CN109599597A - A kind of high current battery core and the power battery comprising the battery core - Google Patents

A kind of high current battery core and the power battery comprising the battery core Download PDF

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Publication number
CN109599597A
CN109599597A CN201710923326.5A CN201710923326A CN109599597A CN 109599597 A CN109599597 A CN 109599597A CN 201710923326 A CN201710923326 A CN 201710923326A CN 109599597 A CN109599597 A CN 109599597A
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CN
China
Prior art keywords
negative electrode
battery
battery core
current collector
negative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710923326.5A
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Chinese (zh)
Inventor
邢诗娜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hengdian Group DMEGC Magnetics Co Ltd
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Hengdian Group DMEGC Magnetics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hengdian Group DMEGC Magnetics Co Ltd filed Critical Hengdian Group DMEGC Magnetics Co Ltd
Priority to CN201710923326.5A priority Critical patent/CN109599597A/en
Publication of CN109599597A publication Critical patent/CN109599597A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of high current battery core and include the power battery of the battery core.The battery core includes: negative electrode tab, diaphragm and positive plate, and negative electrode tab and positive plate are separated by the diaphragm and wind to form battery core, and the negative electrode tab is integrated in one with negative electrode lug;In the deployed state, negative electrode slurry is coated in addition to the white space reserved along side on negative current collector;And the negative electrode slurry layer that coating zone is formed constitutes negative electrode tab with negative current collector, the negative current collector of white space is as negative electrode lug.In battery core of the invention, negative electrode lug and negative electrode tab are integrated, the stable structure after winding, without the tab that additionally accesses or weld come the problems such as connecting, avoid the failure welding as caused by welding process.Moreover, because increasing the contact area of cathode Yu steel shell metal, without connecting metal by welding, to be effectively improved high internal resistance phenomenon caused by rosin joint, the heavy-current discharge performance of power battery is improved, improves production qualification rate.

Description

A kind of high current battery core and the power battery comprising the battery core
Technical field
The invention belongs to technical field of lithium batteries, are related to a kind of battery core, more particularly to a kind of big electricity of 18650 power batteries Galvanic electricity core, power battery and manufacturing process.
Background technique
As the function of 18650 power batteries is increasing and perfect, user is also further frequent to the use of lithium battery, more More to need the lithium battery and charging current of larger capacity.How lithium battery is more rapidly full of to the important need as user It asks, and the emphasis of current lithium battery industry research and development.
Lithium battery electric core is formed by positive plate, negative electrode tab, membrane winding, and in the prior art, the both ends of negative electrode tab are set respectively There are tab and the outer tab of cathode in cathode, tab is welded with outer mode of the tab with steel shell Jing Guo spot welding of cathode in the cathode after winding It is connected together, since failure welding can be generated in welding process, rosin joint, high internal resistance phenomenon is caused, to influence the big electricity of battery Charge-discharge performance is flowed, and then leads to the reduction of battery production qualification rate, or even impact to security performance.
In order to reduce the internal resistance of lithium battery, reduces the polarization of inside battery, promote its charge-discharge performance, it is general in the prior art It is to increase the quantity of tab all over the method used.For winding-type lithium battery, pole can be increased by increasing core parallel connection quantity Ear quantity, but on the one hand this can reduce battery capacity, on the other hand reduce the preparation efficiency of battery.
105355983 A of CN discloses a kind of lithium ion battery cell and lithium ion battery, by positive plate, negative Multiple anode ears, multiple negative electrode lugs are arranged in sequence on pole piece respectively, and make positive plate multiple anode ears and negative electrode tab it is more A negative electrode lug forms tab iterative structure or the staggered structure of tab.This method can improve the high rate performance of battery, and It can be improved the consistency of battery core, be conducive to extend with modularization in groups.But it there is cumbersome, the meta position of multiple tabs Set the problem of being difficult to control and easily shifting.
Summary of the invention
For the above problem exists in the prior art, the present invention passes through the Nomenclature Composition and Structure of Complexes for improving lithium battery electric core negative electrode tab And the way of contact of battery core bottom and steel shell, rosin joint is generated when solving battery cathode ear and steel shell welding, causes high internal resistance The problem of phenomenon.
In the present invention, " the high current battery core " refers to: battery core of the invention is improved using battery made of the battery core Heavy-current discharge performance.
In order to achieve the above object, the invention adopts the following technical scheme:
In a first aspect, the present invention provides a kind of battery core, especially a kind of power battery core, comprising: negative electrode tab, diaphragm And positive plate, the negative electrode tab and the positive plate separate and wind to form battery core by the diaphragm;
Wherein, in the deployed state, on negative current collector in addition to the white space reserved along side, it is coated with cathode slurry Material;And the negative electrode slurry layer that coating zone is formed constitutes negative electrode tab, the negative current collector conduct of white space with negative current collector Negative electrode lug, i.e. negative electrode tab are integrated in one with negative electrode lug.
The present invention improves the high rate performance of product by the transformation to core strueture, process aspect, and 3C is put
Capacitance conservation rate can be improved 1% or so, meet the needs of large current density, and providing for lithium battery market needs It asks.
In the present invention, the battery core can be conventional batteries battery core, be also possible to electrical core of power battery.It is more suitable for 18650 battery battery cores are further preferably used as 18650 electrical core of power battery.
Preferably, the negative current collector is copper foil.
As the optimal technical scheme of battery core of the present invention, the white space is rectangle.
Preferably, the white space is in the side of the long side of negative current collector, and the white space is in negative current collector Width direction on shared ratio be 1:(8~20), such as 1:8,1:9,1:10,1:12,1:13,1:15,1:16,1:17, 1:18 or 1:20 etc., preferably 1:10.
Preferably, the coiling direction is the length direction of negative current collector.
Preferably, after winding, the negative electrode lug exposes to battery core sustained height.
Preferably, the negative electrode lug is located at the bottom of the battery core.
As the optimal technical scheme of battery core of the present invention, the positive plate by plus plate current-collecting body and be formed in it is described just Anode sizing agent layer on the collector of pole is constituted.
Preferably, the plus plate current-collecting body is aluminium foil.
Preferably, anode ear is connected on the positive plate.
As the further preferred technical solution of battery core of the present invention, the battery core includes negative electrode tab, diaphragm and anode Piece, the negative electrode tab are separated by the diaphragm with the positive plate and wind to be formed along the length direction of negative current collector copper foil Battery core;
Wherein, the positive plate is made of plus plate current-collecting body aluminium foil and the anode sizing agent layer being formed on the aluminium foil, institute It states and is connected with anode ear on positive plate and exposes to battery core;The negative electrode tab is integrated in one with negative electrode lug, and negative electrode lug exposes to Battery core sustained height;
In the deployed state, it is coated in addition to the rectangle white space along length side on negative current collector copper foil Negative electrode slurry;And the negative electrode slurry layer that coating zone is formed constitutes negative electrode tab, rectangle white space with negative current collector copper foil Negative current collector copper foil as negative electrode lug.
Second aspect, the present invention provide a kind of power battery, and the power battery includes battery case and is located at outside battery Battery core described in first aspect inside shell, and the negative electrode lug of battery core is contacted with outer casing bottom.
Preferably, the battery case is any one in steel shell or aluminum hull.
Power battery of the present invention can be 18650 power batteries, be also possible to other power electrics commonly used in the art Pond.
In the present invention, the manufacturing process of power battery is not especially limited, those skilled in the art are referred to existing Method disclosed in technology is manufactured.
Compared with the prior art, the invention has the following beneficial effects:
(1) the invention discloses a kind of battery core, especially a kind of power battery core, by the deployed state negative Pole collector leaves some space region as negative electrode lug along side, and prepares negative electrode tab in remaining position coating negative electrode slurry, then Negative electrode tab, diaphragm and positive plate are wound into battery core, negative electrode lug after winding can be made to expose to the battery core.Battery core of the invention Structure novel, negative electrode lug and negative electrode tab are integrated, the stable structure after winding, and the tab without additionally accessing or welding comes Connection avoids the failure welding as caused by welding process, the problems such as rosin joint and internal resistance are high.
(2) battery is prepared using battery core of the invention, when being assembled into shell, it is only necessary to convey the negative electrode lug of negative electrode tab one (i.e. The above-mentioned negative current collector for being left white region, for example it is left white the copper foil in region) contact steel shell bottom, avoid soldering polar ear band The problems such as rosin joint come, further, since the contact area of cathode Yu steel shell metal is increased, without connecting by welding Metal improves the heavy-current discharge performance of power battery to be effectively improved high internal resistance phenomenon caused by rosin joint, improves production Qualification rate.
Detailed description of the invention
Fig. 1 is the coating schematic diagram of negative electrode slurry on the negative current collector copper foil before winding, wherein 1 generation in embodiment 1 Coating zone on table negative current collector;2 represent white space namely the corresponding copper foil of white space.
Fig. 2 is the structural schematic diagram of the battery core wound, wherein 2 represent the corresponding copper of white space in embodiment 1 Foil, as negative electrode lug;3 represent anode ear.
Specific embodiment
To further illustrate the technical scheme of the present invention below with reference to the accompanying drawings and specific embodiments.
Embodiment 1
A kind of battery core and 18650 power batteries using the battery core are present embodiments provided, the battery core includes: cathode Piece, diaphragm and positive plate, the negative electrode tab and the positive plate are separated by the diaphragm and wind to form battery core, and feature exists In:
The negative electrode tab is integrated in one with negative electrode lug;
In the deployed state, negative electrode slurry is coated in addition to the white space reserved along side on negative current collector;And The negative electrode slurry layer and negative current collector that coating zone is formed constitute negative electrode tab, and the negative current collector of white space is as cathode Ear.
The preparation of battery core:
(1) negative electrode tab and negative electrode lug are integrated in one:
On negative current collector copper foil in addition to the white space reserved along length side, it is coated with negative electrode slurry (coating The region for having negative electrode slurry is coating zone), dry, the negative electrode slurry layer and copper foil that coating zone is formed constitute negative electrode tab, empty The corresponding copper foil of white region is as negative electrode lug;
Wherein, white space ratio shared in the width direction of copper foil is 1:10;
(2) above-mentioned negative electrode tab is separated and is wound by diaphragm with positive plate, form battery core, it is same that negative electrode lug exposes to battery core One height.
The preparation of 18650 power batteries:
Battery core is put into inside the steel shell of 18650 power batteries, and negative electrode lug is contacted with steel shell bottom, using routine techniques Assembling obtains 18650 power batteries.
Fig. 1 is the coating schematic diagram of negative electrode slurry on the negative current collector copper foil before winding, wherein 1 generation in the present embodiment Coating zone on table negative current collector;2 represent white space namely the corresponding copper foil of white space.
Fig. 2 is the structural schematic diagram of the battery core wound, wherein 2 represent the corresponding copper of white space in the present embodiment Foil, as negative electrode lug;3 represent anode ear.
Embodiment 2
In addition to white space ratio shared in the width direction of copper foil is 1:8, other content is same as Example 1.
Embodiment 3
In addition to white space ratio shared in the width direction of copper foil is 1:20, other content is same as Example 1.
Embodiment 4
In addition to white space ratio shared in the width direction of copper foil is 1:15, other content is same as Example 1.
Embodiment 5
In addition to steel shell is replaced with aluminum hull, other content is same as Example 1.
Comparative example 1
The difference of this comparative example 1 and embodiment 1 is only that following the description:
In lithium battery electric core preparation process, negative electrode slurry is fully coated on negative current collector, the cathode slurry after drying Material and negative current collector constitute negative electrode tab, and the both ends of negative electrode tab are respectively equipped with the outer tab of tab and cathode in cathode, after winding Tab welds together with outer mode of the tab with steel shell Jing Guo spot welding of cathode in cathode, due to that can generate welding in welding process It is bad, rosin joint, high internal resistance phenomenon are caused, to influence the high rate during charging-discharging of battery, and then causes battery production qualified Rate reduces, or even impacts to security performance.
18650 power batteries of this comparative example 1 are kept relative to the 3C discharge capacity of 18650 power batteries of embodiment 1 Rate has dropped 1% or so.
The Applicant declares that the present invention is explained by the above embodiments method detailed of the invention, but the present invention not office Be limited to above-mentioned method detailed, that is, do not mean that the invention must rely on the above detailed methods to implement.Technical field Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention Addition, selection of concrete mode etc., all of which fall within the scope of protection and disclosure of the present invention.

Claims (10)

1. a kind of battery core, comprising: negative electrode tab, diaphragm and positive plate, the negative electrode tab and the positive plate by the diaphragm every It opens and winds to form battery core, it is characterised in that:
In the deployed state, negative electrode slurry is coated in addition to the white space reserved along side on negative current collector;And it coats The negative electrode slurry layer and negative current collector that region is formed constitute negative electrode tab, and the negative current collector of white space is as negative electrode lug, i.e., Negative electrode tab is integrated in one with negative electrode lug.
2. battery core according to claim 1, which is characterized in that the battery core be 18650 battery battery cores, preferably 18650 Electrical core of power battery.
3. battery core according to claim 1 or 2, which is characterized in that the negative current collector is copper foil.
4. battery core according to claim 1-3, which is characterized in that the white space is rectangle.
5. battery core according to claim 1-4, which is characterized in that length of the white space in negative current collector The side on side, and white space ratio shared in the width direction of negative current collector is 1:(8~20), preferably 1:10;
Preferably, the coiling direction is the length direction of negative current collector.
6. battery core according to claim 1-5, which is characterized in that after winding, the negative electrode lug exposes to electricity Core sustained height;
Preferably, the negative electrode lug is located at the bottom of the battery core.
7. battery core according to claim 1-6, which is characterized in that the positive plate is by plus plate current-collecting body and formation It is constituted in the anode sizing agent layer on the plus plate current-collecting body;
Preferably, the plus plate current-collecting body is aluminium foil.
8. battery core according to claim 1-7, which is characterized in that be connected with anode ear on the positive plate.
9. a kind of power battery, which is characterized in that the power battery includes battery case and is located inside the battery case Such as the described in any item battery cores of claim 1-8, and the negative electrode lug of battery core is contacted with outer casing bottom.
10. power battery according to claim 9, which is characterized in that the battery case is times in steel shell or aluminum hull It anticipates one kind.
CN201710923326.5A 2017-09-30 2017-09-30 A kind of high current battery core and the power battery comprising the battery core Pending CN109599597A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110224109A (en) * 2019-05-23 2019-09-10 湖北锂诺新能源科技有限公司 Anode pole piece, cathode pole piece and battery core and lithium battery and preparation method thereof
CN114069113A (en) * 2021-12-08 2022-02-18 深圳聚锂能源有限公司 Button cell and preparation method thereof
CN114142105A (en) * 2021-10-18 2022-03-04 佛山(华南)新材料研究院 Winding battery cell, preparation method thereof and winding battery
CN114284572A (en) * 2021-12-31 2022-04-05 四川启睿克科技有限公司 Roll up core structure and lithium ion battery

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104953171A (en) * 2015-06-30 2015-09-30 深圳市博亿能科技有限公司 Lithium ion battery
CN207302884U (en) * 2017-09-13 2018-05-01 东莞凯德新能源有限公司 A kind of cylinder high-power lithium ion capacitor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104953171A (en) * 2015-06-30 2015-09-30 深圳市博亿能科技有限公司 Lithium ion battery
CN207302884U (en) * 2017-09-13 2018-05-01 东莞凯德新能源有限公司 A kind of cylinder high-power lithium ion capacitor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110224109A (en) * 2019-05-23 2019-09-10 湖北锂诺新能源科技有限公司 Anode pole piece, cathode pole piece and battery core and lithium battery and preparation method thereof
CN114142105A (en) * 2021-10-18 2022-03-04 佛山(华南)新材料研究院 Winding battery cell, preparation method thereof and winding battery
CN114069113A (en) * 2021-12-08 2022-02-18 深圳聚锂能源有限公司 Button cell and preparation method thereof
CN114284572A (en) * 2021-12-31 2022-04-05 四川启睿克科技有限公司 Roll up core structure and lithium ion battery

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