CN109575359A - A kind of preparation method and application of nanometer silver antimicrobial liquid - Google Patents
A kind of preparation method and application of nanometer silver antimicrobial liquid Download PDFInfo
- Publication number
- CN109575359A CN109575359A CN201811495492.0A CN201811495492A CN109575359A CN 109575359 A CN109575359 A CN 109575359A CN 201811495492 A CN201811495492 A CN 201811495492A CN 109575359 A CN109575359 A CN 109575359A
- Authority
- CN
- China
- Prior art keywords
- silver
- preparation
- nano
- nanometer silver
- antimicrobial liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Abstract
The invention discloses kind of a preparation method and application for nanometer silver antimicrobial liquid, the preparation method of the nanometer silver antimicrobial liquid utilizes hydro-thermal method, using polyvinylpyrrolidone as protective agent, prepares nano silver colloidal sol solution with glucose direct-reduction silver nitrate；It prepares relatively easy, easily controllable, and carries out in hydrothermal reaction kettle in a closed system, the volatilization and preparation that can be effectively prevented noxious material are to the substance of air-sensitive.Obtained nanometer silver antimicrobial liquid crystal property is preferable, Nano silver grain is spherical shape, belong to the nano silver of centroid cubic crystal system, it is dispersed preferable, grain diameter is uniform, for most of grain diameter in 20nm or so, stability is strong, can be widely applied to timber anti-biotic material, anti-bacterial fibre, antimicrobial building material, antibiotic plastic.
Description
Technical field
The present invention relates to the technical field of nano silver material preparation process more particularly to a kind of preparations of nanometer silver antimicrobial liquid
Method and application.
Background technique
The property of nano material is generally dependent on its size and shape, therefore a free-revving engine of nano material preparation is exactly
Realize the control to nano-particles size and shape, and the control of shape is much difficult to the control of size.This is because being in
The nanoparticle of upper state tends to mutually reunite and grow up, and the variation of environment may also influence the growth of nanoparticle.Cause
This, the nanoparticle of conventional method preparation is generally the irregular spherical shape of size wider distribution.By adjust nanoparticle at
Nucleus growth environment, controls the Growth kinetics of nanoparticle, to realize the controllable preparation of nano-particles size and pattern.Nanometer
There are many preparation methods of silver powder, including chemical reduction method, ultrasonic wave added synthetic method, magnetron sputtering method, template, photo-reduction
Method, crystal seed method, polyol process, microemulsion method, electrochemical process, biological reducing method, hydro-thermal method etc..
In the living environment of the mankind, there is countless bacteriums, they are multiplied wherein by different routes of transmission
It lives.Bacterium is proliferated quickly in a humid environment, people's various household items used in everyday be all bacteria breed procreation and
The suitable place propagated.These bacteriums generate abnormal stimulation to human skin and induce various skin diseases, and it is strong to influence human body
Health.In recent years, the trend that various bacterial viruses are significantly increased, various viral bacteriosis are also increasingly spread unchecked, therefore,
Research on antibacterial and application to articles for daily use have very important significance to protection human health.
A kind of specific form of the nano silver as metallic silver, since its particle is extremely small, large specific surface area is made it have
Significant skin effect, quantum size effect and quantum tunneling effect, thus make nano silver that there is very strong activity and permeability,
Its bactericidal effect is hundreds times of common silver.Nano silver is a kind of antibacterial agent, have stronger antibacterial, bactericidal effect and its
The antibacterial activity of wide spectrum, the antibacterial effect that there is traditional inorganic antiseptic to be unable to reach, has no drug resistance, highly-safe.With anti-
The bacterial drug resistance of raw element increasingly aggravates, and research and application of the nano silver in antibiotic and sterilizing field increasingly receive extensive pass
Note.
But prepare in the prior art nano silver method exist substantially complex process and it is at high cost the problems such as, it is obtained
Nano silver bad dispersibility, granularity is big and uneven, and stability difference etc. is to be improved.
Summary of the invention
The purpose of the invention is to overcome the above-mentioned prior art, a kind of preparation side of nanometer silver antimicrobial liquid is provided
The preparation method of method and application, the nanometer silver antimicrobial liquid utilizes hydro-thermal method, using polyvinylpyrrolidone as protective agent, with glucose
Direct-reduction silver nitrate prepares nano silver colloidal sol solution；Prepared in hydrothermal reaction kettle it is relatively easy, easily controllable, and close
It is carried out in closure system, the volatilization of noxious material can be effectively prevented and prepares the substance to air-sensitive.Obtained nanometer
Silver-colored antimicrobial fluid crystal property is preferable, and Nano silver grain is spherical shape, belongs to the nano silver of centroid cubic crystal system, dispersibility is preferable, particle
Uniform particle diameter, for most of grain diameter in 20nm or so, stability is strong, can be widely applied to timber anti-biotic material, anti-bacterial fibre,
Antimicrobial building material, antibiotic plastic.
The technical solution adopted by the present invention to solve the technical problems is: a kind of preparation method of nanometer silver antimicrobial liquid, packet
Include following steps:
(1) 1g polyvinylpyrrolidone is dissolved in formation polyvinylpyrrolidone water in 20ml distilled water at room temperature
It is molten；
(2) 0.1mol/L NaOH solution 10ml and 0.2mol/L are sequentially added in aqueous povidone solution
Glucose solution 10ml, being sufficiently stirred with glass bar makes it be uniformly dispersed, and 0.05mol/L AgNO is then added3Solution 20ml,
Become the reaction solution of black gray expandable；
(3) obtained reaction solution is transferred to using polytetrafluoroethylene (PTFE) as in the 100ml hydrothermal reaction kettle of liner, at 140 DEG C
Lower airtight heating 6h, to after the reaction was completed, take out reaction solution from reaction kettle, make its cooled to room temperature；
(4) by reaction solution taking-up and with the revolving speed centrifugal treating of 8000rpm, most of organic matter in solvent is removed；
(5) it is repeatedly washed using distilled water as dispersing agent with detergent, obtains nanometer silver antimicrobial liquid.
Further, the distilled water in the step (1) is secondary distilled water.
In addition, the invention further relates to the application of nano-antibacterial liquid obtained by the preparation method of the nanometer silver antimicrobial liquid, it should
Nano-antibacterial liquid is applied to timber anti-biotic material, anti-bacterial fibre, antimicrobial building material, antibiotic plastic.
Anti-bacterial fibre: fiber can adsorb many microorganisms, such as bacterium, virus etc., these most of microorganisms are being suitable for
At a temperature of, it can be proliferated quickly, thus various harm are generated to the mankind.Work as so adding antibacterial agent in the fibre and becoming
Moderns pursue the demand of high-quality life.
Antimicrobial building material: the building materials such as antimicrobial building material such as antibiotic paint, anti-bacteria ceramic, antimicrobial sheet material are in hospital, supermarket, food
Application in the environment more demanding to bacterium, mould bacterial content such as product warehouse, food field shows more and more important.Therefore by nothing
Machine antimicrobial technology is introduced into building material product, will assign its antibacterial functions tool and has very important significance.
Antibiotic plastic: various plastic products in daily life are easily infected since temperature, humidity are suitable
Bacterium and virus.Therefore developed country can be killed the bacterium stain on plastics within a certain period of time using antibacterial agent therein
Extremely or inhibit its breeding, keeps itself clean state, reduce the cross contamination occurred because using plastic products.Oneself is in household electric
It has obtained widely answering in the articles such as device, chemical building material product, telecom communication product, food packaging article and kitchen article, toy
With.
In conclusion the preparation method of nanometer silver antimicrobial liquid of the invention utilizes hydro-thermal method, it is with polyvinylpyrrolidone
Protective agent prepares nano silver colloidal sol solution with glucose direct-reduction silver nitrate；It is prepared in hydrothermal reaction kettle relatively easy, easy
It is carried out in control, and in a closed system, the volatilization of noxious material can be effectively prevented and prepares the object to air-sensitive
Matter.Obtained nanometer silver antimicrobial liquid crystal property is preferable, and Nano silver grain is spherical shape, belongs to the nano silver of centroid cubic crystal system,
Dispersed preferably grain diameter is uniform, and for most of grain diameter in 20nm or so, stability is strong, and it is anti-to can be widely applied to timber
Bacterium material, anti-bacterial fibre, antimicrobial building material, antibiotic plastic.
Detailed description of the invention
Fig. 1 is the XRD spectrum of nanometer silver antimicrobial liquid；
Fig. 2 is the SEM figure of nanometer silver antimicrobial liquid.
Specific embodiment
Embodiment 1
An a kind of preparation method for nanometer silver antimicrobial liquid, includes the following steps: described in the present embodiment 1
(1) 1g polyvinylpyrrolidone is dissolved in formation polyvinylpyrrolidone water in 20ml distilled water at room temperature
It is molten；
(2) 0.1mol/L NaOH solution 10ml and 0.2mol/L are sequentially added in aqueous povidone solution
Glucose solution 10ml, being sufficiently stirred with glass bar makes it be uniformly dispersed, and 0.05mol/L AgNO is then added3Solution 20ml,
Become the reaction solution of black gray expandable；
(3) obtained reaction solution is transferred to using polytetrafluoroethylene (PTFE) as in the 100ml hydrothermal reaction kettle of liner, at 140 DEG C
Lower airtight heating 6h, to after the reaction was completed, take out reaction solution from reaction kettle, make its cooled to room temperature；
(4) by reaction solution taking-up and with the revolving speed centrifugal treating of 8000rpm, most of organic matter in solvent is removed；
(5) it is repeatedly washed using distilled water as dispersing agent with detergent, obtains nanometer silver antimicrobial liquid.
In the present embodiment, the distilled water in the step (1) is secondary distilled water.
In addition, the invention further relates to the application of nano-antibacterial liquid obtained by the preparation method of the nanometer silver antimicrobial liquid, it should
Nano-antibacterial liquid is applied to timber anti-biotic material, anti-bacterial fibre, antimicrobial building material, antibiotic plastic.
Anti-bacterial fibre: fiber can adsorb many microorganisms, such as bacterium, virus etc., these most of microorganisms are being suitable for
At a temperature of, it can be proliferated quickly, thus various harm are generated to the mankind.Work as so adding antibacterial agent in the fibre and becoming
Moderns pursue the demand of high-quality life.
Antimicrobial building material: the building materials such as antimicrobial building material such as antibiotic paint, anti-bacteria ceramic, antimicrobial sheet material are in hospital, supermarket, food
Application in the environment more demanding to bacterium, mould bacterial content such as product warehouse, food field shows more and more important.Therefore by nothing
Machine antimicrobial technology is introduced into building material product, will assign its antibacterial functions tool and has very important significance.
Antibiotic plastic: various plastic products in daily life are easily infected since temperature, humidity are suitable
Bacterium and virus.Therefore developed country can be killed the bacterium stain on plastics within a certain period of time using antibacterial agent therein
Extremely or inhibit its breeding, keeps itself clean state, reduce the cross contamination occurred because using plastic products.Oneself is in household electric
It has obtained widely answering in the articles such as device, chemical building material product, telecom communication product, food packaging article and kitchen article, toy
With.
Fig. 1 is the XRD spectrum of nanometer silver antimicrobial liquid, in 1g PVP, the glucose of the NaOH of 0.1mol/L, 0.2mol/L,
0.05mol/L AgNO3Solution, temperature be 140 DEG C at hydro-thermal reaction 6h preparation condition under.As shown in Figure 1, nano silver is in 2 θ
To there is 5 apparent absorption peaks at 38.10 °, 44.36 °, 64.47 °, 77.42 °, 81.30 °, the peak position of nano silver with
Data are consistent on JCPDS card 04-0783, correspond respectively to (111), (200), (220), (311), (222) of cubic system silver
Crystal face illustrates that sample is the elemental silver of centroid cubic crystal system；The curved diffraction peak is quite sharp, show sample crystallization performance compared with
It is good.Using the XRD spectrum of nanometer silver antimicrobial liquid, the average-size for calculating nano silver particles crystal grain by Scherrer formula is big
Small, the results are shown in Table 1.Table 1 the result shows that: crystallite dimension is calculated in 20nm or so in each crystal face.
The average grain size of 1 nano silver of table
| Crystal face | 111 | 200 | 220 | 311 | 222 |
| D(nm) | 20.02 | 21.43 | 20.02 | 19.34 | 20.67 |
Fig. 2 is in 1g PVP, the glucose of the NaOH of 0.1mol/L, 0.2mol/L, the AgNO of 0.05mol/L3Solution, temperature
Degree is the SEM figure that hydro-thermal reaction 6h prepares nanometer silver antimicrobial liquid at 140 DEG C.By Fig. 2, gained Nano silver grain is spherical shape, dispersion
Property is preferable, and grain diameter is uniform, and most of grain diameter is in 20nm or so.This sample place 30d after, the shape of nano-silver powder and
Partial size is there is no significantly changing, and also there is no significantly reuniting, what is obtained is still the good nano-silver powder of dispersion.It says
The nano-silver powder of bright preparation has very strong stability.
In the forming process of nano silver, add surfactant, make its be adsorbed on nano-Ag particles surface make them it
Between there are a kind of steric hindrance repulsion potential energy, potential barrier just will increase between such particle, to prevent particle agglomeration.In reaction temperature
Degree is 140 DEG C, the glucose of 0.2mol/L, 0.05mol/L AgNO3 solution, under conditions of the reaction time is 6h, when being with PEG
When dispersing agent, nano silver particles are reunited than more serious, and pattern is irregular, and particle is larger；When using PVA as dispersing agent constantly, particle
Reunite more serious, is generated almost without the particle of complete pattern；When using CTAB as dispersing agent, the spheroidal nanometer of class is formd
Silver, but grain diameter is larger while also having some particles reunion.It thus is seen that the presence of PVP is for spherical nano-silver pattern
It is formed with significant impact.
Using PVP as dispersing agent, the glucose of 0.2mol/L, 0.05mol/L AgNO3Solution, reaction time 6h, instead
Temperature is answered to have a significant impact the particle size and its pattern of nano silver.When temperature is lower, when being 50 DEG C, nucleation rate is relatively
Height, growth rate is relatively low, causes gained nano-Ag particles pattern imperfect and reunites seriously, while partial size is smaller, only
More than ten nanometers；When temperature is 100 DEG C, nano-Ag particles pattern tends towards stability, and only small part is reunited, and partial size is close to 20nm；Temperature
When degree is 140 DEG C, to disperse uniform nano silver particles, partial size is in 20nm or so；When temperature is 200 DEG C, it is fiercer to react,
The probability collided between particle increases, and causes to reunite than more serious, obtained nano-Ag particles partial size becomes larger and is distributed also not
It is uniformly 30-50nm.
It is 140 DEG C in reaction temperature, the glucose of 0.2mol/L, 0.05mol/LAgNO3Solution, reaction time 6h,
The concentration of NaOH has a significant impact to the formation of nano silver and its pattern, and the micro change of NaOH will cause nanoscale silver
Very big variation.When the concentration of NaOH is zero, reaction speed is very slow, nucleation rate be less than growth rate, nano silver nucleus to
Each crystal face growth, so that there are triangles for gained nano silver, hexagon is rodlike, the various patterns such as spherical shape；When the concentration of NaOH is
When 0.025mol/L, reaction speed is accelerated, and nucleation rate is accordingly also accelerated, and the silver particles of small particle can be along the biggish silver in part
Nucleating surface continued growth, the nano silver of formation are that particle diameter distribution is non-uniform discoid, and partial size is 100nm or so；Work as NaOH
Concentration be 0.05mol/L when, nucleation and growth carries out simultaneously, obtains the uniform ball shaped nano Argent grain of particle diameter distribution, partial size
Size is 50nm or so；When the concentration of NaOH is 0.1mol/L, atom has reached saturated concentration, nucleation speed in nucleation process
Rate is greater than growth rate, obtains the ball shaped nano Argent grain that partial size is smaller and is evenly distributed, and particle size is 20nm or so；Continue
Increase the concentration of NaOH when making its 0.15mol/L, due to nucleation rate too greatly and growth rate is too small that nano silver is caused to be reunited.
To sum up described, when the concentration of NaOH is 0.1mol/L, obtained spherical nano-silver particle distribution is uniform, and partial size is minimum.
It is 140 DEG C in reaction temperature, the glucose of 0.2mol/L, 0.05mol/L AgNO3When solution, the reaction time is to receiving
The formation of meter Yin has a great impact with pattern.As seen from the figure, reaction time 2h, nano silver particles are mostly small with nucleation stage
Graininess exists, and pattern is irregular, and partial size is mostly in more than ten rans；Reaction time is 4h, the pattern of spherical nano silver
More regular, particle diameter distribution is more uniform；Reaction time is 9h, and the silver particles of small particle continue along the biggish nucleating surface in part
Growth, thus the nano-Ag particles size formed is extremely uneven；React 18h after, little particle partial size increase, partial size redistribution compared with
Uniformly, it is possible thereby to infer during the reaction, with the continuity in reaction time, small particles tachyauxesis at big particle, with
Reaction time continues to extend to 18h or more, and particle can constantly increase, and finally obtained particle size will reach unanimity, this is
Due to joined dispersing agent PVP in experiment so that the little particle dispersion adhered in the larger particles of reunion, so that overall ruler
It is very little to tend to be more uniform again.The result shows that selecting the reaction time preferable for 6h.
PVP is a kind of common high molecular surfactant, white or off-white powder or particle, is with hygroscopicity
Runny powder, it is odorless, it is dissolved in water, alkali, acid and polar organic solvent, there is very strong dilatancy, it can be with multiclass substance network
It closes, is widely used in the preparation process of nano silver particles, surfactant PVP can play dispersion and protection in the reaction
Effect can inhibit the unconfined diffusion of nano silver particles and attachment in particle formation and growth course, control particle it is each to
Anisotropic growth, thus have larger impact for the formation and pattern of nano silver particles.In AgNO3Concentration is 0.05mol/L, NaOH
Concentration is 0.1mol/L, and reaction temperature is 140 DEG C, reaction time 6h, and when PVP is 0g, the silver particles of generation will occur
Reunite, the aggregate pattern of formation is irregular；0.6g PVP is added, the nanoscale silver of generation is not single, and particle diameter distribution is uneven
It is even；When 1.0gPVP is added, particle diameter distribution is uniform, is single dispersing ball nano silver；When 1.5g PVP is added, class ball is formed
Shape nano silver particles, particle size is smaller but particle diameter distribution is uneven.It can therefrom learn with PVP increasing concentrations, particle ruler
Very little smaller, dispersion effect is better, pattern closer to spherical, but with the increasing particle diameter distribution of concentration tend to less uniformly, because
This selection 1.0g PVP is appropriate.
The formation of silver-colored crystal includes two processes of nucleation and crystal growth, and nucleation process needs certain degree of supersaturation to overcome table
Face energy potential, nucleus growth process is then on the basis of nucleation early period, and the elemental silver newly restored is adsorbed on original nucleating surface
And grow up, the two processes are existed simultaneously in dropwise addition AgNO3In the overall process of solution, but early period based on being nucleated, stage with
Based on nucleus growth.When silver nitrate concentration is lower, if silver nitrate concentration is respectively 0.01mol/L, with the increasing of silver nitrate concentration
Greatly, the silver-colored nucleus of generation increases, and degree of super saturation is relatively low, and nucleus growth speed is slower, therefore the nano silver generated
The partial size of grain is smaller；As the increase of silver nitrate concentration, such as silver nitrate concentration are respectively 0.05mol/L growth rate with nucleation speed
When rate is identical, reach saturation state, the nano silver partial size generated at this time is minimum；As silver nitrate concentration further increases, satiety
Constantly increase with degree, maintains higher level so that the growth rate of silver-colored crystal is greater than nucleation rate, and therefore, generation is received
The partial size of rice Argent grain is larger.
The above described is only a preferred embodiment of the present invention, not making any form to technical solution of the present invention
On limitation.According to the technical essence of the invention any simple modification to the above embodiments, equivalent variations and repair
Decorations, in the range of still falling within technical solution of the present invention.
Claims (3)
1. a kind of preparation method of nanometer silver antimicrobial liquid, which comprises the steps of:
(1) by 1g polyvinylpyrrolidone be dissolved at room temperature in 20ml distilled water formed polyvinylpyrrolidone it is water-soluble；
(2) grape of 0.1mol/L NaOH solution 10ml and 0.2mol/L is sequentially added in aqueous povidone solution
Sugar juice 10ml, being sufficiently stirred with glass bar makes it be uniformly dispersed, and 0.05mol/L AgNO is then added3Solution 20ml, becomes
The reaction solution of black gray expandable；
(3) obtained reaction solution is transferred to using polytetrafluoroethylene (PTFE) as in the 100ml hydrothermal reaction kettle of liner, it is close at 140 DEG C
Heating 6h is closed, to after the reaction was completed, take out reaction solution from reaction kettle, make its cooled to room temperature；
(4) by reaction solution taking-up and with the revolving speed centrifugal treating of 8000rpm, most of organic matter in solvent is removed；
(5) it is repeatedly washed using distilled water as dispersing agent with detergent, obtains nanometer silver antimicrobial liquid.
2. a kind of preparation method of nanometer silver antimicrobial liquid according to claim 1, which is characterized in that in the step (1)
Distilled water be secondary distilled water.
3. the application of nano-antibacterial liquid obtained by the preparation method of nanometer silver antimicrobial liquid according to claim 1, which is characterized in that
Nano-antibacterial liquid is applied to timber anti-biotic material, anti-bacterial fibre, antimicrobial building material, antibiotic plastic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811495492.0A CN109575359A (en) | 2018-12-07 | 2018-12-07 | A kind of preparation method and application of nanometer silver antimicrobial liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811495492.0A CN109575359A (en) | 2018-12-07 | 2018-12-07 | A kind of preparation method and application of nanometer silver antimicrobial liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109575359A true CN109575359A (en) | 2019-04-05 |
Family
ID=65929040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811495492.0A Pending CN109575359A (en) | 2018-12-07 | 2018-12-07 | A kind of preparation method and application of nanometer silver antimicrobial liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109575359A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111804927A (en) * | 2019-04-10 | 2020-10-23 | 近镒生技股份有限公司 | Nano silver particle, porous material composition and preparation method thereof |
| CN112717197A (en) * | 2020-09-30 | 2021-04-30 | 合肥天太科技有限公司 | Sterilizing and antiviral liquid dressing capable of inhibiting viruses and preparation method thereof |
| CN114367316A (en) * | 2022-01-20 | 2022-04-19 | 桂林清研皓隆新材料有限公司 | Composite photocatalyst, preparation method and application thereof, antibacterial liquid and preparation method thereof |
| CN114467973A (en) * | 2022-01-07 | 2022-05-13 | 台山市新建业（药用）五金包装有限公司 | Nano-silver antibacterial material for food-grade and/or medical-grade packaging material and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1653907A (en) * | 2005-01-27 | 2005-08-17 | 浙江大学 | Method for preparing nanometer silver solution and nanometer silver powder by using high polymer as stabilizer |
| WO2006049379A1 (en) * | 2004-11-08 | 2006-05-11 | Bio Dreams Co. Ltd. | Composition for controlling pathogenic microorganisms in plants |
| WO2006049478A1 (en) * | 2004-11-08 | 2006-05-11 | Bio Dreams Co. Ltd. | Anti-microbial fiber products |
| CN101999412A (en) * | 2010-11-19 | 2011-04-06 | 佘振定 | Nano-silver solution and preparation method thereof |
| CN103563983A (en) * | 2012-07-24 | 2014-02-12 | 上海纳米技术及应用国家工程研究中心有限公司 | Nano-silver peroxide composite antibacterial solution and preparation method thereof |
| CN105268991A (en) * | 2015-11-09 | 2016-01-27 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing high-concentration nano silver monomer dispersion liquid |
-
2018
- 2018-12-07 CN CN201811495492.0A patent/CN109575359A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006049379A1 (en) * | 2004-11-08 | 2006-05-11 | Bio Dreams Co. Ltd. | Composition for controlling pathogenic microorganisms in plants |
| WO2006049478A1 (en) * | 2004-11-08 | 2006-05-11 | Bio Dreams Co. Ltd. | Anti-microbial fiber products |
| CN1653907A (en) * | 2005-01-27 | 2005-08-17 | 浙江大学 | Method for preparing nanometer silver solution and nanometer silver powder by using high polymer as stabilizer |
| CN101999412A (en) * | 2010-11-19 | 2011-04-06 | 佘振定 | Nano-silver solution and preparation method thereof |
| CN103563983A (en) * | 2012-07-24 | 2014-02-12 | 上海纳米技术及应用国家工程研究中心有限公司 | Nano-silver peroxide composite antibacterial solution and preparation method thereof |
| CN105268991A (en) * | 2015-11-09 | 2016-01-27 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing high-concentration nano silver monomer dispersion liquid |
Non-Patent Citations (1)
| Title |
|---|
| 刘艳娥等: "水热法制备球形纳米银粒子及其表征", 《材料导报》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111804927A (en) * | 2019-04-10 | 2020-10-23 | 近镒生技股份有限公司 | Nano silver particle, porous material composition and preparation method thereof |
| CN112717197A (en) * | 2020-09-30 | 2021-04-30 | 合肥天太科技有限公司 | Sterilizing and antiviral liquid dressing capable of inhibiting viruses and preparation method thereof |
| CN114467973A (en) * | 2022-01-07 | 2022-05-13 | 台山市新建业（药用）五金包装有限公司 | Nano-silver antibacterial material for food-grade and/or medical-grade packaging material and preparation method thereof |
| CN114367316A (en) * | 2022-01-20 | 2022-04-19 | 桂林清研皓隆新材料有限公司 | Composite photocatalyst, preparation method and application thereof, antibacterial liquid and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109575359A (en) | A kind of preparation method and application of nanometer silver antimicrobial liquid | |
| CN101731272B (en) | Method for preparing antibacterial nanometer silver colloid | |
| An et al. | Preparation and characterization of silver‐chitosan nanocomposite particles with antimicrobial activity | |
| Vijayakumar et al. | Biosynthesis, characterisation and anti-bacterial effect of plant-mediated silver nanoparticles using Artemisia nilagirica | |
| CN107858046B (en) | Super-hydrophobic coating with self-cleaning and antibacterial functions and preparation method thereof | |
| CN105776179B (en) | A kind of water soluble quaternary ammonium salinization Nano carbon balls and preparation method and application | |
| CN106818869B (en) | A kind of preparation method of carbon-based nano carbon/carbon-copper composite material | |
| CN104525966B (en) | A kind of xanthan gum-argentum nano composite material and preparation method thereof | |
| CN102191681A (en) | Antibacterial non-woven fabric and method for producing non-woven fabric product | |
| Maryan et al. | Synthesize of nano silver using cellulose or glucose as a reduction agent: the study of their antibacterial activity on polyurethan fibers | |
| CN115068605B (en) | Ag (silver) alloy 2 S@TCPP-UiO-66-NH 2 Light response nano antibacterial material, preparation method and application thereof | |
| Ding et al. | Facile preparation of raspberry-like PS/ZnO composite particles and their antibacterial properties | |
| Jose et al. | Spectroscopic and thermal investigation of silver nanoparticle dispersed biopolymer matrix bovine serum albumin: A promising antimicrobial agent against the Pathogenic Bacterial Strains | |
| Su et al. | Mesoporous silica doped with different water-soluble ligands to enhance the antibacterial performance of nano zinc oxides by coordination effect | |
| CN113577027A (en) | Reinforced preparation method of polymer-stabilized inorganic antibacterial nanoparticles | |
| CN108213459B (en) | Preparation method of glucan/nano gold-silver alloy compound | |
| Hong et al. | Metal-phenolic coated rod-like silica nanocarriers with pH responsiveness for pesticide delivery | |
| CN112831068B (en) | Preparation method of novel antibacterial composite material | |
| CN102190904A (en) | Production method of antibacterial high-water-absorbability resin | |
| CN109744255A (en) | A kind of surface coating method of spherical nano silver antibacterial material | |
| CN109161224A (en) | A kind of composite antibacterial filler and preparation method for plastics | |
| Beiraghdar et al. | Surfactant-assisted ZnO thin films prepared by sol–gel dip coating for applied antibacterial coatings: a comparative study with solvothermal-derived ZnO powders | |
| CN114848818A (en) | Berberine derivative-metal complex nano material and preparation method and application thereof | |
| CN111842926A (en) | Method for continuously preparing silver nanoparticles by turbulence enhancement, and obtained material and application thereof | |
| Moreno et al. | Modulation of bactericidal action in polymer nanocomposites: Light-tuned Ag+ release from electrospun PMMA fibers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190405 |