CN109610756A - A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming - Google Patents
A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming Download PDFInfo
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- CN109610756A CN109610756A CN201811448565.0A CN201811448565A CN109610756A CN 109610756 A CN109610756 A CN 109610756A CN 201811448565 A CN201811448565 A CN 201811448565A CN 109610756 A CN109610756 A CN 109610756A
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- Prior art keywords
- ceramic tile
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- titanium dioxide
- ceramic
- inorganic nano
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/142—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming, including ceramic tile main body, the back side of ceramic tile main body is the bottom surface in conjunction with building wall or ground, the front of ceramic tile main body is the surface that high temperature is fired, the ceramic tile body surfaces are microcellular structure layer, ceramic tile body surfaces are coated with inorganic nano ceramic layer, the bottom surface of the inorganic nano ceramic layer infiltrates into microcellular structure layer and combines with the surface of ceramic tile main body, the inorganic nano surface ceramii layer is coated with nanometer titanium dioxide layer, and the back side of the ceramic tile main body is equipped with rectangular channel.The present invention sprays nanometer titanium dioxide layer, nano-titanium dioxide plays the role of degerming disinfection, the noxious materials such as formaldehyde, ammonia, benzene, TVOC of thick air after interior decoration can also be absorbed, and inorganic nano ceramic layer is the carrier of nanometer titanium dioxide layer, adsorptivity of the inorganic nano ceramic layer in ceramic tile main body is enhanced, causes nanometer titanium dioxide layer to fail after avoiding nanometer titanium dioxide layer from being rubbed off easily.
Description
Technical field
The present invention relates to ceramic tile fields, and in particular to a kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming.
Background technique
Nano-titanium dioxide is a kind of white powder, has antibacterial, self-cleaning is anti-aging, and shielding ultraviolet rays function, it is not
But ultraviolet light can be absorbed, moreover it is possible to reflect, scatters ultraviolet function.It is permanent to sterilize under action of ultraviolet radiation, it is demonstrated experimentally that with
0.1mg/cm3 concentration nanometer anatase titania can thoroughly kill pernicious HeLa cell, and with superoxide dismutase
Enzyme (SOD) additive amount increases, and the efficiency that optically catalytic TiO 2 kills cancer cell improves much, to hay bacillus, var. niger
The killing rate of gemma, salmonella, tooth branch bacterium and aspergillus reach 98% or more, aoxidize concentration with optically catalytic TiO 2 to handle
Tap water can also greatly reduce the bacterial population in water, can prevent from polluting, deodorization taste removal.
Nano-titanium dioxide makes titanium dioxide activate and generate and urges with height under the action of daylight or light ultraviolet light
Change free radical, very strong oxidation and reducing power can be generated, can be catalytically decomposed that be attached to various formaldehyde of ceramic tile surface etc. organic
Object and part inorganic matter, are added titanium dioxide in ceramic tile, and substance of any pickup on surface includes greasy dirt, photograph of the bacterium in light
It penetrates down, due to the catalytic action of titanium dioxide, aoxidizes these hydrogen compound substances further, become gas or be easy to wipe
The substance fallen.
Well known ceramic tile is made of shading, green body, ground coat enamel, overglaze, the metope or Land leveling, beauty decorated with ceramic tile
It sees, is wear-resisting, anticorrosive, in recent years since in fitment process, finishing and new furniture generate many toxic and harmful gas, making one
Start pay attention to finishing material environment protecting, not only finishing material is required not release toxic and harmful gas, it is also desirable to fit up material
Material can decompose toxic and harmful gas, it is thus proposed that ceramic tile surface and wall surface spraying nano-titanium dioxide after having fitted up
Method, nano-titanium dioxide play the role of degerming disinfection, can also absorb the formaldehyde of thick air after interior decoration, ammonia, benzene,
The noxious materials such as TVOC, the nano-titanium dioxide of spraying can also generate automatic clean effect, i.e. spraying nano-titanium dioxide
Ceramic tile surface can keep cleaning afterwards, it is not easy to be stained with dirt, still, in-situ spraying nano-titanium dioxide has some very big lack
It falls into, after spray coating, adsorptivity of the nano-titanium dioxide on ceramic tile is not strong enough, is easy to be rubbed off, and reduces degerming disinfection etc.
Effect.
Summary of the invention
There is provided a kind of using inorganic nano ceramics as the net first of the bacterium of nano TiO 2 carrying body for an object of the present invention
Ecological ceramic tile of aldehyde and preparation method thereof.
A kind of ecological ceramic tile of the net formaldehyde of degerming, including ceramic tile main body, the back side of the ceramic tile main body are and building wall
The bottom surface that face or ground combine, the front of the ceramic tile main body are the surface that high temperature is fired, the ceramic tile body surfaces
For microcellular structure layer, the ceramic tile body surfaces are coated with inorganic nano ceramic layer, the bottom of the inorganic nano ceramic layer
Face infiltrates into microcellular structure layer and combines with the surface of ceramic tile main body, and the inorganic nano surface ceramii layer is coated with nanometer two
Titanium oxide layer, the back side of the ceramic tile main body are equipped with rectangular channel, and the ceramic tile body surfaces are equipped with surrounding edge, the surrounding edge
Thickness be greater than the thickness that the inorganic nano ceramic layer and nanometer titanium dioxide layer are superimposed.
Preferably, the inorganic nano ceramic layer is coated with above ceramic main body surface and applies nanometer titanium dioxide layer in 30 seconds
On cloth, the inorganic nano ceramic layer and the nanometer titanium dioxide layer form mosaic coating.
Preferably, the mosaic coating thickness is not more than 0.03 millimeter.
Preferably, the inorganic nano ceramic layer with a thickness of 0.05-0.08 millimeters.
Preferably, the nanometer titanium dioxide layer with a thickness of 0.09-0.12 millimeters.
Preferably, the nano-titanium dioxide partial size of the nanometer titanium dioxide layer is 50-100nm.
A kind of preparation method of the ecological ceramic tile of the net formaldehyde of degerming, which is characterized in that make as follows:
Step 1: when using ball milling mud, pouring into titanium dioxide nanoparticle, obtain containing the ordinary porcelain for entering nano-titanium dioxide
Brick cleans ceramic tile surface using common ceramic tile as substrate, removes dust, greasy dirt, and ceramic tile biscuit is made in gravel.
Step 2: the back side of ceramic tile biscuit being polished into rectangular channel using sander.
Step 3: going out depressed area in the surface grinding of ceramic tile biscuit using grinder, form surrounding edge structure.
Step 4: the glazing on biscuit, first dipping and then again cloth dry powder glaze.
Step 5: after glaze layer is dry, slipware being placed in kiln and is fired by glaze, that is, fambed ceramic tile is made.
Step 6: spraying an inorganic nano ceramic layer in depressed area using spray gun.
Step 7: within 30 seconds, when inorganic nano ceramic layer does not complete surface drying, carrying out nanometer titanium dioxide layer spraying.
Step 8: placing normal temperature environment and stand 2 hours, complete the preparation of ceramic tile.
The invention has the benefit that the present invention using inorganic nano ceramic layer as the carrier of nanometer titanium dioxide layer, enhances
Adsorptivity of the inorganic nano ceramic layer in ceramic tile main body, leads to nanometer after avoiding nanometer titanium dioxide layer from being rubbed off easily
Titanium dioxide layer failure.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
In figure: ceramic tile main body 1, microcellular structure layer 2, inorganic nano ceramic layer 3, nanometer titanium dioxide layer 4, surrounding edge 5, rectangle
Slot 6.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments, is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
As shown in connection with fig. 1, the ecological ceramic tile of the net formaldehyde of a kind of degerming, including ceramic tile main body 1, the ceramic tile main body 1
The back side is the bottom surface in conjunction with building wall or ground, and 1 front of the ceramic tile main body is the surface that high temperature is fired, described
1 surface of ceramic tile main body be microcellular structure layer 2,1 surface of ceramic tile main body is coated with inorganic nano ceramic layer 3, described
3 layers of bottom surface of inorganic nano ceramics infiltrates into microcellular structure layer 2 to be combined with the surface of ceramic tile main body 1, described inorganic to receive
Rice 3 surface of ceramic layer is coated with nanometer titanium dioxide layer 4, and the back side of the ceramic tile main body 1 is equipped with rectangular channel 6, the ceramic tile
1 surface of main body is equipped with surrounding edge 5, and the thickness of the surrounding edge 5 is greater than the inorganic nano ceramic layer 3 and nanometer titanium dioxide layer
The thickness of 4 superpositions.
The inorganic nano ceramic layer 3 is coated with above ceramic main body surface and is coated with nanometer titanium dioxide layer 4 in 30 seconds,
The inorganic nano ceramic layer 3 and the nanometer titanium dioxide layer 4 form mosaic coating.
The mosaic coating thickness is not more than 0.03 millimeter.
The inorganic nano ceramic layer 3 with a thickness of 0.05-0.08 millimeters.
The nanometer titanium dioxide layer 4 with a thickness of 0.09-0.12 millimeters.
The nano-titanium dioxide partial size of the nanometer titanium dioxide layer 4 is 50-100nm.
A kind of preparation method of the ecological ceramic tile of the net formaldehyde of degerming, which is characterized in that make as follows:
Step 1: when using ball milling mud, pouring into titanium dioxide nanoparticle, obtain containing the ordinary porcelain for entering nano-titanium dioxide
Brick cleans ceramic tile surface using common ceramic tile as substrate, removes dust, greasy dirt, and ceramic tile biscuit is made in gravel;
Step 2: the back side of ceramic tile biscuit being polished into rectangular channel using sander;
Step 3: going out depressed area in the surface grinding of ceramic tile biscuit using grinder, form surrounding edge structure;
Step 4: the glazing on biscuit, first dipping and then again cloth dry powder glaze;
Step 5: after glaze layer is dry, slipware being placed in kiln and is fired by glaze, that is, fambed ceramic tile is made;
Step 6: spraying an inorganic nano ceramic layer in depressed area using spray gun;
Step 7: within 30 seconds, when inorganic nano ceramic layer does not complete surface drying, carrying out nanometer titanium dioxide layer spraying;
Step 8: placing normal temperature environment and stand 2 hours, complete the preparation of ceramic tile.
The invention has the benefit that the present invention using inorganic nano ceramic layer as the carrier of nanometer titanium dioxide layer, enhances
Adsorptivity of the inorganic nano ceramic layer in ceramic tile main body, leads to nanometer after avoiding nanometer titanium dioxide layer from being rubbed off easily
Titanium dioxide layer failure.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of ecological ceramic tile of the net formaldehyde of degerming, including ceramic tile main body, the back side of the ceramic tile main body is and building wall
Or the bottom surface that ground combines, the front of the ceramic tile main body are the surface that high temperature is fired, which is characterized in that the ceramic tile
Body surfaces are microcellular structure layer, and the ceramic tile body surfaces are coated with inorganic nano ceramic layer, the inorganic nano pottery
The bottom surface of enamel coating infiltrates into microcellular structure layer and combines with the surface of ceramic tile main body, and the inorganic nano surface ceramii layer applies
Cloth nanometer titanium dioxide layer, the back side of the ceramic tile main body are equipped with rectangular channel, and the ceramic tile body surfaces are equipped with surrounding edge, institute
The thickness for the surrounding edge stated is greater than the thickness that the inorganic nano ceramic layer and nanometer titanium dioxide layer are superimposed.
2. a kind of ecological ceramic tile of the net formaldehyde of degerming according to claim 1, which is characterized in that the inorganic nano pottery
Enamel coating is coated with upper ceramic main body surface in 30 seconds and is coated with nanometer titanium dioxide layer, the inorganic nano ceramic layer with it is described
Nanometer titanium dioxide layer formed mosaic coating.
3. a kind of ecological ceramic tile of the net formaldehyde of degerming according to claim 2, which is characterized in that the mosaic coating thickness
No more than 0.03 millimeter.
4. a kind of ecological ceramic tile of the net formaldehyde of degerming according to claim 1, which is characterized in that the inorganic nano pottery
Enamel coating with a thickness of 0.05-0.08 millimeters.
5. a kind of ecological ceramic tile of the net formaldehyde of degerming according to claim 1, which is characterized in that the nanometer titanium dioxide
Titanium layer with a thickness of 0.09-0.12 millimeters.
6. a kind of ecological ceramic tile of the net formaldehyde of degerming according to claim 1, which is characterized in that the nanometer titanium dioxide
The nano-titanium dioxide partial size of titanium layer is 50-100nm.
7. a kind of preparation method of the ecological ceramic tile of the net formaldehyde of degerming, which is characterized in that make as follows:
Step 1: when using ball milling mud, pouring into titanium dioxide nanoparticle, obtain containing the ordinary porcelain for entering nano-titanium dioxide
Brick cleans ceramic tile surface using common ceramic tile as substrate, removes dust, greasy dirt, and ceramic tile biscuit is made in gravel;
Step 2: the back side of ceramic tile biscuit being polished into rectangular channel using sander;
Step 3: going out depressed area in the surface grinding of ceramic tile biscuit using grinder, form surrounding edge structure;
Step 4: the glazing on biscuit, first dipping and then again cloth dry powder glaze;
Step 5: after glaze layer is dry, slipware being placed in kiln and is fired by glaze, that is, fambed ceramic tile is made;
Step 6: spraying an inorganic nano ceramic layer in depressed area using spray gun;
Step 7: within 30 seconds, when inorganic nano ceramic layer does not complete surface drying, carrying out nanometer titanium dioxide layer spraying;
Step 8: placing normal temperature environment and stand 2 hours, complete the preparation of ceramic tile.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811448565.0A CN109610756A (en) | 2018-11-30 | 2018-11-30 | A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming |
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CN201811448565.0A CN109610756A (en) | 2018-11-30 | 2018-11-30 | A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming |
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CN109610756A true CN109610756A (en) | 2019-04-12 |
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CN201811448565.0A Pending CN109610756A (en) | 2018-11-30 | 2018-11-30 | A kind of ecological ceramic tile and preparation method thereof of the net formaldehyde of degerming |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110357667A (en) * | 2019-04-30 | 2019-10-22 | 佛山市非同科技有限公司 | One kind removing formaldehyde ceramic tile and its manufacturing method |
CN111792670A (en) * | 2020-06-22 | 2020-10-20 | 佛山欧神诺陶瓷有限公司 | Titanium dioxide photocatalyst, preparation method thereof and application thereof in ceramic tiles |
-
2018
- 2018-11-30 CN CN201811448565.0A patent/CN109610756A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110357667A (en) * | 2019-04-30 | 2019-10-22 | 佛山市非同科技有限公司 | One kind removing formaldehyde ceramic tile and its manufacturing method |
CN111792670A (en) * | 2020-06-22 | 2020-10-20 | 佛山欧神诺陶瓷有限公司 | Titanium dioxide photocatalyst, preparation method thereof and application thereof in ceramic tiles |
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Application publication date: 20190412 |
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