CN109536942A - A kind of power connection fitting laser melting coating surface reinforcing method - Google Patents

A kind of power connection fitting laser melting coating surface reinforcing method Download PDF

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Publication number
CN109536942A
CN109536942A CN201811285652.9A CN201811285652A CN109536942A CN 109536942 A CN109536942 A CN 109536942A CN 201811285652 A CN201811285652 A CN 201811285652A CN 109536942 A CN109536942 A CN 109536942A
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CN
China
Prior art keywords
power connection
connection fitting
laser melting
melting coating
corrosion
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CN201811285652.9A
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CN109536942B (en
Inventor
顾建
李冬青
周立宪
刘胜春
张军
司佳钧
刘臻
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State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
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State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • C23C24/103Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Laser Beam Processing (AREA)

Abstract

It include that (1) pre-processes the fitting the present invention relates to a kind of method of power connection fitting surface peening;(2) surface consolidation material is prepared;(3) laser melting coating;(4) cladding layer, the metal alloy powders that the composition is 30~50 μm of granularity are handled comprising: basic phase, hard phase and anti-corrosion phase;The basic phase includes Si 2.5~3.0%, C 2.0~2.5%;The hard phase includes W 4.0~6%, Cr 5.8%~7.5%, B 0.3~0.8%;The anti-corrosion mutually includes Al 5.0~6.5%.After laser melting coating preparation process, on electric armour clamp rigid collective surface metallurgical bonding occurs for metal alloy powders, and the mechanical performance of power connection fitting contact surface is greatly improved, to prevent the security risks such as fracture, there is the meaning greatly promoted.

Description

A kind of power connection fitting laser melting coating surface reinforcing method
Technical field
The present invention relates to a kind of power connection fitting surface reinforcing methods, belong to field of surface engineering technique, specifically relate to And a kind of power connection fitting laser melting coating surface reinforcing method.
Background technique
Connection gold utensil is the important connection carrying fitting of transmission line of electricity, it is securely and reliably directly related to transmission line of electricity Long-term safety operation.Abrasion is the important link for influencing electric armour clamp and being on active service safely.Wherein fretting wear and corrosion wear characteristic It is two important indicators for determining electric armour clamp service life.Power connection fitting is mainly contacted by surface and realizes two fittings Between mechanical connection.But during its practical military service, since the contact of bring connection gold utensil is waved in aeolian vibration or strong wind The friction and wear behavior on surface easily weakens the mechanical performance of contact surface, to bring the security risks such as fracture.And it is extra-high The characteristics of pressure transmission line is that conveying distance is long, need to undergo different atmospheric environments, and electric armour clamp surface corrosion is be easy to cause to wear, Accelerate the rate of power connection fitting disabler.Therefore, the abrasion of power connection fitting surface rub resistance and corrosion-resistant mill are improved Damage performance is fitting design, an important consideration index in process.
Hot spray process is a kind of common surface strengthening technology, and this method is by powdered or Filamentous metal or nonmetallic Material is heated to melting or semi-molten state, then stays itself or compressed air to be ejected into certain speed by flame pretreated Matrix surface, deposition and formed have various functions surface covering a kind of technology, make material obtain it is wear-resistant, corrosion-resistant Equal excellent properties.
But in practical applications, hot spray process also exposes some defects, such as the knot of thermally sprayed coating and base metal For resultant force based on mechanical interlock, the impact resistance of coating is not high;Secondly, thermal jet layer have certain porosity, consistency compared with It is low, carry out repairing sizes more difficult to the part of abrasion.
Accordingly, it is desirable to provide one kind can reduce power connection fitting wear condition, while there is stronger operate again A kind of method of property.
Summary of the invention
It is electrically connected not changing the purpose of the present invention is being surface-treated by laser melting coating to power connection fitting On the basis of fitting raw material, change physical aspect, the chemical content on surface etc., achieve the purpose that change surface mechanical performance, To improve the military service performance of power connection fitting.What the present invention was implemented with the following technical solutions:
A kind of method of power connection fitting surface peening, that improves is, method includes the following steps:
(1) fitting is pre-processed;
(2) surface consolidation material is prepared;
(3) laser melting coating;
(4) cladding layer is handled.
A kind of power connection fitting surface peening composition, it is improved in that the composition is 30~50 μ of granularity The metal alloy powders of m comprising: basic phase, hard phase and anti-corrosion phase;
By mass percentage:
The basic phase includes: Si 2.5~3.0%, C 2.0~2.5%;
The hard phase includes: W 4.0~6%, Cr 5.8%~7.5%, B 0.3~0.8%;
The anti-corrosion mutually includes: Al 5.0~6.5%.
Further,
The basic phase includes: Si 2.5%, C 2.5%;
The hard phase includes: W 5.0%, Cr 7.0%, B 0.8%;
The anti-corrosion mutually includes: Al 5.5%.
Further, the laser melting coating includes:
The shield gas flow rate 15L/min, 1500~2500W of power, 200~600mm/min of scanning speed, powder feeding rate The laser melting coating for being 5mm × 5mm for 12~18g/min and spot diameter.
Further, (4) handle the cladding layer, and the processing includes that barefoot is cut and rolled.
Further, the cladding layer barefoot is cut into 0.2~0.5mm, until the surface roughness of Ra < 0.8 μm;
Under pretightning force 50-2000N, 5-30 μm of Oscillation Amplitude and 15-80kHz supersonic frequency, rolled with 10-50m/min Speed carries out multiple tracks and rolls step pitch 0.2-1.5mm.
Compared with the immediate prior art, technical solution provided by the invention has following excellent effect:
(1) metal alloy powders provided by the invention are after laser melting coating preparation process, on electric armour clamp steel matrix surface Metallurgical bonding occurs, coating hardness is increased to 890HV, the mechanical performance of power connection fitting contact surface is greatly improved, thus Prevent the security risks such as fracture.
(2) laser melting coating surface reinforcing method provided by the invention can promote to be formed firmly by the addition of W, Cr, B element Matter phase, improves coating hardness, wearability, and the addition of Al element can be obviously improved the corrosion resistance of coating surface, average corrosion speed Rate can be reduced to 0.0913, to extend electric armour clamp service life, there is great dissemination.
(3) method that laser melting coating surface reinforcing method provided by the invention combines laser melting coating and ultrasonic burnishing, work Skill controllability is strong, high production efficiency, it is easy to accomplish automation control has significant practical implementation meaning convenient for promoting.
(4) coating structure provided by the invention by laser melting coating surface peening is fine and close, no significant defect, porosity It is small, the part of abrasion is easy to carry out repairing sizes, operability is extremely strong in practical applications.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general Logical technical staff's every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment 1
(1) substrate pretreated
To power connection fitting No. 35 polishings of steel matrix sand for surface paper, derusting, oil removing, smooth finish surface is obtained.
(2) laser melting coating
The composition proportion of laser cladding powder are as follows: 5.5%Al, 5.5%W, 7.0%Cr, 2.5%Si, 2.5%C, 0.8% B;Surplus is Fe and inevitable impurity.Cladding is subjected to mechanical mixture according to chemical component with metal alloys powder, is mixed It is dry after closing uniformly, it is fitted into powder feeder.Laser equipment argon gas guard mode in cladding process adjusts laser cladding technological parameter Are as follows: laser power 2000W, scanning speed 300mm/min, powder feeding rate are 14g/min, and spot diameter is 5mm × 5mm;Argon Throughput are as follows: 15L/min.Make cladding material and electric armour clamp that metallurgical reaction occur with No. 35 steel under the technological parameter, is formed Abrasion-proof corrosion-proof erosion resisting coating.
Embodiment 2
(1) substrate pretreated
It polishes power connection fitting 35CrMo steel matrix sand for surface paper, derusting, oil removing, obtains smooth finish surface.
(2) laser melting coating
The composition proportion of laser cladding powder are as follows: 6.0%Al;, 4.5%W, 6.0%Cr, 2.5%Si, 2.5%C, 0.5% B;Surplus is Fe and inevitable impurity.Cladding is subjected to mechanical mixture according to chemical component with metal alloys powder, is mixed It is dry after closing uniformly, it is fitted into powder feeder.Laser equipment argon gas guard mode in cladding process adjusts laser cladding technological parameter Are as follows: laser power 2000W, scanning speed 240mm/min, powder feeding rate are 15g/min, and spot diameter is 5mm × 5mm;Argon Throughput are as follows: 15L/min.Make cladding material and electric armour clamp 35CrMo steel that metallurgical reaction, shape occur under the technological parameter At abrasion-proof corrosion-proof erosion resisting coating.
Embodiment 3
(1) substrate pretreated
It polishes power connection fitting Q345R steel matrix sand for surface paper, derusting, oil removing, obtains smooth finish surface.
(2) laser melting coating
The composition proportion of laser cladding powder are as follows: 5.5%Al;, 5.0%W, 7.0%Cr, 2.5%Si, 2.5%C, 0.8% B;Surplus is Fe and inevitable impurity.Cladding is subjected to mechanical mixture according to chemical component with metal alloys powder, is mixed It is dry after closing uniformly, it is fitted into powder feeder.Laser equipment argon gas guard mode in cladding process adjusts laser cladding technological parameter Are as follows: laser power 2000W, scanning speed 300mm/min, powder feeding rate are 12g/min, and spot diameter is 5mm × 5mm;Argon Throughput are as follows: 15L/min.Make cladding material and electric armour clamp Q345R steel that metallurgical reaction occur under the technological parameter, is formed resistance to Grind corrosion-resistant finishes.
Data recorded in above-described embodiment are subjected to sorting-out in statistics, laser cladding powder proportion is as shown in table 1:
Table one
Embodiment label W/% Cr/% B/% Al/% Si/% C/%
1 5.5 7.0 0.8 5.5 2.5 2.5
2 4.5 6.0 0.5 6.0 2.5 2.5
3 5.0 7.0 0.8 5.5 2.5 2.5
Laser cladding technological parameter is as shown in Table 2:
Table two
Laser cladding layer performance is as shown in Table 3:
Table three
Embodiment label Coating hardness Critical fracture energy release rate Average corrosion rate
1 890HV 232J/m2 0.0986
2 728HV 392J/m2 0.0913
3 812HV 286J/m2 0.0975
Through the foregoing embodiment and experimental test data can obtain, after provided above scheme of the invention, design Cladding powder after providing laser melting coating preparation process, metallurgical bonding occurs in electric armour clamp matrix surface, interface cohesion is strong Degree is high.The coating structure is fine and close, no significant defect.The addition of element W, Cr, B can form hard phase, improve coating hardness, wear-resisting Property, and the addition of Al element can be obviously improved the corrosion resistance of coating surface.To reach improve fitting surface abrasion resistance and The purpose of corrosion resistance.Preparation process is simple, low in cost, convenient for promoting, has significant practical implementation meaning.More than Described is only presently preferred embodiments of the present invention, is not intended to limit the invention, all within the spirits and principles of the present invention, Any modification, equivalent replacement, improvement and so on, within accompanying claims protection scope of the present invention.

Claims (6)

1. a kind of method of power connection fitting surface peening, which is characterized in that method includes the following steps:
(1) fitting is pre-processed;
(2) surface consolidation material is prepared;
(3) laser melting coating;
(4) cladding layer is handled.
2. a kind of power connection fitting surface peening composition, which is characterized in that the gold that the composition is 30~50 μm of granularity Belong to alloy powder comprising: basic phase, hard phase and anti-corrosion phase;
By mass percentage:
The basic phase includes Si 2.5~3.0%, C 2.0~2.5%;
The hard phase includes W 4.0~6%, Cr 5.8%~7.5%, B 0.3~0.8%;
The anti-corrosion mutually includes Al 5.0~6.5%.
3. a kind of power connection fitting surface peening composition as claimed in claim 2, which is characterized in that
The basic phase includes Si 2.5%, C 2.5%;
The hard phase includes W 5.0%, Cr 7.0%, B 0.8%;
The anti-corrosion mutually includes Al 5.5%.
4. a kind of power connection fitting surface reinforcing method as described in claim 1, which is characterized in that the laser melting coating packet It includes:
The shield gas flow rate 15L/min, 1500~2500W of power, 200~600mm/min of scanning speed, powder feeding rate are 12 The laser melting coating that~18g/min and spot diameter are 5mm × 5mm.
5. a kind of power connection fitting surface reinforcing method as described in claim 1, (4) handle the cladding layer, feature It is, the processing includes that barefoot is cut and rolled.
6. a kind of power connection fitting surface reinforcing method as described in claim 1, which is characterized in that by the cladding layer barefoot 0.2~0.5mm is cut, until the surface roughness of Ra < 0.8 μm;
Under pretightning force 50-2000N, 5-30 μm of Oscillation Amplitude and 15-80kHz supersonic frequency, with 10-50m/min rolling speed It carries out multiple tracks and rolls step pitch 0.2-1.5mm.
CN201811285652.9A 2018-10-31 2018-10-31 Laser cladding surface strengthening method for electric power connecting fitting Active CN109536942B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811285652.9A CN109536942B (en) 2018-10-31 2018-10-31 Laser cladding surface strengthening method for electric power connecting fitting

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Application Number Priority Date Filing Date Title
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CN109536942B CN109536942B (en) 2023-11-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110735104A (en) * 2019-10-28 2020-01-31 山东大学 in-situ ultrasonic rolling integrated device and method for thermal spraying

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643901A (en) * 2008-08-06 2010-02-10 沈阳新松机器人自动化股份有限公司 Alloy coating for crystallizer surface laser cladding and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643901A (en) * 2008-08-06 2010-02-10 沈阳新松机器人自动化股份有限公司 Alloy coating for crystallizer surface laser cladding and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110735104A (en) * 2019-10-28 2020-01-31 山东大学 in-situ ultrasonic rolling integrated device and method for thermal spraying

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