CN109550375A - Desulphurization denitration equipment and its technique - Google Patents

Desulphurization denitration equipment and its technique Download PDF

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Publication number
CN109550375A
CN109550375A CN201710884077.3A CN201710884077A CN109550375A CN 109550375 A CN109550375 A CN 109550375A CN 201710884077 A CN201710884077 A CN 201710884077A CN 109550375 A CN109550375 A CN 109550375A
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CN
China
Prior art keywords
partition
absorption tower
flue gas
absorbing liquid
flue
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CN201710884077.3A
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Chinese (zh)
Inventor
刘绍辉
黄乃乔
袁明辉
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PINGXIANG PUTIAN HI-TECH INDUSTRIAL Co Ltd
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PINGXIANG PUTIAN HI-TECH INDUSTRIAL Co Ltd
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Priority to CN201710884077.3A priority Critical patent/CN109550375A/en
Publication of CN109550375A publication Critical patent/CN109550375A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to desulphurization denitration equipment, including ash handling equipment, oxygen regulating device, absorption tower and absorbing liquid circulating slot, the ash handling equipment, oxygen regulating device passes sequentially through flue with absorption tower and is connected to, the front end of the ash handling equipment connects gas inlet, flow control valve is equipped between the gas inlet and ash handling equipment, the first temperature control equipment is equipped between the ash handling equipment and oxygen regulating device, second temperature control device is equipped between the oxygen regulating device and absorption tower, air-introduced machine is equipped between the second temperature control device and absorption tower, the first valve is equipped between first temperature control equipment and ash handling equipment, the absorbing liquid circulating slot is connect with absorption tower, the present invention can be sufficiently separated the particulate matter in flue gas, and by extending movement routine of the flue gas in absorption tower, extend the reaction time, it is right Flue gas carries out abundant desulfurization and denitrification reaction, so that flue gas reaches discharge standard.

Description

Desulphurization denitration equipment and its technique
Technical field
The present invention relates to flue gases purification field more particularly to desulphurization denitration equipment and its technique.
Background technique
In China denitrating flue gas market, it is China NO that catalysts selective, which restores (SCR) technology,XThe main skill of emission control Art, but its active temperature is at 380-420 DEG C, and coking flue gas is 180 DEG C or so after waste heat recycles, and is far below SCR catalyst Active temperature, for the operational characteristic of China's coking flue gas, recycling flue gas desulfurization and denitrification new technology under cryogenic conditions in research and development It is the important measures that China realizes sustainable development, huge economic benefit and environmental benefit will be brought.As flue gas desulfurization is de- The development of nitre technology, each state has all carried out the research of low-temperature flue gas simultaneous SO_2 and NO removal technology, but does not all have also both at home and abroad now There is mature low-temperature denitration technology, all in research and development and experimental stage, there is also more problems for existing technology, such as in flue gas Containing a large amount of particulate matter, desulphurization denitration is insufficient, and especially in wet process, particulate matter can largely effect on the de- of flue gas Sulphur denitration reaction, flue gas are contacted with absorbing liquid and are not enough, and the reaction time falls short of, so that flue gas emission is not up to standard.
Summary of the invention
In view of the above-mentioned state of the art, technical problem to be solved by the present invention lies in provide a kind of to be sufficiently separated Particulate matter in flue gas, and the desulphurization denitration equipment and its technique of abundant desulfurization and denitrification reaction are carried out to the flue gas after separation.
The technical scheme of the invention to solve the technical problem is: desulphurization denitration equipment, including ash handling equipment, oxygen Gas control device, absorption tower and absorbing liquid circulating slot, the ash handling equipment, oxygen regulating device and absorption tower pass sequentially through flue gas The front end of pipeline connection, the ash handling equipment connects gas inlet, and flow is equipped between the gas inlet and ash handling equipment and is adjusted Valve is equipped with the first temperature control equipment, the oxygen regulating device and absorption between the ash handling equipment and oxygen regulating device It is equipped with second temperature control device between tower, is equipped with air-introduced machine between the second temperature control device and absorption tower, described the The first valve is equipped between one temperature control equipment and ash handling equipment, the absorbing liquid circulating slot is connect with absorption tower;
The ash handling equipment includes the motor of dust cleaning brush, driving dust cleaning brush, dust collecting box and ceramic filter plate, the dust cleaning brush In the horizontal flue section between flow control valve and the first valve, the outer circumferential direction of the dust cleaning brush and the inner wall of flue It offsets, the ceramic filter plate is arranged between dust cleaning brush and the first valve, end and the ceramic filter plate phase of the dust cleaning brush It is of use in the dust for removing ceramic filter plate surface, the bottom of the flue section between the flow control valve and the first valve It is provided with the ash discharging hole being connected to dust collecting box, the lower section of the ash discharging hole is equipped with the second valve;
It is provided with baffle assembly in the absorption tower, which includes first to be from bottom to top equidistantly staggered Partition, second partition, third partition and the 4th partition, the first partition, second partition, third partition, the 4th partition etc. are big, The first partition, third partition, is provided with multiple funnel-shaped holes on the 4th partition at second partition, and the multiple funnel-shaped hole is close Collection is arranged on partition, and described be staggered refers to, first partition and third partition are arranged in the same side on absorption tower, second every Side opposite with first partition, third partition in absorption tower is arranged in the 4th partition in plate, and second partition front end protrudes into Between one partition and third partition, third plate front end is protruded between second partition and the 4th partition, the first partition and Four partitions are fixedly mounted in absorption tower, and the second partition and third partition are slidably connected with inner wall of tower is absorbed, in absorption tower Wall is equipped with the guide rail for second partition, the sliding of third partition, and the outside on the absorption tower is equipped with driving second partition and moves horizontally The first cylinder and the second cylinder for moving horizontally of driving third partition;
The top on the absorption tower is equipped with spray tube, and the top of the spray tube is equipped with filling adsorption layer, which passes through Pipeline is connect with absorbing liquid circulating slot, and the bottom on the absorption tower is equipped with liquid outlet, which is followed by pipeline and absorbing liquid The bottom of annular groove is connected to, and the gas outlet to discharge flue gas after purification, absorb the bottom of the tower and fume pipe are provided at the top of absorption tower Road junction is provided with air inlet, and the first partition is arranged above air inlet.
Further, the big opening end of the funnel-shaped hole is towards at the top of absorption tower, and osculum end is and big towards absorb the bottom of the tower Mouthful end is flushed with partition upper surface, and osculum end is downwardly projected partition lower surface, the up big and down small structure setting of funnel-shaped hole, so that When absorbing liquid spray is on partition, can be passed through from funnel-shaped hole, as the diminution in aperture forms thread, and cooperate first every Plate, second partition, third partition, the 4th partition are from bottom to top staggered and multiple funnel-shaped holes are densely arranged in partition On, multi-stage spray can be formed, so that absorbing liquid comes into full contact with flue gas, thus to the NO in flue gasX、SO2It carries out sufficiently de- It removes, in addition, first partition, second partition, third partition, the 4th partition are from bottom to top staggered, when absorbing liquid floods partition When, partition can obstruct flue gas and directly move straight up, so that flue gas is moved along baffle surface, extend the mobile road of flue gas Diameter, to extend the haptoreaction time of flue gas and absorbing liquid, so that absorbing liquid comes into full contact with flue gas, thus in flue gas NOX、SO2Sufficiently removed.
Further, the absorbing liquid circulating slot is also connected with waste liquid device, which can recycle circulation fluid.
Further, the ash discharging hole is funnel-shaped, is convenient to clean the grey wall surface along funnelform ash discharging hole to get off It falls into dust collecting box.
Further, the distance between the first partition, second partition, third partition and the 4th partition are greater than zero, should First partition, second partition, third partition and the 4th partition length be greater than the width of absorption tower half so that partition staggered row Column form bypass channel, extend the movement routine of flue gas.
Further, the spray tube is equipped with multiple spray heads, and the spray head and spray tube are rotatablely connected, so that absorbing Liquid multi-faceted can spray.
Further, the filling adsorption layer is active carbon layer, further purification discharge flue gas.
The technique that desulphurization denitration is carried out using the above-mentioned equipment for flue gas desulfurization and denitrification, is included the following steps:
A, the flue gas that temperature is 160-180 DEG C after waste heat recycling first passes through ash handling equipment and carries out ash disposal processing;
B, ash disposal treated flue gas passes through the first temperature control equipment, and adjusting flue-gas temperature is 130-150 DEG C, by flue gas It is passed through in oxygen regulating device and is reacted, promote NOXIt is converted into NO2
C, the flue gas after reacting with oxygen passes through second temperature control device, and adjusting flue-gas temperature is 110-130 DEG C, flue gas Enter absorption tower from the air inlet of absorb the bottom of the tower by air-introduced machine and carries out desulfurization and denitrification reaction;
D, the absorbing liquid in absorbing liquid circulating slot is sprayed into absorption tower by the spray tube in absorption tower, in spray, is inhaled It receives liquid and forms multi-stage spray by the funnel-shaped hole on first partition, second partition, third partition, the 4th partition, in flue gas NOX、SO2It is sufficiently removed, and is absorbed and filter by filling adsorption layer, so that flue gas reaches discharge standard, from absorption tower The discharge of top gas outlet, when absorbing liquid did not had four partitions, the first cylinder of starting, the second cylinder drive second partition, third Partition moves horizontally, to play agitaion to absorbing liquid, improves the mobile activity of flue gas, and control the spray on absorption tower Leaching amount and the discharge amount of absorb the bottom of the tower liquid outlet balance, which send the liquid product in absorption tower into absorbing liquid and recycle In slot;
E, circulation fluid in absorbing liquid circulating slot introduce waste liquid device handled, recycling, be eventually converted into sulphur Hydrochlorate and nitrate mixture.
Compared with the prior art, the advantages of the present invention are as follows: the present invention is by setting ash handling equipment, by ceramic filter plate pair Flue gas is filtered, and ceramic filter plate has the characteristics that the obstructed ash of ventilation, can divide the particulate matter in flue gas with gas completely From, so that particulate matter is avoided to influence the desulfurization and denitrification reaction of subsequent flue gas, in addition, the setting of oxygen regulating device, so that cigarette NO in gasXIt is converted into NO2, convenient for the absorption of absorbing liquid, thus desulphurization denitration as sufficient as possible, finally, by absorption tower Baffle assembly is set, which includes the first partition being from bottom to top equidistantly staggered, second partition, third partition With the 4th partition, bypass channel is formed, extends the movement routine of flue gas, and cooperate funnel-shaped hole densely arranged on partition, makes It when obtaining on absorbing liquid spray to partition, can be passed through from funnel-shaped hole, as the diminution in aperture forms thread, and cooperate first Partition, second partition, third partition, the 4th partition be from bottom to top staggered and multiple funnel-shaped holes it is densely arranged every On plate, multi-stage spray can be formed, so that absorbing liquid comes into full contact with flue gas, thus to the NO in flue gasX、SO2It carries out sufficiently de- It removes, in addition, first partition, second partition, third partition, the 4th partition are from bottom to top staggered, when absorbing liquid floods partition When, partition can obstruct flue gas and directly move straight up, so that flue gas is moved along baffle surface, extend the mobile road of flue gas Diameter to extend the haptoreaction time of flue gas and absorbing liquid, and cooperates the first cylinder, the second cylinder driving second partition, the Three partitions move horizontally, to play agitaion to absorbing liquid, the mobile activity of flue gas are improved, so that absorbing liquid and flue gas It comes into full contact with, thus to the NO in flue gasX、SO2It is sufficiently removed, reaches discharge standard.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is the structural schematic diagram under partition moving condition of the present invention;
Fig. 3 is the top view of partition of the present invention;
Fig. 4 is the cross-sectional view of partition of the present invention;
As shown, 1 absorption tower, 1.1 air inlets, 1.2 gas outlets, 1.3 liquid outlets, 2 oxygen regulating devices, 3 first temperature Degree control device, 4 second temperature control devices, 5 air-introduced machines, 6 absorbing liquid circulating slots, 7 gas inlets, 8 flues, 9 first Partition, 10 second partitions, 11 third partitions, 12 the 4th partitions, 13 funnel-shaped holes, 14 spray tubes, 15 spray heads, 16 filling adsorptions Layer, 17 waste liquid devices, 18 flow control valves, 19 first valves, 20 second valves, 21 ash discharging holes, 22 dust collecting boxes, 23 ceramic filters Plate, 24 dust cleaning brushs, 25 motors, 26 first cylinders, 27 second cylinders.
Specific embodiment
Present invention will be further explained below with reference to the attached drawings and specific embodiments.
As shown in Figs 1-4, desulphurization denitration equipment, including ash handling equipment, oxygen regulating device 2, absorption tower 1 and absorbing liquid are followed Annular groove 6, the ash handling equipment, oxygen regulating device 2 and absorption tower 1 pass sequentially through flue 8 and are connected to, the ash handling equipment Front end connects gas inlet 7, and flow control valve 18, the ash handling equipment and oxygen are equipped between the gas inlet 7 and ash handling equipment It is equipped with the first temperature control equipment 3 between gas control device 2, the second temperature is equipped between the oxygen regulating device 2 and absorption tower 1 Control device 4 is spent, air-introduced machine 5, the first temperature control dress are equipped between the second temperature control device 4 and absorption tower 1 It sets and is equipped with the first valve 19 between 3 and ash handling equipment, the absorbing liquid circulating slot 6 is connect with absorption tower 1;
The ash handling equipment includes dust cleaning brush 24, the motor 25 for driving dust cleaning brush 24, dust collecting box 22 and ceramic filter plate 23, In the horizontal flue section between flow control valve 18 and the first valve 19 of the dust cleaning brush 24, the periphery of the dust cleaning brush 24 It offsets to the inner wall with flue, the ceramic filter plate 23 is arranged between dust cleaning brush 24 and the first valve 19, described clear The dust that the end of ash brush 24 and ceramic filter plate 23 offset for removing 23 surface of ceramic filter plate, the flow control valve 18 The bottom of flue section between the first valve 19 is provided with the ash discharging hole 21 being connected to dust collecting box 22, under the ash discharging hole 21 Side is equipped with the second valve 20;
It is provided with baffle assembly in the absorption tower 1, which includes to be from bottom to top equidistantly staggered One partition 9, second partition 10, third partition 11 and the 4th partition 12, the first partition 9, second partition 10, third partition 11, the 4th partition 12 etc. is big, which second partition 10, third partition 11, is provided with multiple leakages on the 4th partition 12 Bucket shape hole 13, the multiple funnel-shaped hole 13 is densely arranged on partition, and described be staggered refers to, first partition 9 and third Partition 11 is arranged in the same side on absorption tower 1, second partition 10 and the 4th partition 12 be arranged in absorption tower 1 with first partition 9, The opposite side of third partition 11, and 10 front end of second partition is protruded between first partition 9 and third partition 11, third partition 11 Front end is protruded between second partition 10 and the 4th partition 12, and the first partition 9 and the 4th partition 12 are fixedly mounted on absorption tower 1 Interior, the second partition 10 and third partition 11 are slidably connected with 1 inner wall of absorption tower, 1 inner wall of absorption tower be equipped with for second every The guide rail that plate 10, third partition 11 slide, the outside on the absorption tower 1 are equipped with the first cylinder that driving second partition 10 moves horizontally 26 the second cylinders 27 moved horizontally with driving third partition 11;
The top on the absorption tower 1 is equipped with spray tube 14, and the top of the spray tube 14 is equipped with filling adsorption layer 16, the spray Pipe 14 is connect by pipeline with absorbing liquid circulating slot 6, and the bottom on the absorption tower 1 is equipped with liquid outlet 1.3, and the liquid outlet 1.3 is logical Pipeline is crossed to be connected to the bottom of absorbing liquid circulating slot 6, the top on absorption tower 1 be provided with to discharge purification after flue gas gas outlet 1.2,1 bottom of absorption tower and 8 junction of flue are provided with air inlet 1.1, and the first partition 9 is arranged on air inlet 1.1 Side.
The big opening end of the funnel-shaped hole 13 is towards the top of absorption tower 1, and osculum end is towards 1 bottom of absorption tower, and big opening end It is flushed with partition upper surface, osculum end is downwardly projected partition lower surface, the up big and down small structure setting of funnel-shaped hole 13, so that inhaling When receiving liquid spray on partition, can be passed through from funnel-shaped hole 13, as the diminution in aperture forms thread, and cooperate first every Plate 9, second partition 10, third partition 11, the 4th partition 12 are from bottom to top staggered and multiple funnel-shaped holes 13 are intensively arranged Cloth can form multi-stage spray on partition, so that absorbing liquid comes into full contact with flue gas, thus to the NO in flue gasX、SO2It carries out Sufficiently removing, in addition, first partition 9, second partition 10, third partition 11, the 4th partition 12 are from bottom to top staggered, works as suction When receipts liquid floods partition, partition can obstruct flue gas and directly move straight up, so that flue gas is moved along baffle surface, extend The movement routine of flue gas, thus extend the haptoreaction time of flue gas and absorbing liquid, so that absorbing liquid comes into full contact with flue gas, from And to the NO in flue gasX、SO2Sufficiently removed.
The absorbing liquid circulating slot 6 is also connected with waste liquid device 17, which can recycle circulation fluid.
The distance at the air jet pipe 26 to 8 top of flue is greater than zero, which is circumferentially with multiple fumaroles, The distance at air jet pipe 26 to the top of flue 8 is greater than zero, so that can when dust stratification in 26 liquid honing flue of air jet pipe It is more comprehensive to clear up, prevent dust stratification.
Microseism device 27 is equipped at the center of the filter screen 24, the ash on filter screen 24 can be shaken off, is convenient for by microseism device 27 Deashing.
The ash discharging hole 21 is funnel-shaped, is convenient to clean the ash to get off and falls into collection along the wall surface of funnelform ash discharging hole 21 In cinder box 22.
The distance between the first partition 9, second partition 10, third partition 11 and the 4th partition 12 are greater than zero, this One partition 9, second partition 10, third partition 11 and the 4th partition 12 length be greater than the width of 1 half of absorption tower so that partition It is staggered, forms bypass channel, extend the movement routine of flue gas.
The spray tube 14 is equipped with multiple spray heads 15, and the spray head 15 and spray tube 14 are rotatablely connected, so that absorbing Liquid multi-faceted can spray.
The filling adsorption layer 16 is active carbon layer, further purification discharge flue gas.
Working principle: opening the first valve 19, closes the second valve 20, the cigarette that temperature is 160-180 DEG C after waste heat recycling Gas enters flue 8 from gas inlet 7, and by the adjustable flue gas flow of flow control valve 18, flue gas initially enters ash disposal Device is filtered by ceramic filter plate 23, and ceramic filter plate 23 has the characteristics that the obstructed ash of ventilation, can be by flue gas Grain substance is separated with gas completely, and the dust filtered out is gathered in the flue between flow control valve 18 and the first valve 19 In section, and most of dirt accumulation is on 23 surface of ceramic filter plate, so that the desulphurization denitration for avoiding particulate matter from influencing flue gas is anti- It answers;
Flue gas after ash disposal enters the first temperature control equipment 3, and flue-gas temperature is adjusted to 140 DEG C, then arranges flue gas Enter and reacted in oxygen regulating device 2, since absorbing liquid is to NO2Absorption be better than the absorption to NO, so as far as possible NO is promoted to be oxidized to NO2, when flue-gas temperature is at 140 DEG C, the NO in flue gas is reacted with oxygen is converted to NO2Condition is best, so 3 temperature adjustment of the first temperature control equipment is first passed through before flue gas is reacted with oxygen to 140 DEG C;
Flue gas after peroxidization enters second temperature control device 4, flue-gas temperature is adjusted to 115 DEG C, the temperature Under degree, the desulfurization and denitrification reaction of flue gas is best, and flue gas is then discharged into absorption from the air inlet 1.1 on absorption tower 1 by air-introduced machine 5 In tower 1, the absorbing liquid in absorbing liquid circulating slot 6 is sprayed into absorption tower 1 by the spray tube 14 in absorption tower 1, on spray tube 14 Spray head 15 multidirectional can adjust, realize the multi-faceted spray of all standing,, can when absorbing liquid spray is on partition in spray To be passed through from funnel-shaped hole 13, as the diminution in aperture forms thread, and cooperate first partition 9, second partition 10, third every Plate 11, the 4th partition 12 are from bottom to top staggered and multiple funnel-shaped holes 13 are densely arranged on partition, can be formed more Grade spray, so that absorbing liquid comes into full contact with flue gas, in addition, first partition 9, second partition 10, third partition 11, the 4th partition 12 are from bottom to top staggered, and when absorbing liquid floods partition, partition can obstruct flue gas and directly move straight up, so that cigarette Gas is moved along baffle surface, and flue gas successively bypasses first partition 9, second partition 10, third partition after the entrance of air inlet 1.1 11, the 4th partition 12 detours upwards, extends the movement routine of flue gas, thus extend the haptoreaction time of flue gas and absorbing liquid, And cooperate the first cylinder 26, the second cylinder 27 driving second partition 10, third partition 11 mobile back and forth horizontally, and leak on partition The osculum end in bucket shape hole 13 is downwardly projected partition lower surface, can play agitaion to absorbing liquid in reciprocating movement, mention The mobile activity of high flue gas, so that absorbing liquid comes into full contact with flue gas, thus to NOX, SO in flue gas2It carries out sufficiently de- It removes, and is absorbed and filter by active carbon layer, so that flue gas reaches discharge standard, is discharged from 1 top gas outlet 1.2 of absorption tower, When absorbing liquid did not had four partitions 12, the discharge amount of the spray flow and 1 bottom liquid outlet 1.3 of absorption tower that control absorption tower 1 is flat Liquid product in absorption tower 1 is sent into absorbing liquid circulating slot 6 by weighing apparatus, the liquid outlet 1.3, the circulation in absorbing liquid circulating slot 6 Liquid introduce waste liquid device 17 handled, recycling, be eventually converted into sulfate and nitrate mixture, the present invention is inhaling It receives in the reacting of liquid and flue gas, sprayed before this, after then liquid to be absorbed did not had air inlet 1.1, flue gas is to be passed through in absorbing liquid again Spray, and flue gas extends movement routine during uplink, so that flue gas comes into full contact with absorbing liquid, when extending absorption Between, thus to the NO in flue gasX、SO2Sufficiently removed.
In addition, closing flow control valve 18 and the first valve 19 when handling the dust stratification in ash handling equipment, the second valve is opened 20, it opens motor 25 and dust cleaning brush 24 is driven to rotate brush dust, the end of dust cleaning brush 24 and ceramic filter plate 23 offset and can remove pottery A large amount of dusts of 23 surface of porcelain filter plate accumulation, avoid dust accretions from influencing filtering, and dust cleaning brush 24 can also be cleared up in flue Dust stratification on wall is swept the dust stratification fallen and is precipitated in funnel-form ash discharging hole 21, and is fallen into dust collecting box 22 by ash discharging hole 21.
The technique that desulphurization denitration is carried out using the above-mentioned equipment for flue gas desulfurization and denitrification, is included the following steps:
A, the flue gas that temperature is 160-180 DEG C after waste heat recycling first passes through ash handling equipment and carries out ash disposal processing, passes through ceramics Filter plate 23 is filtered, ceramic filter plate 23 have the characteristics that ventilation it is obstructed ash, can by the particulate matter in flue gas completely with Gas separation, the dust filtered out is gathered in the flue section between flow control valve 18 and the first valve 19, and big portion Divide dirt accumulation on 23 surface of ceramic filter plate, to avoid the desulfurization and denitrification reaction of particulate matter influence flue gas;
B, ash disposal treated flue gas passes through the first temperature control equipment 3, and adjusting flue-gas temperature is 140 DEG C, and flue gas is led to Enter and reacted in oxygen regulating device 2, promotes NOXIt is converted into NO2
C, the flue gas after reacting with oxygen passes through second temperature control device 4, and adjusting flue-gas temperature is 115 DEG C, and flue gas is logical It crosses air-introduced machine 5 and enters the progress of absorption tower 1 desulfurization and denitrification reaction from the air inlet 1.1 of 1 bottom of absorption tower;
D, the absorbing liquid in absorbing liquid circulating slot 6 is sprayed into absorption tower 1 by the spray tube 14 in absorption tower 1, is being sprayed In, absorbing liquid forms multistage by the funnel-shaped hole 13 on first partition 9, second partition 10, third partition 11, the 4th partition 12 Spray, to the NO in flue gasX、SO2It is sufficiently removed, and is absorbed and filter by active carbon layer, so that flue gas reaches discharge mark Standard is discharged from 1 top gas outlet 1.2 of absorption tower, when absorbing liquid did not had four partitions 12, starts the first cylinder 26, the second gas Cylinder 27 drives second partition 10, third partition 11 to move horizontally, to play agitaion to absorbing liquid, improves the movement of flue gas Activity, and control the spray flow on absorption tower 1 and the discharge amount balance of 1 bottom liquid outlet 1.3 of absorption tower, the liquid outlet 1.3 Liquid product in absorption tower 1 is sent into absorbing liquid circulating slot 6;
E, circulation fluid in absorbing liquid circulating slot 6 introduce waste liquid device 17 handled, recycling, be eventually converted into Sulfate and nitrate mixture.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although Present invention has been described in detail with reference to the aforementioned embodiments, it will be understood by those of skill in the art that it still can be right Technical solution documented by foregoing embodiments is modified, or is replaced on an equal basis to part of technical characteristic;And this It modifies or replaces, the spirit and model of technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution It encloses.

Claims (8)

1. desulphurization denitration equipment, which is characterized in that including ash handling equipment, oxygen regulating device (2), absorption tower (1) and absorbing liquid Circulating slot (6), the ash handling equipment, oxygen regulating device (2) pass sequentially through flue (8) with absorption tower (1) and are connected to, described The front end of ash handling equipment connects gas inlet (7), is equipped with flow control valve (18) between the gas inlet (7) and ash handling equipment, The first temperature control equipment (3) are equipped between the ash handling equipment and oxygen regulating device (2), the oxygen regulating device (2) Second temperature control device (4) are equipped between absorption tower (1), between the second temperature control device (4) and absorption tower (1) Equipped with air-introduced machine (5), the first valve (19) are equipped between first temperature control equipment (3) and ash handling equipment, the absorption Liquid circulating slot (6) is connect with absorption tower (1);
The ash handling equipment includes the motor (25) of dust cleaning brush (24), driving dust cleaning brush (24), dust collecting box (22) and ceramic filter Plate (23) should in the horizontal flue section between flow control valve (18) and the first valve (19) of the dust cleaning brush (24) The outer circumferential direction of dust cleaning brush (24) and the inner wall of flue offset, and the ceramic filter plate (23) setting is in dust cleaning brush (24) and the Between one valve (19), the end and ceramic filter plate (23) of the dust cleaning brush (24) offset for removing ceramic filter plate (23) The bottom of the dust on surface, the flue section between the flow control valve (18) and the first valve (19) is provided with and dust collecting box (22) lower section of the ash discharging hole (21) being connected to, the ash discharging hole (21) is equipped with the second valve (20);
It is provided with baffle assembly in the absorption tower (1), which includes first to be from bottom to top equidistantly staggered Partition (9), second partition (10), third partition (11) and the 4th partition (12), the first partition (9), second partition (10), Third partition (11), the 4th partition (12) etc. are big, the first partition (9), second partition (10), third partition (11), the 4th every It is provided on plate (12) multiple funnel-shaped holes (13), the multiple funnel-shaped hole (13) is densely arranged on partition, described to interlock Setting refers to that first partition (9) and third partition (11) are arranged in the same side of absorption tower (1), second partition (10) and the 4th Partition (12) is arranged in absorption tower (1) and the opposite side of first partition (9), third partition (11), and second partition (10) Front end is protruded between first partition (9) and third partition (11), and second partition (10) and the 4th are protruded into third partition (11) front end Between partition (12), the first partition (9) and the 4th partition (12) are fixedly mounted in absorption tower (1), the second partition (10) be slidably connected with third partition (11) with absorption tower (1) inner wall, absorption tower (1) inner wall be equipped with for second partition (10), The guide rail of third partition (11) sliding, the outside on the absorption tower (1) are equipped with the first gas that driving second partition (10) moves horizontally The second cylinder (27) that cylinder (26) and driving third partition (11) move horizontally;
The top of the absorption tower (1) is equipped with spray tube (14), and the top of the spray tube (14) is equipped with filling adsorption layer (16), should Spray tube (14) is connect by pipeline with absorbing liquid circulating slot (6), and the bottom of the absorption tower (1) is equipped with liquid outlet (1.3), should Liquid outlet (1.3) is connected to by pipeline with the bottom of absorbing liquid circulating slot (6), is provided at the top of absorption tower (1) net to discharge The gas outlet (1.2) of flue gas after change, absorption tower (1) bottom and flue (8) junction are provided with air inlet (1.1), and described the One partition (9) setting is above air inlet (1.1).
2. desulphurization denitration equipment according to claim 1, which is characterized in that the big opening end direction of the funnel-shaped hole (13) At the top of absorption tower (1), osculum end is towards absorption tower (1) bottom, and big opening end is flushed with partition upper surface, and osculum end is downwardly projected Partition lower surface.
3. desulphurization denitration equipment according to claim 1, which is characterized in that the absorbing liquid circulating slot (6) is also connected with useless Liquid device (17).
4. desulphurization denitration equipment according to claim 1, which is characterized in that the ash discharging hole (21) is funnel-shaped.
5. desulphurization denitration equipment according to claim 1, which is characterized in that the first partition (9), second partition (10), the distance between third partition (11) and the 4th partition (12) are greater than zero, the first partition (9), second partition (10), the The length of three partitions (11) and the 4th partition (12) is greater than the width of absorption tower (1) half.
6. desulphurization denitration equipment according to claim 1, which is characterized in that the spray tube (14) is equipped with multiple sprays Head (15), the spray head (15) and spray tube (14) are rotatablely connected.
7. desulphurization denitration equipment according to claim 1, which is characterized in that the filling adsorption layer (16) is active carbon Layer.
8. the technique for carrying out desulphurization denitration using desulphurization denitration equipment described in claim 1, which is characterized in that including walking as follows It is rapid:
A, the flue gas that temperature is 160-180 DEG C after waste heat recycling first passes through ash handling equipment and carries out ash disposal processing;
B, ash disposal treated flue gas passes through the first temperature control equipment (3), and adjusting flue-gas temperature is 130-150 DEG C, by flue gas It is passed through in oxygen regulating device (2) and is reacted, promote NOXIt is converted into NO2
C, the flue gas after reacting with oxygen passes through second temperature control device (4), and adjusting flue-gas temperature is 110-130 DEG C, flue gas Enter absorption tower (1) from the air inlet (1.1) of absorption tower (1) bottom by air-introduced machine (5) and carries out desulfurization and denitrification reaction;
D, the absorbing liquid in absorbing liquid circulating slot (6) is sprayed into absorption tower (1) by the spray tube (14) in absorption tower (1), In spray, absorbing liquid is by the infundibulate on first partition (9), second partition (10), third partition (11), the 4th partition (12) Hole (13) forms multi-stage spray, to the NO in flue gasX、SO2It is sufficiently removed, and adsorbed by filling adsorption layer (16) Filter is discharged, when absorbing liquid did not had the 4th partition so that flue gas reaches discharge standard from absorption tower (1) top gas outlet (1.2) (12) when, starting the first cylinder (26), the second cylinder (27) driving second partition (10), third partition (11) are moved horizontally, from And agitaion is played to absorbing liquid, the mobile activity of flue gas is improved, and control spray flow and the absorption tower on absorption tower (1) (1) liquid product in absorption tower (1) is sent into absorbing liquid by the discharge amount balance of bottom liquid outlet (1.3), the liquid outlet (1.3) In circulating slot (6);
E, circulation fluid in absorbing liquid circulating slot (6) introduce waste liquid device (17) handled, recycling, be eventually converted into Sulfate and nitrate mixture.
CN201710884077.3A 2017-09-26 2017-09-26 Desulphurization denitration equipment and its technique Pending CN109550375A (en)

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Publication number Priority date Publication date Assignee Title
CN110652840A (en) * 2019-10-10 2020-01-07 邢二江 Alkali liquor absorption tower with filler backwashing device
CN111266003A (en) * 2020-02-26 2020-06-12 华电电力科学研究院有限公司 Reciprocating stirring type SCR reactor flue gas flow equalizing device and working method thereof

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CN205182696U (en) * 2015-11-17 2016-04-27 麦森能源科技有限公司 Bubbling reactor
CN105964117A (en) * 2016-06-23 2016-09-28 宁波科新化工工程技术有限公司 Integrated desulfurization and denitrification process method for coke oven smoke

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CN201454322U (en) * 2009-07-16 2010-05-12 梁义 Desulfurizing dust remover
CN203625223U (en) * 2013-12-20 2014-06-04 山东绿泉环保工程有限公司 Comprehensive smoke treatment device applied to container glass kiln
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CN110652840A (en) * 2019-10-10 2020-01-07 邢二江 Alkali liquor absorption tower with filler backwashing device
CN111266003A (en) * 2020-02-26 2020-06-12 华电电力科学研究院有限公司 Reciprocating stirring type SCR reactor flue gas flow equalizing device and working method thereof
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