CN109593447A - Vehicle aqueous Lacquer finish polishes and preparation method thereof - Google Patents
Vehicle aqueous Lacquer finish polishes and preparation method thereof Download PDFInfo
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- CN109593447A CN109593447A CN201811395220.3A CN201811395220A CN109593447A CN 109593447 A CN109593447 A CN 109593447A CN 201811395220 A CN201811395220 A CN 201811395220A CN 109593447 A CN109593447 A CN 109593447A
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- parts
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- resin
- lacquer finish
- aqueous lacquer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
This application provides a kind of vehicle aqueous Lacquer finish polishes and preparation method thereof, vehicle with aqueous Lacquer finish polishes according to the mass fraction, including following material component: resin: 15-25 parts of water-borne acrylic acid modified polyester resin, 5-10 parts of aqueous alkide resin, 3-5 parts of water-based fluorocarbon resin, Amino resin 5-7 parts of part, 5-7 parts of high imino group Amino resin；Auxiliary agent: 1.5-3 parts of pH adjusting agent, 0.5-1 parts of defoaming agent, 8-15 parts of coalescing agent, 0.2-1 parts of wetting agent, 0.2-1 parts of levelling agent, 25-35 parts of deionized water.The aqueous Lacquer finish polishes of the application preparation has the following characteristics that the ply adhesion with priming paint is good, recoatability is strong, weatherability is strong, stain resistance is strong.
Description
Technical field
The application belongs to technical field of coatings, and in particular to a kind of vehicle aqueous Lacquer finish polishes and preparation method thereof.
Background technique
Aqueous bicycle paint is the product that current bicycle trade updates, and has very vast potential for future development.From
The Water-borne modification process of driving coating is gradually carried out from priming paint to finishing coat.Early in developed countries such as the 60's of last century Europe, the United States
It has just taken the lead in using aqueous vehicle base paint special.Priming paint existing 90% or more uses water paint, the painting of 88% bicycle at present
Material has also used Water-borne modification technology, and wherein more than 65%, Lacquer finish polishes is also being studied for the application of aqueous metallic basecoat
In kind, industrial applications are less.Existing market paint 85% is oil paint.In view of environmental protection and national policy, many producers are
Through developing sealing wax, but because of price and application property, there are no large-scale applications for sealing wax at present.As Environmental is protected
The attention degree of shield is higher and higher, and " oil turns water " has become inexorable trend.
The generally existing ply adhesion with priming paint of the automobile-used aqueous Lacquer finish polishes of electrical salf-walking currently on the market is poor, again
The defects of painting property is poor, weatherability is poor, stain resistance is poor.
Summary of the invention
To be overcome the problems, such as present in the relevant technologies at least to a certain extent, this application provides a kind of vehicle water
Property Lacquer finish polishes and preparation method thereof.
According to the embodiment of the present application in a first aspect, this application provides a kind of aqueous Lacquer finish polishes of vehicle, by quality
Number meter comprising following material component:
Resin: 15-25 parts of water-borne acrylic acid modified polyester resin, 5-10 parts of aqueous alkide resin, water-based fluorocarbon resin 3-
5 parts, Amino resin 5-7 parts of part, 5-7 parts of high imino group Amino resin；
Auxiliary agent: 1.5-3 parts of pH adjusting agent, 0.5-1 parts of defoaming agent, 8-15 parts of coalescing agent, 0.2-1 parts of wetting agent, levelling
0.2-1 parts of agent, 25-35 parts of deionized water.
Wherein, water-borne acrylic acid modified polyester resin is main film forming substance, aqueous alkide resin and water-based fluorocarbon resin
For functional film forming matter.
Further, the pH adjusting agent uses dimethylethanolamine, so that vehicle is compared with the pH of aqueous Lacquer finish polishes
Stablize.
Further, the defoaming agent uses the mixture function of hydrophobic solid and brokenly bubble polymer without organosilicon
Energy paint antifoaming agent, such as the defoaming agent BYK-011 of Bi Ke chemistry.Since defoaming agent BYK-011 is free of organosilicon, mine is also free of
Object oil, therefore can be used to abolish ultrafiltrate foam.
Further, the coalescing agent uses propandiol butyl ether and butyl.Propandiol butyl ether is to aqueous tree
Resin system has extremely strong solvability, and toxicity is extremely low, is the cosolvent of current safety and environmental protection.Propandiol butyl ether collocation one
The risk of coating high-temp baking blistering can be effectively reduced in quantitative high boiling butyl.Propandiol butyl ether and diethyl
Glycol butyl ether is used in mixed way with the ratio of 3:8-1:1.
Further, the wetting agent and levelling agent are all made of acrylic polymer, such as France's first wound chemistry
The BYK-381 of PW336 and Bi Ke chemistry.The PW336 that France first creates chemistry can be used for most of common water-base resin systems,
It is with following key property: improving levelling and flowing, improves gloss of film, elimination shrinkage cavity and flake, reduces tangerine peel and needle
Hole does not influence ply adhesion, with defoaming and deaeration effect, the wetability for improving ground.The BYK-381 of Bi Ke chemistry has
Have a following key property: improve levelling, improve gloss, prevent shrinkage cavity and pin hole class surface defect, on surface tension without influence.
According to the second aspect of the embodiment of the present application, this application provides a kind of preparations of aqueous Lacquer finish polishes of vehicle
Method comprising following steps:
S1, water-borne acrylic acid modified polyester resin, aqueous alkide resin and water-based fluorocarbon resin are added according to raw material proportioning
Enter in pot of stocking up, open dispersion machine, is stirred with the revolving speed of 400-600r/min.
S2, in whipping process, 1-3min is successively spaced according to raw material proportioning, coalescing agent and pH is added into stock pot
Regulator, and 3-7min is stirred with the revolving speed of 400-600r/min.
S3, deionized water, defoaming agent, wetting agent and levelling agent are sequentially added according to raw material proportioning, and with 400-600r/
The revolving speed of min stirs 8-12min.
Whether the mixture that S4, scraper plate checking step S3 are obtained has shrinkage cavity, if there is shrinkage cavity, then with 800-1000r/min
Revolving speed disperse 8-12min, until there is no shrinkage cavities.
S5, under the revolving speed of 600-800r/min, sequentially add part Amino resin and height according to raw material proportioning
Imino group Amino resin disperses 15-25min, forms uniform mill base to get the aqueous Lacquer finish polishes is arrived.
Further, the coalescing agent uses propandiol butyl ether and butyl；The propandiol butyl ether and two
Butyl glycol ether is sequentially added according to raw material proportioning, and time interval when addition is 1-3min.
According to the above-mentioned specific embodiment of the application it is found that at least having the advantages that the vehicle of the application preparation
Water-borne acrylic acid modified polyester resin is used in mixed way with aqueous Lacquer finish polishes, aqueous alkide resin and water-based fluorocarbon resin are made
For film forming matter, the ply adhesion between aqueous Lacquer finish polishes and priming paint can either be promoted, increases the richness of paint film, again
It can be improved the weatherability and stain resistance of paint film.
The vehicle of the application preparation uses aqueous Lacquer finish polishes to select propandiol butyl ether and butyl collocation as master
Coalescing agent is wanted, resin system viscosity can either be effectively reduced, and height caused by wet film is blocked up, flow time is short can be reduced
The generation of temperature baking paint film bubble problem.
The vehicle wetting agent used in aqueous Lacquer finish polishes and levelling agent of the application preparation are all made of special high-performance
Acrylic polymer can either provide preferable wetability and levelability, and not influence recoatability and ply adhesion, protect
Paint film property is not influenced when repairing and recoat in card coating process.
The vehicle of the application preparation selects the high imino group methyl ether of part Amino resin collocation with aqueous Lacquer finish polishes
Change amino resins to use, can either guarantee hardness of paint film, shorten reaction time and reaction temperature, and paint film recoating can be improved
Property, guarantee the requirement that client's workpiece is reprocessed.
It is to be understood that above-mentioned general description and following specific embodiments are merely illustrative and illustrative, not
The range to be advocated of the application can be limited.
Specific embodiment
For the purposes, technical schemes and advantages of the embodiment of the present application are more clearly understood, it is described in detail below clear
Illustrate the spirit of content disclosed herein, any skilled artisan is in the embodiment for understanding teachings herein
Afterwards, when the technology that can be taught by teachings herein, be changed and modify, without departing from teachings herein spirit with
Range.
About " first " used herein, " second " ... etc., not especially censure the meaning of order or cis-position,
It is non-to limit the application, only for distinguish with same technique term description element or operation.
It is open term about "comprising" used herein, " comprising ", " having ", " containing " etc.,
Mean including but not limited to.
About it is used herein " and/or ", including any of the things or all combination.
It include " two " and " two or more " about " multiple " herein；It include " two about " multiple groups " herein
Group " and " more than two ".
About term used herein " substantially ", " about " etc., to modify it is any can with the quantity of slight change or
Error, but this slight variations or error can't change its essence.In general, slight change that such term is modified or
The range of error can be 20% in some embodiments, in some embodiments can be 10%, can be in some embodiments
5% or other numerical value.It will be understood by those skilled in the art that the aforementioned numerical value referred to can be adjusted according to actual demand, not
As limit.
It is certain to describe the word of the application by lower or discuss in the other places of this specification, to provide this field skill
Art personnel guidance additional in relation to the description of the present application." part " described herein unless otherwise instructed, presses quality
Meter.
Embodiment 1
A kind of aqueous Lacquer finish polishes of vehicle, according to the mass fraction, including following material component:
Resin: 15 parts of water-borne acrylic acid modified polyester resin, 5 parts of aqueous alkide resin, 3 parts of water-based fluorocarbon resin, part
5 parts of Amino resin, 5 parts of high imino group Amino resin；
Auxiliary agent: 1.5 parts of pH adjusting agent, 0.5 part of defoaming agent, 8 parts of coalescing agent, 0.2 part of wetting agent, 0.2 part of levelling agent,
25 parts of deionized water.
In the present embodiment, water-borne acrylic acid modified polyester resin is main film forming substance, aqueous alkide resin and aqueous
Fluorocarbon resin is functional film forming matter.
The pH adjusting agent uses dimethylethanolamine.
The defoaming agent uses the mixture functional paint defoaming of hydrophobic solid and brokenly bubble polymer without organosilicon
Agent, such as the defoaming agent BYK-011 of Bi Ke chemistry.
The coalescing agent uses propandiol butyl ether and butyl.Propandiol butyl ether and butyl with
The mass fraction ratio of 3:8 is used in mixed way.
The wetting agent and levelling agent are all made of acrylic polymer, the PW336 and Bi Kehua that such as France first creates chemistry
BYK-381.
A kind of aqueous Lacquer finish polishes of above-mentioned vehicle the preparation method is as follows:
S1, water-borne acrylic acid modified polyester resin, aqueous alkide resin and water-based fluorocarbon resin are added according to raw material proportioning
Enter in pot of stocking up, open dispersion machine, is stirred with the revolving speed of 400r/min.
S2, in whipping process, 1min is successively spaced according to raw material proportioning, coalescing agent and pH tune is added into stock pot
Agent is saved, and 7min is stirred with the revolving speed of 400r/min.
S3, deionized water, defoaming agent, wetting agent and levelling agent are sequentially added according to raw material proportioning, and with 400r/min's
Revolving speed stirs 12min.
Whether the mixture that S4, scraper plate checking step S3 are obtained has shrinkage cavity, if there is shrinkage cavity, is then turned with 800r/min
Speed dispersion 12min, until there is no shrinkage cavities.
S5, under the revolving speed of 600r/min, sequentially add part Amino resin and high imido according to raw material proportioning
Base Amino resin disperses 25min, forms uniform mill base to get the aqueous Lacquer finish polishes is arrived.
Embodiment 2
A kind of aqueous Lacquer finish polishes of vehicle, according to the mass fraction, including following material component:
Resin: 20 parts of water-borne acrylic acid modified polyester resin, 8 parts of aqueous alkide resin, 4 parts of water-based fluorocarbon resin, part
6 parts of Amino resin, 6 parts of high imino group Amino resin；
Auxiliary agent: 2.5 parts of pH adjusting agent, 0.8 part of defoaming agent, 10 parts of coalescing agent, 0.6 part of wetting agent, 0.6 part of levelling agent,
30 parts of deionized water.
In the present embodiment, the coalescing agent uses propandiol butyl ether and butyl.Propandiol butyl ether and two
Butyl glycol ether is used in mixed way with the mass fraction ratio of 5:8.The selection of other raw materials and embodiment 1 are consistent, do not do herein superfluous
It states.
A kind of aqueous Lacquer finish polishes of above-mentioned vehicle the preparation method is as follows:
S1, water-borne acrylic acid modified polyester resin, aqueous alkide resin and water-based fluorocarbon resin are added according to raw material proportioning
Enter in pot of stocking up, open dispersion machine, is stirred with the revolving speed of 500r/min.
S2, in whipping process, 2min is successively spaced according to raw material proportioning, coalescing agent and pH tune is added into stock pot
Agent is saved, and 5min is stirred with the revolving speed of 500r/min.
S3, deionized water, defoaming agent, wetting agent and levelling agent are sequentially added according to raw material proportioning, and with 500r/min's
Revolving speed stirs 10min.
Whether the mixture that S4, scraper plate checking step S3 are obtained has shrinkage cavity, if there is shrinkage cavity, is then turned with 900r/min
Speed dispersion 10min, until there is no shrinkage cavities.
S5, under the revolving speed of 700r/min, sequentially add part Amino resin and high imido according to raw material proportioning
Base Amino resin disperses 20min, forms uniform mill base to get the aqueous Lacquer finish polishes is arrived.
Embodiment 3
A kind of aqueous Lacquer finish polishes of vehicle, according to the mass fraction, including following material component:
Resin: 25 parts of water-borne acrylic acid modified polyester resin, 10 parts of aqueous alkide resin, 5 parts of water-based fluorocarbon resin, portion
Divide 7 parts of Amino resin, 7 parts of high imino group Amino resin；
Auxiliary agent: 3 parts of pH adjusting agent, 1 part of defoaming agent, 15 parts of coalescing agent, 1 part of wetting agent, 1 part of levelling agent, deionized water
35 parts.
In the present embodiment, the coalescing agent uses propandiol butyl ether and butyl.Propandiol butyl ether and two
Butyl glycol ether is used in mixed way with the mass fraction ratio of 1:1.The selection of other raw materials and embodiment 1 are consistent, do not do herein superfluous
It states.
A kind of aqueous Lacquer finish polishes of above-mentioned vehicle the preparation method is as follows:
S1, water-borne acrylic acid modified polyester resin, aqueous alkide resin and water-based fluorocarbon resin are added according to raw material proportioning
Enter in pot of stocking up, open dispersion machine, is stirred with the revolving speed of 600r/min.
S2, in whipping process, 3min is successively spaced according to raw material proportioning, coalescing agent and pH tune is added into stock pot
Agent is saved, and 3min is stirred with the revolving speed of 600r/min.
S3, deionized water, defoaming agent, wetting agent and levelling agent are sequentially added according to raw material proportioning, and with 600r/min's
Revolving speed stirs 8min.
Whether the mixture that S4, scraper plate checking step S3 are obtained has shrinkage cavity, if there is shrinkage cavity, is then turned with 1000r/min
Speed dispersion 8min, until there is no shrinkage cavities.
S5, under the revolving speed of 800r/min, sequentially add part Amino resin and high imido according to raw material proportioning
Base Amino resin disperses 25min, forms uniform mill base to get the aqueous Lacquer finish polishes is arrived.
The obtained aqueous Lacquer finish polishes of embodiment 1-4 and oil paint and fine work water paint are tested, test result
As shown in table 1.
The performance comparison of 1 the application sample of table and commercially available oil paint and fine work water paint
As it can be seen from table 1 after aqueous Lacquer finish polishes coating provided by the present application, the strong, stain resistance with adhesive force
By force, recoatability is strong etc.；Water resistance is in 720h or more simultaneously, and Saline alkali tolerance 500h, ageing resistance is in 1500h or more, hence it is evident that high
In existing oil paint and fine work water paint, therefore aqueous Lacquer finish polishes water resistance provided by the present application is strong, Saline alkali tolerance is strong,
With extraordinary anti-aging property.
The foregoing is merely the schematical specific embodiments of the application, in the conceptions and principles for not departing from the application
Under the premise of, the equivalent changes and modifications that any those skilled in the art is made should belong to the range of the application protection.
Claims (10)
1. a kind of aqueous Lacquer finish polishes of vehicle, which is characterized in that according to the mass fraction, including following material component:
Resin: 15-25 parts of water-borne acrylic acid modified polyester resin, 5-10 parts of aqueous alkide resin, 3-5 parts of water-based fluorocarbon resin,
Amino resin 5-7 parts of part, 5-7 parts of high imino group Amino resin；
Auxiliary agent: 1.5-3 parts of pH adjusting agent, 0.5-1 parts of defoaming agent, 8-15 parts of coalescing agent, 0.2-1 parts of wetting agent, levelling agent
0.2-1 parts, 25-35 parts of deionized water.
2. the aqueous Lacquer finish polishes of vehicle according to claim 1, which is characterized in that the pH adjusting agent uses dimethyl
Ethanol amine.
3. the aqueous Lacquer finish polishes of vehicle according to claim 1, which is characterized in that the defoaming agent is used without organic
The hydrophobic solid of silicon and the mixture functional paint defoaming agent of brokenly bubble polymer.
4. the aqueous Lacquer finish polishes of vehicle according to claim 1, which is characterized in that the coalescing agent uses propylene glycol
Butyl ether and butyl.
5. the aqueous Lacquer finish polishes of vehicle according to claim 4, which is characterized in that the propandiol butyl ether and diethyl two
Alcohol butyl ether is used in mixed way with the ratio of 3:8-1:1.
6. the aqueous Lacquer finish polishes of vehicle according to claim 1, which is characterized in that the wetting agent and levelling agent are adopted
Use acrylic polymer.
7. a kind of vehicle preparation method of aqueous Lacquer finish polishes, which comprises the following steps:
S1, according to raw material proportioning by water-borne acrylic acid modified polyester resin, aqueous alkide resin and water-based fluorocarbon resin be added it is standby
Expect in pot, open dispersion machine, is stirred with the revolving speed of 400-600r/min；
S2, in whipping process, 1-3min is successively spaced according to raw material proportioning coalescing agent and pH is added into stock pot and adjust
Agent, and 3-7min is stirred with the revolving speed of 400-600r/min；
S3, deionized water, defoaming agent, wetting agent and levelling agent are sequentially added according to raw material proportioning, and with 400-600r/min's
Revolving speed stirs 8-12min；
Whether the mixture that S4, scraper plate checking step S3 are obtained has shrinkage cavity, if there is shrinkage cavity, is then turned with 800-1000r/min
Speed dispersion 8-12min, until there is no shrinkage cavities；
S5, under the revolving speed of 600-800r/min, sequentially add part Amino resin and high imido according to raw material proportioning
Base Amino resin disperses 15-25min, forms uniform mill base to get the aqueous Lacquer finish polishes is arrived.
8. the vehicle according to claim 7 preparation method of aqueous Lacquer finish polishes, which is characterized in that the coalescing agent
Using propandiol butyl ether and butyl.
9. the vehicle according to claim 8 preparation method of aqueous Lacquer finish polishes, which is characterized in that the propylene glycol fourth
Ether and butyl are sequentially added according to raw material proportioning, and time interval when addition is 1-3min.
10. the vehicle according to claim 7 preparation method of aqueous Lacquer finish polishes, which is characterized in that the defoaming agent
Using the mixture functional paint defoaming agent of hydrophobic solid and brokenly bubble polymer without organosilicon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811395220.3A CN109593447A (en) | 2018-11-22 | 2018-11-22 | Vehicle aqueous Lacquer finish polishes and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811395220.3A CN109593447A (en) | 2018-11-22 | 2018-11-22 | Vehicle aqueous Lacquer finish polishes and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109593447A true CN109593447A (en) | 2019-04-09 |
Family
ID=65960247
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811395220.3A Pending CN109593447A (en) | 2018-11-22 | 2018-11-22 | Vehicle aqueous Lacquer finish polishes and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922824A (en) * | 2019-12-07 | 2020-03-27 | 温州环诺新材料科技有限公司 | Universal water-based aluminum profile baking paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057510A (en) * | 2017-01-06 | 2017-08-18 | 河北晨阳工贸集团有限公司 | A kind of electric three-wheel automobile-used aqueous high-temperature baking metal flash paint and coating varnish and preparation method thereof |
| CN107201110A (en) * | 2017-02-21 | 2017-09-26 | 河北晨阳工贸集团有限公司 | Bicycle use high-temperature baking type water-based metal metallic finishe and preparation method thereof |
| CN108250917A (en) * | 2018-01-22 | 2018-07-06 | 河北晨阳工贸集团有限公司 | A kind of high durable stain resistant varnish and its preparation method and application |
-
2018
- 2018-11-22 CN CN201811395220.3A patent/CN109593447A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057510A (en) * | 2017-01-06 | 2017-08-18 | 河北晨阳工贸集团有限公司 | A kind of electric three-wheel automobile-used aqueous high-temperature baking metal flash paint and coating varnish and preparation method thereof |
| CN107201110A (en) * | 2017-02-21 | 2017-09-26 | 河北晨阳工贸集团有限公司 | Bicycle use high-temperature baking type water-based metal metallic finishe and preparation method thereof |
| CN108250917A (en) * | 2018-01-22 | 2018-07-06 | 河北晨阳工贸集团有限公司 | A kind of high durable stain resistant varnish and its preparation method and application |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922824A (en) * | 2019-12-07 | 2020-03-27 | 温州环诺新材料科技有限公司 | Universal water-based aluminum profile baking paint and preparation method thereof |
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Application publication date: 20190409 |