CN109517275A - A kind of paper plastic combined package bag material and preparation method thereof - Google Patents

A kind of paper plastic combined package bag material and preparation method thereof Download PDF

Info

Publication number
CN109517275A
CN109517275A CN201811416914.0A CN201811416914A CN109517275A CN 109517275 A CN109517275 A CN 109517275A CN 201811416914 A CN201811416914 A CN 201811416914A CN 109517275 A CN109517275 A CN 109517275A
Authority
CN
China
Prior art keywords
paper
layer
parts
package bag
combined package
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811416914.0A
Other languages
Chinese (zh)
Inventor
王文明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Xicheng Plastic Products Co Ltd
Original Assignee
Tongling Xicheng Plastic Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Xicheng Plastic Products Co Ltd filed Critical Tongling Xicheng Plastic Products Co Ltd
Priority to CN201811416914.0A priority Critical patent/CN109517275A/en
Publication of CN109517275A publication Critical patent/CN109517275A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2565/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D2565/38—Packaging materials of special type or form
    • B65D2565/381—Details of packaging materials of special type or form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of paper plastic combined package bag material, raw material includes plastic film layer, adhesive-layer and nanometer paper layer, and wherein plastic film layer raw material includes: polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, lubricant；Nanometer paper layer raw material includes: paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester.The present invention also proposes the preparation method of paper plastic combined package bag material, includes the following steps: polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, and plastic film layer is made through film extrusion；Paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are uniformly mixed, through copy paper, cooling, dry obtained nanometer paper layer；Paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.The intensity of paper plastic combined package bag material of the present invention is high, wear-resisting property is good.

Description

A kind of paper plastic combined package bag material and preparation method thereof
Technical field
The present invention relates to field of packaging material more particularly to a kind of paper plastic combined package bag material and its preparation sides Method.
Background technique
Paper and plastics compound bag-composite plastic woven bag is made after the tape casting is compound using Polywoven Bag as substrate, packet The three-in-one complex pocket of cloth/film and cloth/three-in-one complex pocket of film/paper have been included, there is intensity height, good waterproof performance, rakish spy Point is widely used in the powderies such as Packaging Engineering plastics, rubber raw materials, building materials, food, chemical fertilizer, cement or granular solid material And Flexible articles.The plastic layer of paper and plastics compound bag uses polypropylene or polyethylene for substrate, and wear-resisting property is poor, makes for a long time The phenomenon that will appear rupture after, service life is short, is not able to satisfy people's demand.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of paper plastic combined package bag material and its preparations Method, intensity height, the wear-resisting property that packaging bag is made are good, and waterproof, moisture-proof not go mouldy, application prospect is wide.
The present invention proposes a kind of paper plastic combined package bag material, and raw material includes plastic film layer, adhesive-layer and nanometer paper layer, Wherein plastic film layer raw material includes: 80-100 parts of polypropylene by weight, and modified mesoporous illite 5-15 parts, silane coupling agent 1- 3 parts, 0.5-2 parts of stabilizer, 0.5-1.5 parts of lubricant；Nanometer paper layer raw material includes: paper mulberry nanofiber 80-120 by weight Part, 5-10 parts of cotton synthetic fibre fiber, 3-6 parts of polyvinyl alcohol, 3-6 parts of nanofiller, 3-4 parts of carragheen, polyglyceryl fatty acid ester 0.5- 1.5 part.
Preferably, modified mesoporous illite is the mesoporous illite of maleation polybutene oligomer surface graft modification, Grafting rate is 5-10%.
Preferably, lubricant is ethylene bis stearamide.
Preferably, stabilizer is terres rares stabilizer.
Preferably, nanofiller is nano-titanium dioxide and/or nanometer basic zirconium phosphate.
Preferably, adhesive-layer is aqueous polyurethane adhesive.
The present invention also proposes the preparation method of above-mentioned paper plastic combined package bag material, includes the following steps:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through being extruded into Plastic film layer is made in film；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It closes uniformly, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
The present invention obtains poly- third using polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, lubricant as raw material Alkene plastics film material, wherein can be shown by the way that the mesoporous illite of maleation polybutene oligomer surface graft modification is added Write the intensity and wear-resisting property for mentioning plastic film layer material；With paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, card Drawing glue, polyglyceryl fatty acid ester is that raw material obtains a nanometer paper layer, has the characteristics that intensity is high, wear-resisting, corrosion resistant；The present invention uses Aqueous polyurethane adhesive is adhesive layer, and by plastic film layer and and nanometer paper layer is hot sticky compound obtains paper plastic combined package bag material Intensity is high, wear-resisting property is good, waterproof, moisture-proof not go mouldy, raw material sources of the invention are wide, cheap, preparation process letter Just, at low cost, application prospect is wide.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of paper plastic combined package bag material, raw material include plastic film layer, aqueous polyurethane adhesive layer and nanometer paper Layer, wherein plastic film layer raw material includes: 80 parts of polypropylene by weight, modified mesoporous 5 parts of illite, 1 part of silane coupling agent, dilute 0.5 part of great soil group stabilizer, 0.5 part of ethylene bis stearamide；Nanometer paper layer raw material includes: paper mulberry nanofiber 80 by weight Part, 5 parts of cotton synthetic fibre fiber, 3 parts of polyvinyl alcohol, 3 parts of nano-titanium dioxide, 3 parts of carragheen, 0.5 part of polyglyceryl fatty acid ester.
The preparation method of above-mentioned paper plastic combined package bag material, includes the following steps:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through being extruded into Plastic film layer is made in film；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It closes uniformly, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
Embodiment 2
A kind of paper plastic combined package bag material, raw material include plastic film layer, aqueous polyurethane adhesive layer and nanometer paper Layer, wherein plastic film layer raw material includes: 100 parts of polypropylene by weight, and modified mesoporous 15 parts of illite, 3 parts of silane coupling agent, 2 parts of terres rares stabilizer, 1.5 parts of ethylene bis stearamide；Nanometer paper layer raw material includes: paper mulberry nanofiber 120 by weight Part, 10 parts of cotton synthetic fibre fiber, 6 parts of polyvinyl alcohol, 6 parts of nanometer basic zirconium phosphate, 4 parts of carragheen, 1.5 parts of polyglyceryl fatty acid ester.
The preparation method of above-mentioned paper plastic combined package bag material, includes the following steps:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through being extruded into Plastic film layer is made in film；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It closes uniformly, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
Embodiment 3
A kind of paper plastic combined package bag material, raw material include plastic film layer, aqueous polyurethane adhesive layer and nanometer paper Layer, wherein plastic film layer raw material includes: 90 parts of polypropylene by weight, and modified mesoporous 10 parts of illite, 2 parts of silane coupling agent, 1.5 parts of terres rares stabilizer, 1.0 parts of ethylene bis stearamide；Nanometer paper layer raw material includes: paper mulberry nanofiber by weight 100 parts, 7 parts of cotton synthetic fibre fiber, 4.5 parts of polyvinyl alcohol, 4.5 parts of nano-titanium dioxide, 3.5 parts of carragheen, polyglyceryl fatty acid ester 1.0 part.
The preparation method of above-mentioned paper plastic combined package bag material, includes the following steps:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through being extruded into Plastic film layer is made in film；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It closes uniformly, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
Embodiment 4
A kind of paper plastic combined package bag material, raw material include plastic film layer, aqueous polyurethane adhesive layer and nanometer paper Layer, wherein plastic film layer raw material includes: 85 parts of polypropylene by weight, and modified mesoporous 8 parts of illite, 2.5 parts of silane coupling agent, 1.8 parts of terres rares stabilizer, 1.3 parts of ethylene bis stearamide；Nanometer paper layer raw material includes: paper mulberry nanofiber by weight 110 parts, 9 parts of cotton synthetic fibre fiber, 5.5 parts of polyvinyl alcohol, 5.5 parts of nanometer basic zirconium phosphate, 3.6 parts of carragheen, polyglyceryl fatty acid ester 1.2 Part.
The preparation method of above-mentioned paper plastic combined package bag material, includes the following steps:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through being extruded into Plastic film layer is made in film；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It closes uniformly, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
As a comparison case with commercially available general paper-plastic packing bag, paper plastic combined package bag material is made with 1-4 of the embodiment of the present invention Through wear-resisting test data measured such as the following table 1.
Table 1
Test item Burst index (Kpam2/g) Surface abrasion situation
Embodiment 1 6.6 Without noticeable wear
Embodiment 2 6.5 Without noticeable wear
Embodiment 3 6.1 Without noticeable wear
Embodiment 4 6.3 Without noticeable wear
Comparative example 3.5 Noticeable wear
It can be seen that by upper 1 test result of table compared to comparative example, paper plastic combined package bag material is made in embodiment 1-4 Wear-resisting property is good, intensity is high, people's demand can be met.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (7)

1. a kind of paper plastic combined package bag material, which is characterized in that its raw material includes plastic film layer, adhesive-layer and nanometer paper layer, Wherein plastic film layer raw material includes: 80-100 parts of polypropylene by weight, and modified mesoporous illite 5-15 parts, silane coupling agent 1- 3 parts, 0.5-2 parts of stabilizer, 0.5-1.5 parts of lubricant；Nanometer paper layer raw material includes: paper mulberry nanofiber 80-120 by weight Part, 5-10 parts of cotton synthetic fibre fiber, 3-6 parts of polyvinyl alcohol, 3-6 parts of nanofiller, 3-4 parts of carragheen, polyglyceryl fatty acid ester 0.5- 1.5 part.
2. paper plastic combined package bag material according to claim 1, which is characterized in that modified mesoporous illite is maleic anhydride Change the mesoporous illite of polybutene oligomer surface graft modification, grafting rate 5-10%.
3. paper plastic combined package bag material according to claim 1, which is characterized in that lubricant is ethylene bis stearamide.
4. paper plastic combined package bag material according to claim 1, which is characterized in that stabilizer is terres rares stabilizer.
5. paper plastic combined package bag material according to claim 1, which is characterized in that nanofiller is nano-titanium dioxide And/or nanometer basic zirconium phosphate.
6. paper plastic combined package bag material according to claim 1, which is characterized in that adhesive-layer is aqueous polyurethane viscose glue Agent.
7. a kind of preparation method of paper plastic combined package bag material as described in claim 1, which is characterized in that including walking as follows It is rapid:
It is S1, polypropylene, modified mesoporous illite, silane coupling agent, stabilizer, mix lubricant is uniform, through film extrusion system Obtain plastic film layer；
S2, paper mulberry nanofiber, cotton synthetic fibre fiber, polyvinyl alcohol, nanofiller, carragheen, polyglyceryl fatty acid ester are mixed It is even, through copy paper, cooling, dry obtained nanometer paper layer；
S3, paper plastic combined package bag material is made in plastic film layer, adhesive-layer and heated adhere to of nanometer paper layer.
CN201811416914.0A 2018-11-26 2018-11-26 A kind of paper plastic combined package bag material and preparation method thereof Pending CN109517275A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811416914.0A CN109517275A (en) 2018-11-26 2018-11-26 A kind of paper plastic combined package bag material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811416914.0A CN109517275A (en) 2018-11-26 2018-11-26 A kind of paper plastic combined package bag material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109517275A true CN109517275A (en) 2019-03-26

Family

ID=65778834

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811416914.0A Pending CN109517275A (en) 2018-11-26 2018-11-26 A kind of paper plastic combined package bag material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109517275A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101451004A (en) * 2008-12-26 2009-06-10 大连塑料研究所有限公司 Film for producing composite paper-like film and paper-like film and method for producing the same
CN105035493A (en) * 2015-05-29 2015-11-11 铜陵方正塑业科技有限公司 Stretch-resisting paper-plastic compound bag and preparation method thereof
CN106012668A (en) * 2016-06-17 2016-10-12 铜陵方正塑业科技有限公司 Abrasion-resistant paper-plastic composite bag and preparation method thereof
CN107177102A (en) * 2017-07-13 2017-09-19 宿松县罗汉宕农林开发有限公司 A kind of Tea planting waterproof plastic mulch film
CN107364206A (en) * 2017-06-22 2017-11-21 芜湖蓝天工程塑胶有限公司 Antibacterial paper and plastics compound bag of high intensity and preparation method thereof
CN108864521A (en) * 2018-04-14 2018-11-23 福建省大投科技有限公司 A kind of high filled polyolefin fibrous paper of inorganic particle and manufacturing method
CN109989292A (en) * 2019-03-01 2019-07-09 徐扣华 A kind of preparation method of starch base sticking agent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101451004A (en) * 2008-12-26 2009-06-10 大连塑料研究所有限公司 Film for producing composite paper-like film and paper-like film and method for producing the same
CN105035493A (en) * 2015-05-29 2015-11-11 铜陵方正塑业科技有限公司 Stretch-resisting paper-plastic compound bag and preparation method thereof
CN106012668A (en) * 2016-06-17 2016-10-12 铜陵方正塑业科技有限公司 Abrasion-resistant paper-plastic composite bag and preparation method thereof
CN107364206A (en) * 2017-06-22 2017-11-21 芜湖蓝天工程塑胶有限公司 Antibacterial paper and plastics compound bag of high intensity and preparation method thereof
CN107177102A (en) * 2017-07-13 2017-09-19 宿松县罗汉宕农林开发有限公司 A kind of Tea planting waterproof plastic mulch film
CN108864521A (en) * 2018-04-14 2018-11-23 福建省大投科技有限公司 A kind of high filled polyolefin fibrous paper of inorganic particle and manufacturing method
CN109989292A (en) * 2019-03-01 2019-07-09 徐扣华 A kind of preparation method of starch base sticking agent

Similar Documents

Publication Publication Date Title
CA1236394A (en) Process for the preparation of insect repelling/killing film
US5306550A (en) Biodegradable composition and shaped article obtained therefrom
CN101001919B (en) Antimicrobial and antistatic polymers and methods of using such polymers on various substrates
US6281298B1 (en) Water-based pressure sensitive adhesives having enhanced characteristics
AU617812B2 (en) Phosphate ester biocide with protein/inorganic carrier
WO1995012602A1 (en) Antibacterial, antifungal and antiviral agent
US5861470A (en) Two component water-based adhesives for use in dry-bond laminating
JPH03134033A (en) Production of antifungal polyolefin resin molding
US3876452A (en) Articles coated with hydralyzed copolymer of ethylene and alkyl acrylate
CN104803638A (en) Inorganic dry powder mildew-proof texture coating material and production method thereof
CN109577100B (en) Photooxygenically degradable polyethylene coated paper and preparation method and application thereof
CN108299711A (en) A kind of anti-bacterial packaging film and processing method
CN103946449A (en) Use of dispersions based on polyvinyl acetate as a barrier layer
CN100443297C (en) Method of detackifying an edge face of a roll of tape
CN109517275A (en) A kind of paper plastic combined package bag material and preparation method thereof
GB2246355A (en) Biodegradable composition,shaped article obtained therefrom and method of producing biodegradable material
CN111517873A (en) Controlled-release fertilizer coating agent and preparation method thereof, controlled-release fertilizer and application thereof
WO1992018173A1 (en) Medical tubing
EP0132078A3 (en) Coating or moulding compositions
CN115819821A (en) Heat-resistant environment-friendly plastic woven bag and preparation process thereof
CN107815270A (en) A kind of corrugated case making Aqueous Adhesives and preparation method thereof
CN109535524A (en) A kind of highstrenghtpiston packs inner bag material and preparation method thereof
US3595828A (en) 3-phenyl - 2 - propen-1-ones and 3-phenyl-1-propanones as biostats in plastics,paints and textiles
KR102659000B1 (en) Inorganic material-based composition for paper coating with excellent insulation and water resistance and paper coating method using the same
CN109021383A (en) A kind of anti-slip, antistatic environmentally-friendly plastic woven bag composition of raw materials

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190326