CN109537295A - A kind of acid protease dye pre-treating method of wool fabric - Google Patents
A kind of acid protease dye pre-treating method of wool fabric Download PDFInfo
- Publication number
- CN109537295A CN109537295A CN201811238604.4A CN201811238604A CN109537295A CN 109537295 A CN109537295 A CN 109537295A CN 201811238604 A CN201811238604 A CN 201811238604A CN 109537295 A CN109537295 A CN 109537295A
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- CN
- China
- Prior art keywords
- wool
- acid protease
- treating method
- wool fabric
- carboxyethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Abstract
The invention discloses a kind of acid proteases of wool fabric to contaminate pre-treating method, including prerinse, deionized water wetting wool and hydrogen peroxide three (2- carboxyethyl) phosphonium salt hydrochlorate with bath three steps of bleaching.The acid protease dye pre-treating method of the wool fabric destroys the scale layer of wool fiber using three (2- carboxyethyl) phosphines as the reducing agent of disulfide bond, and simple with bath processing wool fiber step, thinning effect is good;With using compared with three (2- carboxyethyl) phosphines, the favorable solubility of three (2- carboxyethyl) phosphonium salt hydrochlorates, the reactivity in aqueous solution is strong, and stability is high.
Description
Technical field
The present invention relates to the refinement technology fields of fiber in wool fabric, and in particular to a kind of acidic protein of wool fabric
Enzyme contaminates pre-treating method.
Background technique
Clothes develop to lightening, comfortableization, Leisure orchards, functionalization, superior direction on the market at present.Wool textile is worn
Prodding and itching feeling and sense of discomfort be one of the main reason for influencing its use, and this is because the whole partially thick and fineness of wool fiber
It is discrete it is big caused by, and superfine wool is mainly produced in Australia, and limited amount, expensive.The scheme of replacement is to sheep
Hair carries out micronization processes, and fine wool fabric has the feel and style of similar goat cashmere fabric, can make full use of wool in this way
Resource improves the added value of wool product.
The thinning method of wool mainly distinguishes physical method and chemical method two major classes, and wherein physical method uses the side of slenderised wool
Formula carries out, main that chemical method is selected to be refined for wool fabric.Chemical method include chloridising, dioxygen water treating method,
Potassium permanganate facture, formic acid succusion, alkaline etching and Protease Treatment method.But protein decomposition enzyme be first will be easy
Hydrolyzable moiety decompose, will lead in this way fiber each section decrement it is irregular, intensity excessively declines;On the other hand, enzyme itself is molecule
Biggish protein, poor permeability are measured, and the scale layer of wool contains more disulfide bond, structure is hard, and resistance to enzymolysis ability is strong,
It needs to pre-process wool.But pretreated extent of reaction control difficulty, it is mainly shown as scale damage layer and corrodes
To the cortical layer of fiber, intensity sharply declines.
Summary of the invention
It is an object of the invention to overcome defect existing in the prior art, a kind of acid protease of wool fabric is provided
Pre-treating method is contaminated, three (2- carboxyethyl) phosphonium salt hydrochlorates are soluble easily in water, restore wool surface using three (2- carboxyethyl) phosphines
Disulfide bond, destroy fiber scale layer, with acid protease with bath processing wool fiber, thinning effect is good.
To achieve the above object, the technical solution of the present invention is as follows: a kind of acid protease of wool fabric contaminates pre-treatment side
Method, which comprises the following steps:
S1: wool is placed in prerinse in soap lye or aqueous acetone solution, drying;
S2: wool obtained by S1 is impregnated into 10~20min in deionized water, squeezes and removes excessive moisture;
S3: wool obtained by S2 is placed in the bath enzymatic treatment liquid containing three (2- carboxyethyl) phosphonium salt hydrochlorates and acid protease,
40~50 DEG C are heated to, then 2~4h of insulation reaction takes out wool, abundant cleaning, drying obtains before contaminating through acid protease
The wool fabric of processing.
Preferred technical solution is, with wool fabric poidometer, the dosage of tricarboxylic ethyl phosphine is 1.5 in a bath enzymatic treatment liquid
~4%owf.
Preferred technical solution is, with wool fabric poidometer, the dosage of acid protease is 0.8 in a bath enzymatic treatment liquid
~3% owf.
Preferred technical solution is that the pH value of a bath enzymatic treatment liquid is 5~6.
Preferred technical solution is also to contain alkaline pH adjuster in a bath enzymatic treatment liquid, alkaline pH adjuster is
Combination selected from one or more of sodium phosphate, disodium-hydrogen, sodium acetate and sodium hydroxide.
The advantages and beneficial effects of the present invention are:
The acid protease dye pre-treating method of the wool fabric is broken as the reducing agent of disulfide bond using three (2- carboxyethyl) phosphines
The scale layer of bad wool fiber, simple with bath processing wool fiber step, thinning effect is good;
With using compared with three (2- carboxyethyl) phosphines, the favorable solubility of three (2- carboxyethyl) phosphonium salt hydrochlorates, the reaction in aqueous solution
Active strong, stability is high.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more
Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
1 wool fabric of embodiment acid protease dye pre-treating method the following steps are included:
S1: wool is placed in prerinse in soap lye or aqueous acetone solution, drying;
S2: wool obtained by S1 is impregnated into 10min in deionized water, squeezes and removes excessive moisture;
S3: wool obtained by S2 is placed in the bath enzymatic treatment liquid containing three (2- carboxyethyl) phosphonium salt hydrochlorates and acid protease,
50 DEG C are heated to, then insulation reaction 2h takes out wool, abundant cleaning, drying, obtains contaminating pre-treatment through acid protease
Wool fabric.
With wool fabric poidometer, the dosage of tricarboxylic ethyl phosphine is 4%owf in a bath enzymatic treatment liquid.
With wool fabric poidometer, the dosage of acid protease is 0.8% owf in a bath enzymatic treatment liquid.
The pH value of one bath enzymatic treatment liquid is 6.
Also contain alkaline pH adjuster in one bath enzymatic treatment liquid, alkaline pH adjuster is sodium phosphate.
Embodiment 2
Embodiment 2 the difference from embodiment 1 is that:
S2: wool obtained by S1 is impregnated into 20min in deionized water, squeezes and removes excessive moisture;
S3: wool obtained by S2 is placed in the bath enzymatic treatment liquid containing three (2- carboxyethyl) phosphonium salt hydrochlorates and acid protease,
40 DEG C are heated to, then insulation reaction 4h takes out wool, abundant cleaning, drying, obtains contaminating pre-treatment through acid protease
Wool fabric.
With wool fabric poidometer, the dosage of tricarboxylic ethyl phosphine is 1.5%owf in a bath enzymatic treatment liquid.
With wool fabric poidometer, the dosage of acid protease is 3% owf in a bath enzymatic treatment liquid.
The pH value of one bath enzymatic treatment liquid is 5.
Also contain alkaline pH adjuster in one bath enzymatic treatment liquid, alkaline pH adjuster is disodium-hydrogen.
Embodiment 3
Embodiment 3 the difference from example 2 is that:
S2: wool obtained by S1 is impregnated into 15min in deionized water, squeezes and removes excessive moisture;
S3: wool obtained by S2 is placed in the bath enzymatic treatment liquid containing three (2- carboxyethyl) phosphonium salt hydrochlorates and acid protease,
45 DEG C are heated to, then insulation reaction 3h takes out wool, abundant cleaning, drying, obtains contaminating pre-treatment through acid protease
Wool fabric.
With wool fabric poidometer, the dosage of tricarboxylic ethyl phosphine is 2.5%owf in a bath enzymatic treatment liquid.
With wool fabric poidometer, the dosage of acid protease is 2% owf in a bath enzymatic treatment liquid.
The pH value of one bath enzymatic treatment liquid is 5.5.
Also contain alkaline pH adjuster in one bath enzymatic treatment liquid, alkaline pH adjuster is the solution of sodium hydroxide 10%.
Comparative example
Comparative example is based on embodiment 1, and difference is, three (2- carboxyethyl) phosphonium salt hydrochlorates are not contained in treatment fluid.
Detection is sampled to the fiber in wool fabric, 20 groups is sampled, is averaged, wool obtained by embodiment 1-3 is knitted
Wool fineness in object is between 20~21 microns, and the wool fineness in wool fabric obtained by comparative example is being 21.35 microns,
Respectively less than untreated 22.40 microns of wool of fineness, but in contrast, the average fineness of wool obtained by embodiment 1-3
It is smaller.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (5)
1. a kind of acid protease of wool fabric contaminates pre-treating method, which comprises the following steps:
S1: wool is placed in prerinse in soap lye or aqueous acetone solution, drying;
S2: wool obtained by S1 is impregnated into 10~20min in deionized water, squeezes and removes excessive moisture;
S3: wool obtained by S2 is placed in the bath enzymatic treatment liquid containing three (2- carboxyethyl) phosphonium salt hydrochlorates and acid protease,
40~50 DEG C are heated to, then 2~4h of insulation reaction takes out wool, abundant cleaning, drying obtains before contaminating through acid protease
The wool fabric of processing.
2. the acid protease of wool fabric according to claim 1 contaminates pre-treating method, which is characterized in that knitted with wool
Object poidometer, a dosage for bathing tricarboxylic ethyl phosphine in enzymatic treatment liquid is 1.5~4%owf.
3. the acid protease of wool fabric according to claim 1 contaminates pre-treating method, which is characterized in that knitted with wool
Object poidometer, a dosage for bathing acid protease in enzymatic treatment liquid is 0.8~3% owf.
4. the acid protease of wool fabric according to claim 1 contaminates pre-treating method, which is characterized in that at a bath enzyme
The pH value for managing liquid is 5~6.
5. the acid protease of wool fabric according to claim 4 contaminates pre-treating method, which is characterized in that at a bath enzyme
Also contain alkaline pH adjuster in reason liquid, alkaline pH adjuster is selected from sodium phosphate, disodium-hydrogen, sodium acetate and hydrogen-oxygen
Change the combination of one or more of sodium.
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CN201811238604.4A CN109537295A (en) | 2018-10-23 | 2018-10-23 | A kind of acid protease dye pre-treating method of wool fabric |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110791857A (en) * | 2019-10-15 | 2020-02-14 | 江阴市长泾花园毛纺织有限公司 | Production process of jacquard color point woolen cloth |
Citations (4)
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CN102965959A (en) * | 2012-11-19 | 2013-03-13 | 天津工业大学 | Wool refining treating fluid and treating method |
CN104153195A (en) * | 2014-08-06 | 2014-11-19 | 东华大学 | Finishing method for enabling wool fabric to have anti-felting function |
CN104404763A (en) * | 2014-12-04 | 2015-03-11 | 东华大学 | Method for preparing antistatic anti-felting wool fabric with good dyeing property |
CN104746347A (en) * | 2013-12-27 | 2015-07-01 | 淄博佳谊日用化工有限公司 | Blanching, scouring and bleaching one-bath refining treatment fluid for wool fabric and treating method |
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2018
- 2018-10-23 CN CN201811238604.4A patent/CN109537295A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102965959A (en) * | 2012-11-19 | 2013-03-13 | 天津工业大学 | Wool refining treating fluid and treating method |
CN104746347A (en) * | 2013-12-27 | 2015-07-01 | 淄博佳谊日用化工有限公司 | Blanching, scouring and bleaching one-bath refining treatment fluid for wool fabric and treating method |
CN104153195A (en) * | 2014-08-06 | 2014-11-19 | 东华大学 | Finishing method for enabling wool fabric to have anti-felting function |
CN104404763A (en) * | 2014-12-04 | 2015-03-11 | 东华大学 | Method for preparing antistatic anti-felting wool fabric with good dyeing property |
Non-Patent Citations (3)
Title |
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刘建勇等: "基于三羧乙基膦/亚硫酸氢钠体系的羊毛角蛋白溶解历程 ", 《高分子材料科学与工程》 * |
王江波等: "TCEP在羊毛角蛋白上的应用 ", 《毛纺科技》 * |
王洁等: "一浴法酸性蛋白酶羊毛细化改性研究", 《毛纺科技》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110791857A (en) * | 2019-10-15 | 2020-02-14 | 江阴市长泾花园毛纺织有限公司 | Production process of jacquard color point woolen cloth |
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Application publication date: 20190329 |