CN109599514A - A kind of uniform temperature type lithium battery - Google Patents

A kind of uniform temperature type lithium battery Download PDF

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Publication number
CN109599514A
CN109599514A CN201811221431.5A CN201811221431A CN109599514A CN 109599514 A CN109599514 A CN 109599514A CN 201811221431 A CN201811221431 A CN 201811221431A CN 109599514 A CN109599514 A CN 109599514A
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CN
China
Prior art keywords
partition
temperature
lithium battery
battery
accommodating chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811221431.5A
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Chinese (zh)
Inventor
曹超然
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Zhengxi Biaowang New Energy Co Ltd
Original Assignee
Anhui Zhengxi Biaowang New Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Zhengxi Biaowang New Energy Co Ltd filed Critical Anhui Zhengxi Biaowang New Energy Co Ltd
Priority to CN201811221431.5A priority Critical patent/CN109599514A/en
Publication of CN109599514A publication Critical patent/CN109599514A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/617Types of temperature control for achieving uniformity or desired distribution of temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/653Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • H01M10/6555Rods or plates arranged between the cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/657Means for temperature control structurally associated with the cells by electric or electromagnetic means
    • H01M10/6572Peltier elements or thermoelectric devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/659Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention discloses a kind of uniform temperature type lithium batteries, including shell, partition and upper cover, partition is installed on enclosure interior, partition is to be made from a material that be thermally conductive with shell, partition is multiple and is from left to right successively intervally arranged, appoint and forms the battery cavities for being placed with single battery monomer between two adjacent partitions, each battery inner cavity surface is covered with heat-conducting layer, the profiling chamber with lithium battery form fit is formed inside heat-conducting layer, each diaphragm internal is equipped with the accommodating chamber of opening upwards, solid-liquid phase change energy-accumulation material is filled in each accommodating chamber, upper cover is packaged in shell upper end, upper cover lower surface is equipped with the seal convexity for being sealed in accommodating chamber upper end;The present invention is used for thermally conductive partition by setting inside housings, and the temperature of enclosure interior is transmitted uniformly;It is absorbed by the phase transition process of energy storage materials of phase change or discharges a large amount of latent heat, the temperature of single battery monomer can be automatically adjusted, reduce the temperature difference between each battery cell.

Description

A kind of uniform temperature type lithium battery
Technical field
The invention belongs to technical field of lithium batteries, are specifically related to a kind of uniform temperature type lithium battery.
Background technique
Lithium battery is with voltage is high, light-weight, energy density is high, service life cycle is long, self discharge is low and memoryless effect The characteristics of answering, has captured rapidly the overwhelming majority in batteries of electric automobile market, and lithium battery can generate biggish in use Heat radiates improper the problem of will cause battery life decline or even burning, and brings to the use of lithium battery greatly safe hidden Suffer from;Currently, lithium battery device is mainly radiated by the way of Forced Air Convection heat transfer, due to the thermal coefficient of air Low, the defects of thermal capacitance is small, cause heat transfer coefficient small, radiating efficiency is low, and flowing of the air in cell apparatus unevenly will Influence the temperature consistency of cell apparatus.
Summary of the invention
In view of this, being used for the purpose of the present invention is to provide a kind of uniform temperature type lithium battery by being arranged inside housings Thermally conductive partition enables the temperature of enclosure interior to transmit uniformly;Also, absorbed by the phase transition process of energy storage materials of phase change or A large amount of latent heat is discharged, the temperature of single battery monomer can be automatically adjusted, reduces the temperature difference between each battery cell.
In order to achieve the above object, a kind of uniform temperature type lithium battery of the present invention, including shell, partition and upper cover, partition installation In enclosure interior, partition is to be made from a material that be thermally conductive with shell, and partition is multiple and is from left to right successively intervally arranged, Ren Xiang The battery cavities for being placed with single battery monomer are formed between two adjacent partitions, each battery inner cavity surface is covered with thermally conductive Layer, heat-conducting layer inside form the profiling chamber with lithium battery form fit, and each diaphragm internal is equipped with the accommodating chamber of opening upwards, often Solid-liquid phase change energy-accumulation material is filled in a accommodating chamber, upper cover is packaged in shell upper end, and upper cover lower surface is equipped with and is sealed in receiving The seal convexity of chamber upper end.
Further, the solid-liquid phase change energy-accumulation material is FTC self-temperature-adjusting phase change energy-accumulation material.
It further, further include semiconductor chilling plate, temperature sensor and PID controller, the housing bottom lower surface is set There is the first groove, the semiconductor chilling plate for promptly radiating is installed in the first groove, housing bottom upper surface is equipped with second Groove is equipped with the temperature sensor for temperature sensor in the second groove, the cold end that semiconductor chilling plate has and first recessed Rooved face contact, semiconductor chilling plate and temperature sensor are electrically connected with the PID controller for being located at hull outside respectively.
Further, the seal convexity is embedded in accommodating chamber upper end, and seal convexity surface is equipped with the rubber layer for sealing.
Further, the heat-conducting layer is thermally conductive gel coating.
The beneficial effects of the present invention are:
1. the temperature consistency that a kind of uniform temperature type lithium battery of the present invention can be improved enclosure interior;The temperature of each battery cell by with The partition of the neighbouring battery cell is transmitted, so that the uniformity of temperature profile of enclosure interior;Also, pass through phase-changing energy-storing The phase transition process of material absorbs or discharges a large amount of latent heat, can automatically adjust the temperature of single battery monomer, reduce each battery Temperature difference between monomer;In addition, being filled in each accommodating chamber since each diaphragm internal is equipped with the accommodating chamber of opening upwards Solid-liquid phase change energy-accumulation material, so that battery cell and solid-liquid phase change energy-accumulation material are as close to that is, heat transfer distance is small, energy It is enough to carry out temperature adjusting in time;On this basis, accommodating chamber upper end is sealed by seal convexity, avoids solid-liquid phase change Energy-accumulation material is converted to the leakage problem generated when liquid.
2. the service life that a kind of uniform temperature type lithium battery of the present invention is conducive to extend each battery cell;FTC self-temperature-adjusting phase change Energy-accumulation material produces saturated acid using new processes such as the critical extraction of plant, the distillation of vacuum refrigeration analysis layer, saponification, is become by chemistry Change, is grafted in macromolecular or filling takes small molecule, generate a kind of novel substance, which has larger potential heat value, to approach room temperature (18 DEG C, 24 DEG C) of temperature be transformation temperature, avoid the charge and discharge electro-temperature of each battery cell excessively high or too low, be conducive to extend each The service life of battery cell;Also, FTC self-temperature-adjusting phase change energy-accumulation material is environmentally protective, corrosion-free, pollution-free, free from extraneous odour, right Environment and human body are harmless.
3. a kind of uniform temperature type lithium battery of the present invention is conducive to further increase whole safety;When heat occurs in battery cell When out of control, temperature is excessively high and climbs comparatively fast, so that the temperature of enclosure interior has sharply raised trend, at this point, in shell The temperature change in portion sends PID controller to through temperature sensor, is compared with the temperature of setting, and resulting deviation of signal is logical PID mode adjustment processing is crossed, command signal is issued by PID controller, control semiconductor chilling plate carries out fast-refrigerating, so that shell The temperature in internal portion reduces rapidly, so as to avoid the chain reaction generated due to lithium battery thermal runaway.
Detailed description of the invention
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, the present invention provides following attached drawing and carries out Illustrate:
Fig. 1 is a kind of front section view of uniform temperature type lithium battery of the present invention;
Fig. 2 is the enlarged structure schematic diagram in Fig. 1 at A;
Fig. 3 is the top view of partition described in a kind of uniform temperature type lithium battery of the present invention.
Appended drawing reference: 1- shell;2- partition;3- upper cover;4- battery cell;5- heat-conducting layer;6- solid-liquid phase change accumulation of energy material Material;7- semiconductor chilling plate;8- temperature sensor;9-PID controller;21- accommodating chamber;31- seal convexity.
Specific embodiment
Below in conjunction with attached drawing, a preferred embodiment of the present invention will be described in detail.
As shown in Figure 1 to Figure 3;A kind of uniform temperature type lithium battery of the present invention, including shell 1, partition 2 and upper cover 3;Partition 2 is pacified Inside shell 1, partition 2 is to be made from a material that be thermally conductive with shell 1, and here, Heat Conduction Material uses metal material;Partition 2 Be it is multiple and be from left to right successively intervally arranged, form one between two partitions 2 of Ren Xianglin and be placed with single battery monomer 4 Battery cavities;Each battery inner cavity surface is covered with heat-conducting layer 5, and the profiling with lithium battery form fit is formed inside heat-conducting layer 5 Thermally conductive gel coating can be used in chamber, here, heat-conducting layer 5;The accommodating chamber 21 of opening upwards, each receiving are equipped with inside each partition 2 Solid-liquid phase change energy-accumulation material 6 is filled in chamber 21, upper cover 3 is packaged in 1 upper end of shell, and 3 lower surface of upper cover is equipped with and is sealed in receiving The seal convexity 31 of 21 upper end of chamber.
The temperature of each battery cell 4 with the partition 2 of the neighbouring battery cell 4 by being transmitted, so that inside shell 1 Uniformity of temperature profile;Also, it is absorbed by the phase transition process of energy storage materials of phase change or discharges a large amount of latent heat, can adjusted automatically The temperature for saving single battery monomer 4, reduces the temperature difference between each battery cell 4.
In addition, energy storage materials of phase change includes solid-liquid phase change energy-accumulation material 6 and solid-solid phase-change energy-accumulation material, wherein for For solid-solid phase-change energy-accumulation material, more than solid-solid phase-change temperature, when they become plastic crystals from crystalline solid, plasticity is brilliant There is biggish vapour pressure, mutability is that gas escapes, if using solid-solid phase-change energy-accumulation material, it is necessary to consider that gas escapes when body The problem of bring air pressure increases;And solid-liquid phase change energy-accumulation material 6 is only the mutual conversion between solid and liquid, no gas Evolution problem, therefore, present embodiment use solid-liquid phase change energy-accumulation material 6.
Preferably, solid-liquid phase change energy-accumulation material 6 is FTC self-temperature-adjusting phase change energy-accumulation material.The substance has larger latent heat Value, phase transition temperature point are (18 DEG C, 24 DEG C), and the charge and discharge electro-temperature that can be avoided each battery cell 4 is excessively high or too low, favorably In the service life for extending each battery cell 4;Also, FTC self-temperature-adjusting phase change energy-accumulation material is environmentally protective, corrosion-free, pollution-free, It is free from extraneous odour, harmless to environment and human body.
Preferably, present embodiment further includes semiconductor chilling plate 7, temperature sensor 8 and PID controller 9,1 bottom of shell Lower surface is equipped with the first groove, is equipped with the semiconductor chilling plate 7 for promptly radiating in the first groove, on 1 bottom of shell Surface is equipped with the second groove, and the temperature sensor 8 for temperature sensor is equipped in the second groove, and semiconductor chilling plate 7 has Cold end contacted with the first groove surfaces, semiconductor chilling plate 7 and temperature sensor 8 for incuding 1 temperature of shell respectively with PID controller 9 outside shell 1 is electrically connected.When thermal runaway occurs in percentage of batteries monomer 4, temperature is excessively high and climbs Comparatively fast, so that the temperature inside shell 1 has sharply raised trend, at this point, the temperature change inside shell 1 is through temperature sensing Device 8 sends PID controller 9 to, is compared with the temperature of setting, and resulting deviation of signal is handled by PID mode adjustment, by PID controller 9 issues command signal, and control semiconductor chilling plate 7 carries out fast-refrigerating, so that the temperature inside shell 1 is rapid It reduces, so as to avoid the generation due to lithium battery thermal runaway.It should be noted that present embodiment is by temperature change to lithium Battery thermal runaway is judged in advance, and is quickly reacted, and the safety of present embodiment is effectively increased.
Preferably, seal convexity 31 is embedded in 21 upper end of accommodating chamber, and 31 surface of seal convexity is equipped with the rubber for sealing Layer.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention and not to limit it, although logical It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be Various changes are made to it in form and in details, without departing from claims of the present invention limited range.

Claims (5)

1. a kind of uniform temperature type lithium battery, it is characterised in that: including shell, partition and upper cover, partition is installed on enclosure interior, partition Be to be made from a material that be thermally conductive with shell, partition be it is multiple and be from left to right successively intervally arranged, two partitions of Ren Xianglin it Between form the battery cavities for being placed with single battery monomer, each battery inner cavity surface is covered with heat-conducting layer, inside heat-conducting layer The profiling chamber with lithium battery form fit is formed, each diaphragm internal is equipped with the accommodating chamber of opening upwards, fills out in each accommodating chamber Filled with solid-liquid phase change energy-accumulation material, upper cover is packaged in shell upper end, and upper cover lower surface is equipped with the sealing for being sealed in accommodating chamber upper end Protrusion.
2. a kind of uniform temperature type lithium battery as described in claim 1, it is characterised in that: the solid-liquid phase change energy-accumulation material is FTC Self-temperature-adjusting phase change energy-accumulation material.
3. a kind of uniform temperature type lithium battery as described in claim 1, it is characterised in that: further include semiconductor chilling plate, temperature biography Sensor and PID controller, the housing bottom lower surface be equipped with the first groove, is equipped in the first groove for promptly radiating Semiconductor chilling plate, housing bottom upper surface are equipped with the second groove, and the temperature biography for temperature sensor is equipped in the second groove Sensor, the cold end that semiconductor chilling plate has are contacted with the first groove surfaces, semiconductor chilling plate and temperature sensor respectively with PID controller positioned at hull outside is electrically connected.
4. a kind of uniform temperature type lithium battery as claimed in any one of claims 1 to 3, it is characterised in that: the seal convexity insertion In accommodating chamber upper end, seal convexity surface is equipped with the rubber layer for sealing.
5. a kind of uniform temperature type lithium battery as claimed in any one of claims 1 to 3, it is characterised in that: the heat-conducting layer is thermally conductive Gel coating.
CN201811221431.5A 2018-10-19 2018-10-19 A kind of uniform temperature type lithium battery Pending CN109599514A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111864314A (en) * 2020-07-24 2020-10-30 苏州华骞时代新能源科技有限公司 Lithium cell group temperature equalization mechanism
CN115498328A (en) * 2022-11-07 2022-12-20 山东大学 Semi-open type battery thermal management device coupled with battery surface
CN118281419A (en) * 2024-05-31 2024-07-02 四川信息职业技术学院 Power battery phase change material temperature control box and temperature control method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014235803A (en) * 2013-05-31 2014-12-15 古河電池株式会社 Storage battery system
CN105518928A (en) * 2014-11-10 2016-04-20 深圳市大疆创新科技有限公司 Battery, heat management apparatus thereof and uav having battery
CN107302114A (en) * 2017-07-11 2017-10-27 浙江谷神能源科技股份有限公司 Lithium battery with heat alert device
CN107666025A (en) * 2016-07-27 2018-02-06 四川省同华科技有限公司 The heat management system of two temperature control
CN207651633U (en) * 2017-12-08 2018-07-24 南昌航空大学 A kind of heat management coupled system of dynamic lithium battery group
CN207705268U (en) * 2018-01-02 2018-08-07 重庆长安汽车股份有限公司 A kind of Vehicular dynamic battery module

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014235803A (en) * 2013-05-31 2014-12-15 古河電池株式会社 Storage battery system
CN105518928A (en) * 2014-11-10 2016-04-20 深圳市大疆创新科技有限公司 Battery, heat management apparatus thereof and uav having battery
CN107666025A (en) * 2016-07-27 2018-02-06 四川省同华科技有限公司 The heat management system of two temperature control
CN107302114A (en) * 2017-07-11 2017-10-27 浙江谷神能源科技股份有限公司 Lithium battery with heat alert device
CN207651633U (en) * 2017-12-08 2018-07-24 南昌航空大学 A kind of heat management coupled system of dynamic lithium battery group
CN207705268U (en) * 2018-01-02 2018-08-07 重庆长安汽车股份有限公司 A kind of Vehicular dynamic battery module

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111864314A (en) * 2020-07-24 2020-10-30 苏州华骞时代新能源科技有限公司 Lithium cell group temperature equalization mechanism
CN115498328A (en) * 2022-11-07 2022-12-20 山东大学 Semi-open type battery thermal management device coupled with battery surface
CN115498328B (en) * 2022-11-07 2024-05-31 山东大学 Semi-open battery thermal management device coupled with battery surface
CN118281419A (en) * 2024-05-31 2024-07-02 四川信息职业技术学院 Power battery phase change material temperature control box and temperature control method

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Application publication date: 20190409

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