CN109594415A - A kind of novel cation is without soap starch base phenylpropyl alcohol-rosin milk and preparation method - Google Patents
A kind of novel cation is without soap starch base phenylpropyl alcohol-rosin milk and preparation method Download PDFInfo
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- CN109594415A CN109594415A CN201811616322.3A CN201811616322A CN109594415A CN 109594415 A CN109594415 A CN 109594415A CN 201811616322 A CN201811616322 A CN 201811616322A CN 109594415 A CN109594415 A CN 109594415A
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- Prior art keywords
- parts
- rosin
- cation
- acrylic emulsion
- self
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
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Abstract
The invention discloses a kind of cation soap-free starch base phenylpropyl alcohol-rosin milks for corrugated paper top sizing, to make cationic styrene-acrylic emulsion and natural rosin by oneself as raw material, raw material sources are extensive, starch and rosin will be added in raw material, the cost of styrene-acrylic emulsion can be substantially reduced, overcome original styrene-acrylic emulsion high production cost, the problems such as polluting environment, wherein cation emulsion can voluntarily be adsorbed in negatively charged fiber surface, it only needs a small amount of or alumina is not added can be glued under near-neutral sulfite deinking, meet recycling economy development theory, to have good market prospects and economic value.
Description
Technical field
The present invention relates to a kind of cation soap-free starch base phenylpropyl alcohol-rosin milks for corrugated paper top sizing.
Belong to a kind of cation soap-free starch base phenylpropyl alcohol-rosin milk product for corrugated paper top sizing.It solves
Packaging Box poor water resistance during current express delivery, there is the problems such as pollution.
Background technique
It is exactly by Cypres and boiled surface currently, generalling use surface sizing technique in paper industry
Size-press starch mixing, the technical process that paper surface is glued by sizing applicator.
Styrene-acrylic emulsion surface sizing agent has good water-resistance, and film forming and latex film is functional, with paper
Fiber is tightly combined, and has good Surface Sizing Properties.But its higher cost, addition aluminum sulfate is also needed in Process of Applying Glue
Equal auxiliary agents can just play good effect, and the emulsifier in system has hydrophily, will affect its Surface Sizing Properties, remaining
Emulsifier also can cause environmental pollution.
Starch resource is abundant, cheap, has good stiffness and film forming, is a kind of height that natural green is degradable
Molecular compound is widely used in paper for surface sizing, but its water-resistance is not strong, insufficient with paper fibre binding force, knot
The defective tightness of conjunction.
Dispersion rosin size, it is to be modified with cationic agent to natural rosin, is then emulsified, or use cationic agent
It is modified to size emulsion, make it have hydrophily and positive charge feature.Cationic dispersion rosin size can voluntarily be adsorbed in negatively charged
The fiber surface of lotus only needs a small amount of alumina that can contain part calcium carbonate still in copy paper under near-neutral sulfite deinking, while in systems
It is able to maintain good sizing efficiency.
Based on the above issues, if being able to achieve the effect of three's unification, paper sizing performance had both been can satisfy, but also with valence
The cheap feature of lattice, at the same it is free from environmental pollution, meet contemporary environment protection requirement.Cation soap-free starch base phenylpropyl alcohol-rosin cream
Liquid development will have certain research significance.We have consulted related data document thus, and there is presently no the correlations of such lotion
Document report.
Summary of the invention
The object of the present invention is to provide a kind of cation soap-free styrene-acrylate-rosin milk for corrugated paper top sizing and
Preparation method.
Above-mentioned purpose is realized by following technical scheme: a kind of for a kind of sun for corrugated paper top sizing
Ion soap-free styrene-rosin milk, composition include: 30~40 parts of rosin, 5~8 parts of stearic acid, 5~8 parts of paraffin,
3~5 parts of cation colophony (self-control), 40~50 parts of cationic styrene-acrylic emulsion (self-control), 2-3 parts of peregal, 1~2 part
OP-10,4-6 parts of polyvinyl alcohol.The present invention with homemade cationic styrene-acrylic emulsion, rosin, stearic acid, paraffin be mainly at
Point, it is equipped with self-control cation colophony, peregal etc. and prepares cationic phenylpropyl alcohol-rosin milk.
Phenylpropyl alcohol-the rosin milk, is made of in parts by weight following raw materials: 35 parts of rosin, 6 parts of stearic acid,
6 parts of paraffin, 3.5 parts of cation colophony (self-control), 45 parts of cationic styrene-acrylic emulsion (self-control), 3 parts of peregal, 1 part
OP-10,4 parts of polyvinyl alcohol.
The corrugated paper sizing preparation method of lotion, this method comprises the following steps: will first calculate the rosin weighed, stone
Wax, stearic acid, cation colophony, peregal, are added in reactor, are heated to 90 DEG C, object to be mixed is at molten condition, system
Stirring is started when flowing back, and adjusts 300 turns/min of revolving speed, the ethyl alcohol being evaporated in original mixture, then by load weighted self-control
Cationic styrene-acrylic emulsion is slowly added in reactor after being heated to 80 DEG C, continues to stir 20min.1000 turns/min of revolving speed is improved,
The hot water and OP-10 for rapidly joining 90 DEG C carry out phase inversion, form the lotion of oil-in-water structure, continue after stirring 15min, reduce and turn
Speed is to 500 turns, after ice bath is cooled to 35 DEG C hereinafter, stirring 30min, filtering and discharging.
Beneficial effects of the present invention: products material is originated from natural material starch and rosin, is modified to it, graft copolymerization
Cationic styrene-acrylic emulsion substantially increases the water resistance of paper, tensile strength etc., while reducing emulsification using emulsifier-free emulsion polymerization
Influence of the agent to the pollution of environment and to paper water-resistance.Product Green environmental protection, it is safe and non-toxic, it, can to health of human body fanout free region
The advantages that Natural Degradation.
This work introduces DMC cationic monomer, can effectively be combined in Process of Applying Glue with paper fibre, helps without adding
Agent aluminum sulfate is stayed, the pollution to environment is reduced.Preparation process uses room temperature phase conversion method, and manufacturing equipment is simple, and technique easily carries out.
The environment protection water-based antirust agent that the present invention prepares has many advantages, such as preparation process simple, beautiful decoration, environmental-friendly.
The present invention is that had after being added water and stirred construction drying using active peat, river sand, talcum powder, rubber powder, cellulose etc.
There are certain water resistance, aesthetics, adsorptivity and bioactivity.Wall is applied to by brushing, spraying, roller coating and special construction mode
Body surface face has the characteristics that decoration, protection, environmental protection, absorption pollutant after dry.
Subject cationic is formed without soap starch base phenylpropyl alcohol-rosin milk raw material, have safety and environmental protection, production it is simple,
The advantages that low in cost, environmentally protective.
Specific embodiment
Embodiment 1: a kind of cation soap-free starch base phenylpropyl alcohol-rosin milk for corrugated paper top sizing, group
At include: 30~40 parts of rosin, 5~8 parts of stearic acid, 5~8 parts of paraffin, 3~5 parts of cation colophony (self-control),
40~50 parts of cationic styrene-acrylic emulsion (self-control), 2-3 parts of peregal, 1~2 part of OP-10,4-6 part polyvinyl alcohol.
Embodiment 2: it according to cation soap-free starch base phenylpropyl alcohol-rosin milk described in embodiment 1, is pressed by following raw materials
Parts by weight composition: 35 parts of rosin, 6 parts of stearic acid, 6 parts of paraffin, 3.5 parts of cation colophony (self-control), 45 parts
Cationic styrene-acrylic emulsion (self-control), 3 parts of peregal, 1 part of OP-10,4 parts of polyvinyl alcohol.
Embodiment 3: it according to cation soap-free starch base phenylpropyl alcohol-rosin milk described in embodiment 1, is diluted with water 1:10
Glue application solution afterwards is equably applied to paper surface with sizing stick, carries out top sizing to paper.
Embodiment 4: production method according to the following steps: first will calculate weigh rosin, paraffin, stearic acid, cation colophony,
Peregal is added in reactor, is heated to 90 DEG C, and object to be mixed starts stirring at molten condition, when system flows back, and is adjusted
300 turns/min of revolving speed is saved, the ethyl alcohol being evaporated in original mixture is heated to then by load weighted self-control cationic styrene-acrylic emulsion
It is slowly added in reactor after 80 DEG C, continues to stir 20min.Improve 1000 turns/min of revolving speed, rapidly join 90 DEG C hot water and
OP-10 carries out phase inversion, forms the lotion of oil-in-water structure, continues after stirring 15min, reduces revolving speed to 500 turns, ice bath is cooled to
After 35 DEG C hereinafter, stir 30min, filtering and discharging.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (3)
1. a kind of cation soap-free starch base phenylpropyl alcohol-rosin milk for corrugated paper top sizing, composition includes: under
Raw material is stated to form in parts by weight: 30~40 parts of rosin, 5~8 parts of stearic acid, 5~8 parts of paraffin, 3~5 parts sun from
Sub- rosin (self-control), 40~50 parts of cationic styrene-acrylic emulsion (self-control), 2-3 parts of peregal, 1~2 part of OP-10,4-6 part
Polyvinyl alcohol；The present invention using homemade cationic styrene-acrylic emulsion, rosin, stearic acid, paraffin as main component, be equipped with self-control sun from
Sub- rosin, peregal etc. prepare cationic starch base phenylpropyl alcohol-rosin milk.
2. cation soap-free starch base phenylpropyl alcohol-rosin milk of corrugated paper top sizing according to claim 1, feature
It is: is made of in parts by weight following raw materials: 35 parts of rosin, 6 parts of stearic acid, 6 parts of paraffin, 3.5 parts of cation pine
Fragrant (self-control), 45 parts of cationic styrene-acrylic emulsion (self-control), 3 parts of peregal, 1 part of OP-10,4 parts of polyvinyl alcohol.
3. the cation soap-free styrene-acrylate of corrugated paper top sizing described according to claim 1-one of 2-rosin milk preparation
Method, it is characterized in that: this method comprises the following steps: first will calculate weigh rosin, paraffin, stearic acid, cation colophony,
Peregal is added in reactor, is heated to 90 DEG C, and object to be mixed starts stirring at molten condition, when system flows back, and is adjusted
300 turns/min of revolving speed is saved, the ethyl alcohol being evaporated in original mixture is heated to then by load weighted self-control cationic styrene-acrylic emulsion
Be slowly added in reactor after 80 DEG C, continue stir 20min, improve 1000 turns/min of revolving speed, rapidly join 90 DEG C hot water and
OP-10 carries out phase inversion, forms the lotion of oil-in-water structure, continues after stirring 15min, reduces revolving speed to 500 turns, ice bath is cooled to
After 35 DEG C hereinafter, stir 30min, filtering and discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811616322.3A CN109594415A (en) | 2018-12-28 | 2018-12-28 | A kind of novel cation is without soap starch base phenylpropyl alcohol-rosin milk and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811616322.3A CN109594415A (en) | 2018-12-28 | 2018-12-28 | A kind of novel cation is without soap starch base phenylpropyl alcohol-rosin milk and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109594415A true CN109594415A (en) | 2019-04-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811616322.3A Pending CN109594415A (en) | 2018-12-28 | 2018-12-28 | A kind of novel cation is without soap starch base phenylpropyl alcohol-rosin milk and preparation method |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1184185A (en) * | 1997-12-03 | 1998-06-10 | 中国科学院广州化学研究所 | preparation of sizing synergist |
| JP2003155690A (en) * | 2001-11-19 | 2003-05-30 | Japan Pmc Corp | Rosin-based emulsion composition, method for sizing paper and paper |
| CN103469684A (en) * | 2012-06-09 | 2013-12-25 | 江苏五洲纸业有限公司 | Method for producing modified rosin sizing agent |
-
2018
- 2018-12-28 CN CN201811616322.3A patent/CN109594415A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1184185A (en) * | 1997-12-03 | 1998-06-10 | 中国科学院广州化学研究所 | preparation of sizing synergist |
| JP2003155690A (en) * | 2001-11-19 | 2003-05-30 | Japan Pmc Corp | Rosin-based emulsion composition, method for sizing paper and paper |
| CN103469684A (en) * | 2012-06-09 | 2013-12-25 | 江苏五洲纸业有限公司 | Method for producing modified rosin sizing agent |
Non-Patent Citations (5)
| Title |
|---|
| 付小龙等: "淀粉接枝苯丙无皂共聚物乳液的制备与表征", 《中国造纸学报》 * |
| 吴宗华等: "阳离子型苯丙乳液与阳离子分散松香施胶剂的协同作用", 《造纸化学品》 * |
| 安郁琴等（主编）: "《制浆造纸助剂》", 31 May 2003, 中国轻工业出版社 * |
| 纪培红: "改性松香丙烯酸酯表面施胶剂对纸张性能的影响", 《中华纸业》 * |
| 纪培红等: "阳离子松香乳液的制备及其施胶性能", 《造纸科学与技术》 * |
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Application publication date: 20190409 |