CN109590197A - A kind of auxiliary power unit turborotor protective coating preparation method - Google Patents

A kind of auxiliary power unit turborotor protective coating preparation method Download PDF

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Publication number
CN109590197A
CN109590197A CN201811291196.9A CN201811291196A CN109590197A CN 109590197 A CN109590197 A CN 109590197A CN 201811291196 A CN201811291196 A CN 201811291196A CN 109590197 A CN109590197 A CN 109590197A
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CN
China
Prior art keywords
coating
blade
protective coating
power unit
auxiliary power
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Pending
Application number
CN201811291196.9A
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Chinese (zh)
Inventor
何黎明
晁国涛
付俊波
郭双全
任天明
谢长城
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No 5719 Factory of PLA
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No 5719 Factory of PLA
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Priority to CN201811291196.9A priority Critical patent/CN109590197A/en
Publication of CN109590197A publication Critical patent/CN109590197A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/32Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • B05D3/0272After-treatment with ovens
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • C23C14/042Coating on selected surface areas, e.g. using masks using masks
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/16Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/32Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C23C14/325Electric arc evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5893Mixing of deposited material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

The invention discloses a kind of auxiliary power unit turborotor coating protection preparation methods, include the following steps;Oil removal treatment: water blast is carried out using the white fused alumina of 120 mesh, acetone soak is then used, degreases;Spraying protection bottom: silico-aluminum AlSi slurry is sprayed into the blade passage position with spray gun;Protect bottom inspection: metallographic examination protects underlayer thickness in 40~60 μ ms, should be without rarefaction defect in coating;Protective coating pre-treatment: blade and blade pelvic part position is subjected to water blast: vacuum arc plating protective coating using 280 mesh white fused aluminas, coating coating is carried out after the completion of cleaning;DIFFUSION TREATMENT: the blade is put into vacuum drying oven and is diffused processing.It is an advantage of the invention that selecting AlSi coating as bottom, the excellent CoCrAlY coating of hot corrosion resistance improves the thermophilic corrosion-resistance performance of coating compared to conventional single AlSi coating as surface layer.

Description

A kind of auxiliary power unit turborotor protective coating preparation method
Technical field
The present invention relates to aircraft engine maintenance technical field, especially a kind of auxiliary power unit turborotor is applied Layer protection preparation method.
Background technique
Turborotor is one of the core component of gas-turbine unit most critical, and major function is by high temperature height The rectification of compression ignition gas flows to turbine rotor blade by the required method of salary distribution and direction, and turbine wheel shaft rotation is made to drive compressor acting. Turborotor immediately combustor exit, operating temperature is high, the temperature difference is big, is subjected to the impact and erosion of high-temperature fuel gas for a long time, Blade is not required nothing more than with enough elevated temperature strengths, also to there is good high temperature resistant property, is depended merely on alloy itself and is difficult simultaneously completely The two requirements of foot, need high-temperature protection coating in most cases.At present usually used coating include coat of aluminide, MCrAlY coating and thermal barrier coating.Wherein coat of aluminide due to preparation method it is simple, it is low in cost, while high temperature resistance Can be excellent, therefore it is widely used as turbo blade high-temperature protection coating.
Auxiliary power unit (APU) is substantially a small-sized aero gas turbine engine, turbine inlet temperature about 900 ℃.Turborotor is under the working environment, since the fused salts such as Na2SO4, K2SO4 are easy gradually to sink in blade and blade pelvic part position Product, leaf pelvic part position is mainly based on High Temperature Hot-corrosion Behaviorof, while leaf basin constantly bears the impact of high-temperature high-pressure fuel gas, protective coating It is easy to mostly use single AlSi coating to make greatly by even influence blade base performance, especially current turborotor is destroyed In the case where protective coating, leaf basin heat erosion is particularly evident.
Summary of the invention
The purpose of the present invention is to overcome the shortcomings of the existing technology, provides a kind of auxiliary power unit turborotor painting Layer protection preparation method selectively prepares a kind of composite coating in the blade and blade pelvic part position for being subject to heat erosion destruction, improves The hot corrosion resistance of blade extends blade service life.
The purpose of the present invention is achieved through the following technical solutions: a kind of auxiliary power unit turborotor coating is anti- Preparation method is protected, is included the following steps;
Oil removal treatment: the guide vane of high pressure turbine of auxiliary power unit is subjected to water blast using the white fused alumina of 120 mesh, then It using acetone soak, degreases, and is dried for standby;
Spraying protection bottom: silico-aluminum AlSi slurry is sprayed into the blade passage position with spray gun, with a thickness of 40~60 μ Then m carries out intermediate temperature setting and high-temperature vacuum DIFFUSION TREATMENT, form AlSi and protect bottom;
Protect bottom inspection: metallographic examination protects underlayer thickness in 40~60 μ ms, should be without rarefaction defect in coating;
Protective coating pre-treatment: blade and blade pelvic part position is subjected to water blast using 280 mesh white fused aluminas, is then placed in deionized water 20~30min of ultrasonic cleaning is carried out, then carries out 10~15min of acetone soak;
Coating protective coating: vacuum arc plating protective coating, when being evacuated to 10-2~10-3Pa, to the blade carry out from Son cleaning, operating voltage 200V, arc current 600A, clearance time are greater than 2min, coating coating are carried out after the completion of cleaning, apply Voltage 30V, arc current 600A, coating time 2h are plated, about 36 μm~40 μm of thickness of coating is obtained;
DIFFUSION TREATMENT: the blade being put into vacuum drying oven and is diffused processing, after furnace pressure is less than 10-2 Pa, heating To 980 DEG C, 3h is kept the temperature, with furnace vacuum cooled to 600 DEG C hereinafter, filling 1200~1500mbar argon gas is cooled to 80 after heat preservation DEG C or less come out of the stove;
Protective coating inspection: by coating test piece on tooling device more than 90-degree bent, check that test piece external surface coating should be without de- It falls, chip off-falling.
Specifically, the intermediate temperature setting process is: the blade after spraying silico-aluminum slurry is heated to 80 DEG C of heat preservations 30min then heats to 300 DEG C, keeps the temperature 30min.
Specifically, the high-temperature vacuum DIFFUSION TREATMENT process is: spraying silico-aluminum slurry rear blade is placed vacuum It is evacuated to 10Pa in furnace or is higher than 10Pa, 1000 DEG C are warming up in 2.5h, keeps the temperature 3h, vacuum furnace cooling after heat preservation To 400 DEG C, then pours 1~2bar argon gas and be cooled to 80 DEG C or less and come out of the stove.
Specifically, further include non-coating position protection step, use shield jig by the leaf before coating protective coating It is protected at the non-coating position of piece.
Specifically, the basis material of the auxiliary power unit is Mar-M247.
Specifically, the protective coating is CoCrAlY thermal barrier coating.
Specifically, the silico-aluminum AlSi is the dedicated silico-aluminum of aviation.The invention has the following advantages that
1, select AlSi coating as bottom, the excellent CoCrAlY coating of hot corrosion resistance is as surface layer, compared to routine Single AlSi coating improves the thermophilic corrosion-resistance performance of coating.
2, it by applying AlSi coating in turborotor water passage surface, is selectively applied in the compound CoCrAlY of leaf basin Layer, improves the ability of blade and blade basin corrosion and heat resistant, while guaranteeing that blade back has preferable high temperature oxidation resistance, effectively extends Blade service life.
3, AlSi+CoCrAlY composite coating after spreading carries out bend test, without apparent disbonding phenomenon, Anchoring strength of coating is high, is not susceptible to disbonding when vanes are impacted by high-temperature fuel gas in the operating condition.
4, the coating performance of the method for the present invention preparation is excellent, reliable in quality is stable, not only can be in military aero-engine Upper use, and can extend on the turborotors such as domestic gas turbine and use, it prolongs its service life, has simultaneously Significant social benefit.
Detailed description of the invention
Fig. 1 is flow chart of the invention;
Fig. 2 is that failure blade coatings damage metallographic;
Fig. 3 is the composite coating metallographic of preparation.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing, but protection scope of the present invention is not limited to following institute It states.
As shown in Fig. 1 ~ 3, a kind of auxiliary power unit turborotor coating protection preparation method, including following step Suddenly;
Oil removal treatment: the guide vane of high pressure turbine of auxiliary power unit is subjected to water blast using the white fused alumina of 120 mesh, then It using acetone soak, degreases, and is dried for standby;
Spraying protection bottom: silico-aluminum AlSi slurry is sprayed into the blade passage position with spray gun, with a thickness of 40~60 μ Then m carries out intermediate temperature setting and high-temperature vacuum DIFFUSION TREATMENT, form AlSi and protect bottom;
Protect bottom inspection: metallographic examination protects underlayer thickness in 40~60 μ ms, should be without rarefaction defect in coating;
Protective coating pre-treatment: blade and blade pelvic part position is subjected to water blast using 280 mesh white fused aluminas, is then placed in deionized water 20~30min of ultrasonic cleaning is carried out, then carries out 10~15min of acetone soak;
Coating protective coating: vacuum arc plating protective coating, when being evacuated to 10-2~10-3Pa, to the blade carry out from Son cleaning, operating voltage 200V, arc current 600A, clearance time are greater than 2min, coating coating are carried out after the completion of cleaning, apply Voltage 30V, arc current 600A, coating time 2h are plated, about 36 μm~40 μm of thickness of coating is obtained;
DIFFUSION TREATMENT: the blade is put into vacuum drying oven and is diffused processing: after furnace pressure is less than 10-2 Pa, heating To 980 DEG C, 3h is kept the temperature, with furnace vacuum cooled to 600 DEG C hereinafter, filling 1200~1500mbar argon gas is cooled to 80 after heat preservation DEG C or less come out of the stove;
Protective coating inspection: by coating test piece on tooling device more than 90-degree bent, check that test piece external surface coating should be without de- It falls, chip off-falling.
Further, the intermediate temperature setting process is: the blade after spraying silico-aluminum slurry is heated to 80 DEG C of guarantors Warm 30min then heats to 300 DEG C, keeps the temperature 30min.
Further, the high-temperature vacuum DIFFUSION TREATMENT process is: spraying silico-aluminum slurry rear blade being placed true It is evacuated to 10Pa in empty furnace or is higher than 10Pa, 1000 DEG C are warming up in 2.5h, keeps the temperature 3h, vacuum is cold with furnace after heat preservation But it to 400 DEG C, then pours 1~2bar argon gas and is cooled to 80 DEG C or less and come out of the stove.
It further, further include non-coating position protection step, it will be described using shield jig before coating protective coating It is protected at the non-coating position of blade.
Further, the basis material of the auxiliary power unit is Mar-M247.
Further, the protective coating is CoCrAlY thermal barrier coating.
Further, the silico-aluminum AlSi is the dedicated silico-aluminum of aviation.A layer in Fig. 2 is AlSi coating, and B is CoCrAlY coating.
The above, only presently preferred embodiments of the present invention not do limitation in any form to the present invention.It is any ripe Those skilled in the art is known, without departing from the scope of the technical proposal of the invention, all using technology contents described above Many possible changes and modifications or equivalent example modified to equivalent change are made to technical solution of the present invention.Therefore, all It is the content without departing from technical solution of the present invention, any change modification made to the above embodiment of technology according to the present invention, Equivalent variations and modification belong to the protection scope of the technical program.

Claims (7)

1. a kind of aviation auxiliary power unit turborotor protective coating preparation method, it is characterised in that: including following step Suddenly;
Oil removal treatment: the guide vane of high pressure turbine of auxiliary power unit is subjected to water blast using the white fused alumina of 120 mesh, then It using acetone soak, degreases, and is dried for standby;
Spraying protection bottom: silico-aluminum AlSi slurry is sprayed into the blade passage position with spray gun, with a thickness of 40~60 μ Then m carries out intermediate temperature setting and high-temperature vacuum DIFFUSION TREATMENT, form AlSi and protect bottom;
Protect bottom inspection: metallographic examination protects underlayer thickness in 40~60 μ ms, should be without rarefaction defect in coating;
Protective coating pre-treatment: blade and blade pelvic part position is subjected to water blast using 280 mesh white fused aluminas, is then placed in deionized water 20~30min of ultrasonic cleaning is carried out, then carries out 10~15min of acetone soak;
Coating protective coating: vacuum arc plating protective coating is evacuated to 10-2~10-3When Pa, ion is carried out to the blade Cleaning, operating voltage 200V, arc current 600A, clearance time are greater than 2min, coating coating, coating are carried out after the completion of cleaning Voltage 30V, arc current 600A, coating time 2h obtain about 36 μm~40 μm of thickness of coating;
DIFFUSION TREATMENT: the blade being put into vacuum drying oven and is diffused processing, when furnace pressure is less than 10-2After Pa, it is warming up to 980 DEG C, 3h is kept the temperature, with furnace vacuum cooled to 600 DEG C hereinafter, filling 1200~1500mbar argon gas is cooled to 80 DEG C after heat preservation It comes out of the stove below;
Protective coating inspection: by coating test piece on tooling device more than 90-degree bent, check that test piece external surface coating should be without de- It falls, chip off-falling.
2. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature Be: the intermediate temperature setting process is: the blade after spraying silico-aluminum slurry being heated to 80 DEG C of heat preservation 30min, then 300 DEG C are warming up to, 30min is kept the temperature.
3. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature Be: the high-temperature vacuum DIFFUSION TREATMENT process is: spraying silico-aluminum slurry rear blade being placed in vacuum drying oven and is vacuumized To 10Pa or it is higher than 10Pa, 1000 DEG C is warming up in 2.5h, keeps the temperature 3h, vacuum cools to 400 DEG C with the furnace after heat preservation, so After pour 1~2bar argon gas and be cooled to 80 DEG C or less and come out of the stove.
4. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature It is: further includes non-coating position protection step, use shield jig by the non-coating of the blade before coating protective coating It is protected at position.
5. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature Be: the basis material of the auxiliary power unit is Mar-M247.
6. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature Be: the protective coating is CoCrAlY thermal barrier coating.
7. a kind of auxiliary power unit turborotor protective coating preparation method according to claim 1, feature Be: the silico-aluminum AlSi is the dedicated silico-aluminum of aviation.
CN201811291196.9A 2018-10-31 2018-10-31 A kind of auxiliary power unit turborotor protective coating preparation method Pending CN109590197A (en)

Priority Applications (1)

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CN201811291196.9A CN109590197A (en) 2018-10-31 2018-10-31 A kind of auxiliary power unit turborotor protective coating preparation method

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Application Number Priority Date Filing Date Title
CN201811291196.9A CN109590197A (en) 2018-10-31 2018-10-31 A kind of auxiliary power unit turborotor protective coating preparation method

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6296447B1 (en) * 1999-08-11 2001-10-02 General Electric Company Gas turbine component having location-dependent protective coatings thereon
CN101460708A (en) * 2006-06-08 2009-06-17 西门子公司 Coated turbine component and method of coating a turbine component
CN102936713A (en) * 2012-11-28 2013-02-20 中国南方航空工业(集团)有限公司 Method for seeping aluminum silicon from aluminum silicon slurry

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6296447B1 (en) * 1999-08-11 2001-10-02 General Electric Company Gas turbine component having location-dependent protective coatings thereon
CN101460708A (en) * 2006-06-08 2009-06-17 西门子公司 Coated turbine component and method of coating a turbine component
CN102936713A (en) * 2012-11-28 2013-02-20 中国南方航空工业(集团)有限公司 Method for seeping aluminum silicon from aluminum silicon slurry

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
何黎明等: "AlSi+CoCrAlY复合涂层对MAR-M247合金力学性能的影响", 《航空维修与工程》 *
刘劲松,蒲玉兴主编: "《航空工程材料》", 31 August 2015 *

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Application publication date: 20190409