CN109534770A - A kind of foam concrete and preparation method thereof - Google Patents

A kind of foam concrete and preparation method thereof Download PDF

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Publication number
CN109534770A
CN109534770A CN201811558018.8A CN201811558018A CN109534770A CN 109534770 A CN109534770 A CN 109534770A CN 201811558018 A CN201811558018 A CN 201811558018A CN 109534770 A CN109534770 A CN 109534770A
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CN
China
Prior art keywords
parts
foam concrete
solid waste
binder
foaming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811558018.8A
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Chinese (zh)
Inventor
黄洋
仇春虎
张志敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU TRAFFIC ENGINEERING GROUP Co Ltd
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SUZHOU TRAFFIC ENGINEERING GROUP Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201811558018.8A priority Critical patent/CN109534770A/en
Publication of CN109534770A publication Critical patent/CN109534770A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

It include solid waste, epoxy resin, curing agent, binder, sodium metasilicate, foaming agent according to mass parts the present invention relates to a kind of foam concrete is provided.After preparation method includes the following steps: that (1) crushes solid waste, add water and stir uniformly;(2) epoxy resin, binder, sodium metasilicate and foaming agent is added to stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured;(5) concrete after pouring is conserved.Beneficial effects of the present invention: the method that the present invention prepares foam concrete is simple, and foam concrete compression strength obtained is high.Foam concrete of the invention uses protide foaming agent, and bubble content height, light weight, foam stability energy are good, and thermal and insulating performance is good, and soundproof effect is fine, while fire resistance is fine.The present invention can use solid waste, not only can be reduced the pollution of solid waste discharge generation, but also energy save the cost, economic and environment-friendly.

Description

A kind of foam concrete and preparation method thereof
Technical field
The invention belongs to the field of building materials, are to be related to a kind of foam concrete and preparation method thereof more specifically.
Background technique
When foam concrete a kind of benefit it is useless, environmentally friendly, energy saving, it is cheap and have non-flame properties novel building energy-saving material, than It plays " hard isolation " that traditional concrete is done and cost is greatly saved, and have the characteristic of lightweight, and have enough intensity, have simultaneously There is gap that can inhale noise, there is the special efficacy of sound insulation.Specifically, (1) high-strength light: foam concrete density is small, the common bubble of roofing Foam concrete density rating is A300, A400, A500 grades, 280~500KG/m3 of density, and intensity is greater than 0.30~1.00MPa, is made It for roof heat insulation, looks for that slope quality of materials is light, intensity is high, it is strong to mitigate building self weight, bearing capacity.(2) good to keep the temperature, is heat-insulated Performance: since, containing a large amount of closed tiny holes, thermal property is excellent, and roofing often uses foam concrete close in foam concrete Grade thermal coefficient is spent between 0.06~0.12W/ (M.K), and there are good heat preservation and energy conservation effects, meet 65% building section It can require.(3) keep the temperature, look for slope integrated: foam concrete roof heat insulation, sloping layer primary raw material are using ordinary cement, scene Production, mechanization production, pumping keep the temperature, look for slope integrated construction, and identical as base's material, overall performance is excellent.(4) it constructs Speed is fast: cast-in-place foamed concrete roof heat insulation, sloping layer, and operation injectability is strong, mechanization degree is high, mobility is strong, can Long-distance sand transport carries out large-area construction, and construction operation is fast, short time limit, and saving of labor is time saving.
Summary of the invention
Many benefits based on foam concrete, the present invention provides a kind of new foam concrete, according to mass parts packet Include following raw material: 10-25 parts of solid waste, 10-20 parts of epoxy resin, 1-4 parts of curing agent, 30-50 parts of binder, 2-4 parts of sodium metasilicate, 1-2 parts of foaming agent.
Epoxy resin is added and curing agent can increase the caking property and toughness of concrete, binder can increase the work with solid waste With, increase the caking property and fastness of concrete, sodium metasilicate can be modified concrete, be filled in gap, further increase Add the density of internal structure.
The present invention is further arranged to, and foam concrete includes following raw material according to mass parts: 15-20 parts of solid waste, epoxy 12-16 parts of resin, 3-4 parts of curing agent, 40-46 parts of binder, 2-3 parts of sodium metasilicate, 1.5-2 parts of foaming agent.
The present invention is further arranged to, and the binder is the mixed of one or both of sodium carboxymethylcellulose or cement Close object.
The present invention is further arranged to, and the cement is in sulphate aluminium cement, metasilicic acid cement or aluminate cement It is a kind of.
The present invention is further arranged to, and the solid material is one or more of flyash, gangue or clinker Mixture.
The present invention is further arranged to, and the foaming agent includes that mass ratio is (5-8): (2-3): 1 cow hoof angle, appropriate Ca (OH) 2 and NaHSO3.
The present invention is further arranged to, and raw material further includes the magnesium sulfate of 1-2 mass parts.
The present invention is further arranged to, and the curing agent is one or both of diethylenetriamine or triethylene tetramine Mixture.
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved.
The present invention is further arranged to, the condition conserved to concrete are as follows: temperature is 18-22 DEG C, humidity 85%- 95%.
In conclusion the invention has the following advantages:
(1) foam concrete produced by the present invention, preparation method is simple, natural curing.
(2) foam concrete compression strength produced by the present invention is high.
(3) foam concrete of the invention uses protide foaming agent, is combined using cow hoof angle with mineral material foaming Foam concrete block is prepared, bubble content height, light weight, foam stability energy are good.
(4) production finished product is reduced, the self weight of finished product itself is reduced and reduces the heavy burdens for secondary transhipment, while foam concrete Self-characteristic determines its lightweight, and thermal and insulating performance is good, since it has many gaps so soundproof effect is fine, while fire resisting Property is fine, and overall performance is good.
(5) present invention can use solid waste, not only can be reduced the pollution of solid waste discharge generation, but also energy save the cost, economic ring It protects.
Specific embodiment
In the following detailed description, many details are proposed, in order to complete understanding of the present invention.But It will be apparent to those skilled in the art that the present invention can not need some details in these details In the case of implement.Below to the description of embodiment just for the sake of provided by showing example of the invention to it is of the invention more Understand well.
Embodiment 1
A kind of foam concrete includes following raw material according to mass parts: 10 parts of flyash, 10 parts of gangue, clinker 5 Part, 10 parts of epoxy resin, 2 parts of diethylenetriamine, 2 parts of triethylene tetramine, 30 parts of sodium carboxymethylcellulose, 3 parts of sodium metasilicate, sulfuric acid 1.6 parts of magnesium, 1 part of cow hoof angle, 20.3 parts, NaHSO30.1 parts of appropriate Ca (OH).
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 18 DEG C, humidity 95%.
Embodiment 2
A kind of foam concrete includes following raw material according to mass parts: 5 parts of flyash, 5 parts of gangue, epoxy resin 20 parts, 1 part of triethylene tetramine, 40 parts of sodium carboxymethylcellulose, 2 parts of sodium metasilicate, 1 part of magnesium sulfate, 0.8 part of cow hoof angle, appropriate Ca (OH) 20.2 parts, NaHSO30.1 parts.
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 19 DEG C, humidity 90%.
Embodiment 3
A kind of foam concrete includes following raw material according to mass parts: 12 parts of gangue, 10 parts of clinker, epoxy resin 12 parts, 2 parts of triethylene tetramine, 50 parts of sulphate aluminium cement, 4 parts of sodium metasilicate, 2 parts of magnesium sulfate, 0.6 part of cow hoof angle, appropriate Ca (OH) 20.25 parts, NaHSO30.15 parts.
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 22 DEG C, humidity 85%.
Embodiment 4
A kind of foam concrete includes following raw material according to mass parts: 18 parts of flyash, 14 parts of epoxy resin, diethyl 3 parts of alkene triamine, 40 parts of metasilicic acid cement, 2.4 parts of sodium metasilicate, 1 part of cow hoof angle, 20.4 parts, NaHSO30.09 parts of appropriate Ca (OH).
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 19 DEG C, humidity 88%.
Embodiment 5
A kind of foam concrete includes following raw material according to mass parts: 10 parts of gangue, 16 parts of epoxy resin, diethyl 2 parts of alkene triamine, 30 parts of sodium carboxymethylcellulose, 10 parts of aluminate cement, 3.2 parts of sodium metasilicate.
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 20 DEG C, humidity 89%.
Embodiment 6
A kind of foam concrete includes following raw material according to mass parts: 23 parts of clinker, 16 parts of epoxy resin, divinyl 4 parts of triamine, 42 parts of aluminate cement, 3.6 parts of sodium metasilicate, 0.8 part of cow hoof angle, 20.2 parts, NaHSO30.05 parts of appropriate Ca (OH).
The present invention also provides the preparation method of above-mentioned foam concrete, which specifically comprises the following steps: (1) It after solid waste is crushed, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add epoxy resin, binder, Sodium metasilicate and foaming agent stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A;(4) mixture A is poured It builds;(5) concrete after pouring is conserved, condition are as follows: temperature is 21 DEG C, humidity 92%.
Sample dry density, water absorption rate, compression strength are surveyed according to method in JG/T266-2011 " foam concrete " It is fixed.Also do not occur collapsing when sample density reaches 240kg/m3 steeping phenomenon.Sample demoulding time is in 110min or more;Sample water absorption rate 15% or more;Sample 3d compression strength at least improves 0.09MPa.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than limits the protection scope of invention.It is aobvious So, described embodiment is only section Example of the present invention, rather than whole embodiments.Based on these embodiments, ability Domain those of ordinary skill every other embodiment obtained without creative efforts, belongs to institute of the present invention Scope of protection.Although referring to above-described embodiment, invention is explained in detail, those of ordinary skill in the art according to So creative work can not be made to according to circumstances mutual group of the feature in various embodiments of the present invention in the absence of conflict Other adjustment are made in conjunction, additions and deletions, so that different, the essential other technologies scheme without departing from design of the invention is obtained, these Technical solution similarly belongs to invention which is intended to be protected.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (10)

1. a kind of foam concrete, which is characterized in that it includes following raw material according to mass parts: 10-25 parts of solid waste, epoxy resin 10-20 parts, 1-4 parts of curing agent, 30-50 parts of binder, 2-4 parts of sodium metasilicate, 1-2 parts of foaming agent.
2. foam concrete according to claim 1, which is characterized in that it includes following raw material: solid waste according to mass parts 15-20 parts, 12-16 parts of epoxy resin, 3-4 parts of curing agent, 40-46 parts of binder, 2-3 parts of sodium metasilicate, 1.5-2 parts of foaming agent.
3. foam concrete according to claim 1, which is characterized in that the binder is sodium carboxymethylcellulose or water The mixture of one or both of mud.
4. foam concrete according to claim 3, which is characterized in that the cement is sulphate aluminium cement, metasilicic acid One of cement or aluminate cement.
5. foam concrete according to claim 1, which is characterized in that the solid material is flyash, gangue or clinker One or more of mixture.
6. foam concrete according to claim 1, which is characterized in that the foaming agent includes that mass ratio is (5-8): (2-3): 1 cow hoof angle, appropriate Ca (OH)2And NaHSO3
7. foam concrete according to claim 1, which is characterized in that raw material further includes the magnesium sulfate of 1-2 mass parts.
8. foam concrete according to claim 1, which is characterized in that the curing agent is diethylenetriamine or triethylene The mixture of one or both of tetramine.
9. the preparation method of foam concrete according to claim 1-8, which is characterized in that preparation method tool It after body includes the following steps: that (1) crushes solid waste, adds water and stirs uniformly, the quality of water is 0.3-0.4 times of solid waste;(2) add again Enter epoxy resin, binder, sodium metasilicate and foaming agent to stir evenly;(3) it adds curing agent and is uniformly mixing to obtain mixture A; (4) mixture A is poured;(5) concrete after pouring is conserved.
10. the preparation method of foam concrete according to claim 9, which is characterized in that conserved to concrete Condition are as follows: temperature is 18-22 DEG C, humidity 85%-95%.
CN201811558018.8A 2018-12-19 2018-12-19 A kind of foam concrete and preparation method thereof Pending CN109534770A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811558018.8A CN109534770A (en) 2018-12-19 2018-12-19 A kind of foam concrete and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811558018.8A CN109534770A (en) 2018-12-19 2018-12-19 A kind of foam concrete and preparation method thereof

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Publication Number Publication Date
CN109534770A true CN109534770A (en) 2019-03-29

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110255964A (en) * 2019-07-12 2019-09-20 福建闽华建材科技发展有限公司 A kind of foam concrete reinforcing agent
CN110340105A (en) * 2019-06-24 2019-10-18 张开翅 A kind of method that rubbish silicidation recycles
CN112777987A (en) * 2021-02-01 2021-05-11 东北大学 Iron tailing foam concrete and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110340105A (en) * 2019-06-24 2019-10-18 张开翅 A kind of method that rubbish silicidation recycles
CN110340105B (en) * 2019-06-24 2021-07-30 张开翅 Garbage silicification recycling method
CN110255964A (en) * 2019-07-12 2019-09-20 福建闽华建材科技发展有限公司 A kind of foam concrete reinforcing agent
CN112777987A (en) * 2021-02-01 2021-05-11 东北大学 Iron tailing foam concrete and preparation method thereof
CN112777987B (en) * 2021-02-01 2021-12-28 东北大学 Iron tailing foam concrete and preparation method thereof

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Application publication date: 20190329

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