CN109594961A - The flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir - Google Patents

The flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir Download PDF

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Publication number
CN109594961A
CN109594961A CN201910014160.4A CN201910014160A CN109594961A CN 109594961 A CN109594961 A CN 109594961A CN 201910014160 A CN201910014160 A CN 201910014160A CN 109594961 A CN109594961 A CN 109594961A
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Prior art keywords
oil reservoir
rosin milk
flammable
aqueous rosin
combustion
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CN201910014160.4A
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CN109594961B (en
Inventor
尹长海
马春宝
王德伟
姚长江
高玉军
贾财华
段效威
刘长环
桑雨
熊忠平
曲冬雪
周明旺
黄海礁
肖家宏
孙立超
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China Petroleum and Natural Gas Co Ltd
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China Petroleum and Natural Gas Co Ltd
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/243Combustion in situ
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/13Methods or devices for cementing, for plugging holes, crevices or the like
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Feeding And Controlling Fuel (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a kind of flammable plugging technologies of aqueous rosin milk water logging fireflood oil reservoir.The technique includes: the 1) solid content and hole condition according to aqueous rosin milk, and select aqueous rosin milk is 30-40% using solid content, adds 0.5-1% combustion adjuvant, spare;2) mixed liquor for obtaining step 1) injects stratum with injection device;3) it reinjects combustion-supporting envelope and alters agent;4) air is replaced to pit shaft liquid level to oil reservoir lower bound;5) electric ignition device, starting point firer's sequence are opened.The principle of the present invention are as follows: after aqueous rosin milk enters oil reservoir, rosin reduces formation pore throat by being adsorbed on rock surface, blocks up without dead, has certain closure anti-channeling to act on stratum, and after oil reservoir is lighted, rosin can be used as fuel supplement burning.It is subsequent to supplement oxidation combustion adjuvant and foaming agent, the effect of combustion-supporting and anti-channeling is assisted, realizes pollution-free uniform fireflood.

Description

The flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir
Technical field
The invention belongs to field use fields.More particularly to a kind of aqueous flammable closure work of rosin milk water logging fireflood oil reservoir Skill.
Background technique
Fireflood is exactly using the heavy component in in-place oil as fuel, using air or oxygen rich gas as combustion-supporting Agent takes the methods of spontaneous combustion and manual firing that reservoir temperature is made to reach crude oil burning point, and is continuously injected into combustion adjuvant, makes Crude Oil Sustained combustion, combustion reaction generates a large amount of heat, heated oil reservoir, so that reservoir temperature rises to 600~700 DEG C, heavy component It cracks at high temperature, the gas and water vapour of light oil, burning generation that gas, the heavy oil pyrolysis of injection generate are for driving Crude oil is flowed to producing well, and is produced from producing well.
It is that air onlap is serious that combustion in situ, which recovers the oil there are a significant deficiency, and top development degree is big, when exploitation enters Certain degree can cause has channeling, and especially own to develop oil reservoir, has channeling degree is bigger.
Current common ignition process causes fire floor position to employ unevenness, and the oil reservoir for being not suitable for fireflood generates coking waste, Subsequent developable resource is greatly reduced, the heavy crude reservoir of steam soak exploitation is carried out especially for oneself, coking waste is asked Topic is particularly acute.
Heavy oil wells envelope alter technical aspect mainly and have the particulate species such as traditional cements blocking agent, high temperature organogel, thermosetting resin, The types such as gel particle blocking agent, foam class water shutoff agent.The wherein particulate species such as traditional cements blocking agent there are partial sizes big, non-selectivity, The disadvantages of easily causing reservoir damage;High temperature organogel is on the high side;Thermosetting resin non-selectivity, curing rate are non-to temperature It is often sensitive, poor controllability;Gel particle blocking agent can not inject earth formation deep;Foam class water shutoff agent plugging strength is too low, stratum is suitable Answering property is poor.
Patent 201510909656.X discloses a kind of fireflood envelope and alters agent and preparation method thereof;Patent 201410592158.2 Disclose a kind of combustion in situ ignition method and device;Patent 201410592160.X discloses a kind of combustion in situ combustion-assistant ignition Method;Patent 201510887763.7 discloses a kind of regulating section of oil wells agent and its preparation and application;Patent 201611253606.1 Disclose a kind of sulfur-fixating combustion-promoting high temp profile control agent and the preparation method and application thereof;Patent 201610617729.2 disclose it is a kind of to The equipment of coal dust and the ignition method of combustion in situ are injected in oil reservoir;Patent 201410592183.0 discloses a kind of oil exploitation In profile control envelope alter method and device;Patent 201610116728.X discloses the tune in the has channeling channel of a kind of pair of fireflood gas injection well Cut open method and its tubing string;Patent 201510887763.7 discloses a kind of regulating section of oil wells agent and its preparation and application;Patent 201610454433.3 disclosing a kind of method of combustion in situ air foam profile control;Viscous crude fireflood profile control temporarily blocks up mechanism experiment and grinds Study carefully, " Inner Mongol petrochemical industry ", 1006-7981, (2011) 22-0154-03;Heavy crude reservoir fireflood injection-production well chemical regulation skill Art, " special reservoirs ", 2016,23 (5): 122-125;The research of thin interbed heavy crude reservoir fireflood development behavior control technique, " changes Work management ", 2014 (20): 118-118.
The fireflood reservoir profile method mentioned in above-mentioned patent and article, profile control envelope used, which alters agent, to burn, and exist In various degree the problem of pollution stratum, efficient resource is wasted, the raising of ultimate recovery is influenced.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of aqueous rosin milk water logging fireflood oil reservoir flammable closure Technique, is suitable for water logging heavy crude reservoir, and handling up near wellbore zone oil saturation lower (aqueous 95-98%) turns fireflood injection Well, making igniting, uniformly burning is abundant.
In order to achieve the goal above, the invention adopts the following technical scheme:
A kind of flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir, the technique include:
1) according to the solid content and hole condition of aqueous rosin milk, select rosin milk is 30-40% using solid content, then 0.5-1% combustion adjuvant is added, it is spare.
The present invention selects commercially available aqueous rosin milk, and rosin milk is rosin and its ester lotion, also known as dispersion rosin size, cream White slightly blue light liquid, relative density 1.06.Solid content 48%~50%, 0.1~0.2 μm of partial size.PH value 4.5~6.5 sticks Spend (25 DEG C) 200mPas.
2) mixed liquor for obtaining step 1) injects stratum with injection device;Preferably, injection rate is 30-50 tons.
3) it reinjects combustion-supporting envelope and alters agent;Preferably, it is the side 50-100 that the combustion-supporting envelope, which alters the injection rate of agent,.
4) air is replaced to pit shaft liquid level to oil reservoir lower bound.
5) electric ignition device, starting point firer's sequence are opened.
Present invention is generally directed to more round steam soak blocks, and water logging, formation depletion is serious, and oil saturation is lower (aqueous 95-98%), and have has channeling risk, it handles up and turns the injection well of fireflood, make igniting uniformly, burning sufficiently, improves point igneous Power.The principle of the present invention are as follows: after aqueous rosin milk enters oil reservoir, rosin reduces earth bore by being adsorbed on rock surface Larynx, is blocked up without dead, has certain closure anti-channeling to act on stratum, and after oil reservoir is lighted, rosin can be used as fuel supplement burning.It is subsequent Oxidation combustion adjuvant and foaming agent can also be supplemented, the effect of combustion-supporting and anti-channeling is assisted, realizes pollution-free uniform fireflood.
Preferably, the combustion adjuvant includes and is not limited to calper calcium peroxide, ammonium persulfate, calcium ammonium nitrate, ammonium nitrate, nitric acid The combination of one or more of the oxidants such as potassium, potassium permanganate, potassium hyperchlorate and manganese dioxide.
Preferably, when the solid content for emulsifying aqueous rosin milk when using solid content, is diluted with water to choosing higher than selected Fixed uses solid content.
Preferably, the combustion-supporting envelope is altered agent and is prepared by the following method: dodecyldimethylammonium hydroxide inner salt 40-50wt%, K-12 lauryl sodium sulfate 40-50wt%, ammonium persulfate 10-20wt%;Water is added to be formulated as the solution of 1-5%.Wherein 12 Alkyl dimethyl betaine and k-12 lauryl sodium sulfate are foaming agent, and ammonium persulfate is combustion adjuvant.
In a preferred embodiment of the invention, the combustion-supporting envelope is altered agent and is prepared by the following method: dimethyl Base glycine betaine 40wt%, k-12 lauryl sodium sulfate 40wt%, ammonium persulfate 20wt%;Water is added to be formulated as the solution of 1-5%.
Compared with the prior art, the present invention has the following beneficial effects:
(1) water base sealing agent can enter oil reservoir deep.
(2) combustion adjuvant is added, burning is abundant.
(3) combustion-supporting closure, double effects.
Specific embodiment
In order to illustrate more clearly of the present invention, below with reference to preferred embodiment, the present invention is described further.Ability Field technique personnel should be appreciated that following specifically described content is illustrative and be not restrictive, this should not be limited with this The protection scope of invention.
Embodiment 1:
Certain oilfield fireflood injection well, 25 wheels of handling up, water logging, aqueous 97%, data is shown, steam soak involves range oil-containing Saturation degree is low.For smooth ignition, implement following technique:
1, scheme tripping in electric ignition tool is pressed.
2,50 tons of aqueous rosin milk is selected, solid content 40% is mixed into 0.2 ton of ammonium persulfate, spare.
3, above-mentioned mixed liquor injection device is injected into stratum.Injection pressure 4.2MPa, injection rate 20m3/h。
4, it reinjects combustion-supporting envelope and alters agent (dodecyldimethylammonium hydroxide inner salt 40%, k-12 lauryl sodium sulfate 40%, mistake Ammonium sulfate 20%, weight percent, technical grade.Clear water prepares 1% solution) 100 sides.Injection pressure 4.0MPa, injection rate 20m3/h。
5, it is replaced with 5000 mark side's air, makes pit shaft liquid level to oil reservoir lower bound.Gas injection speed 9830Nm3/ d, gas injection Pressure 5.5MPa.
6, electric ignition device is opened, normal ignition process is started.The well designs 450 DEG C of firing temperature or more, and maximum is implemented Power 95KW, lights a fire 19 days by 478 DEG C of actual ignition temperature, gas injection speed 10412Nm3/ d, gas injection pressure 5.5-5.0- 6.0MPa。
7, the well is smoothly lighted, and has channeling does not occur for corresponding producing well, reaches construction purpose.
Obviously, the above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be pair The restriction of embodiments of the present invention may be used also on the basis of the above description for those of ordinary skill in the art To make other variations or changes in different ways, all embodiments can not be exhaustive here, it is all to belong to this hair The obvious changes or variations that bright technical solution is extended out are still in the scope of protection of the present invention.

Claims (7)

1. a kind of flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir, which is characterized in that the technique includes:
1) according to the solid content and hole condition of aqueous rosin milk, select aqueous rosin milk is 30-40% using solid content, then 0.5-1% combustion adjuvant is added, it is spare;
2) mixed liquor for obtaining step 1) injects stratum with injection device;
3) it reinjects combustion-supporting envelope and alters agent;
4) air is replaced to pit shaft liquid level to oil reservoir lower bound;
5) electric ignition device, starting point firer's sequence are opened.
2. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that described Combustion adjuvant includes and is not limited to calper calcium peroxide, ammonium persulfate, calcium ammonium nitrate, ammonium nitrate, potassium nitrate, potassium permanganate, potassium hyperchlorate With the combination of one or more of the oxidants such as manganese dioxide.
3. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that work as water Property rosin milk solid content be higher than it is selected using solid content when, be diluted with water to and selected use solid content.
4. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that described Combustion-supporting envelope is altered agent and is prepared by the following method: dodecyldimethylammonium hydroxide inner salt 40-50wt%, k-12 lauryl sodium sulfate 40-50wt%, ammonium persulfate 10-20wt%;Water is added to be formulated as the solution of 1-5%.
5. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that described Combustion-supporting envelope is altered agent and is prepared by the following method: dodecyldimethylammonium hydroxide inner salt 40wt%, k-12 lauryl sodium sulfate 40wt%, ammonium persulfate 20wt%;Water is added to be formulated as the solution of 1-5%.
6. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that step 2) 30-50 tons of the injection rate in.
7. the flammable plugging technology of aqueous rosin milk water logging fireflood oil reservoir according to claim 1, which is characterized in that described The injection rate that combustion-supporting envelope alters agent is the side 50-100.
CN201910014160.4A 2019-01-08 2019-01-08 Combustible plugging process for water-based rosin emulsion water flooding fire flooding oil reservoir Active CN109594961B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102071918A (en) * 2010-12-22 2011-05-25 中国石油天然气集团公司 Thick oil reservoir fire flooding oil extraction combustion-supporting ignition method
CN105696990A (en) * 2016-03-02 2016-06-22 中国石油天然气股份有限公司 Profile control method for gas channeling passage of fireflooding gas-injection well and pipe column for profile control method
CN106317315A (en) * 2015-06-26 2017-01-11 中国石油化工股份有限公司 Plugging agent for oil reservoir fracture plugging
US20170158947A1 (en) * 2015-12-08 2017-06-08 Chevron U.S.A. Inc. Methods for hydrocarbon recovery
CN106869886A (en) * 2017-02-03 2017-06-20 中国石油天然气股份有限公司 The oil production method of pre- air injection
CN108119092A (en) * 2017-12-01 2018-06-05 中国石油天然气股份有限公司 A kind of watered out reservoirs fireflood producing well selectively envelope alters agent and its application

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102071918A (en) * 2010-12-22 2011-05-25 中国石油天然气集团公司 Thick oil reservoir fire flooding oil extraction combustion-supporting ignition method
CN106317315A (en) * 2015-06-26 2017-01-11 中国石油化工股份有限公司 Plugging agent for oil reservoir fracture plugging
US20170158947A1 (en) * 2015-12-08 2017-06-08 Chevron U.S.A. Inc. Methods for hydrocarbon recovery
CN105696990A (en) * 2016-03-02 2016-06-22 中国石油天然气股份有限公司 Profile control method for gas channeling passage of fireflooding gas-injection well and pipe column for profile control method
CN106869886A (en) * 2017-02-03 2017-06-20 中国石油天然气股份有限公司 The oil production method of pre- air injection
CN108119092A (en) * 2017-12-01 2018-06-05 中国石油天然气股份有限公司 A kind of watered out reservoirs fireflood producing well selectively envelope alters agent and its application

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