CN109610186A - One kind can touch screen artificial leather - Google Patents

One kind can touch screen artificial leather Download PDF

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Publication number
CN109610186A
CN109610186A CN201811548337.0A CN201811548337A CN109610186A CN 109610186 A CN109610186 A CN 109610186A CN 201811548337 A CN201811548337 A CN 201811548337A CN 109610186 A CN109610186 A CN 109610186A
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CN
China
Prior art keywords
parts
surface layer
touch screen
artificial leather
pvc
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Pending
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CN201811548337.0A
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Chinese (zh)
Inventor
陈瑞来
陈炳琪
陈尚泰
林芙蓉
茅金彬
林曙杰
陈海金
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Fujian Polytech Technology Corp Ltd
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Fujian Polytech Technology Corp Ltd
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Priority to CN201811548337.0A priority Critical patent/CN109610186A/en
Publication of CN109610186A publication Critical patent/CN109610186A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other

Abstract

It can touch screen artificial leather the present invention relates to one kind, including the surface layer and foaming layer set gradually, the surface layer is PU surface layer or PVC surface layer, and the PU surface layer includes that following parts by weight prepare raw material: 95-105 parts of polyurethane resin, 100-110 parts of solvent, 0.1-0.3 parts of levelling agent, 2-4 parts of conductive auxiliary agent, 13-16 parts of aging agent and 1-10 parts of colorant;The PVC surface layer includes that following parts by weight prepare raw material: 95-105 parts of PVC paste resin, 65-73 parts of plasticizer, 8-10 parts of aluminum paste, 2-4 parts of conductive auxiliary agent, 1-3 parts of stabilizer and 4-6 parts of colorant.It is of the invention can touch screen artificial leather have leather made integrally to obtain electric conductivity, and the electric conductivity obtained can form the medium of conduction weak current with human body, and then artificial leather is made to obtain touch screen functionality.

Description

One kind can touch screen artificial leather
Technical field
Invention is related to artificial leather technology, in particular to one kind can touch screen artificial leather.
Background technique
Common PU/PVC composite artificial leather is compound with pvc material or pvc material and polyurethane material It forms, then base fabric fabric laminating forms, because the plastic material electric conductivity of polyvinyl chloride is poor.Along with the fabric of fitting is usual It is also that cotton material and terylene material conduction are worse, conduction electricity cannot be formed with human body by being done using this leather on glove industry articles The medium of weak current.The many people of society are using the mobile phone for having touch screen functionality now, when especially north winter is cold, such as Fruit wears gloves, using touch-screen mobile phone very it is out of the ordinary just.It needs to unglove, bare finger uses the electronic product of touch screen.
Summary of the invention
The technical problems to be solved by the present invention are: provide it is a kind of may be implemented touch screen can touch screen artificial leather.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention are as follows:
One kind can touch screen artificial leather, including the surface layer and foaming layer set gradually, the surface layer is PU surface layer or the face PVC Layer, the PU surface layer include that following parts by weight prepare raw material: 95-105 parts of polyurethane resin, 100-110 parts of solvent, levelling agent 0.1-0.3 parts, 2-4 parts of conductive auxiliary agent, 13-16 parts of aging agent and 1-10 parts of colorant;The PVC surface layer includes following parts by weight Prepare raw material: 95-105 parts of PVC paste resin, 65-73 parts of plasticizer, 8-10 parts of aluminum paste, conduction help: 2-4 parts, steady Determine 1-3 parts and colorant 4-6 parts of agent.
The beneficial effects of the present invention are:
The present invention by the way that conductive auxiliary agent is being added in PU surface material, in PVC surface material be added conductive auxiliary agent and Metal powder (aluminum paste) reaches the technology effect for improving the electric conductivity of artificial leather cladding so that surface layer be made to obtain electric conductivity Fruit, and the concrete component of surface layer is designed, so that the electric conductivity obtained can form the medium of conduction weak current with human body, in turn So that artificial leather is obtained touch screen functionality, and it is of the invention can touch screen artificial leather there is the good flexible performance and standard used touch screen True performance.Artificial leather of the invention can be made into gloves or protection tool, can also use in the same old way.
Specific embodiment
To explain the technical content, the achieved purpose and the effect of the present invention in detail, it is explained below in conjunction with embodiment.
The most critical design of the present invention is: conductive auxiliary agent is added in surface material, acquisition makes surface layer obtain electric conductivity Can, and the concrete component of surface layer is designed, so that the electric conductivity obtained can form the medium of conduction weak current with human body, in turn Artificial leather is set to obtain touch screen functionality.
The present invention provide one kind can touch screen artificial leather, including the surface layer and foaming layer set gradually, the surface layer is the face PU Layer or PVC surface layer, the PU surface layer include that following parts by weight prepare raw material: 95-105 parts of polyurethane resin, solvent 100-110 Part, 0.1-0.3 parts of levelling agent, 2-4 parts of conductive auxiliary agent, 13-16 parts of aging agent and 1-10 parts of colorant;The PVC surface layer includes Following parts by weight prepare raw material: 95-105 parts of PVC paste resin, 65-73 parts of plasticizer, 8-10 parts of aluminum paste, conduction help 2-4 parts of agent, 1-3 parts of stabilizer and 4-6 parts of colorant.
As can be seen from the above description, the beneficial effects of the present invention are:
Conductive auxiliary agent and gold is added by the way that conductive auxiliary agent is added in PU surface material in the present invention in PVC surface material Belong to powder (aluminum paste), so that surface layer be made to obtain electric conductivity, reach the technical effect for improving the electric conductivity of artificial leather cladding, And the concrete component of surface layer is designed, so that the electric conductivity obtained can form the medium of conduction weak current with human body, and then make Artificial leather obtains touch screen functionality, and it is of the invention can touch screen artificial leather there is the good flexible performance used touch screen and accurate Performance.Artificial leather of the invention can be made into gloves or protection tool, can also use in the same old way.
Conductive auxiliary agent and gold is added by the way that conductive auxiliary agent is added in PU surface material in the present invention in PVC surface material Belong to powder (aluminum paste).Usual artificial leather plastic layer is thicker, and conductive poorer, plastic layer effect between 0.3-0.5mm is preferable.Too Thin skin material can be poor, and warming poor.Too thick electric conductivity is first weak to meeting.And be made into product feel can hard flexibility ratio become Difference.Base fabric made of the base fabric conductive fiber material of selection, base fabric thickness will select the phozy -0.5mmm of 0.2mm/ to play villus Soft base fabric.It is optimal can touch screen leather thicknesses control in 0.7-1.0mm.This conductive fiber includes metallic compound Type conductive fiber, metal system conductive fiber etc..Human biological electricity spread by this conductive fiber structure and is led and electronic product, Realize touch screen functionality.Specifically, human body is conductor, when finger touch screen, electronics is transferred on touch screen from human body and can be operated Screen, because common leather insulate, the transfer of electronics is blocked, therefore can not operating handset screen.And touch screen leather finger tip conductive fabric Function served as bridge is played between capacitance plate and finger, has evaded the defect that knitting wool, cotton and cortex gloves cannot be conductive.Therefore leather It is fabricated to the achievable contact action such as gloves.On the one hand gloves play heat preservation protective action, on the other hand can take on finger and touching Touch the electric conductor between screen.For principle, as long as the object operator control panel of couple current can be formed with screen touch face Curtain.General cotton gloves poor conductors, band gloves operation is equivalent to handle and screen barrier is opened, and the electric conductivity of skin is opposite It is good, but gloves can generally make liner of other materials, and liner is generally non-conductive.So to select the base done with conductive fiber Cloth.
Further, as a specific component example, can touch screen artificial leather include the surface layer and foaming layer set gradually, The surface layer is PU surface layer, and the PU surface layer includes that following parts by weight prepare raw material: 95 parts of polyurethane resin, 100 parts of solvent, 0.1 part of levelling agent, 2 parts of conductive auxiliary agent, 13 parts of aging agent and 1 part of colorant.Alternatively, the PU surface layer includes following parts by weight Prepare raw material: 105 parts of polyurethane resin, 110 parts of solvent, 0.3 part of levelling agent, 4 parts of conductive auxiliary agent, 16 parts of aging agent and colorant 10 parts.Again alternatively, the PU surface layer includes that following parts by weight prepare raw material: 100 parts of polyurethane resin, 105 parts of solvent, levelling 0.2 part of agent, 3 parts of conductive auxiliary agent, 15 parts of aging agent and 5 parts of colorant.
For another example, another specific component example, can touch screen artificial leather include the surface layer and foaming layer set gradually, the face Layer is PVC surface layer, and the PVC surface layer includes that following parts by weight prepare raw material: 95 parts of PVC paste resin, plasticizer 65 Part, 8 parts of aluminum paste, 2 parts of conductive auxiliary agent, 1 part of stabilizer and 4 parts of colorant.Alternatively, the PVC surface layer includes following parts by weight Prepare raw material: 105 parts of PVC paste resin, 73 parts of plasticizer, 10 parts of aluminum paste, 4 parts of conductive auxiliary agent, 3 parts of stabilizer and color 6 parts of material.Again alternatively, the PVC surface layer includes that following parts by weight prepare raw material: 100 parts of PVC paste resin, plasticizer 68 Part, 9 parts of aluminum paste, 3 parts of conductive auxiliary agent, 3 parts of stabilizer and 5 parts of colorant.
Further, the foaming layer includes that following parts by weight prepare raw material: 95-105 parts of PVC paste resin increases Mould agent 75-85 parts, 15-25 parts of filler material, 8-10 parts of aluminum paste, 2-4 parts of conductive auxiliary agent, 2-4 parts of foaming stabiliser, foaming agent 3- 5 parts and colorant 4-6 parts.
Seen from the above description, as a specific component example, the foaming layer includes that the preparation of following parts by weight is former Material: 101 parts of PVC paste resin, 82 parts of plasticizer, 23 parts of filler material, 9.2 parts of aluminum paste, 3.3 parts of conductive auxiliary agent, foaming are steady Determine 3.5 parts of agent, 4.5 parts of foaming agent and 5.3 parts of colorant.Another specific component example, the foaming layer include following parts by weight Prepare raw material: 99 parts of PVC paste resin, 79 parts of plasticizer, 19 parts of filler material, 8.9 parts of aluminum paste, conductive auxiliary agent 2.8 Part, 3.6 parts of foaming stabiliser, 4.2 parts of foaming agent and 5.2 parts of colorant.
Further, in the surface layer, the viscosity of the surface layer slurry of PU surface layer is 900-1500CPS, with a thickness of 3-15; The viscosity of the surface layer slurry of PVC surface layer is 2000-25000CPS, with a thickness of 0.1-0.15mm.
Seen from the above description, as a specific parameter designing example, the viscosity of the surface layer slurry of PU surface layer is 1100CPS, with a thickness of 8;The viscosity of the surface layer slurry of PVC surface layer is 22000CPS, with a thickness of 0.12mm.Another specific ginseng Number design example, the viscosity of the surface layer slurry of PU surface layer is 1400CPS, with a thickness of 12;The viscosity of the surface layer slurry of PVC surface layer For 24000CPS, with a thickness of 0.14mm.
Further, further include middle layer when the surface layer is PU surface layer, the middle layer be set to surface layer and foaming layer it Between, the middle layer includes that following parts by weight prepare raw material: 95-105 parts of PVC paste resin, 70-80 parts of plasticizer, aluminium 8-10 parts of silver paste, 2-4 parts of conductive auxiliary agent, 1-3 parts of stabilizer and 5-10 parts of colorant.
Seen from the above description, as a specific component example, the middle layer includes that the preparation of following parts by weight is former Material: 102 parts of PVC paste resin, 78 parts of plasticizer, 9.5 parts of aluminum paste, 3.5 parts of conductive auxiliary agent, 2.5 parts of stabilizer and colorant 8.6 part.Another specific component example, the middle layer include that following parts by weight prepare raw material: PVC paste resin 99 Part, 74 parts of plasticizer, 8.8 parts of aluminum paste, 2.8 parts of conductive auxiliary agent, 1.9 parts of stabilizer and 6.5 parts of colorant.
Further, the middle layer with a thickness of 0.1-0.15mm.
Seen from the above description, as a specific parameter designing example, the thickness of middle layer can for 0.11mm, 0.12mm or 0.14mm.
Further, foaming layer with a thickness of 0.15-0.35mm.
Seen from the above description, as a specific parameter designing example, the thickness of foaming layer can for 0.21mm, 0.32mm or 0.25mm.
It further, further include base cloth layer, the material of the base cloth layer is conductive fiber.
Seen from the above description, base cloth layer selects the base fabric with conductive fiber material, for example, the electric conductivity of base fabric Are as follows: under conditions of 20 DEG C and 65% relative humidity, resistance 103Ohm.
Further, it is described can touch screen artificial leather overall thickness be 0.8-1.17mm.
Seen from the above description, as a specific parameter designing example, can the overall thickness of touch screen artificial leather can be controlled in 0.88,0.96,1.12 or 1.16mm.
Further, the electric conductivity of PU surface layer or the conductive auxiliary agent in PVC surface layer are as follows: for 20 DEG C and relatively wet in temperature Under conditions of degree is 65%, resistance is (0.8-1.2) × 107Ohm.
Seen from the above description, in the present invention, PU surface layer or the conductive auxiliary agent in PVC surface layer, the conduction in foaming layer are helped Conductive auxiliary agent in agent and middle layer, above-mentioned conductive auxiliary agent can be 20 in temperature according to electric conductivity in selection DEG C and relative humidity be 65% under conditions of, resistance be (0.8-1.2) × 107Ohm, this range are selected.
Further, it is described can touch screen artificial leather electric conductivity are as follows: in temperature be 20 DEG C and relative humidity is 65% Under the conditions of, resistance is (1.23-3.76) × 107Ohm.
Seen from the above description, as a specific component example, can touch screen artificial leather may include the face PU set gradually Layer, middle layer, foaming layer and base cloth layer, this can touch screen artificial leather monolithic conductive performance can be controlled in temperature be 20 DEG C and phase Under conditions of being 65% to humidity, resistance is (1.38-3.76) × 107Ohm;It, can touch screen as another specific component example Artificial leather may include PVC surface layer, foaming layer and the base cloth layer set gradually, this can touch screen artificial leather monolithic conductive performance it is controllable For system under conditions of temperature is 20 DEG C and relative humidity is 65%, resistance is (1.23-3.56) × 107Ohm.
Embodiment 1
The present embodiment can touch screen artificial leather, for a kind of half PU artificial leather, specifically, its preparation process includes following step It is rapid:
Step (1): the dual-purpose release paper of PU needed for selecting is 900- in the release recto even spread viscosity 1500CPS polyurethane slurry: polyurethane color compound coating thickness influences the depth of color in 3-15, the number of coating weight Shallow and surface physical property, polyurethane colour mixing slurry by weight ratio are as follows:
Polyurethane resin: 100 parts
Solvent: 100-110 parts
Levelling agent: 0.1-0.3 parts
Conductive auxiliary agent: 3 parts
Aging agent: 15 parts
Colorant: 1-10 parts;
Step (2): the coating thickness and post-processing temperature in coating polyurethane coloring mixing slurry are directly proportional.Coating thickness is resistance to It is directly proportional to grind physical property.
Note: the conductive auxiliary agent of selection is with can reduce resistance in (0.8- under the relative humidity of 20 DEG C of temperature, 65% 1.2)×107Ohm (i.e. 107Ohms) electric conductivity conductive auxiliary agent.
Step (3): will be coated with polyurethane has the release paper of mill base material poly- by 100 DEG C -135 of the obtained coloring of temperature drying Urethane surface layer film.
Step (4): prepared polyvinyl chloride pulp is coated on above-mentioned polyurethane cover.PVC Interlayer Formulation Coating thickness be 0.1-0.15mm or so.It is dried 2 minutes or so by 160 DEG C or so.Obtained PVC not foamed interlayer.
Interlayer Formulation is as follows:
PVC paste resin: 100 parts
Plasticizer: 75 parts
Aluminium silver medal: 8-10 parts
Conductive auxiliary agent: 3 parts
Stabilizer: 2 parts
Colorant: 5-10 parts;
Note: above-mentioned aluminum paste is that the general sudden strain of a muscle silver paste of leather industry is used to that pearly-lustre color is adjusted to use, because aluminum paste is metal material Material, the electric conductivity that the present invention is designed for for Reinforced PVC material.Conductive auxiliary agent described in formula is in polrvinyl chloride product In play the role of gently lowering plastic resistance, thus make electric current meet electric current needed for artificial leather wants touch screen (i.e. be no more than 0.15 The very faint electric current conduction of milliampere).
Step (5): the polyvinyl chloride foam layer slurry prepared being coated in above-mentioned polyvinyl chloride middle layer, and coating is dry Thickness is 0.25mm or so by 185 DEG C or so of blowing oven, is foamed to required multiplying power.The formula of polyvinyl chloride foam layer is such as Under:
PVC paste resin: 100 parts
Plasticizer: 80 parts
Filler material: 20 parts
Aluminium silver medal: 8-10 parts
Conductive auxiliary agent: 3 parts
Foaming stabiliser: 3 parts
Foaming agent: 4 parts
Colorant: 5 parts;
Step (6): coating thickness and electric conductivity in coating polyvinyl chloride are inversely proportional.It is coated with thicker touch screen effect more Difference.Table 1 disclose the present embodiment can touch screen artificial leather each layer of thickness and corresponding total resistance value.
Table 1
Step (7): by coating medium and base fabric, (base fabric needed for here need to use the base fabric with conductive fiber material, have (20 DEG C and when 65% relative humidity, resistance is 10 for good electric conductivity7Ω).Polyurethane resin or aqueous fitting are selected in fitting Material.The solvent or diluent that viscosity reduction is 6000-9000CPS to viscosity, can arrange in pairs or groups according to cost.It is spread evenly across using coating machine above-mentioned On the layer of PVC foam material, the foodstuff amount of coating medium controls the foodstuff amount in 90-130G/Y according to peel strength and feel, and selects Determine base fabric.The base fabric posted and release paper are entered baking oven together to dry at 135 DEG C.
Step (8): dry coating medium leather removed from release paper after wind.
Embodiment 2
The present embodiment can touch screen artificial leather, be a kind of PVC artificial leather, specifically, its preparation process the following steps are included:
Step (1): PVC release paper needed for selecting is 2000- in the release recto even spread viscosity Prepared polyvinyl chloride pulp is coated in above-mentioned release paper by 25000CPS polyvinyl chloride pulp.PVC surface layer formula Coating thickness be 0.1mm-0.15mm or so.It is dried 2 minutes or so by 160 degree or so.Obtained PVC does not foam surface layer.
The surface layer formula of Welvic is as follows:
PVC paste resin: 100 parts
Plasticizer: 68 parts
Aluminium silver medal: 8-10 parts
Conductive auxiliary agent: 3 parts
Stabilizer: 2 parts
Colorant: 5-10 parts;
Above-mentioned aluminum paste is the general sudden strain of a muscle silver paste of leather industry, for adjusting pearly-lustre color to use, because aluminum paste is metal material, It here is the electric conductivity for Reinforced PVC material.Conductive auxiliary agent described in formula is also to play in polrvinyl chloride product gently Shade the effect of low plastic resistance, and to meet electric current needed for artificial leather realizes touch screen, (required electric current is that correspondence is very faint Conduction electric current).
The coating thickness of surface layer formula is 0.10mm-.15mm or so (according to specific required feel and wear-resisting requirement come certainly Determine surface thickness).It is dried 2 minutes or so by 160 degree or so.Obtained PVC does not foam surface layer.
Step (2): the polyvinyl chloride foam layer slurry prepared is coated on above-mentioned polyvinyl chloride top, is coated with dry thickness It foams by 185 DEG C or so of blowing oven to required multiplying power for 0.25mm or so.The formula of polyvinyl chloride foam layer is such as Under:
PVC paste resin: 100 parts
Plasticizer: 75 parts
Filler material: 20 parts
Aluminium silver medal: 8-10 parts
Conductive auxiliary agent: 3 parts
Foaming stabiliser: 3 parts
Foaming agent: 4 parts
Colorant: 5 parts;
Step (3): coating thickness and electric conductivity in coating polyvinyl chloride are inversely proportional.It is coated with thicker touch screen effect more Difference.Table 2 disclose the present embodiment can touch screen artificial leather each layer of thickness and corresponding total resistance value.
Table 2
Step (4): by coating medium and base fabric (base fabric needed for here is had to the base fabric with conductive fiber material, With good electric conductivity, (20 DEG C and when 65% relative humidity, resistance is 103Ω).Polyurethane resin or aqueous is selected in fitting Coating medium.The solvent or diluent that viscosity reduction is 6000-9000CPS to viscosity, can arrange in pairs or groups according to cost.It is spread evenly across using coating machine On the layer of front PVC foam material, the foodstuff amount of coating medium is made according to salty press of intensity hand is increased in 90-130G/Y, and selected base fabric. The base fabric posted and release paper are entered baking oven together to dry at 135 DEG C.
Step (5): dry coating medium leather removed from release paper after winding can (can if you need to do aftertreatment products To send next process to process).
In conclusion it is provided by the invention can touch screen artificial leather have leather made integrally to obtain electric conductivity, and obtain Electric conductivity can form the medium of conduction weak current with human body, and then artificial leather is made to obtain touch screen functionality.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalents made by bright description are applied directly or indirectly in relevant technical field, are similarly included in this hair In bright scope of patent protection.

Claims (10)

1. one kind can touch screen artificial leather, including the surface layer and foaming layer set gradually, which is characterized in that
The surface layer is PU surface layer or PVC surface layer, and the PU surface layer includes that following parts by weight prepare raw material: polyurethane resin 95-105 parts, 100-110 parts of solvent, 0.1-0.3 parts of levelling agent, 2-4 parts of conductive auxiliary agent, 13-16 parts of aging agent and colorant 1- 10 parts;The PVC surface layer includes that following parts by weight prepare raw material: 95-105 parts of PVC paste resin, plasticizer 65-73 Part, 8-10 parts of aluminum paste, 2-4 parts of conductive auxiliary agent, 1-3 parts of stabilizer and 4-6 parts of colorant.
2. according to claim 1 can touch screen artificial leather, which is characterized in that the foaming layer includes the system of following parts by weight Standby raw material: 95-105 parts of PVC paste resin, 75-85 parts of plasticizer, 15-25 parts of filler material, 8-10 parts of aluminum paste, conduction help 2-4 parts of agent, 2-4 parts of foaming stabiliser, 3-5 parts of foaming agent and 4-6 parts of colorant.
3. according to claim 1 can touch screen artificial leather, which is characterized in that in the surface layer, the surface layer slurry of PU surface layer Viscosity be 900-1500CPS, with a thickness of 3-15;The viscosity of the surface layer slurry of PVC surface layer is 2000-25000CPS, thickness For 0.1-0.15mm.
4. according to claim 1 can touch screen artificial leather, which is characterized in that when the surface layer is PU surface layer, further include Interbed, the middle layer are set between surface layer and foaming layer, and the middle layer includes that following parts by weight prepare raw material: polychlorostyrene second Resin 95-105 parts of alkene paste, 70-80 parts of plasticizer, 8-10 parts of aluminum paste, 2-4 parts of conductive auxiliary agent, 1-3 parts of stabilizer and colorant 5- 10 parts.
5. according to claim 4 can touch screen artificial leather, which is characterized in that the middle layer with a thickness of 0.1- 0.15mm。
6. according to claim 1 or 2 can touch screen artificial leather, which is characterized in that foaming layer with a thickness of 0.15- 0.35mm。
7. according to claim 1 can touch screen artificial leather, which is characterized in that it further include base cloth layer, the material of the base cloth layer Matter is conductive fiber.
8. according to claim 1 can touch screen artificial leather, which is characterized in that it is described can the overall thickness of touch screen artificial leather be 0.8-1.17mm。
9. according to claim 1 can touch screen artificial leather, which is characterized in that the conductive auxiliary agent in PU surface layer or PVC surface layer Electric conductivity are as follows: under conditions of temperature is 20 DEG C and relative humidity is 65%, resistance be (0.8-1.2) × 107Ohm.
10. according to claim 1 can touch screen artificial leather, which is characterized in that it is described can touch screen artificial leather electric conductivity Are as follows: under conditions of temperature is 20 DEG C and relative humidity is 65%, resistance is (1.23-3.76) × 107Ohm.
CN201811548337.0A 2018-12-18 2018-12-18 One kind can touch screen artificial leather Pending CN109610186A (en)

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CN114188071A (en) * 2021-12-10 2022-03-15 洋紫荆油墨(中山)有限公司 Thermosetting conductive slurry and preparation method and application thereof
CN115179625A (en) * 2021-04-06 2022-10-14 南亚塑胶工业股份有限公司 Leather material and automobile instrument board composite structure

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CN105133364A (en) * 2015-10-22 2015-12-09 福建宝利特科技股份有限公司 Allochroic artificial leather and preparation method thereof
CN105603769A (en) * 2016-03-02 2016-05-25 福鼎市永大合成革有限公司 Synthetic leather for touch screen gloves and preparation method thereof
CN105951471A (en) * 2016-06-24 2016-09-21 万桦(常州)新材料科技有限公司 Manufacturing method of environment-friendly conductive touch screen material used for gloves
CN105951466A (en) * 2016-07-12 2016-09-21 合肥科天水性科技有限责任公司 Water-based screen-touch glove leather and preparation method thereof

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CN105133364A (en) * 2015-10-22 2015-12-09 福建宝利特科技股份有限公司 Allochroic artificial leather and preparation method thereof
CN105603769A (en) * 2016-03-02 2016-05-25 福鼎市永大合成革有限公司 Synthetic leather for touch screen gloves and preparation method thereof
CN105951471A (en) * 2016-06-24 2016-09-21 万桦(常州)新材料科技有限公司 Manufacturing method of environment-friendly conductive touch screen material used for gloves
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