CN109627796A - A kind of pitch and preparation method thereof that cast-type is granulated - Google Patents
A kind of pitch and preparation method thereof that cast-type is granulated Download PDFInfo
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- CN109627796A CN109627796A CN201811584517.4A CN201811584517A CN109627796A CN 109627796 A CN109627796 A CN 109627796A CN 201811584517 A CN201811584517 A CN 201811584517A CN 109627796 A CN109627796 A CN 109627796A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 95
- 239000000463 material Substances 0.000 claims abstract description 51
- 239000010426 asphalt Substances 0.000 claims abstract description 45
- 239000011162 core material Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000004014 plasticizer Substances 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims abstract description 14
- 230000002035 prolonged effect Effects 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 3
- 239000011295 pitch Substances 0.000 claims description 158
- 229920005989 resin Polymers 0.000 claims description 29
- 239000011347 resin Substances 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 18
- 238000002844 melting Methods 0.000 claims description 17
- 230000008018 melting Effects 0.000 claims description 17
- 230000002207 retinal effect Effects 0.000 claims description 13
- 239000005662 Paraffin oil Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 238000005266 casting Methods 0.000 claims description 9
- 239000011280 coal tar Substances 0.000 claims description 9
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 150000003505 terpenes Chemical class 0.000 claims description 8
- 235000007586 terpenes Nutrition 0.000 claims description 8
- 150000002885 octadecanoids Chemical class 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 6
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 6
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 5
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 5
- KHPFIDDXCRYEHS-UHFFFAOYSA-N 2-butyloctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)CCCC KHPFIDDXCRYEHS-UHFFFAOYSA-N 0.000 claims description 4
- 150000003097 polyterpenes Chemical class 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 45
- 239000002245 particle Substances 0.000 abstract description 7
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000009413 insulation Methods 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 2
- 239000004567 concrete Substances 0.000 description 10
- 238000001816 cooling Methods 0.000 description 9
- 239000002826 coolant Substances 0.000 description 8
- 238000012856 packing Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 4
- 239000011604 retinal Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000011384 asphalt concrete Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229940038384 octadecane Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000005128 Sapium sebiferum Nutrition 0.000 description 1
- 244000057114 Sapium sebiferum Species 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- ZRHANBBTXQZFSP-UHFFFAOYSA-M potassium;4-amino-3,5,6-trichloropyridine-2-carboxylate Chemical compound [K+].NC1=C(Cl)C(Cl)=NC(C([O-])=O)=C1Cl ZRHANBBTXQZFSP-UHFFFAOYSA-M 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2495/00—Bituminous materials, e.g. asphalt, tar or pitch
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Working-Up Tar And Pitch (AREA)
Abstract
The embodiment of the invention discloses the pitch and preparation method thereof that a kind of cast-type is granulated, composition includes following each substances: agent, plasticizer and adhesive are prolonged in casing material, interior core material, promotor, increasing.The pitch that cast-type of the invention is granulated, which can be directly added into, to be mixed field and mixes in cylinder, pitch particle is crushed and melted by the high shear force and heat that gather materials, mixing asphalt avoids the disadvantages of taller temperature saves after liquid asphalt needs insulation vehicle to be transported, arrives at scene；It can also be achieved and liquid asphalt is saved and transported at normal temperature, it is energy saving, develop a circular economy, protect harmonious development.
Description
Technical field
The present embodiments relate to the manufacturing technology fields that pitch is granulated, and in particular to a kind of pitch that cast-type is granulated and
Preparation method.
Background technique
Crude oil carries out deep processing by petrochemical industry refinery, and light component goes production high added value product, heavy constituent drip toward downstream
Green raw material is also to play most important property during infrastructure, and asphalt stock needs high temperature during preservation, transport etc.,
The components such as volatile polycyclic aromatic hydrocarbon for a long time, harm health are developed under a kind of normal temperature state and are saved and the pitch of transport, for section
About the energy, develop a circular economy, harmonious development protected to be important measure.
During asphalt pavement construction, produces asphalt concrete and modified asphalt concrete is all using liquid
Heavy traffic paving asphalt and polymer modified asphalt under state, heavy traffic paving asphalt and polymer modified asphalt under liquid to production concrete
It is using refinery as starting point, hot charge is transported by insulation vehicle to asphalt blending station, is squeezed into asphalt tank by live bitumenpump
Heat preservation saves, and when use, which is warming up to required temperature again and enters batching plant and mix, produces bituminous concrete in cylinder.Crude oil passes through Atmospheric vacuum
Asphaltic by-products are High temperature storages in refinery after distillation, are also to need High temperature storage in transportational process, it is existing to arrive at blending station
It is also to need High temperature storage after.One, it certainly will be more vigilant to the safety of transport；Two, a large amount of energy certainly will be needed to it
Heating, energy burning and pitch high-temperature volatile itself will generate exhaust emissions.Therefore, it develops under a kind of normal temperature state and protects
The pitch deposited and transported is very important.
Chinese invention patent discloses a kind of globular asphalt granulating device and prilling process, and the device of invention design is related to
One vertical shaft, shaft is driven by power device to be rotated, and lower end connects hemispherical centrifugation pot, passes through centrifugal rotational speed and raw material
Flow control particle size, granulation speed is fast, quality is good, however, it is very difficult to meet common heavy traffic paving asphalt or polymer modified asphalt
It is granulated.Chinese invention patent also discloses a kind of Hard asphalt granulation method and its device, and the invention is by the hard of molten condition
Pitch by distributing device with the uniform cloth of drop-wise revolution steel band on, revolution steel band below setting cool water shower to steel band cool down,
End isolates and falls off the particle of curing molding again, and simple process, operating cost are low, still, to low softening point, viscosity it is lesser
Pitch is not applicable.Chinese invention patent also discloses a kind of pitch pelletizer, which includes hopper, nozzle, cylindric granulation
Net, water cooling pond and scraper plate realize that pitch is granulated by cold water, and structure is simple, at low cost, still, are still difficult to meet common
Heavy traffic paving asphalt or polymer modified asphalt are granulated.
Summary of the invention
For this purpose, the embodiment of the present invention provides a kind of pitch and preparation method thereof that cast-type is granulated, to solve the prior art
The preparation process of middle pitch is complicated, safety is poor, at high cost and be difficult to meet common heavy traffic paving asphalt or polymer modified asphalt
The problem of granulation.
To achieve the goals above, embodiments of the present invention provide the following technical solutions:
A kind of pitch that cast-type is granulated, composition includes following each substances: casing material, interior core material, promotor, increasing are prolonged
Agent, plasticizer and adhesive, wherein the casing material be the casing material containing high softening point bitumen, the interior core material be containing
There is the interior core material of low softening point asphalt, the promotor is the promotor containing sulfenamide or thiurams；Containing thio
Agent is prolonged in the increasing of sodium sulphate or polycyclic aromatic hydrocarbon sodium sulfonate；The plasticizer is the plasticizer containing paraffin oil or retinal；The glue
Glutinous agent is the adhesive containing terpene resin or C 9 petroleum resin.
The weight that the casing material, interior core material, promotor, increasing prolong agent, plasticizer and adhesive is respectively as follows: institute
State casing material are as follows: 5~15 parts；The interior core material are as follows: 60~90 parts；The promotor are as follows: 0.01~0.5 part；Agent is prolonged in the increasing
Are as follows: 5~10 parts；The plasticizer are as follows: 0.5~2 part；The adhesive: 1~5 part.
The casing material is any one in high-quality pitch, No. 10 pitches or No. 30 pitches, and the high softening-point drips
Blueness is that softening point is higher than plain asphalt or polymer modified asphalt, and temperature is at 95 DEG C or more；The high-quality pitch contains for asphalitine
Amount is higher than the pitch of plain asphalt or polymer modified asphalt.
The interior core material is No. 70 pitches, the SBS of No. 90 pitches, No. 110 pitches, the SBS modified pitch of I-D, I-C are modified
Pitch, the SBS modified pitch of I-B, the SBS modified pitch of I-A, the SBR modified pitch of II-C, II-B SBR modified pitch or
Any one in the SBR modified pitch of II-A.
The promotor is one of sulfenamide type accelerators, thuriam acceserator or octadecanoid acid or any several
The mixture of kind.
It is in sodium thiosulfate, polycyclic aromatic hydrocarbon sodium sulfonate, sulphur sodium aluminate, triethanolamine or butyl stearic acid that agent is prolonged in the increasing
One or any of several mixture.
The plasticizer is one of paraffin oil, retinal or coal tar or any several mixture.
The adhesive is terpene resin, C 9 petroleum resin, coumarone indene resin, polyterpene resin or polyvinyl butyral
One of or any several mixture.
A kind of preparation method for the pitch that cast-type is granulated, comprising the following steps:
S1: casing material is subjected to pre- melt processed, and the temperature of pre- melt processed is 160~210 DEG C, and interior core material is carried out
Isothermal holding, and the temperature setting of isothermal holding is 100~160 DEG C；
S2: promotor is added in casing material and carries out mixed melting stirring, obtains the first mixture；
S3: agent the first mixture of addition is prolonged into increasing and is mixed, the second mixture is obtained；
S4: being added plasticizer into the second mixture, be mixed, and obtains third mixture；
S5: attached one layer of adhesive is wrapped up in the outer surface of interior core material, then in one layer of third mixture of its surface casting, obtains institute
The pitch that the cast-type stated is granulated.
The partial size for the pitch that the cast-type is granulated is 5~10mm, and single quality is 3~8g.
The embodiment of the present invention has the advantage that
1) embodiment of the present invention wraps up in the asphalt surface for being attached to low softening point using the pitch of high softening-point, avoids low softening point
Pitch is directly granulated easily there is a phenomenon where being bonded, and hard grades of bitumen prilling can only be applicable in by having broken original technology, enrich drip
Blueness is granulated manufacturing technology.
2) the common heavy traffic paving asphalt of tradition or polymer modified asphalt are all to be saved with liquid condition, and need high temperature,
The bitumen technology that the embodiment of the present invention then utilizes cast-type to be granulated, causes solid for common heavy traffic paving asphalt or polymer modified asphalt
Particle can be saved under normal temperature state, also relatively convenient for subsequent transportation aspect, only need general wagon, nothing
Special insulation vehicle is needed to be transported.
3) embodiment of the present invention can will directly cause solid by dispensing device when pitch mixes practical application
The pitch addition of grain is mixed and stirred field and is mixed in cylinder, and pitch particle is crushed and melted by the high shear force and heat that gather materials,
Mixing asphalt, it is energy saving thus without using high-temperature heating tank and heat-conducting oil heating system at the scene, it reduces
Carbon emission.
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
Embodiment 1
The preparation method for the pitch that the cast-type that the embodiment of the present invention 1 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
10 parts of the high-quality pitch of casing material, 70 parts of the pitch of interior core material 70,0.2 part of sulfenamide type accelerators, thiosulfuric acid
8 parts of sodium, 1 part of paraffin oil, 4 parts of terpene resin；
Preparation method concrete operations are as follows:
S1: the high-quality pitch of casing material is subjected to pre- melt processed, the temperature of pre- melt processed is 210 DEG C, interior core material 70
Pitch carries out isothermal holding, and the temperature setting of isothermal holding is 120 DEG C；
S2: the high-quality pitch of casing material is added in sulfenamide type accelerators and carries out mixed melting stirring, obtains the first mixing
Object, wherein mixed melting mixing speed is 30r/min, mixing time 15min；
S3: the first mixture is added in sodium thiosulfate and is mixed, the second mixture is obtained, wherein mixing is stirred
Mixing speed is 40r/min, mixing time 20min；
S4: being added paraffin oil into the second mixture, be mixed, and obtains third mixture, wherein is mixed
Speed is 45r/min, mixing time 15min；
S5: attached floor terpene resin is wrapped up in No. 70 pitch outer surfaces of interior core material, then in the one layer of third mixing of its surface casting
Object obtains the pitch that the cast-type is granulated, cooling, packing, wherein and the partial size for the pitch that cast-type is granulated is 5~10mm,
Single quality is 3~8g, and coolant temperature is 10~30 DEG C, the pitch 1 that final obtained cast-type is granulated.
Embodiment 2
The preparation method for the pitch that the cast-type that the embodiment of the present invention 2 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
5 parts of the pitch of casing material 10,80 parts of the pitch of interior core material 90,0.3 part of thuriam acceserator, polycyclic aromatic hydrocarbon sulfonic acid
5 parts of sodium, 1.5 parts of retinal, 3 parts of C 9 petroleum resin；
Preparation method concrete operations are as follows:
S1: No. 10 pitches of casing material are subjected to pre- melt processed, the temperature of pre- melt processed is 200 DEG C, interior core material 90
Pitch carries out isothermal holding, and the temperature setting of isothermal holding is 110 DEG C；
S2: being added No. 10 pitches of casing material for thuriam acceserator and carry out mixed melting stirring, obtain the first mixture,
Wherein, the speed of mixed melting stirring is 20r/min, mixing time 20min；
S3: the first mixture is added in polycyclic aromatic hydrocarbon sodium sulfonate and is mixed, the second mixture is obtained, wherein is mixed
The speed for closing stirring is 50r/min, mixing time 25min；
S4: being added retinal into the second mixture, be mixed, and obtains third mixture, wherein is mixed
Speed be 40r/min, mixing time 20min；
S5: attached floor C 9 petroleum resin is wrapped up in No. 90 pitch outer surfaces of interior core material, then in one layer of third of its surface casting
Mixture obtains the pitch that the cast-type is granulated, cooling, packing, wherein and the partial size for the pitch that cast-type is granulated is 5~
10mm, single quality are 3~8g, and coolant temperature is 10~30 DEG C, finally obtained pitch 2.
Embodiment 3
The preparation method for the pitch that the cast-type that the embodiment of the present invention 3 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
15 parts of the pitch of casing material 30,60 parts of the pitch of interior core material 110,0.4 part of octadecanoid acid, 7 parts of sulphur sodium aluminate, rosin
1.5 parts, 3 parts of C 9 petroleum resin of oil；
Preparation method concrete operations are as follows:
S1: No. 30 pitches of casing material are subjected to pre- melt processed, the temperature of pre- melt processed is 190 DEG C, interior core material 110
Pitch carries out isothermal holding, and the temperature setting of isothermal holding is 100 DEG C；
S2: No. 30 pitches of casing material are added in octadecanoid acid and carry out mixed melting stirring, obtain the first mixture, wherein
The speed of mixed melting stirring is 35r/min, mixing time 10min；
S3: the first mixture is added in sulphur sodium aluminate and is mixed, the second mixture is obtained, wherein is mixed
Speed be 40r/min, mixing time 25min；
S4: being added coal tar into the second mixture, be mixed, and obtains third mixture, wherein is mixed
Speed be 45r/min, mixing time 20min；
S5: attached floor coumarone indene resin is wrapped up in No. 110 pitch outer surfaces of interior core material, then mixed in one layer of third of its surface casting
Object is closed, the pitch that the cast-type is granulated, cooling, packing are obtained, wherein the partial size for the pitch that cast-type is granulated is 5~
10mm, single quality are 3~8g, and coolant temperature is 10~30 DEG C, finally obtained pitch 3.
Embodiment 4
The preparation method for the pitch that the cast-type that the embodiment of the present invention 4 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
15 parts of the high-quality pitch of casing material, interior core material I-D 0.1 part of 80 parts of SBS modified pitch, sulfenamide type accelerators,
5 parts of 1 part of mixture, the polyterpene resin of 7 parts of triethanolamine, paraffin oil and coal tar；
Preparation method concrete operations are as follows:
S1: the high-quality pitch of casing material is subjected to pre- melt processed, the temperature of pre- melt processed is 210 DEG C, interior core material I-D's
SBS modified pitch carries out isothermal holding, and the temperature setting of isothermal holding is 160 DEG C；
S2: the high-quality pitch of casing material is added in sulfenamide type accelerators and carries out mixed melting stirring, obtains the first mixing
Object, wherein the speed of mixed melting stirring is 38r/min, mixing time 15min；
S3: the first mixture is added in triethanolamine and is mixed, the second mixture is obtained, wherein is mixed
Speed be 45r/min, mixing time 20min；
S4: the mixture of paraffin oil and coal tar being added into the second mixture, is mixed, and obtains third mixing
Object, wherein the speed of mixing is 45r/min, mixing time 20min；
S5: attached one layer of polyterpene resin is wrapped up in the SBS modified pitch outer surface of interior core material I-D, then at one layer of its surface casting
Third mixture obtains the pitch that the cast-type is granulated, cooling, packing, wherein the partial size for the pitch that cast-type is granulated is
5~10mm, single quality are 3~8g, and coolant temperature is 10~30 DEG C, finally obtained pitch 4.
Embodiment 5
The preparation method for the pitch that the cast-type that the embodiment of the present invention 5 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
60 parts of SBS modified pitch, sulfenamide type accelerators and the octadecane of 8 parts of the pitch of casing material 10, interior core material I-C
Acid 0.5 part of mixture, 5 parts of butyl stearic acid, paraffin oil and retinal 4 parts of 2 parts of mixture, polyvinyl butyral；
Preparation method concrete operations are as follows:
S1: the high-quality pitch of casing material is subjected to pre- melt processed, the temperature of pre- melt processed is 205 DEG C, interior core material I-C's
SBS modified pitch carries out isothermal holding, and the temperature setting of isothermal holding is 155 DEG C；
S2: the high-quality pitch of casing material is added in the mixture of sulfenamide type accelerators and octadecanoid acid and carries out mixed melting
Stirring, obtains the first mixture, wherein the speed of mixed melting stirring is 45r/min, mixing time 15min；
S3: the first mixture is added in butyl stearic acid and is mixed, the second mixture is obtained, wherein mixing is stirred
The speed mixed is 45r/min, mixing time 25min；
S4: the mixture of paraffin oil and retinal being added into the second mixture, is mixed, and obtains third mixing
Object, wherein the speed of mixing is 50r/min, mixing time 20min；
S5: attached layer of polyethylene butyral is wrapped up in the SBS modified pitch outer surface of interior core material I-C, then is poured on its surface
One layer of third mixture of note obtains the pitch that the cast-type is granulated, cooling, packing, wherein the pitch that cast-type is granulated
Partial size is 5~10mm, and single quality is 3~8g, and coolant temperature is 10~30 DEG C, finally obtained pitch 5.
Embodiment 6
The preparation method for the pitch that the cast-type that the embodiment of the present invention 6 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
70 parts of SBS modified pitch, sulfenamide type accelerators and the thiuram of 7 parts of the pitch of casing material 30, interior core material I-B
The mixture 2 that 0.3 part of mixture, the sulphur aluminic acid of class promotor are received with 8 parts of the stearic mixture of butyl, retinal and coal tar
Part, 3 parts of mixture of coumarone indene resin and polyvinyl butyral；
Preparation method concrete operations are as follows:
S1: No. 30 pitches of casing material are subjected to pre- melt processed, the temperature of pre- melt processed is 185 DEG C, interior core material I-B's
SBS modified pitch carries out isothermal holding, and the temperature setting of isothermal holding is 150 DEG C；
S2: the mixture of sulfenamide type accelerators and thuriam acceserator addition No. 30 pitches of casing material are mixed
Fusing stirring is closed, the first mixture is obtained, wherein the speed of mixed melting stirring is 40r/min, mixing time 18min；
S3: sulphur aluminic acid is received and is mixed with butyl the first mixture of stearic mixture addition, obtains second
Mixture, wherein the speed of mixing is 40r/min, mixing time 28min；
S4: the mixture of retinal and coal tar being added into the second mixture, is mixed, and obtains third mixing
Object, wherein the speed of mixing is 40r/min, mixing time 28min；
S5: attached one layer of coumarone indene resin and polyvinyl butyral are wrapped up in the SBS modified pitch outer surface of interior core material I-B
Mixture, then in one layer of third mixture of its surface casting, the pitch that the cast-type is granulated is obtained, cooling dispenses,
In, the partial size for the pitch that cast-type is granulated is 5~10mm, and single quality is 3~8g, and coolant temperature is 10~30 DEG C, most
Obtained pitch 6 eventually.
Embodiment 7
The preparation method for the pitch that the cast-type that the embodiment of the present invention 7 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
70 parts of SBR modified pitch, thuriam acceserator and the octadecane of 8 parts of the pitch of casing material 10, interior core material II-C
The nine petroleum tree of 0.8 part of 10 parts of mixture, retinal, terpene resin and carbon of 0.3 part of acid, polycyclic aromatic hydrocarbon sodium sulfonate and triethanolamine
3 parts of the mixture of rouge；
Preparation method concrete operations are as follows:
S1: No. 20 pitches of casing material are subjected to pre- melt processed, the temperature of pre- melt processed is 205 DEG C, interior core material II-C
SBR modified pitch carry out isothermal holding, the temperature setting of isothermal holding is 150 DEG C；
S2: the high-quality pitch of the addition casing material of thuriam acceserator and octadecanoid acid is subjected to mixed melting stirring, is obtained
To the first mixture, wherein the speed of mixed melting stirring is 42r/min, mixing time 15min；
S3: the first mixture is added in the mixture of polycyclic aromatic hydrocarbon sodium sulfonate and triethanolamine and is mixed, is obtained
Second mixture, wherein the speed of mixing is 42r/min, mixing time 27min；
S4: being added retinal into the second mixture, be mixed, and obtains third mixture, wherein is mixed
Speed be 40r/min, mixing time 24min；
S5: the mixed of attached one layer of terpene resin and C 9 petroleum resin is wrapped up in the SBR modified pitch outer surface of interior core material II-C
Object is closed, then in one layer of third mixture of its surface casting, obtains the pitch that the cast-type is granulated, cooling, packing, wherein
The partial size for the pitch that cast-type is granulated is 5~10mm, and single quality is 3~8g, and coolant temperature is 10~30 DEG C, final to make
Obtain pitch 7.
Embodiment 8
The preparation method for the pitch that the cast-type that the embodiment of the present invention 8 provides is granulated, the pitch which is granulated is under
State each material composition of parts by weight:
0.3 part of 80 parts of SBR modified pitch, octadecanoid acid, the thiosulfuric acid of 13 parts of the pitch of casing material 30, interior core material II-A
6 parts of the mixture of sodium and sulphur sodium aluminate, paraffin oil, retinal and coal tar 2 parts of mixture, C 9 petroleum resin, coumarone
5 parts of mixture of resin and polyvinyl butyral；
Preparation method concrete operations are as follows:
S1: No. 30 pitches of casing material are subjected to pre- melt processed, the temperature of pre- melt processed is 190 DEG C, interior core material II-A
SBR modified pitch carry out isothermal holding, the temperature setting of isothermal holding is 145 DEG C；
S2: No. 30 pitches of casing material are added in octadecanoid acid and carry out mixed melting stirring, obtain the first mixture, wherein
The speed of mixed melting stirring is 37r/min, mixing time 18min；
S3: the first mixture is added in the mixture of sodium thiosulfate and sulphur sodium aluminate and is mixed, obtains second
Mixture, wherein the speed of mixing is 43r/min, mixing time 26min；
S4: the mixture of paraffin oil, retinal and coal tar is added into the second mixture, is mixed, is obtained
Third mixture, wherein the speed of mixing is 36r/min, mixing time 22min；
S5: attached one layer of C 9 petroleum resin, coumarone indene resin are wrapped up in the SBR modified pitch outer surface of interior core material II-A and is gathered
The mixture of vinyl butyral, then in one layer of third mixture of its surface casting, the pitch that the cast-type is granulated is obtained,
Cooling, packing, wherein the partial size for the pitch that cast-type is granulated is 5~10mm, and single quality is 3~8g, and coolant temperature is
10~30 DEG C, pitch 8 is finally made.
The pitch being granulated to the cast-type of embodiment 1-8 preparation is sampled, and is carried out detection according to asphalt test regulation and is made
At the asphaltic nature index of particle, core material has common heavy traffic paving asphalt also to have polymer modified asphalt in the pitch that cast-type is granulated.
The experimental data are shown in the following table 1.
The bitumen technology property index that 1 cast-type of table is granulated
From above-mentioned experimental data: the either common heavy traffic paving asphalt of interior core material or modified pitch, according to this cast-type
The pitch that liquid heat preservation saves is become the pitch particle that solid is stored at room temperature by the preparation method of the pitch of granulation, needle penetration,
The technological properties such as softening point, ductility index still meets the technological property index request of interior core material itself.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (10)
1. the pitch that a kind of cast-type is granulated, which is characterized in that it includes following each substances: casing material, interior core material, promotion that it, which is formed,
Agent, plasticizer and adhesive are prolonged in agent, increasing, wherein the casing material is the casing material containing high softening point bitumen, the inner core
Material is the interior core material containing low softening point asphalt, and the promotor is the promotor containing sulfenamide or thiurams；Contain
There are sodium thiosulfate or the increasing of polycyclic aromatic hydrocarbon sodium sulfonate to prolong agent；The plasticizer is the plasticizer containing paraffin oil or retinal；
The adhesive is the adhesive containing terpene resin or C 9 petroleum resin.
2. the pitch that cast-type according to claim 1 is granulated, which is characterized in that the casing material, interior core material, promotion
The weight that agent, plasticizer and adhesive are prolonged in agent, increasing is respectively as follows: the casing material are as follows: 5~15 parts；The interior core material
Are as follows: 60~90 parts；The promotor are as follows: 0.01~0.5 part；Agent is prolonged in the increasing are as follows: 5~10 parts；The plasticizer are as follows: 0.5~2
Part；The adhesive: 1~5 part.
3. the pitch that cast-type according to claim 1 is granulated, which is characterized in that the casing material is high-quality pitch, 10
Any one in number pitch or No. 30 pitches, and the high softening point bitumen is that softening point is higher than plain asphalt or polymer changes
Property pitch, temperature is at 95 DEG C or more；The high-quality pitch is that asphalt content is higher than plain asphalt or polymer modified asphalt
Pitch.
4. the pitch that cast-type according to claim 2 is granulated, which is characterized in that the interior core material is No. 70 pitches, 90
Number pitch, No. 110 pitches, the SBS modified pitch of I-D, the SBS modified pitch of I-C, the SBS modified pitch of I-B, I-A SBS
Modified pitch, the SBR modified pitch of II-C, the SBR modified pitch of II-B or II-A SBR modified pitch in any one.
5. the pitch that cast-type according to claim 2 is granulated, which is characterized in that the promotor is sulfenamide rush
Into one of agent, thuriam acceserator or octadecanoid acid or any several mixture.
6. the pitch that cast-type according to claim 2 is granulated, which is characterized in that the increasing prolong agent be sodium thiosulfate,
One of polycyclic aromatic hydrocarbon sodium sulfonate, sulphur sodium aluminate, triethanolamine or butyl stearic acid or any several mixture.
7. the pitch that cast-type according to claim 2 is granulated, which is characterized in that the plasticizer is paraffin oil, rosin
One of oil or coal tar or any several mixture.
8. the pitch that cast-type according to claim 1 is granulated, which is characterized in that the adhesive is terpene resin, carbon
One of 9 petroleum resin, coumarone indene resin, polyterpene resin or polyvinyl butyral or any several mixture.
9. a kind of preparation method for the pitch that cast-type is granulated, which comprises the following steps:
S1: casing material is subjected to pre- melt processed, and the temperature of pre- melt processed is 160~210 DEG C, and interior core material is kept the temperature
Processing, and the temperature setting of isothermal holding is 100~160 DEG C；
S2: promotor is added in casing material and carries out mixed melting stirring, obtains the first mixture；
S3: agent the first mixture of addition is prolonged into increasing and is mixed, the second mixture is obtained；
S4: being added plasticizer into the second mixture, be mixed, and obtains third mixture；
S5: wrapping up in attached one layer of adhesive in the outer surface of interior core material, then in one layer of third mixture of its surface casting, obtains described
The pitch that cast-type is granulated.
10. the preparation method for the pitch that cast-type according to claim 9 is granulated, which is characterized in that the cast-type is made
The partial size of the pitch of grain is 5~10mm, and single quality is 3~8g.
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| CN102027070A (en) * | 2008-08-29 | 2011-04-20 | 威廉·R·拜莱 | Rubberized asphalt pellets |
| US20150307713A1 (en) * | 2012-12-05 | 2015-10-29 | Eiffage Travaux Publics | Bituminous composition in the form of granules and method for preparing same |
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| CN108795075A (en) * | 2018-07-02 | 2018-11-13 | 周祥 | A kind of granulating modified pitch and preparation method thereof |
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2018
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|---|---|---|---|---|
| CN102027070A (en) * | 2008-08-29 | 2011-04-20 | 威廉·R·拜莱 | Rubberized asphalt pellets |
| US20150307713A1 (en) * | 2012-12-05 | 2015-10-29 | Eiffage Travaux Publics | Bituminous composition in the form of granules and method for preparing same |
| CN105585858A (en) * | 2014-10-22 | 2016-05-18 | 中国石油化工股份有限公司 | Modified asphalt composition particles and preparation method thereof |
| CN108384035A (en) * | 2018-02-01 | 2018-08-10 | 武汉理工大学 | A kind of hud typed slag base composite modified asphalt particle and preparation method thereof |
| CN108795075A (en) * | 2018-07-02 | 2018-11-13 | 周祥 | A kind of granulating modified pitch and preparation method thereof |
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