CN109629275A - A kind of lightweight rigidity self-lubricating composite rope and preparation method thereof - Google Patents

A kind of lightweight rigidity self-lubricating composite rope and preparation method thereof Download PDF

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Publication number
CN109629275A
CN109629275A CN201811598237.9A CN201811598237A CN109629275A CN 109629275 A CN109629275 A CN 109629275A CN 201811598237 A CN201811598237 A CN 201811598237A CN 109629275 A CN109629275 A CN 109629275A
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Prior art keywords
rope
layer
yarn
wire rope
core
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CN109629275B (en
Inventor
宋炳涛
沈明
姜润喜
邱延平
李甜
石士超
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Withropenet Group Co Ltd
SHANDONG LUPU TECHNOLOGY Co Ltd
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Withropenet Group Co Ltd
SHANDONG LUPU TECHNOLOGY Co Ltd
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    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/16Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
    • D07B1/162Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber enveloping sheathing
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/02Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
    • D07B1/025Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/10Rope or cable structures
    • D07B2201/104Rope or cable structures twisted
    • D07B2201/1076Open winding
    • D07B2201/108Cylinder winding, i.e. S/Z or Z/S
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2047Cores
    • D07B2201/2052Cores characterised by their structure
    • D07B2201/2065Cores characterised by their structure comprising a coating
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2083Jackets or coverings
    • D07B2201/2087Jackets or coverings being of the coated type
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2083Jackets or coverings
    • D07B2201/2088Jackets or coverings having multiple layers
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2083Jackets or coverings
    • D07B2201/209Jackets or coverings comprising braided structures
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • D07B2205/2032Polyacrylics
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • D07B2205/2039Polyesters
    • D07B2205/2042High performance polyesters, e.g. Vectran
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • D07B2205/2064Polyurethane resins

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Ropes Or Cables (AREA)

Abstract

The invention discloses a kind of lightweight rigidity self-lubricating composite ropes and preparation method thereof, it is related to field of rope, it include wire rope core (1), wrapping layer (2) and covered plastics layer (3), the multi layer spiral structure with circular cross section that the wire rope core (1) is interwoven by ultra high molecular weight polyethylene fiber rope yarn spiral, spiral is oppositely arranged between layers, composite finishing coating is set outside each layer of parallel rope yarn, ingredient accounts for 10-30% in composite finishing liquid on wire rope core (1) cross section, wrapping layer (2) are set outside the wire rope core (1), covered plastics layer (3) are set outside the wrapping layer (2).Rope section of the invention is circle, and strength-weight ratio is high, can substitute wirerope completely in hoisting and hanging, drilling prospection field.

Description

A kind of lightweight rigidity self-lubricating composite rope and preparation method thereof
Technical field
The present invention relates to field of rope, specifically a kind of lightweight rigidity self-lubricating composite rope and its preparation side Method.
Background technique
Every field is covered in the use of wirerope at present --- and suspension bridge, lifting etc. the characteristics of wirerope also clearly remove Except basic intensity, steel wire rope sling is for comparable hardness, high temperature resistant, resistance to certain corrosion, is conductor.But with chemical fibre class rope The shortcomings that rope compares, wirerope is that density of material is big, and quality is high, not easy to operate.But chemical fibre cable have it is soft, light, high-strength, The advantages of easily knotting.Therefore in many application fields, chemical fibre cable gradually substitutes steel wire cable.
Although in some fields, chemical fibre cable completely substitute wirerope, the especially lightweight of high-performance fiber rope, The main reason for high-strength, corrosion resistance, even more substitution wirerope product.But under lifting, multilaminate coiled operating condition, to rope Rigidity requirement is high, while requiring lightweight, has high strength-weight ratio, chemical fibre cable is more with the obvious advantage than steel wire cable.But change Fine class rope due to itself flexibility, laterally it is easily-deformable, cause winch wind, overlapping use when extrusion deformation, rope The problems such as displacement, is easy initiation accident;Once chemical fibre cable wearability and scratch resistant ability are poor simultaneously, in use by external force Cutting easily causes fiber fracture of rope and leads to a disaster.Chemical fibre cable will substitute wirerope and still need to solve that rope hardness is low, rope The problems such as skin-friction force is big, and section is non-round.
Summary of the invention
To solve above-mentioned technical problem, the present invention provides a kind of lightweight rigidity self-lubricating composite rope and its Preparation method, rope section are circle, and strength-weight ratio is high, can substitute steel wire completely in hoisting and hanging, drilling prospection field Rope.
The technical solution used to solve the technical problems of the present invention is that:
A kind of lightweight rigidity self-lubricating composite rope, includes wire rope core, wrapping layer and covered plastics layer, the wire rope core is by supra polymer The multi layer spiral structure with circular cross section that weight polyethylene fiber rope yarn spiral is interwoven, spiral is reversed between layers Composite finishing coating is arranged in setting, each layer of parallel rope yarn outside, and ingredient accounts for 10- in composite finishing liquid on the wire rope core cross section 30%, wrapping layer is arranged in the wire rope core outside, and covered plastics layer is arranged outside the wrapping layer.
The wrapping layer is set as sheath made of being woven as aromatic polyamide fibre.
The finishing fluid of composite finishing coating in the wire rope core outside every layer of parallel rope yarn mainly by functional urethane or Polyacrylate aqueous coating glue composition, it further includes in solution weight ratio 1.3%-2% that the weight proportion with water, which is 2:1~4:1, Thickener, 0.5%-1.5% defoaming agent.
The covered plastics layer is melted by PE through pultrusion, forms the polyethylene clad of 1-3mm thickness in rope surface.
A kind of preparation method of lightweight rigidity self-lubricating composite rope, is achieved by the steps of:
1) rope designs: according to rope specification, designing the thickness of covered plastics layer, calculates rope sectional area, accounts for according to rope yarn area 70-90% calculates rope yarn radical and fineness;
2) preparation rope yarn: several ultra high molecular weight polyethylene fiber multifilament being twisted by ring and are twisted, and the twist is 10~20 twirls/m;
3) spiral interweaves: designing the wire rope core number of plies according to rope diameter, is arranged every layer of yarn spirals using rope machine is turned round, screw pitch foundation Depending on rope speed and torsion are fast out, twisting is opposite between the adjacent number of plies;
4) coating: using the functional urethane or polyacrylate aqueous coating glue prepared between every layer of yarn of wire rope core Composite finishing coating is carried out, by die orifice plastic squeeze, carries out the heating, drying of coating solution in the outer layer of wire rope core, binding efficiency is greater than 40%.
5) knitted thermal sheath: by aromatic polyamide yarn interlacement weave at rope sheath, wrapping layer is formed;
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding through round die orifice, in rope Outside forms covered plastics layer.
The lightweight rigidity self-lubricating composite rope that the present invention illustrates ensure that rope by the structure design for wire rope core Section is circle, and the wire rope core strength efficiency that spiral is interwoven is higher than wire rope core made of braiding;Wire rope core cordage yarn it is compound The setting of the sheath of top finish and wrapping layer, ensure that the rigidity of rope while reducing the weight of rope, realize same Every meter of quality of rope is the 1/7 of every meter of quality of wirerope, at low cost, safety and environmental protection under intensity;The design of rope covered plastics layer guarantees The self-lubricating of rope surface reduces rope surface frictional force, and protection rope supporting part is invaded by other substances, extends rope Service life, wound on winder neat, do not lead to the problem of extrusion deformation;To sum up, which has light weight, rigidity Greatly, it the features such as section circle, self-lubricating, thoroughly realizes and realizes its function using fibrecord substitution wirerope, reduce rope Manipulation strength and industrial energy consumption, be suitble to large-scale promotion application.
Detailed description of the invention
Fig. 1 is cross section structure schematic diagram of the present invention.
Specific embodiment
The present invention will be described in detail in the following with reference to the drawings and specific embodiments:
It include wire rope core 1, wrapping layer 2 and covered plastics layer 3 as shown in Figure 1, a kind of lightweight rigidity self-lubricating composite rope, it is described The multi layer spiral structure with circular cross section that wire rope core 1 is interwoven by ultra high molecular weight polyethylene fiber rope yarn spiral, layer Spiral is oppositely arranged between layer, guarantees balance, composite finishing coating, the wire rope core is arranged outside each layer of parallel rope yarn Ingredient accounts for 10-30% in composite finishing liquid on 1 cross section, and wrapping layer 2 is arranged outside the wire rope core 1, sets outside the wrapping layer 2 Set covered plastics layer 3.
As preferred mode, in the present embodiment, the wrapping layer 2 is set as being woven by aromatic polyamide fibre Sheath, so that rope is had high temperature resistant and heat-proof quality, can adapt under worst hot case, play the role of protect inner core.
As preferred mode, in the present embodiment, composite finishing coating in the wire rope core 1 outside every layer of parallel rope yarn Finishing fluid is mainly made of functional urethane or polyacrylate aqueous coating glue, and the weight proportion with water is 2:1~4:1, Further include the defoaming agent of thickener in solution weight ratio 1.3%-2%, 0.5%-1.5%, guarantees the circular cross section in wire rope core 1 In, resin portion occupied area is 10%~30%.
As preferred mode, in the present embodiment, the covered plastics layer 3 is melted by PE through pultrusion, in rope surface shape At the polyethylene clad of 1-3mm thickness.Rope section circularity is improved by this covered plastics layer 3, enhances the self-lubrication of rope, is enhanced Rope rigidity uses convenient for winding.
A kind of preparation method of lightweight rigidity self-lubricating composite rope of the present invention, is achieved by the steps of:
1) rope designs: according to rope specification, designing the thickness of covered plastics layer, calculates rope sectional area, accounts for 70- according to rope yarn area 90%, (ingredient in composite finishing liquid) resin area accounts for 10-30%, calculates rope yarn radical and fineness;
2) preparation rope yarn: several ultra high molecular weight polyethylene fiber multifilament being twisted by ring and are twisted, and the twist is 10~20 twirls/m;
3) spiral interweaves: design 1 number of plies of wire rope core according to rope diameter, arranged every layer of yarn spirals using rope machine is turned round, screw pitch according to According to rope speed out and depending on turning round speed, twisting is opposite between the adjacent number of plies;
4) coating: using the functional urethane or polyacrylate aqueous coating glue prepared to every layer of yarn of wire rope core 1 it Between carry out composite finishing coating, by die orifice plastic squeeze, carry out the heating, drying of coating solution in the outer layer of wire rope core 1, binding efficiency is greater than 40%;
5) knitted thermal sheath: by aromatic polyamide yarn interlacement weave at rope sheath, wrapping layer 2 is formed;
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding through round die orifice, in rope Outside forms covered plastics layer 3.
Embodiment 1
Making a ultimate strength is 180kN, and diameter is 24mm lightweight rigidity self-lubricating composite rope, real as follows It is existing:
1) rope designs: rope diameter 24mm, covered plastics layer 2mm, then plastic preceding rope diameter is 20mm, aromatic series braiding shield Set is 2mm, and the diameter of wire rope core is 16mm.According to HMPE yarn accounting 80% calculate, the diameter of yarn and be 12.8mm, design yarn Line radical is 30;
2) preparation rope yarn: 20 conjunction 1500D ultra high molecular weight polyethylene fiber multifilament are added into 15 twirls/m, half is positive, a half reverse;
3) it prepares wire rope core: 30 yarns of restricting is entried on turning round rope machine by internal layer to outer layer according to the structure of 3+6+9+12, the One layer of 3 rope yarn are by rotating in the forward direction, and 6 rope yarns of the second layer are by reversely rotating, and 9 rope yarns of third layer are by rotating in the forward direction, and the 4th layer 12 rope yarns are by reversely rotating, and rope speed is 1m/min out, and torsion rope machine revolving speed is 30r/min, and wire rope core screw pitch is 30mm;
4) coating: configuring the polyurethane resin top finish liquid of 4:1, and thickener addition 1.5%, defoaming agent addition 0.5% is added, right Each layer of rope yarn carries out top finish, by die orifice plastic squeeze, carries out the heating, drying of coating solution, binding efficiency in the outer layer of wire rope core 1 Greater than 40%;
5) rope sheath, yarn knitted thermal sheath: are woven by 64 strand of 2 conjunction 1500D aromatic polyamide fibre yarns interwoven The twist is 120 twirls/m, and orientation is 32 bursts of forward directions, and 32 strands reversed, and braid angle is 30 °, hauling speed 30cm/min, weaves revolving speed For 5r/min, rope pitch is 60mm, rope diameter 20mm;
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding, pultrusion speed through round die orifice 0.5-2m/min, die orifice model 23.5, final cord break strength is 18.3 tons.
Embodiment 2
Making a ultimate strength is 198kN, and diameter is 20mm lightweight rigidity self-lubricating composite rope, real as follows It is existing:
1) rope designs: rope diameter 20mm, covered plastics layer 1mm, then plastic preceding rope diameter is 18mm, aromatic series braiding shield Set is 1mm, and the diameter of wire rope core is 16mm.According to HMPE yarn accounting 70% calculate, the diameter of yarn and be 13.3mm, design yarn Line radical is 36;
2) 20 conjunction 1500D ultra-high molecular weight fibers multifilament preparation rope yarn: are added into 10 twirls/m;
3) it prepares wire rope core: 36 yarns of restricting is entried on turning round rope machine by internal layer to outer layer according to the structure of 3+6+12+15, the One layer of 3 rope yarn are by rotating in the forward direction, and 6 rope yarns of the second layer are by reversely rotating, and 12 rope yarns of third layer are by rotating in the forward direction, and the 4th layer 15 rope yarns are by reversely rotating, and rope speed is 0.5m/min out, and torsion rope machine revolving speed is 20r/min, and wire rope core screw pitch is 24mm;
4) coating: configuring the polyurethane resin coating solution of 2:1, thickener addition 2%, defoaming agent addition 1.5% is added, to each layer Yarn of restricting carries out top finish, by die orifice plastic squeeze, carries out the heating, drying of coating solution in the outer layer of wire rope core 1, binding efficiency is greater than 40%;
5) rope sheath, yarn knitted thermal sheath: are woven by 64 strand of 1 conjunction 1500D aromatic polyamide fibre yarns interwoven The twist is 150 twirls/m, and orientation is 32 bursts of forward directions, and 32 strands reversed, and braid angle is 45 °, hauling speed 30cm/min, weaves revolving speed For 5r/min, rope pitch is 80mm, rope diameter 18mm;
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding, pultrusion speed through round die orifice 0.5-2m/min, die orifice model 19.5, final cord break strength is 20 tons.
Embodiment 3
Making a ultimate strength is 33kN, and diameter is 10mm lightweight rigidity self-lubricating composite rope, real as follows It is existing:
1) rope designs: rope diameter 10mm, covered plastics layer 1mm, then plastic preceding rope diameter is 8mm, aromatic series braiding shield Set is 1mm, and the diameter of wire rope core is 6mm.According to HMPE yarn accounting 90% calculate, the diameter of yarn and be 5.8mm, design yarn Radical is 11;
2) 10 conjunction 1500D ultra-high molecular weight fibers multifilament preparation rope yarn: are added into 20 twirls/m;
3) it prepares wire rope core: 11 yarns of restricting is entried on turning round rope machine by internal layer to outer layer according to the structure of 3+8, first layer 3 Root rope yarn is by rotating in the forward direction, and 8 rope yarns of the second layer are by reversely rotating, and rope speed is 0.2m/min out, and torsion rope machine revolving speed is 20r/ Min, wire rope core screw pitch are 40mm.
4) the polyurethane resin coating solution of 3:1, thickener addition 1.3%, defoaming agent addition 1%, to first layer coating: are configured Top finish is carried out with the second layer, by die orifice plastic squeeze, carries out the heating, drying of coating solution in the outer layer of wire rope core 1, binding efficiency is big In 40%;
5) rope sheath, yarn knitted thermal sheath: are woven by 64 strand of 1 conjunction 1500D aromatic polyamide fibre yarns interwoven The twist is 150 twirls/m, and orientation is 32 bursts of forward directions, and 32 strands reversed, and braid angle is 45 °, hauling speed 20cm/min, weaves revolving speed For 5r/min, rope pitch is 40mm, rope diameter 8mm;
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding, pultrusion speed through round die orifice 0.5-2m/min, die orifice model 9.8, final cord break strength is 3.3 tons.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, this technology neck The variations, modifications, additions or substitutions that the technical staff in domain is made within the essential scope of the present invention also should belong to of the invention Protection scope.

Claims (5)

1. a kind of lightweight rigidity self-lubricating composite rope, which is characterized in that include wire rope core (1), wrapping layer (2) and covered plastics layer (3), the multilayer spiral shell with circular cross section that the wire rope core (1) is interwoven by ultra high molecular weight polyethylene fiber rope yarn spiral Structure is revolved, spiral is oppositely arranged between layers, and composite finishing coating, the wire rope core (1) is arranged outside each layer of parallel rope yarn Ingredient accounts for 10-30% in composite finishing liquid on cross section, wrapping layer (2) is arranged outside the wire rope core (1), the wrapping layer (2) is outside Covered plastics layer (3) are arranged in portion.
2. lightweight rigidity self-lubricating composite rope according to claim 1, which is characterized in that the wrapping layer (2) sets It is set to sheath made of being woven as aromatic polyamide fibre.
3. lightweight rigidity self-lubricating composite rope according to claim 1, which is characterized in that every in the wire rope core (1) The finishing fluid of composite finishing coating outside layer parallel rope yarn is mainly by functional urethane or polyacrylate aqueous coating glue Composition, it further includes thickener, the 0.5%-1.5% in solution weight ratio 1.3%-2% that the weight proportion with water, which is 2:1~4:1, Defoaming agent.
4. lightweight rigidity self-lubricating composite rope according to claim 1, which is characterized in that the covered plastics layer (3) by PE melting forms the polyethylene clad of 1-3mm thickness through pultrusion, in rope surface.
5. a kind of preparation method of lightweight rigidity self-lubricating composite rope as described in claim 1, which is characterized in that pass through Following steps are realized:
Rope design: according to rope specification, designing the thickness of covered plastics layer (3), calculate rope sectional area, accounts for according to rope yarn area 70-90% calculates rope yarn radical and fineness;
Preparation rope yarn: several ultra high molecular weight polyethylene fiber multifilament being twisted by ring and are twisted, and the twist is 10~20 twirls/m;
3) spiral interweaves: designing wire rope core (1) number of plies according to rope diameter, is arranged every layer of yarn spirals using rope machine is turned round, screw pitch According to rope speed out and depending on turning round speed, twisting is opposite between the adjacent number of plies;
4) coating: using the functional urethane or polyacrylate aqueous coating glue prepared to every layer of yarn of wire rope core (1) Between carry out composite finishing coating, by die orifice plastic squeeze, carry out the heating, drying of coating solution, binding efficiency in the outer layer of wire rope core (1) Greater than 40%;
5) it knitted thermal sheath: by aromatic polyamide yarn interlacement weave at rope sheath, is formed wrapping layer (2);
6) it makes plastic rope: rope being fed into plastic wrapping machine and carries out plastic, pultrusion, solidification, molding through round die orifice, in rope Outside forms covered plastics layer (3).
CN201811598237.9A 2018-12-26 2018-12-26 Lightweight rigid self-lubricating composite rope and preparation method thereof Active CN109629275B (en)

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Publication number Priority date Publication date Assignee Title
CN110776670A (en) * 2019-11-27 2020-02-11 李涛 PU plastic-coated steel wire and preparation method and application thereof
CN111996824A (en) * 2020-08-21 2020-11-27 江苏神力船舶设备有限公司 Manufacturing method of low-temperature-resistant mooring rope for ship
CN112626895A (en) * 2020-12-10 2021-04-09 鲁普耐特集团有限公司 Core-spun algae-proof rope and manufacturing method thereof
CN112761008A (en) * 2020-12-31 2021-05-07 浙江四兄绳业有限公司 Cable convenient for identifying twisted strands of cable core and preparation method and application thereof

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CN105256620A (en) * 2015-11-03 2016-01-20 山东鲁普科技有限公司 Three-layer composite marine rope and manufacture method thereof
CN210104410U (en) * 2018-12-26 2020-02-21 山东鲁普科技有限公司 Lightweight rigid self-lubricating composite rope

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JP2004036027A (en) * 2002-07-02 2004-02-05 Tokusen Kogyo Co Ltd Elastomer composite steel cord and method for producing the same
CN1898085A (en) * 2003-10-22 2007-01-17 Ctc电缆公司 Aluminum conductor composite core reinforced cable and method of manufacture
CN103485222A (en) * 2013-10-14 2014-01-01 无锡通用钢绳有限公司 Wire rope
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110776670A (en) * 2019-11-27 2020-02-11 李涛 PU plastic-coated steel wire and preparation method and application thereof
CN111996824A (en) * 2020-08-21 2020-11-27 江苏神力船舶设备有限公司 Manufacturing method of low-temperature-resistant mooring rope for ship
CN112626895A (en) * 2020-12-10 2021-04-09 鲁普耐特集团有限公司 Core-spun algae-proof rope and manufacturing method thereof
CN112626895B (en) * 2020-12-10 2023-08-22 鲁普耐特集团有限公司 Core-spun algae-preventing rope and manufacturing method thereof
CN112761008A (en) * 2020-12-31 2021-05-07 浙江四兄绳业有限公司 Cable convenient for identifying twisted strands of cable core and preparation method and application thereof

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