CN109550350A - A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device - Google Patents

A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device Download PDF

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Publication number
CN109550350A
CN109550350A CN201811463651.9A CN201811463651A CN109550350A CN 109550350 A CN109550350 A CN 109550350A CN 201811463651 A CN201811463651 A CN 201811463651A CN 109550350 A CN109550350 A CN 109550350A
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China
Prior art keywords
gas
oil
liquid nitrogen
liquid
cold
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CN201811463651.9A
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Inventor
柳润泽
李欣
王春岚
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SHENGLI OILFIELD SINO SHENGLI ENGINEERING Co Ltd
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SHENGLI OILFIELD SINO SHENGLI ENGINEERING Co Ltd
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Priority to CN201811463651.9A priority Critical patent/CN109550350A/en
Publication of CN109550350A publication Critical patent/CN109550350A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device, liquid nitrogen storage tank, cold incubator, booster fan, gas-liquid separator and the output pump, the bottom discharge port of the liquid nitrogen storage tank is connect by pipeline with the cooling tube import of cold incubator, and the cooling tube outlet connection nitrogen of cold incubator goes nitrogen seal system;Vaporizing oil-gas pipeline connects the Oil/Gas Pipe import of cold incubator by booster fan, the Oil/Gas Pipe outlet connection gas-liquid separator of cold incubator, the gaseous phase outlet of gas-liquid separator empties, liquid-phase outlet connects head tank by output pump, advantage are as follows: the VOC rate of recovery is up to 99.999%, reduce the discharge quantity of volatile organic compounds and ozone depleting substances, recycling is thorough, it is without secondary pollution (such as without waste water, nitrogenfree oxide, no acidic gas, without dioxin), operation cost is low, without cleaning, intermittently operated strong flexibility, sledge installing meter and batch machining may be implemented, installation, management cost is low.

Description

A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device
Technical field
The present invention relates to vaporizing oil-gas recovery processing techniques during Oil & Gas Storage, in particular to a kind of to utilize liquid nitrogen cryogenics Condensed oil-gas recycles comprehensive management of technology.
Background technique
Domestic petroleum industry petroleum vapor recovery routine techniques mainly has absorption method, absorption process, membrane separation process, condensation method at present Deng.Wherein, absorption method loss is big, operating cost is high, and common active carbon is with adsorbance is smaller, time of equilibrium adsorption is long, no Suitable for handling high concentration organic gas, desorbing more difficult feature, the heat of condensation of adsorption process is also easy to produce security risk;Absorption process Equipment occupation space is big, operation energy consumption is high, and exhaust emissions index is difficult to meet existing discharge standard, and there are secondary pollutions, no It is suitble to intermittently operated;Membrane separation process needs bigger inside oil gas internal circulating load to meet exhaust emissions requirement, and power-equipment is negative Lotus is bigger, and investment is high, and film is also easy to produce discharge layer in the case where gas concentration is low, air capacity is big, and there are security risks, no It is suitble to intermittently operated;Condensation method critical component is refrigeration compressor, the characteristics of condensation method technique be it is concise directly, be not required to secondary working Skill processing, recycling product are without secondary pollution.But it is limited by refrigerant, refrigerant and energy consumption, the condensation temperature of refrigeration compressor has Limit (- 40 DEG C~-70 DEG C of general condensation temperature), cannot will volatilize completely oil gas liquefaction, tail gas cannot reach discharge standard (≤ 25g/m3).
Liquid nitrogen is a kind of multifunction refrigeration agent/refrigerant, have it is nontoxic, non-corrosive and nonflammable, can achieve- 196 DEG C of normal boiling point.
To solve refrigeration compressor condensing refrigerant amount deficiency, the problem that the VOC rate of recovery is low, exhaust emissions is not up to standard, this hair Bright proposition is recycled vaporizing oil-gas using liquid nitrogen cryogenics condensation method, improves the VOC rate of recovery, to reach dirty to environment zero Contaminate purpose.
Summary of the invention
It is an object of the invention to provide a kind of liquid nitrogen cryogenics condensation VOC recovery processing work to solve prior art deficiency Skill.
Main technical schemes of the invention are:
A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device, including liquid nitrogen storage tank, cold incubator, booster fan, gas-liquid separation The bottom discharge port of device and output pump, the liquid nitrogen storage tank is connect by pipeline with the cooling tube import of cold incubator, cold guarantor The cooling tube outlet connection nitrogen of incubator goes nitrogen seal system;Vaporizing oil-gas pipeline connects the oil of cold incubator by booster fan Tracheal entrance, the Oil/Gas Pipe outlet connection gas-liquid separator of cold incubator, the gaseous phase outlet emptying of gas-liquid separator, liquid-phase outlet Head tank is connected by output pump.
The cold incubator includes heat exchanger, condenser, oil-gas pipeline and cooling line, and oil-gas pipeline is sequentially connected one Grade heat exchanger, pipe separator, secondary condenser, pipe separator, three-level condenser, cooling line are sequentially connected three-level condensation Device, pipe separator, secondary condenser, pipe separator, first-class heat exchanger.
A plurality of pipe device device in parallel in the cold incubator.
The step are as follows:
1) vaporizing oil-gas enters cold incubator after booster fan is pressurized and exchanges heat, and condensed lime set passes through pipeline point It is recycled from device and gas-liquid separator, fixed gas emptying;
2) nitrogen evaporated after exchanging heat seals gas source as nitrogen, carries out nitrogen envelope, cooling for oil gas storage tank.
Heat-exchanging process first passes around first-class heat exchanger in the step 1), will volatilize the water vapour condensation abjection in gas, The Volatile Gas of abjection water vapour enters secondary condenser swap-in row heat exchange, if Volatile Gas is not up to standard after secondary condenser heat exchange, It automatically opens condenser three times and carries out heat exchange.
Secondary condenser design temperature is -40 degree in the step 1), and three-level design of condenser temperature is -110 ~-185 degree.
Liquid nitrogen cryogenics condense VOC and are recycled technology, and since liquid nitrogen cooling capacity is very high, the VOC rate of recovery is arranged up to 99.999% It deflates and can reach the zero-emission of organic matter, reduce volatile organic compounds and ozone depleting substances is discharged into the number in environment Amount, recycling is thorough, (such as without waste water, nitrogenfree oxide, no acidic gas, no dioxin) without secondary pollution, recovery product quality Height, and since the quantity of transmission parts is few, mostly static equipment, good reliability, simultaneously because liquid nitrogen price is lower, operation cost Low (being calculated with the treatment scale of 100m3/h gas, liquid nitrogen consumption is only 0.14t/h), without cleaning, intermittently operated flexibility By force, sledge installing meter and batch machining may be implemented, installation, management cost are low.
Detailed description of the invention
Attached drawing 1 is process flow chart of the invention.
In figure: 1 liquid nitrogen storage tank, 2 booster fans, 3 first-class heat exchangers, 4 pipe separators, 5. secondary condenser, 6 three-levels Condenser, 7 gas-liquid separators, the cold incubator of 8 output pump 9.
Specific embodiment
The invention patent is described further with reference to the accompanying drawing.
A kind of liquid nitrogen cryogenics condense VOC recycling and processing device, including liquid nitrogen storage tank 1, cold incubator 9, booster fan 2, The bottom discharge port of gas-liquid separator 7 and output pump 8, liquid nitrogen storage tank 1 is connected by the cooling tube import of pipeline and cold incubator 9 It connects, the cooling tube outlet connection nitrogen of cold incubator 9 goes nitrogen seal system;Vaporizing oil-gas pipeline is connected cold by booster fan 2 The Oil/Gas Pipe import of incubator 9, the Oil/Gas Pipe outlet connection gas-liquid separator 7 of cold incubator 9, the gas phase of gas-liquid separator 7 go out Mouth emptying, liquid-phase outlet connect head tank by output pump 8.
The cold incubator 9 includes heat exchanger, condenser, oil-gas pipeline and cooling line, and oil-gas pipeline is sequentially connected First-class heat exchanger 3, pipe separator 4, secondary condenser 5, pipe separator 4, three-level condenser 6, cooling line is sequentially connected Three-level condenser 6, pipe separator 4, secondary condenser 5, pipe separator 4, first-class heat exchanger 3.
A plurality of pipe device device in parallel in the cold incubator 9.
The step are as follows: 1) vaporizing oil-gas enters cold incubator 9 after the pressurization of booster fan 2 and exchanges heat, cold Lime set after solidifying is recycled by pipe separator 4 and gas-liquid separator 7, fixed gas emptying;2) it is evaporated after exchanging heat Nitrogen seals gas source as nitrogen, carries out nitrogen envelope, cooling for oil gas storage tank.
Heat-exchanging process first passes around first-class heat exchanger 3 in the step 1), will volatilize the water vapour condensation abjection in gas, The Volatile Gas of abjection water vapour enters 5 swap-in row heat exchange of secondary condenser, if Volatile Gas does not reach after secondary condenser 5 exchanges heat Mark automatically opens condenser three times and carries out heat exchange.
5 design temperature of secondary condenser is -40 degree in the step 1), and 6 design temperature of three-level condenser is -110 ~-185 degree.
Since the product quality of recycling is higher, can be used directly as raw material or product.The nitrogen evaporated after condensation can be made Gas source is sealed for the nitrogen of atmospheric storage tank, the protection gas that also can be used as other equipment utilizes (nitrogen gas purity is higher).

Claims (6)

1. a kind of liquid nitrogen cryogenics condense VOC recycling and processing device, including liquid nitrogen storage tank (1), cold incubator (9), booster fan (2), gas-liquid separator (7) and output pump (8), it is characterised in that: the bottom discharge port of the liquid nitrogen storage tank (1) passes through pipeline It is connect with the cooling tube import of cold incubator (9), the cooling tube outlet connection nitrogen of cold incubator (9) goes nitrogen seal system;Volatilization Oil-gas pipeline connects the Oil/Gas Pipe import of cold incubator (9), the Oil/Gas Pipe outlet of cold incubator (9) by booster fan (2) It connects gas-liquid separator (7), the gaseous phase outlet emptying of gas-liquid separator (7), liquid-phase outlet connects raw material by output pump (8) Tank.
2. a kind of liquid nitrogen cryogenics according to claim 1 condense VOC recycling and processing device, it is characterised in that the cold guarantor Incubator (9) includes heat exchanger, condenser, oil-gas pipeline and cooling line, and oil-gas pipeline is sequentially connected first-class heat exchanger (3), pipe Road separator (4), secondary condenser (5), pipe separator (4), three-level condenser (6), it is cold that cooling line is sequentially connected three-level Condenser (6), pipe separator (4), secondary condenser (5), pipe separator (4), first-class heat exchanger (3).
3. a kind of liquid nitrogen cryogenics according to claim 1 or 2 condense VOC recycling and processing device, it is characterised in that described A plurality of pipe device device in parallel in cold incubator (9).
4. a kind of liquid nitrogen cryogenics according to claim 1 condense VOC recovery processing technique, it is characterised in that the step Are as follows:
1) vaporizing oil-gas enters cold incubator (9) after booster fan (2) pressurization and exchanges heat, and condensed lime set passes through Pipe separator (4) and gas-liquid separator (7) are recycled, fixed gas emptying;
2) nitrogen evaporated after exchanging heat seals gas source as nitrogen, carries out nitrogen envelope, cooling for oil gas storage tank.
5. a kind of liquid nitrogen cryogenics according to claim 4 condense VOC recovery processing technique, it is characterised in that the step 1) heat-exchanging process first passes around first-class heat exchanger (3) in, will volatilize the water vapour condensation abjection in gas, deviates from the volatilization of water vapour Gas enters secondary condenser (5) swap-in row heat exchange, if Volatile Gas is not up to standard after secondary condenser (5) heat exchange, automatically opens three Secondary condenser carries out heat exchange.
6. a kind of liquid nitrogen cryogenics according to claim 4 or 5 condense VOC recovery processing technique, it is characterised in that described Secondary condenser (5) design temperature is -40 degree in step 1), and three-level condenser (6) design temperature is -110~-185 degree.
CN201811463651.9A 2018-12-03 2018-12-03 A kind of liquid nitrogen cryogenics condensation VOC recycling and processing device Pending CN109550350A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021047414A1 (en) * 2019-09-09 2021-03-18 轮通空调节能设备(上海)有限公司 Rotary self-defrosting condensation device
CN113244734A (en) * 2021-06-24 2021-08-13 青岛市金旭环境工程有限公司 Oil gas recovery method
CN115646125A (en) * 2022-11-08 2023-01-31 瑞燃(上海)环境工程技术有限公司 System and method for purifying and recycling high-concentration hydrogen chloride tail gas
CN116493746A (en) * 2023-04-26 2023-07-28 徐州重型机械有限公司 Laser welding machine for cleaning protective lenses in real time and cleaning method

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US5450728A (en) * 1993-11-30 1995-09-19 Air Products And Chemicals, Inc. Recovery of volatile organic compounds from gas streams
US20080202160A1 (en) * 2007-01-11 2008-08-28 Stefan Wolf Method and device for fractionated cryocondensation
CN102743892A (en) * 2012-07-18 2012-10-24 南京都乐制冷设备有限公司 Energy-saving anti-freezing oil gas recovery device
CN202792809U (en) * 2012-08-03 2013-03-13 刘恩东 Cooling capacity recovery system
CN103301750A (en) * 2012-03-07 2013-09-18 陶氏环球技术有限公司 Membrane stripping process for removing volatile organic compounds from a latex
CN206008358U (en) * 2016-08-25 2017-03-15 湖北弘仪电子科技股份有限公司 A kind of oil-gas recovery system utilizing condensation process
CN106744633A (en) * 2017-01-23 2017-05-31 山东宏达科技集团有限公司 One kind is anti-to fire gas recovery system for oil
CN207614389U (en) * 2017-10-29 2018-07-17 李庆彪 The three-level condensing unit of volatile organic compounds
CN209771738U (en) * 2018-12-03 2019-12-13 森诺科技有限公司 Liquid nitrogen low-temperature condensation VOC recovery processing device

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Publication number Priority date Publication date Assignee Title
US5450728A (en) * 1993-11-30 1995-09-19 Air Products And Chemicals, Inc. Recovery of volatile organic compounds from gas streams
US20080202160A1 (en) * 2007-01-11 2008-08-28 Stefan Wolf Method and device for fractionated cryocondensation
CN103301750A (en) * 2012-03-07 2013-09-18 陶氏环球技术有限公司 Membrane stripping process for removing volatile organic compounds from a latex
CN102743892A (en) * 2012-07-18 2012-10-24 南京都乐制冷设备有限公司 Energy-saving anti-freezing oil gas recovery device
CN202792809U (en) * 2012-08-03 2013-03-13 刘恩东 Cooling capacity recovery system
CN206008358U (en) * 2016-08-25 2017-03-15 湖北弘仪电子科技股份有限公司 A kind of oil-gas recovery system utilizing condensation process
CN106744633A (en) * 2017-01-23 2017-05-31 山东宏达科技集团有限公司 One kind is anti-to fire gas recovery system for oil
CN207614389U (en) * 2017-10-29 2018-07-17 李庆彪 The three-level condensing unit of volatile organic compounds
CN209771738U (en) * 2018-12-03 2019-12-13 森诺科技有限公司 Liquid nitrogen low-temperature condensation VOC recovery processing device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021047414A1 (en) * 2019-09-09 2021-03-18 轮通空调节能设备(上海)有限公司 Rotary self-defrosting condensation device
CN113244734A (en) * 2021-06-24 2021-08-13 青岛市金旭环境工程有限公司 Oil gas recovery method
CN115646125A (en) * 2022-11-08 2023-01-31 瑞燃(上海)环境工程技术有限公司 System and method for purifying and recycling high-concentration hydrogen chloride tail gas
CN115646125B (en) * 2022-11-08 2023-10-31 瑞燃(上海)环境工程技术有限公司 System and method for purifying and recycling high-concentration hydrogen chloride tail gas
CN116493746A (en) * 2023-04-26 2023-07-28 徐州重型机械有限公司 Laser welding machine for cleaning protective lenses in real time and cleaning method

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Address after: 257000 Shandong Province, Dongying city the Yellow River Road No. 721 senuo Victory Mansion

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