CN109589741A - Vocs efficient treatment process in a kind of toxic organic exhaust gas - Google Patents

Vocs efficient treatment process in a kind of toxic organic exhaust gas Download PDF

Info

Publication number
CN109589741A
CN109589741A CN201811226357.6A CN201811226357A CN109589741A CN 109589741 A CN109589741 A CN 109589741A CN 201811226357 A CN201811226357 A CN 201811226357A CN 109589741 A CN109589741 A CN 109589741A
Authority
CN
China
Prior art keywords
exhaust gas
tracheae
spongy layer
tipping tube
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811226357.6A
Other languages
Chinese (zh)
Other versions
CN109589741B (en
Inventor
腊孟珂
陆朝阳
余文敬
朱瑞瑞
胡琦玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing University environmental planning and Design Institute Group Co., Ltd
Original Assignee
Nanjing University Environmental Planning And Design Research Institute Stock Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing University Environmental Planning And Design Research Institute Stock Co filed Critical Nanjing University Environmental Planning And Design Research Institute Stock Co
Priority to CN201811226357.6A priority Critical patent/CN109589741B/en
Publication of CN109589741A publication Critical patent/CN109589741A/en
Application granted granted Critical
Publication of CN109589741B publication Critical patent/CN109589741B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0036Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/11Clays
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses vocs efficient treatment process in a kind of toxic organic exhaust gas, belong to exhaust-gas treatment field.Vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device, enrichment facility and burner, the purification device includes tipping tube and vertical pipe, and diagonally downward, the tipping tube upper end is active carbon layer to the tipping tube;The middle position of the tipping tube and vertical pipe is provided with one-way ventilating film, the one-way ventilating film both ends are respectively arranged with the first spongy layer and the second spongy layer, the second spongy layer upper end is provided with clay layer, it is provided with hydrophobic permeable membrane above the clay layer, is provided with organic solvent above the hydrophobic permeable membrane;The present invention is first by exhaust gas by adsorbing, then using degradation of burning is carried out after concentration, to utterly destroy vocs in toxic organic exhaust gas.

Description

Vocs efficient treatment process in a kind of toxic organic exhaust gas
Technical field
The present invention relates to exhaust-gas treatment fields, efficiently locate more specifically to vocs in a kind of toxic organic exhaust gas Science and engineering skill.
Background technique
VOCs is the english abbreviation of volatile organic compounds (volatile organic compounds);According to WHO It defines, volatile organic compounds (VOC) refers under normal pressure, 50 DEG C -260 DEG C of boiling point of various organic compounds.VOC presses it Chemical structure can be further divided into: alkanes, aromatic hydrocarbons, esters, aldehydes and other etc..What is identified at present has more than 300 Kind.It is most common to have benzene,toluene,xylene, styrene, trichloro ethylene, chloroform, trichloroethanes, diisocyanate (TDI), two isocyanide toluene esters etc.;In addition to formaldehyde, most volatile organic compounds are generally all not soluble in water and readily soluble In organic solvent.Their own concentration is frequently not very high indoors, but several VOC are collectively resided in room air When, synergy is very important.Since their types are more, the concentration of single component is low, and being usually used in TVOC indicates indoor In volatile organic compounds total amount.TVOC is to measure the indoor articles such as building interior trim finishing and furniture.To interior One important indicator of air quality influence degree;
The present invention provides a kind of effective method for handling the VOCS in toxic organic exhaust gas.
Summary of the invention
To solve the above problems, the present invention adopts the following technical scheme that.
Vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device, enrichment facility And burner, the purification device include tipping tube and vertical pipe, the tipping tube diagonally downward, the tipping tube Upper end is active carbon layer;The middle position of the tipping tube and vertical pipe is provided with one-way ventilating film, the one-way ventilating Film both ends are respectively arranged with the first spongy layer and the second spongy layer, and the second spongy layer upper end is provided with clay layer, described Clay layer above be provided with hydrophobic permeable membrane, be provided with organic solvent above the hydrophobic permeable membrane;
The burner includes vertical tracheae, and the inside of the vertical tracheae supports the bottom of taper tracheae by bracket End, the outer wall of the taper tracheae are provided with multiple ventholes, are provided with burner above the taper tracheae.
Preferably, first spongy layer and the second spongy layer are wet sponge.
Preferably, ring of igniting is provided between the taper tracheae and burner, the ring of igniting cuts for annular Face is half of ellipse;The ring of igniting is internally provided with a main channel and a plurality of subchannel, and main channel is connected to a plurality of point The one end in channel, the other end are the hole of ring outer surface of igniting.
Beneficial effect
Compared with the prior art, the present invention has the advantages that the present invention first by exhaust gas through absorption, then using concentration after Degradation of burning is carried out, to utterly destroy vocs in toxic organic exhaust gas.
Detailed description of the invention
Fig. 1 is process flow chart of the invention;
Fig. 2 is the structural schematic diagram of purification device of the present invention;
Fig. 3 is the structural schematic diagram of burner of the present invention;
Fig. 4 is the structural schematic diagram of taper tracheae of the present invention.
Figure label explanation:
1, purification device;2, enrichment facility;3, burner;4, tipping tube;5, vertical pipe;6, active carbon layer;7, one-way ventilating Film;8, the first spongy layer;9, the second spongy layer;10, clay layer;11, hydrophobic permeable membrane;12, organic solvent;13, vertical tracheae; 14, taper tracheae;15, venthole;16, combustion apparatus;17, it ignites ring.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention;Technical solution in the embodiment of the present invention carries out clear, complete Site preparation description;Obviously;Described embodiments are only a part of the embodiments of the present invention;Instead of all the embodiments.It is based on Embodiment in the present invention;It is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment;It shall fall within the protection scope of the present invention.
Please refer to Fig. 1-4, vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification dress Set 1, enrichment facility 2 and burner 3, purification device 1 includes tipping tube 4 and vertical pipe 5, tipping tube 4 diagonally downward, tipping tube 4 upper ends are active carbon layer 6;The middle position of tipping tube 4 and vertical pipe 5 is provided with one-way ventilating film 7,7 both ends of one-way ventilating film It is respectively arranged with the first spongy layer 8 and the second spongy layer 9,9 upper end of the second spongy layer is provided with clay layer 10,10 top of clay layer It is provided with hydrophobic permeable membrane 11, the top of hydrophobic permeable membrane 11 is provided with organic solvent 12;
Burner 3 includes vertical tracheae 13, and the inside of vertical tracheae 13 supports the bottom end of taper tracheae 14, taper by bracket The outer wall of tracheae 14 is provided with multiple ventholes 15, and the top of taper tracheae 14 is provided with burner 16.
First spongy layer 8 and the second spongy layer 9 are wet sponge.
Ring 17 of igniting is provided between taper tracheae 14 and burner 16, ring 17 of igniting is annular, and section is ellipse half It is round;Ring 17 of igniting is internally provided with a main channel and a plurality of subchannel, and main channel is connected to one end of a plurality of subchannel, another It holds as the hole for 17 outer surface of ring of igniting.
Working principle:
The exhaust gas being collected into is passed through to the upper end of tipping tube first, active carbon layer 6 is first passed around and is adsorbed, then passes through first Spongy layer 8 is full of moisture on first spongy layer 8, can adsorb exhaust gas formaldehyde at this time, pass through again after then passing through individual event ventilated membrane 7 The second spongy layer 9, the first spongy layer 8 and the second spongy layer 9 are crossed other than absorbing and being dissolved in the substance of water in exhaust gas, also has and stablizes The effect of individual event ventilated membrane 7, otherwise one-way ventilating film is under regular one-way ventilating effect, or gradually fenestra increases, and loses The effect of one-way ventilating;Then exhaust gas enters back into clay layer 10, continues the absorption of exhaust gas, then passes through hydrophobic permeable membrane again It enters in organic solvent;Absorption before entering back into organic solvent, primarily to by large particulate matter and exhaust gas in exhaust gas Temperature reduce and be dissolved in water substance absorption fall, subsequently into organic solvent, enter enrichment facility by the exhaust gas of purification It is concentrated in 2, subsequently into burner;
Exhaust gas enters in the vertical tracheae in burner, and gas can be divided into 2 parts, and 1 part does not fall under taper tracheae In, another part has entered in taper tracheae, and combustion apparatus jets out flames downwards at this time, and peripheral flame is in ring of igniting Under the action of, formed it is intermediate small, below big flame, in addition, dissipated outward from venthole into the flame in taper tracheae, from And flame flame envelope is more blown it is outside, under the action of flame flow, exhaust gas more towards vertical tracheae edge, and this When, by the effect of ignite ring and taper tracheae, the flame envelope of the edge of vertical tracheae is most, and passes through the process of flame more It is long;At the same time, it ignites and is additionally provided with channel inside ring, the combustion-supporting ingredient such as oxygen can be passed through, to main channel so as to reality Existing flame is more prosperous, to realize the more thorough combustion degradation of exhaust gas, realization reaches zero emission standards.
It is described above;It is merely preferred embodiments of the present invention;But scope of protection of the present invention is not limited thereto; Anyone skilled in the art is in the technical scope disclosed by the present invention;According to the technique and scheme of the present invention and its It improves design and is subject to equivalent substitution or change;It should be covered by the scope of protection of the present invention.

Claims (3)

1. vocs efficient treatment process in a kind of toxic organic exhaust gas, including sequentially connected purification device (1), enrichment facility (2) and burner (3), it is characterised in that: the purification device (1) includes tipping tube (4) and vertical pipe (5), described Diagonally downward, the tipping tube (4) upper end is active carbon layer (6) to tipping tube (4);The tipping tube (4) and vertical pipe (5) Middle position be provided with one-way ventilating film (7), described one-way ventilating film (7) both ends are respectively arranged with the first spongy layer (8) With the second spongy layer (9), described the second spongy layer (9) upper end is provided with clay layer (10), above the clay layer (10) It is provided with hydrophobic permeable membrane (11), organic solvent (12) is provided with above the hydrophobic permeable membrane (11);
The burner (3) includes vertical tracheae (13), and the inside of the vertical tracheae (13) passes through bracket cone of support The outer wall of the bottom end of shape tracheae (14), the taper tracheae (14) is provided with multiple ventholes (15), the taper tracheae (14) combustion apparatus (16) are provided with above.
2. vocs efficient treatment process in a kind of toxic organic exhaust gas according to claim 1, it is characterised in that: described The first spongy layer (8) and the second spongy layer (9) be wet sponge.
3. vocs efficient treatment process in a kind of toxic organic exhaust gas according to claim 1, it is characterised in that: described Taper tracheae (14) and burner (16) between be provided with ring of igniting (17), the ring of igniting (17) be annular, section For half of ellipse;The ring of igniting (17) is internally provided with a main channel and a plurality of subchannel, and main channel connection is a plurality of One end of subchannel, the other end are the hole of ring (17) outer surface of igniting.
CN201811226357.6A 2018-10-22 2018-10-22 VOCs treatment process in a kind of toxic organic exhaust gas Active CN109589741B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811226357.6A CN109589741B (en) 2018-10-22 2018-10-22 VOCs treatment process in a kind of toxic organic exhaust gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811226357.6A CN109589741B (en) 2018-10-22 2018-10-22 VOCs treatment process in a kind of toxic organic exhaust gas

Publications (2)

Publication Number Publication Date
CN109589741A true CN109589741A (en) 2019-04-09
CN109589741B CN109589741B (en) 2019-08-16

Family

ID=65957054

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811226357.6A Active CN109589741B (en) 2018-10-22 2018-10-22 VOCs treatment process in a kind of toxic organic exhaust gas

Country Status (1)

Country Link
CN (1) CN109589741B (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1222014B1 (en) * 1999-10-22 2004-06-02 Accentus plc Method for plasma treatment of gases
CN2897408Y (en) * 2006-03-01 2007-05-09 钟礼晖 Catalytic concentrating purifier for treating industrial organic waste gas
CN102824822A (en) * 2012-09-12 2012-12-19 南京工业大学 Membrane separation air purification device
CN203336605U (en) * 2013-06-04 2013-12-11 江阴陆臣科技有限公司 High-concentration/normal-concentration VOC gas processing device
CN204816146U (en) * 2015-07-29 2015-12-02 河北先河正源环境治理技术有限公司 VOCs purifier
CN106731483A (en) * 2017-03-21 2017-05-31 上海兰宝环保科技有限公司 It is suitable for the exhaust treatment system of high humility organic exhaust gas

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1222014B1 (en) * 1999-10-22 2004-06-02 Accentus plc Method for plasma treatment of gases
CN2897408Y (en) * 2006-03-01 2007-05-09 钟礼晖 Catalytic concentrating purifier for treating industrial organic waste gas
CN102824822A (en) * 2012-09-12 2012-12-19 南京工业大学 Membrane separation air purification device
CN203336605U (en) * 2013-06-04 2013-12-11 江阴陆臣科技有限公司 High-concentration/normal-concentration VOC gas processing device
CN204816146U (en) * 2015-07-29 2015-12-02 河北先河正源环境治理技术有限公司 VOCs purifier
CN106731483A (en) * 2017-03-21 2017-05-31 上海兰宝环保科技有限公司 It is suitable for the exhaust treatment system of high humility organic exhaust gas

Also Published As

Publication number Publication date
CN109589741B (en) 2019-08-16

Similar Documents

Publication Publication Date Title
CN205361016U (en) Volatile organic exhaust gas system is handled in ozone - biological filter combination
CN110562977A (en) Preparation method of biomass charcoal material with high specific surface area and toluene adsorption effect
CN105883804A (en) Preparation method of porous carbon nanomaterial for adsorbing methylene blue
CN109589741B (en) VOCs treatment process in a kind of toxic organic exhaust gas
CN107313131A (en) The active carbon filament environment-friendly materials and preparation method of a kind of rapid classification purification air
CN109569512A (en) A kind of preparation method and application of modified activated carbon absorbent
CN211631021U (en) Flowerpot capable of purifying air
CN109012612A (en) A kind of high-performance zeolite composite adsorbing material and its preparation method and application
CN206338538U (en) A kind of adjustable pipeline air exhaust water device
CN108404598A (en) Activated carbon adsorption and catalytic combustion system
CN205700066U (en) A kind of novel tower gas drying equipment
CN107140635A (en) Macropore biological activated carbon of adjustable pore space and its preparation method and application
CN105502377B (en) A kind of method of modifying of activated coco nut charcoal
CN206064147U (en) For the afforestation equipment of waste gas cleaning system
CN211358259U (en) Air purification filter screen
CN102492846B (en) Charcoal carries the enriching method of rare precious metal spent catalyst
CN209130908U (en) A kind of combustion-supporting equipment of VOCs treatment
CN204128868U (en) A kind of gaseous mercury volatilization device
CN203954989U (en) Exhaust gas adsorption device
CN208177495U (en) A kind of medical test rack for test tube
CN209423278U (en) A kind of Adsorption Concentration catalytic combustion device
CN203954926U (en) Waste gas recovering device
CN110523263A (en) Utilize the exhaust gas processing device and method of mineralized waste processing gas phase extracting tail gas
CN206793599U (en) A kind of abatement equipment of indoor decoration pollution gas
CN107376610A (en) A kind of kitchen emission-control equipment

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder

Address after: 5 / F, building A6, No. 9, Kechuang Avenue, Liuhe District, Nanjing City, Jiangsu Province 211500

Patentee after: Nanjing University environmental planning and Design Institute Group Co., Ltd

Address before: 5 / F, building A6, No. 9, Kechuang Avenue, Liuhe District, Nanjing City, Jiangsu Province 211500

Patentee before: ACADEMY OF ENVIRONMENTAL PLANNING & DESIGN CO., LTD. NANJING University

CP01 Change in the name or title of a patent holder