CN109588645A - A kind of compound water retaining agent and its application method improving bullfrog quality - Google Patents

A kind of compound water retaining agent and its application method improving bullfrog quality Download PDF

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Publication number
CN109588645A
CN109588645A CN201910048202.6A CN201910048202A CN109588645A CN 109588645 A CN109588645 A CN 109588645A CN 201910048202 A CN201910048202 A CN 201910048202A CN 109588645 A CN109588645 A CN 109588645A
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China
Prior art keywords
bullfrog
water retaining
retaining agent
compound water
quality
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CN201910048202.6A
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Chinese (zh)
Inventor
唐春霞
任发政
鲍敏
陈冲
王鹏杰
张琪
王境波
刘建国
杨雪红
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New (shanghai) Catering Management Co Ltd
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New (shanghai) Catering Management Co Ltd
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Priority to CN201910048202.6A priority Critical patent/CN109588645A/en
Publication of CN109588645A publication Critical patent/CN109588645A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/432Addition of inorganic compounds, e.g. minerals; oligo-elements
    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22BSLAUGHTERING
    • A22B5/00Accessories for use during or after slaughtering
    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22BSLAUGHTERING
    • A22B5/00Accessories for use during or after slaughtering
    • A22B5/0005Eviscerating devices, e.g. removing rectum, anus, intestines, brain tissue, hypophysis
    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22BSLAUGHTERING
    • A22B5/00Accessories for use during or after slaughtering
    • A22B5/0017Apparatus for cutting, dividing or deboning carcasses
    • A22B5/0052Severing the head or the jaw of a carcass, slaughterhouse operations on animal heads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Neurosurgery (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

The present invention provides a kind of compound water retaining agents and its application method for improving bullfrog quality, the raw material of the compound water retaining agent includes polyphosphate and sodium bicarbonate, polyphosphate is in alkalinity, the pH of bullfrog meat can be improved, it can also be in conjunction with the protein bound polyvalent metal ion of myoarchitecture, make the carboxyl separate out in protein, make protein belt negative electrical charge, increases the electrostatic repulsion between carboxyl.Polyphosphate can provide stronger ionic strength, can increase the solubility of fribrillin etc., be conducive to muscle protein and be changed into rarefaction, can also dissociate actomyosin, increase the retentiveness of meat, while further improving the tenderness of meat.Sodium bicarbonate also can provide alkaline environment, and increase the bulkiness of meat, and making bullfrog, albumen network structure is more loose after treatment, and retentiveness significantly increases, and tenderness is improved, to improve the edible quality of bullfrog, further expand the market of bullfrog.

Description

A kind of compound water retaining agent and its application method improving bullfrog quality
Technical field
The invention belongs to food processing technology field, in particular to a kind of compound water retaining agent for improving bullfrog quality and its answer Use method.
Background technique
Bullfrog originates in eastern United States, introduces China inland later, is a kind of large edible frog, and China gives birth to mainly by cultivation It produces, because its delicious meat is delicate and full of nutrition, low fat high protein, increasingly by the favor of the majority of consumers.Current bullfrog It is main by butchering, freezing, the processing technologys such as cold storage are made into frozen product and are sold.However bullfrog product presently, there are Main problem is that its retentiveness reduces after thawing, and causes a large amount of juice loss.Juice loss has not only seriously affected bullfrog Subsequent processing quality causes its mouthfeel to harden, and tenderness is poor, also reduces the nutritive value of bullfrog.
It is currently used be used to improve bullfrog tenderness, the method that improves its water-retaining property be with applied to pork, beef and The water-retaining agent of the flesh of fish etc. to bullfrog carries out jelly pre-treatment, but as the enterprise for seeking large-scale development, it should possess oneself With targetedly key foundation formula, and because of the content and class of connective tissue, fribrillin of different meats etc. Type is different, and same water-retaining agent is variant to the Water-saving effect of different meats, and most suitable activity is also different, existing water conservation technology It is lack of pertinence, causes the water holding capacity of last bullfrog poor, mouthfeel is hardened.
Summary of the invention
In view of the above-mentioned problems, the object of the present invention is to provide a kind of compound water retaining agent for improving bullfrog quality and its application sides Method.Bullfrog is handled using the compound water retaining agent, the retentiveness of bullfrog can be increased, improve its tenderness, to improve the food of bullfrog With quality, the market of bullfrog is further expanded.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of compound water retaining agent improving bullfrog quality, raw material includes polyphosphate and sodium bicarbonate, the weight of the raw material Portion rate are as follows:
Polyphosphate 0.1 ~ 1.5
Sodium bicarbonate 0.1 ~ 3.
Further, the polyphosphate include one of sodium pyrophosphate, sodium tripolyphosphate and calgon or It is several.
Further, in the compound water retaining agent each raw material weight fraction ratio are as follows:
Sodium pyrophosphate 0.1 ~ 0.5
Sodium tripolyphosphate 0.1 ~ 0.5
Calgon 0.1 ~ 0.5
Sodium bicarbonate 0.1 ~ 3.
Further, in the compound water retaining agent each raw material weight fraction ratio are as follows:
Sodium pyrophosphate 0.2
Sodium tripolyphosphate 0.3
Calgon 0.1
Sodium bicarbonate 2.
In order to solve the above technical problems, the answering in the processing of bullfrog meat the present invention also provides the compound water retaining agent With.
It is another object of the present invention to what is be achieved through the following technical solutions:
A method of bullfrog is handled using the compound water retaining agent, comprising the following steps:
(1) pre-treatment of bullfrog: by bullfrog slaughter, impregnating 5-10min after removing frog head and front and back toe in water purification, rear to remove Internal organ, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in water conservation buffer In, tumbling 2-5h;
The water conservation buffer is dissolved by compound water retaining agent according to any one of claims 1-4 to be made;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, quick-frozen 5- 15min, freezing are placed on -20 DEG C to get freezing bullfrog is arrived.
Further, the mass percent of each raw material is respectively as follows: in the water conservation buffer
Sodium pyrophosphate 0.1 ~ 0.5%
Sodium tripolyphosphate 0.1 ~ 0.5%
Calgon 0.1 ~ 0.5%
Sodium bicarbonate 0.1 ~ 3%.
Further, the temperature of step (2) the compound water retaining agent processing is 2 DEG C ~ 10 DEG C.
The action principle of compound water retaining agent of the present invention, as shown in Figure 1:
Water-retaining property refers to that meat products in pressurization, chopping, heating, freezing, defrosting and the processing such as marinated or storage, is kept The ability of its Free water.Retentiveness is affected by pH value, and the retention ability of meat products is minimum at isoelectric point (pI), increases its pH Value will improve meat products retentiveness far from pI.Tenderness refer to meat when edible mouthfeel it is old tender, reacted the quality of meat.Shadow The essence for ringing Meat Tenderness is mainly the content of connective tissue and the chemical structure and state of property and fribrillin.Structure Main component at connective tissue is collagen, and content and wherein thermal stability interlinkage number of keys difference, tenderness is also different, The tenderness of meat is improved it is necessary to try the content of collagen in reduction meat.Fribrillin includes actin, flesh ball egg White and actomyosin, the content of fribrillin reduces in meat, and the tenderness of meat can also improve.
The mechanism of action that phosphate improves meat mainly has the following: first is that improving the pH of meat, deviateing the pI of meat albumen. The increase of pH value will lead to electrostatic repulsion between meat albumen or internal, improve retention ability.Second is that chelated metal ions, make albumen The carboxyl of matter is free, increases the electrostatic repulsion between carboxyl, makes protein structure relaxation, the infiltration and diffusion to moisturize.Third is that mentioning For stronger ionic strength, albumen solubility is improved, the crosslinking of collagen is reduced, increases the dissolution of fribrillin, add Protective film, which is formed, on meat surface when hot reduces cooking loss.Fourth is that dissociation actomyosin, increases meat retentiveness, improves simultaneously Tenderness.In addition phosphate has slight fungistatic effect and antioxidation.Sodium bicarbonate is a kind of alkaline leavening agent, appropriate meeting Make meat that certain bulkiness be presented, in addition sodium bicarbonate is in alkalinity, adjustable pH.
The present invention having the beneficial effect that compared with prior art
1, the present invention is directed to the architectural characteristic of bullfrog itself musculature, and having investigated there is best Water-saving effect to have bullfrog Ingredient to be imitated, further experiment is carried out to these effective components and obtains best complex formula, finally obtained bullfrog is best in quality, and one Aspect is to improve the solubility of fribrillin etc., increases the dissolution of actomyosin, on the other hand increases the swollen of meat Song Xing, making bullfrog, albumen network structure is more loose after treatment, and retention ability significantly increases, while also improving the tenderness of meat;
2, in the method for the present invention using compound water retaining agent processing bullfrog, the slaughter process of bullfrog is soaked after removing frog head Remove internal organ after bubble again, in this way processing can abundant bloodletting, make the good color of the presentation of finished product;In addition keep compound water retaining agent molten The temperature of liquid is 4 DEG C or so, and such cryogenic conditions help to inhibit the growth and breeding of microorganism, preferably keeps bullfrog meat Quality.
Detailed description of the invention
Fig. 1 is the action principle schematic diagram of compound water retaining agent of the present invention;
Fig. 2 is the cooking loss measurement result schematic diagram of different group bullfrogs in embodiment 1;
Fig. 3 is the elasticity measurement result schematic diagram of different group bullfrogs in embodiment 1;
Fig. 4 is the chewiness measurement result schematic diagram of different group bullfrogs in embodiment 1;
Fig. 5 is the cooking loss measurement result schematic diagram of different group bullfrogs in embodiment 2;
Fig. 6 is the elasticity measurement result schematic diagram of different group bullfrogs in embodiment 2;
Fig. 7 is the chewiness measurement result schematic diagram of different group bullfrogs in embodiment 2;
Fig. 8 is the cooking loss measurement result schematic diagram of different group bullfrogs in embodiment 3;
Fig. 9 is the elasticity measurement result schematic diagram of different group bullfrogs in embodiment 3;
Figure 10 is the chewiness measurement result schematic diagram of different group bullfrogs in embodiment 3;
Figure 11 is the cooking loss measurement result schematic diagram of different group bullfrogs in embodiment 4;
Figure 12 is the elasticity measurement result schematic diagram of different group bullfrogs in embodiment 4;
Figure 13 is the chewiness measurement result schematic diagram of different group bullfrogs in embodiment 4;
1-4 in Fig. 2-Figure 13 is respectively indicated:
1 indicates the bullfrog without any processing, i.e. blank group, and 2 and 3 indicate the bullfrog of two kinds of brands available on the market, 4 tables Show the bullfrog of compound water retaining agent processing.
Specific embodiment
The present invention is further explained in the light of specific embodiments, but the present invention is not limited to following embodiments.
It is conventional method unless otherwise specified in following embodiments.
Embodiment 1
A kind of compound water retaining agent for improving bullfrog quality is present embodiments provided, raw material includes polyphosphate and sodium bicarbonate, The weight fraction ratio of the raw material are as follows:
Sodium pyrophosphate 0.3
Sodium tripolyphosphate 0.3
Calgon 0.1
Sodium bicarbonate 1.
Each raw material is weighed according to aforementioned proportion, water conservation buffer is formulated as, makes the sodium pyrophosphate, sodium tripolyphosphate, six The mass percent of sodium metaphosphate and sodium bicarbonate is respectively 0.3%, 0.3%, 0.1% and 1%.
Bullfrog, specific steps are handled using the compound water retaining agent are as follows:
(1) pre-treatment of bullfrog: by bullfrog slaughter, 8min is impregnated in water purification after removing frog head and front and back toe, in rear removal It is dirty, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in 4 DEG C of above-mentioned guarantor In water buffer, tumbling 2h;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, quick-frozen 5min, Freezing is placed on -20 DEG C to get freezing bullfrog is arrived.
The freezing bullfrog that will be obtained carries out the detection of cooking loss, elasticity and chewiness respectively, and concrete outcome is as follows:
As shown in Fig. 2, the cooking loss minimum obtained using the bullfrog that this composite water conservation agent prescription is handled, substantially less than blank group With commercially available two groups.
As shown in figure 3, it is best using the elasticity that the bullfrog that this composite water conservation agent prescription is handled obtains, significantly due to blank group With commercially available two groups.
As shown in figure 4, it is optimal using the chewiness that the bullfrog that this composite water conservation agent prescription is handled obtains, it is significantly better than blank It organizes and commercially available two groups.
Embodiment 2
A kind of compound water retaining agent for improving bullfrog quality is present embodiments provided, raw material includes polyphosphate and sodium bicarbonate, The weight fraction ratio of the raw material are as follows:
Sodium pyrophosphate 0.2
Sodium tripolyphosphate 0.3
Calgon 0.1
Sodium bicarbonate 2.
Each raw material is weighed according to aforementioned proportion, water conservation buffer is formulated as, makes the sodium pyrophosphate, sodium tripolyphosphate, six The mass percent of sodium metaphosphate and sodium bicarbonate is respectively 0.2%, 0.3%, 0.1% and 2%.
Bullfrog, specific steps are handled using the compound water retaining agent are as follows:
(1) pre-treatment of bullfrog: by bullfrog slaughter, 5min is impregnated in water purification after removing frog head and front and back toe, in rear removal It is dirty, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in 4 DEG C of above-mentioned guarantor In water buffer, tumbling 3h;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, it is quick-frozen 10min, freezing are placed on -20 DEG C to get freezing bullfrog is arrived.
The freezing bullfrog that will be obtained carries out the detection of cooking loss, elasticity and chewiness respectively, and concrete outcome is as follows:
As shown in figure 5, the cooking loss minimum obtained using the bullfrog that this composite water conservation agent prescription is handled, substantially less than blank group With commercially available two groups.
As shown in fig. 6, it is best using the elasticity that the bullfrog that this composite water conservation agent prescription is handled obtains, significantly due to blank group With commercially available two groups.
As shown in fig. 7, it is optimal using the chewiness that the bullfrog that this composite water conservation agent prescription is handled obtains, it is significantly better than blank It organizes and commercially available two groups.
Embodiment 3
A kind of compound water retaining agent for improving bullfrog quality is present embodiments provided, raw material includes polyphosphate and sodium bicarbonate, The weight fraction ratio of the raw material are as follows:
Sodium pyrophosphate 0.3
Sodium tripolyphosphate 0.4
Sodium bicarbonate 1.
Each raw material is weighed according to aforementioned proportion, water conservation buffer is formulated as, makes the sodium pyrophosphate, sodium tripolyphosphate and carbon The mass percent of sour hydrogen sodium is respectively 0.3%, 0.4% and 1%.
Bullfrog, specific steps are handled using the compound water retaining agent are as follows:
(1) pre-treatment of bullfrog: by bullfrog slaughter, 8min is impregnated in water purification after removing frog head and front and back toe, in rear removal It is dirty, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in 4 DEG C of above-mentioned guarantor In water buffer, tumbling 2h;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, quick-frozen 5min, Freezing is placed on -20 DEG C to get freezing bullfrog is arrived.
The freezing bullfrog that will be obtained carries out the detection of cooking loss, elasticity and chewiness respectively, and concrete outcome is as follows:
As shown in figure 8, the cooking loss minimum obtained using the bullfrog that this composite water conservation agent prescription is handled, substantially less than blank group With commercially available two groups.
As shown in figure 9, it is best using the elasticity that the bullfrog that this composite water conservation agent prescription is handled obtains, significantly due to blank group With commercially available two groups.
As shown in Figure 10, the chewiness obtained using the bullfrog that this composite water conservation agent prescription is handled is optimal, is significantly better than sky White group and two groups commercially available.
Embodiment 4
A kind of compound water retaining agent for improving bullfrog quality is present embodiments provided, raw material includes polyphosphate and sodium bicarbonate, The weight fraction ratio of the raw material are as follows:
Sodium tripolyphosphate 0.4
Calgon 0.3
Sodium bicarbonate 2.
Weigh each raw material according to aforementioned proportion, be formulated as water conservation buffer, make the sodium tripolyphosphate, calgon and The mass percent of sodium bicarbonate is respectively 0.4%, 0.3% and 2%.
Bullfrog, specific steps are handled using the compound water retaining agent are as follows:
(1) pre-treatment of bullfrog: by bullfrog slaughter, 8min is impregnated in water purification after removing frog head and front and back toe, in rear removal It is dirty, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in 4 DEG C of above-mentioned guarantor In water buffer, tumbling 2h;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, quick-frozen 5min, Freezing is placed on -20 DEG C to get freezing bullfrog is arrived.
The freezing bullfrog that will be obtained carries out the detection of cooking loss, elasticity and chewiness respectively, and concrete outcome is as follows:
As shown in figure 11, the cooking loss obtained using the bullfrog that this composite water conservation agent prescription is handled is minimum, substantially less than blank It organizes and commercially available two groups.
As shown in figure 12, the elasticity obtained using the bullfrog that this composite water conservation agent prescription is handled is best, significantly due to blank It organizes and commercially available two groups.
As shown in figure 13, the chewiness obtained using the bullfrog that this composite water conservation agent prescription is handled is optimal, is significantly better than sky White group and two groups commercially available.

Claims (8)

1. a kind of compound water retaining agent for improving bullfrog quality, which is characterized in that the raw material of the compound water retaining agent includes poly phosphorus Hydrochlorate and sodium bicarbonate, the weight fraction ratio of the raw material are as follows:
Polyphosphate 0.1 ~ 1.5
Sodium bicarbonate 0.1 ~ 3.
2. the compound water retaining agent according to claim 1 for improving bullfrog quality, which is characterized in that the polyphosphate packet Include one or more of sodium pyrophosphate, sodium tripolyphosphate and calgon.
3. the compound water retaining agent according to claim 1 or 2 for improving bullfrog quality, which is characterized in that the composite water conservation The weight fraction ratio of each raw material in agent are as follows:
Sodium pyrophosphate 0.1 ~ 0.5
Sodium tripolyphosphate 0.1 ~ 0.5
Calgon 0.1 ~ 0.5
Sodium bicarbonate 0.1 ~ 3.
4. the compound water retaining agent according to claim 3 for improving bullfrog quality, which is characterized in that in the compound water retaining agent The weight fraction ratio of each raw material are as follows:
Sodium pyrophosphate 0.2
Sodium tripolyphosphate 0.3
Calgon 0.1
Sodium bicarbonate 2.
5. application of the described in any item compound water retaining agents of claim 1-4 in the processing of bullfrog meat.
6. a kind of method using the compound water retaining agent processing bullfrog as described in claim any one of 1-4, which is characterized in that described Method the following steps are included:
(1) pre-treatment of bullfrog: by bullfrog slaughter, impregnating 5-10min after removing frog head and front and back toe in water purification, rear to remove Internal organ, peeling, cleaning, the bullfrog after being cleaned;
(2) compound water retaining agent is handled: by the bullfrog after step (1) pre-treatment is cleaned, being soaked in water conservation buffer In, tumbling 2-5h;
The water conservation buffer is dissolved by compound water retaining agent according to any one of claims 1-4 to be made;
(3) bullfrog freezes and stores: will through step (2) compound water retaining agent, treated that bullfrog is placed in liquid nitrogen, quick-frozen 5- 15min, freezing are placed on -20 DEG C to get freezing bullfrog is arrived.
7. according to the method described in claim 6, it is characterized in that, the mass percent of each raw material is divided in the water conservation buffer Not are as follows:
Sodium pyrophosphate 0.1 ~ 0.5%
Sodium tripolyphosphate 0.1 ~ 0.5%
Calgon 0.1 ~ 0.5%
Sodium bicarbonate 0.1 ~ 3%.
8. according to the method described in claim 6, it is characterized in that, the temperature of step (2) the compound water retaining agent processing is 2 DEG C ~10℃。
CN201910048202.6A 2019-01-18 2019-01-18 A kind of compound water retaining agent and its application method improving bullfrog quality Pending CN109588645A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN111084337A (en) * 2019-12-18 2020-05-01 江苏省农业科学院 Method for improving water-retaining property and quality of meat product
CN113973900A (en) * 2021-10-22 2022-01-28 集美大学 Method for freezing and refreshing bullfrogs
CN114176196A (en) * 2021-11-10 2022-03-15 湖北省兴发磷化工研究院有限公司 Frozen bullfrog quality improving method
CN114304543A (en) * 2021-12-16 2022-04-12 湖北省兴发磷化工研究院有限公司 Crab leg meat processing method

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CN106912554A (en) * 2017-03-03 2017-07-04 福清朝辉水产食品有限公司 A kind of phosphate-free water-retaining agent and its application method for peeled shrimp
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CN103564520A (en) * 2013-11-21 2014-02-12 北京美添前景科技有限公司 Efficient water-holding color retention agent for meat products, and preparing and using methods thereof
CN103976324A (en) * 2014-05-30 2014-08-13 辽宁禾丰食品有限公司 Rattan pepper-flavor quick-frozen chicken breast seasoning formula and using method thereof
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Publication number Priority date Publication date Assignee Title
CN111084337A (en) * 2019-12-18 2020-05-01 江苏省农业科学院 Method for improving water-retaining property and quality of meat product
CN113973900A (en) * 2021-10-22 2022-01-28 集美大学 Method for freezing and refreshing bullfrogs
CN114176196A (en) * 2021-11-10 2022-03-15 湖北省兴发磷化工研究院有限公司 Frozen bullfrog quality improving method
CN114304543A (en) * 2021-12-16 2022-04-12 湖北省兴发磷化工研究院有限公司 Crab leg meat processing method

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