CN109553302A - A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof - Google Patents
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof Download PDFInfo
- Publication number
- CN109553302A CN109553302A CN201811629617.4A CN201811629617A CN109553302A CN 109553302 A CN109553302 A CN 109553302A CN 201811629617 A CN201811629617 A CN 201811629617A CN 109553302 A CN109553302 A CN 109553302A
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- CN
- China
- Prior art keywords
- resistance
- cast iron
- fastness
- explosion
- glaze slip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/06—Frit compositions, i.e. in a powdered or comminuted form containing halogen
Abstract
The invention discloses a kind of high acidproof, fastness to alkalies, resistance to explosion cast iron enamel glaze slip and preparation method thereof, a kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are formulated by following weight: glaze block 42-53%, quartzy 6-10%, enamel pigment 3-5%, borax 0.3-0.5%, nitric acid 0.3-0.5%, soda ash 0.4-0.7%, cobalt dioxide 3%-10%, water surplus, the quartz are the quartz of 325-1000 mesh.Beneficial effect is: zirconium dioxide is added in the cast iron enamel glaze slip can greatly improve the alkaline resistance properties of enamel, the finished product made of the cast iron enamel glaze slip has high acidproof grade, good corrosion resistance, wearability, alkaline resistance properties and resistance to chilling performance, a kind of preparation method of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, simple process, it is suitble to large-scale production, high production efficiency is low in cost.
Description
Technical field
The present invention relates to cast iron enamel glaze slip technical fields, more particularly to a kind of high acidproof, fastness to alkali, the cast iron of resistance to explosion
Enamel Slip and preparation method thereof.
Background technique
Vitreous enamel is for the application of slip in metal mold, and group becomes alkali-boron-silicate glass state material, by vitreous enamel
The application of slip can be firmly combined on metal body after being burnt into green body, have protective effect and decoration function to green body；Existing casting
Iron-enamel product is tested according to cast iron enamel grade conformance testing specifications, and acidproof grade can only achieve B grades or B+ grades, enamel glass
The enamel of glass industry at present is general acid-proofenamel, and alkali resistance is not able to satisfy the requirement of alkaline media user, common acidproof
The alkali corrosion resistance index of glaze is 7g/24hm3；The application that 60 DEG C of weak alkaline mediums below can only be met, for 60 DEG C or more
Highly basic medium client, then be extremely difficult to the demand of client.
Summary of the invention
The object of the invention is that providing a kind of high acidproof, fastness to alkali, the cast iron of resistance to explosion to solve the above-mentioned problems
Enamel Slip and preparation method thereof.
The present invention through the following technical solutions to achieve the above objectives:
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof, the height is acidproof, fastness to alkali, resistance to quick-fried
It splits cast iron enamel glaze slip to be formulated by following weight: glaze block 42-53%, quartzy 6-10%, enamel pigment 3-5%, borax 0.3-
0.5%, nitric acid 0.3-0.5%, soda ash 0.4-0.7%, cobalt dioxide 3%-10%, water surplus, the quartz are the stone of 325-1000 mesh
English.
Further, the high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are formulated by following weight: glaze
Block 50%, quartz 8%, enamel pigment 4%, borax 0.4%, nitric acid 0.4%, soda ash 0.5%, cobalt dioxide 5.7%, water 31%.
Further, the glaze block includes following each component substance: silica 63%, titanium dioxide 3%, three oxidations
Two boron 3%, aluminum oxide 3%, calcium oxide 3%, sodium oxide molybdena 20%, prodan 3%, cobalt oxide 2%.
A kind of preparation method of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, comprising the following steps:
A, the substance of the following each components by weight percent of preparation, glaze block 50%, quartz 8%, enamel pigment 4%, borax 0.4%, nitric acid 0.4%,
Soda ash 0.5%, cobalt dioxide 5.7%, water 31%；
B, ready water in the step a is added in ball mill, in a certain order by the material in the step a
It is added separately in ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in the step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, it controls the slurry in the step c and is allowed to concentration control in a certain range.
Further, the revolving speed of ball mill is 30-40 revs/min in the step b.
Further, the concentration of slurries obtained in the step d should be 1.65-1.75 grams per milliliter.
Compared with prior art, beneficial effects of the present invention are as follows:
1, the alkaline resistance properties of enamel can be greatlyd improve by zirconium dioxide being added in the cast iron enamel glaze slip；
2, the finished product made of the cast iron enamel glaze slip has a high acidproof grade, good corrosion resistance, wearability, alkaline resistance properties with
And resistance to chilling performance；
3, a kind of high acidproof, fastness to alkali, the preparation method of resistance to explosion cast iron enamel glaze slip, simple process are suitble to large-scale production,
High production efficiency, it is low in cost.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Embodiment 1
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are by such as
Lower weight is formulated: glaze block 50%, quartz 8%, enamel pigment 4%, borax 0.4%, nitric acid 0.4%, soda ash 0.5%, cobalt dioxide
5.7%, water 31%.
Preparation method:
A, the substance of the following each components by weight percent of preparation, glaze block 50%, quartz 8%, enamel pigment 4%, borax 0.4%, nitric acid 0.4%,
Soda ash 0.5%, cobalt dioxide 5.7%, water 31%；
B, water ready in step a is added in ball mill, is in a certain order separately added into the material in step a
Into ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, the slurry in rate-determining steps c is allowed to concentration control in a certain range.
Embodiment 2
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are by such as
Lower weight is formulated: glaze block 45%, quartz 7%, enamel pigment 4%, borax 0.5%, nitric acid 0.5%, soda ash 0.6%, cobalt dioxide
5.4%, water 37%.
Preparation method:
A, the substance of the following each components by weight percent of preparation, glaze block 45%, quartz 7%, enamel pigment 4%, borax 0.5%, nitric acid 0.5%,
Soda ash 0.6%, cobalt dioxide 5.4%, water 37%；
B, water ready in step a is added in ball mill, is in a certain order separately added into the material in step a
Into ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, the slurry in rate-determining steps c is allowed to concentration control in a certain range.
Embodiment 3
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are by such as
Lower weight is formulated: glaze block 52%, quartz 6%, enamel pigment 5%, borax 0.5%, nitric acid 0.5%, soda ash 0.6%, cobalt dioxide
5.4%, water 30%.
Preparation method:
A, the substance of the following each components by weight percent of preparation, glaze block 52%, quartz 6%, enamel pigment 5%, borax 0.5%, nitric acid 0.5%,
Soda ash 0.6%, cobalt dioxide 5.4%, water 30%；
B, water ready in step a is added in ball mill, is in a certain order separately added into the material in step a
Into ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, the slurry in rate-determining steps c is allowed to concentration control in a certain range.
Embodiment 4
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are by such as
Lower weight is formulated: glaze block 42%, quartz 10%, enamel pigment 5%, borax 0.5%, nitric acid 0.5%, soda ash 0.7%, cobalt dioxide
5.3%, water 36%.
Preparation method:
A, prepare the substance of following each components by weight percent, glaze block 42%, quartz 10%, enamel pigment 5%, borax 0.5%, nitric acid
0.5%, soda ash 0.7%, cobalt dioxide 5.3%, water 36%；
B, water ready in step a is added in ball mill, is in a certain order separately added into the material in step a
Into ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, the slurry in rate-determining steps c is allowed to concentration control in a certain range.
Embodiment 5
A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip are by such as
Lower weight is formulated: glaze block 48%, quartz 10%, enamel pigment 3%, borax 0.3%, nitric acid 0.3%, soda ash 0.7%, cobalt dioxide
5.7%, water 32%.
Preparation method:
A, prepare the substance of following each components by weight percent, glaze block 48%, quartz 10%, enamel pigment 3%, borax 0.3%, nitric acid
0.3%, soda ash 0.7%, cobalt dioxide 5.7%, water 32%；
B, water ready in step a is added in ball mill, is in a certain order separately added into the material in step a
Into ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, the slurry in rate-determining steps c is allowed to concentration control in a certain range.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention
Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements
It all fall within the protetion scope of the claimed invention.
Claims (6)
1. a kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip, it is characterised in that: the described height is acidproof, fastness to alkali, resistance to
Explosion cast iron enamel glaze slip is formulated by following weight: glaze block 42-53%, quartzy 6-10%, enamel pigment 3-5%, borax 0.3-
0.5%, nitric acid 0.3-0.5%, soda ash 0.4-0.7%, cobalt dioxide 3%-10%, water surplus, the quartz are the stone of 325-1000 mesh
English.
2. a kind of high acidproof, fastness to alkali according to claim 1, resistance to explosion cast iron enamel glaze slip, it is characterised in that: described
The acidproof, fastness to alkali of height, resistance to explosion cast iron enamel glaze slip is formulated by following weight: glaze block 50%, quartzy 8%, enamel pigment
4%, borax 0.4%, nitric acid 0.4%, soda ash 0.5%, cobalt dioxide 5.7%, water 31%.
3. a kind of high acidproof, fastness to alkali according to claim 2, resistance to explosion cast iron enamel glaze slip, it is characterised in that: described
Glaze block include following each component substance: silica 63%, titanium dioxide 3%, diboron trioxide 3%, aluminum oxide 3%,
Calcium oxide 3%, sodium oxide molybdena 20%, prodan 3%, cobalt oxide 2%.
4. the preparation method of a kind of high acidproof, fastness to alkali according to claim 1, resistance to explosion cast iron enamel glaze slip, including
Following steps:
A, the substance of the following each components by weight percent of preparation, glaze block 50%, quartz 8%, enamel pigment 4%, borax 0.4%, nitric acid 0.4%,
Soda ash 0.5%, cobalt dioxide 5.7%, water 31%；
B, ready water in the step a is added in ball mill, in a certain order by the material in the step a
It is added separately in ball mill, material is uniformly mixed by ball mill rotation, obtains slurry；
C, slurry obtained in the step b is filtered with the sieve of 40-60 mesh, obtains slurry；
D, it controls the slurry in the step c and is allowed to concentration control in a certain range.
5. the preparation method of a kind of high acidproof, fastness to alkali according to claim 4, resistance to explosion cast iron enamel glaze slip, special
Sign is: the revolving speed of ball mill is 30-40 revs/min in the step b.
6. the preparation method of a kind of high acidproof, fastness to alkali according to claim 4, resistance to explosion cast iron enamel glaze slip, special
Sign is: the concentration of slurries obtained in the step d should be 1.65-1.75 grams per milliliter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811629617.4A CN109553302A (en) | 2018-12-28 | 2018-12-28 | A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811629617.4A CN109553302A (en) | 2018-12-28 | 2018-12-28 | A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109553302A true CN109553302A (en) | 2019-04-02 |
Family
ID=65871786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811629617.4A Pending CN109553302A (en) | 2018-12-28 | 2018-12-28 | A kind of high acidproof, fastness to alkali, resistance to explosion cast iron enamel glaze slip and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB847225A (en) * | 1955-11-07 | 1960-09-07 | Minnesota Mining & Mfg | Improved porcelain enamelling frits |
| CN102408196A (en) * | 2010-09-21 | 2012-04-11 | 湖南立发釉彩科技有限公司 | Fish-scaling-resistant enamel glaze for hot-rolled steel plates |
| CN105036556A (en) * | 2015-07-06 | 2015-11-11 | 昆山美邦环境科技有限公司 | Acid resistant enamel slip, and method using slip to make enamel product |
| CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
| CN108249762A (en) * | 2018-03-23 | 2018-07-06 | 深圳市金合联供应链技术有限公司 | A kind of grate high acid-proof cast iron Enamel Slip and preparation method thereof |
-
2018
- 2018-12-28 CN CN201811629617.4A patent/CN109553302A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB847225A (en) * | 1955-11-07 | 1960-09-07 | Minnesota Mining & Mfg | Improved porcelain enamelling frits |
| CN102408196A (en) * | 2010-09-21 | 2012-04-11 | 湖南立发釉彩科技有限公司 | Fish-scaling-resistant enamel glaze for hot-rolled steel plates |
| CN105036556A (en) * | 2015-07-06 | 2015-11-11 | 昆山美邦环境科技有限公司 | Acid resistant enamel slip, and method using slip to make enamel product |
| CN105948500A (en) * | 2016-04-28 | 2016-09-21 | 攀枝花学院 | Enamel glaze material, enamel slurry, and preparation method and application thereof |
| CN108249762A (en) * | 2018-03-23 | 2018-07-06 | 深圳市金合联供应链技术有限公司 | A kind of grate high acid-proof cast iron Enamel Slip and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20190402 |