CN109574218A - Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate apparatus and method - Google Patents

Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate apparatus and method Download PDF

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CN109574218A
CN109574218A CN201811576291.3A CN201811576291A CN109574218A CN 109574218 A CN109574218 A CN 109574218A CN 201811576291 A CN201811576291 A CN 201811576291A CN 109574218 A CN109574218 A CN 109574218A
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reactor
short distance
distance nitration
fermentation
denitrification
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CN109574218B (en
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彭永臻
张方斋
王众
姜浩
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Beijing University of Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate

Abstract

Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate apparatus and method, belong to high-ammonia-nitrogen sewage sludge organism process field.Treatment of advanced stage landfill leachate initially enters short distance nitration reactor and influent ammonia nitrogen is completely converted into nitrite nitrogen;The water outlet of 92.6% short distance nitration enters fermentation coupling denitrification reactor together with excess sludge and realizes that denitrification and the synchronous of excess sludge digestion carry out;It, which is discharged, is then mixed into anaerobic ammonia oxidation reactor with the water outlet of remaining 7.4% short distance nitration, and the nitrite nitrogen that the ammonia nitrogen and short distance nitration for discharging fermentation process generate further is removed.The present invention is completed at the same time residual sludge reduction than the advanced nitrogen for the treatment of of advanced stage landfill leachate in the low C/N of realization.

Description

Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process handles advanced stage garbage filter The apparatus and method of liquid
Technical field
The present invention relates to a kind of short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process to handle treatment of advanced stage landfill leachate skill Art belongs to high-ammonia-nitrogen sewage sludge organism process field.
Background technique
In recent years, being continuously increased with municipal solid waste yield, landfill method are increasingly becoming most widely used in the world General processing and method of disposal.Fill the percolate that generates because have complicated component, water quality and quantity change greatly, organic matter and ammonia nitrogen The water quality characteristics such as high, the microbial nutrition element ratio imbalance of concentration, make it be treated as in international coverage still unsolved problem One of.Traditional biological denitrification process is by NH4 +- N is converted into N03 -- N, then pass through denitrification for N03 -- N is converted into nitrogen from water Evolution.The denitrification stage is with N03 -- N is electron acceptor, and mineralized nitrogen is that nitrogen completes biology as electron donor by organic matter Denitrogenation.Organic carbon source there is a serious shortage of being barrier that mature leachate nitric efficiency can not improve, cause traditional biological denitrogenation to be imitated Rate can only achieve 10% or so, and additional organic carbon source can significantly increase the expense of sewage water denitrification.
Excess sludge is that the by-product in biological wastewater treatment process contains large amount of organic, is generated after anaerobic fermentation Volatile short chain fatty acids can be used as the high-quality carbon source of biological denitrification process.Exploitation excess sludge in carbon source and be subject to benefit With two stubborn problems of sewage treatment plant's carbon source deficiency and residual sludge reduction can be solved simultaneously.However excess sludge is sent out It is discharged during ferment along with a large amount of ammonia nitrogen, it will be significantly if sludge-digestion liquid is flowed back into sewage treatment plant without processing Increase sewage treatment nitrogen load and operation energy consumption.It is, therefore, desirable to provide the device and method of more efficiently denitrogenation.
Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process handles treatment of advanced stage landfill leachate, first high-concentration ammonia-nitrogen Treatment of advanced stage landfill leachate realize that stable nitrite nitrogen accumulates by short distance nitration process, excess sludge is anti-in fermentation denitrification It answers in device and is digested, electron donor of the organic carbon source of generation as denitrification process, the Asia that most of short distance nitration is generated Nitrate-nitrogen reduction is nitrogen.The ammonia nitrogen of sludge digestion process release and the water outlet of remaining short distance nitration are acted on by Anammox Further removed.It compares as a kind of no external carbon addition biological denitrification process with traditional biological denitrification process, not only saves About 25% aeration quantity and 100% carbon source, while excess sludge reduction effect can be completed.
Summary of the invention
The invention proposes short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate sides Method, specifically treatment of advanced stage landfill leachate initially enter short distance nitration reactor and influent ammonia nitrogen are completely converted into nitrite nitrogen; The water outlet of 92.6% short distance nitration enters fermentation coupling denitrification reactor together with excess sludge and realizes denitrification and excess sludge The synchronous of digestion carries out;It, which is discharged, is then mixed into anaerobic ammonia oxidation reactor with the water outlet of remaining 7.4% short distance nitration, makes The nitrite nitrogen that the ammonia nitrogen and short distance nitration of fermentation process release generate further is removed.
The purpose of the present invention is achieved through the following technical solutions:
Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate device, feature exist In, including raw water water tank (1), short distance nitration reactor (2), the first intermediate water tank (3), excess sludge conservation tank (4), fermentation coupling Close denitrification reactor (5), the second intermediate water tank (6), anaerobic ammonia oxidation reactor (7);The raw water water tank is equipped with overflow pipe And water outlet;The short distance nitration reactor (2) is equipped with air compressor (2.1), gas flowmeter (2.2), aeration sand head (2.3), the first water inlet (2.5), the first sample tap (2.9), the first discharge outlet (2.10), the first blender (2.7), first into Water peristaltic pump (2.4), pH/DO real-time monitoring device (2.8), ORP real-time monitoring device (2.6);The fermentation coupling denitrification Reactor (5) is equipped with the second water inlet (5.2), the first mud inlet (5.3), the second discharge outlet (5.6), the second water inlet peristaltic pump (5.1), the second blender (5.4), pH real-time watch device (5.5);The anaerobic ammonia oxidation reactor is equipped with blow-down pipe (7.6), third water inlet (7.2), third water inlet peristaltic pump (7.1), the first refluxing opening (7.7), the first reflux peristaltic pump (7.9), the second refluxing opening (7.10), three phase separator (7.4), exhaust outlet (7.5), airbag (7.3), third discharge outlet (7.6);
Raw water water tank (1) passes through the first water inlet peristaltic pump (2.4) and the first water inlet of short distance nitration reactor (2.5) phase Even;The first water outlet of short distance nitration reactor (2.10) respectively with the first intermediate water tank water inlet (3.1) and the second intermediate water tank Water inlet (6.2) is connected, and air is by air compressor (2.1), gas flowmeter (2.2) eventually by aeration sand head (2.3) Squeeze into short distance nitration reactor (2);First intermediate water tank water outlet (3.3) passes through the second water inlet peristaltic pump (5.1) and fermentation coupling The second water inlet of denitrification reactor (5.2) are closed to be connected;Sludge conservation tank (4) and fermentation the first mud inlet of coupling denitrification (5.3) it is connected;Fermentation the second discharge outlet of coupling denitrification reactor (5.6) is connected with the second intermediate water tank (6);Second intermediate water Case water outlet (6.4) is connected by third water inlet peristaltic pump (7.1) with anaerobic ammonia oxidation reactor third water inlet (7.2);Detest The first refluxing opening of anaerobic ammonium oxidation reactor (7.7) is connected by the first reflux peristaltic pump (7.9) with the second refluxing opening (7.10).
Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process, which is carried out, using described device handles treatment of advanced stage landfill leachate Method, which is characterized in that including following procedure:
1) short distance nitration sludge, fermentation coupling denitrification sludge, anaerobic ammonium oxidation sludge are added to short distance nitration respectively In reactor, fermentation coupling denitrification reactor and anaerobic ammonia oxidation reactor, it is dirty that control adds rear each reactor mixed liquor Mud concentration is respectively 4125-5079mg/L, 8797-16522mg/L and 5633-6210mg/L.
2) treatment of advanced stage landfill leachate in raw water water tank is pumped into short distance nitration reactor, opens the first blender and sky Air compressor controls short distance nitration reactor dissolved oxygen concentration 0.2-0.5mg/L, needs to consume basicity during short distance nitration, When pH is preferably minimized i.e. " ammonia valley point " after reaction, aeration time is by pH/DO real-time monitoring device strict control, when pH song Line occurs stopping aeration when " ammonia valley point ", closes the first blender and air compressor, will be discharged after precipitating 30min according to 25:2 Volume ratio is discharged into the first and second intermediate water tanks respectively.
3) it is anti-to be pumped into the coupling denitrification that ferments by the second water inlet peristaltic pump of opening for the first intermediate water tank Central Asia nitrate wastewater Device is answered, while sludge in storage mud tank being added to fermentation coupling denitrification reactor, denitrification process is a generation basicity Process, as the carry out pH of reaction constantly rises, inflection point i.e. " nitrite elbow " will occur in pH curve after denitrification, beat The second blender is opened, the anoxia stirring time passes through pH/DO real-time monitoring device strict control by aeration time, when pH curve goes out Stop stirring when existing " nitrite elbow ", the second blender of closing, supernatant is discharged into the second intermediate water tank after precipitating 90min.
4) it opens third water inlet peristaltic pump nitrite nitrogen/ammonia nitrogen that concentration ratio in the second intermediate water tank is 1-1.32 gives up Water is pumped into anaerobic ammonia oxidation reactor, and control third water inlet wriggling flow rate pump is 0.15L/h, anaerobic ammonia oxidation reactor waste water by First refluxing opening is pumped into the second refluxing opening by the first reflux peristaltic pump, and control the first reflux wriggling flow rate pump is 0.45L/h.
Technical principle
Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate apparatus and method, it is first Treatment of advanced stage landfill leachate is first pumped into short distance nitration reactor, influent ammonia nitrogen is completely converted into nitrite nitrogen.Short distance nitration reaction 92.6% water outlet enters the first intermediate water tank in device, and remaining 7.4% water outlet enters the second intermediate water tank.First intermediate water tank Middle nitrite nitrogen waste water enters fermentation coupling denitrification reactor together with excess sludge and realizes that denitrification and excess sludge digest Synchronous carry out.It can be discharged along with ammonia nitrogen in sludge digestion process, in order to realize advanced nitrogen, fermentation coupling denitrification reaction The water outlet of device and the second intermediate water tank nitrite nitrogen waste water are mixed into anaerobic ammonia oxidation reactor, are acted on by Anammox The nitrite nitrogen that the ammonia nitrogen and short distance nitration for discharging fermentation process generate further is removed.The present invention is realizing low C/N Advanced nitrogen than treatment of advanced stage landfill leachate is completed at the same time residual sludge reduction.
Short distance nitration-fermentation/denitrification of the present invention-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate dress It sets and is had the advantage that with method
1) by the way that excess sludge is fermented, the combination of denitrification and Anammox, realize truly The advanced nitrogen for the treatment of of advanced stage landfill leachate achievees the purpose that saving carbon source adds and processing cost.
2) short distance nitration that the present invention uses is acted on using inorganic carbon as carbon source, and mineralized nitrogen is nitrous state by ammonia oxidation bacteria Nitrogen has saved 25% aeration quantity compared with traditional complete nitrification, and in the metabolic process without N2O is generated, therefore this technique greenhouse Gas discharge is few.
3) influent ammonia nitrogen is completely converted by nitrite nitrogen, Real-Time Control Strategy by pH curve real-time control aeration time Nitrification can be not only strict controlled in the short distance nitration stage, but also avoid the growth of NOB caused by overexposure gas and the energy Waste.
4) reaction time of short distance nitration and fermentation coupling denitrification is all made of pH curve real-time control, when water inlet advanced stage rubbish The fluctuation of rubbish leachate quality still can realize the efficient removal of system nitrogen with the stable operation of system.
5) organic carbon source that excess sludge fermentation process generates can generate short distance nitration process as electron donor Nitrite nitrogen is reduced to nitrogen.While saving 100% carbon source, the digestion of excess sludge is completed.
6) ammonia nitrogen of excess sludge fermentation process release is acted on by Anammox is further removed, and is realized late The advanced nitrogen of phase landfill leachate is handled.
Detailed description of the invention
Fig. 1 is the device of the invention figure.
Specific embodiment
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
As shown in Figure 1, short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate dress It sets, which is characterized in that including raw water water tank (1), short distance nitration reactor (2), the first intermediate water tank (3), excess sludge deposit Tank (4), fermentation coupling denitrification reactor (5), the second intermediate water tank (6), anaerobic ammonia oxidation reactor (7);
The raw water water tank is equipped with overflow pipe and water outlet;The short distance nitration reactor (2) is equipped with air compressor (2.1), gas flowmeter (2.2), aeration sand head (2.3), the first water inlet (2.5), the first sample tap (2.9), the first draining Mouth (2.10), the first blender (2.7), the first water inlet peristaltic pump (2.4), pH/DO real-time monitoring device (2.8), ORP are supervised in real time It surveys device (2.6);The fermentation coupling denitrification reactor (5) is equipped with the second water inlet (5.2), the first mud inlet (5.3), the Two discharge outlet (5.6), the second water inlet peristaltic pump (5.1), the second blender (5.4), pH real-time watch device (5.5);It is described to detest Anaerobic ammonium oxidation reactor is equipped with blow-down pipe (7.6), third water inlet (7.2), third water inlet peristaltic pump (7.1), the first refluxing opening (7.7), the first reflux peristaltic pump (7.9), the second refluxing opening (7.10), three phase separator (7.4), exhaust outlet (7.5), airbag (7.3), third discharge outlet (7.6);
Raw water water tank (1) passes through the first water inlet peristaltic pump (2.4) and the first water inlet of short distance nitration reactor (2.5) phase Even;The first water outlet of short distance nitration reactor (2.10) respectively with the first intermediate water tank water inlet (3.1) and the second intermediate water tank Water inlet (6.2) is connected, and air is by air compressor (2.1), gas flowmeter (2.2) eventually by aeration sand head (2.3) Squeeze into short distance nitration reactor (2);First intermediate water tank water outlet (3.3) passes through the second water inlet peristaltic pump (5.1) and fermentation coupling The second water inlet of denitrification reactor (5.2) are closed to be connected;Sludge conservation tank (4) and fermentation the first mud inlet of coupling denitrification (5.3) it is connected;Fermentation the second discharge outlet of coupling denitrification reactor (5.6) is connected with the second intermediate water tank (6);Second intermediate water Case water outlet (6.4) is connected by third water inlet peristaltic pump (7.1) with anaerobic ammonia oxidation reactor third water inlet (7.2);Detest The first refluxing opening of anaerobic ammonium oxidation reactor (7.7) is connected by the first reflux peristaltic pump (7.9) with the second refluxing opening (7.10).
Specific test water is practical treatment of advanced stage landfill leachate in the present embodiment, the ammonia nitrogen concentration that is averaged for 1736 ± 40mg/L, COD mean concentration are 2109 ± 200mg/L, and average basicity is 4000 ± 1000mg/L (with CaCO3Meter).It tests short Journey nitrator uses batch-type SBR, dischargeable capacity 10L, drains ratio 50%;Fermentation coupling denitrification reactor, which uses, to be had Effect volume is 6L batch-type SBR, sludge volume dosing ratio 16.7-41.7%;Anaerobic ammonia oxidation reactor uses up-flow anaerobism Sludge bed reactor (UASB) dischargeable capacity is 2L;
Specific operation process is as follows:
1) short distance nitration sludge, fermentation coupling denitrification sludge, anaerobic ammonium oxidation sludge are added to short distance nitration respectively In reactor, fermentation coupling denitrification reactor and anaerobic ammonia oxidation reactor, it is dirty that control adds rear each reactor mixed liquor Mud concentration is respectively 4125-5079mg/L, 8797-16522mg/L and 5633-6210mg/L.
2) treatment of advanced stage landfill leachate in raw water water tank is pumped into short distance nitration reactor, opens the first blender and sky Air compressor controls short distance nitration reactor dissolved oxygen concentration 0.2-0.5mg/L, needs to consume basicity during short distance nitration, When pH is preferably minimized i.e. " ammonia valley point " after reaction, aeration time is by pH/DO real-time monitoring device strict control, when pH song Line occurs stopping aeration when " ammonia valley point ", closes the first blender and air compressor, will be discharged after precipitating 30min according to 25:2 Volume ratio is discharged into the first and second intermediate water tanks respectively.
3) it is anti-to be pumped into the coupling denitrification that ferments by the second water inlet peristaltic pump of opening for the first intermediate water tank Central Asia nitrate wastewater Device is answered, while sludge in storage mud tank being added to fermentation coupling denitrification reactor, denitrification process is a generation basicity Process, as the carry out pH of reaction constantly rises, inflection point i.e. " nitrite elbow " will occur in pH curve after denitrification, beat The second blender is opened, the anoxia stirring time passes through pH/DO real-time monitoring device strict control by aeration time, when pH curve goes out Stop stirring when existing " nitrite elbow ", the second blender of closing, supernatant is discharged into the second intermediate water tank after precipitating 90min.
4) it opens third water inlet peristaltic pump nitrite nitrogen/ammonia nitrogen that concentration ratio in the second intermediate water tank is 1-1.32 gives up Water is pumped into anaerobic ammonia oxidation reactor, and control third water inlet wriggling flow rate pump is 0.15L/h, anaerobic ammonia oxidation reactor waste water by First refluxing opening is pumped into the second refluxing opening by the first reflux peristaltic pump, and control the first reflux wriggling flow rate pump is 0.45L/h.
Long run test the result shows that:
Short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process is respectively 1736 in influent ammonia nitrogen, total nitrogen and COD concentration Under conditions of ± 40mg/L, 2023 ± 75mg/L and 2109 ± 200mg/L, nitrogen removal rate and TN removel rate can reach To 98.7% and 0.52kg/m3d.Excess sludge more than 62.5% completes minimizing, average cell decaying speed within the system Rate is 0.274/d, and mean sludge digestion rate is up to 5.96kg/m3d。

Claims (2)

1. short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process processing treatment of advanced stage landfill leachate device, which is characterized in that Including raw water water tank (1), short distance nitration reactor (2), the first intermediate water tank (3), excess sludge conservation tank (4), fermentation coupling Denitrification reactor (5), the second intermediate water tank (6), anaerobic ammonia oxidation reactor (7);
The raw water water tank is equipped with overflow pipe and water outlet;The short distance nitration reactor (2) be equipped with air compressor (2.1), Gas flowmeter (2.2), aeration sand head (2.3), the first water inlet (2.5), the first sample tap (2.9), the first discharge outlet (2.10), the first blender (2.7), the first water inlet peristaltic pump (2.4), pH/DO real-time monitoring device (2.8), ORP real-time monitoring Device (2.6);The fermentation coupling denitrification reactor (5) is equipped with the second water inlet (5.2), the first mud inlet (5.3), second Discharge outlet (5.6), the second water inlet peristaltic pump (5.1), the second blender (5.4), pH real-time watch device (5.5);The anaerobism Ammonia oxidation reactor is equipped with blow-down pipe (7.6), third water inlet (7.2), third water inlet peristaltic pump (7.1), the first refluxing opening (7.7), the first reflux peristaltic pump (7.9), the second refluxing opening (7.10), three phase separator (7.4), exhaust outlet (7.5), airbag (7.3), third discharge outlet (7.6);
Raw water water tank (1) is connected by the first water inlet peristaltic pump (2.4) with the first water inlet of short distance nitration reactor (2.5);It is short The first water outlet of journey nitrator (2.10) respectively with the first intermediate water tank water inlet (3.1) and the second intermediate water tank water inlet (6.2) it is connected, air is squeezed by air compressor (2.1), gas flowmeter (2.2) eventually by aeration sand head (2.3) short Journey nitrator (2);First intermediate water tank water outlet (3.3) couples anti-nitre with fermentation by the second water inlet peristaltic pump (5.1) Change the second water inlet of reactor (5.2) to be connected;Sludge conservation tank (4) is connected with fermentation the first mud inlet of coupling denitrification (5.3); Fermentation the second discharge outlet of coupling denitrification reactor (5.6) is connected with the second intermediate water tank (6);Second intermediate water tank water outlet (6.4) it is connected by third water inlet peristaltic pump (7.1) with anaerobic ammonia oxidation reactor third water inlet (7.2);Anammox The first refluxing opening of reactor (7.7) is connected by the first reflux peristaltic pump (7.9) with the second refluxing opening (7.10).
2. carrying out short distance nitration-fermentation/denitrification-anaerobic ammonia oxidation process using claim 1 described device handles advanced stage rubbish Rubbish percolate, which is characterized in that including following procedure:
1) short distance nitration sludge, fermentation coupling denitrification sludge, anaerobic ammonium oxidation sludge are added to short distance nitration and is reacted respectively In device, fermentation coupling denitrification reactor and anaerobic ammonia oxidation reactor, it is dense that control adds rear each reactor mixed liquor sludge Degree is respectively 4125-5079mg/L, 8797-16522mg/L and 5633-6210mg/L;
2) treatment of advanced stage landfill leachate in raw water water tank is pumped into short distance nitration reactor, opens the first blender and air pressure Contracting machine controls short distance nitration reactor dissolved oxygen concentration 0.2-0.5mg/L, needs to consume basicity during short distance nitration, when anti- PH is preferably minimized i.e. " ammonia valley point " after answering, and aeration time is by pH/DO real-time monitoring device strict control, when pH curve goes out Stop aeration when existing " ammonia valley point ", close the first blender and air compressor, will be discharged after precipitating 30min according to 25:2 volume Than being discharged into the first and second intermediate water tanks respectively;
3) it opens the second water inlet peristaltic pump and the first intermediate water tank Central Asia nitrate wastewater is pumped into fermentation coupling denitrification reactor, Sludge in storage mud tank is added to fermentation coupling denitrification reactor simultaneously, denitrification process is the process of a generation basicity, As the carry out pH of reaction constantly rises, inflection point i.e. " nitrite elbow " will occur in pH curve after denitrification, open the Two blenders, anoxia stirring time pass through pH/DO real-time monitoring device strict control by aeration time, when pH curve occurs Stop stirring when " nitrite elbow ", the second blender of closing, supernatant is discharged into the second intermediate water tank after precipitating 90min.
4) third water inlet peristaltic pump is opened to pump nitrite nitrogen/ammonia nitrogen waste water that concentration ratio in the second intermediate water tank is 1-1.32 Enter anaerobic ammonia oxidation reactor, control third water inlet wriggling flow rate pump is 0.15L/h, and anaerobic ammonia oxidation reactor waste water is by first Refluxing opening is pumped into the second refluxing opening by the first reflux peristaltic pump, and control the first reflux wriggling flow rate pump is 0.45L/h.
CN201811576291.3A 2018-12-22 2018-12-22 Device and method for treating late landfill leachate through shortcut nitrification-fermentation/denitrification-anaerobic ammonia oxidation process Active CN109574218B (en)

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