CN109536993A - A kind of method of electrodeposit metals zinc in eutectic solvent - Google Patents
A kind of method of electrodeposit metals zinc in eutectic solvent Download PDFInfo
- Publication number
- CN109536993A CN109536993A CN201910065065.7A CN201910065065A CN109536993A CN 109536993 A CN109536993 A CN 109536993A CN 201910065065 A CN201910065065 A CN 201910065065A CN 109536993 A CN109536993 A CN 109536993A
- Authority
- CN
- China
- Prior art keywords
- eutectic solvent
- carbamide
- zinc
- deposition
- electro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The invention belongs to a kind of methods of electrodeposit metals zinc in metallurgical technology field more particularly to eutectic solvent.Include the following steps: S1, under an inert atmosphere, carbamide and glyoxaline ion liquid are mixed, form carbamide-imidazoles eutectic solvent, the molar ratio of the carbamide and glyoxaline ion liquid is 1.9~2.1:1；S2, Zinc oxide powder is added in the carbamide-imidazoles eutectic solvent, stirs to get mixing liquid；S3, it inserts electrodes into the mixing liquid, carries out electrodeposition process, wherein the time of electro-deposition is 2~6h；Electrode is taken out after S4, electro-deposition, the electrolyte of cleaning electrode surface adhesion obtains metallic zinc in electrode surface after drying.Using zinc oxide as electrolysis raw material in this method, electrodeposition process anode generates oxygen, and carbamide-imidazoles eutectic solvent electrochemical window is wider, and insensitive to water and air, electrolyte can be recycled.
Description
Technical field
The invention belongs to a kind of methods of electrodeposit metals zinc in metallurgical technology field more particularly to eutectic solvent.
Background technique
Zinc is the fourth-largest non-ferrous metal that yield is only second to aluminium, copper and lead.One is plated on the surface of steel and steel construction piece
Layer zinc, surface can generate layer protecting film at normal temperature, have excellent corrosion resistance, therefore it is zinc-plated be widely used in automobile,
The industries such as building, ship, light industry.
Zinc hydrometallurgy process, including leaching, Purification of zinc sulfate solution, zinc electrolysis three big steps of deposition are mainly used at present,
Wherein electrodepositing zinc is also easy to produce hydrogen embrittlement in acid system, and current efficiency is relatively low.
There are many document report about electrodeposit metals zinc in ion liquid system, because ionic liquid has certain uniquenesses
Physicochemical properties, such as it is non-corrosive, hydrogen-free be precipitated, thermal stability is good, electrochemical window mouth width, fusing point are low and good conductivity
Deng.Early in 1997, Printer and Hussey just reported the lewis acidity AlCl at 40 DEG C3- 1- methyl -3- ethyl miaow
(AlCl in oxazolinium ion liquid3- MeEtimCl, molar ratio 60:40) electrodepositing zinc on Copper substrate, however AlCl3Base ionic liquid
It is easy to absorb water in air, contains metallic aluminium in the product that electro-deposition obtains.1999, Lin and Sun discovery were in Louis
Acid ZnCl2- 1- ethyl -3- methylimidazolium chloride (ZnCl2- EMIC, molar ratio 50:50) electro-deposition can be in ionic liquid
Pure metallic zinc is obtained, the ionic liquid is also sensitive to water and air.In decades later, ZnCl2- EMIC ionic liquid
It is used for the zinc-containing alloys such as electro-deposition Cu-Zn alloy, Cd-Zn alloy, Zn-Co alloy and Zn-Te alloy.
In addition, some researches show that ZnCl2- N- butyl-N- crassitude cdicynanmide, ZnCl2- 1- butyl -1- methylpyrrole
Alkane difluoromethane sulfimide, ZnCl2Tetramethyl ammonium chloride-propene carbonate, ZnCl2Urea and ZnCl2Choline chloride
(ChCl)-ethylene glycol plasma liquid can also be used for electrodepositing zinc and its alloy.But electrodeposit metals in above-mentioned ionic liquid
The raw material that zinc uses is zinc chloride, also extremely harmful to human health with hygroscopicity.
Summary of the invention
(1) technical problems to be solved
For existing technical problem, the present invention provides a kind of method of electrodeposit metals zinc in eutectic solvent,
Using zinc oxide as raw material in this method, zinc oxide itself is nontoxic, stablizes in surrounding air, and the cost ratio of zinc oxide
The cost of zinc chloride is more economical.
(2) technical solution
The present invention provides a kind of method of electrodeposit metals zinc in eutectic solvent, includes the following steps:
S1, under an inert atmosphere mixes carbamide and glyoxaline ion liquid, and it is molten to form carbamide-imidazoles eutectic
The molar ratio of agent, the carbamide and glyoxaline ion liquid is 1.9~2.1:1；
S2, Zinc oxide powder is added in the carbamide-imidazoles eutectic solvent, stirs to get mixing liquid；
S3, it inserts electrodes into the mixing liquid, carries out electrodeposition process, wherein the time of electro-deposition is 2~6h；
Electrode is taken out after S4, electro-deposition, the electrolyte of cleaning electrode surface adhesion obtains metal in electrode surface after drying
Zinc.
Further, in the step S2, molar concentration of the Zinc oxide powder in mixing liquid be 0.25~
0.49mol/L。
Further, the temperature of electro-deposition is 80~150 DEG C in the step S3.
Further, the constant potential of electro-deposition is -1.1~-1.4V vs.Ag, constant current density in the step S3
For 15~30mA/cm2。
Further, in the step S2, Zinc oxide powder is added in carbamide-imidazoles eutectic solvent, stirring 12
~for 24 hours.
Further, in the step S1, the molar ratio of carbamide and glyoxaline ion liquid is 2:1.
Further, in the step S1, the cation of glyoxaline ion liquid is 1- alkyl -3- methylimidazole, wherein
Alkyl is one of ethyl, butyl, hexyl and octyl；Anion is one of fluorine, chlorine, bromine and tetrafluoro boric acid.
Further, in the step S3, electrode includes working electrode, reference electrode and auxiliary electrode；
The working electrode is one of copper, tungsten, nickel, titanium, molybdenum and stainless steel；
The reference electrode is Ag/AgCl；
The auxiliary electrode is one of tungsten, nickel, titanium, molybdenum or stainless steel.
Further, the step S2~S4 is carried out under inert atmosphere or air atmosphere.
(3) beneficial effect
The beneficial effects of the present invention are:
1, the raw material that uses is zinc oxide in the present invention, and electrode is inert metal, thus the anodic product of electrodeposition process
For oxygen, cathode product is metallic zinc, and smelting process does not have the generation of exhaust gas, waste water and waste residue, the clean nothing of whole process green
Pollution.
2, using urea-disubstituted imidazole eutectic solvent as electrolyte in the present invention, wherein the price of urea is relatively inexpensive,
The eutectic solvent for reducing production cost, and being formed is not easy to react water and air, thus can under air atmosphere into
The electro-deposition of row metal zinc.
3, disubstituted imidazole class ionic liquid electrochemical window used in the present invention is wider (about 3V), can be to avoid acidity
The generation of electrodepositing zinc occurs in solution liberation of hydrogen side reaction and Hydrogen Brittleness Phenomena, thus the current efficiency of electrodeposition process is higher,
Support electrolyte can recycle.
Detailed description of the invention
Fig. 1 is the XRD spectrum for the metallic zinc that electro-deposition obtains in the embodiment of the present invention 1；
Fig. 2 is the SEM spectrum for the metallic zinc that electro-deposition obtains in the embodiment of the present invention 1；
Fig. 3 is the EDS map for the metallic zinc that electro-deposition obtains in the embodiment of the present invention 1.
Specific embodiment
In order to preferably explain the present invention, in order to understand, with reference to the accompanying drawing, by specific embodiment, to this hair
It is bright to be described in detail.
Embodiment 1
S1, at room temperature, by carbamide and 1- butyl -3- methylimidazolium chloride ionic liquid, 2:1 is mixed in molar ratio, control
100 DEG C of temperature processed, colourless as clear as crystal carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent is formed after agitated.
S2, zinc oxide solid powder is added to carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent, stirring
12h is dissolved completely in zinc oxide solid powder in carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent.At this point,
Molar concentration of the zinc oxide in carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent is 0.49mol/L.
S3, will be using copper as working electrode, Ag/AgCl is reference electrode, and titanium is that the electrode of auxiliary electrode is inserted and contains zinc oxide
Carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent in, control the carbamide -1- butyl -3- first containing zinc oxide
The temperature of base imidazolitm chloride eutectic solvent is 100 DEG C, and electro-deposition 2h is carried out under the conditions of constant potential -1.1V (vs.Ag).
Electrode is taken out after S4, electro-deposition, with a small amount of electrolyte of acetone and distilled water cleaning electrode surface adhesion, after dry
Metallic zinc is obtained on copper surface.
The preparation of carbamide -1- butyl -3- methylimidazolium chloride eutectic solvent is being full of argon gas in the step S1
It is carried out in glove box, wherein the content of oxygen and water is lower than 0.1ppm, and the step S2~S4 is carried out under atmospheric environment.
As shown in Figure 1, 2, 3, respectively XRD, SEM and EDS map of metallic zinc obtained in the present embodiment.
Embodiment 2
S1, at room temperature, by carbamide and 1- ethyl-3-methylimidazole tetrafluoroborate, 1.9:1 is mixed in molar ratio, control
80 DEG C of temperature processed, colourless as clear as crystal carbamide -1- ethyl-3-methylimidazole tetrafluoroborate eutectic is formed after agitated
Solvent.
S2, carbamide -1- ethyl-3-methylimidazole tetrafluoroborate eutectic solvent is added in zinc oxide solid powder,
Stirring for 24 hours, makes zinc oxide solid powder be dissolved completely in carbamide -1- ethyl-3-methylimidazole tetrafluoroborate eutectic molten
In agent.At this point, molar concentration of the zinc oxide in carbamide -1- butyl -3- methyl imidazolium tetrafluoroborate eutectic solvent is
0.25mol/L。
S3, will be using stainless steel as working electrode, Ag/AgCl is reference electrode, and tungsten is that the electrode of auxiliary electrode is inserted containing aerobic
In the carbamide -1- butyl -3- methyl imidazolium tetrafluoroborate eutectic solvent for changing zinc, the carbamide-containing zinc oxide is controlled
The temperature of 1- butyl -3- methyl imidazolium tetrafluoroborate eutectic solvent is 80 DEG C, in constant potential -1.4V (vs.Ag) condition
Lower progress electro-deposition 6h.
Electrode is taken out after S4, electro-deposition, with a small amount of electrolyte of acetone and distilled water cleaning electrode surface adhesion, after dry
Metallic zinc is obtained in stainless steel surface.
Step S1~the S4 is carried out in the glove box full of argon gas, and wherein the content of oxygen and water is lower than
0.1ppm。
Embodiment 3
S1, at room temperature, by carbamide and 1- propyl -3- methylimidazole bromide, 2:1 is mixed in molar ratio, controls temperature
120 DEG C, colourless as clear as crystal carbamide -1- propyl -3- methylimidazole bromide eutectic solvent is formed after agitated.
S2, zinc oxide solid powder is added to carbamide -1- propyl -3- methylimidazole bromide eutectic solvent, stirring
16h is dissolved completely in zinc oxide solid powder in carbamide -1- propyl -3- methylimidazole bromide eutectic solvent.At this point,
Molar concentration of the zinc oxide in carbamide -1- propyl -3- methylimidazole bromide eutectic solvent is 0.45mol/L.
S3, will be using nickel as working electrode, Ag/AgCl is reference electrode, and stainless steel is that the electrode of auxiliary electrode is inserted containing aerobic
In the carbamide -1- propyl -3- methylimidazole bromide eutectic solvent for changing zinc, the carbamide -1- propyl-containing zinc oxide is controlled
The temperature of 3- methylimidazole bromide eutectic solvent is 120 DEG C, carries out electro-deposition under the conditions of constant potential -1.2V (vs.Ag)
6h。
Electrode is taken out after S4, electro-deposition, with a small amount of electrolyte of acetone and distilled water cleaning electrode surface adhesion, after dry
Metallic zinc is obtained in nickel surface.
The preparation of carbamide -1- propyl -3- methylimidazole bromide eutectic solvent is being full of argon gas in the step S1
It is carried out in glove box, wherein the content of oxygen and water is lower than 0.1ppm, and the step S2~S4 is carried out under atmospheric environment.
Embodiment 4
S1, at room temperature, by carbamide and 1- hexyl -3- methylimidazole bromide, 2.1:1 is mixed in molar ratio, controls temperature
130 DEG C, colourless as clear as crystal carbamide -1- hexyl -3- methylimidazole bromide eutectic solvent is formed after agitated.
S2, zinc oxide solid powder is added to carbamide -1- hexyl -3- methylimidazole bromide eutectic solvent, stirring
20h is dissolved completely in zinc oxide solid powder in carbamide -1- hexyl -3- methylimidazole bromide eutectic solvent.At this point,
Molar concentration of the zinc oxide in carbamide -1- hexyl -3- methylimidazole bromide eutectic solvent is 0.33mol/L.
S3, will be using tungsten as working electrode, Ag/AgCl is reference electrode, and nickel is that the electrode of auxiliary electrode is inserted and contains zinc oxide
Carbamide -1- hexyl -3- methylimidazole bromide eutectic solvent in, control the carbamide -1- hexyl -3- first containing zinc oxide
The temperature of base imidazoles bromide eutectic solvent is 100 DEG C, in constant current density 15mA/cm2Under the conditions of carry out electro-deposition 4h.
Electrode is taken out after S4, electro-deposition, with a small amount of electrolyte of acetone and distilled water cleaning electrode surface adhesion, after dry
Metallic zinc is obtained on tungsten surface.
Step S1~the S4 is carried out in the glove box full of argon gas, and wherein the content of oxygen and water is lower than
0.1ppm。
Embodiment 5
S1, at room temperature, by carbamide and 1- octyl -3- methylimidazole villiaumite, 2:1 is mixed in molar ratio, controls temperature
150 DEG C, colourless as clear as crystal carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent is formed after agitated.
S2, zinc oxide solid powder is added to carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent, stirring
22h is dissolved completely in zinc oxide solid powder in carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent.At this point,
Molar concentration of the zinc oxide in carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent is 0.41mol/L.
S3, will be using titanium as working electrode, Ag/AgCl is reference electrode, and molybdenum is that the electrode of auxiliary electrode is inserted and contains zinc oxide
Carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent in, control the carbamide -1- octyl -3- first containing zinc oxide
The temperature of base imidazoles villiaumite eutectic solvent is 150 DEG C, in constant current density 30mA/cm2Under the conditions of carry out electro-deposition 3h.
Electrode is taken out after S4, electro-deposition, with a small amount of electrolyte of acetone and distilled water cleaning electrode surface adhesion, after dry
Metallic zinc is obtained on titanium surface.
The preparation of carbamide -1- octyl -3- methylimidazole villiaumite eutectic solvent is being full of argon gas in the step S1
It is carried out in glove box, wherein the content of oxygen and water is lower than 0.1ppm, and the step S2~S4 is carried out under atmospheric environment.
In above-described embodiment 1~5, carbamide-imidazoles eutectic solvent after electro-deposition be can be recycled.Electricity is heavy
Anodic product during product is oxygen, and cathode product is metallic zinc, and smelting process does not have the generation of exhaust gas, waste water and waste residue,
Whole process green is clean pollution-free.
The technical principle of the invention is described above in combination with a specific embodiment, these descriptions are intended merely to explain of the invention
Principle shall not be construed in any way as a limitation of the scope of protection of the invention.Based on explaining herein, those skilled in the art
It can associate with other specific embodiments of the invention without creative labor, these modes fall within this hair
Within bright protection scope.
Claims (7)
1. a kind of method of electrodeposit metals zinc in eutectic solvent, which comprises the steps of:
S1, under an inert atmosphere mixes carbamide and glyoxaline ion liquid, forms carbamide-imidazoles eutectic solvent, institute
The molar ratio for stating carbamide and glyoxaline ion liquid is 1.9~2.1:1；
S2, Zinc oxide powder is added in the carbamide-imidazoles eutectic solvent, stirs to get mixing liquid；
S3, it inserts electrodes into the mixing liquid, carries out electrodeposition process, wherein the time of electro-deposition is 2~6h；
Electrode is taken out after S4, electro-deposition, the electrolyte of cleaning electrode surface adhesion obtains metallic zinc in electrode surface after drying.
2. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S2
In, molar concentration of the Zinc oxide powder in mixing liquid is 0.25~0.49mol/L.
3. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S3
The temperature of middle electro-deposition is 80~150 DEG C.
4. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S3
The constant potential of middle electro-deposition is -1.1~-1.4V vs.Ag, and constant current density is 15~30mA/cm2。
5. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S2
In, Zinc oxide powder is added in carbamide-imidazoles eutectic solvent, stirring 12~for 24 hours.
6. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S1
In, the molar ratio of carbamide and glyoxaline ion liquid is 2:1.
7. the method for electrodeposit metals zinc in eutectic solvent according to claim 1, which is characterized in that the step S1
In, the cation of glyoxaline ion liquid is 1- alkyl -3- methylimidazole, wherein alkyl is ethyl, butyl, hexyl and octyl
One of；Anion is one of fluorine, chlorine, bromine and tetrafluoro boric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065065.7A CN109536993A (en) | 2019-01-23 | 2019-01-23 | A kind of method of electrodeposit metals zinc in eutectic solvent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065065.7A CN109536993A (en) | 2019-01-23 | 2019-01-23 | A kind of method of electrodeposit metals zinc in eutectic solvent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109536993A true CN109536993A (en) | 2019-03-29 |
Family
ID=65838445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910065065.7A Pending CN109536993A (en) | 2019-01-23 | 2019-01-23 | A kind of method of electrodeposit metals zinc in eutectic solvent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109536993A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111826691A (en) * | 2020-08-21 | 2020-10-27 | 东北大学 | Method for preparing zinc-tantalum alloy by using solvated ionic liquid |
| CN113088856A (en) * | 2021-03-31 | 2021-07-09 | 江西科技师范大学 | Deep eutectic solvent hot galvanizing additive and preparation method and application thereof |
| CN113881977A (en) * | 2021-11-12 | 2022-01-04 | 东北大学 | Method for preparing zinc-titanium alloy at low temperature by taking titanium oxycarbide as anode |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108315763A (en) * | 2018-05-09 | 2018-07-24 | 东北大学 | A method of preparing metallic zinc using ionic liquid electrolytic oxidation zinc |
| CN108441886A (en) * | 2018-05-09 | 2018-08-24 | 东北大学 | A method of preparing metal using ionic liquid electrolytic metal oxide |
| CN108611664A (en) * | 2018-05-09 | 2018-10-02 | 东北大学 | A method of preparing metallic lead using ionic liquid electrolytic oxidation lead |
-
2019
- 2019-01-23 CN CN201910065065.7A patent/CN109536993A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108315763A (en) * | 2018-05-09 | 2018-07-24 | 东北大学 | A method of preparing metallic zinc using ionic liquid electrolytic oxidation zinc |
| CN108441886A (en) * | 2018-05-09 | 2018-08-24 | 东北大学 | A method of preparing metal using ionic liquid electrolytic metal oxide |
| CN108611664A (en) * | 2018-05-09 | 2018-10-02 | 东北大学 | A method of preparing metallic lead using ionic liquid electrolytic oxidation lead |
Non-Patent Citations (1)
| Title |
|---|
| AIMIN LIU等: "Electrodeposition of Zinc from Zinc Oxide in 2:1 Urea/1-Butyl-3-methylimidazolium Chloride Ionic Liquid", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111826691A (en) * | 2020-08-21 | 2020-10-27 | 东北大学 | Method for preparing zinc-tantalum alloy by using solvated ionic liquid |
| CN111826691B (en) * | 2020-08-21 | 2021-09-21 | 东北大学 | Method for preparing zinc-tantalum alloy by using solvated ionic liquid |
| CN113088856A (en) * | 2021-03-31 | 2021-07-09 | 江西科技师范大学 | Deep eutectic solvent hot galvanizing additive and preparation method and application thereof |
| CN113088856B (en) * | 2021-03-31 | 2022-12-23 | 江西科技师范大学 | Deep eutectic solvent hot galvanizing additive and preparation method and application thereof |
| CN113881977A (en) * | 2021-11-12 | 2022-01-04 | 东北大学 | Method for preparing zinc-titanium alloy at low temperature by taking titanium oxycarbide as anode |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109536993A (en) | A kind of method of electrodeposit metals zinc in eutectic solvent | |
| CN107190283B (en) | A kind of method that nearly room temperature is co-deposited magnesium neodymium master alloy | |
| ZA200603562B (en) | Process for electrolytic production of aluminum | |
| CN107190282B (en) | A kind of room temperature molten salt and its preparation method and application | |
| CN106967998B (en) | The method for preparing Al-Li master alloys as the nearly room temperature electro-deposition of raw material using lithia | |
| Yasinskiy et al. | Electrochemical reduction and dissolution of liquid aluminium in thin layers of molten halides | |
| Wei et al. | Cathodic process of aluminum deposition in NaF-AlF 3-Al 2 O 3 melts with low cryolite ratio | |
| Zhang et al. | Ionic liquid metallurgy: novel electrolytes for metals extraction and refining technology | |
| CN102108529B (en) | Method for preparing aluminum-gadolinium-samarium alloy by fused salt electrolysis | |
| CN101343750B (en) | Application of sulphuric acid hydrogen imidazole ion liquid in electrolytical refined copper | |
| Tian | Ionic liquids as green electrolytes for Aluminum and Aluminum-alloy production | |
| Li et al. | Electrochemical reduction of Tm on Mg electrodes and co-reduction of Mg, Li and Tm on W electrodes | |
| Liu et al. | Physicochemical properties of 1, 3-dimethyl-2-imidazolinone− ZnCl2 solvated ionic liquid and its application in zinc electrodeposition | |
| CN113846353A (en) | Method for preparing aluminum magnesium alloy by using polar aprotic organic solvent | |
| Yasinskiy et al. | Electrochemical characterization of the liquid aluminium bipolar electrode for extraction of noble metals from spent catalysts | |
| US11111591B2 (en) | Methods and compositions for electrochemical deposition of metal rich layers in aqueous solutions | |
| CN105671598A (en) | Method for directly preparing aluminum foil through low temperature electrolysis | |
| CN108779566A (en) | The electrochemical deposition of element in water-bearing media | |
| Rudenko et al. | Borated graphite cathodes for low-temperature aluminum electrolysis | |
| CN107630234B (en) | A method of scandium bearing master alloy is prepared using villaumite oxide system molten-salt electrolysis | |
| Kiatisereekul et al. | Reaction of aluminium alloy in NaOH with 8-hydroxyquinoline for application as anode electrodes | |
| HAARBERG | Electrowinning of Aluminum—Challenges and Possibilities for Reducing the Carbon Footprint— | |
| Xu et al. | Electrochemical preparation of titanium and its alloy in ionic liquid | |
| CN113881977A (en) | Method for preparing zinc-titanium alloy at low temperature by taking titanium oxycarbide as anode | |
| Wang et al. | Electrochemical Behavior of Cermet Anodes in Na 3 AlF 6-K 3 AlF 6-Based Low-Melting Electrolytes for Aluminium Electrolysis |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190329 |