jian application Chinese invention patent " a method of gutter oil is adulterated in detection edible blend oil ", number of patent application 201710250870, application publication number CN107014802A.
Xu Jian application Chinese invention patent " a kind of process using ultrasonic technology production biodiesel ", patent Application number 201710076164, application publication number CN106753810A.
The graduate Long Zerong of Xinjiang Uygur Autonomous Regions's product quality supervision and inspection;Deer is firm;Liu Li;Zhao Jianyong;Wang Li Great waves;Zhao Liang;Dong Shuqing;" flow injection spec-trophotometry identifies device and its side of gutter oil to Li Hui application Chinese invention patent Method ", number of patent application 201710004312, application publication number CN106680525A.
In terms of Deutsche Bundespatent:
ARCHER DANIELS MIDLAND CO application Deutsche Bundespatent " Biodiesel production processes And biodiesel produced therefrom " (patent No. AU002006330770A1).
DINGECAD S A, AR application Deutsche Bundespatent " PLANTA QUIMICA MODULAR ECOLOGICA PARA LA OBTENCION DE BIODIESEL Y SUBPRODUCTOS A PARTIR DE PRODUCTOS AGRICOLAS OLEAGINOSOS, PROCESAMIENTO DE LOS MISMOS Y BIODIESEL Y SUBPRODUCTOS " (the patent No. AR000000054690A1).
UNIV ESTADUAL DE CAMPINAS UNICAMP, BR application Deutsche Bundespatent " microrreator, uso do microrreator, processo microfluídico de síntese de biodiesel e biodiesel Assim obtido " (patent No. BR102016028508A2).
FUNDACAO ASSIS GURGACZ, BR application Deutsche Bundespatent " ADITIVO NATURAL ANTIOXIDANTE A BASE DE SABURá, PARA O USO EM BIODIESEL E BIODIESEL CONTENDO ADITIVO NATURAL DE SABUR á " (patent No. BR102013009606A2).
UNIV ESTADUAL DA PARAIBA, BR application Deutsche Bundespatent " processo para classifica O de biodiesel e instrumento para classificalo de biodiesel " (the patent No. BR000PI1104468A2).
MINERACAO CURIMBABA LTDA, BR application Deutsche Bundespatent " processo para obteno de biodiesel a partir de àleos e/ou gorduras vegetais e/ou gorduras animais, Virgens ou usados e biodiesel assim obtido " (patent No. BR000PI1005000A2).
BIODIESEL DE ANDALUCIA 2004 S A, ES application Deutsche Bundespatent " procedimento para obtenho de biodiesel a partir de óleos vegetais de grau de acidez variável em Sistema cont ì nuo e combust ì vel biodiesel obtido " (patent No. BR000PI0707162A2).
SAKAMOTO AKIRA, JP;SUGIOKA TETUO, JP application Deutsche Bundespatent " sistema de motor Movido a biodiesel e m é todo de operao de motor movido a biodiesel " (the patent No. BR000PI0706612A2).
INDIAN OIL CORP LTD, IN application Deutsche Bundespatent " processo para produzir um Biodiesel, e, biodiesel " (patent No. BR000PI0500790A).
CHEVRON ORONITE CO, US;CHEVRON ORONITE TECH B V, NL application Deutsche Bundespatent 《LUBRICATING OIL COMPOSITIONS COMPRISING A BIODIESEL FUEL AND A MANNICH CONDENSATION PRODUCT " (patent No. CA000003031693A1).
In terms of Japan Patent:
Nihon Univ. School Juridical Person has applied for Japan Patent " バ イ オ デ ィ ー ゼ Le fuel production method and び manufacturing device " (patent No. JP, 2018-145218, A).
" ガ ス タ ー ビ Application fires へ in baked device to ゼ ネ ラ Le エ レ Network ト リ ッ Network カ Application パ ニ イ application Japan Patent バ イ オ デ ィ ー ゼ Le injects め シ ス テ system and び method " (patent No. JP, 2017-096257, A).
JFE environment Co., Ltd. has applied for Japan Patent " バ イ オ デ ィ ー ゼ Le fuel production method お I び バ イ オ デ ィ ー ゼ Le fuel production apparatus " (patent No. JP, 2017-088779, A).
" ガ ス タ ー ビ Application fires へ in baked device to ゼ ネ ラ Le エ レ Network ト リ ッ Network カ Application パ ニ イ application Japan Patent バ イ オ デ ィ ー ゼ Le injection system is imperial " (patent No. JP, 2017-078417, A).
Kumamoto University has applied for Japan Patent " バ イ オ デ ィ ー ゼ Le manufacturing method and び バ イ オ デ ィ ー ゼ Le manufacturing device " (patent No., 2017-014319, A).
Ha Application Star マ Application ペ ト ロ ケ ミ カ Le エ Le エ ル シ ー application Japan Patent " バ イ オ デ ィ ー ゼ Le To Base づ く ア Le キ Le aromatic compound か ら induces さ れ surface-active drug " (patent No. JP, 2016-216488, A).
JFE ス チ ー Le Co., Ltd. has applied for Japan Patent " バ イ オ デ ィ ー ゼ Le fuel production method " (patent Number JP, 2016-017094, A).
Flower マ テ リ ア Le founds in Co., Ltd., and he has applied for that " steaming of バ イ オ デ ィ ー ゼ Le oil stays purification to fill to Japan Patent Set " (patent No. JP, 2015-203068, A).
It is state-run grind study carefully out development legal person produce industry skill art TotalHe research institute applied for Japan Patent " high-quality バ イ オ デ ィ ー ゼ Le fuel production method " (patent No. JP, 2015/056767, A1).
It is Japanese special that he has applied ペ ト ロ レ オ Block ラ ジ レ イ ロ ソ シ エ ダ ア ノ ニ マ-ペ ト ロ Block ラ ス " メ チ Le バ イ オ デ ィ ー ゼ Le か ら バ イ オ lubrication drug The manufacture The Ru method and び work as this method To I り and obtain ら れ benefit Ru バ イ オ lubricates drug " (patent No. JP, 2015-059176, A).
The island National University Corporation LuInfants university application Japan Patent " the raw な い バ イ オ デ ィ ー of グ リ セ リ Application The pair ゼ Le fuel production method " (patent No. JP, 2015-013951, A).
Legal person of the school Doshisha University applied Japan Patent " バ イ オ デ ィ ー ゼ Le fuel making catalyst composition, when this Catalyst composition manufacturing method, when the catalyst composition The い バ イ オ デ ィ ー ゼ Le fuel production method and び When this method To uses さ れ Ru バ イ オ デ ィ ー ゼ Le fuel making device " (patent No. JP, 2012-161733, A).
It is state-run grind to study carefully out development legal person and produce industry skill art TotalHe research institute applied for that " エ ス テ Le exchanges catalyst and び to Japan Patent Catalyst The い バ イ オ デ ィ ー ゼ Le fuel production method " (patent No. JP, 2014/115356, A1).
School artificial person Chubu University application Japan Patent " バ イ オ デ ィ ー ゼ Le fuel making シ ス テ system and び バ イ オ デ ィ ー ゼ Le fuel production method " (patent No. JP, 2014-122317, A).
ユ ニ チ カ Co., Ltd. has applied for Japan Patent " バ イ オ デ ィ ー ゼ Le fuel container resin combination お I び そ れ The い formed body " (patent No. JP, 2014-058597, A).
National University Corporation's Fukushima university application Japan Patent " バ イ オ デ ィ ー ゼ Le fuel production method " is (specially Benefit JP, 2014-027908, A).
In terms of United States Patent (USP):
ALM Holding Company (Onalaska, WI) and Ergon Asphalt & Emulsions, Inc. (Jackson, MS) has applied for United States Patent (USP) " Biodiesel emulsion comprising a lecithin-based Emulsifier for cleaning bituminous coated equipment " (patent No. 10,202,564).
FORD MOTOR COMPANY BRASIL LTDA (Sao Bernardo do Campo, BR) has applied for the U.S. Patent " Biodiesel resistant PVC/NBR rubber composition " (patent No. 10,166,863).
The Lubrizol Corporation (Wickliffe, OH) has applied for United States Patent (USP) " Coupled Phenols for use in biodiesel engines " (patent No. 10,113,132).
INSTITUTO MEXICANO DEL PETROLEO (Mexico City, MX) has applied for United States Patent (USP) " Use of heterogeneous acid catalysts based on mixed metal salts to produce Biodiesel " (patent No. 10,065,915).
Korea Institute of Science and Technology (Seoul, KR) has applied for United States Patent (USP) 《Transformed Synechococcus elongatus having capability of producing biodiesel From carbon dioxide and method for producing biodiesel using the same " (the patent No. 10,036,046).
Auburn University (Auburn, AL) has applied for United States Patent (USP) " Treated biodiesel Glycerin " (patent No. 10,034,475).
ECOLAB USA INC. (St. Paul, MN) has applied for United States Patent (USP) " Biodiesel-based emulsion Defoamer and method for making the same " (patent No. 10,005,007).
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY (Annandale, NJ) has applied for the U.S. Patent " Hydroprocessing of biodiesel fuels and blends " (patent No. 10,000,712).
SeaChange Group LLC (Brunswick, ME) has applied for United States Patent (USP) " Biodiesel glycerol Emulsion fuel mixtures " (patent No. 9,976,096).
National Taiwan Normal University (Taipei, TW) has applied for United States Patent (USP) " Methods For producing biodiesel by recombinant lipase " (patent No. 9,970,035).
Renewable Energy Group, Inc. (Ames, IA) have applied for United States Patent (USP) " Methods and Devices for producing biodiesel and products obtained therefrom " (patent No. 9,957, 464).
Genuine Bio-Fuel, Inc. (Indiantown, FL) have applied for United States Patent (USP) " Method and system for production of biodiesel utilizing ultrasonic shear mixing to reduce the amount of energy needed by 45 to 50% and eliminate the use of Water " (patent No. 9,944,871).
Xtrudx Technologies, Inc. (Seattle, WA) have applied for United States Patent (USP) " Production of Biodiesel from oils and fats via supercritical water " (patent No. 9,932,532).
Kansai Chemical Engineering Co., Ltd. (Hyogo, JP) and Bio-Energy Corporation (Hyogo, JP) has applied for United States Patent (USP) " Continuous production of biodiesel Fuel by enzymatic method " (patent No. 9,879,291).
CONSIGLIO NAZIONALE DELLE RICERCHE (Rome, IT) has applied for United States Patent (USP) " One-pot process for the production of biodiesel and glycerol ether mixtures useful as Biofuels " (patent No. 9,873,843).
HUNTSMAN PETROCHEMICAL LLC (The Woodlands, TX) has applied for United States Patent (USP) " Surface Active agents derived from biodiesel-based alkylated aromatic compounds " (patent Number 9,873,664).
Argent Energy (UK) Limited (London, GB)Argent Energy Limited (London, GB) applied United States Patent (USP) " Biodiesel composition and related process and products " (specially Benefit number is 9,868,918).
Thompson; Jeffery (Cookeville, TN), Cooper; John K. (Chattanooga, TN), Oyanader;Mario A. (Cookeville, TN) has applied for United States Patent (USP) " Mechanically enhanced Separation of reaction products in biodiesel production " (patent No. 9,868,917).
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY (Annandale, NJ) has applied for the U.S. Patent " Methods of inhibiting precipitation of biodiesel fuel components " (patent No. 9,840,678).
Lynch; Joan (Chicago, IL), Tran;Bo (Chicago, IL) has applied for United States Patent (USP) 《Fertilizer and fertilizer additive compositions and methods comprising by- products from the manufacture of fatty acid alkyl esters and/or biodiesel 》 (patent No. 9,796,896).
SMARTFLOW TECHNOLOGIES, INC. (Apex, NC) have applied for United States Patent (USP) " Biodiesel fuel Production, separation methods and systems " (patent No. 9,783,750).
Auburn University (Auburn, AL) has applied for United States Patent (USP) " Treated biodiesel Glycerin " (patent No. 9,756,854).
EMCEE ELECTRONICS, INC. (Venice, FL) have applied for United States Patent (USP) " Biodiesel Detector " (patent No. 9,804,086).
From the point of view of above-mentioned data at home and abroad, developed country's gutter oil research emphasis is to be processed into gutter oil with Chemical Engineering Technology Biodiesel, several steps detect without too big demand fast qualitative screening there is no edible oil is mixed.Chinese gutter oil is fixed In terms of measuring detection technique, the most commonly used is spectral techniques for traditional gutter oil and novel trench oil, are detected and are tied according to a large amount of gutter oils Fruit has had relevant map, highly developed.Traditional gutter oil in terms of fast qualitative screening detection technique, also compared at It is ripe, but because novel trench oil derives from animal tallow, fusing point and ultraviolet absorbance are obviously different from traditional gutter oil, temporarily When do not retrieve fast qualitative screening detecting instrument for novel trench oil also.
Summary of the invention
To solve above-mentioned the deficiencies in the prior art, this patent devises the two-parameter fast qualitative sieve of animality novel trench oil Look into detector.Novel trench oil component source is mainly animal fat, and traditional trench oil component source is more plant oil Rouge, this patent are different from the physical characteristics of traditional gutter oil for novel trench oil, and two-parameter is fusing point and ultraviolet absorbance.
This instrument work structuring is: including capillary, ultraviolet-ray diode UV-LED, UV detector U7, heater HEATER, temp probe PT100, main control chip U5, display screen LCD.
Capillary bottom of the tube is inserted into tested novel trench oil, for observing the shape after tested novel trench oil reaches melting temperature State.
Ultraviolet-ray diode UV-LED and UV detector U7 arrange that UV light permeability is tested novel trench oil face-to-face Afterwards, it then is radiated above UV detector U7, to obtain ultraviolet absorbance.
Main control chip U5 connects ultraviolet-ray diode UV-LED, UV detector U7, heater by peripheral circuit HEATER, temp probe PT100, display screen LCD.
This equipment circuit structure is: visiting including Switching Power Supply U1, DC-DC chip U2 and U3, temperature detection chip U4, temperature Head PT100, main control chip U5, solid-state relay U6, heater HEATER, display screen LCD, triode Q1, ultraviolet-ray diode UV-LED, UV detector U7.
Switching Power Supply U1 connection DC-DC chip U2 and U3.
The U2 connection of DC-DC chip temperature detection chip U4 and main control chip U5.
DC-DC chip U3 connection display screen LCD and UV detector U7.
Main control chip U5 is separately connected temperature detection chip U4, display screen LCD, solid-state relay U6, UV detector U7。
Triode Q1 connection ultraviolet-ray diode UV-LED.
Solid-state relay U6 connection heater HEATER.
Temp probe PT100 connection temperature detection chip U4.
Compared with the existing technology, the beneficial effect of this patent is:
Traditional gutter oil is more mature in terms of fast qualitative screening detection technique, but because novel trench oil is from dynamic Object fat, fusing point and ultraviolet absorbance are obviously different from traditional gutter oil, this instrument detects the fusing point and purple of novel trench oil Outside line absorbance, much more convenient than spectral detection as qualitative detection, testing cost also wants much lower, is relatively suitble to public security, work Quotient, quality inspection carry out on-site law-enforcing primary dcreening operation.
Detailed description of the invention
Fig. 1 is the work structuring figure of this instrument.
Fig. 2 is the work flow diagram of this instrument.
Fig. 3 is the circuit diagram of this instrument.
It is respectively in figure: capillary, ultraviolet-ray diode UV-LED, UV detector U7, heater HEATER, temperature Pop one's head in PT100, main control chip U5, display screen LCD, Switching Power Supply U1, DC-DC chip U2 and U3, temperature detection chip U4, solid-state Relay U6, display screen LCD.
Specific embodiment
The preferred embodiment of this patent is described in detail with reference to the accompanying drawing, so that the advantages of this patent and feature energy It is easy to be readily appreciated by one skilled in the art, so that the protection scope to this patent is more clearly defined, should manages Solution, specific embodiment described herein only to explain this patent, are not used to limit this patent.
Please refer to work structuring figure attached drawing 1, including capillary, ultraviolet-ray diode UV-LED, UV detector U7 plus Hot device HEATER, temp probe PT100, main control chip U5, display screen LCD.
Capillary bottom of the tube is inserted into tested novel trench oil, after gutter oil is heated, capillary for observe be tested it is novel The suction scale of gutter oil.
Ultraviolet-ray diode UV-LED and UV detector U7 arrange that UV light permeability is tested novel trench oil face-to-face Afterwards, it then is radiated above UV detector U7, to obtain ultraviolet absorbance.
Main control chip U5 connects ultraviolet-ray diode UV-LED, UV detector U7, heater by peripheral circuit HEATER, temp probe PT100, display screen LCD.
Work flow diagram attached drawing 2 is please referred to, firstly, AC220V energization access switch power supply U1.
Then, DC12V enters DC-DC power source chip U2U3, and remaining chip is powered.
Then, novel trench oil samples are packed into, capillary is inserted into.
Then, main control chip U4 controls heater HEATER work, and temp probe PT100 continues sample as feedback Heating when reaching capillary scale, observes the temperature shown on display screen LCD, obtains sample melting temperature.
Then, UV LED UV-LED and ultraviolet light detector U6 cooperates, and detects novel trench oil samples Ultraviolet optical absorbance.
Finally, being controlled by main control chip U4, ultraviolet optical absorbance is shown on display screen LCD.
Please refer to circuit diagram attached drawing 3, including Switching Power Supply U1, DC-DC chip U2 and U3, temperature detection chip U4, temperature Pop one's head in PT100, main control chip U5, solid-state relay U6, heater HEATER, display screen LCD, triode Q1, two pole of ultraviolet light Pipe UV-LED, UV detector U7.
Switching Power Supply U1 connection DC-DC chip U2 and U3, Switching Power Supply U1 input AC220V export DC12V.
DC-DC chip U2 and U3 input DC12V, and DC-DC chip U2 exports DC3.3V power supply, DC-DC chip U3 output DC5.0V power supply.
DC-DC chip U2 connection temperature detection chip U4 and main control chip U5, provide DC3.3V power supply for them.
DC-DC chip U3 connection display screen LCD and UV detector U7, provide DC5.0V power supply for them.
Main control chip U5 is separately connected temperature detection chip U4, display screen LCD, solid-state relay U6, UV detector U7, the VCC of main control chip U5 are DC3.3V.
The temperature signal of main control chip U5 temperature detection chip U4 input, the VCC of temperature detection chip U4 are DC3.3V, temperature The Rref spent outside detection chip U4 is ambient compensation resistance.
Temp probe PT100 connection temperature detection chip U4.
Main control chip U5 connection display screen LCD, effect is display ultraviolet absorptivity and temperature, the VCC of display screen LCD are DC5.0V。
The control terminal of the 51 pins driving solid-state relay U6 of main control chip U5, signal is DC2.85V adjustable pulse PWM, It is fed back by temp probe PT100, novel trench oil is heated to predetermined temperature, when by observation capillary arrival scale Temperature obtains the fusing point of novel trench oil.
The load end of solid-state relay U6 connects heater HEATER, load end power supply DC12V.
46 pin the driving triode Q1, triode Q1 of main control chip U5 drive ultraviolet-ray diode UV-LED, triode Q1 power supply is DC5.0V, and the driving voltage of triode Q1 is DC0.7-2.85V.
The VCC of UV detector U7 is DC5.0V, and Vout output uitraviolet intensity signal draws to the 91 of main control chip U5 Foot, range are DC0-400mV.
UV LED UV-LED and ultraviolet light detector U6 cooperates, and detects the ultraviolet light of novel trench oil samples Absorbance.
In key part in instrument: Switching Power Supply U1 uses HDR-60-12.
DC-DC chip U2 uses MP1473.
DC-DC chip U3 uses MP1475.
Temperature detection chip U4 uses MAX31865-ET.
Main control chip U5 uses LPC1763.
Solid-state relay U6 uses SSR-05DA.
UV detector U7 uses GUVA-S12F.
Triode Q1 uses 2N6045.
Display screen LCD uses A186425.
The basic principles and main features and advantage of this patent have been shown and described above.The technical staff of the industry should Understand, this patent is not restricted to the described embodiments, and the description in above embodiments and description only illustrates this patent Principle, under the premise of not departing from this patent spirit and scope, this patent be will also have various changes and improvements, these change and change Into both falling within the scope of claimed this patent.Range is claimed by appended claims and its equivalent in this patent It defines.

Claims (10)

1. the two-parameter fast qualitative screening detector of animality novel trench oil, it is characterised in that: including Switching Power Supply U1, DC- DC chip U2 and U3, temperature detection chip U4, temp probe PT100, main control chip U5, solid-state relay U6, heater HEATER, display screen LCD, triode Q1, ultraviolet-ray diode UV-LED, UV detector U7;Switching Power Supply U1 connection DC- DC chip U2 and U3, DC-DC chip U2 connection temperature detection chip U4 and main control chip U5, DC-DC chip U3 connection display screen LCD and UV detector U7, main control chip U5 be separately connected temperature detection chip U4, display screen LCD, solid-state relay U6, UV detector U7, triode Q1 connection ultraviolet-ray diode UV-LED, solid-state relay U6 connection heater HEATER, temperature Degree probe PT100 connection temperature detection chip U4.
2. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: Switching Power Supply U1 uses HDR-60-12.
3. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: DC-DC chip U2 uses MP1473.
4. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: DC-DC chip U3 uses MP1475.
5. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: Temperature detection chip U4 uses MAX31865-ET.
6. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: Main control chip U5 uses LPC1763.
7. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: Solid-state relay U6 uses SSR-05DA.
8. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: UV detector U7 uses GUVA-S12F.
9. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, it is characterised in that: Triode Q1 uses 2N6045.
10. the two-parameter fast qualitative screening detector of animality novel trench oil according to claim 1, feature exist In: display screen LCD uses A186425.
CN201910123317.7A 2019-02-19 2019-02-19 The two-parameter fast qualitative screening detector of animality novel trench oil Withdrawn CN109632682A (en)

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