CN109592847A - Oil production waste water in oil field processing method - Google Patents

Oil production waste water in oil field processing method Download PDF

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Publication number
CN109592847A
CN109592847A CN201811592950.2A CN201811592950A CN109592847A CN 109592847 A CN109592847 A CN 109592847A CN 201811592950 A CN201811592950 A CN 201811592950A CN 109592847 A CN109592847 A CN 109592847A
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CN
China
Prior art keywords
waste water
water
oil
processing method
oil field
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Pending
Application number
CN201811592950.2A
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Chinese (zh)
Inventor
唐安中
张志海
张�诚
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Beijing Xinsheng Huaneng Science And Technology Development Co Ltd
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Beijing Xinsheng Huaneng Science And Technology Development Co Ltd
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Priority to CN201811592950.2A priority Critical patent/CN109592847A/en
Publication of CN109592847A publication Critical patent/CN109592847A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)
  • Activated Sludge Processes (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses oil production waste water in oil field processing methods, including following processing step: 1) waste water is injected into conditioning tank by oil-field flooding, converges waste water, regulating water quality;2) waste water after adjusting enters oxygen compatibility pool, and acidification is hydrolyzed to waste water;3) by step 2), treated that waste water enters aerobic tank, carries out aerobic respiration to the activated sludge in waste water, removes pollutant;4) by step 3), treated that waste water enters MBR membrane cisterna, carries out sewage and sludge separating treatment to waste water;5) by step 4), treated that water quality is filtered processing;6) filtered water quality enters clear water reserviors;7) it carries out disinfection sterilization processing to the water quality in injected clear water pond.The invention reside in providing, a kind of wastewater treatment method process is simple, the water quality reaching standard after wastewater treatment, and has simplified wastewater treatment process, reduces the oil production waste water in oil field processing method of production cost.

Description

Oil production waste water in oil field processing method
Technical field
The present invention relates to waste water technology field more particularly to a kind of oil production waste water in oil field processing methods.
Background technique
Due to containing above-mentioned harmful substance, environment will be generated seriously oilfield sewage by emitting if without administering Influence: the crude oil swum on the water surface will completely cut off air, reduce the dissolved oxygen in water, and attach to aquatile body surface and exhale Desorption system is lethal by its.Hydrogen sulfide violent in toxicity will be generated by anaerobic digestion by being deposited on water-bed oil.Heavy crude attaches to mud Sha Shang will affect inhabiting and breeding for aquatile;It, can be to water body and soil containing the organic matter that some toxicity are big in oilfield sewage Earth pollutes;Organic matter and inorganic matter in oilfield sewage are the rich nutritive materials of bacterium in water, as a result cause slowly to flow Water area water-quality deteriorate, blackening is smelly;If oilfield sewage polluted drinking water, heavy metal element therein enters after human body to dirty Internal organs generates serious damage;Acid-base property, high salinity oilfield sewage, once pouring into farmland will lead to farmland soda acid, saline and alkaline Change, crops is made to be difficult to grow.
For the technique of oil field at home produced water treatment at present still based on sedimentation, oil removal and filtering, each oil field condition of water quality is different, Treatment process is also not quite similar.Conventional oil field re-injection water treatment technology, it is most of all using " natural subsidence oil removing-coagulation removes " three-stage " conventional treatment process of oil-filtering oil removing ".For in, the oily waste water of low permeability pay, generally " three sections Formula " processing plus " fine filtering " technique.But
Chinese Patent Application No. are as follows: 201510587704.8, the applying date are as follows: on 09 16th, 2015, publication date are as follows: 2015 On November 25, in, patent name: the oil field wastewater treatment technique based on special membrane;It is useless to disclose a kind of oil field based on special membrane Water treatment technology, including first stage oil removing oil removal, second stage electrochemical appliance aoxidize broken glue, and the phase III utilizes core Heart SuperRO system desalination carries out oil removing and oil removal, then benefit except three main workshop sections such as COD, using nanometer air-floating apparatus Materialization is carried out with the best electrochemical appliance of oxidability is useless to dirt, the mass-transfer efficiency between each substance is improved, when shortening reaction Between and reduce chemical consumption, so that realizing only needs relatively simple pretreatment that waste water can be made to be directly entered membranous system, ensure system The stable and service life of system greatly reduces the construction cost of environmental protection and the operating cost of sewage treatment.
A kind of oil field wastewater treatment technique of the patent disclosure, still, the oil field wastewater treatment process flow are complicated, processing Poor water quality afterwards, and water quality treatment higher cost, are unable to satisfy the market demand.
Summary of the invention
Object of the present invention is to simple, the wastewater treatments that overcomes the deficiencies of the prior art and provide a kind of wastewater treatment method process Water quality reaching standard afterwards, and wastewater treatment process has been simplified, reduce the oil production waste water in oil field processing method of production cost.
In order to achieve the object of the present invention, following technical scheme can be taken:
Oil production waste water in oil field processing method, including following processing step:
Waste water is injected into conditioning tank by step 1) oil-field flooding, converges waste water, regulating water quality;
Waste water after step 2) is adjusted enters oxygen compatibility pool, and acidification is hydrolyzed to waste water;
Treated that waste water enters aerobic tank by step 2) for step 3), carries out aerobic exhale to the activated sludge in waste water It inhales, removes pollutant;
Treated that waste water enters MBR membrane cisterna by step 3) for step 4), carries out sewage and sludge separating treatment to waste water;
Treated that water quality is filtered processing by step 4) for step 5);
The filtered water quality of step 6) enters clear water reserviors;
Step 7) carries out disinfection sterilization processing to the water quality in injected clear water pond.
If the waste water of the step 3) processing is not up to standard, return step 2) it is further processed.
The sludge reflux separated in the step 4) is further handled by oxygen compatibility pool to step 2).
If the sewage separated in the step 4) is not up to standard, return step 2) it is further processed.
The step 4) includes secondary settling tank processing, separates the sludge in waste water.
It includes by mechanical filter filtration treatment that the step 5), which is filtered processing to water quality,.
The mechanical filter includes quartz filter and more medium filter.
The step 7) makes to handle by ultraviolet sterilization to the water quality sterilization processing that carries out disinfection.
The beneficial effects of the present invention are: the 1, present invention carries out oil field wastewater treatment by MBR biofilm, waste water stream is handled Journey is simple, and treated, and water quality qualification is up to standard, meets national water standard;2, present invention optimizes waste water treatment process, significantly Waste water cost is reduced, the water quality that enables that treated is stablized qualified up to standard;3, oil field wastewater treatment technique of the present invention more ring It protects, is suitble to popularity.
Detailed description of the invention
Fig. 1 is oil production waste water in oil field of embodiment of the present invention processing method flow chart;
Specific embodiment
With reference to the accompanying drawing and the embodiment of the present invention is described in further detail invention.
Embodiment 1
Currently, oil extraction-generated waste water be as crude oil is extracted from oil reservoir together, and pass through crude oil collection and just plus Work whole process.This waste water has following characteristics:
(1) water temperature is high.General sewage temperature is at 50 degree or so.Difference, such as north oil field are 60-70 to individual fields Degree, northwest oil field are 30 degree or so.
(2) salinity is high.Different Sewage Disposal its salinity in different oil fields and same oil field has very big difference, low Only hundreds of mg/litres, high reaches hundreds of thousands of mg/litres.
(3) it is dissolved with a certain amount of gas.Such as hold solution oxygen, carbon dioxide, hydrogen sulfide and has some naphthenics Equal organic matters.
(4) contain a certain amount of suspended solid.Such as silt particle: including clay, silty sand and spun yarn;Various corrosion products and dirt: Including Fe2O3、CaO、FeS、CaCO3、CaSO4Deng;Bacterium: including sulfate reducing bacteria, saprophytic bacteria and iron bacteria, sulfur bacteria;Have Machine object: including gum asphalt class and paraffin class etc..
(5) a certain number of demulsifiers of remaining.
Referring to Fig. 1, oil production waste water in oil field processing method of the present invention, including following processing step:
Waste water is injected into conditioning tank by step 1) oil-field flooding, converges waste water, regulating water quality S1;
Waste water after step 2) is adjusted enters oxygen compatibility pool, and acidification S2 is hydrolyzed to waste water;
Treated that waste water enters aerobic tank by step 2) for step 3), carries out aerobic exhale to the activated sludge in waste water It inhales, further larger molecular organics in waste water is resolved into biodegradable small organic molecule, remove pollutant S3;
Treated that waste water enters MBR membrane cisterna by step 3) for step 4), carries out sewage and sludge separating treatment to waste water S4;The MBR film is to be handled by biofilm waste water;
Step 5) is by step 4) treated water quality is filtered processing S5;
The filtered water quality of step 6) enters clear water reserviors S6;
Step 7) carries out disinfection sterilization processing S7 to the water quality in injected clear water pond.
In the present embodiment, since condensed oil sewage is usually containing some organic matters difficult to degrade, biofilm wastewater treatment is logical The purpose of hydrolysis acidification is crossed, and is to improve the biodegradability of waste water, the load of subsequent Aerobic Process for Treatment is reduced, guarantees aerobic life The treatment effect of object contact-oxidation pool.
1,2 grade of biofilm contact oxidation pond is mainly degraded some intermediate organic matters decomposed by hydrolysis acidification, into one Step reduces the COD of sewage since the substrates concentration in sewage reduces step by step, and the biofacies of 1,2 grade of biomembrane oxidation pond is special Property will be different, and by after the domestication of microorganism, formed be suitable for degradation of organic substances flora.
In the present embodiment, waste water is injected into conditioning tank by the step 1) actually oil field, converges waste water, regulating water quality It is balanced;
Step 2) the waste water enters oxygen compatibility pool, and using facultative aerobe, acidification is hydrolyzed to waste water;It is ready for entry into Aerobic tank process section;
After the step 3) waste water enters aerobic tank, some intermediate organic matters decomposed by hydrolysis acidification of mainly degrading, The COD of sewage is further decreased due to the substrates in sewage, reduces the substrates concentration step by step;
In the step 4), described treated that waste water enters that MBR membrane cisterna carries out wastewater treatment, indeed through MBR Biofilm is handled.
The MBR biofilm has apparent advantage compared with traditional activated sludge process, this is also selection biofilm One of the reason of handling thick waste water.The microorganism concn of biofilm is higher than traditional activated sludge process, the microorganism of high concentration It is the basis for guaranteeing wastewater treatment efficiency, especially to condensed oil sewage, reinforces the effect of mass transmitting between bacterium and organic matter, realize sludge The separation of residence time and hydraulic detention time increase the contact probability of bacterium and organic matter.Also, since activity is dirty in aerobic tank The appearance of special efficacy bacterium (especially dominant microflora) in the increase of mud concentration and sludge improves biochemical reaction rate.Meanwhile passing through drop Low F/M ratio reduces excess sludge yield (even zero) and has more reliability to the degradation for realizing condensed oil sewage, and biofilm is resistance to The ability of impact is stronger.
Filtered by step 4) treated water quality by step 5), in injection step 6) clear water reserviors, further pass through Step 7) sterilization processing makes water quality reaching standard, is then discharged, and completes all processes of wastewater treatment.
Preferably, if the waste water of the step 3) processing is not up to standard, return step 2) it is further processed.That is, good The waste water that oxygen pond is handled is not up to standard, then, returns to oxygen compatibility pool and re-start wastewater treatment.
The sludge reflux separated in the step 4) is further handled by oxygen compatibility pool to step 2).That is, The sludge reflux separated by the MBR biofilm further does wastewater treatment to oxygen compatibility pool, repeated multiple times, finally by sludge Processing is clean.
Preferably, if the sewage separated in the step 4) is not up to standard, return step 2) it is further processed.
Preferably, the step 4) includes secondary settling tank processing, separates the sludge in waste water.
The secondary settling tank mainly realizes the water centrifugation of part aerobic sludge, since biomembrane dirt is in free sludge quantity side Face is substantially distinguished from traditional activated sludge process, therefore the setting of secondary settling tank also has guaranteeing role to the effect of sewage treatment.
Preferably, it includes by mechanical filter filtration treatment that the step 5), which is filtered processing to water quality,.
It is further preferred that the mechanical filter includes quartz filter and more medium filter.
Water quality is further filtered by the mechanical filter, water quality is complied with standard more, water quality is made further to reach conjunction Case marker is quasi-.
Preferably, the step 7) makes to handle by ultraviolet sterilization to the water quality sterilization processing that carries out disinfection.
Filtered water quality ensure that water quality can be up to standard, complete the last work of wastewater treatment by ultraviolet sterilization Skill up to standard can be discharged by the water quality of disinfection and sterilization.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.

Claims (8)

1. a kind of oil production waste water in oil field processing method, it is characterised in that: including following processing step:
Waste water is injected into conditioning tank by step 1) oil-field flooding, converges waste water, regulating water quality;
Waste water after step 2) is adjusted enters oxygen compatibility pool, and acidification is hydrolyzed to waste water;
Treated that waste water enters aerobic tank by step 2) for step 3), carries out aerobic respiration to the activated sludge in waste water, goes Depollution object;
Treated that waste water enters MBR membrane cisterna by step 3) for step 4), carries out sewage and sludge separating treatment to waste water;
Treated that water quality is filtered processing by step 4) for step 5);
The filtered water quality of step 6) enters clear water reserviors;
Step 7) carries out disinfection sterilization processing to the water quality in injected clear water pond.
2. the oil production waste water in oil field processing method according to claim 1, it is characterised in that: the step 3) processing If waste water it is not up to standard, return step 2) be further processed.
3. oil production waste water in oil field processing method according to claim 1, it is characterised in that: the dirt separated in the step 4) Mud is back to step 2), is further handled by oxygen compatibility pool.
4. oil production waste water in oil field processing method according to claim 1, it is characterised in that: the dirt separated in the step 4) If water is not up to standard, return step 2) it is further processed.
5. oil production waste water in oil field processing method according to claim 1, it is characterised in that: the step 4) includes secondary settling tank Processing, separates the sludge in waste water.
6. oil production waste water in oil field processing method according to claim 4, it is characterised in that: the step 5) carries out water quality Filtration treatment includes passing through mechanical filter filtration treatment.
7. oil production waste water in oil field processing method according to claim 6, it is characterised in that: the mechanical filter includes stone Sand filter and more medium filter.
8. oil production waste water in oil field processing method according to claim 1, it is characterised in that: the step 7) carries out water quality Disinfection and sterilization processing makes to handle by ultraviolet sterilization.
CN201811592950.2A 2018-12-25 2018-12-25 Oil production waste water in oil field processing method Pending CN109592847A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811592950.2A CN109592847A (en) 2018-12-25 2018-12-25 Oil production waste water in oil field processing method

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Application Number Priority Date Filing Date Title
CN201811592950.2A CN109592847A (en) 2018-12-25 2018-12-25 Oil production waste water in oil field processing method

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CN109592847A true CN109592847A (en) 2019-04-09

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103183447A (en) * 2011-12-29 2013-07-03 宜兴市金琪洋生物质环境治理技术咨询有限公司 Treatment method of piggery wastewater
CN104973731A (en) * 2015-06-29 2015-10-14 安徽省安庆市皖清环保科技有限公司 Domestic wastewater treatment method
CN105731735A (en) * 2016-04-13 2016-07-06 中国水利水电科学研究院 Integrated rural sewage treatment device
CN205710303U (en) * 2016-04-25 2016-11-23 山西德恒机电科技有限公司 A kind of MBR waste water treating and reutilizing system
CN108821515A (en) * 2018-07-20 2018-11-16 华兰生物工程重庆有限公司 A kind of bio-pharmaceuticals sewage disposal system and method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103183447A (en) * 2011-12-29 2013-07-03 宜兴市金琪洋生物质环境治理技术咨询有限公司 Treatment method of piggery wastewater
CN104973731A (en) * 2015-06-29 2015-10-14 安徽省安庆市皖清环保科技有限公司 Domestic wastewater treatment method
CN105731735A (en) * 2016-04-13 2016-07-06 中国水利水电科学研究院 Integrated rural sewage treatment device
CN205710303U (en) * 2016-04-25 2016-11-23 山西德恒机电科技有限公司 A kind of MBR waste water treating and reutilizing system
CN108821515A (en) * 2018-07-20 2018-11-16 华兰生物工程重庆有限公司 A kind of bio-pharmaceuticals sewage disposal system and method

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Application publication date: 20190409