CN109545571A - A kind of preparation method of hollow tubular self-supporting super capacitor electrode material - Google Patents
A kind of preparation method of hollow tubular self-supporting super capacitor electrode material Download PDFInfo
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- CN109545571A CN109545571A CN201811442133.9A CN201811442133A CN109545571A CN 109545571 A CN109545571 A CN 109545571A CN 201811442133 A CN201811442133 A CN 201811442133A CN 109545571 A CN109545571 A CN 109545571A
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- 239000007772 electrode material Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000003990 capacitor Substances 0.000 title claims abstract description 15
- 239000010949 copper Substances 0.000 claims abstract description 86
- 239000006260 foam Substances 0.000 claims abstract description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052802 copper Inorganic materials 0.000 claims abstract description 34
- 239000000126 substance Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 238000003786 synthesis reaction Methods 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 22
- 239000000758 substrate Substances 0.000 abstract description 14
- 239000011149 active material Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 239000006258 conductive agent Substances 0.000 abstract description 3
- AQMRBJNRFUQADD-UHFFFAOYSA-N copper(I) sulfide Chemical compound [S-2].[Cu+].[Cu+] AQMRBJNRFUQADD-UHFFFAOYSA-N 0.000 abstract description 3
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 abstract description 3
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/66—Current collectors
- H01G11/68—Current collectors characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/66—Current collectors
- H01G11/70—Current collectors characterised by their structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
A kind of preparation method of hollow tubular self-supporting super capacitor electrode material of the disclosure of the invention, belongs to electrode material for super capacitor preparation technical field, and in particular to a kind of using foam copper as the preparation of the hollow tubular self-supporting material of substrate.It is applied in supercapacitor by the self-supporting electrode material of substrate of foam copper, since active material to be deposited directly in conductive substrates, produces efficient ion/electron-transport path, reduce the contact resistance between conductive substrates and active material.It eliminates adhesive and conductive agent during manufacturing electrode material simultaneously to use, to optimize the preparation process of electrode material.The present invention provides one kind directly to grow one layer of Kocide SD on foam copper, vulcanizes Cu/Cu (OH) followed by hydro-thermal method2, the cuprous sulfide Cu@Cu of one layer of hollow tubular has finally been grown on foam copper surface2S electrode material for super capacitor, the material show excellent chemical property.
Description
Technical field
The invention belongs to electrode material for super capacitor preparation technical fields, and in particular to a kind of using foam copper as substrate
The preparation of hollow tubular self-supporting material.
Background technique
In supercapacitor field, rarely has people's research by the self-supporting material of substrate of foam copper, foam copper and tradition are steeped
Foam nickel substrate, which compares, has the advantage that (1) has higher electric conductivity and ductility, and (2) preparation cost is lower.With foam
Copper is that the self-supporting electrode material of substrate applies in supercapacitor, since active material is deposited directly to conductive substrates
On, efficient ion/electron-transport path is produced, the contact resistance between conductive substrates and active material is reduced.Simultaneously
It eliminates adhesive and conductive agent during manufacturing electrode material to use, to optimize the preparation process of electrode material.This
Invention then provides one kind and directly grows one layer of Kocide SD on foam copper, vulcanizes Cu/Cu followed by hydro-thermal method
(OH)2, the cuprous sulfide Cu@Cu of one layer of hollow tubular has finally been grown on foam copper surface2S electrode of super capacitor material
Material, the Cu@Cu of hollow tubular2S has bigger specific surface area, provides more for faraday's redox reaction of material
Reactivity site, therefore there is better chemical property.
Summary of the invention
Technical solution of the present invention is mainly simplified positive electrode preparation process and raising electrode material chemical property
And proposing a kind of foam copper is the preparation of the hollow tubular self-supporting super capacitor electrode material with special appearance of substrate
Method.
Technical solution of the present invention is a kind of preparation method of hollow tubular self-supporting super capacitor electrode material, this method
Include:
Step 1: the pretreatment of foam copper；
By foam copper with concentration be 1-2mol/L dilute hydrochloric acid processing 30-60min, then with acetone soln be ultrasonically treated 30-
It is dry to be finally transferred into vacuum oven by 60min；
Step 2: synthesis Cu/Cu (OH)2；
By NaOH and (NH4)2S2O8It is dissolved in deionized water respectively, by the deionized water solution of NaOH and (NH4)2S2O8's
Deionized water solution after mixing evenly, mixes rapidly respectively, makes mixed solution NaOH and (NH4)2S2O8Molal weight ratio
For 2:1；Then the foam copper that pretreatment obtains is soaked in stand in solution and is reacted；Last deionized water repeated flushing is transferred to
Dry 10-12h in 20-40 DEG C of vacuum oven；
Step 3: synthesis Cu@Cu2S；
By the obtained Cu/Cu of step 2 (OH)2It is put into polytetrafluoroethylcontainer container, the thioacetamide of 1mol/L is added
As solvent, 100-120 DEG C of reaction 3-7h in reaction kettle；It is dry to after the reaction was completed, be transferred to vacuum oven；
Step 4: the dry hollow tubular Cu@Cu completed2Electrode material of the S as supercapacitor carries out electrochemistry
It can test.
A process for preparing the electrodes come, due to being that the material of growth in situ out, preparation process are more excellent on foam copper
In traditional cladding process；Foam copper has better electric conductivity and ductility compared to nickel foam simultaneously, and the cost of preparation is also low
In nickel foam；The Cu@Cu of hollow tubular2S has bigger specific surface area, provides for faraday's redox reaction of material
More reactivity sites, therefore there is better chemical property；
It is applied in supercapacitor by the self-supporting electrode material of substrate of foam copper, since active material is directly heavy
Product produces efficient ion/electron-transport path, reduces connecing between conductive substrates and active material in conductive substrates
Electric shock resistance.It eliminates adhesive and conductive agent during manufacturing electrode material simultaneously to use, to optimize electrode material
Preparation process.The present invention provides one kind directly to grow one layer of Kocide SD on foam copper, followed by hydro-thermal method sulphur
Change Cu/Cu (OH)2, the cuprous sulfide Cu@Cu of one layer of hollow tubular has finally been grown on foam copper surface2S supercapacitor
Electrode material, the material show excellent chemical property.
Detailed description of the invention
Fig. 1 is Cu@Cu2S electrode material production flow diagram；
Fig. 2 is Cu@Cu2The XRD diagram of S electrode material, it is known that this Success in Experiment is prepared for self-supporting electrode of super capacitor
Material, diffraction maximum match well with standard card PDF#83-1462；
Fig. 3 is Cu@Cu2The SEM of S material difference enlargement ratio schemes, it is known that self-supporting material shows three-dimensional and is arranged alternately
Hollow tubular structure, tube length is about at 3 μm；
Fig. 4 is Cu@Cu2CV at S material is respectively 100,110,120 DEG C in vulcanization time schemes, and material is in 5mV s-1's
Specific capacity under scanning speed is respectively 2.76,3.68,2.37F cm-2；
Fig. 5 is Cu@Cu2EIS at S material is respectively 100,110,120 DEG C in vulcanization time schemes, equivalent series resistance point
It Wei not 2.22,1.98,4.46 Ω.
Specific embodiment
Prepare the detailed process of electrode material for super capacitor:
Example 1
Step (1) pretreatment of foam copper: will buy resulting foam copper and be cut to area 1cm*1cm size.It is soaked in
It is ultrasonically treated 30-60min respectively in the dilute hydrochloric acid solution and acetone soln that concentration is 1-2mol/L, at above-mentioned two step
Reason, gets rid of the impurity on foam copper surface, then to be transferred into 20 DEG C of vacuum oven dry 6h stand-by.
Step (2), Cu/Cu (OH)2Synthesis: weigh molal weight than the NaOH and (NH for 2:14)2S2O8It is dissolved in respectively
It is stirred in 25ml deionized water.After being stirred evenly respectively to the two, it is mixed rapidly, then step (1) pretreatment is obtained
Foam copper be soaked in above-mentioned solution stand reaction 1h.A large amount of deionized water repeated flushing are used after complete reaction, then are turned
It is stand-by to move to 40 DEG C of vacuum oven dry 6h.
Step (3), Cu@Cu2The synthesis of S: by step (2) obtained Cu/Cu (OH)2It is put into polytetrafluoroethyllining lining,
Take 1mol/L thioacetyl amine aqueous solution as solvent, 100 DEG C of reaction 3-7h of hydro-thermal in reaction kettle.Obtained material after the reaction was completed
Expect 60-80 DEG C of vacuum dry 1-2h again, obtains the self-supporting Cu@Cu of hollow tubular2S material.
Step (4), by the obtained Cu@Cu of step (3)2S is as working electrode, and platinized platinum is used as to electrode, and Hg/HgO makees
Electrochemical property test is carried out on electrochemical operation platform for reference electrode.
Example 1 is 100 DEG C of obtained electrode material for super capacitor Cu@Cu by curing temperature2S is in current density
5mVs-1Current density under by CV figure measure area specific capacity be 2.76F cm-2, equivalent series resistance is 2.22 Ω.
Example 2
Step (1) pretreatment of foam copper: will buy resulting foam copper and be cut to area 1cm*1cm size.It is soaked in
It is ultrasonically treated 30-60min respectively in the dilute hydrochloric acid solution and acetone soln that concentration is 1-2mol/L, at above-mentioned two step
Reason, gets rid of the impurity on foam copper surface, then to be transferred into 20-40 DEG C of vacuum oven dry 6-8h stand-by.
Step (2), Cu/Cu (OH)2Synthesis: weigh molal weight than the NaOH and (NH for 2:14)2S2O8It is dissolved in respectively
It is stirred in 25ml deionized water.After being stirred evenly respectively to the two, it is mixed rapidly, then step (1) pretreatment is obtained
Foam copper be soaked in above-mentioned solution stand reaction 1h.A large amount of deionized water repeated flushing are used after complete reaction, then are turned
It is stand-by to move to 40 DEG C of vacuum oven dry 8h.
Step (3), Cu@Cu2The synthesis of S: by step (2) obtained Cu/Cu (OH)2It is put into polytetrafluoroethyllining lining,
Take 1mol/L thioacetyl amine aqueous solution as solvent, 110 DEG C of reaction 3-7h of hydro-thermal in reaction kettle.Obtained material after the reaction was completed
Expect 60-80 DEG C of vacuum dry 1-2h again, obtains the self-supporting Cu@Cu of hollow tubular2S material；
Step (4), by the obtained Cu@Cu of step (3)2S is as working electrode, and platinized platinum is used as to electrode, and Hg/HgO makees
Electrochemical property test is carried out on electrochemical operation platform for reference electrode.
Example 2 is 110 DEG C of obtained electrode material for super capacitor Cu@Cu by curing temperature2S is in current density
5mVs-1Current density under by CV figure measure area specific capacity be 3.68F cm-2, equivalent series resistance is 1.98 Ω.
Example 3
Step (1) pretreatment of foam copper: will buy resulting foam copper and be cut to area 1cm*1cm size.It is soaked in
It is ultrasonically treated 30-60min respectively in the dilute hydrochloric acid solution and acetone soln that concentration is 1-2mol/L, at above-mentioned two step
Reason, gets rid of the impurity on foam copper surface, then to be transferred into 20-40 DEG C of vacuum oven dry 6-8h stand-by.
Step (2), Cu/Cu (OH)2Synthesis: weigh molal weight than the NaOH and (NH for 2:14)2S2O8It is dissolved in respectively
It is stirred in 25ml deionized water.After being stirred evenly respectively to the two, it is mixed rapidly, then step (1) pretreatment is obtained
Foam copper be soaked in above-mentioned solution stand reaction 1h.A large amount of deionized water repeated flushing are used after complete reaction, then are turned
It is stand-by to move to 20 DEG C of vacuum oven dry 6h.
Step (3), Cu@Cu2The synthesis of S: by step (2) obtained Cu/Cu (OH)2It is put into polytetrafluoroethyllining lining,
Take 1mol/L thioacetyl amine aqueous solution as solvent, 120 DEG C of reaction 3-7h of hydro-thermal in reaction kettle.Obtained material after the reaction was completed
Expect 60-80 DEG C of vacuum dry 1-2h again, obtains the self-supporting Cu@Cu of hollow tubular2S material.
Step (4), by the obtained Cu@Cu of step (3)2S is as working electrode, and platinized platinum is used as to electrode, and Hg/HgO makees
Electrochemical property test is carried out on electrochemical operation platform for reference electrode.
Example 3 is 100 DEG C of obtained electrode material for super capacitor Cu@Cu by curing temperature2S is in current density
5mVs-1Current density under by CV figure measure area specific capacity be 2.37F cm-2, equivalent series resistance is 4.46 Ω.
Claims (1)
1. a kind of preparation method of hollow tubular self-supporting super capacitor electrode material, this method comprises:
Step 1: the pretreatment of foam copper；
By foam copper with concentration be 1-2mol/L dilute hydrochloric acid processing 30-60min, then with acetone soln be ultrasonically treated 30-60min,
It is dry to be finally transferred into vacuum oven；
Step 2: synthesis Cu/Cu (OH)2；
By NaOH and (NH4)2S2O8It is dissolved in deionized water respectively, by the deionized water solution of NaOH and (NH4)2S2O8Go from
Sub- aqueous solution after mixing evenly, mixes rapidly respectively, makes mixed solution NaOH and (NH4)2S2O8Molal weight ratio be 2:
1；Then the foam copper that pretreatment obtains is soaked in stand in solution and is reacted；Last deionized water repeated flushing is transferred to 20-
Dry 10-12h in 40 DEG C of vacuum oven；
Step 3: synthesis Cu@Cu2S；
By the obtained Cu/Cu of step 2 (OH)2It is put into polytetrafluoroethylcontainer container, the thioacetamide of 1mol/L is added as molten
Agent, 100-120 DEG C of reaction 3-7h in reaction kettle；It is dry to after the reaction was completed, be transferred to vacuum oven；
Step 4: the dry hollow tubular Cu@Cu completed2Electrode material of the S as supercapacitor carries out chemical property survey
Examination.
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| CN201811442133.9A CN109545571A (en) | 2018-11-29 | 2018-11-29 | A kind of preparation method of hollow tubular self-supporting super capacitor electrode material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113299491A (en) * | 2021-05-31 | 2021-08-24 | 中南大学 | Photo-thermal enhanced supercapacitor electrode material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105024071A (en) * | 2015-06-24 | 2015-11-04 | 三峡大学 | Cu2S/Cu anode material for lithium ion battery and preparation method |
| CN106629814A (en) * | 2017-01-23 | 2017-05-10 | 吉林大学 | Sulfur-doped three-dimensional porous cuprous oxide nano-material and application thereof to electrochemical hydrogen evolution reaction |
-
2018
- 2018-11-29 CN CN201811442133.9A patent/CN109545571A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105024071A (en) * | 2015-06-24 | 2015-11-04 | 三峡大学 | Cu2S/Cu anode material for lithium ion battery and preparation method |
| CN106629814A (en) * | 2017-01-23 | 2017-05-10 | 吉林大学 | Sulfur-doped three-dimensional porous cuprous oxide nano-material and application thereof to electrochemical hydrogen evolution reaction |
Non-Patent Citations (2)
| Title |
|---|
| WANGDONG LU,ET AL.: ""Fabrication of cuprous sulfide nanorods supported on copper foam for nonenzymatic amperometric determination of glucose and hydrogen peroxide"", 《RSC ADV.》 * |
| 田瀚卿: ""金属硫化物的制备复合及其超级电容器性能的研究"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113299491A (en) * | 2021-05-31 | 2021-08-24 | 中南大学 | Photo-thermal enhanced supercapacitor electrode material and preparation method thereof |
| CN113299491B (en) * | 2021-05-31 | 2022-06-21 | 中南大学 | Photo-thermal enhanced supercapacitor electrode material and preparation method thereof |
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