CN109589741A - Vocs efficient treatment process in a kind of toxic organic exhaust gas - Google Patents
Vocs efficient treatment process in a kind of toxic organic exhaust gas Download PDFInfo
- Publication number
- CN109589741A CN109589741A CN201811226357.6A CN201811226357A CN109589741A CN 109589741 A CN109589741 A CN 109589741A CN 201811226357 A CN201811226357 A CN 201811226357A CN 109589741 A CN109589741 A CN 109589741A
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- Prior art keywords
- exhaust gas
- tracheae
- spongy layer
- tipping tube
- layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
- B01D46/0036—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/11—Clays
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses vocs efficient treatment process in a kind of toxic organic exhaust gas, belong to exhaust-gas treatment field.Vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device, enrichment facility and burner, the purification device includes tipping tube and vertical pipe, and diagonally downward, the tipping tube upper end is active carbon layer to the tipping tube;The middle position of the tipping tube and vertical pipe is provided with one-way ventilating film, the one-way ventilating film both ends are respectively arranged with the first spongy layer and the second spongy layer, the second spongy layer upper end is provided with clay layer, it is provided with hydrophobic permeable membrane above the clay layer, is provided with organic solvent above the hydrophobic permeable membrane;The present invention is first by exhaust gas by adsorbing, then using degradation of burning is carried out after concentration, to utterly destroy vocs in toxic organic exhaust gas.
Description
Technical field
The present invention relates to exhaust-gas treatment fields, efficiently locate more specifically to vocs in a kind of toxic organic exhaust gas
Science and engineering skill.
Background technique
VOCs is the english abbreviation of volatile organic compounds (volatile organic compounds);According to WHO
It defines, volatile organic compounds (VOC) refers under normal pressure, 50 DEG C -260 DEG C of boiling point of various organic compounds.VOC presses it
Chemical structure can be further divided into: alkanes, aromatic hydrocarbons, esters, aldehydes and other etc..What is identified at present has more than 300
Kind.It is most common to have benzene,toluene,xylene, styrene, trichloro ethylene, chloroform, trichloroethanes, diisocyanate
(TDI), two isocyanide toluene esters etc.;In addition to formaldehyde, most volatile organic compounds are generally all not soluble in water and readily soluble
In organic solvent.Their own concentration is frequently not very high indoors, but several VOC are collectively resided in room air
When, synergy is very important.Since their types are more, the concentration of single component is low, and being usually used in TVOC indicates indoor
In volatile organic compounds total amount.TVOC is to measure the indoor articles such as building interior trim finishing and furniture.To interior
One important indicator of air quality influence degree;
The present invention provides a kind of effective method for handling the VOCS in toxic organic exhaust gas.
Summary of the invention
To solve the above problems, the present invention adopts the following technical scheme that.
Vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device, enrichment facility
And burner, the purification device include tipping tube and vertical pipe, the tipping tube diagonally downward, the tipping tube
Upper end is active carbon layer;The middle position of the tipping tube and vertical pipe is provided with one-way ventilating film, the one-way ventilating
Film both ends are respectively arranged with the first spongy layer and the second spongy layer, and the second spongy layer upper end is provided with clay layer, described
Clay layer above be provided with hydrophobic permeable membrane, be provided with organic solvent above the hydrophobic permeable membrane;
The burner includes vertical tracheae, and the inside of the vertical tracheae supports the bottom of taper tracheae by bracket
End, the outer wall of the taper tracheae are provided with multiple ventholes, are provided with burner above the taper tracheae.
Preferably, first spongy layer and the second spongy layer are wet sponge.
Preferably, ring of igniting is provided between the taper tracheae and burner, the ring of igniting cuts for annular
Face is half of ellipse;The ring of igniting is internally provided with a main channel and a plurality of subchannel, and main channel is connected to a plurality of point
The one end in channel, the other end are the hole of ring outer surface of igniting.
Beneficial effect
Compared with the prior art, the present invention has the advantages that the present invention first by exhaust gas through absorption, then using concentration after
Degradation of burning is carried out, to utterly destroy vocs in toxic organic exhaust gas.
Detailed description of the invention
Fig. 1 is process flow chart of the invention;
Fig. 2 is the structural schematic diagram of purification device of the present invention;
Fig. 3 is the structural schematic diagram of burner of the present invention;
Fig. 4 is the structural schematic diagram of taper tracheae of the present invention.
Figure label explanation:
1, purification device;2, enrichment facility;3, burner;4, tipping tube;5, vertical pipe;6, active carbon layer;7, one-way ventilating
Film;8, the first spongy layer;9, the second spongy layer;10, clay layer;11, hydrophobic permeable membrane;12, organic solvent;13, vertical tracheae;
14, taper tracheae;15, venthole;16, combustion apparatus;17, it ignites ring.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention;Technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description;Obviously;Described embodiments are only a part of the embodiments of the present invention;Instead of all the embodiments.It is based on
Embodiment in the present invention;It is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment;It shall fall within the protection scope of the present invention.
Please refer to Fig. 1-4, vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification dress
Set 1, enrichment facility 2 and burner 3, purification device 1 includes tipping tube 4 and vertical pipe 5, tipping tube 4 diagonally downward, tipping tube
4 upper ends are active carbon layer 6;The middle position of tipping tube 4 and vertical pipe 5 is provided with one-way ventilating film 7,7 both ends of one-way ventilating film
It is respectively arranged with the first spongy layer 8 and the second spongy layer 9,9 upper end of the second spongy layer is provided with clay layer 10,10 top of clay layer
It is provided with hydrophobic permeable membrane 11, the top of hydrophobic permeable membrane 11 is provided with organic solvent 12;
Burner 3 includes vertical tracheae 13, and the inside of vertical tracheae 13 supports the bottom end of taper tracheae 14, taper by bracket
The outer wall of tracheae 14 is provided with multiple ventholes 15, and the top of taper tracheae 14 is provided with burner 16.
First spongy layer 8 and the second spongy layer 9 are wet sponge.
Ring 17 of igniting is provided between taper tracheae 14 and burner 16, ring 17 of igniting is annular, and section is ellipse half
It is round;Ring 17 of igniting is internally provided with a main channel and a plurality of subchannel, and main channel is connected to one end of a plurality of subchannel, another
It holds as the hole for 17 outer surface of ring of igniting.
Working principle:
The exhaust gas being collected into is passed through to the upper end of tipping tube first, active carbon layer 6 is first passed around and is adsorbed, then passes through first
Spongy layer 8 is full of moisture on first spongy layer 8, can adsorb exhaust gas formaldehyde at this time, pass through again after then passing through individual event ventilated membrane 7
The second spongy layer 9, the first spongy layer 8 and the second spongy layer 9 are crossed other than absorbing and being dissolved in the substance of water in exhaust gas, also has and stablizes
The effect of individual event ventilated membrane 7, otherwise one-way ventilating film is under regular one-way ventilating effect, or gradually fenestra increases, and loses
The effect of one-way ventilating;Then exhaust gas enters back into clay layer 10, continues the absorption of exhaust gas, then passes through hydrophobic permeable membrane again
It enters in organic solvent;Absorption before entering back into organic solvent, primarily to by large particulate matter and exhaust gas in exhaust gas
Temperature reduce and be dissolved in water substance absorption fall, subsequently into organic solvent, enter enrichment facility by the exhaust gas of purification
It is concentrated in 2, subsequently into burner;
Exhaust gas enters in the vertical tracheae in burner, and gas can be divided into 2 parts, and 1 part does not fall under taper tracheae
In, another part has entered in taper tracheae, and combustion apparatus jets out flames downwards at this time, and peripheral flame is in ring of igniting
Under the action of, formed it is intermediate small, below big flame, in addition, dissipated outward from venthole into the flame in taper tracheae, from
And flame flame envelope is more blown it is outside, under the action of flame flow, exhaust gas more towards vertical tracheae edge, and this
When, by the effect of ignite ring and taper tracheae, the flame envelope of the edge of vertical tracheae is most, and passes through the process of flame more
It is long;At the same time, it ignites and is additionally provided with channel inside ring, the combustion-supporting ingredient such as oxygen can be passed through, to main channel so as to reality
Existing flame is more prosperous, to realize the more thorough combustion degradation of exhaust gas, realization reaches zero emission standards.
It is described above;It is merely preferred embodiments of the present invention;But scope of protection of the present invention is not limited thereto;
Anyone skilled in the art is in the technical scope disclosed by the present invention;According to the technique and scheme of the present invention and its
It improves design and is subject to equivalent substitution or change;It should be covered by the scope of protection of the present invention.
Claims (3)
1. vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device (1), enrichment facility
(2) and burner (3), it is characterised in that: the purification device (1) includes tipping tube (4) and vertical pipe (5), described
Diagonally downward, the tipping tube (4) upper end is active carbon layer (6) to tipping tube (4);The tipping tube (4) and vertical pipe (5)
Middle position be provided with one-way ventilating film (7), described one-way ventilating film (7) both ends are respectively arranged with the first spongy layer (8)
With the second spongy layer (9), described the second spongy layer (9) upper end is provided with clay layer (10), above the clay layer (10)
It is provided with hydrophobic permeable membrane (11), organic solvent (12) is provided with above the hydrophobic permeable membrane (11);
The burner (3) includes vertical tracheae (13), and the inside of the vertical tracheae (13) passes through bracket cone of support
The outer wall of the bottom end of shape tracheae (14), the taper tracheae (14) is provided with multiple ventholes (15), the taper tracheae
(14) combustion apparatus (16) are provided with above.
2. vocs efficient treatment process in a kind of toxic organic exhaust gas according to claim 1, it is characterised in that: described
The first spongy layer (8) and the second spongy layer (9) be wet sponge.
3. vocs efficient treatment process in a kind of toxic organic exhaust gas according to claim 1, it is characterised in that: described
Taper tracheae (14) and burner (16) between be provided with ring of igniting (17), the ring of igniting (17) be annular, section
For half of ellipse;The ring of igniting (17) is internally provided with a main channel and a plurality of subchannel, and main channel connection is a plurality of
One end of subchannel, the other end are the hole of ring (17) outer surface of igniting.
Priority Applications (1)
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CN201811226357.6A CN109589741B (en) | 2018-10-22 | 2018-10-22 | VOCs treatment process in a kind of toxic organic exhaust gas |
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CN201811226357.6A CN109589741B (en) | 2018-10-22 | 2018-10-22 | VOCs treatment process in a kind of toxic organic exhaust gas |
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CN109589741A true CN109589741A (en) | 2019-04-09 |
CN109589741B CN109589741B (en) | 2019-08-16 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1222014B1 (en) * | 1999-10-22 | 2004-06-02 | Accentus plc | Method for plasma treatment of gases |
CN2897408Y (en) * | 2006-03-01 | 2007-05-09 | 钟礼晖 | Catalytic concentrating purifier for treating industrial organic waste gas |
CN102824822A (en) * | 2012-09-12 | 2012-12-19 | 南京工业大学 | Membrane separation air purification device |
CN203336605U (en) * | 2013-06-04 | 2013-12-11 | 江阴陆臣科技有限公司 | High-concentration/normal-concentration VOC gas processing device |
CN204816146U (en) * | 2015-07-29 | 2015-12-02 | 河北先河正源环境治理技术有限公司 | VOCs purifier |
CN106731483A (en) * | 2017-03-21 | 2017-05-31 | 上海兰宝环保科技有限公司 | It is suitable for the exhaust treatment system of high humility organic exhaust gas |
-
2018
- 2018-10-22 CN CN201811226357.6A patent/CN109589741B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1222014B1 (en) * | 1999-10-22 | 2004-06-02 | Accentus plc | Method for plasma treatment of gases |
CN2897408Y (en) * | 2006-03-01 | 2007-05-09 | 钟礼晖 | Catalytic concentrating purifier for treating industrial organic waste gas |
CN102824822A (en) * | 2012-09-12 | 2012-12-19 | 南京工业大学 | Membrane separation air purification device |
CN203336605U (en) * | 2013-06-04 | 2013-12-11 | 江阴陆臣科技有限公司 | High-concentration/normal-concentration VOC gas processing device |
CN204816146U (en) * | 2015-07-29 | 2015-12-02 | 河北先河正源环境治理技术有限公司 | VOCs purifier |
CN106731483A (en) * | 2017-03-21 | 2017-05-31 | 上海兰宝环保科技有限公司 | It is suitable for the exhaust treatment system of high humility organic exhaust gas |
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Address after: 5 / F, building A6, No. 9, Kechuang Avenue, Liuhe District, Nanjing City, Jiangsu Province 211500 Patentee after: Nanjing University environmental planning and Design Institute Group Co., Ltd Address before: 5 / F, building A6, No. 9, Kechuang Avenue, Liuhe District, Nanjing City, Jiangsu Province 211500 Patentee before: ACADEMY OF ENVIRONMENTAL PLANNING & DESIGN CO., LTD. NANJING University |
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