CN109576767A - A kind of chromium plating production equipment of nothing waste discharge containing chromium - Google Patents

A kind of chromium plating production equipment of nothing waste discharge containing chromium Download PDF

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Publication number
CN109576767A
CN109576767A CN201710904720.4A CN201710904720A CN109576767A CN 109576767 A CN109576767 A CN 109576767A CN 201710904720 A CN201710904720 A CN 201710904720A CN 109576767 A CN109576767 A CN 109576767A
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CN
China
Prior art keywords
chromium
pipeline
chromium plating
plating
pump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710904720.4A
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Chinese (zh)
Inventor
黄蕊
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Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710904720.4A priority Critical patent/CN109576767A/en
Publication of CN109576767A publication Critical patent/CN109576767A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/16Regeneration of process solutions
    • C25D21/18Regeneration of process solutions of electrolytes

Abstract

The invention discloses a kind of chromium plating production equipments of nothing waste discharge containing chromium, including chrome-plating bath, cleaning device, chromic acid recyclable device, waste treatment equipment, resistance to acid pump and chromium plating room, the chrome-plating bath pipeline respectively with cleaning device, chromic acid recyclable device and waste treatment equipment connection;The chromic acid recyclable device includes gas gathering mask, air delivery device, recovery tower, centrifuge and neutralizing tower;The waste treatment equipment includes central groove, recycle liquid pump, filter, recycling bins, filter press and air pump;The resistance to acid pump is mounted on the pipeline between level-one rinse bath and recovery tower;The chromium plating room is connect by pipeline with recovery tower.Chromium plating production equipment of the invention can control material balance, do not generate chromate waste water by chrome-plating bath, cleaning device, chromic acid recyclable device, waste treatment equipment, resistance to acid pump and chromium plating room;In chromic acid recyclable device, the characteristic of chromic acid is adsorbed using cooling down to chromium mist, chromic acid is improved and recycles ability, make gas emission compliance.

Description

A kind of chromium plating production equipment of nothing waste discharge containing chromium
Technical field
The present invention relates to electroplating technology, the chromium plating production for particularly relating to a kind of nothing waste discharge containing chromium is set It is standby.
Background technique
In workpiece chromium plating production processing, first is that when cleaning the workpiece after plating, the generated cleaning sullage containing chromium It is directly discharged to sewer pipe, causes water pollution;Second is that in chrome-plating process, due to using insoluble anode, cathode current effect Rate is again very low, causes a large amount of hydrogen and oxygen evolution, when gas escapes liquid level, has chromic acid, forms chromium mist and is discharged in the air, right Atmosphere causes serious pollution;Third is that being inevitably generated some solid sundries in chrome-plating process, in plating solution, i.e., containing chromium Industrial residue, waste residue are drenched by sleet and are soaked, and contained Cr VI, which will be dissolved in permeate the ground water or entrance river, lake, to be polluted Environment causes bigger harm.For generating three waste discharge during workpiece chromium plating production processing, the processing of waste liquid sewage is adopted Sewage-treatment plant is set certainly with enterprise or concentration is sent to sewage treatment plant and is uniformly processed, and this method significantly increases enterprise Industry production cost;The processing of exhaust gas chromium mist is using the ease for placing foamed plastics fragment or fragment retardance chromium mist on the liquid level of plating solution Out, inconvenient for operation but when workpiece goes out slot;In addition chromic acid oxidability is very strong, has erosion to the fragment of addition, makes point Solution product accumulates in the plating solution, influences quality of coating.
Summary of the invention
It is above-mentioned existing effectively to overcome the object of the present invention is to provide a kind of chromium plating production equipment of nothing waste discharge containing chromium The deficiency of technology.
The scheme that the present invention solves technical problem is: a kind of chromium plating production equipment of nothing waste discharge containing chromium, including chromium plating Slot, cleaning device, chromic acid recyclable device, waste treatment equipment, resistance to acid pump and chromium plating room, the chrome-plating bath pipeline is respectively and clearly Cleaning device, chromic acid recyclable device and waste treatment equipment connection;The cleaning device include level-one rinse bath, second level rinse bath, Three-level rinse bath, level Four rinse bath and water supply device, water supply device are located at the top of level Four rinse bath;The chromic acid recycling dress It sets including gas gathering mask, air delivery device, recovery tower, centrifuge and neutralizing tower, gas gathering mask is located at the top of chrome-plating bath, with gas gathering mask The other end for the gas pipeline being fixedly connected is fixedly connected with recovery tower;The waste treatment equipment includes central groove, circulation fluid Pump, filter, recycling bins, filter press and air pump, central slot position pass through pipeline and chromium plating in the side of chrome-plating bath, central groove Slot connection and it is lower than chrome-plating bath, in the centrally located slot of the entrance of recycle liquid pump, the outlet of recycle liquid pump is connect with filter, mistake The outlet of filter is connect with chrome-plating bath feed inlet pipeline;The resistance to acid pump is mounted on the pipe between level-one rinse bath and recovery tower On road;The chromium plating room is connect by pipeline with recovery tower.
Preferably, the waste treatment equipment further includes supersonic cleaning machine, and supersonic cleaning machine is mounted on filter, The outlet of filter is connect with feed opening of press filter pipeline, and another import of filter press is connect with air pump sebific duct, filter press Outlet is connected with recycling bins, and filter press is also connect with central groove pipeline.
Further, the recovery tower is successively arranged four rooms from the bottom to top, and indoor equipped with evaporator first, evaporator is logical Piping is connected with the compressor of recovery tower, and PVC filament net is equipped in second Room, PVC granule is equipped in third room, in PVC Particle is equipped with spray tube and return pipe, and spray tube connects with one end of resistance to acid pump, and the other end of resistance to acid pump and first is clearly Washing trough connects, and the heat exchanger that heat exchange is carried out with chromium plating room is equipped in fourth ventricle.
Further, the cleaning device further includes piece installing workbench, and piece installing workbench is located at the top of level Four rinse bath.
Compared with prior art, the beneficial effects of the present invention are: chromium plating production equipment of the invention, by chrome-plating bath, clear Cleaning device, chromic acid recyclable device, waste treatment equipment, resistance to acid pump and chromium plating room, can control material balance, not generate useless containing chromium Water;In chromic acid recyclable device, the characteristic of chromic acid is adsorbed using cooling down to chromium mist, chromic acid is improved and recycles ability, discharge gas It is up to standard;In waste treatment equipment, waste is made to carry out harmless treatment in obturator, unharmful substance outflow is not polluted Environment.Chromium plating production equipment of the invention, high production efficiency, it is at low cost, can have been renovated from source chromium plating generation waste liquid, Exhaust gas, waste sludge discharge problem, avoid environmental pollution.
Detailed description of the invention
Fig. 1 is structural block diagram of the invention;
Figure label: 100, chrome-plating bath;200, cleaning device;210, level-one rinse bath;220, second level rinse bath;230, three-level is clear Washing trough;240, level Four rinse bath;250, water supply device;300, chromic acid recyclable device;310, gas gathering mask;320, air delivery device; 330, recovery tower;331, evaporator;332, PVC filament net;333, PVC granule;334, heat exchanger;340, centrifuge;350, it neutralizes Tower;360, compressor;370, spray tube;380, return pipe;400, waste treatment equipment;410, central groove;420, recycle liquid pump; 430, filter;440, recycling bins;450, filter press;460, air pump;470, supersonic cleaning machine;500, resistance to acid pump;600, Chromium plating room.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail:
Referring to Fig. 1, chromium plating production equipment of the invention, including it is chrome-plating bath 100, cleaning device 200, chromic acid recyclable device 300, useless Object processing unit 400, resistance to acid pump 500 and chromium plating room 600,100 pipeline of chrome-plating bath respectively with cleaning device 200, chromic acid 400 connection of recyclable device 300 and waste treatment equipment;The cleaning device 200 includes level-one rinse bath 210, second level rinse bath 220, three-level rinse bath 230, level Four rinse bath 240 and water supply device 250, water supply device 250 are located at level Four rinse bath 240 Top;The chromic acid recyclable device 300 includes gas gathering mask 310, air delivery device 320, recovery tower 330, centrifuge 340 and neutralizing tower 350, gas gathering mask 310 is located at the top of chrome-plating bath 100, the other end for the gas pipeline 320 being fixedly connected with gas gathering mask 310 with Recovery tower 330 is fixedly connected;The waste treatment equipment 400 includes central groove 410, recycle liquid pump 420, filter 430, recycling Case 440, filter press 450 and air pump 460, central groove 410 are located at the side of chrome-plating bath 100, central groove 410 by pipeline with The connection of chrome-plating bath 100 and it is lower than chrome-plating bath 100, in the centrally located slot 410 of the entrance of recycle liquid pump 420, recycle liquid pump 420 Outlet is connect with filter 430, and the outlet of filter 430 is connect with 100 feed inlet pipeline of chrome-plating bath;The resistance to acid pump 500 It is mounted on the pipeline between level-one rinse bath 210 and recovery tower 330;The chromium plating room 600 is connected by pipeline and recovery tower 330 It connects.The waste treatment equipment 400 further includes supersonic cleaning machine 470, and supersonic cleaning machine 470 is mounted on filter 430, The outlet of filter 430 is connect with 450 feed inlet pipeline of filter press, and another import of filter press 450 and 460 sebific duct of air pump connect It connects, the outlet of filter press 450 is connected with recycling bins 440, and filter press 450 is also connect with 410 pipeline of central groove.The recovery tower 330 are successively arranged four rooms from the bottom to top, and indoor equipped with evaporator 331 first, evaporator 331 passes through pipeline and recovery tower 330 compressor 360 is connected, and PVC filament net 332 is equipped in second Room, PVC granule 333 is equipped in third room, at PVC Grain 333 is equipped with spray tube 370 and return pipe 380, and spray tube 370 connects with one end of resistance to acid pump 500, resistance to acid pump 500 The other end connect with the first rinse bath 210, in fourth ventricle be equipped with chromium plating room 600 carry out heat exchange heat exchanger 334.Institute Stating cleaning device 200 further includes piece installing workbench, and piece installing workbench is located at the top of level Four rinse bath 240.
The process of this equipment chromic acid recycling is: after the chromium mist generated in chrome-plating process is collected by gas gathering mask 310, passing through gas transmission Device 320 enters recovery tower 330, and the temperature of chromium mist is reduced by the evaporator 331 in recovery tower 330, makes the chromic acid in chromium mist Become liquid by the adsorption of PVC filament net 332 and PVC granule 333;The temperature for reducing chromium mist, can make PVC filament net 332 and PVC Chromic acid in 333 adsorption chromium mist of particle is more thorough.Gas after absorption without chromic acid passes through heat exchanger 334 and electroplating chamber Air in 600 carries out heat exchange to meet the indoor operating temperature of plating, is then sent into neutralizing tower 350 by centrifuge 340 and reaches It is discharged after mark.The chromic acid of 333 Adsorption on Surface of PVC filament net 332 and PVC granule in recovery tower 330, with resistance to acid pump 500 inhale come Level-one rinse bath 210 in liquid washed by spray tube 370, the cleaning liquid of generation leans on and recovery tower 330 and level-one The return pipe 380 that rinse bath 210 connects flows back to level-one rinse bath 210, to achieve the purpose that discharge chromic acid not into atmosphere.
This equipment chromium plating waste treatment process is: chromium plating liquid passes through recycle liquid pump 420, filter 430 by central groove 410 To 100 circulating filtration of chrome-plating bath, the solid impurity in chromium plating liquid is rested on the strainer of filter 430.Supersonic cleaning machine 470 are periodically cleaned by ultrasonic the strainer of filter 430, and the cleaning solution with solid impurity flows into filter press 450;Starting is empty Air pump 460 carries out filters pressing to 450 cleaning liquid inside of filter press, and filtrate flows back to central groove 410.Filter cake with solid impurity leans on filters pressing After scraper plate in machine 450 is discharged to the progress harmless treatment of recycling bins 440, fixed-end forces factory is sent.

Claims (4)

1. a kind of chromium plating production equipment of nothing waste discharge containing chromium, including chrome-plating bath, cleaning device, chromic acid recyclable device, waste Processing unit, resistance to acid pump and chromium plating room, it is characterised in that: the chrome-plating bath pipeline is filled with cleaning device, chromic acid recycling respectively It sets and waste treatment equipment connection;The cleaning device includes that level-one rinse bath, second level rinse bath, three-level rinse bath, level Four are clear Washing trough and water supply device, water supply device are located at the top of level Four rinse bath;The chromic acid recyclable device includes gas gathering mask, gas transmission Device, recovery tower, centrifuge and neutralizing tower, gas gathering mask are located at the top of chrome-plating bath, the appendix being fixedly connected with gas gathering mask The other end in road is fixedly connected with recovery tower;The waste treatment equipment include central groove, recycle liquid pump, filter, recycling bins, Filter press and air pump, in the side of chrome-plating bath, central groove is connect by pipeline with chrome-plating bath and lower than chromium plating central slot position Slot, in the centrally located slot of the entrance of recycle liquid pump, the outlet of recycle liquid pump is connect with filter, the outlet and chromium plating of filter The connection of slot feed inlet pipeline;The resistance to acid pump is mounted on the pipeline between level-one rinse bath and recovery tower;The chromium plating room It is connect by pipeline with recovery tower.
2. a kind of chromium plating production equipment of nothing waste discharge containing chromium according to claim 1, it is characterised in that: the waste Processing unit further includes supersonic cleaning machine, and supersonic cleaning machine is mounted on filter, the outlet of filter and filter press into The connection of material mouth pipeline, another import of filter press are connect with air pump sebific duct, and the outlet of filter press is connected with recycling bins, filter press Also it is connect with central groove pipeline.
3. a kind of chromium plating production equipment of nothing waste discharge containing chromium according to claim 1, it is characterised in that: the recycling Tower is successively arranged four rooms from the bottom to top, and indoor equipped with evaporator first, evaporator passes through the compressor of pipeline and recovery tower It is connected, PVC filament net is equipped in second Room, PVC granule is equipped in third room, spray tube and reflux is equipped in PVC granule Pipe, spray tube connect with one end of resistance to acid pump, and the other end of resistance to acid pump connects with the first rinse bath, is equipped in fourth ventricle The heat exchanger of heat exchange is carried out with chromium plating room.
4. a kind of chromium plating production equipment of nothing waste discharge containing chromium according to claim 1, it is characterised in that: the cleaning Device further includes piece installing workbench, and piece installing workbench is located at the top of level Four rinse bath.
CN201710904720.4A 2017-09-29 2017-09-29 A kind of chromium plating production equipment of nothing waste discharge containing chromium Pending CN109576767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710904720.4A CN109576767A (en) 2017-09-29 2017-09-29 A kind of chromium plating production equipment of nothing waste discharge containing chromium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710904720.4A CN109576767A (en) 2017-09-29 2017-09-29 A kind of chromium plating production equipment of nothing waste discharge containing chromium

Publications (1)

Publication Number Publication Date
CN109576767A true CN109576767A (en) 2019-04-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710904720.4A Pending CN109576767A (en) 2017-09-29 2017-09-29 A kind of chromium plating production equipment of nothing waste discharge containing chromium

Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112323128A (en) * 2020-10-09 2021-02-05 厦门欧士佩电镀厂有限公司 Emission reduction type electroplating cleaning method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112323128A (en) * 2020-10-09 2021-02-05 厦门欧士佩电镀厂有限公司 Emission reduction type electroplating cleaning method

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Application publication date: 20190405