CN109621555A - Plastics chimney filter tube body and preparation method thereof - Google Patents
Plastics chimney filter tube body and preparation method thereof Download PDFInfo
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- CN109621555A CN109621555A CN201910038422.0A CN201910038422A CN109621555A CN 109621555 A CN109621555 A CN 109621555A CN 201910038422 A CN201910038422 A CN 201910038422A CN 109621555 A CN109621555 A CN 109621555A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1692—Other shaped material, e.g. perforated or porous sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Filtering Materials (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparation methods of plastics chimney filter tube body, and 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, maleic anhydride grafting, isophorone diisocyanate, ethylene vinyl acetate, benzoisothiazolinone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene are prepared into plastics composite;Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, is added into injection molding machine, prepares tube body crude product according to 140 degree of meltings, 240 degree of molding techniques;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying, as tube body.Plastics chimney filter disclosed by the invention, which belongs to, to be cleaned again using environmentally friendly machine, and traditional filter bag equipment can be directly replaced, and be not necessary to modify existing dust-collecting equipment, while service life of equipment is long, and service life can be greater than traditional 10 times or more.
Description
The present invention is a kind of entitled plastics chimney filter and the plastics composite for the plastics chimney filter, the applying date are
On May 24th, 2017, application No. is the divisional applications of 201710412275X patent application, belong to product preparation method part.
Technical field
The invention belongs to field of environment protection equipment, and in particular to a kind of preparation method of plastics chimney filter tube body.
Background technique
With the development of modern industry, influence caused by health of the dust to environment and the mankind is got worse, effectively
Dust pollution is administered, Environmental protection pay attention to day by day and global warming phenomenon are serious in recent years, in order to advocate carbon reduction,
Environmental protection industry flourishes, and purifies the living environment of the mankind, it has also become proprietary common recognition.Existing chimney filter is only flat, filter
Pipe discounting end is divided into pointed and rectangular, and existing plastics chimney filter pulse dust cleaning has dead angle, causes ash-removal effect difference and filter area small;
Precipitron operation pressure is high;Conventional filter bag can not be replaced.
Summary of the invention
The object of the present invention is to provide a kind of plastics chimney filters, are used for deduster dedusting, are good for the environment development.
To achieve the above object of the invention, the technical solution adopted by the present invention is that: a kind of plastics chimney filter, by 3- aminopropyltriethoxy
Dimethoxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add two isocyanide of isophorone
Acid esters stirs 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone, 140 degree are stirred
It mixes 2 hours, is cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl group
Phosphordithiic acid pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;So
Afterwards by mixture at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture after heat treatment is squeezed out
Machine is granulated to obtain plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, according to 140 degree
Melting, 240 degree of molding techniques prepare tube body, reinforcing ring and reinforcing rod integrated component crude product;Then by tube body, reinforcing ring with plus
Strong bar integrated component crude product, which is put into boiling water, to be handled 2 hours, is taken out, heated-air drying, as tube body, reinforcing ring and reinforcing rod one
Component;Tube body, reinforcing ring and reinforcing rod integrated component and base combination are obtained into plastics chimney filter.
The invention also discloses a kind of preparation methods of plastics chimney filter, comprising the following steps: by 3- aminopropyltriethoxy diformazan
Oxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add isophorone diisocyanate
Ester stirs 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone, 140 degree of stirrings 2
Hour, it is cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl disulfides
It is mixed for phosphopyridine, triethylene tetramine, end hydroxy butadiene with batch mixer, forms finely dispersed mixture;Then will
Mixture is at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture extruder after heat treatment is made
Grain obtains plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, melted according to 140 degree,
240 degree of molding techniques prepare tube body, reinforcing ring and reinforcing rod integrated component crude product;Then by tube body, reinforcing ring and reinforcing rod
Integrated component crude product is put into boiling water and handles 2 hours, takes out, heated-air drying, as tube body, reinforcing ring and reinforcing rod one portion
Part;Tube body, reinforcing ring and reinforcing rod integrated component and base combination are obtained into plastics chimney filter.
In the present invention, chimney filter is hatch frame, and whole similar tubulose, bottom is mounted on shell, and top opening is used for arteries and veins
Rush in wind, tube wall filtration;The reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;The tube body
Cross section is gear type structure;The tooth top and tooth socket of the gear type structure are all arcuate structure;The reinforcing ring is located at tube body
One end;Circular platform type bulge-structure is equipped among the pedestal;The reinforcing rod is 4~8;The reinforcing rod and reinforcing ring connect
Contact is evenly distributed on reinforcing ring;The reinforcing rod is flat structure;The contact point of the reinforcing rod and tube body is located at gear
At the tooth socket of type structure;Each reinforcement pole length is consistent;The angle of the arcuate structure is 30~150 degree;The gear
The height of the tooth of type structure is reinforce pole length 28~34%.
The invention also discloses a kind of plastics chimney filter feedstock compositions, by 3- aminopropyltriethoxy dimethoxysilane, gather
Ethylene oxide castor oil and maleic anhydride are grafted on 90 degree and stir 1 hour, add isophorone diisocyanate, stir at 110 degree
It mixes 80 minutes, adds ethylene vinyl acetate and benzoisothiazolinone, 140 degree are stirred 2 hours, are cooled to
Room temperature obtains mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine,
Triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture 180
Under degree, 2MPa, closed heat treatment 2 hours;Then it under 235 degree, is granulated the mixture extruder after heat treatment to obtain plastics
Composition;The plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin.
The invention also discloses a kind of plastics chimney filter plastics composite, the plastics composite is prepared as, by 3- ammonia
Hydroxypropyl methyl dimethoxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add different Fo Er
Ketone diisocyanate stirs 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone,
140 degree are stirred 2 hours, are cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane,
Dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixing
Object;Then by mixture at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, by the mixing after heat treatment
Object extruder is granulated to obtain plastics composite.
The invention also discloses a kind of preparation methods of plastics chimney filter plastics composite, include the following steps, by 3- ammonia
Hydroxypropyl methyl dimethoxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add different Fo Er
Ketone diisocyanate stirs 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone,
140 degree are stirred 2 hours, are cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane,
Dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixing
Object;Then by mixture at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, by the mixing after heat treatment
Object extruder is granulated to obtain plastics composite.
The invention also discloses a kind of plastics chimney filter tube body, the tube body is prepared as, by 3- aminopropyltriethoxy dimethoxy
Base silane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add isophorone diisocyanate,
It is stirred 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone, 140 degree of stirrings 2 are small
When, it is cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithio
Phosphopyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then it will mix
Object is closed at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated
Obtain plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, melted according to 140 degree,
240 degree of molding techniques prepare tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying,
As tube body.
The invention also discloses a kind of preparation methods of plastics chimney filter tube body, include the following steps, by 3- aminopropyltriethoxy
Dimethoxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, add two isocyanide of isophorone
Acid esters stirs 80 minutes at 110 degree, adds ethylene vinyl acetate and benzoisothiazolinone, 140 degree are stirred
It mixes 2 hours, is cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl group
Phosphordithiic acid pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;So
Afterwards by mixture at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture after heat treatment is squeezed out
Machine is granulated to obtain plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, according to 140 degree
Melting, 240 degree of molding techniques prepare tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, hot wind
Drying, as tube body.
In the present invention, the 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, maleic anhydride are grafted, are different
Isophorone diisocyanate, ethylene vinyl acetate, benzoisothiazolinone, polytetrafluoroethylparticle particle, methyl three
Methoxy silane, dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene mass ratio be 22: 11: 12:
42:24:14:28:32:11:5:21;The mass ratio of the plastics composite and uramit, paraffin is 100: 15: 7.
The present invention cooperates using so that gap is more uniform for paraffin using uramit as major porogen, especially logical
The heating of two steps is crossed, sky is avoided and is prematurely formed, the uniformity in the hole also fully ensured that, this does not see in the prior art, especially
It is follow-up hydrothermal processing, this is that the present invention is pioneering, substantially avoids the influence of impurity in hole, and several combinations produce obtained from
Product filter effect is excellent, and combines plastics composite, effectively can generate suction with particulate pollutant, even organic pollutant
Attached effect.
The present invention designs discounting formula structure in addition to creative in structure, improves the mechanical property and filtering of product
Effect mainly realizes fine efficient filtering and mechanical property, service life by preparing raw material and preparation process
Greatly improve.Existing plastics chimney filter is all polypropylene or doping polypropylene injection molding preparation, because polypropylene is easy to process, phase
To cheap, but there is a problem of that apparent poor mechanical property, poor filtration effect, service life are short, the present invention reopens thinking, asks
Teach materialogy expert, design it is new prepare raw material and technique, although upper complicated compared with existing product in cost and preparation,
It is the filter effect with long service life and high-precision, positive and negative calculating is handled for the enterprise for using chimney filter
Same gas, cost of consumption are the 32% of existing product, can be calculated, and in simple terms, product of the present invention price is existing
3 times of product or so, but service life of the present invention is at least 10 times of existing product, it is easy to it calculates, after practical application, the present invention
It is still low cost.
Chimney filter processing gas needs to have excellent wear-resisting property, strainability, heat resistance, it is also necessary to excellent power
Learn performance, flame retardant property;Existing product generally all addition inorganic material are to improve some performances, but organic-inorganic product is natural
Heterogeneity cause to be modified the defect that not can avoid still between two-phase anyway, the short time is not seen, but in high temperature height
Under wet gas constantly washes away, defect point can constantly expand, and lead to damage of product, and the invention avoids this problems, this is also this
Long one of the reason of invention life of product, but by reasonable organic matter compatibility, obtained product still mechanical property, heat-resisting
Performance, wear-resisting property are excellent, do not reduce quality.
In the present invention, for synthesis mixture as high-strength, high-anti-friction material of main part, polytetrafluoroethylene (PTFE) is mechanical strong to improve
Degree and processing performance simultaneously reduce coefficient of friction;The self-lubricating of organo-silicon compound and organosulfur compound to improve product
Property, while 3- aminopropyltriethoxy dimethoxysilane can also improve the affinity between product composition, polyoxyethylene caster
Oil increases activity, improves the reactivity between product;The present invention is not to reach technical effect by a kind of or two or three kind of substance,
But gas chromatography is organically subjected to compatibility, synergistic effect is played after reaction, can just obtain excellent technical effect, such as
The cooperation of silicon and sulphur not only improves product heat resistance and also gives good flame retardant property, such as based on the cooperation of acid anhydrides, ester, ketone
Material provides excellent mechanical support;Etc..
Plastics composite of the invention can be in wider hardness range elasticity with higher and intensity, excellent wear-resisting
Property, oil resistivity, fatigue durability and anti-vibration resistance, antiseptic property is good after end hydroxy butadiene is reacted with Emulsifier EL-60;
Using resin combination as major ingredient, reactive compound is selected to adjust reactivity and stability, by organosilicon, Organic fluoride characteristic,
Enhance the wear resistence of itself, degrees of fusion, mobility between small molecule guarantee each component, so that performance reaches optimal state;
In addition to good adhesive property, also there is enough intensity and good wear-resisting property between each resin.Generally, it is added
The intensity of epoxyn can be improved in certain inorganic filler, and can also improve other property of adhesive
Can, it is corrosion-resistant, wear-resisting, thermally conductive after ethylene vinyl acetate is reacted with triethylene tetramine, end hydroxy butadiene
Property it is good, thermal expansion coefficient is low, can play skeleton and wear-resistant effect, Emulsifier EL-60, maleic anhydride grafting can be with
Reduce coefficient of friction, product can be made to become smooth, coefficient of friction becomes smaller.
Due to the above technical solutions, the present invention has the following advantages over the prior art:
Strengthening part is creatively arranged in the present invention in chimney filter, avoids under the intensity as caused by overall gear structure
Drop, the problem of stability difference, and by limiting strengthening part various parameters, reach not only stable chimney filter, but also do not influence gas flowing
Effect;Tooth top structure is equipped among chimney filter pedestal for the first time, by the inside tooth top in chimney filter bottom, when air pulse undershoot to tooth top
When structure, it is effectively formed rebound, plays the role of distributing air-flow, increases pulse lavage effect;Sintering of plastics chimney filter is not necessary to simultaneously
There is inner support frame, it is not easy to wear, cost can be reduced, mitigates chimney filter weight while promoting filter effect, overcomes existing skill
The problem that art chimney filter can aggravate;Discounting area increases, and increases filter area;In addition equipment reduces occupied area, can also reduce and make
Valence cost;Height by changing section number of teeth mesh, gear teeth tips part adjusts filtration contact area, using etc. static pressure at
Type can not only guarantee that the deformation comparison of product is small, can also require according to product design, change the cross section parameters of chimney filter,
To increase the filtration contact area of chimney filter to a certain extent, to improve the filter effect or save the cost of chimney filter.It is designing
In the case where identical filter area, identical filtering surface can be reached by reducing the dosage of chimney filter or reducing the caliber of chimney filter
Product, and space occupied by the screen pipe of more slim pipe diameter can be fewer, can thus reduce the volume of chimney filter, and saving steel is used
Amount, to generally save the manufacturing cost of filter plant;Plastics chimney filter structure composition is reasonable, and disassembly is easy, and is applicable in a variety of mistakes
Filter occasion;Material forms for sintering of plastics, and intensity is big, and sintering precision is high and wearability is strong;Filter type is absorption, surface filtration
It is combined with in-depth filtration, work principle of filter is mainly inertial collision, diffusion and retention, relative to cyclone dust removal, stratum granulosum mistake
Filtering dust collecting, electrostatic precipitation, wet sprinkling dedusting etc., not only high dust collection efficiency, filtering accuracy are high, obvious heat of smoke utilization rate is high, and
And use scope is wide, high temperature resistant, corrosion-resistant.
Plastics chimney filter disclosed by the invention, which belongs to, can clean again using environmentally friendly machine, and cleaning effect is best;It can be direct
Traditional filter bag equipment is replaced, is not necessary to modify existing dust-collecting equipment, while service life of equipment is long, service life can be greater than tradition
It 10 times of type or more, not only summarizes, also can determine from accelerating damage to test, the wear life of product of the present invention is existing from actual motion
There are 12.5 times of product;Reduce operation operating cost, the dust removal process suitable for high temperature, acid-base property coal-fired flue-gas.
Specific embodiment
The present invention will be further described below with reference to examples:
Embodiment one
It is small that 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree of stirrings 1
When, add isophorone diisocyanate, 110 degree stir 80 minutes, add ethylene vinyl acetate with
Benzoisothiazolinone, 140 degree are stirred 2 hours, are cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, first
Base trimethoxy silane, dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, shape
At finely dispersed mixture;Then by mixture at 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree,
Mixture extruder after heat treatment is granulated to obtain plastics composite, i.e. plastics chimney filter plastics composite;
Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, is added into note
In molding machine, tube body, reinforcing ring and reinforcing rod integrated component crude product are prepared according to 140 degree of meltings, 240 degree of molding techniques;Then
Tube body, reinforcing ring and reinforcing rod integrated component crude product are put into boiling water and handled 2 hours, is taken out, heated-air drying, as tube body,
Reinforcing ring and reinforcing rod integrated component;Tube body, reinforcing ring and reinforcing rod integrated component and base combination are obtained into plastics chimney filter.
Above-mentioned 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, maleic anhydride grafting, isophorone two are different
Cyanate, ethylene vinyl acetate, benzoisothiazolinone, polytetrafluoroethylparticle particle, methyl trimethoxy oxygroup silicon
Alkane, dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxy butadiene mass ratio be 22: 11: 12: 42: 24: 14:
28:32:11:5:21;The mass ratio of plastics composite and uramit, paraffin is 100: 15: 7;To above-mentioned tubular body (without reinforcement
Bar and reinforcing ring, for testing) the indexs such as bending strength, tensile strength and wear rate detected, tensile strength is greater than 250
Megapascal, bending strength be greater than 380 megapascal, less than 0.007%, 10,000 time wet-milling loss rate of 5000 dry grinding loss rates less than 0.005%,
Abrasion index is less than 18 (GB3960-83);Toughness of products is strong, wear-resistant, and coefficient of friction is small, reduces noise;Oxygen index (OI) is 51;
10% sodium hydroxide solution impregnates 30 minutes surfaces without influence;Regular hydrochloric acid impregnates 15 minutes surfaces without influence.
Embodiment two
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body
Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce
Bar is 8;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length
3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure
Angle be 150 degree;The height of the tooth of gear type structure is reinforce pole length 28%;Above structure is all conventional geometry knot
Structure.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering
Efficiency is greater than 2.2 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product
On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention: also can determine from accelerating damage to test, the wear life of product of the present invention is existing
There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours
It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤
1.2%, ring stiffness >=21KN/m2。
Embodiment three
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body
Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce
Bar is 4;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length
3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure
Angle be 30 degree;The height of the tooth of gear type structure is reinforce pole length 34%.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering
Efficiency is greater than 2.3 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product
On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention: also can determine from accelerating damage to test, the wear life of product of the present invention is existing
There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours
It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤
1.2%, ring stiffness >=21KN/m2。
Example IV
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body
Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce
Bar is 6;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length
3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure
Angle be 100 degree;The height of the tooth of gear type structure is reinforce pole length 30%;Circular platform type protrusion knot is equipped among pedestal
Structure.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering
Efficiency is greater than 2.5 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product
On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention: also can determine from accelerating damage to test, the wear life of product of the present invention is existing
There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours
It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤
1.2%, ring stiffness >=21KN/m2。
Claims (4)
1. a kind of plastics chimney filter tube body, it is characterised in that: the tube body is prepared as, by 3- aminopropyltriethoxy dimethoxy silicon
Alkane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, isophorone diisocyanate are added, 110
Degree stirring 80 minutes adds ethylene vinyl acetate and benzoisothiazolinone, and 140 degree are stirred 2 hours, cold
But mixture is obtained to room temperature;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid
Pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture
At 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated to obtain
Plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, according to 140 degree of meltings, 240 degree
Molding technique prepares tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying is as managed
Body.
2. plastics chimney filter tube body according to claim 1, it is characterised in that: the 3- aminopropyltriethoxy dimethoxysilane,
Emulsifier EL-60, maleic anhydride grafting, isophorone diisocyanate, ethylene vinyl acetate, benzisoxa
Thiazolinone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, triethylene tetramine, end hydroxyl
The mass ratio of base polybutadiene is 22: 11: 12: 42: 24: 14: 28: 32: 11: 5: 21;The plastics composite and uramit,
The mass ratio of paraffin is 100: 15: 7.
3. the preparation method of plastics chimney filter tube body, which is characterized in that include the following steps, by 3- aminopropyltriethoxy dimethoxy silicon
Alkane, Emulsifier EL-60 and maleic anhydride are grafted on 90 degree and stir 1 hour, isophorone diisocyanate are added, 110
Degree stirring 80 minutes adds ethylene vinyl acetate and benzoisothiazolinone, and 140 degree are stirred 2 hours, cold
But mixture is obtained to room temperature;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid
Pyridine, triethylene tetramine, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture
At 180 degree, 2MPa, closed heat treatment 2 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated to obtain
Plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, according to 140 degree of meltings, 240 degree
Molding technique prepares tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying is as managed
Body.
4. the preparation method of plastics chimney filter tube body according to claim 3, it is characterised in that: the 3- aminopropyltriethoxy diformazan
Oxysilane, Emulsifier EL-60, maleic anhydride grafting, isophorone diisocyanate, vinyl-vinyl-acetic ester copolymerization
Object, benzoisothiazolinone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, triethylene
Tetramine, end hydroxy butadiene mass ratio be 22: 11: 12: 42: 24: 14: 28: 32: 11: 5: 21;The plastics composite with
Uramit, paraffin mass ratio be 100: 15: 7.
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CN109603311A (en) | 2019-04-12 |
CN107233766B (en) | 2019-07-09 |
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