CN109594369A - A kind of quick upper dyeing method of superfine fibre suede - Google Patents

A kind of quick upper dyeing method of superfine fibre suede Download PDF

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Publication number
CN109594369A
CN109594369A CN201811407521.3A CN201811407521A CN109594369A CN 109594369 A CN109594369 A CN 109594369A CN 201811407521 A CN201811407521 A CN 201811407521A CN 109594369 A CN109594369 A CN 109594369A
Authority
CN
China
Prior art keywords
treatment fluid
dyeing
parts
suede
superfine fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811407521.3A
Other languages
Chinese (zh)
Inventor
胡忠杰
韩芹
张其斌
孙向浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI HUAFON MICREOFIBRE TECHNOLOGY Co Ltd
Original Assignee
SHANGHAI HUAFON MICREOFIBRE TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI HUAFON MICREOFIBRE TECHNOLOGY Co Ltd filed Critical SHANGHAI HUAFON MICREOFIBRE TECHNOLOGY Co Ltd
Priority to CN201811407521.3A priority Critical patent/CN109594369A/en
Publication of CN109594369A publication Critical patent/CN109594369A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/002Locally enhancing dye affinity of a textile material by chemical means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes

Abstract

The invention discloses a kind of quick upper dyeing methods of superfine fibre suede, include the following steps: to immerse superfine fiber chemical leather in treatment fluid, pad, dry after padding, the woven fabric suede after drying is dyed;The treatment fluid includes the component of following parts by weight: 8-20 parts of aqueous polyurethane, 0.3-0.5 parts of dispersing agent, 0.5-1.5 parts of anti-settling agent, 0.2-1 parts of defoaming agent, 100 parts of deionized water.The present invention is since aqueous polyurethane particle enters in the gap of superfine fibre, and uniformly, dye level, color homogeneity and dry fastness, fastness to wet rubbing all increase upper dye in subsequent dyeing.The present invention solves in superfine fibre suede normal dyeing in the prior art the problem of fastness to wet rubbing is low, dyeing dyeing defect, dark color easily fades.

Description

A kind of quick upper dyeing method of superfine fibre suede
Technical field
The present invention relates to the quick upper dyeing methods of superfine fibre suede.
Background technique
Superfine fiber chemical leather is the third generation rtificial leather after PVC, PU, it is to use and the island natural leather Zhong Ding Similar 6 superfine fibre of polyamide fibre of the structure and performance of collagenous fibres, is made the high-density non-woven fabrics with tridimensional network, then The excellent polyurethane with open type microcellular structure of filling capacity, made of being handled through post-processing.This synthetic leather is super with island is determined The intrinsic hygroscopicity of thin collagenous fibres natural leather.Thus, it is either special from internal microstructure or appearance tactile impression, physics Property and snugness of fit etc., can compare favourably with advanced natural leather.In addition, superfine fiber chemical leather is in chemically-resistant Property, mass uniformity, production and processing adaptability and waterproof anti-mildew etc. be better than natural leather, to make case Packet, clothes, shoes and automobile interior decoration etc. have vast potential for future development.
Superfine fiber chemical leather is made of 6 fiber of ultra-fine nylon and polyurethane two parts.Polyamide fibre 6 is polyamide structure, point Containing end amido in minor structure, can be dyed by acid dyes, neutral dye and reactive dye for wool.But 6 fiber of ultra-fine nylon Thinner than general fibre more, large specific surface area, so there are a series of problems in dyeing, as dyeing rate is too fast, colour rendering Difference and dyefastness difference etc..The primary chemical composition of polyurethane is polyurethanes, it is by soft chain segment and hard segment group At block copolymer.Using acid dyeing, the dyefastness of product is poor, and using neutral dyeing, there is a huge sum of moneys The problem of belonging to (such as Co, Cr) pollution.
Summary of the invention
The object of the present invention is to provide a kind of quick upper dyeing methods of superfine fibre suede, to overcome the prior art to exist Defect.
Method of the invention, includes the following steps:
Superfine fiber chemical leather is immersed in treatment fluid, is padded, the liquid carrying rate of super fiber leather is 50%~70%;It is dried after padding It is dry, the woven fabric suede after drying is subjected to normal dyeing.
The treatment fluid includes the component of following parts by weight:
The preparation method is as follows:
It by dispersing agent, anti-settling agent, defoaming agent, is slowly added in deionized water and is uniformly mixed under high speed dispersion, then will Aqueous polyurethane, which is added thereto, tells emulsification, obtains the treatment fluid;
The aqueous polyurethane is selected from Dongguan meter Ren Zhan Chemical Co., Ltd., and the trade mark is the product of MR-705.
The anti-settling agent is surfactant solution, is selected from Guangzhou Yan Gu trade Co., Ltd, trade mark KYC-426 Product;
The dispersing agent is the copolymer of the affinity groups containing pigment, is selected from Guangzhou Yan Gu trade Co., Ltd, the trade mark For the product of KYC-9166;
The defoaming agent is non-silicon high molecular polymer, is selected from Guangzhou Yan Gu trade Co., Ltd, trade mark KYC- 750 product;
The preparation method of the superfine fibre suede, woven fabric suede common staining method, for details, reference can be made to documents: Qu Jianbo, synthetic leather material and technology [M], Beijing, Chemical Industry Press, 2015.9;
The present invention is compared with traditional people's colouring method, since aqueous polyurethane particle enters the gap of superfine fibre In, uniformly, dye level, color homogeneity and dry fastness, fastness to wet rubbing are all mentioned upper dye in subsequent dyeing It is high.The present invention solves in superfine fibre suede normal dyeing in the prior art that fastness to wet rubbing is low, dyes dyeing defect, dark The problem of easily fading.
Specific embodiment
Present invention is further described in detail With reference to embodiment, it should be appreciated that these embodiments are only used for Illustrate the present invention rather than limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, this Field technical staff can make various changes and modification to the present invention, these equivalences equally fall within the application the appended claims Limited range.
Embodiment 1
Superfine fiber chemical leather is immersed in treatment fluid, is padded, the liquid carrying rate of super fiber leather is 50%;It is dried after padding, it will Woven fabric suede after drying carries out normal dyeing.
The treatment fluid includes the component of following parts by weight:
The preparation method is as follows:
It by dispersing agent, anti-settling agent, defoaming agent, is slowly added in deionized water and is uniformly mixed under high speed dispersion, then will Aqueous polyurethane, which is added thereto, tells emulsification, obtains the treatment fluid;
The color fastness xerotripsis of obtained super fiber leather >=3-4 grades, wet rubbing >=2-3 grades.
Embodiment 2
Superfine fiber chemical leather is immersed in treatment fluid, is padded, the liquid carrying rate of super fiber leather is 70%;It is dried after padding, it will Woven fabric suede after drying carries out normal dyeing.
The treatment fluid includes the component of following parts by weight:
The preparation method is as follows:
It by dispersing agent, anti-settling agent, defoaming agent, is slowly added in deionized water and is uniformly mixed under high speed dispersion, then will Aqueous polyurethane, which is added thereto, tells emulsification, obtains the treatment fluid;
Color fastness xerotripsis >=5 grade of obtained super fiber leather, wet rubbing >=3-4 grades.
Embodiment 3
Superfine fiber chemical leather is immersed in treatment fluid, is padded, the liquid carrying rate of super fiber leather is 60%;It is dried after padding, it will Woven fabric suede after drying carries out normal dyeing.
The treatment fluid includes the component of following parts by weight:
The preparation method is as follows:
It by dispersing agent, anti-settling agent, defoaming agent, is slowly added in deionized water and is uniformly mixed under high speed dispersion, then will Aqueous polyurethane, which is added thereto, tells emulsification, obtains the treatment fluid;
Color fastness xerotripsis >=4 grade of obtained super fiber leather, wet rubbing >=3 grade.

Claims (5)

1. a kind of quick upper dyeing method of superfine fibre suede, which comprises the steps of:
Superfine fiber chemical leather is immersed in treatment fluid, pads, is dried after padding, the woven fabric suede after drying is contaminated Color;
The treatment fluid includes the component of following parts by weight:
2. the method according to claim 1, wherein treatment fluid the preparation method is as follows:
Dispersing agent, anti-settling agent and defoaming agent are added in deionized water and are uniformly mixed, then aqueous polyurethane is added thereto cream Change, obtains the treatment fluid.
3. method according to claim 1 or 2, which is characterized in that it is MR-705 that the aqueous polyurethane, which is selected from the trade mark, Product.
4. method according to claim 1 or 2, which is characterized in that the anti-settling agent is surfactant solution, described Dispersing agent be the affinity groups containing pigment copolymer, the defoaming agent be non-silicon high molecular polymer.
5. method according to claim 1 or 2, which is characterized in that the liquid carrying rate of super fiber leather is 50%~70%.
CN201811407521.3A 2018-11-23 2018-11-23 A kind of quick upper dyeing method of superfine fibre suede Pending CN109594369A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811407521.3A CN109594369A (en) 2018-11-23 2018-11-23 A kind of quick upper dyeing method of superfine fibre suede

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811407521.3A CN109594369A (en) 2018-11-23 2018-11-23 A kind of quick upper dyeing method of superfine fibre suede

Publications (1)

Publication Number Publication Date
CN109594369A true CN109594369A (en) 2019-04-09

Family

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Family Applications (1)

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CN201811407521.3A Pending CN109594369A (en) 2018-11-23 2018-11-23 A kind of quick upper dyeing method of superfine fibre suede

Country Status (1)

Country Link
CN (1) CN109594369A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368340A (en) * 2008-10-14 2009-02-18 陕西科技大学 Final finishing technique for superfine fibre chemical leather
CN103451962A (en) * 2013-08-28 2013-12-18 山东丝绸纺织职业学院 Unstable island type PA6/PU suede superfine fiber synthetic leather pad-dyeing process by using vat dye
CN102817243B (en) * 2012-09-07 2014-08-13 上海华峰超纤材料股份有限公司 Conductive polyurethane superfine fiber suede leather and preparing method thereof
CN104499299A (en) * 2014-12-18 2015-04-08 陕西科技大学 Surface treatment color fixing method for suede type superfine fiber synthetic leather
CN103421158B (en) * 2013-08-06 2015-07-29 陕西科技大学 A kind of preparation method and application's method of the fixing and hyperchromicity agent for superfine fiber chemical leather dyeing
CN105401451A (en) * 2015-12-24 2016-03-16 福建隆上超纤有限公司 Production method of high-performance suede superfine fiber synthetic leather for clothing
CN108360187A (en) * 2018-04-28 2018-08-03 四川大学 A kind of colouring method of terylene type superfine fiber chemical leather

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368340A (en) * 2008-10-14 2009-02-18 陕西科技大学 Final finishing technique for superfine fibre chemical leather
CN102817243B (en) * 2012-09-07 2014-08-13 上海华峰超纤材料股份有限公司 Conductive polyurethane superfine fiber suede leather and preparing method thereof
CN103421158B (en) * 2013-08-06 2015-07-29 陕西科技大学 A kind of preparation method and application's method of the fixing and hyperchromicity agent for superfine fiber chemical leather dyeing
CN103451962A (en) * 2013-08-28 2013-12-18 山东丝绸纺织职业学院 Unstable island type PA6/PU suede superfine fiber synthetic leather pad-dyeing process by using vat dye
CN104499299A (en) * 2014-12-18 2015-04-08 陕西科技大学 Surface treatment color fixing method for suede type superfine fiber synthetic leather
CN105401451A (en) * 2015-12-24 2016-03-16 福建隆上超纤有限公司 Production method of high-performance suede superfine fiber synthetic leather for clothing
CN108360187A (en) * 2018-04-28 2018-08-03 四川大学 A kind of colouring method of terylene type superfine fiber chemical leather

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
于晓成等: "《提高不定岛型海岛纤维合成革摩擦色牢度方法讨论》", 《中国皮革》 *
姜怀: "《生态纺织的构建与评价》", 30 November 2005, 东华大学出版社 *
宋兵等: "《超细纤维合成革的染色性能及研究进展》", 《中国皮革》 *
强涛涛: "《合成革化学品》", 31 July 2016, 中国轻工业出版社 *
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Application publication date: 20190409