CN109579608A - A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger - Google Patents

A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger Download PDF

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Publication number
CN109579608A
CN109579608A CN201811627374.0A CN201811627374A CN109579608A CN 109579608 A CN109579608 A CN 109579608A CN 201811627374 A CN201811627374 A CN 201811627374A CN 109579608 A CN109579608 A CN 109579608A
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China
Prior art keywords
heat exchanger
cleaning
outer cover
electromagnetic valve
cleaning solution
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Pending
Application number
CN201811627374.0A
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Chinese (zh)
Inventor
余成鹏
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Hangzhou Jianyi Technology Co Ltd
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Hangzhou Jianyi Technology Co Ltd
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Application filed by Hangzhou Jianyi Technology Co Ltd filed Critical Hangzhou Jianyi Technology Co Ltd
Priority to CN201811627374.0A priority Critical patent/CN109579608A/en
Publication of CN109579608A publication Critical patent/CN109579608A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G9/00Cleaning by flushing or washing, e.g. with chemical solvents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Cleaning In General (AREA)

Abstract

The present invention relates to technical field of heat exchangers, and disclose the Fouling Cleaning equipment and its control method of a kind of tubular heat exchanger, including outer cover of heat exchanger, the left and right sides of the outer cover of heat exchanger is fixedly installed with the first installing pipe for importing fluid low in calories and the second mounting plate for exporting fluid low in calories respectively, the left and right sides of the outer cover of heat exchanger inner cavity is welded with fixed plate, the outer surface of two fixed plates and the inner surface of outer cover of heat exchanger are welding, are fixedly installed with catheter between two outer cover of heat exchanger.The Fouling Cleaning equipment and its control method of the tubular heat exchanger, cooperate the intelligent inside for entering outer cover of heat exchanger using cleaning solution solenoid valve control cleaning solution of PH meter by control cabinet, it ensure that cleaning solution dosage becomes more accurate, avoid the problem of cleaning solution dosage excessively causes cleaning wastage of material, again because of the reduction of cleaning solution dosage, while reducing the subsequent burden to cleaning solution secondary treatment.

Description

A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger
Technical field
The present invention relates to technical field of heat exchangers, the Fouling Cleaning equipment and its manipulation of specially a kind of tubular heat exchanger Method.
Background technique
The horizontal tubular heat exchanger used now takes high temperature wastewater to carry out heat recovery conversion, since waste liquid is work Industry waste liquid, can be in pipeline outer wall fouling, since tubular heat exchanger is to guarantee whole sealing in tubular heat exchanger containing impurity Property, it is non-dismountable equipment, causes cleaning difficulty big.
The cleaning way of existing tubular heat exchanger takes chemical cleaning, is chemically to be equipped with acidic chemical cleaning agent It pours into and carries out soaking wash cycles inside heat exchanger, when cleaning needs a large amount of acidic cleaner, because these cleaning agents are all Chemicals (such as hydrochloric acid, sulfuric acid and corrosion inhibiter) configures, and reaches heat exchanger cleaning effect, such processing mode there are still Following problems:
One, since tubular heat exchanger can not be dismantled, internal soil content can not confirm, cause the dosage of cleaning agent that can not determine, Dosage is very few to cause dirt that can not be removed totally, so as to cause heat exchanger local stoppages, so that heated effluent can not be successfully discharge, Influence the efficiency of subsequent waste liquid hot-cast socket;Dosage excessively causes the waste of cleaning agent again, while occurring discharge waste liquid again and needing The problem of secondary treatment, increases the cost of liquid waste processing.
Although two, the inside and outside wall of heat exchanger internal pipeline all does transpassivation processing, since cleaning agent needs in heat exchanger Portion's residence time is long, stops meeting heat exchanging device for a long time and is corrosive, greatly wears and tears the passivating film inside heat exchanger, very To the problem of damaging heat exchanger tube, heat exchanger caused to damage.
Summary of the invention
The present invention provides the Fouling Cleaning equipment and its control method of a kind of tubular heat exchanger, have cleaning agent materials Precisely with etch-proof advantage, solves existing Process of Chemical Cleaning cleaning agent dosage waste and increase subsequent treatment cost and cleaning The problem of corrosion bad heat exchanger.
The invention provides the following technical scheme: a kind of Fouling Cleaning equipment of tubular heat exchanger, including outer cover of heat exchanger, The left and right sides of the outer cover of heat exchanger is fixedly installed with the first installing pipe for importing fluid low in calories and respectively for leading Second mounting plate of fluid low in calories out, the left and right sides of the outer cover of heat exchanger inner cavity are welded with fixed plate, two fixations The outer surface of plate and the inner surface of outer cover of heat exchanger are welding, are fixedly installed with catheter between two outer cover of heat exchanger, The both ends of the catheter extend through two fixed plates, and the bottom of the outer cover of heat exchanger inner cavity is fixedly installed with positioned at drain The first steadying plate outside pipe is fixedly installed with second outside catheter at the top of the outer cover of heat exchanger inner cavity and stablizes Plate, the left and right sides of the outer cover of heat exchanger top surface are fixedly installed with inlet tube and drain between two fixed plates respectively It manages, is fixedly installed with tee tube at the top of the inlet tube, be communicated at the top of the tee tube due to importing high heat fluid Input pipe, be communicated with for exporting high heat fluid, cleaning solution and the liquid suction pipe of passivating solution at the top of the drain pipe, it is described Control cabinet is placed at the top of outer cover of heat exchanger, the inside of the control cabinet is equipped with electric signal transducer and time-delay relay, And the output end of electric signal transducer and the input terminal of time-delay relay are electrically connected, the right side of the control cabinet passes through conducting wire electricity Property be connected with positioned at liquid suction pipe positive PH meter, the sensing head of the PH meter is placed on the interior of outer cover of heat exchanger by drain pipe Portion, the left and right sides of the tee tube passes through conduit and is fixedly installed with cleaning liquid electromagnetic valve and passivation liquid electromagnetic valve, described clear The output end of washing lotion solenoid valve and the input terminal and control cabinet that clean liquid electromagnetic valve is electrically connected.
Optionally, second steadying plate is located at the right of the first steadying plate, and the quantity of first steadying plate is three, The top of three first steadying plates and the bottom of the second steadying plate offer jagged.
Optionally, the input pipe is interconnected when heat exchanger runs well with inlet tube.
Optionally, the fixed plate and catheter junction are equipped with seal rubber.
Optionally, control method is as follows:
Step 1: cleaning liquid electromagnetic valve is in starting state first, passivation liquid electromagnetic valve is in off state, by opening cleaning solution To cleaning solution is injected inside outer cover of heat exchanger, the liquid of liquid suction pipe heat exchanging device interior of shell continues drawing liquid, PH is counted solenoid valve It is placed in drain pipe, then the pH value of PH meter detection cleaning solution, the pH value that PH meter will test are imported in control cabinet by conducting wire Electric signal transducer;
Step 2: electric signal transducer input signal closes cleaning liquid electromagnetic valve at this time when pH value is neutral, at the same be delayed after The electric appliance trigger predetermined time then opens passivation liquid electromagnetic valve and injects passivating solution, when the induction end of PH meter senses heat exchange The passivating solution of device interior of shell;
Step 3: taking out PH meter, passivating solution is extracted out by liquid suction pipe, completes the cleaning and passivation of heat exchanging device shell.
Optionally, the left end of the cleaning liquid electromagnetic valve is communicated with cleaning solution ingress pipe, the right side of the passivation liquid electromagnetic valve End is communicated with passivating solution ingress pipe.
Optionally, it is low concentration cleaning solution that the cleaning solution that liquid electromagnetic valve imports is cleaned in the first step.
Optionally, time-delay relay delay time and liquid suction pipe take out the cleaning solution institute inside fixed plate to the greatest extent in the third step It takes time consistent, avoids passivating solution and mix to reduce Passivation Treatment effect with cleaning solution.
Optionally, the signal adapter is pulse signal converter, model 4-20ma series, so that signal transmits For space state, and interval time and cleaning liquid electromagnetic valve and to be passivated liquid electromagnetic valve valve opening time consistent.
The present invention have it is following the utility model has the advantages that
1, the Fouling Cleaning equipment and its control method of the tubular heat exchanger cooperates PH meter intelligent using clear by control cabinet Washing lotion solenoid valve control cleaning solution enters the inside of outer cover of heat exchanger, ensure that cleaning solution dosage becomes more accurate, avoids Cleaning solution dosage excessively cause cleaning wastage of material the problem of, and because cleaning solution dosage reduction, while reduce it is subsequent right The burden of cleaning solution secondary treatment.
2, the Fouling Cleaning equipment and its control method of the tubular heat exchanger cooperates the intelligent benefit of PH meter by control cabinet The inside for entering outer cover of heat exchanger with passivating solution solenoid valve control passivating solution, allows passivating solution to timely enter outer cover of heat exchanger Inside, avoid cleaning solution and rest on the inside of outer cover of heat exchanger for a long time and cause the outside of catheter by corrosion leakage Problem, while also ensuring the timeliness of Passivation Treatment.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention;
Fig. 2 is flow diagram of the present invention;
Fig. 3 is the first steadying plate structural schematic diagram of the invention;
Fig. 4 is the second steadying plate structural schematic diagram of the invention.
In figure: 1, outer cover of heat exchanger;11, fixed plate;12, catheter;13, the first steadying plate;14, the second steadying plate;15, First installing pipe;16, the second mounting plate;17, inlet tube;18, drain pipe;2, control cabinet;21, PH is counted;22, conducting wire;23, it is passivated Liquid electromagnetic valve;24, liquid electromagnetic valve is cleaned;3, liquid suction pipe;4, tee tube;5, input pipe.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Please refer to Fig. 1-4, a kind of Fouling Cleaning equipment of tubular heat exchanger, including outer cover of heat exchanger 1, outer cover of heat exchanger 1 left and right sides is fixedly installed with the first installing pipe 15 for importing fluid low in calories and respectively for exporting fluid low in calories The second mounting plate 16, the left and right sides of 1 inner cavity of outer cover of heat exchanger is welded with fixed plate 11, and the second steadying plate 14 is located at first The right of steadying plate 13, the quantity of the first steadying plate 13 are three, the top of three the first steadying plates 13 and the second steadying plate 14 Bottom offer jagged, component of the cleaning solution to the greatest extent between two fixed plates 11 is connect Touching, avoids the catheter 12 positioned at bottom and is difficult to thoroughly contact with cleaning solution, to guarantee the quality of cleaning process, two solid The outer surface of fixed board 11 and the inner surface of outer cover of heat exchanger 1 are welding, are fixedly installed with catheter between two outer cover of heat exchanger 1 12, the both ends of catheter 12 extend through two fixed plates 11, and the bottom of 1 inner cavity of outer cover of heat exchanger is fixedly installed with positioned at drain The first steadying plate 13 outside pipe 12, second be fixedly installed at the top of 1 inner cavity of outer cover of heat exchanger outside catheter 12 Steadying plate 14, the left and right sides of 1 top surface of outer cover of heat exchanger are fixedly installed with the inlet tube between two fixed plates 11 respectively 17 and drain pipe 18, the top of inlet tube 17 is fixedly installed with tee tube 4, and the top of tee tube 4 is communicated with due to importing high fever The input pipe 5 of fluid is measured, input pipe 5 is interconnected when heat exchanger runs well with inlet tube 17, and the top of drain pipe 18 connects It is connected with the liquid suction pipe 3 for exporting high heat fluid, cleaning solution and passivating solution, the top of outer cover of heat exchanger 1 is placed with control cabinet 2, the inside of control cabinet 2 is equipped with electric signal transducer and time-delay relay, and signal adapter is pulse signal converter, type Number for 4-20ma series, so that signal is transmitted as space state, and interval time and cleaning liquid electromagnetic valve 24 and it is passivated liquid electromagnetic 23 valve opening time of valve is consistent, and the input terminal of the output end of electric signal transducer and time-delay relay is electrically connected, control The right side of case 2 processed is electrically connected with by conducting wire 22 passes through drain positioned at the sensing head that the positive PH of liquid suction pipe 3 counts 21, PH meter 21 Pipe 18 is placed on the inside of outer cover of heat exchanger 1, and fixed plate 11 and 12 junction of catheter are equipped with seal rubber, so that two fixations Liquid between plate 11 will not leak to the inside of fixed plate 11, ensure that the liquid inside fixed plate 11 in heat transfer process In non-contaminated state, the left and right sides of tee tube 4 passes through conduit and is fixedly installed with cleaning liquid electromagnetic valve 24 and passivation liquid electromagnetic The output end of valve 23, the input terminal and control cabinet 2 that clean liquid electromagnetic valve 24 and clean liquid electromagnetic valve 24 is electrically connected.
Optionally, control method is as follows:
Step 1: cleaning liquid electromagnetic valve 24 is in starting state first, passivation liquid electromagnetic valve 23 is in off state, it is clear by opening Washing lotion solenoid valve 24 is communicated with cleaning solution importing to cleaning solution, the left end of cleaning liquid electromagnetic valve 24 is injected inside outer cover of heat exchanger 1 The right end of pipe, passivation liquid electromagnetic valve 23 is communicated with passivating solution ingress pipe, and the liquid inside 3 heat exchanging device shell 1 of liquid suction pipe continues PH meter 21 is placed in drain pipe 18 by drawing liquid, and then the pH value of 21 detection cleaning solution of PH meter, the pH value that PH meter 21 will test are logical The electric signal transducer that conducting wire 22 imports in control cabinet 2 is crossed, the cleaning solution that cleaning liquid electromagnetic valve 24 imports in the first step is low dense Cleaning solution is spent, so that cleaning agent dosage be avoided excessively to cause cleaning wastage of material and ask erosion outside fixed plate 11 is excessive Topic;
Step 2: electric signal transducer input signal closes cleaning liquid electromagnetic valve 24 at this time when pH value is neutral, it is delayed simultaneously The relay trigger predetermined time then opens passivation liquid electromagnetic valve 23 and injects passivating solution, when the induction end induction of PH meter 21 Passivating solution to inside outer cover of heat exchanger 1;
Step 3: taking out PH meter 21, passivating solution is extracted out by liquid suction pipe 3, completes the cleaning and passivation of heat exchanging device shell 1, the Time-delay relay delay time is consistent with the time required to liquid suction pipe 3 takes out the cleaning solution inside fixed plate 11 to the greatest extent in three steps, avoids Passivating solution mixes to reduce Passivation Treatment effect with cleaning solution.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of Fouling Cleaning equipment of tubular heat exchanger, including outer cover of heat exchanger (1), it is characterised in that: the heat exchanger The left and right sides of shell (1) is fixedly installed with the first installing pipe (15) for importing fluid low in calories and low for exporting respectively The left and right sides of the second mounting plate (16) of heat fluid, outer cover of heat exchanger (1) inner cavity is welded with fixed plate (11), and two The outer surface of a fixed plate (11) and the inner surface of outer cover of heat exchanger (1) are to weld, solid between two outer cover of heat exchanger (1) Dingan County is equipped with catheter (12), and the both ends of the catheter (12) extend through two fixed plates (11), the outer cover of heat exchanger (1) bottom of inner cavity is fixedly installed with first steadying plate (13) external positioned at catheter (12), and the outer cover of heat exchanger (1) is interior Second steadying plate (14) external positioned at catheter (12) is fixedly installed at the top of chamber, outer cover of heat exchanger (1) top surface The left and right sides is fixedly installed with inlet tube (17) and drain pipe (18) between two fixed plates (11), the feed liquor respectively It is fixedly installed with tee tube (4), is communicated at the top of the tee tube (4) due to importing high heat fluid at the top of pipe (17) Input pipe (5) is communicated with for exporting high heat fluid, cleaning solution and the liquid suction pipe of passivating solution at the top of the drain pipe (18) (3), it is placed with control cabinet (2) at the top of the outer cover of heat exchanger (1), the inside of the control cabinet (2) is equipped with electric signal and turns Parallel operation and time-delay relay, and the input terminal of the output end of electric signal transducer and time-delay relay is electrically connected, the control The right side of case (2) is electrically connected with by conducting wire (22) positioned at the positive PH meter (21) of liquid suction pipe (3), the sense of the PH meter (21) Gauge head is placed on the inside of outer cover of heat exchanger (1) by drain pipe (18), and the left and right sides of the tee tube (4) passes through conduit It is fixedly installed with cleaning liquid electromagnetic valve (24) and passivation liquid electromagnetic valve (23), the cleaning liquid electromagnetic valve (24) and cleaning liquid electromagnetic The input terminal of valve (24) and the output end of control cabinet (2) are electrically connected.
2. a kind of Fouling Cleaning equipment of tubular heat exchanger according to claim 1, it is characterised in that: described second is steady Fixed board (14) is located at the right of the first steadying plate (13), and the quantity of first steadying plate (13) is three, three described first The top of steadying plate (13) and the bottom of the second steadying plate (14) offer jagged.
3. a kind of Fouling Cleaning equipment of tubular heat exchanger according to claim 1, it is characterised in that: the input pipe (5) it is interconnected when heat exchanger runs well with inlet tube (17).
4. a kind of Fouling Cleaning equipment of tubular heat exchanger according to claim 1, it is characterised in that: the fixed plate (11) and catheter (12) junction is equipped with seal rubber.
5. a kind of Fouling Cleaning equipment of tubular heat exchanger according to claim 1, control method is as follows, feature It is: step 1: cleaning liquid electromagnetic valve (24) is in starting state first, passivation liquid electromagnetic valve (23) is in off state, passes through It is interior to injection cleaning solution, liquid suction pipe (3) heat exchanging device shell (1) inside outer cover of heat exchanger (1) to open cleaning liquid electromagnetic valve (24) The liquid in portion continues drawing liquid, and PH meter (21) is placed in drain pipe (18), and then PH counts the pH value of (21) detection cleaning solution, PH The pH value that meter (21) will test imports the electric signal transducer in control cabinet (2) by conducting wire (22);Step 2: in when pH value being Property when, electric signal transducer input signal closes cleaning liquid electromagnetic valve (24) at this time, while time-delay relay trigger is predetermined Time then opens passivation liquid electromagnetic valve (23) and injects passivating solution, when the induction end of PH meter (21) senses outer cover of heat exchanger (1) Internal passivating solution;Step 3: taking out PH meter (21), passivating solution is extracted out by liquid suction pipe (3), is completed heat exchanging device shell (1) Cleaning and passivation.
6. a kind of control method of the Fouling Cleaning equipment of tubular heat exchanger according to claim 5, it is characterised in that: The left end of cleaning liquid electromagnetic valve (24) is communicated with cleaning solution ingress pipe, and the right end of passivation liquid electromagnetic valve (23) is communicated with Passivating solution ingress pipe.
7. the Fouling Cleaning equipment and its control method, feature of a kind of tubular heat exchanger according to claim 5 exist In: it is low concentration cleaning solution that the cleaning solution that liquid electromagnetic valve (24) import is cleaned in the first step.
8. the Fouling Cleaning equipment and its control method, feature of a kind of tubular heat exchanger according to claim 5 exist In: time-delay relay delay time is taken out the cleaning solution that fixed plate (11) are internal to the greatest extent with liquid suction pipe (3) and is taken in the third step Between it is consistent, avoid passivating solution and mixed with cleaning solution to reducing Passivation Treatment effect.
9. the Fouling Cleaning equipment and its control method, feature of a kind of tubular heat exchanger according to claim 5 exist In: the signal adapter is pulse signal converter, and model 4-20ma is serial, so that signal is transmitted as space state, And interval time is consistent with cleaning liquid electromagnetic valve (24) and passivation liquid electromagnetic valve (23) valve opening time.
CN201811627374.0A 2018-12-28 2018-12-28 A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger Pending CN109579608A (en)

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CN201811627374.0A CN109579608A (en) 2018-12-28 2018-12-28 A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger

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Application Number Priority Date Filing Date Title
CN201811627374.0A CN109579608A (en) 2018-12-28 2018-12-28 A kind of the Fouling Cleaning equipment and its control method of tubular heat exchanger

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114367247A (en) * 2021-12-10 2022-04-19 中氢新能(北京)新能源技术研究院有限公司 Spacer and shell and tube reaction unit

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201688748U (en) * 2010-02-09 2010-12-29 彭迪昆 Special cleaning device for wall-hanging boiler
CN202008210U (en) * 2011-04-15 2011-10-12 浙江兰通空调设备有限公司 Self-cleaning efficient automobile air conditioner system
CN202032923U (en) * 2011-04-06 2011-11-09 北京化工大学 Tube-shell type heat exchanger of large-small hole baffle plate with gap
CN102636047A (en) * 2012-05-04 2012-08-15 南京航空航天大学 Multishell pass shell and tube type heat exchanger
CN103673747A (en) * 2012-09-07 2014-03-26 王刚 Fast washing equipment for large-size heat exchangers and washing method
CN104406452A (en) * 2014-11-14 2015-03-11 攀枝花钢企欣宇化工有限公司 Water scale cleaning method for nickel heat exchanger
CN204329716U (en) * 2014-12-12 2015-05-13 山东龙力生物科技股份有限公司 A kind of heat exchanger circulation apparatus for eliminating sludge
CN206146272U (en) * 2016-11-14 2017-05-03 佛山科学技术学院 Crisscross concave surface pipe shell and tube type heat exchanger

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201688748U (en) * 2010-02-09 2010-12-29 彭迪昆 Special cleaning device for wall-hanging boiler
CN202032923U (en) * 2011-04-06 2011-11-09 北京化工大学 Tube-shell type heat exchanger of large-small hole baffle plate with gap
CN202008210U (en) * 2011-04-15 2011-10-12 浙江兰通空调设备有限公司 Self-cleaning efficient automobile air conditioner system
CN102636047A (en) * 2012-05-04 2012-08-15 南京航空航天大学 Multishell pass shell and tube type heat exchanger
CN103673747A (en) * 2012-09-07 2014-03-26 王刚 Fast washing equipment for large-size heat exchangers and washing method
CN104406452A (en) * 2014-11-14 2015-03-11 攀枝花钢企欣宇化工有限公司 Water scale cleaning method for nickel heat exchanger
CN204329716U (en) * 2014-12-12 2015-05-13 山东龙力生物科技股份有限公司 A kind of heat exchanger circulation apparatus for eliminating sludge
CN206146272U (en) * 2016-11-14 2017-05-03 佛山科学技术学院 Crisscross concave surface pipe shell and tube type heat exchanger

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114367247A (en) * 2021-12-10 2022-04-19 中氢新能(北京)新能源技术研究院有限公司 Spacer and shell and tube reaction unit

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