CN109613196A - Based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system - Google Patents

Based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system Download PDF

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Publication number
CN109613196A
CN109613196A CN201811571919.0A CN201811571919A CN109613196A CN 109613196 A CN109613196 A CN 109613196A CN 201811571919 A CN201811571919 A CN 201811571919A CN 109613196 A CN109613196 A CN 109613196A
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fish
water quality
sensor
electrocardiosignal
line monitoring
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CN109613196B (en
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任宗明
乔琳琳
任佰川
任佰祥
刘跃丹
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Ji'nan Instrument Co Ltd
Shandong Normal University
South China Institute of Environmental Science of Ministry of Ecology and Environment
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Ji'nan Instrument Co Ltd
Shandong Normal University
South China Institute of Environmental Science of Ministry of Ecology and Environment
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Application filed by Ji'nan Instrument Co Ltd, Shandong Normal University, South China Institute of Environmental Science of Ministry of Ecology and Environment filed Critical Ji'nan Instrument Co Ltd
Priority to CN201811571919.0A priority Critical patent/CN109613196B/en
Priority to CA3053603A priority patent/CA3053603C/en
Priority to PCT/CN2019/072599 priority patent/WO2020010836A1/en
Priority to EP19756312.5A priority patent/EP3646783A4/en
Publication of CN109613196A publication Critical patent/CN109613196A/en
Priority to US16/555,883 priority patent/US10571448B2/en
Priority to ZA2019/05816A priority patent/ZA201905816B/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/186Water using one or more living organisms, e.g. a fish
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)

Abstract

The present disclosure discloses one kind to be based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system, comprising: obtains the fish body electrocardiosignal of several particular point in time after fish body electrocardiosignal and fish contact measured water quality before fish contact measured water quality;Each fish body electrocardiosignal QRS interphase duration of acquisition and the electrocardiographicdata data of QT interphase duration are extracted respectively;Analyze fish contact measured water quality before and fish contact measured water quality after several particular point in time electrocardiographicdata data variation, if variation is more than preset threshold, pollutant kind is judged, and obtain the water quality parameter of water quality parameter sensor acquisition, otherwise, water body to be measured is qualified;Specific pollutant kind and contaminant capacity range are further determined that according to the water quality parameter that water quality parameter sensor acquires.

Description

Based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system
Technical field
The disclosure belongs to the technical field of water quality assessment, is related to one kind and is supervised online based on the cardiac electrical water body burst pollution of fish Survey method, apparatus and system.
Background technique
With the ability enhancing of mankind reforming society and the continuous development of industrialization, chemurgy, water body environment pollution is cured Add seriously, environmental problem is severe, and pop-up threat takes place frequently.Water body pop-up threat is that water resource water quality deteriorates in a short time The water pollution phenomenon that rate increases suddenly due to the discharge approach that it is not fixed, and happens suddenly, is violent, often in a short time A large amount of noxious pollutants are discharged, therefore threat will cause to human health and life security, ecology is restrict and is held with economic Supervention exhibition.Therefore realization is highly important with assessment to the on-line monitoring of water body pop-up threat.
Currently, mainly having test paper method, portable instrument analytic approach and laboratory system point for water body pop-up threat Analysis method etc..But test paper method error is larger, is easy by reviewer's subjective impact and is easy to be influenced by environmental factor variation; Portable instrument specificity is strong, but its price is higher.The method for wherein detecting Heavy Metals In Environment object has a volt-ampere electrode Method, when volt-ampere determination of electrode nature difference big parameter, will frequently replace electrode, and testing result is vulnerable to sample radix effect Influence.Portable gas chromatograph-mass spectrometer is organic pollutant in detection environment, it by the high resolution of gas-chromatography and Mass detector can show that stronger qualitative ability is combined to different structure molecule.
However, these methods are all only assessed after pop-up threat occurs, water body burst pollution can not achieve The on-line monitoring of accident cannot in time promptly assess water pollution burst accident, be unable to the reduction water body of maximum possible Burst pollution loses to caused by economic, society and natural environment.Therefore, it realizes and water body pop-up threat is monitored on-line It is particularly significant with assessing, to carry out early warning and assessment to water body pop-up threat in time, reduce as far as possible it is economical with from The loss of right environment.
Summary of the invention
For the deficiencies in the prior art, present disclose provides one kind to be existed based on the cardiac electrical water body burst pollution of fish Line monitoring method, apparatus and system, the fish based on the real-time continuous online electrocardiogram acquisition under holding fish normally travelling state Electrocardio and various water quality parameter sensors acquisition water quality parameter, online comprehensive analysis water quality situation, to water body burst pollution into Row on-line monitoring and assessment, the disclosure have universality, can be widely applied to water body pop-up threat on-line monitoring and comment Estimate.
One or more other embodiments of the present disclosure provide a kind of based on fish cardiac electrical water body burst pollution on-line monitoring side Method.
One kind being based on the cardiac electrical water body burst pollution on-line monitoring method of fish, this method comprises:
Obtain before fish contact measured water quality several specific times after fish body electrocardiosignal and fish contact measured water quality The fish body electrocardiosignal of point;
Each fish body electrocardiosignal QRS interphase duration of acquisition and the electrocardiographicdata data of QT interphase duration are extracted respectively;
Analyze fish contact measured water quality before and fish contact measured water quality after several particular point in time electrocardiographicdata data Variation, if variation be more than preset threshold, judge pollutant kind, and obtain water quality parameter sensor acquisition water quality ginseng Number, otherwise, water body to be measured are qualified;
Specific pollutant kind and contaminant capacity range are further determined that according to the water quality parameter that water quality parameter sensor acquires.
Further, in the method, obtain respectively before several fish contact measured water quality fish body electrocardiosignal and The fish body electrocardiosignal of several particular point in time after contact measured water quality.
Further, this method further include: fish body electrocardiosignal is pre-processed, the pretreatment includes filtering and goes Except interference is handled.
Further, the water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, Chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
Further, in the method, it while fish body electrocardiosignal and fish before fish contact measured water quality being obtained connects The water quality parameter for touching the fish body electrocardiosignal of several particular point in time and the acquisition of water quality parameter sensor after water quality to be measured, for into Row water body burst pollution on-line monitoring.
According to the other side of one or more other embodiments of the present disclosure, a kind of computer-readable storage medium is also provided Matter.
A kind of computer readable storage medium, wherein being stored with a plurality of instruction, described instruction is suitable for by terminal device Reason device, which loads and executes described one kind, is based on the cardiac electrical water body burst pollution on-line monitoring method of fish.
According to the other side of one or more other embodiments of the present disclosure, a kind of terminal device is also provided.
A kind of terminal device, using internet terminal equipment, including processor and computer readable storage medium, processor For realizing each instruction;Computer readable storage medium is suitable for by processor load simultaneously for storing a plurality of instruction, described instruction It executes described a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish.
According to the other side of one or more other embodiments of the present disclosure, also provide a kind of based on the cardiac electrical water body of fish Burst pollution on-line monitoring system.
One kind being based on the cardiac electrical water body burst pollution on-line monitoring system of fish, which is based on a kind of based on fish electrocardio Water body burst pollution on-line monitoring method realize, comprising:
Fish electrocardio real-time acquisition device, signal receiver, water quality parameter sensor and computing terminal equipment;
The fish electrocardio real-time acquisition device is installed in fish body by agreeing with the carrier of equipment for fish shape, and the carrier is real The gravity and buoyancy equivalent state of existing carrier and fish electrocardio real-time acquisition device;
The fish electrocardio real-time acquisition device includes waterproof case, the miniature electrocardio letter of fixed placement in the waterproof case Number processing unit, storage device connected to it and battery, the miniature electrocardiogram signal processing device by conducting wire connection electrode, The electrode outlet of the waterproof case bottom end setting extraction electrode, electrode are pierced into acquisition original electrocardiographicdigital letter in fish body cardiocoelom Number, and electrocardiosignal is handled by wire transmission to the miniature electrocardiogram signal processing device;The waterproof case side The through-hole for placing signal projector is arranged in face, and the signal projector transmitting terminal is logical by passing through in the waterproof case main body Hole and with through-hole be tightly connected, the signal projector is connect with battery and miniature electrocardiogram signal processing device respectively, at transmitting Electrocardiosignal after reason completes fish heart real time signal acquisition to signal receiver engaged therewith;
The signal receiver is installed on basin sidewall, for receiving treated electrocardiosignal, and by received electrocardio Signal is sent to computing terminal equipment;
The water quality parameter sensor receives the acquisition signal of computing terminal equipment, by acquiring based on water quality parameter is sent to Calculate terminal device, the water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
Further, the water quality parameter sensor includes temperature sensor, turbidity transducer, pH sensor, conductivity Sensor, ammonia nitrogen sensor, total phosphorus sensor, total nitrogen sensor, TOC sensor, COD sensor, chlorophyll sensor and again Metal sensor;The heavy metal sensor include cadmium sensor, chromium sensor, copper sensor, fe sensor, zinc sensor, Lead sensor and manganese sensor.
Further, the electrode of the system includes acquisition electrode and reference electrode, and the acquisition electrode is embedded to wait adopt In the cardiocoelom of the fish of fish gathering body-centered electric signal, the reference electrode is embedded to the nephrodinic of the fish of fish body electrocardiosignal to be collected Near hole, the acquisition electrode and the reference electrode are embedded to the intracorporal equal length of fish.
The disclosure the utility model has the advantages that
One kind described in the disclosure is based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system, will Water body pop-up threat is monitored on-line based on fish electrocardio index and water quality parameter analysis assessment technology combines, and electrocardio is different It is often starting switch for other water quality monitoring instruments, only EGC parameter is abnormal, just starts monitoring analysis, is effectively saved electricity Can, it finds that EGC parameter is abnormal by monitoring analysis platform, real-time online sampling will be carried out to water quality, and further collect Heshui The specific monitoring result of matter parameter heavy metal sensor or the on-line analysis of TOC and COD are as a result, to further determine that tool Body pollution species and contaminant capacity range, thus in time efficiently and accurately realize for water pollution accident on-line monitoring with comment Estimate, it is ensured that the timely monitoring and evaluation of water body pop-up threat monitoring is fed back, biological monitoring and physics and chemistry monitoring are mutually tied It closes.
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide further understanding of the present application, and the application's shows Meaning property embodiment and its explanation are not constituted an undue limitation on the present application for explaining the application.
Fig. 1 is one of disclosure one or more embodiment based on the cardiac electrical water body burst pollution on-line monitoring of fish Method flow diagram;
Fig. 2 is one of disclosure one or more embodiment based on the cardiac electrical water body burst pollution on-line monitoring of fish Systematic schematic diagram;
Fig. 3 is one of disclosure one or more embodiment based on the cardiac electrical water body burst pollution on-line monitoring of fish System structure diagram;
Wherein, 1 is waterproof case, and 2 be battery, and 3 be signal projector, and 4 be miniature electrocardiogram signal processing device, and 5 be to lead Line, 6 be electrode, and 7 be carrier, and 8 be fish body, and 9 be sink, and 10 be signal receiver, and 11 be computer.
Specific embodiment:
Below in conjunction with the attached drawing in the embodiment of the present disclosure, the technical solution in the embodiment of the present disclosure is carried out clear, complete Site preparation description, it is clear that described embodiment is only disclosure a part of the embodiment, instead of all the embodiments.It is based on Embodiment in the disclosure, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment belongs to the range of disclosure protection.
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.Unless another It indicates, all technical and scientific terms that the present embodiment uses have and the application person of an ordinary skill in the technical field Normally understood identical meanings.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
It should be noted that flowcharts and block diagrams in the drawings show according to various embodiments of the present disclosure method and The architecture, function and operation in the cards of system.It should be noted that each box in flowchart or block diagram can represent A part of one module, program segment or code, a part of the module, program segment or code may include one or more A executable instruction for realizing the logic function of defined in each embodiment.It should also be noted that some alternately Realization in, function marked in the box can also occur according to the sequence that is marked in attached drawing is different from.For example, two connect The box even indicated can actually be basically executed in parallel or they can also be executed in a reverse order sometimes, This depends on related function.It should also be noted that each box and flow chart in flowchart and or block diagram And/or the combination of the box in block diagram, the dedicated hardware based system that functions or operations as defined in executing can be used are come It realizes, or the combination of specialized hardware and computer instruction can be used to realize.
In the absence of conflict, the features in the embodiments and the embodiments of the present application can be combined with each other below with reference to Attached drawing and embodiment are described further the disclosure.
Water quality can be monitored in real time based on fish ecg analysis, thus in time to water body pop-up threat Early warning and assessment are carried out, reduces the loss of economy and natural environment as far as possible.The present invention can not incite somebody to action in the prior art in order to overcome The problem of real-time monitoring water quality is with to water body pop-up threat online evaluation provides and a kind of fish is being kept normally to move about state Under real-time continuous online ECG collection device and guarantee that water body is prominent as the starter of various water quality parameter sensors It sends out contamination accident on-line monitoring and assesses timely and effectively method.
One or more other embodiments of the present disclosure provide a kind of based on fish cardiac electrical water body burst pollution on-line monitoring side Method.
As shown in Figure 1, a kind of be based on the cardiac electrical water body burst pollution on-line monitoring method of fish, this method comprises:
Obtain before fish contact measured water quality several specific times after fish body electrocardiosignal and fish contact measured water quality The fish body electrocardiosignal of point;
Each fish body electrocardiosignal QRS interphase duration of acquisition and the electrocardiographicdata data of QT interphase duration are extracted respectively;
Analyze fish contact measured water quality before and fish contact measured water quality after several particular point in time electrocardiographicdata data Variation, if variation be more than preset threshold, judge pollutant kind, and obtain water quality parameter sensor acquisition water quality ginseng Number, otherwise, water body to be measured are qualified;
Specific pollutant kind and contaminant capacity range are further determined that according to the water quality parameter that water quality parameter sensor acquires.
Further, in the method, obtain respectively before several fish contact measured water quality fish body electrocardiosignal and The fish body electrocardiosignal of several particular point in time after contact measured water quality.
Further, this method further include: fish body electrocardiosignal is pre-processed, the pretreatment includes filtering and goes Except interference is handled.
Further, the water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, Chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
Further, in the method, it while fish body electrocardiosignal and fish before fish contact measured water quality being obtained connects The water quality parameter for touching the fish body electrocardiosignal of several particular point in time and the acquisition of water quality parameter sensor after water quality to be measured, for into Row water body burst pollution on-line monitoring.
Further, in the method, the sensor of conventional five parameters (temperature, turbidity, pH, conductivity, ammonia nitrogen) is normal Operation, then anomalous ecg is that other water quality monitoring instruments start switch that (that is in addition to five parameters, other parameters connect electricity But it does not work, only ECG is abnormal, just starts monitoring analysis).
According to the other side of one or more other embodiments of the present disclosure, a kind of computer-readable storage medium is also provided Matter.
A kind of computer readable storage medium, wherein being stored with a plurality of instruction, described instruction is suitable for by terminal device Reason device, which loads and executes described one kind, is based on the cardiac electrical water body burst pollution on-line monitoring method of fish.
According to the other side of one or more other embodiments of the present disclosure, a kind of terminal device is also provided.
A kind of terminal device, using internet terminal equipment, including processor and computer readable storage medium, processor For realizing each instruction;Computer readable storage medium is suitable for by processor load simultaneously for storing a plurality of instruction, described instruction It executes described a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish.
These computer executable instructions execute the equipment according to each reality in the disclosure Apply method or process described in example.
In the present embodiment, computer program product may include computer readable storage medium, containing for holding The computer-readable program instructions of row various aspects of the disclosure.Computer readable storage medium, which can be, can keep and store By the tangible device for the instruction that instruction execution equipment uses.Computer readable storage medium for example can be-- but it is unlimited In-- storage device electric, magnetic storage apparatus, light storage device, electric magnetic storage apparatus, semiconductor memory apparatus or above-mentioned Any appropriate combination.The more specific example (non exhaustive list) of computer readable storage medium includes: portable computing Machine disk, hard disk, random access memory (RAM), read-only memory (ROM), erasable programmable read only memory (EPROM or Flash memory), static random access memory (SRAM), Portable compressed disk read-only memory (CD-ROM), digital versatile disc (DVD), memory stick, floppy disk, mechanical coding equipment, the punch card for being for example stored thereon with instruction or groove internal projection structure, with And above-mentioned any appropriate combination.Computer readable storage medium used herein above is not interpreted instantaneous signal itself, The electromagnetic wave of such as radio wave or other Free propagations, the electromagnetic wave propagated by waveguide or other transmission mediums (for example, Pass through the light pulse of fiber optic cables) or pass through electric wire transmit electric signal.
Computer-readable program instructions described herein can be downloaded to from computer readable storage medium it is each calculate/ Processing equipment, or outer computer or outer is downloaded to by network, such as internet, local area network, wide area network and/or wireless network Portion stores equipment.Network may include copper transmission cable, optical fiber transmission, wireless transmission, router, firewall, interchanger, gateway Computer and/or Edge Server.Adapter or network interface in each calculating/processing equipment are received from network to be counted Calculation machine readable program instructions, and the computer-readable program instructions are forwarded, for the meter being stored in each calculating/processing equipment In calculation machine readable storage medium storing program for executing.
Computer program instructions for executing present disclosure operation can be assembly instruction, instruction set architecture (ISA) Instruction, machine instruction, machine-dependent instructions, microcode, firmware instructions, condition setup data or with one or more programmings The source code or object code that any combination of language is write, the programming language include the programming language-of object-oriented such as C++ etc., and conventional procedural programming languages-such as " C " language or similar programming language.Computer-readable program refers to Order can be executed fully on the user computer, partly be executed on the user computer, as an independent software package Execute, part on the user computer part on the remote computer execute or completely on a remote computer or server It executes.In situations involving remote computers, remote computer can include local area network by the network-of any kind (LAN) or wide area network (WAN)-is connected to subscriber computer, or, it may be connected to outer computer (such as utilize internet Service provider is connected by internet).In some embodiments, by being believed using the state of computer-readable program instructions Breath comes personalized customization electronic circuit, such as programmable logic circuit, field programmable gate array (FPGA) or programmable logic Array (PLA), the electronic circuit can execute computer-readable program instructions, to realize the various aspects of present disclosure.
According to the other side of one or more other embodiments of the present disclosure, also provide a kind of based on the cardiac electrical water body of fish Burst pollution on-line monitoring system.
To real-time continuous online electrocardiogram acquisition under holding fish normally travelling state, while every water quality indicator exist Line monitoring: temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, chlorophyll and various heavy metal sensors The monitoring of (Cd, Cr, Cu, Fe, Zn, Pb, Mn, etc.), and it is equipped with real-time online water quality sampling technology.Wherein various water quality parameters Unified decision is carried out by monitoring analysis platform.If be abnormal in water quality monitoring Process-centric electrical parameter, electrocardio ginseng Number exception is starting switch for the operation of real-time online water quality sampling technology and the parameter in addition to conventional five parameters.Therefore, this skill Art will be combined based on fish EGC parameter research and application and water quality parameter analysis assessment, can be promptly prominent to water body in time Hair contamination accident is assessed, harm reduction.
As shown in Fig. 2-Fig. 3, one kind being based on the cardiac electrical water body burst pollution on-line monitoring system of fish, which is based on one Kind is realized based on the cardiac electrical water body burst pollution on-line monitoring method of fish, comprising:
Fish electrocardio real-time acquisition device, signal receiver, water quality parameter sensor and computing terminal equipment;
The fish electrocardio real-time acquisition device is installed in fish body by agreeing with the carrier of equipment for fish shape, and the carrier is real The gravity and buoyancy equivalent state of existing carrier and fish electrocardio real-time acquisition device;
The fish electrocardio real-time acquisition device includes waterproof case, the miniature electrocardio letter of fixed placement in the waterproof case Number processing unit, storage device connected to it and battery, the miniature electrocardiogram signal processing device by conducting wire connection electrode, The electrode outlet of the waterproof case bottom end setting extraction electrode, electrode are pierced into acquisition original electrocardiographicdigital letter in fish body cardiocoelom Number, and electrocardiosignal is handled by wire transmission to the miniature electrocardiogram signal processing device;The waterproof case side The through-hole for placing signal projector is arranged in face, and the signal projector transmitting terminal is logical by passing through in the waterproof case main body Hole and with through-hole be tightly connected, the signal projector is connect with battery and miniature electrocardiogram signal processing device respectively, at transmitting Electrocardiosignal after reason completes fish heart real time signal acquisition to signal receiver engaged therewith;
The signal receiver is installed on basin sidewall, for receiving treated electrocardiosignal, and by received electrocardio Signal is sent to computing terminal equipment;
The water quality parameter sensor receives the acquisition signal of computing terminal equipment, by acquiring based on water quality parameter is sent to Calculate terminal device, the water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
The water quality parameter sensor includes temperature sensor, turbidity transducer, pH sensor, conductivity sensor, ammonia Nitrogen sensor, total phosphorus sensor, total nitrogen sensor, TOC sensor, COD sensor, chlorophyll sensor and heavy metal sensing Device;The heavy metal sensor includes cadmium sensor, chromium sensor, copper sensor, fe sensor, zinc sensor, lead sensor With manganese sensor.
The electrode of the system includes acquisition electrode and reference electrode, and the acquisition electrode is embedded to fish body electrocardio to be collected In the cardiocoelom of the fish of signal, the reference electrode is embedded near the cloacal aperture of the fish of fish body electrocardiosignal to be collected, institute It states acquisition electrode and the reference electrode is embedded to the intracorporal equal length of fish.
Ecg signal acquiring memory can acquire the electrocardiosignal of fish body, and interference signal is filtered by filtering technique Fall, and filtered signal is stored, has the function of acquisition, filter function and storage semiotic function.
Signal projector can launch collected electrocardiosignal, and signal passes through water body and air, be emitted to letter Number receiver, signal receiver can receive the electrocardiosignal by water body and air.
Conducting wire is connected with ecg signal acquiring memory, is mainly used to transmit signal, issues from one end of waterproof case, Conducting wire has three altogether, is made by copper wire, crust TPE thermoplastics type's rubber coated.
Electrode connects in the end of three conducting wires, and with the preparation of silvery fine needle, silver needle diameter is 0.25mm, and has needle Point, to be pierced into fish body cardiocoelom.
There is the metal corresponding interface contacted with battery in the other end of electrocardiogram acquisition memory, in order to connect battery, Collector is supplied to be powered.
Waterproof case is made of metal alloy, and electrocardiogram acquisition memory is wrapped up with cell sealing, is at sealing It is designed as screw connection structure, it is easy to disassemble to replace battery etc..
Saddle carrier selects low-density materials, is printed by 3D printer, being placed on after agreeing with device can not in water It as sinking, will not float, reach the state that just its gravity is equal with buoyancy, avoid causing to bear a heavy burden to fish body, influence fish Normal travelling.
Wherein, for ensure to for water body pop-up threat on-line monitoring and analysis, this monitoring water quality on line with comment Estimate system and be divided into two kinds of operational modes: each instrument, which can operate normally, in the first system is monitored water quality, various water Matter index real time on-line monitoring guarantees specific and comprehensive to the monitoring of water quality.But this kind of mode relatively relatively expends electric power resource etc.. Second of mode is that routinely five parameters i.e. temperature, turbidity, pH, conductivity, ammonia nitrogen normal operation are monitored water quality, such as core Electric index is abnormal, he just will start in the starting of water quality monitoring instrument, starts comprehensive monitoring analysis.
Under different heavy metal contaminants stress, the electrocardio of zebra fish will appear different variations.QRS interphase and a huge sum of money Belonging to pollutant stress has apparent correlation, is observed by research and analysis QRS interphase can monitor heavy metal pollution in water quality Object.QT interphase and organic pollutant stress have apparent correlation, are observed by research and analysis QT interphase can monitor water quality Middle organic pollutant.Therefore we come the type for judging pollutant can be organic matter or a huge sum of money in conjunction with the exception of EGC parameter Belong to.And further gather the specific monitoring result of water quality parameter heavy metal sensor and the on-line analysis knot of TOC and COD Fruit, so that specific pollutant kind and contaminant capacity range are further determined that, to efficiently and accurately realize in time dirty for water body The on-line monitoring of dye accident and assessment.Wherein we are equipped with real-time online water quality sampling technology, and anomalous ecg is that water quality is adopted automatically The switch of sample.Once we have found that EGC parameter is abnormal by monitoring analysis platform in this way, real-time online will be carried out to water quality Sampling.
By taking pollutant is organic pollutant decis as an example, when the first mode operation of the system, chemical index monitoring System and Biological indicators monitoring system and water quality assessment system are all up, real-time monitoring water quality.If there is organic matter When decis, then every chemical index can change, while electrocardio is bright by analytical data, and the electrocardio of zebra fish is respectively joined Number, as the concentration of decis increases, P wave, Q wave, R wave, S wave and T wave amplitude be in reduced trend, and PR interphase, QRS Interphase, ST interphase and QT interphase when personal attendant's decis concentration raising and increase.Wherein between the QT based on linear regression The correlation analysis of phase and environmental pressure (E) show P wave and R wave and decis environmental pressure (E) there are significant correlation, and QT Interphase and environmental pressure (E) have extremely significant related, therefore QT interphase and organic pollutant stress have apparent correlation.Between QT Phase can monitor organic pollutant in water quality.Therefore we can be come the type for judging pollutant in conjunction with the exception of EGC parameter Organic matter or heavy metal.
And further gather the specific monitoring result of water quality parameter heavy metal sensor or the index meeting of TOC and COD The higher on-line analysis of occurrence value is as a result, to further determine that specific pollutant kind and contaminant capacity range, thus high in time Effect is accurately realized on-line monitoring and assessment for water pollution accident.Once electrocardiographicdata data exception simultaneously, just will start water Matter samples automatically, acquires water sample, analyzes water sample, the pollutant kind of comprehensive detection pop-up threat.The system When two kinds of mode operations, if water quality does not pollute normally, only conventional five parameters, that is, temperature, turbidity, pH, conductivity, ammonia Nitrogen normal operation is monitored water quality, but the monitoring of remaining chemical index is not run.If electrocardiographicdata data is abnormal, he Water quality monitoring instrument and water quality sample automatically just will start, and starts comprehensive monitoring and analyzes water quality.
QRS interphase and heavy metal contaminants stress have apparent correlation, are observed by research and analysis QRS interphase can be with Monitor heavy metal contaminants in water quality.QT interphase and organic pollutant stress have apparent correlation.QT interphase can monitor water Organic pollutant in matter.Therefore we come the type that judges pollutant can be organic matter or again in conjunction with the exception of EGC parameter Metal.And further gather the specific monitoring result of water quality parameter heavy metal sensor or the on-line analysis of TOC and COD As a result, being directed to water body to efficiently and accurately realize in time to further determine that specific pollutant kind and contaminant capacity range The on-line monitoring of contamination accident and assessment.Wherein we are equipped with real-time online water quality sampling technology, and anomalous ecg is real-time online The switch of sampling.Once we have found that EGC parameter is abnormal by monitoring analysis platform in this way, water quality will exist in real time Line sampling.And further gathers the specific monitoring result of water quality parameter heavy metal sensor or the online of TOC and COD is divided Analysis is directed to water to efficiently and accurately realize in time as a result, to further determine that specific pollutant kind and contaminant capacity range The on-line monitoring of body pollution accident and assessment.Wherein we are equipped with real-time online water quality sampling technology, anomalous ecg be water quality from The switch of dynamic sampling.Once we have found that EGC parameter is abnormal by monitoring analysis platform in this way, water quality will be carried out real-time On-line sampling.
The disclosure the utility model has the advantages that
One kind described in the disclosure is based on the cardiac electrical water body burst pollution on-line monitoring method of fish, apparatus and system, will Water body pop-up threat is monitored on-line based on fish electrocardio index and water quality parameter analysis assessment technology combines, and electrocardio is different It is often starting switch for other water quality monitoring instruments, only EGC parameter is abnormal, just starts monitoring analysis, is effectively saved electricity Can, it finds that EGC parameter is abnormal by monitoring analysis platform, real-time online sampling will be carried out to water quality, and further collect Heshui The specific monitoring result of matter parameter heavy metal sensor or the on-line analysis of TOC and COD are as a result, to further determine that tool Body pollution species and contaminant capacity range, thus in time efficiently and accurately realize for water pollution accident on-line monitoring with comment Estimate, it is ensured that the timely monitoring and evaluation of water body pop-up threat monitoring is fed back, biological monitoring and physics and chemistry monitoring are mutually tied It closes.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for the skill of this field For art personnel, various changes and changes are possible in this application.Within the spirit and principles of this application, made any to repair Change, equivalent replacement, improvement etc., should be included within the scope of protection of this application.Therefore, the disclosure is not intended to be limited to this These embodiments shown in text, and it is to fit to the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1. one kind is based on the cardiac electrical water body burst pollution on-line monitoring method of fish, which is characterized in that this method comprises:
Obtain before fish contact measured water quality several particular point in time after fish body electrocardiosignal and fish contact measured water quality Fish body electrocardiosignal;
Each fish body electrocardiosignal QRS interphase duration of acquisition and the electrocardiographicdata data of QT interphase duration are extracted respectively;
Analyze fish contact measured water quality before and fish contact measured water quality after several particular point in time electrocardiographicdata data change Change, if variation is more than preset threshold, judge pollutant kind, and obtains the water quality parameter of water quality parameter sensor acquisition, it is no Then, water body to be measured is qualified;
Specific pollutant kind and contaminant capacity range are further determined that according to the water quality parameter that water quality parameter sensor acquires.
2. as described in claim 1 a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish, which is characterized in that In the method, it obtains respectively before several fish contact measured water quality several after fish body electrocardiosignal and contact measured water quality The fish body electrocardiosignal of particular point in time.
3. as described in claim 1 a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish, which is characterized in that This method further include: fish body electrocardiosignal is pre-processed, the pretreatment includes filtering and removing interference processing.
4. as described in claim 1 a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish, which is characterized in that The water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
5. as described in claim 1 a kind of based on the cardiac electrical water body burst pollution on-line monitoring method of fish, which is characterized in that In the method, while several spies after fish body electrocardiosignal and fish contact measured water quality being obtained before fish contact measured water quality It fixes time the water quality parameter of fish body electrocardiosignal a little and the acquisition of water quality parameter sensor, it is online for carrying out water body burst pollution Monitoring.
6. a kind of computer readable storage medium, wherein being stored with a plurality of instruction, which is characterized in that described instruction is suitable for by terminal The processor of equipment is loaded and is executed according to any one of claims 1 to 5 a kind of dirty based on the cardiac electrical water body burst of fish Contaminate on-line monitoring method.
7. a kind of terminal device, using internet terminal equipment, including processor and computer readable storage medium, processor is used In each instruction of realization;Computer readable storage medium is for storing a plurality of instruction, which is characterized in that described instruction is suitable for by handling Device is loaded and is executed according to any one of claims 1 to 5 a kind of based on the cardiac electrical water body burst pollution on-line monitoring of fish Method.
8. one kind is based on the cardiac electrical water body burst pollution on-line monitoring system of fish, which is based on as appointed in claim 1-5 One kind described in one is based on the cardiac electrical water body burst pollution on-line monitoring method of fish and realizes characterized by comprising
Fish electrocardio real-time acquisition device, signal receiver, water quality parameter sensor and computing terminal equipment;
The fish electrocardio real-time acquisition device is installed in fish body by agreeing with the carrier of equipment for fish shape, and the carrier, which is realized, to be carried The gravity and buoyancy equivalent state of body and fish electrocardio real-time acquisition device;
The fish electrocardio real-time acquisition device includes waterproof case, in the waterproof case at the miniature electrocardiosignal of fixed placement Device, storage device connected to it and battery are managed, the miniature electrocardiogram signal processing device is described by conducting wire connection electrode The electrode outlet of extraction electrode is arranged in waterproof case bottom end, and electrode, which is pierced into fish body cardiocoelom, acquires original electro-cardiologic signals, and Electrocardiosignal is handled by wire transmission to the miniature electrocardiogram signal processing device;The waterproof case side setting For placing the through-hole of signal projector, the signal projector transmitting terminal by passed through in the waterproof case main body through-hole and with Through-hole is tightly connected, and the signal projector is connect with battery and miniature electrocardiogram signal processing device respectively, and treated for transmitting Electrocardiosignal completes fish heart real time signal acquisition to signal receiver engaged therewith;
The signal receiver is installed on basin sidewall, for receiving treated electrocardiosignal, and by received electrocardiosignal It is sent to computing terminal equipment;
The water quality parameter sensor receives the acquisition signal of computing terminal equipment, is sent to calculating eventually for acquiring water quality parameter End equipment, the water quality parameter include temperature, turbidity, pH, conductivity, ammonia nitrogen, total phosphorus, total nitrogen, TOC, COD, chlorophyll, Cd, Cr, Cu, Fe, Zn, Pb and Mn.
9. as claimed in claim 8 a kind of based on the cardiac electrical water body burst pollution on-line monitoring system of fish, which is characterized in that The water quality parameter sensor include temperature sensor, turbidity transducer, pH sensor, conductivity sensor, ammonia nitrogen sensor, Total phosphorus sensor, total nitrogen sensor, TOC sensor, COD sensor, chlorophyll sensor and heavy metal sensor;The huge sum of money Belonging to sensor includes cadmium sensor, chromium sensor, copper sensor, fe sensor, zinc sensor, lead sensor and manganese sensor.
10. as claimed in claim 8 a kind of based on the cardiac electrical water body burst pollution on-line monitoring system of fish, feature exists In the electrode of the system includes acquisition electrode and reference electrode, and the acquisition electrode is embedded to fish body electrocardiosignal to be collected Fish cardiocoelom in, the reference electrode is embedded near the cloacal aperture of the fish of fish body electrocardiosignal to be collected, described to adopt Collector and the reference electrode are embedded to the intracorporal equal length of fish.
CN201811571919.0A 2018-07-11 2018-12-21 Fish electrocardio-based water body sudden pollution online monitoring method, device and system Active CN109613196B (en)

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CN201811571919.0A CN109613196B (en) 2018-12-21 2018-12-21 Fish electrocardio-based water body sudden pollution online monitoring method, device and system
CA3053603A CA3053603C (en) 2018-07-11 2019-01-22 Method and system for comprehensive evaluation of organic compound and heavy metal pollution in water based on fish electrocardio
PCT/CN2019/072599 WO2020010836A1 (en) 2018-07-11 2019-01-22 Fish electrocardiogram based comprehensive evaluation method and system for organic matter and heavy-metal water pollution
EP19756312.5A EP3646783A4 (en) 2018-07-11 2019-01-22 Fish electrocardiogram based comprehensive evaluation method and system for organic matter and heavy-metal water pollution
US16/555,883 US10571448B2 (en) 2018-07-11 2019-08-29 Method and system for comprehensive evaluation of organic compound and heavy metal pollution in water based on fish electrocardio
ZA2019/05816A ZA201905816B (en) 2018-07-11 2019-09-03 Method and system for comprehensive evaluation of organic compound and heavy metal pollution in water based on fish electrocardio

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