CN109626328A - A kind of portable chlorination apparatus for forming hydrogen - Google Patents
A kind of portable chlorination apparatus for forming hydrogen Download PDFInfo
- Publication number
- CN109626328A CN109626328A CN201811527962.7A CN201811527962A CN109626328A CN 109626328 A CN109626328 A CN 109626328A CN 201811527962 A CN201811527962 A CN 201811527962A CN 109626328 A CN109626328 A CN 109626328A
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- China
- Prior art keywords
- cylinder
- tower
- rod
- column casing
- shaped lid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000005660 chlorination reaction Methods 0.000 title claims abstract description 13
- 239000001257 hydrogen Substances 0.000 title claims abstract description 13
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 10
- 239000007789 gas Substances 0.000 claims abstract description 45
- 239000012530 fluid Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 34
- 239000007788 liquid Substances 0.000 claims description 21
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 230000008676 import Effects 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 80
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract description 42
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract description 42
- 238000002360 preparation method Methods 0.000 abstract description 4
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- -1 cylinder Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 62
- 239000000243 solution Substances 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 230000005484 gravity Effects 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000001360 synchronised effect Effects 0.000 description 2
- 238000002207 thermal evaporation Methods 0.000 description 2
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/07—Purification ; Separation
- C01B7/0706—Purification ; Separation of hydrogen chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention belongs to chemical gas preparation technical field, specifically a kind of portable chlorination apparatus for forming hydrogen, including cylinder, inlet tube, escape pipe, transverse slat, skewback, column casing, tower-shaped lid, pull rod and swing rod；The transverse slat is connected on cylinder inboard wall and is sealed to a storage cavities between the transverse slat and cylinder body bottom；The cylinder lateral wall bottom is provided with leakage fluid dram；Described leakage fluid dram one end is connected to storage cavities；The column casing is connected in the middle part of transverse slat, is provided with venthole on the side wall of column casing two sides；The skewback, which is connected between transverse slat two sides and the skewback and column casing, gap, and skewback sidewall upper is equipped with oblique angle；The transverse slat two sides are provided with inlet；The inlet upper end is in the gap between skewback and column casing；The tower-shaped lid is located above column casing and the tower-shaped lid is slidably connected on column casing outer wall, and the configuration of the present invention is simple is easy to operate, energy conservation and environmental protection, improves the generating rate of hydrogen chloride gas.
Description
Technical field
The invention belongs to chemical gas preparation technical field, specifically a kind of portable chlorination apparatus for forming hydrogen.
Background technique
HCL gas is commonly used in medical industry, mainly uses heating, enriching sulfuric acid etc. by the volatile hydrogen chloride in concentrated hydrochloric acid
Out, then through filtering out obtained by steam.
In existing hydrogen chloride preparation process, come out volatile hydrogen chloride dilute hydrochloric acid heating, while a large amount of water can be taken out of
There is dry difficulty in vapour；And gas is generated and is difficult to control, and there are larger problems for storage, and the concentrated sulfuric acid are added dilute
In hydrochloric acid, since the concentrated sulfuric acid has strong absorptive, and heat release when being mixed with water, cause temperature to increase, hydrogen chloride, which largely volatilizees, to be made
Standby hydrogen chloride gas；But the hydrogen chloride formation speed of this method is not easy to control, easily causes container inner pressure excessive, and hydrogen chloride has by force
Corrosivity can not apply safety valve pressure release, therefore easily cause safety accident.Therefore, it is necessary to one kind to be suitable for by dilute hydrochloric acid and dense
Sulfuric acid prepares the device of hydrogen chloride gas, to realize the purpose of the easy preparation of hydrogen chloride gas.
Summary of the invention
In order to make up for the deficiencies of the prior art, a kind of portable chlorination apparatus for forming hydrogen proposed by the present invention, it is of the invention
The heat of the hydrogen chloride gas generated and generation, energy conservation and environmental protection mention when purpose is that the concentrated sulfuric acid and dilute hydrochloric acid is made full use of to react
The generating rate of high hydrogen chloride gas.
The technical solution adopted by the present invention to solve the technical problems is: a kind of portable hydrogen chloride hair of the present invention
Generating apparatus, including cylinder, inlet tube, escape pipe, transverse slat, skewback, column casing, tower-shaped lid, pull rod and swing rod；The transverse slat is connected in
A storage cavities are sealed on cylinder inboard wall and between the transverse slat and cylinder body bottom；The cylinder lateral wall bottom is provided with drain
Mouthful；Described leakage fluid dram one end is connected to storage cavities；The column casing is connected in the middle part of transverse slat, is provided with outlet on the side wall of column casing two sides
Hole；The skewback, which is connected between transverse slat two sides and the skewback and column casing, gap, and skewback sidewall upper is equipped with oblique angle；It is described
Transverse slat two sides are provided with inlet；The inlet upper end is in the gap between skewback and column casing；The tower-shaped lid is located at column
Above cylinder and the tower-shaped lid is slidably connected on column casing outer wall, and tower-shaped lid two sides side wall is equipped with gas vent, tower-shaped cover outer wall
Bottom is equipped with oblique angle, and the oblique angle on the tower-shaped oblique angle and skewback covered matches, and tower-shaped cover is sealed in stationary state
The gap between skewback and tower-shaped lid is closed, surrounds a closed cavity between tower-shaped lid and column casing；The pull rod is connected in tower-shaped
Lid top middle portion, pull rod upper end is equidistant to be equipped with multiple ring gears, and volute spring is equipped between pull rod top and cylinder top inner wall,
Pull rod lower end is hinged with multiple diversion rods by hinged block；The diversion rod is circumferentially uniformly distributed along pull rod center, diversion rod with it is tower-shaped
It is equipped with tension spring between lid, is provided with multiple deflector holes on diversion rod；It is circumferentially evenly equipped on the cylinder top inner wall along body centre
Multiple connecting rods；Described connecting rod one end is hinged on cylinder inboard wall, and the connecting rod other end is hinged in the middle part of swing rod；It is set inside the swing rod
There is cavity；Multiple liquid outlets are equipped with below the cavity；Described swing rod one end is contacted with steel ring, and steel ring can make circumferentially uniformly distributed
Swing link synchronous is swung, and one end on swing rod close to pull rod is provided with the gear teeth and the gear teeth and ring gear cooperate；Two inlet tubes about
Body centre is arranged symmetrically, and inlet tube is arranged in the cavity of cylinder top and inlet tube one end connection swing rod；The cylinder top
Middle part is provided with through-hole；The escape pipe is connected to through-hole.When work, a certain amount of water of injection in column casing, by the concentrated sulfuric acid and dilute salt
Acid pours into inner barrel from the inlet tube of cylinder top two sides respectively, and the concentrated sulfuric acid enters the cavity in swing rod under liquid outlet flow direction
Side, meanwhile, cavity of the dilute hydrochloric acid through swing rod flows to lower section from liquid outlet, passes through during below the concentrated sulfuric acid and dilute hydrochloric acid flow direction
Crossing diversion rod and tentatively mixing makes the two react, and on the one hand generates hydrogen chloride gas and dilute sulfuric acid, on the other hand generates heat,
Hydrogen chloride gas enters escape pipe by the through-hole in the middle part of cylinder top, by escape pipe discharge collect, dilute sulfuric acid and not instead
The complete concentrated sulfuric acid and dilute hydrochloric acid is answered again be sufficiently mixed reacting via the deflector hole flow direction lower section on diversion rod, instead
The heat that should be generated heats cylinder, and the water in column casing is generated vapor by thermal evaporation, and vapor expanded by heating will be above column casing
Tower-shaped lid jack up upwards, the pull rod of the tower-shaped side of covering is moved upwards with tower-shaped lid, the connected ring gear band movable pendulum in pull rod upper end
Bar is swung up, and the volute spring on pull rod top is pressurized, when tower-shaped lid is by jack-up certain altitude, the inclined-plane of tower-shaped lid lower end with
Inclined-plane on skewback is detached from, and the gap that the dilute sulfuric acid sufficiently obtained after reaction enters between cylinder and skewback enters via inlet
Storage cavities store, venthole when tower-shaped lid continues upper sliding, on the gas vent and column casing side wall on tower-shaped lid side wall
When opposite, the gas in closed cavity that tower-shaped lid and column casing surround sprays so that air pressure reduction in closed cavity, tower-shaped to cover
Slide downward is until initial position under the action of gravity and volute spring, the tower-shaped pull rod covered with moving down, thus
Drive swing rod to lower swing, when the closed cavity between tower-shaped lid and column casing again by it is closed when, the gas in closed cavity is again
Tower-shaped caping can be risen, tower-shaped lid, which is constantly jacked up and put down, can make swing rod reciprocally swinging, when the concentrated sulfuric acid is abundant with dilute hydrochloric acid
The dilute sulfuric acid stored in storage cavities is discharged from leakage fluid dram after having reacted.
The cylinder body outer wall is equipped with insulating ring；Helical pipe is equipped in the insulating ring；Helical pipe lower end import
It is connected to air inlet pipe one end；The air inlet pipe other end passes through cylinder lateral wall, skewback and is connected to column casing inner space with column casing side wall.
When work, on the one hand the gas in closed cavity that tower-shaped lid is surrounded with column casing jacks up tower-shaped lid upwards, some gas
It is passed through in the helical pipe in insulating ring by air inlet pipe, insulating ring is heated to heat insulating ring to cylinder, is added
The concentrated sulfuric acid and dilute hydrochloric acid react in fast cylinder, improve the generating rate of hydrogen chloride.
Sliding block is slidably connected in the through-hole of the cylinder top；Drawstring, sliding block top are equipped between the sliding block and pull rod
End is equipped with reset spring；Groove is provided in the through-hole；The height of the groove is greater than the height of sliding block.When work, in cylinder
The hydrogen chloride gas that the concentrated sulfuric acid and dilute hydrochloric acid reaction generate flows to the through-hole of cylinder top, and the sliding block in through-hole is chlorinated hydrogen
It jacks up until sliding block lower end enters in groove, hydrogen chloride gas flows to escape pipe by groove and is collected, and works as hydrogen chloride gas
Through-hole is closed again via escape pipe discharge rear slider slide downward under the action of gravity and reset spring, forms one
A circulation, while sliding block is jacked up drawstring pull pull rod move up can assist it is tower-shaped cover shifting, to increase tower-shaped lid
The number moved up, and then increase the shake number of diversion rod, so that the mixed solution above diversion rod is more fully mixed
It closes, improves the efficiency for generating hydrogen chloride.
The cylinder lateral wall is equipped with multiple stirring rods；It is hinged on the side wall of cylinder in the middle part of the stirring rod；It is described to stir
Mixing bar upper end is arc structure, and stirring rod is located at below swing rod.When work, swing rod is when swinging back and forth, below swing rod
The arc end part of stirring rod is squeezed by swing link end part occurs certain deformation, and stirring rod can swing certain angle, work as swing rod
When the arc end part of end and stirring rod is detached from, stirring rod returns to initial position again, so that stirring rod swings back and forth,
Stirring rod lower end can be stirred the mixed liquor of the concentrated sulfuric acid and dilute hydrochloric acid, so that the two is more fully mixed, reaction rate is more
Fastly, the rate for generating hydrogen chloride gas is improved.
The vertical diversion rod arrangement of deflector hole and the deflector hole rounded corner.When work, the concentrated sulfuric acid and dilute hydrochloric acid are being led
After tentatively mixing reacts in flow post, remaining solution flows to cylinder lower part, the vertical deflector hole cloth of deflector hole via deflector hole
Setting can make have certain angle when solution flow direction lower section, so that more fully mixed behind solution flow direction lower section, deflector hole rounded corner makes
It obtains when solution flows through and is not easy to stop, and then solution is avoided to carry out local heating to the end of deflector hole, to reduce water conservancy diversion nose end
Portion's stress is concentrated, and diversion rod is prevented to be deformed due to stress concentration.
The cavity of the swing rod is taper, and the small end of cavity is close to pull rod.When work, when swing rod is swung, in cavity
The concentrated sulfuric acid and dilute hydrochloric acid are thrown away via liquid outlet, and the centrifugal force being subject at the big end of cavity is big, and the solution of accumulation is more, so that cavity
The solution that liquid outlet at big end is thrown away is more, and solution is thrown out of rear more fully mixed, accelerates reacting for the concentrated sulfuric acid and dilute hydrochloric acid
Rate improves the generating rate of hydrogen chloride.
Beneficial effects of the present invention are as follows:
1. the present invention can make the concentrated sulfuric acid and dilute hydrochloric acid mixed by setting swing rod, tower-shaped lid, column casing, pull rod and diversion rod
It closes uniformly, reacts more abundant, improve the formation efficiency of hydrogen chloride, while the hydrogen chloride gas and heat of generation can be made full use of
Amount realizes the circulation running of whole device, energy saving, the configuration of the present invention is simple, easy to operate, energy conservation and environmental protection.
2. the present invention drives stirring rod to mix the concentrated sulfuric acid and dilute hydrochloric acid by setting stirring rod using the swing of swing rod
It closes liquid ceaselessly to stir, promotes the two reaction rate, keep reaction more abundant, improve the generating rate of hydrogen chloride gas.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention；
Fig. 2 is A-A cross-sectional view in Fig. 1；
Fig. 3 is enlarged drawing at B in Fig. 1；
In figure: cylinder 1, inlet tube 2, escape pipe 3, transverse slat 4, inlet 41, skewback 5, column casing 6, venthole 61, tower-shaped lid
7, gas vent 71, pull rod 8, ring gear 81, swing rod 9, cavity 91, liquid outlet 92, storage cavities 10, diversion rod 11, deflector hole 111,
It is tension spring 12, connecting rod 13, through-hole 14, insulating ring 15, helical pipe 16, air inlet pipe 17, sliding block 18, drawstring 19, reset spring 20, recessed
Slot 21, stirring rod 22, closed cavity 23, volute spring 24, leakage fluid dram 25, steel ring 26.
Specific embodiment
A kind of portable chlorination apparatus for forming hydrogen of the invention is carried out using Fig. 1-Fig. 3 as described below.
Such as Fig. 1-Fig. 3, a kind of portable chlorination apparatus for forming hydrogen of the present invention, including cylinder 1, inlet tube 2, outlet
Pipe 3, transverse slat 4, skewback 5, column casing 6, tower-shaped lid 7, pull rod 8 and swing rod 9；The transverse slat 4 is connected on 1 inner wall of cylinder and the cross
Plate 4 and cylinder are sealed to a storage cavities 10 between 1 bottom；1 sidewall bottom of cylinder is provided with leakage fluid dram 25；The drain
25 one end of mouth are connected to storage cavities 10；The column casing 6 is connected in 4 middle part of transverse slat, is provided with venthole 61 on 6 two sides side wall of column casing；
The skewback 5 is connected in 4 two sides of transverse slat and has gap between the skewback 5 and column casing 6, and 5 sidewall upper of skewback is equipped with oblique angle；Institute
It states 4 two sides of transverse slat and is provided with inlet 41；41 upper end of inlet is in the gap between skewback 5 and column casing 6；It is described tower-shaped
Lid 7 is located at 6 top of column casing and the tower-shaped lid 7 is slidably connected on 6 outer wall of column casing, and tower-shaped 7 two sides side wall of lid is equipped with exhaust
Hole 71, tower-shaped 7 outer wall bottom of lid are equipped with oblique angle, and the oblique angle on tower-shaped lid 7 matches with the oblique angle on skewback 5, so that tower-shaped lid 7
The gap between skewback 5 and tower-shaped lid 7 can be closed in stationary state, and a confined air is surrounded between tower-shaped lid 7 and column casing 6
Chamber 23；The pull rod 8 is connected in tower-shaped 7 top middle portion of lid, and 8 upper end of pull rod is equidistant to be equipped with multiple ring gears 81,8 top of pull rod and
Volute spring 24 is equipped between 1 top inner wall of cylinder, 8 lower end of pull rod is hinged with multiple diversion rods 11 by hinged block；It is described to lead
Flow post 11 is circumferentially uniformly distributed along 8 center of pull rod, and tension spring 12 is equipped between diversion rod 11 and tower-shaped lid 7, is provided on diversion rod 11 multiple
Deflector hole 111；Multiple connecting rods 13 are circumferentially evenly equipped with along 1 center of cylinder on the 1 top inner wall of cylinder；13 one end of connecting rod hinge
It connects on 1 inner wall of cylinder, 13 other end of connecting rod is hinged on 9 middle part of swing rod；Cavity 91 is equipped with inside the swing rod 9；The cavity
91 lower sections are equipped with multiple liquid outlets 92；Described 9 one end of swing rod is contacted with steel ring 26, and steel ring 26 can make circumferentially uniformly distributed swing rod 9
Synchronous hunting, one end on swing rod 9 close to pull rod 8 is provided with the gear teeth and the gear teeth and ring gear 81 cooperate；Two inlet tubes 2 about
Cylinder 1 is centrosymmetrically arranged, and inlet tube 2 is arranged in the cavity 91 on 1 top of cylinder and 2 one end of inlet tube connection swing rod 9；The cylinder
1 top middle portion of body is provided with through-hole 14；The escape pipe 3 is connected to through-hole 14.When work, a certain amount of water of injection in column casing 6 will
The concentrated sulfuric acid and dilute hydrochloric acid pour into inside cylinder 1 from the inlet tube 2 of 1 top two sides of cylinder respectively, and the concentrated sulfuric acid enters the sky in swing rod 9
Chamber 91 flows to lower section from liquid outlet 92, meanwhile, cavity 91 of the dilute hydrochloric acid through swing rod 9 flows to lower section from liquid outlet 92, in the concentrated sulfuric acid
Tentatively mixing during flowing to lower section with dilute hydrochloric acid by diversion rod 11 makes the two react, and on the one hand generates hydrogen chloride gas
On the other hand body and dilute sulfuric acid generate heat, hydrogen chloride gas enters escape pipe 3 by the through-hole 14 of 1 top middle portion of cylinder, by
The discharge of escape pipe 3 collects, and dilute sulfuric acid and the complete concentrated sulfuric acid of unreacted and dilute hydrochloric acid are via the deflector hole on diversion rod 11
111 flow direction lower sections again be sufficiently mixed reacting, and the heat for reacting generation heats cylinder 1, and the water in column casing 6 is heated
Evaporation generates vapor, and vapor expanded by heating jacks up the tower-shaped lid 7 of 6 top of column casing upwards, the pull rod 8 of tower-shaped 7 top of lid
As tower-shaped lid 7 moves upwards, the connected ring gear 81 in 8 upper end of pull rod drives swing rod 9 to be swung up, the Conical Projectile on 8 top of pull rod
Spring 24 is pressurized, and when tower-shaped lid 7 is by jack-up certain altitude, the inclined-plane of tower-shaped 7 lower end of lid and the inclined-plane on skewback 5 are detached from, sufficiently
The gap that the dilute sulfuric acid obtained after reaction enters between cylinder 1 and skewback 5 is stored via inlet 41 into storage cavities 10
Come, when tower-shaped lid 7 continues upper sliding, when the gas vent 71 on tower-shaped 7 side wall of lid is opposite with the venthole 61 on 6 side wall of column casing,
Gas in the closed cavity 23 that tower-shaped lid 7 and column casing 6 surround sprays so that air pressure reduces in closed cavity 23, and tower-shaped lid 7 exists
Slide downward is until the pull rod 8 on initial position, tower-shaped lid 7 is with moving down under the action of gravity and volute spring 24,
To drive swing rod 9 to lower swing, when the closed cavity 23 between tower-shaped lid 7 and column casing 6 again by it is closed when, closed cavity 23
Interior gas again can jack up tower-shaped lid 7, and tower-shaped lid 7, which is constantly jacked up and put down, can make 9 reciprocally swinging of swing rod, work as the concentrated sulfuric acid
The dilute sulfuric acid stored in storage cavities 10 is discharged from leakage fluid dram 25 after sufficiently having been reacted with dilute hydrochloric acid.
1 outer wall of cylinder is equipped with insulating ring 15；Helical pipe 16 is equipped in the insulating ring 15；The helical pipe 16
Lower end import is connected to 17 one end of air inlet pipe；17 other end of air inlet pipe passes through 1 side wall of cylinder, skewback 5 and 6 side wall of column casing and connects
6 inner space of through post cylinder.When work, the gas in closed cavity 23 that tower-shaped lid 7 is surrounded with column casing 6 is on the one hand by tower-shaped lid 7
It jacks up upwards, some gas is passed through in the helical pipe 16 in insulating ring 15 by air inlet pipe 17, is heated to insulating ring 15
To allow insulating ring 15 to heat cylinder 1, accelerates reacting for the concentrated sulfuric acid and dilute hydrochloric acid in cylinder 1, improve the life of hydrogen chloride
At rate.
Sliding block 18 is slidably connected in the through-hole 14 on 1 top of cylinder；Drawstring is equipped between the sliding block 18 and pull rod 8
19,18 top of sliding block is equipped with reset spring 20；Groove 21 is provided in the through-hole 14；The height of the groove 21 is greater than sliding block 18
Height.When work, the hydrogen chloride gas that the concentrated sulfuric acid and dilute hydrochloric acid reaction generate in cylinder 1 flows to the through-hole 14 on 1 top of cylinder,
Sliding block 18 in through-hole 14 is chlorinated hydrogen and jacks up until 18 lower end of sliding block enters in groove 21, and hydrogen chloride gas passes through groove
21, which flow to escape pipe 3, is collected, when rear slider 18 is discharged in gravity and reset spring 20 via escape pipe 3 in hydrogen chloride gas
It acts on lower slide downward to be again closed through-hole 14, forms a circulation, drawstring 19 pulls while sliding block 18 is jacked up
Pull rod 8, which moves up, can assist tower-shaped lid 7 to move up, to increase the number that tower-shaped lid 7 moves up, and then increase diversion rod
11 shake number improves the efficiency for generating hydrogen chloride so that the mixed solution of 11 top of diversion rod more fully mixes.
1 side wall of cylinder is equipped with multiple stirring rods 22；It is hinged on the side wall of cylinder 1 in the middle part of the stirring rod 22；
22 upper end of stirring rod is arc structure, and stirring rod 22 is located at 9 lower section of swing rod.When work, swing rod 9 is when swinging back and forth, position
It is squeezed in the arc end part of the stirring rod 22 of 9 lower section of swing rod by 9 end of swing rod and certain deformation occurs, stirring rod 22 can be put
Dynamic certain angle, when the arc end part of 9 end of swing rod and stirring rod 22 is detached from, stirring rod 22 returns to initial position again,
So that stirring rod 22 swings back and forth, 22 lower end of stirring rod can be stirred the mixed liquor of the concentrated sulfuric acid and dilute hydrochloric acid, be made
It is more fully mixed to obtain the two, reaction rate faster, improves the rate for generating hydrogen chloride gas.
The deflector hole 111 vertical diversion rod 11 arrangement and 111 rounded corner of the deflector hole.When work, the concentrated sulfuric acid and dilute
Hydrochloric acid on diversion rod 11 tentatively mixing react after, remaining solution flows to 1 lower part of cylinder, water conservancy diversion via deflector hole 111
The vertical deflector hole 111 in hole 111 arrangement can make have certain angle when solution flow direction lower section, so that mixing more behind solution flow direction lower section
Sufficiently, it is not easy to stop when 111 rounded corner of deflector hole flows through solution, and then solution is avoided to carry out the end of deflector hole 111
Local heating prevents diversion rod 11 to be deformed due to stress concentration to reduce 111 end stress of deflector hole concentration.
The cavity 91 of the swing rod 9 is taper, and the small end of cavity 91 is close to pull rod 8.It is empty when swing rod 9 is swung when work
The concentrated sulfuric acid and dilute hydrochloric acid in chamber 91 are thrown away via liquid outlet 92, and the centrifugal force being subject at the big end of cavity 91 is big, accumulation it is molten
Liquid is more, so that the solution that the liquid outlet 92 at 91 big end of cavity is thrown away is more, solution is thrown out of rear more fully mixed, accelerates dense sulphur
The reaction rate of acid and dilute hydrochloric acid, improves the generating rate of hydrogen chloride.
Specific workflow is as follows:
When work, a certain amount of water of injection in column casing 6, by the concentrated sulfuric acid and dilute hydrochloric acid respectively from 1 top two sides of cylinder into
Liquid pipe 2 is poured into inside cylinder 1, and the concentrated sulfuric acid enters the cavity 91 in swing rod 9 and flows to lower section from liquid outlet 92, meanwhile, dilute hydrochloric acid warp
The cavity 91 of swing rod 9 flows to lower section from liquid outlet 92, passes through diversion rod 11 during below the concentrated sulfuric acid and dilute hydrochloric acid flow direction
Preliminary mixing makes the two react, and on the one hand generates hydrogen chloride gas and dilute sulfuric acid, on the other hand generates heat, hydrogen chloride gas
Body flows to the through-hole 14 on 1 top of cylinder, the sliding block 18 in through-hole 14 be chlorinated hydrogen jack up until 18 lower end of sliding block enter it is recessed
In slot 21, hydrogen chloride gas flows to escape pipe 3 by groove 21 and is collected, after hydrogen chloride gas is discharged via escape pipe 3
Through-hole 14 is closed by slide downward under the action of gravity and reset spring 20 of sliding block 18 again, forms a circulation, sliding
Drawstring 19 pulls pull rod 8 to move up tower-shaped lid 7 can be assisted to move up while block 18 is jacked up, thus increase tower-shaped lid 7 to
The number of upper movement, and then increase the shake number of diversion rod 11, so that the mixed solution of 11 top of diversion rod is more fully
Mixing improves the efficiency for generating hydrogen chloride；
Dilute sulfuric acid and the complete concentrated sulfuric acid of unreacted and dilute hydrochloric acid flow to 1 lower part of cylinder, deflector hole via deflector hole 111
The 111 vertical arrangements of deflector hole 111 can make have certain angle when solution flow direction lower section, more fill so that mixing behind solution flow direction lower section
Point, faster, 111 rounded corner of deflector hole is not easy to stop reaction rate when solution is flowed through, and then avoids solution to deflector hole 111
End carry out local heating, thus reduce 111 end stress of deflector hole concentration, prevent diversion rod 11 due to stress concentrate generate
Deformation, the heat for reacting generation heat cylinder 1, and the water in column casing 6 is generated vapor by thermal evaporation, and a part of vapor is logical
It crosses in the helical pipe 16 that air inlet pipe 17 is passed through in insulating ring 15, insulating ring 15 is heated to allow insulating ring 15 to cylinder
1 heating accelerates reacting for the concentrated sulfuric acid and dilute hydrochloric acid in cylinder 1, improves the generating rate of hydrogen chloride, another part vapor is heated
Expansion jacks up the tower-shaped lid 7 of 6 top of column casing upwards, and the pull rod 8 above tower-shaped lid 7 is moved upwards with tower-shaped lid 7, pull rod 8
The connected ring gear 81 in upper end drives swing rod 9 to be swung up, and the volute spring 24 on 8 top of pull rod is pressurized, when tower-shaped lid 7 is jacked up one
When determining height, the inclined-plane of tower-shaped 7 lower end of lid and the inclined-plane on skewback 5 are detached from, and the dilute sulfuric acid sufficiently obtained after reaction enters cylinder 1
Gap between skewback 5 is stored via inlet 41 into storage cavities 10, when tower-shaped lid 7 continues upper sliding, when tower-shaped
When gas vent 71 on 7 side wall of lid is opposite with the venthole 61 on 6 side wall of column casing, closed cavity that tower-shaped lid 7 and column casing 6 surround
Gas in 23 sprays so that air pressure reduces in closed cavity 23, tower-shaped lid 7 under the action of gravity and volute spring 24 to
Lower slider is until the pull rod 8 on initial position, tower-shaped lid 7 is with moving down, to drive swing rod 9 to lower swing, when tower-shaped
Closed cavity 23 between lid 7 and column casing 6 again by it is closed when, the gas in closed cavity 23 again can jack up tower-shaped lid 7, tower
Shape lid 7, which is constantly jacked up and put down, can make 9 reciprocally swinging of swing rod, the concentrated sulfuric acid and dilute salt when swing rod 9 is swung, in cavity 91
Acid is thrown away via liquid outlet 92, and the centrifugal force being subject at the big end of cavity 91 is big, and the solution of accumulation is more, so that at 91 big end of cavity
The solution that throws away of liquid outlet 92 it is more, solution is thrown out of rear more fully mixed, accelerate the reaction rate of the concentrated sulfuric acid and dilute hydrochloric acid,
Improve the generating rate of hydrogen chloride；
Meanwhile the arc end part of the stirring rod 22 positioned at 9 lower section of swing rod is squeezed by 9 end of swing rod and certain change occurs
Shape, stirring rod 22 can swing certain angle, and when the arc end part of 9 end of swing rod and stirring rod 22 is detached from, stirring rod 22 is again heavy
Initial position newly is returned to, so that stirring rod 22 swings back and forth, 22 lower end of stirring rod can be mixed the concentrated sulfuric acid and dilute hydrochloric acid
It closes liquid to be stirred, so that the two is more fully mixed, reaction rate faster, improves the rate for generating hydrogen chloride gas, when dense sulphur
The dilute sulfuric acid stored in storage cavities 10 is discharged from leakage fluid dram 25 after sufficiently having reacted with dilute hydrochloric acid for acid.
More than, it is illustrated about one embodiment of the present invention, but the present invention is not limited to the above embodiments, not
Various changes are able to carry out in the range of disengaging present subject matter.
Claims (6)
1. a kind of portable chlorination apparatus for forming hydrogen, it is characterised in that: including cylinder (1), inlet tube (2), escape pipe (3), cross
Plate (4), skewback (5), column casing (6), tower-shaped lid (7), pull rod (8) and swing rod (9)；The transverse slat (4) is connected in cylinder (1) inner wall
A storage cavities (10) is sealed between the upper and described transverse slat (4) and cylinder (1) bottom；Cylinder (1) sidewall bottom is opened
There are leakage fluid dram (25)；Described leakage fluid dram (25) one end is connected to storage cavities (10)；The column casing (6) is connected in the middle part of transverse slat (4),
Venthole (61) are provided on the side wall of column casing (6) two sides；The skewback (5) is connected in transverse slat (4) two sides and the skewback (5) and column
There is gap between cylinder (6), skewback (5) sidewall upper is equipped with oblique angle；Transverse slat (4) two sides are provided with inlet (41)；It is described into
Liquid mouth (41) upper end is located in the gap between skewback (5) and column casing (6)；The tower-shaped lid (7) is located above column casing (6) and institute
It states tower-shaped lid (7) to be slidably connected on column casing (6) outer wall, tower-shaped lid (7) two sides side wall is equipped with gas vent (71), tower-shaped lid
(7) outer wall bottom is equipped with oblique angle, and the oblique angle on tower-shaped lid (7) matches with the oblique angle on skewback (5), so that tower-shaped lid (7) exists
The gap between skewback (5) and tower-shaped lid (7) can be closed when stationary state, surround one between tower-shaped lid (7) and column casing (6)
Closed cavity (23)；The pull rod (8) is connected in tower-shaped lid (7) top middle portion, and pull rod (8) upper end is equidistant to be equipped with multiple ring gears
(81), volute spring (24) are equipped between pull rod (8) top and cylinder (1) top inner wall, pull rod (8) lower end is cut with scissors by hinged block
It is connected to multiple diversion rods (11)；The diversion rod (11) is circumferentially uniformly distributed along pull rod (8) center, diversion rod (11) and tower-shaped lid (7)
Between be equipped with tension spring (12), be provided with multiple deflector holes (111) on diversion rod (11)；Along cylinder on the inner wall of cylinder (1) top
(1) center is circumferentially evenly equipped with multiple connecting rods (13)；Described connecting rod (13) one end is hinged on cylinder (1) inner wall, and connecting rod (13) is another
One end is hinged in the middle part of swing rod (9)；Cavity (91) are equipped with inside the swing rod (9)；Be equipped with below the cavity (91) it is multiple go out
Liquid mouth (92)；It is contacted with steel ring (26) described swing rod (9) one end；The steel ring (26) can make circumferentially uniformly distributed swing rod (9) same
Step is swung；One end on swing rod (9) close to pull rod (8) is provided with the gear teeth and the gear teeth and ring gear (81) cooperate；Two inlet tubes
(2) it is centrosymmetrically arranged about cylinder (1), inlet tube (2) is arranged in cylinder (1) top and inlet tube (2) one end connection swing rod
(9) cavity (91)；Cylinder (1) top middle portion is provided with through-hole (14)；The escape pipe (3) is connected to through-hole (14).
2. a kind of portable chlorination apparatus for forming hydrogen according to claim 1, it is characterised in that: cylinder (1) outer wall
Equipped with insulating ring (15)；Helical pipe (16) are equipped in the insulating ring (15)；Helical pipe (16) the lower end import with into
The connection of tracheae (17) one end；Air inlet pipe (17) other end passes through cylinder (1) side wall, skewback (5) is connected to column casing (6) side wall
Column casing (6) inner space.
3. a kind of portable chlorination apparatus for forming hydrogen according to claim 1, it is characterised in that: cylinder (1) top
Through-hole (14) in slidably connect sliding block (18)；Drawstring (19) are equipped between the sliding block (18) and pull rod (8), sliding block (18)
Top is equipped with reset spring (20)；It is intermediate in the through-hole (14) to be provided with groove (21)；The height of the groove (21), which is greater than, to be slided
The height of block (18).
4. a kind of portable chlorination apparatus for forming hydrogen according to claim 1, it is characterised in that: cylinder (1) side wall
It is equipped with multiple stirring rods (22)；It is hinged on the side wall of cylinder (1) in the middle part of the stirring rod (22)；On the stirring rod (22)
End is arc structure, and stirring rod (22) is located at below swing rod (9).
5. a kind of portable chlorination apparatus for forming hydrogen according to claim 1, it is characterised in that: the deflector hole (111)
Vertical diversion rod (11) arrangement and the deflector hole (111) rounded corner.
6. a kind of portable chlorination apparatus for forming hydrogen according to claim 1, it is characterised in that: the sky of the swing rod (9)
Chamber (91) is taper, and the small end of cavity (91) is close to pull rod (8).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811527962.7A CN109626328B (en) | 2018-12-13 | 2018-12-13 | Portable hydrogen chloride generating device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811527962.7A CN109626328B (en) | 2018-12-13 | 2018-12-13 | Portable hydrogen chloride generating device |
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| CN109626328A true CN109626328A (en) | 2019-04-16 |
| CN109626328B CN109626328B (en) | 2024-02-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811527962.7A Active CN109626328B (en) | 2018-12-13 | 2018-12-13 | Portable hydrogen chloride generating device |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110975375A (en) * | 2019-12-31 | 2020-04-10 | 重庆华彬伟玻璃有限公司 | Scissor water recovery device |
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| CN208038038U (en) * | 2018-01-26 | 2018-11-02 | 天津中津药业股份有限公司 | A kind of safe generation tank efficiently preparing hydrogen chloride gas |
| CN208218404U (en) * | 2018-05-15 | 2018-12-11 | 杭州东日节能技术有限公司 | A kind of continuity method hydrochloric acid full stripping produces the device of hydrogen chloride gas |
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| US2444256A (en) * | 1946-07-19 | 1948-06-29 | Shell Dev | Method for manufacturing hydrogen chloride |
| CN2161602Y (en) * | 1993-06-26 | 1994-04-13 | 苏州硫酸厂 | Hydrogen chloride generator by sulphuric acid extracting method |
| CN104338419A (en) * | 2014-11-11 | 2015-02-11 | 南通星球石墨设备有限公司 | Combined hydrogen chloride absorption tower |
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| CN110975375A (en) * | 2019-12-31 | 2020-04-10 | 重庆华彬伟玻璃有限公司 | Scissor water recovery device |
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| CN109626328B (en) | 2024-02-06 |
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