CN1096280A - High-effect cement special for concrete - Google Patents

High-effect cement special for concrete Download PDF

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Publication number
CN1096280A
CN1096280A CN94104016A CN94104016A CN1096280A CN 1096280 A CN1096280 A CN 1096280A CN 94104016 A CN94104016 A CN 94104016A CN 94104016 A CN94104016 A CN 94104016A CN 1096280 A CN1096280 A CN 1096280A
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China
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cement
type
portland
label
contain
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CN94104016A
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陈恩义
廉慧珍
覃维祖
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Tsinghua University
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Tsinghua University
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Priority to CN94104016A priority Critical patent/CN1096280A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

A kind of high-effect cement special for concrete belongs to building material field.This cement special by label greater than 525 #(contain 525 #) portland-type cement adds material modified, superplasticizer, expandable material and cooperate and form.Its prescription is that label is greater than 525 #(contain 525 #) portland-type cement 65~80%, material modified 10~25%, superplasticizer 1.5~2.5%, expandable material 7~15%.Material modified is in levigate blast-furnace slag, flyash, zeolite rock powder, the silicon ash any.Superplasticizer is solid, powdery high efficiency water reducing agent such as naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer.Expandable material is general cement expansive material such as U-shaped cement expansive material, composite expanding agent, alumite plumping agent.This cement special can be at the construction field (site) directly by general concrete formulating method by different proportioning waters, common sand, stone, add that this cement special promptly can be made into the preparation of high efficient concrete that meets different requirements.

Description

High-effect cement special for concrete
The present invention relates to be used for the cement of concrete and goods thereof, especially for having the concrete that high-durability can require and the cement of goods thereof.Belong to building material field.
Preparation of high efficient concrete (High Performance Concrete-HPC) is a kind of new concrete of country's research and development recent years such as France, the U.S., Japan, Canada, and its more traditional concrete on the proportioning mentality of designing has had a new breakthrough.Compare with traditional concrete; preparation of high efficient concrete has characteristics such as high application property (satisfying pumping or little requirement of shaking), high strength (intensity was not less than 50MPa in 28 days), low drying shrinkage, high permeability resistant, high-durability, is applicable to the concrete works that Highrise buildings, bridge, high tower, nuclear reactor protection shell and antiknock engineering etc. have increased durability to require.
Announced June 29 at French Patent FR2640962A1(90) in method with starting material such as silicate cement, liquid agent, defoamer, silicon ash, quartz sand powder, steel fiber, normal sands, cobble preparation preparation of high efficient concrete is proposed, this concrete can be used in the military antiknock engineering, and mark is supported following 28 days ultimate compression strength of condition and reached 70MPa.Countries such as Japan, the U.S. then adopt the method for the high-effect water reducer of low water-cement ratio (W/C=0.25~0.35) while admixture, an amount of active addition, swelling agent or thickening material to prepare preparation of high efficient concrete at the construction field (site), used cement is silicate cement, and high-effect water reducer mostly is liquid.The above-mentioned method for preparing preparation of high efficient concrete requires construction department to purchase multiple starting material and admixture simultaneously, at the construction field (site) or concrete mixing plant repeatedly measure computing, complex manufacturing technology, the production cost height, simultaneously construction technical staff is had relatively high expectations, have carelessness just may cause accident resulting from poor quality of projects slightly.
The purpose of this invention is to provide a kind of cement special, can be with this cement special at the construction field (site) directly by general concrete formulating method, promptly water, common sand, stone and cement are mixed with preparation of high efficient concrete.
High-effect cement special for concrete of the present invention is greater than 525 at label #(contain 525 #) portland-type cement in add material modified, superplasticizer, expandable material.Material modified is levigate blast-furnace slag, flyash, zeolite rock powder, silicon ash.Superplasticizer is the solid, powdery high efficiency water reducing agent, as naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer.Expandable material is commercially available cement expansive material, as U type cement expansive material, composite expanding agent, alumite plumping agent.
Each component ratio of cement special of the present invention is: label is greater than 525 #(contain 525 #) portland-type cement 65~80%, material modified 10~25%, superplasticizer 1.5~2.5%, expandable material 7~15%.
High-effect cement special for concrete of the present invention can be by following mix grinding prepared:
Figure 94104016X_IMG1
Illustrate that embodiment is as follows:
1, embodiment one
Cement production:
Label is greater than 525 #(contain 525 #) portland-type cement 65%+U type swelling agent 10%+ ground slag powder 25%+1.7% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → I type cement
Concrete mix recommended parameter (kg/m 3):
I type cement: 548, sand (medium sand): 780, rubble (5~25mm): 915, water 170, (W/C=0.31);
The concrete performance assay:
Application property Standard degree spare intensity (MPa) Limited expansion rate (%) *
The slump (cm) Degree of mobilization (cm) 3 days 7 days 28 days In the water 14 days In the air 28 days
21 48~50 30 47 61 0.012 -0.002
Annotate: * limits the ratio of reinforcement 0.785%.
2, embodiment two
Label is greater than 525 #(contain 525 #) portland-type cement 65%+ II level flyash 20%+ alumite plumping agent 15%+1.7% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → I type cement
Concrete mix recommended parameter (kg/m 3):
I type cement: 528, medium sand (fineness modulus 2.8): 750, limestone gravel (5~20mm): 917, water: 185, (W/C=0.35);
The concrete performance assay:
Figure 94104016X_IMG2
Annotate: * limits the ratio of reinforcement 0.785%.
3, embodiment three
Cement production:
Label is greater than 525 #(contain 525 #) portland-type cement 65%+ II level flyash 20%+ alumite plumping agent 15%+1.5% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → II type cement
Concrete mix recommended parameter (kg/m 3):
II type cement: 617, medium sand (fineness modulus 2.8): 716, rubble (5~15mm): 876,
Water: 185, (W/C=0.30);
The concrete performance assay:
Figure 94104016X_IMG3
Annotate: * limits the ratio of reinforcement 0.785%.
4, embodiment four
Label is greater than 525 #(contain 525 #) portland-type cement 73%+ II level flyash 15%+U-II type swelling agent 12%+1.5% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → II type cement
Concrete mix recommended parameter (kg/m 3):
II type cement: 514, medium sand (fineness modulus 3.0): 729, rubble (5~25mm): 966, water 185, (W/C=0.35);
The concrete performance assay:
Figure 94104016X_IMG4
Annotate: * limits the ratio of reinforcement 0.785%.
5, embodiment five
Cement production:
Label is greater than 525 #(contain 525 #) the levigate zeolite rock powder 10%+ of portland-type cement 83%+ composite expanding agent 7%+2.5% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → III type cement
Concrete mix recommended parameter (kg/m 3):
III type cement: 625, medium sand (fineness modulus 2.8): 714, limestone gravel (5~25mm): 986, water 175, (W/C=0.28);
The concrete performance assay:
Figure 94104016X_IMG5
Annotate: * limits the ratio of reinforcement 0.785%.
6, embodiment six
Label is greater than 525 #(contain 525 #) portland-type cement 80%+ silicon ash 10%+U-II type swelling agent 10%+2.5% naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer → mixing is levigate 15~20 minutes (0.08mm tails over≤5.0%) → III type cement
Concrete mix recommended parameter (kg/m 3):
Type III cement: 600, medium sand (fineness modulus 2.8): 722, rubble (5~25mm): 998, water: 180, (W/C=0.30);
The concrete performance assay:
Figure 94104016X_IMG6
Annotate: * limits the ratio of reinforcement 0.785%.
With the cement special of different model of the present invention, can make the preparation of high efficient concrete of different requirements at the construction field (site) by different proportionings.
I type cement special concrete formulating method routinely can make the C50 concrete.
II type cement special concrete formulating method routinely can make the C60 concrete.
III type cement special concrete formulating method routinely can make the C70 concrete.

Claims (7)

1, a kind of high-effect cement special for concrete is characterized in that at label greater than 525 #(contain 525 #) add material modified, superplasticizer, expandable material in the portland-type cement, said material modified be in levigate blast-furnace slag, flyash, zeolite rock powder, the silicon ash any, said superplasticizer is the solid, powdery high efficiency water reducing agent, as naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer, said expandable material is commercially available cement expansive material, as U type cement expansive material, composite expanding agent, alumite plumping agent, each component ratio of this cement special is: label is greater than 525 #(contain 525 #) portland-type cement 65~80%, material modified 10~25%, superplasticizer 1.5~2.5%, expandable material 7~15%.
2, cement special according to claim 1 is characterized by each set of dispense ratio and is: label is greater than 525 #(contain 525 #) portland-type cement 65%+U type swelling agent 10%+ ground slag powder 25%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 1.7%.
3, according to the said cement special of claim 1, it is characterized by its each set of dispense ratio and be: label is greater than 525 #(contain 525 #) portland-type cement 65%+ II level flyash 20%+ alumite plumping agent 15%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 1.7%.
4, according to the said cement special of claim 1, it is characterized by its each set of dispense ratio and be: label is greater than 525 #(contain 525 #) portland-type cement 65%+ II level flyash 20%+ alumite plumping agent 15%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 1.5%.
5, according to the said cement special of claim 1, it is characterized by it and the ratio of each component is: label is greater than 525 #(contain 525 #) portland-type cement 73%+ II level flyash 15%+U-II type swelling agent 12%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 1.5%.
6, according to the said cement special of claim 1, it is characterized by it and the ratio of each component is: label is greater than 525 #(contain 525 #) the levigate zeolite rock powder 10%+ of portland-type cement 83%+ composite expanding agent 7%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 2.5%.
7, according to the said cement special of claim 1, it is characterized by its each set of dispense ratio and be: label is greater than 525 #(contain 525 #) portland-type cement 80%+ silicon ash 10%+U-II type swelling agent 10%+ naphthalene sulfonate formaldehyde condensate type highly-efficient water reducer 2.5%.
CN94104016A 1994-04-15 1994-04-15 High-effect cement special for concrete Pending CN1096280A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1041712C (en) * 1994-12-14 1999-01-20 华南理工大学 Method for preparing high impervious and anticorrosive concrete with ternary agent
CN100357211C (en) * 2006-04-26 2007-12-26 刘正卫 Cement mortar plasticizer
CN100398480C (en) * 2004-07-21 2008-07-02 柳州欧维姆机械股份有限公司 High-strength cement mortar and construction process for pouring said mortar thereof
CN101172820B (en) * 2007-10-25 2010-04-14 武汉理工大学 Method for producing high-strength high damping concrete
CN106747637A (en) * 2016-12-23 2017-05-31 河南华泰新材科技股份有限公司 A kind of water penetration foam concrete
CN107298553A (en) * 2016-12-02 2017-10-27 徐州中联混凝土有限公司 A kind of cement artware slurry
CN108285359A (en) * 2018-03-29 2018-07-17 合肥市闵葵电力工程有限公司 A kind of repairing cement special based polyalcohol mortar and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1041712C (en) * 1994-12-14 1999-01-20 华南理工大学 Method for preparing high impervious and anticorrosive concrete with ternary agent
CN100398480C (en) * 2004-07-21 2008-07-02 柳州欧维姆机械股份有限公司 High-strength cement mortar and construction process for pouring said mortar thereof
CN100357211C (en) * 2006-04-26 2007-12-26 刘正卫 Cement mortar plasticizer
CN101172820B (en) * 2007-10-25 2010-04-14 武汉理工大学 Method for producing high-strength high damping concrete
CN107298553A (en) * 2016-12-02 2017-10-27 徐州中联混凝土有限公司 A kind of cement artware slurry
CN106747637A (en) * 2016-12-23 2017-05-31 河南华泰新材科技股份有限公司 A kind of water penetration foam concrete
CN108285359A (en) * 2018-03-29 2018-07-17 合肥市闵葵电力工程有限公司 A kind of repairing cement special based polyalcohol mortar and preparation method thereof

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