CN109536251A - Lubricant oil composite and preparation method thereof and micro lubricating oil is prepared with the composition - Google Patents
Lubricant oil composite and preparation method thereof and micro lubricating oil is prepared with the composition Download PDFInfo
- Publication number
- CN109536251A CN109536251A CN201811329176.6A CN201811329176A CN109536251A CN 109536251 A CN109536251 A CN 109536251A CN 201811329176 A CN201811329176 A CN 201811329176A CN 109536251 A CN109536251 A CN 109536251A
- Authority
- CN
- China
- Prior art keywords
- lubricant oil
- oil composite
- micro lubricating
- composite
- lubricating oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 36
- 239000003921 oil Substances 0.000 title claims abstract description 36
- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 title description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 18
- 239000008103 glucose Substances 0.000 claims abstract description 18
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 11
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims abstract description 6
- 239000011574 phosphorus Substances 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 235000019198 oils Nutrition 0.000 claims description 33
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- -1 fatty alcohol phosphate Chemical class 0.000 claims description 17
- 229910019142 PO4 Inorganic materials 0.000 claims description 15
- 235000021317 phosphate Nutrition 0.000 claims description 15
- 239000010452 phosphate Substances 0.000 claims description 13
- 235000005687 corn oil Nutrition 0.000 claims description 12
- 239000002285 corn oil Substances 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- CJFLBOQMPJCWLR-UHFFFAOYSA-N bis(6-methylheptyl) hexanedioate Chemical compound CC(C)CCCCCOC(=O)CCCCC(=O)OCCCCCC(C)C CJFLBOQMPJCWLR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 230000006837 decompression Effects 0.000 claims description 7
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 239000001384 succinic acid Substances 0.000 claims description 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 3
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229940055577 oleyl alcohol Drugs 0.000 claims description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 2
- 239000007848 Bronsted acid Substances 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 claims description 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 claims description 2
- 235000021081 unsaturated fats Nutrition 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- 238000005461 lubrication Methods 0.000 abstract description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007866 anti-wear additive Substances 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000002173 cutting fluid Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000005864 Sulphur Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000219094 Vitaceae Species 0.000 description 2
- 235000021021 grapes Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920001917 Ficoll Polymers 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a kind of lubricant oil composites, it is characterised in that: by being prepared including glucose, dicarboxylic acids；Wherein, glucose: the molar ratio of dicarboxylic acids is 1:2-3.Using lubricant oil composite prepared by the present invention, with bigger molecular weight, its lubricity, extreme pressure anti-wear, rust-preventing characteristic, biodegradability are good, traditional extreme pressure anti-wear additives containing chlorine, sulphur, phosphorus can be completely or partially replaced to be used in micro lubricating oil, a small amount of micro lubricating oil is just able to satisfy lubrication, extreme-pressure anti-wear and the antirust requirement of intermetallic composite coating；Cooperate minimum quantity lubrication device to use, 95% or more the usage amount of cutting fluid can be saved, energy-saving and emission-reduction, environmental protection effect are significant.
Description
Technical field
The invention belongs to lubrication technical fields, and in particular, to a kind of lubricant oil composite and preparation method thereof and with should
Composition prepares micro lubricating oil.
Background technique
Traditional metal cutting process carries out a large amount of shower formula lubrications, lubricant using mineral oil or vegetable oil or cutting fluid
Usage amount it is big, not only waste of resource, causes the huge pollution of processing site and environment, while can also seriously affect operator
Health.
To solve these problems, certain progress, Minimal Quantity Lubrication Technology solution are obtained to the research of Minimal Quantity Lubrication Technology in the recent period
The problems such as above lubricant usage amount of having determined is big, seriously polluted, but the research to micro lubricating agent, but application aspect there is also
Certain problem, mainly lubricates and cooling problem not can solve.
Research to micro lubricating oil is an interesting challenge.
Summary of the invention
In view of disadvantages described above, the present invention is directed to overcome the deficiencies of the prior art and provide a kind of lubricant oil composite and its system
Preparation Method and micro lubricating oil is prepared with the composition.
To achieve the above object, a kind of lubricant oil composite provided by the invention, which is characterized in that by include glucose,
Dicarboxylic acids is prepared,
Wherein, above-mentioned glucose, dicarboxylic acids molar ratio be 1:2-3；Optimum mole ratio is 2:5.
Above-mentioned dicarboxylic acids be selected from fumaric acid and its derivative, maleic acid and its derivative, succinic acid and its derivative, oneself
One or more of diacid and its derivative, suberic acid and its derivative, decanedioic acid and its derivative.
The present invention also provides the preparation methods of above-mentioned lubricant oil composite: weighing glucose, dicarboxylic acids point in proportion
180-240 DEG C Jia Ru not be heated with stirring in reaction kettle, sufficiently reaction 6-12 hour, moisture, as a kind of lubrication is discharged in decompression
Fluid composition.
Further, in the preparation method of above-mentioned ficoll aliphatic ester provided by the invention: in order to improve reaction speed
Catalyst can also be added in reactant and accelerate reaction for degree；
The catalyst is selected from one of Bronsted acid, ion exchange resin, molecular sieve；
The catalyst preferably is selected from phosphoric acid；When catalyst selects phosphoric acid, effective component accounts for the 0.5- of reactant total weight
1%.It being also an advantage that when catalyst selects phosphoric acid, phosphoric acid can react with glucose and generate glucose phosphate ester,
Glucose phosphate ester has relatively good extreme pressure anti-wear, while catalyst reduces production cost without separation.
In addition, the present invention also provides a kind of micro lubricating oils containing above-mentioned lubricant oil composite, which is characterized in that by with
The component of lower weight percent is fabricated:
Above-mentioned fatty alcohol phosphate is selected from saturation or the pure and mild phosphoric acid of unsaturated fat or phosphorus pentoxide reacts generation
One or more of aliphatic alcohol ester；
Above-mentioned corn oil is selected from commercially available corn oil (or maize germ oil)；
Above-mentioned fatty alcohol phosphate preferably is selected from three laruyl alcohol phosphates, Conditions of Trilauryl Phosphite Ester, isomerous tridecanol phosphorus
One or more of acid esters, oleyl alcohol phosphate, three Di-phosphorus pentonides.
In addition, the present invention provides the preparation methods of the micro lubricating oil of above-mentioned lubricant oil composite: by lubricating oil composition
When object, corn oil, diisooctyl adipate, fatty alcohol phosphate mix to transparent at a temperature of 40~60 DEG C.
The action and effect of invention
Using lubricant oil composite prepared by the present invention, there is bigger molecular weight, lubricity, extreme pressure anti-wear,
Rust-preventing characteristic, biodegradability are good, can completely or partially replace it is traditional containing chlorine, sulphur, phosphorus extreme pressure anti-wear additives be used in it is micro
In lubricating oil, a small amount of micro lubricating oil is just able to satisfy lubrication, extreme-pressure anti-wear and the antirust requirement of intermetallic composite coating；Cooperate micro-
It measures lubricating arrangement to use, 95% or more the usage amount of cutting fluid can be saved, energy-saving and emission-reduction, environmental protection effect are significant.
In the present invention, corn oil has good lubricity and biodegradability.
In the present invention, diisooctyl adipate provides good lubricity, and biological degradability is good, while lower movement
Viscosity can effectively reduce the kinematic viscosity of micro lubricating oil, be easy to use in minimum quantity lubrication device.
In the present invention, fatty alcohol phosphate, have good lubricity and extreme pressure anti-wear, can partially replace sulfur-bearing,
Extreme pressure anti-wear additives containing chlorine.
In formula of the invention, after above-mentioned each component mixing, it is based on its respective design feature, can be occurred intermolecular weak
Key active force is mixed after mutually promoting, improves and excite the properties such as mutual lubricity, dissolubility and extreme pressure anti-wear.
Specific embodiment
Embodiment one
Weigh 180.16g (1mol) glucose, 232.14g (2mol) maleic acid is separately added into reaction kettle, agitating and heating
To 240 DEG C, sufficiently reaction 12 hours, decompression discharge moisture, as a kind of lubricant oil composite (poly glucose ester).
Weigh lubricant oil composite 300g, corn oil 300g, diisooctyl adipate 300g, three laruyl alcohols of above-mentioned preparation
Phosphate 100g as a kind of micro lubricating oil when mixing to transparent at a temperature of 40 DEG C.
Embodiment two
Weigh 180.16g (1mol) glucose, 354.27g (3mol) succinic acid is separately added into reaction kettle, 5g dilute sulfuric acid
(concentration 10%) is heated with stirring to 180 DEG C, sufficiently reaction 6 hours, decompression discharge moisture, and as a kind of lubricant oil composite is (poly-
Succinic acid glucose ester).
Weigh lubricant oil composite 400g, corn oil 350g, diisooctyl adipate 200g, the phosphorous acid three of above-mentioned preparation
Laurel alcohol ester 50g as a kind of micro lubricating oil when mixing to transparent at a temperature of 50 DEG C or so.
Embodiment three
Weigh 360.32g (2mol) glucose, 730.7g (5mol) adipic acid is separately added into reaction kettle, be heated with stirring to
210 DEG C, 20g phosphoric acid (concentration 50%) sufficiently reaction 9 hours, decompression discharge moisture, as a kind of lubricant oil composite (gathered oneself two
Sour grapes sugar ester).
Weigh lubricant oil composite 350g, corn oil 320g, diisooctyl adipate 260g, the isomery 13 of above-mentioned preparation
As a kind of micro lubricating oil when alcohol phosphate 70g mixes to transparent at 50 DEG C of temperature or so.
Example IV
Weigh 360.32g (2mol) glucose, 860.9g (5mol) suberic acid is separately added into reaction kettle, be heated with stirring to
200 DEG C, 8g phosphoric acid (concentration 85%) sufficiently reaction 10 hours, decompression discharge moisture, as a kind of lubricant oil composite (gathered pungent two
Sour grapes sugar ester).
Weigh lubricant oil composite 320g, corn oil 380g, diisooctyl adipate 220g, the oleyl alcohol phosphoric acid of above-mentioned preparation
As a kind of micro lubricating oil when ester 80g mixes to transparent at 50 °C.
Embodiment five
Weigh 360.32g (2mol) glucose, 1011.25g (5mol) decanedioic acid is separately added into reaction kettle, agitating and heating
To 220 DEG C, 12g phosphoric acid (concentration 85%) sufficiently reaction 8 hours, moisture, as a kind of lubricant oil composite (poly- last of the ten Heavenly stems was discharged in decompression
Diacid glucose ester).
Weigh lubricant oil composite 330g, corn oil 330g, diisooctyl adipate 250g, three isooctanol of above-mentioned preparation
As a kind of micro lubricating oil when phosphate 90g mixes to transparent at 50 DEG C of temperature or so.
Above-described embodiment five is prepared into micro lubricating oil and is applied to gear teeth processing, gear-hobbing machine model:
YK3132；Process gear: diameter 100mm, modulus 2.0mm；Hobboing cutter: TiN coating, diameter 75mm, length 70mm.Originally use 46#
Machinery oil carries out circulation lubrication, and being changed to KS-2107 minimum quantity lubrication device now, (3 nozzles, all nozzles are Shanghai Jin Zhaojie
Can Science and Technology Ltd. production energy-conserving spray nozzle) and above-mentioned preparation micro lubricating oil, the result is as follows:
Claims (10)
1. a kind of lubricant oil composite, it is characterised in that: by being prepared including glucose, dicarboxylic acids；
Wherein, glucose: the molar ratio of dicarboxylic acids is 1:2-3.
2. a kind of lubricant oil composite as described in claim 1, it is characterised in that:
The glucose: the molar ratio of dicarboxylic acids is 2:5.
3. a kind of lubricant oil composite as described in claim 1, it is characterised in that:
The dicarboxylic acids is selected from fumaric acid and its derivative, maleic acid and its derivative, succinic acid and its derivative, adipic acid
And its one or more of derivative, suberic acid and its derivative, decanedioic acid and its derivative.
4. a kind of preparation method of lubricant oil composite a method according to any one of claims 1-3, it is characterised in that: weigh in proportion
Glucose, dicarboxylic acids are separately added into reaction kettle, are heated with stirring to 180-240 DEG C, sufficiently reaction 6-12 hours, decompression discharge
Moisture, as a kind of lubricant oil composite.
5. a kind of preparation method of lubricant oil composite as claimed in claim 4, it is characterised in that:
Catalyst can also be added in reactant and accelerate reaction；
Wherein, the catalyst is selected from one of Bronsted acid, ion exchange resin, molecular sieve.
6. a kind of micro lubricating oil containing lubricant oil composite, which is characterized in that by following components in percentage by weight manufacture
At:
7. a kind of micro lubricating oil containing lubricant oil composite as claimed in claim 6, it is characterised in that:
The corn oil is selected from commercially available corn oil or maize germ oil.
8. a kind of micro lubricating oil containing lubricant oil composite as claimed in claim 6, it is characterised in that:
The fatty alcohol that the fatty alcohol phosphate is selected from saturation or the pure and mild phosphoric acid of unsaturated fat or phosphorus pentoxide reaction generates
One or more of ester.
9. a kind of micro lubricating oil containing lubricant oil composite as claimed in claim 6, it is characterised in that:
The fatty alcohol phosphate is selected from three laruyl alcohol phosphates, Conditions of Trilauryl Phosphite Ester, isomerous tridecanol phosphate, oleyl alcohol
One or more of phosphate, three Di-phosphorus pentonides.
10. a kind of preparation method of the micro lubricating oil containing lubricant oil composite, it is characterised in that:
Lubricant oil composite, corn oil, diisooctyl adipate, fatty alcohol phosphate are mixed at a temperature of 40~60 DEG C
When extremely transparent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811329176.6A CN109536251B (en) | 2018-11-09 | 2018-11-09 | Lubricating oil composition, preparation method thereof and trace lubricating oil prepared from lubricating oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811329176.6A CN109536251B (en) | 2018-11-09 | 2018-11-09 | Lubricating oil composition, preparation method thereof and trace lubricating oil prepared from lubricating oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109536251A true CN109536251A (en) | 2019-03-29 |
| CN109536251B CN109536251B (en) | 2021-06-01 |
Family
ID=65846399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811329176.6A Active CN109536251B (en) | 2018-11-09 | 2018-11-09 | Lubricating oil composition, preparation method thereof and trace lubricating oil prepared from lubricating oil composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109536251B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090149359A1 (en) * | 2007-12-10 | 2009-06-11 | Hundley Lloyd E | Formulation of a metal working fluid |
| WO2015099907A1 (en) * | 2013-12-23 | 2015-07-02 | Exxonmobil Research And Engineering Company | Low viscosity ester lubricant and method for using |
| CN105296081A (en) * | 2015-10-16 | 2016-02-03 | 上海金兆节能科技有限公司 | Degradable minimal quantity lubrication oil and preparation method thereof |
| CN106350190A (en) * | 2016-08-19 | 2017-01-25 | 湖北省化学工业研究设计院 | High-intensity brass plating wire drawing lubricant and preparation method thereof |
| CN108003973A (en) * | 2017-12-15 | 2018-05-08 | 上海金兆节能科技有限公司 | Degradable environment protection micro lubricating oil and preparation method thereof |
-
2018
- 2018-11-09 CN CN201811329176.6A patent/CN109536251B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090149359A1 (en) * | 2007-12-10 | 2009-06-11 | Hundley Lloyd E | Formulation of a metal working fluid |
| WO2015099907A1 (en) * | 2013-12-23 | 2015-07-02 | Exxonmobil Research And Engineering Company | Low viscosity ester lubricant and method for using |
| CN105296081A (en) * | 2015-10-16 | 2016-02-03 | 上海金兆节能科技有限公司 | Degradable minimal quantity lubrication oil and preparation method thereof |
| CN106350190A (en) * | 2016-08-19 | 2017-01-25 | 湖北省化学工业研究设计院 | High-intensity brass plating wire drawing lubricant and preparation method thereof |
| CN108003973A (en) * | 2017-12-15 | 2018-05-08 | 上海金兆节能科技有限公司 | Degradable environment protection micro lubricating oil and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 姚崇正等: "《精细化工产品合成原理》", 31 March 2000, 中国石化出版社 * |
| 高永建等: "长碳链二元酸酯的合成及其物化性能", 《过程工程学报》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109536251B (en) | 2021-06-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105732968B (en) | Ficoll fatty acid ester and preparation method thereof and prepare micro lubricating oil with the ester | |
| CN101230304B (en) | Environment-friendly type transformer oil and preparation method thereof | |
| CN103232548B (en) | A kind of preparation method of glass fibre infiltration esterification starch membrane-forming agent | |
| CN104479825A (en) | Environment-friendly hydraulic-transmission-brake oil for hydraulic, transmission and brake device systems | |
| CN101654636A (en) | Biological type micro lubricating oil and preparation method and application thereof | |
| CN101407739A (en) | Method for preparing biological lubricant oil from raw material Idesia polycarpa oil | |
| CN109439386B (en) | Environment-friendly degradable trace lubricating oil and preparation method thereof | |
| CN109536251A (en) | Lubricant oil composite and preparation method thereof and micro lubricating oil is prepared with the composition | |
| CN104498131A (en) | Method for preparing lithium-based (lithium-based calcium-based) lubricating grease by using waste vegetable oil and application | |
| CN107686763A (en) | Hydraulic engineering food-grade bearing grease and preparation method and application | |
| CN107254346A (en) | A kind of calcium zirconyl phosphate base grease and preparation method thereof | |
| CN103087797B (en) | Preparation method of biodegradable lubricating oil | |
| CN108003973A (en) | Degradable environment protection micro lubricating oil and preparation method thereof | |
| CN108341952A (en) | A kind of low temperature resistant lubricating oil of organosilicon and preparation method thereof | |
| CN106367186B (en) | One vegetable oil base degradable lubricating oil | |
| CN109943390A (en) | The micro lubricating oil of lubricant oil composite and preparation method thereof and combination preparation | |
| CN109609246B (en) | Environment-friendly micro-cutting fluid and preparation method thereof | |
| Vodounon et al. | Eco-friendly additivated lubricating greases made of agricultural resources | |
| CN103468412A (en) | Method for preparing lubricant composition by using waste grease and degradable micro-lubricating oil prepared by using composition | |
| CN107382927A (en) | One kind lubrication oiliness improver and its synthetic method and application | |
| CN102604717A (en) | Complex calcium sulfonate grease and method for preparing same | |
| CN104293427B (en) | A kind of copper ROLLING OIL of oxidation and corrosion and preparation method thereof | |
| CN109337733B (en) | Lubricant composition, preparation method thereof and trace cutting fluid prepared from same | |
| CN115786024B (en) | Preparation method of biodegradable calcium-based lubricating grease | |
| CN107474897A (en) | Phosphorous lube oil additive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240409 Address after: No. 11, Zhunnan Road, Dushanzi District, Karamay, Xinjiang Uygur Autonomous Region, 834000 Patentee after: Xinjiang Hairun Technology Co.,Ltd. Country or region after: China Address before: 200436 room 103, building 4, Lane 299, China Railway Central Plaza, JIANGCHANG West Road, Jing'an District, Shanghai Patentee before: SHANGHAI JINZHAO ENERGY SAVING TECHNOLOGY Co.,Ltd. Country or region before: China |