CN109536110A - A kind of engine casting dedicated reparation glue of cylinder body - Google Patents

A kind of engine casting dedicated reparation glue of cylinder body Download PDF

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Publication number
CN109536110A
CN109536110A CN201811475081.5A CN201811475081A CN109536110A CN 109536110 A CN109536110 A CN 109536110A CN 201811475081 A CN201811475081 A CN 201811475081A CN 109536110 A CN109536110 A CN 109536110A
Authority
CN
China
Prior art keywords
cylinder body
glue
reparation
engine
dedicated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811475081.5A
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Chinese (zh)
Inventor
黄光伟
张京伟
刘旭飞
王跃
曹长青
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Jac Casting Co Ltd
Original Assignee
Hefei Jac Casting Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Jac Casting Co Ltd filed Critical Hefei Jac Casting Co Ltd
Priority to CN201811475081.5A priority Critical patent/CN109536110A/en
Publication of CN109536110A publication Critical patent/CN109536110A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

The present invention relates to a kind of engines to cast the dedicated reparation glue of cylinder body, is mixed by polyurethane-type anaerobic adhesive, ferrocene, graphene powder, silicon carbide, solvent.The reparation glue will not solidify at room temperature, and solidification temperature is 60~70 DEG C, and the shear strength of cured glue layer is high;Under the action of expanding with heat and contract with cold repeatedly, cured glue layer is not easy to be detached from leakage hole, and the probability that secondary gas leakage occurs is low, and engine is effectively avoided to cast cylinder body premature failure, to extend the service life of engine casting cylinder body.

Description

A kind of engine casting dedicated reparation glue of cylinder body
Technical field
The present invention relates to engine casting technology fields more particularly to a kind of engine to cast the dedicated reparation glue of cylinder body.
Background technique
The characteristics of engine casting cylinder body generallys use die-casting process and is made, die-casting process is using mold inner-cavity to thawing Metal applies high pressure.Die-casting process is particularly suitable for manufacture a large number of small and medium-sized castings, therefore die casting is made in a variety of casting processes With widest one kind.Compared with other casting technology, the surface of die casting is more smooth, possesses higher dimensional uniformity.
But using the engine casting cylinder interior of pressing process manufacture usually by a large amount of stomata, if the position of stomata Near combustion chamber in engine casting cylinder body, combustion chamber gas leakage is easily caused.It is current for the engine casting cylinder body of gas leakage It generallys use anaerobic adhesive to be repaired, if also gas leakage after repairing, is determined as waste product.It and is all usually at present to cast engine Cylinder body is immersed in anaerobic adhesive, and then repressurization infiltrates anaerobic adhesive being filled into leakage hole.Engine casting cylinder body is using die casting Aluminium alloy engine made of technique casts cylinder body, and the thermal expansion coefficient of aluminium alloy is differed with the thermal expansion coefficient of anaerobic adhesive after solidification Very big, if leakage hole is larger, anaerobic adhesive is easily detached from leakage hole under the action of expanding with heat and contract with cold repeatedly after solidification, thus Secondary gas leakage is generated, engine is caused to cast cylinder body premature failure, influences the service life of engine casting cylinder body.
Summary of the invention
The present invention is in view of the deficienciess of the prior art, provide a kind of engine casting dedicated reparation glue of cylinder body, specific skill Art scheme is as follows:
A kind of engine casts the dedicated reparation glue of cylinder body, by polyurethane-type anaerobic adhesive, ferrocene, graphene powder, silicon carbide, Solvent is mixed.
As an improvement of the above technical solution, the polyurethane-type anaerobic adhesive, ferrocene, graphene powder, silicon carbide, molten The mass ratio of agent is 100:(7.1~7.9): (10.6~11.5): (5.6~6.3): (50~80).
As an improvement of the above technical solution, the partial size of the graphene powder is less than or equal to 100nm.
As an improvement of the above technical solution, the partial size of the silicon carbide is less than or equal to 100nm.
As an improvement of the above technical solution, the solvent is one of benzene, butanone, methylene chloride.
Beneficial effects of the present invention:
The reparation glue will not solidify at room temperature, and solidification temperature is 60~70 DEG C, and the shear strength of cured glue layer is high;? Under the action of expanding with heat and contract with cold repeatedly, cured glue layer is not easy to be detached from leakage hole, and the probability that secondary gas leakage occurs is low, effectively Engine is avoided to cast cylinder body premature failure, to extend the service life of engine casting cylinder body.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1
100kg polyurethane-type anaerobic adhesive, 7.1kg ferrocene, 10.6kg partial size are less than or equal to the Graphene powder of 100nm Silicon carbide, the 50kg benzene of body, 5.6kg partial size less than or equal to 100nm, which are mixed to obtain, repairs glue.The solidification temperature of the reparation glue Degree is 60 DEG C, and the shear strength that glue is repaired after solidification is 36Mpa.
Embodiment 2
100kg polyurethane-type anaerobic adhesive, 7.6kg ferrocene, 11.1kg partial size are less than or equal to the Graphene powder of 100nm Silicon carbide, the 70kg benzene of body, 6.1kg partial size less than or equal to 100nm, which are mixed to obtain, repairs glue.The solidification temperature of the reparation glue Degree is 66 DEG C, and the shear strength that glue is repaired after solidification is 36.7Mpa.
Embodiment 3
100kg polyurethane-type anaerobic adhesive, 7.9kg ferrocene, 11.5kg partial size are less than or equal to the Graphene powder of 100nm Silicon carbide, the 80kg benzene of body, 6.3kg partial size less than or equal to 100nm, which are mixed to obtain, repairs glue.The solidification temperature of the reparation glue Degree is 70 DEG C, and the shear strength that glue is repaired after solidification is 36.3Mpa.
In the above-described embodiments, the shear strength after polyurethane-type anaerobic adhesive directly solidifies is 30Mpa.Graphene powder and The addition of silicon carbide can reduce the thermal expansion coefficient of the reparation glue, and the addition of silicon carbide, which can also improve, improves the reparation glue Thermal linear expansion coefficient.The ferrocene can be dissolved in solvent and finally be scattered in polyurethane-type anaerobic adhesive.Polyurethane-type anaerobism Glue is under oxygen-free environment, room temperature, that is, curable;And by addition ferrocene so that the solidification temperature of the reparation glue promoted to 60~ 70 DEG C, the reparation glue is at room temperature even at will not rapid curing under oxygen-free environment.
The mode vacuumized can be used by the inside of leakage hole to being full of, so that it is qualified that reparation can be improved in the reparation glue Rate.Engine casting cylinder body is using the casting cylinder body of aluminium alloy engine made of die-casting process.Glue-line cuts after the reparation adhesive curing Shearing stress improves, and the thermal expansion coefficient and thermal linear expansion coefficient of glue-line reduce, so as to significantly improve glue-line and engine The difference of thermal expansion coefficient between cylinder body is cast, avoids causing the hole wall of glue-line and leakage hole to be detached from because expanding with heat and contract with cold, from And lead to that secondary gas leakage occurs.Senile experiment, digestion period three are being carried out using the engine casting cylinder body of the reparation glue reparation Year, leak rate occurs after senile experiment again no more than 2.2%.And common anaerobic adhesive is used, as polyurethane-type anaerobic adhesive is direct Leakage hole is filled into repair obtained control cylinder body, control cylinder body is 3 years carrying out senile experiment, digestion period, aging It is more than 6.9% that leak rate occurs after experiment again.That is, the engine casting cylinder body using the reparation glue reparation will not shift to an earlier date Failure, service life extend.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (5)

1. a kind of engine casts the dedicated reparation glue of cylinder body, it is characterised in that: by polyurethane-type anaerobic adhesive, ferrocene, Graphene powder Body, silicon carbide, solvent are mixed.
2. a kind of engine according to claim 1 casts the dedicated reparation glue of cylinder body, it is characterised in that: the polyurethane-type is detested Oxygen glue, ferrocene, graphene powder, silicon carbide, solvent mass ratio be 100:(7.1~7.9): (10.6~11.5): (5.6 ~6.3): (50~80).
3. a kind of engine according to claim 1 casts the dedicated reparation glue of cylinder body, it is characterised in that: the graphene powder Partial size be less than or equal to 100nm.
4. a kind of engine according to claim 1 casts the dedicated reparation glue of cylinder body, it is characterised in that: the grain of the silicon carbide Diameter is less than or equal to 100nm.
5. a kind of engine according to claim 1 casts the dedicated reparation glue of cylinder body, it is characterised in that: the solvent be benzene, One of butanone, methylene chloride.
CN201811475081.5A 2018-12-04 2018-12-04 A kind of engine casting dedicated reparation glue of cylinder body Pending CN109536110A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811475081.5A CN109536110A (en) 2018-12-04 2018-12-04 A kind of engine casting dedicated reparation glue of cylinder body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811475081.5A CN109536110A (en) 2018-12-04 2018-12-04 A kind of engine casting dedicated reparation glue of cylinder body

Publications (1)

Publication Number Publication Date
CN109536110A true CN109536110A (en) 2019-03-29

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CN201811475081.5A Pending CN109536110A (en) 2018-12-04 2018-12-04 A kind of engine casting dedicated reparation glue of cylinder body

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA85490C2 (en) * 2008-01-08 2009-01-26 Государственное Высшее Учебное Заведение "Украинский Государственный Химико-Технологический Университет" Anaerobic adhesive composition
CN101928525A (en) * 2010-07-23 2010-12-29 北京天山新材料技术有限责任公司 High oil tolerant anaerobic adhesive and preparation method thereof
CN104245875A (en) * 2012-04-26 2014-12-24 陶氏环球技术有限责任公司 Epoxy adhesive composition
CN104356992A (en) * 2014-10-27 2015-02-18 苏州市胶粘剂厂有限公司 Anaerobic adhesive as well as preparation method and application thereof
CN108329886A (en) * 2018-03-21 2018-07-27 烟台泰盛精化科技有限公司 A kind of resistance to high impact-resistant anaerobic structure glue and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA85490C2 (en) * 2008-01-08 2009-01-26 Государственное Высшее Учебное Заведение "Украинский Государственный Химико-Технологический Университет" Anaerobic adhesive composition
CN101928525A (en) * 2010-07-23 2010-12-29 北京天山新材料技术有限责任公司 High oil tolerant anaerobic adhesive and preparation method thereof
CN104245875A (en) * 2012-04-26 2014-12-24 陶氏环球技术有限责任公司 Epoxy adhesive composition
CN104356992A (en) * 2014-10-27 2015-02-18 苏州市胶粘剂厂有限公司 Anaerobic adhesive as well as preparation method and application thereof
CN108329886A (en) * 2018-03-21 2018-07-27 烟台泰盛精化科技有限公司 A kind of resistance to high impact-resistant anaerobic structure glue and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
成来飞: "《复合材料原理及工艺》", 31 March 2018, 西北工业大学出版社 *
李子东: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 *

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Application publication date: 20190329