CN109593403A - A kind of aluminium base Water based metal micro-powder coating and its preparation process - Google Patents

A kind of aluminium base Water based metal micro-powder coating and its preparation process Download PDF

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Publication number
CN109593403A
CN109593403A CN201710927980.3A CN201710927980A CN109593403A CN 109593403 A CN109593403 A CN 109593403A CN 201710927980 A CN201710927980 A CN 201710927980A CN 109593403 A CN109593403 A CN 109593403A
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China
Prior art keywords
parts
based metal
aluminium base
water based
metal micro
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Application number
CN201710927980.3A
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Chinese (zh)
Inventor
王先达
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Cixi Hengda Copper Industry Co Ltd
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Cixi Hengda Copper Industry Co Ltd
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Priority to CN201710927980.3A priority Critical patent/CN109593403A/en
Publication of CN109593403A publication Critical patent/CN109593403A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08Cellulose derivatives
    • C09D101/26Cellulose ethers
    • C09D101/28Alkyl ethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

The invention discloses a kind of aluminium base Water based metal micro-powder coating and its preparation processes, it is related to field of mechanical technique, it is characterized in that, the aluminium base Water based metal micro-powder coating is made of the raw material of following parts by weight: 20-25 parts of hydrochloric acid, 15-20 parts of tartaric acid, 5-10 parts of HS-99, 5-10 parts of dodecyl sulphate, 10-20 parts of additive, the aluminium base Water based metal micro-powder coating technique includes pre-treatment, coating solution is prepared, coating, it rinses, preheating, dry and cool down and etc., the aluminium base Water based metal micro-powder coating prepared through the invention has appearance uniform smooth, have the advantages that compared with high-decoration and there is preferable corrosion resistance and heat resistance, and coating process is simple and convenient, save human cost.

Description

A kind of aluminium base Water based metal micro-powder coating and its preparation process
Technical field
The present invention relates to field of mechanical technique, and in particular to a kind of aluminium base Water based metal micro-powder coating and a kind of aluminium base water system The preparation process of microparticle metal coating.
Background technique
Handling the common method of one kind to Metal surface anti-corrosion both at home and abroad at present is electrogalvanizing, but the pollution of this method is tight The phenomenon that weight, energy consumption are big, and electroplating process is also easy to produce hydrogen embrittlement, cause material embrittlement and fracture.Zinc coat is using temperature by passivating film The limitation of aging temperature, can only be used below at 100 DEG C, there is biggish limitation, is not suitable for using under rugged environment.Electricity Zinc-plated anticorrosion principle is mainly anode loss protection, i.e., zinc coat resistance to corrosion is directly proportional to the thickness of coating, usually In the case of the standard thickness of electro-galvanized layer be about 8-15um, and the thickness of electro-galvanized layer is about 5-10um in actual production, thus Its resistance to corrosion is poor.The corrosion resistance of Hot-dip Galvanizing Coating can be much higher than electro-galvanized layer, but its energy consumption and pollution are even more serious, and Galvanizing thicknesses of layers is big, low precision, is not suitable for precision component and fastener.In recent years, since the regulation of environmental protection is strong Change, traditional process of surface treatment, such as hot-dip and plating all because technical process generates certain pollution, it is many country and ground Area is restricted.The process of surface treatment of steel material expects the birth of free of contamination " green process for treating surface ".
Summary of the invention
That the problem to be solved by the invention is to provide a kind of appearance of coat is uniform and smooth, with compared with high-decoration and have compared with The aluminium base Water based metal micro-powder coating and its preparation process of good corrosion resistance and heat resistance.
To achieve the goals above, the technical scheme adopted by the invention is as follows: a kind of aluminium base Water based metal micro-powder coating by with The raw material of lower parts by weight forms:
2-5 parts of zinc powder,
3-8 parts of aluminium powder,
15-25 parts of chromic anhydride aqueous solution,
10-20 parts of compound phosphoric acid dihydric salt,
10-28 parts of methylcellulose,
3-10 parts of sodium fluoride,
50-80 parts of water.
Preferably, the aluminium base Water based metal micro-powder coating is made of the raw material of following parts by weight:
3 parts of zinc powder,
4 parts of aluminium powder,
18 parts of chromic anhydride aqueous solution,
12 parts of compound phosphoric acid dihydric salt,
15 parts of methylcellulose,
4 parts of sodium fluoride,
55 parts of water.
Preferably, the preparation process of the aluminium base Water based metal micro-powder coating includes the following steps:
(1) part is put into the hydrochloric acid of 1g/1 and impregnates 2-3min, to remove the grease, floating embroidery and oxidation of workpiece surface Object;
(2) raw material of aluminium base Water based metal micro-powder coating is added to the container according to the ratio, stirs 1-2min, until stirring is equal It is even;
(3) part is put into after impregnating 0.8-1.5min in the solution of step (2) and is taken out;
(4) part rinses 2-3min with clear water;
(5) part preheats 10-15min, and temperature is controlled at 75-85 DEG C;
(6) part, which is put into dryer, toasts 25-35min, and temperature is controlled at 280-320 DEG C;
(7) natural cooling.
Beneficial effects of the present invention: the present invention is by by zinc powder, aluminium powder, chromic anhydride aqueous solution, compound phosphoric acid dihydric salt, methyl The raw materials such as cellulose and sodium fluoride are mixed with by weight ratio, and the aluminium base Water based metal micro-powder coating prepared has outer See it is uniform and smooth, have the advantages that compared with high-decoration and there is preferable corrosion resistance and heat resistance, and coating process is simple and convenient, Save human cost.
Specific embodiment
To be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, below with reference to Specific embodiment, the present invention is further explained.
Embodiment:
A kind of preparation process of aluminium base Water based metal micro-powder coating is made of the raw material of following parts by weight:
3 parts of zinc powder,
4 parts of aluminium powder,
18 parts of chromic anhydride aqueous solution,
12 parts of compound phosphoric acid dihydric salt,
15 parts of methylcellulose,
4 parts of sodium fluoride,
55 parts of water.
In the present embodiment, the preparation process of the aluminium base Water based metal micro-powder coating includes the following steps:
(1) part is put into the hydrochloric acid of 1g/1 and soaks 2min, to remove the grease, floating embroidery and oxide of workpiece surface;
(2) raw material of aluminium base Water based metal micro-powder coating is added to the container according to the ratio, stirs 1.5min, until stirring is equal It is even;
(3) part is put into after impregnating 1.2min in the solution of step (2) and is taken out;
(4) part rinses 2.5min with clear water;
(5) part preheats 12min, and temperature is controlled at 80 DEG C;
(6) part, which is put into dryer, toasts 30min, and temperature is controlled at 295 DEG C;
(7) natural cooling.
Based on above-mentioned, the present invention by by zinc powder, aluminium powder, chromic anhydride aqueous solution, compound phosphoric acid dihydric salt, methylcellulose and The raw materials such as sodium fluoride are mixed with by weight ratio, and the aluminium base Water based metal micro-powder coating prepared has appearance uniform light It slides, have the advantages that compared with high-decoration and there is preferable corrosion resistance and heat resistance, and coating process is simple and convenient, saves manpower Cost.
Obviously present invention specific implementation is not subject to the restrictions described above, as long as using method concept and skill of the invention The improvement for the various unsubstantialities that art scheme carries out, or not improved the conception and technical scheme of the invention are directly applied to it Its occasion, it is within the scope of the present invention.

Claims (3)

1. a kind of aluminium base Water based metal micro-powder coating, which is characterized in that the aluminium base Water based metal micro-powder coating is by following weight The raw material composition of part:
2-5 parts of zinc powder,
3-8 parts of aluminium powder,
15-25 parts of chromic anhydride aqueous solution,
10-20 parts of compound phosphoric acid dihydric salt,
10-28 parts of methylcellulose,
3-10 parts of sodium fluoride,
50-80 parts of water.
2. a kind of aluminium base Water based metal micro-powder coating according to claim 1, which is characterized in that the aluminium base Water based metal Micro-powder coating is made of the raw material of following parts by weight:
3 parts of zinc powder,
4 parts of aluminium powder,
18 parts of chromic anhydride aqueous solution,
12 parts of compound phosphoric acid dihydric salt,
15 parts of methylcellulose,
4 parts of sodium fluoride,
55 parts of water.
3. a kind of preparation process of aluminium base Water based metal micro-powder coating according to claim 1 or 2, which is characterized in that packet Include following steps:
(1) part is put into the hydrochloric acid of 1g/l and impregnates 2-3min, to remove the grease, floating embroidery and oxide of workpiece surface;
(2) raw material of aluminium base Water based metal micro-powder coating is added to the container according to the ratio, stirs 1-2min, until stirring evenly;
(3) part is put into after impregnating 0.8-1.5min in the solution of step (2) and is taken out;
(4) part rinses 2-3min with clear water;
(5) part preheats 10-15min, and temperature is controlled at 75-85 DEG C;
(6) part, which is put into dryer, toasts 25-35min, and temperature is controlled at 280-320 DEG C;
(7) natural cooling.
CN201710927980.3A 2017-09-30 2017-09-30 A kind of aluminium base Water based metal micro-powder coating and its preparation process Pending CN109593403A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710927980.3A CN109593403A (en) 2017-09-30 2017-09-30 A kind of aluminium base Water based metal micro-powder coating and its preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710927980.3A CN109593403A (en) 2017-09-30 2017-09-30 A kind of aluminium base Water based metal micro-powder coating and its preparation process

Publications (1)

Publication Number Publication Date
CN109593403A true CN109593403A (en) 2019-04-09

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Country Link
CN (1) CN109593403A (en)

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Application publication date: 20190409