CN109576707A - A kind of fast preparation method of ionic artificial-muscle - Google Patents

A kind of fast preparation method of ionic artificial-muscle Download PDF

Info

Publication number
CN109576707A
CN109576707A CN201811579550.8A CN201811579550A CN109576707A CN 109576707 A CN109576707 A CN 109576707A CN 201811579550 A CN201811579550 A CN 201811579550A CN 109576707 A CN109576707 A CN 109576707A
Authority
CN
China
Prior art keywords
artificial
ionic
fast preparation
muscle
plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811579550.8A
Other languages
Chinese (zh)
Inventor
王延杰
王家乐
徐望舒
张宇霆
骆敏舟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou Campus of Hohai University
Original Assignee
Changzhou Campus of Hohai University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou Campus of Hohai University filed Critical Changzhou Campus of Hohai University
Priority to CN201811579550.8A priority Critical patent/CN109576707A/en
Publication of CN109576707A publication Critical patent/CN109576707A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/42—Coating with noble metals
    • C23C18/44—Coating with noble metals using reducing agents
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/46—Electroplating: Baths therefor from solutions of silver
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/48—Electroplating: Baths therefor from solutions of gold
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention discloses a kind of methods of ionic artificial-muscle quickly prepared.Ion polymer-metal composite material (IPMC) is a kind of ionic electroactive polymer, commonly known as artificial-muscle.The technique is using amberplex (Nafion membrane) as base material, using metal composite as main salt, quickly prepares this ionic artificial-muscle using electric plating method is carried out after physics sandblasting roughening, soaking and reducing plating to realize.The technique realizes that the key that it is quickly prepared is to introduce electroplating surface instead of traditional chemical plating, is greatly saved the time.The present invention is low in cost, and time-consuming of short duration, operating procedure is simple, convenient and efficient, can efficiently prepare the excellent IPMC material of driveability.

Description

A kind of fast preparation method of ionic artificial-muscle
Technical field
The present invention relates to a kind of fast preparation methods of ionic artificial-muscle, belong to intellectual material preparation field.
Background technique
Ion polymer-metal composite material (ionic polymer-metal composites, abbreviation IPMC) is one Kind ionic electroactive polymer, commonly known as artificial-muscle.The material is on amberplex (polyelectrolyte membrane) The sandwich structure that lower surface is formed and either physically or chemically respectively depositing one layer of electrode.Under the driving of 1-3 V voltage IPMC can produce biggish bending deformation；On the contrary, can produce electricity between IPMC electrode if applying mechanically deform or strain Potential difference.So IPMC is a kind of novel intelligent material with electromechanical transducing ability.For other traditional intelligence materials, The outstanding advantages of IPMC are light weights, driving voltage is low, bending deformation is big, flexibility is good, be swift in response and has sensing-cause Dynamic bidirectional reversible function has very big application potential in fields such as space flight and aviation, biomedicine, bionic mechanicals.
In IPMC process flow, repeatedly after immersion-reduction plating, Nafion membrane surface will form one layer of loose electricity of micron order Pole layer, still has higher sheet resistance.In order to further decrease the sheet resistance of material, generally use chemical plating by metal-plated On the surface of the material, but since the gimmick manufacturing speed of chemistry is slower, the period is longer, has specific want for the amount of chemical reagent It asks, preparation process generally will be carried out persistently more than 48 hours, very time-consuming.
Summary of the invention
In order to solve artificial-muscle preparation process time in the prior art, just, time-consuming problem proposes one kind to the present invention Quickly easy preparation method generally can be completed within 24 hours that is, using the preparation process of chemical plating joint plating The preparation process of IPMC material, not only saves the time, but also functional.
The present invention is pre-processed using palladium as main-body electrode material by base film, immersion-reduction plating and electroplating surface three The technique that a stage quickly prepares ionic artificial-muscle IPMC.
The present invention to solve the above-mentioned problems, a kind of technical solution taken are as follows: quick system of ionic artificial-muscle Preparation Method includes the following steps
S01 base film pretreatment: successively clear through sandblasting polishing, ultrasonic wave using amberplex Nafion membrane as base material It washes, pickling and washing is pre-processed；
The plating of S02 soaking and reducing: base film is immersed in after carrying out palladium ion exchange in Pd salting liquid, is allowed to also with reducing solution Original forms one layer of palladium metal layer in ion exchange film surface and obtains pre- plated film；The reducing solution is NaBH4。
S03 electroplating surface: the processing that pre- plated film is electroplated increases material electrodes layer, increases the dependency of palladium, reduces Sheet resistance；
The electroplating surface includes: (1) plating pretreatment: the surrounding of pre- plated film is carried out trimming processing；
(2) it is electroplated: using precious metal salt solution as electroplate liquid, using active metal as anode, using array type metal probe as cathode It is electroplated；
Will be using metals such as titaniums as anode when plating, array type metal probe connects Pd film as cathode, and guarantees array Formula metal probe and Pd film surface close contact.During plating, electroplate liquid is typically chosen containing your gold such as Au Ag Pt Pd Belong to salt.Two sides will be electroplated, and guarantee the uniformity of plating.According to the degree of plating, this step is repeated as many times.
S04 post-processing: base film is cleaned in deionized water, and trimming processing, can be later Li, Na, K in ROH(R Equal alkali metal ions) it impregnates in solution, carry out Na ion exchange.
Further, the sandblasting technique for grinding are as follows: sandblasting polishing roughening carries out base film surface sand-blasting using glass sand, Blasting pressure is 0 .05-0 .5MPa, and base film single side polishes the time as 20-90s.
Further, the aqueous temperature when ultrasonic cleaning be 30-80 DEG C, power 100-400W, when cleaning Between be 10-60min.
Further, pickling is boiled and is washed using hydrochloric acid in step S01, concentration of hydrochloric acid 0.1-0.2mol/L, and controlling the boiling and washing temperature is It 90-100 DEG C, boils and washes the time as 10-60min.
Further, washing temperature is 90-100 DEG C in step S01, and the time is set as 10-60min.
Further, the concentration of the Pd in step S02 in Pd salting liquid is 0.01-0.015mol/L.
Further, reducing solution is the mixed liquor of reducing agent and ammonium hydroxide in step S02, and the reducing agent is NaBH4, The volume ratio of ammonium hydroxide and reducing agent is 100:1-100:5.
Further, the electroplating voltage control is in 0.5-10V, and current control is in 0.001-0.5A, electroplating time single side Plating 20-30 seconds, two sides circulation plating 5-10 times.
Further, concentration of sodium hydroxide solution is 0.1-0.6mol/L when the post-processing, and soaking time is that 1-3 is small When.
Further, during soaking and reducing plating, ion exchange and reduction be in thermostatic control oscillator vibration into Row；Ion exchange must carry out in thermostatic water bath vibrator, and frequency is set as 80-100r/min, and temperature is 40 DEG C -60 DEG C, when Between be 60-180 minutes；Ion reduction must carry out in thermostatic water bath vibrator, and frequency is set as 80-100r/min, and temperature is 40 DEG C -60 DEG C, the time is 30-90 minutes, and time setting is about the half of ion exchange process.Soaking and reducing plating need to be repeated 3 times, Until Pd ionic reaction is complete in Pd salting liquid.
Further, the trimming processing in the pretreatment and post-processing before plating, four sides cut off the area of about 0.5mm-1mm Domain.
Beneficial effect caused by the present invention includes: 1, preparation efficiency height, is mostly chemical plating in existing preparation process.And Chemical plating takes a long time, and generally requires progress 3 times or more, 2 hours time-consuming or more every time.The electroplating process of this technique, every one side Only need to be electroplated 20-30s, plating all processes are about 10 minutes.
2, easy to operate, compared to existing chemical plating, electroplanting device is small and exquisite, and operating procedure is few, using titanium metal net as Anode may be reused, and only need to connect pre- plated film with cathode.
Detailed description of the invention
Fig. 1: being the structural schematic diagram of electroplanting device in the present invention；
1, electroplate liquid in figure, 2, array type metal probe, 3, titanium net, 4, pre- plated film.
Specific embodiment
Further details of explanation is done to the present invention with reference to the accompanying drawings and detailed description, it should be appreciated that The protection scope of the present invention is not limited by the specific implementation manner.
Illustrate preparation method of the invention for preparing the IPMC material that size is about 6cm × 6cm:
1. base film pre-processes
Base film: being cut into the small cube of 6.5cm × 6.5cm by the 1.1. roughening of base film first, and fixing base film exposes Size is the square of 6.0cm × 6.0cm, carries out sandblasting with sand-blasting machine later, using the glass sand of 150#, blasting pressure is set Determine 0.4MPa, the polishing control of base film single side moves with uniform velocity in 90s, sandblasting procedures.Ensure the time phase of every one side sandblasting Together, and more uniformly.
1.2. trimming: base film roughening (sandblasting) terminates, and base film is cut into the square of 6.0cm × 6.0cm, excision is not Sand blasted area.
1.3. matrix Membrane cleaning:
1.3.1. ultrasonic cleaning: ultrasonic cleaner is set as 60 DEG C first, power 250W, scavenging period is set as 30min avoids the metal tweezers using clear-cut margin, leaves scratch to avoid in matrix film surface when clamping base film.Roughening Base film afterwards into the water, surface would generally bubbles attached, before starting cleaning, need rinse to remove blibbing.
1.3.2. hydrochloric acid, which boils, washes: this step is primarily to foreign ion inside removal base film, while to base film Interior cation is purified, cation ic-converted H+, increase hydrionic content in base film, it is plated to facilitate soaking and reducing Ion-exchange reactions in journey.Hydrochloric acid, which is boiled and washed, to be carried out in thermostat water bath, and the time is set as 30min, and temperature is set as 100 DEG C, concentration of hydrochloric acid with 200ml, is held with beaker, is cleaned before base film is put into deionized water to be 0.2mol/L.
1.3.3. deionization boiling is washed: temperature is set as 100 DEG C, and the time is set as 30min.This step is to increase The storage capacity of IPMC material.
2. soaking and reducing plates
2.1. match Pd(palladium) salting liquid: Pd (NH3)4Cl2About 2.048mg/cm2, according to the area of base film, need to weigh M1P =2.048 × S × 2 (face) × (245.5/106.5)=9.442 × S (mg), the Pd (NH of about 339.9mg3)4Cl2.It measures later Ionized water is removed, since the concentration of Pd salt is 0.01mol/L..So needing to weigh V1W =( M1P /245.5)/0.01= M1P/ 2.455 (mL), the about deionized water of 138mL.Finally measure NH3 H2O, ammonia concn are about 25 ~ 28%, ammonium hydroxide and Pd (NH3)4Cl2Ratio be 0.0543ml:1mg.V1N= 0.0543×M1P(mL) it is 18.5ml that, which then takes ammonium hydroxide,.In beaker It is sealed after mixing with preservative film.
2.2. match reducing solution: using NaBH4 as reducing agent, concentration 0.85g/L.Deionized water is measured first.Institute To weigh V2W = VB1 ×5%/0.85(L) = 58.82×VB1(mL), about 186mL.NH is measured later3 H2 O (25- 28%), V2N=0.6×V2W/180 = V2W/ 300 (mL).About 0.62mL.The NaBH of 7.6mg is measured later4It is added and burns Cup, is sealed after mixing with preservative film.
2.3. impregnate: the base film after will be pretreated, which is put into the Pd salting liquid that 2.1 prepare, to be impregnated, later beaker with Preservative film sealing, is put into thermostatic water bath vibrator.Oscillation frequency is set as 90r/min, temperature is 50 DEG C, keeps 1h.
2.4. reduction plating:
After immersion, pretreatment film is taken out, is cleaned 2-3 times with deionized water, is put into reducing solution later, beaker to protect Fresh film sealing, places into thermostatic water bath vibrator.Oscillation frequency is set as 90r/min, temperature is 50 DEG C, keeps 30min.Also It will be pre-processed Membrane cleaning two to three times after original plating with deionized water.
The above 2.1-2.4 step is first immersion-reduction plating, at least needs to repeat immersion-reduction and plate 3 times, until table Surface resistance is down to 1 Ω/ (-square resistance is unit of resistance) hereinafter, obtaining pre- plated film.The time is plated in later immersion-reduction It can be appropriately extended, this time test soaking time and extend one hour every time, the reduction plating time extends 30min every time.
3. electroplating surface: the main purpose of this step is to reduce the sheet resistance of pre- plated film.
3.1. trimming is handled, it is therefore an objective to be prevented pre- plated film upper/lower electrode layer in plating to be connected, be caused plating uneven. Then, pre- plated film 4 is placed in electroplate liquid 1, electroplate liquid 1 is typically chosen containing precious metal salts such as Au Ag Pt Pds.
3.2. electroplating voltage control is in 0.5-10V, and current control is in 0.001-0.5A, using active metals such as titaniums as sun Pole, using titanium net 3 as anode in the present invention, electroplating cathode is array type metal probe 2, metal probe and pre- plated film 4 when plating One face contact.Electroplating time one-side electroplating 20-30 seconds, two sides circulation plating 5-10 times, in order to make electroplated electrode more Uniformly.Guarantee that the sheet resistance of pre- plated film 4 drops to 0.011 Ω/ hereinafter, obtaining IPMC material.
4. post-processing: the trimming of the edge IPMC being handled, is cleaned 2-3 times with deionized water later, is placed in 0.1-0.6mol/ It is impregnated 1-3 hours in the NaOH solution of L, carries out Na ion exchange.
Above-mentioned technique is executed, total preparation time is no more than 24 hours.
The above is only a preferred embodiment of the present invention, and the present invention is not limited in the content of embodiment.For in this field Technical staff for, can have various change and change within the scope of technical solution of the present invention, made any variation and Change, within that scope of the present invention.
The above is only a preferred embodiment of the present invention, and the present invention is not limited in the content of embodiment.For in this field Technical staff for, can have various change and change within the scope of technical solution of the present invention, made any variation and Change, within that scope of the present invention.

Claims (10)

1. a kind of fast preparation method of ionic artificial-muscle, it is characterised in that: include the following steps
S01 base film pretreatment: successively clear through sandblasting polishing, ultrasonic wave using amberplex Nafion membrane as base material It washes, pickling and washing is pre-processed；
The plating of S02 soaking and reducing: base film is immersed in after carrying out palladium ion exchange in Pd salting liquid, then be allowed to reducing solution Reduction forms one layer of palladium metal layer in ion exchange film surface and obtains pre- plated film；
S03 electroplating surface: the processing that pre- plated film is electroplated increases material electrodes layer, increases the dependency of palladium, reduces surface Resistance；
The electroplating surface includes: (1) plating pretreatment: the surrounding of pre- plated film is carried out trimming processing；
(2) it is electroplated: using precious metal salt solution as electroplate liquid, using active metal as anode, using array type metal probe as cathode It is electroplated；
S04 post-processing: base film is cleaned in deionized water, and trimming processing impregnates in aqueous slkali later, carries out ion Exchange.
2. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: the sandblasting polishing Technique are as follows: sandblasting polishes roughening using glass sand progress base film surface sand-blasting, and blasting pressure is 0 .05-0 .5MPa, matrix Film single side polishes the time as 20-90s.
3. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: the ultrasonic wave is clear Aqueous temperature when washing is 30-80 DEG C, power 100-400W, scavenging period 10-60min.
4. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: sour in step S01 It washes to boil using hydrochloric acid and wash, concentration of hydrochloric acid 0.1-0.2mol/L, controlling the boiling and washing temperature is 90-100 DEG C, boils and washes the time as 10-60min.
5. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: water in step S01 Washing temperature is 90-100 DEG C, and the time is set as 10-60min.
6. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: Pd in step S02 The concentration of Pd in salting liquid is 0.01-0.015mol/L.
7. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: in step S02 also Originality solution is the mixed liquor of reducing agent and ammonium hydroxide, and the reducing agent is NaBH4, and the volume ratio of ammonium hydroxide and reducing agent is 100:1- 100:5。
8. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: the electroplating voltage Control is in 0.5-10V, and current control is in 0.001-0.5A, and electroplating time one-side electroplating 20-30 seconds, 5-10 was electroplated in two sides circulation It is secondary.
9. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: when the post-processing Concentration of sodium hydroxide solution is 0.1-0.6mol/L.
10. the fast preparation method of ionic artificial-muscle according to claim 1, it is characterised in that: described to impregnate also During original plating, ion exchange and reduction are carried out in thermostatic control oscillator vibration.
CN201811579550.8A 2018-12-24 2018-12-24 A kind of fast preparation method of ionic artificial-muscle Pending CN109576707A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811579550.8A CN109576707A (en) 2018-12-24 2018-12-24 A kind of fast preparation method of ionic artificial-muscle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811579550.8A CN109576707A (en) 2018-12-24 2018-12-24 A kind of fast preparation method of ionic artificial-muscle

Publications (1)

Publication Number Publication Date
CN109576707A true CN109576707A (en) 2019-04-05

Family

ID=65931472

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811579550.8A Pending CN109576707A (en) 2018-12-24 2018-12-24 A kind of fast preparation method of ionic artificial-muscle

Country Status (1)

Country Link
CN (1) CN109576707A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381866A (en) * 2008-09-02 2009-03-11 西安交通大学 Method for preparing ion polymer-metal composite material
CN102168260A (en) * 2011-04-07 2011-08-31 西安交通大学 Preparation process of palladium electrode ion polymer and metal composite
CN102953053A (en) * 2012-11-13 2013-03-06 西安交通大学 Selective plating process for IPMC (Ionic Polymer Metal Composite) drive
CN103917691A (en) * 2011-11-30 2014-07-09 不二商事株式会社 Method for regenerating plating liquid, plating method, and plating apparatus
CN108048824A (en) * 2017-12-15 2018-05-18 河海大学常州校区 A kind of preparation process at the dendritic interface of ionomer/metal

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381866A (en) * 2008-09-02 2009-03-11 西安交通大学 Method for preparing ion polymer-metal composite material
CN102168260A (en) * 2011-04-07 2011-08-31 西安交通大学 Preparation process of palladium electrode ion polymer and metal composite
CN103917691A (en) * 2011-11-30 2014-07-09 不二商事株式会社 Method for regenerating plating liquid, plating method, and plating apparatus
CN102953053A (en) * 2012-11-13 2013-03-06 西安交通大学 Selective plating process for IPMC (Ionic Polymer Metal Composite) drive
CN108048824A (en) * 2017-12-15 2018-05-18 河海大学常州校区 A kind of preparation process at the dendritic interface of ionomer/metal

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JIN-HAN JEON ET AL.: "Fabrication and actuation of ionic polymer metal composites patterned by combining electroplating with electroless plating", 《COMPOSITES》 *
马春秀等: "Nafion/金属的制备及电形变性能研究", 《宇航材料工艺》 *

Similar Documents

Publication Publication Date Title
CN108483573B (en) Method for desalting by utilizing fluid battery and application thereof
CN105789429B (en) A kind of array-type flexible curved surface self-sensing actuator and preparation method thereof based on IPMC
CN100582303C (en) Ion polymer-metal composite material preparation method
CN101275270A (en) Electrolytic brightening process for martensitic stainless steel holder
CN110184625A (en) A method of improving pure nickel mechanical property
CN105688677A (en) Composite electrode for electrodialysis as well as preparation method and application thereof
CN101956224B (en) Method for electroplating nano composite plated layer
CN104818503A (en) Preparation method of porous copper full-impregnated film of three-dimensional network structure
CN105755519B (en) Gradient anode oxidizing process prepares highly effective air and catchments the method on copper surface
CN106702425B (en) A method of preparing molybdenum disulfide/copper/cobalt catalytic hydrogen evolution layer in foam iron surface
CN108048824A (en) A kind of preparation process at the dendritic interface of ionomer/metal
CN113089036A (en) Preparation method of variable-frequency power ultrasonic electrodeposition nano metal ceramic composite layer
CN109576707A (en) A kind of fast preparation method of ionic artificial-muscle
CN103882483A (en) Device and method for making high-reflectance microprism working mold
CN104152960B (en) A kind of preparation method of high catalytic activity electro catalytic electrode
CN106744902B (en) A kind of preparation method of Ni-coated graphite alkene
CN102522491A (en) Polymer device with driving and sensing capability, preparation thereof and application thereof
CN106809918B (en) A kind of carbon nano tube modified lead dioxide electrode and preparation method thereof
CN108085639B (en) Single-chip spiral ionic polymer metal composite linear driving unit and preparation method thereof
CN117848798A (en) Preparation method of EBSD sample of titanium and titanium alloy
CN107999908A (en) A kind of production method of micro-pit array
CN109680268A (en) A kind of preparation method of copper electrode ionomer-metallic composite artificial-muscle
CN109338422A (en) The preparation method of the preparation method of IPMC material, wherein mesosome, IPMC material
CN110265681A (en) It is a kind of for being catalyzed the combination electrode and its preparation method and application of sodium formate oxidation
CN106769354B (en) Polishing method for aluminium alloy metallographic specimen

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190405