CN109505114A - A kind of high-activity nano antibacterial functions fabric - Google Patents

A kind of high-activity nano antibacterial functions fabric Download PDF

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Publication number
CN109505114A
CN109505114A CN201811379347.6A CN201811379347A CN109505114A CN 109505114 A CN109505114 A CN 109505114A CN 201811379347 A CN201811379347 A CN 201811379347A CN 109505114 A CN109505114 A CN 109505114A
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CN
China
Prior art keywords
nano
fabric
nanometer
antibacterial functions
activity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811379347.6A
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Chinese (zh)
Inventor
刘云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yiwu Meng Zi Ge Clothing Co Ltd
Original Assignee
Yiwu Meng Zi Ge Clothing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yiwu Meng Zi Ge Clothing Co Ltd filed Critical Yiwu Meng Zi Ge Clothing Co Ltd
Priority to CN201811379347.6A priority Critical patent/CN109505114A/en
Publication of CN109505114A publication Critical patent/CN109505114A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12Threads containing metallic filaments or strips
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/08Ramie

Abstract

The invention discloses a kind of high-activity nano antibacterial functions fabrics, including common fabric matrix and nanometer antibacterium coating, the nanometer antibacterium coating to be made of the raw material of following weight percent: 10 ~ 20% nano-titanium dioxides;1 ~ 5% nano zine oxide;1 ~ 5% nano silicon-based oxide;Remainder is thermosol.The present invention uses the nanometer antibacterial function fabric of photocatalysis antibacterial agent preparation, nanometer antibacterium coating formula is reasonable, lower production costs, prepared functional fabric not only has anti-microbial property definite, and dyeing ability is good, test indicate that the antibiotic rate of fabric of the invention after 40 washings for 24 hours reaches 90.0% or more.

Description

A kind of high-activity nano antibacterial functions fabric
Technical field
The invention belongs to functional fabric fields, are related to a kind of antibacterial functions fabric, and in particular to a kind of high-activity nano is anti- Bacterium functional fabric.
Background technique
With the improvement of the quality of life, more and more people recognize the importance of health, therefore people want clothes Ask also higher and higher, for example clothes carry antibacterial action, and the purpose of antibacterial is exactly to have fabric to kill or inhibit to cause The function of germ, and prevent microorganism from propagating by textile, protect a user from the infringement of microorganism.
According to the difference of sterilization mechanism, antibacterial agent can be divided into following three types: first is that inorganic antiseptic, such as: Ag, Cu、Zn、S、As、Ag+、Cu2+Deng;Second is that photocatalysis antibacterial agent, such as: nano-TiO2, nano silicon-based oxide etc.;Third is that with light Catalytic antimicrobial agent is carrier, by its Adsorption For Ag, copper plasma.Nano-antibacterial technology is extremely wide in the application field of textile industry It is general, various types of antibacterial functions textiles, such as underwear, towel, sheet, kitchen article can be developed, hotel, doctor are applied to The various industries such as institute, army, factory, meet people's health requirement.
Since nano silver has excellent antibacterial characteristics, especially superfine nano silver powder, current nano silver textile fabric By people favor, by simple and environmentally-friendly method by nano silver be applied to textile fabric surface as textile fabric function it is whole The hot spot for managing research, as photocatalysis antibacterial agent in textile fabric using rare registration.
Summary of the invention
The technical problem to be solved by the present invention is for the difference of anti-microbial property existing for existing antibacterial functions fabric and when maintaining Between short equal series of problems, provide it is a kind of not only have anti-microbial property definite, but also the antibacterial functions fabric that dyeing ability is good.
The technical solution adopted in the present invention is as follows:
A kind of high-activity nano antibacterial functions fabric, including common fabric matrix and nanometer antibacterium coating, the nano-antibacterial apply Layer is made of the raw material of following weight percent:
10 ~ 20% nano-titanium dioxides;
1 ~ 5% nano zine oxide;
1 ~ 5% nano silicon-based oxide;
Remainder is thermosol.
On the basis of above scheme, the diameter of above-mentioned nano-titanium dioxide, nano zine oxide and nano silicon-based oxide Preferably 2 ~ 10nm.
Further, above-mentioned nanometer antibacterium coating is preferably made of the raw material of following weight percent:
15% nano-titanium dioxide;
3% nano zine oxide;
3% nano silicon-based oxide;
Remainder is thermosol.
Further, the weft yarn of above-mentioned common fabric matrix is the mixed of stainless steel fibre, ramee and cotton fiber Spinning, the percentage composition of the stainless steel fibre, carbon fiber and cotton fiber are preferably respectively 5%, 25% and 70%.
What above-mentioned nanometer antibacterium coating was prepared as follows: by nano-titanium dioxide, nano zine oxide and nano-silicon Base oxide is put into a centrifuge, and after being centrifuged with 18000 ~ 20000rpm, is melted at 60 ~ 80 DEG C, and it is anti-that nanometer is made Bacterium coating.
Compared with prior art, the device have the advantages that it is as follows:
The present invention uses the nanometer antibacterial function fabric of photocatalysis antibacterial agent preparation, and nanometer antibacterium coating formula rationally, is produced into This is lower, and prepared functional fabric not only has anti-microbial property definite, but also dyeing ability is good, test indicate that, the present invention Antibacterial functions fabric after 40 washings antibiotic rate for 24 hours reach 90.0% or more, show to have that anti-microbial property is strong, maintenance The advantage of time length.
Specific embodiment
Of the invention for ease of understanding, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation Example is used only for helping to understand the present invention, should not be regarded as a specific limitation of the invention.
Unless specific instructions, various raw materials of the invention can be by being commercially available;Or the routine side according to this field Method is prepared.Unless otherwise defined or described herein, all professional and scientific terms and art technology used herein are ripe It is identical to practice meaning known to the person of entering.Furthermore any method similar to or equal to what is recorded and material all can be applied to this In inventive method.Unless otherwise stated, all professional and scientific terms and those skilled in the art used herein Known meaning is identical.
Embodiment 1
A kind of high-activity nano antibacterial functions fabric, including common fabric matrix and nanometer antibacterium coating, the common fabric base The weft yarn of body is the mixed yarn of stainless steel fibre, ramee and cotton fiber, and percentage composition is respectively 5%, 25% and 70%;
The nanometer antibacterium coating is made of the raw material of following weight percent:
15% nano-titanium dioxide of 5nm;3% nano zine oxide of 5nm;3% nano silicon-based oxide of 5nm;Remainder is heat When preparation, nano-titanium dioxide, nano zine oxide and nano silicon-based oxide are put into a centrifuge for colloidal sol, with 18000 ~ It after 20000rpm is centrifuged, is melted at 70 DEG C, and nanometer antibacterium coating is made.
By functional fabric prepared by the present embodiment, the antibiotic rate after 40 washings for 24 hours reaches 93.0%, shows this reality The anti-microbial property for applying the functional fabric of example is strong, length of holding time.
Embodiment 2
A kind of high-activity nano antibacterial functions fabric, including common fabric matrix and nanometer antibacterium coating, the common fabric base The weft yarn of body is the mixed yarn of stainless steel fibre, ramee and cotton fiber, and percentage composition is respectively 5%, 25% and 70%;
The nanometer antibacterium coating is made of the raw material of following weight percent:
10% nano-titanium dioxide of 5nm;2% nano zine oxide of 5nm;2% nano silicon-based oxide of 5nm;Remainder is heat When preparation, nano-titanium dioxide, nano zine oxide and nano silicon-based oxide are put into a centrifuge for colloidal sol, with 18000 ~ It after 20000rpm is centrifuged, is melted at 70 DEG C, and nanometer antibacterium coating is made.
By functional fabric prepared by the present embodiment, the antibiotic rate after 40 washings for 24 hours reaches 90.5%, shows this reality The anti-microbial property for applying the functional fabric of example is strong, length of holding time.
Embodiment 3
A kind of high-activity nano antibacterial functions fabric, including common fabric matrix and nanometer antibacterium coating, the common fabric base The weft yarn of body is the mixed yarn of stainless steel fibre, ramee and cotton fiber, and percentage composition is respectively 5%, 25% and 70%;
The nanometer antibacterium coating is made of the raw material of following weight percent:
20% nano-titanium dioxide of 5nm;5% nano zine oxide of 5nm;5% nano silicon-based oxide of 5nm;Remainder is heat When preparation, nano-titanium dioxide, nano zine oxide and nano silicon-based oxide are put into a centrifuge for colloidal sol, with 18000 ~ It after 20000rpm is centrifuged, is melted at 70 DEG C, and nanometer antibacterium coating is made.
By functional fabric prepared by the present embodiment, the antibiotic rate after 40 washings for 24 hours reaches 91.0%, shows this reality The anti-microbial property for applying the functional fabric of example is strong, length of holding time.
Although the detailed description and description of the specific embodiments of the present invention are given above, it should be noted that We can carry out various equivalent changes and modification to above embodiment according to the concept of the present invention, and generated function is made It, should all be within protection scope of the present invention when with the spirit still covered without departing from specification.

Claims (5)

1. a kind of high-activity nano antibacterial functions fabric, including common fabric matrix and nanometer antibacterium coating, which is characterized in that institute Nanometer antibacterium coating is stated to be made of the raw material of following weight percent:
10 ~ 20% nano-titanium dioxides;
1 ~ 5% nano zine oxide;
1 ~ 5% nano silicon-based oxide;
Remainder is thermosol.
2. a kind of high-activity nano antibacterial functions fabric as described in claim 1, which is characterized in that the nanometer titanium dioxide The diameter of titanium, nano zine oxide and nano silicon-based oxide is 2 ~ 10nm.
3. a kind of high-activity nano antibacterial functions fabric as described in claim 1, which is characterized in that the nanometer antibacterium coating It is made of the raw material of following weight percent:
15% nano-titanium dioxide;
3% nano zine oxide;
3% nano silicon-based oxide;
Remainder is thermosol.
4. a kind of high-activity nano antibacterial functions fabric as described in claim 1, which is characterized in that the common fabric base The weft yarn of body is the mixed yarn of stainless steel fibre, ramee and cotton fiber, the stainless steel fibre, carbon fiber and cotton fiber Percentage composition be respectively 5%, 25% and 70%.
5. a kind of high-activity nano antibacterial functions fabric as described in claim 1, which is characterized in that the nano-antibacterial applies What layer was prepared as follows: nano-titanium dioxide, nano zine oxide and nano silicon-based oxide are put into a centrifuge, with It after 18000 ~ 20000rpm is centrifuged, is melted at 60 ~ 80 DEG C, and nanometer antibacterium coating is made.
CN201811379347.6A 2018-11-19 2018-11-19 A kind of high-activity nano antibacterial functions fabric Pending CN109505114A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811379347.6A CN109505114A (en) 2018-11-19 2018-11-19 A kind of high-activity nano antibacterial functions fabric

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Application Number Priority Date Filing Date Title
CN201811379347.6A CN109505114A (en) 2018-11-19 2018-11-19 A kind of high-activity nano antibacterial functions fabric

Publications (1)

Publication Number Publication Date
CN109505114A true CN109505114A (en) 2019-03-22

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114541150A (en) * 2022-04-15 2022-05-27 南通摩登服装有限公司 Antibacterial textile composite fabric and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1184498A (en) * 1995-03-20 1998-06-10 东陶机器株式会社 Method of photocatalytically making the surface of base material ultrahydrophilic, base material having ultrahydraphilic and photocatalytic surface, and process for producing said material
CN2709487Y (en) * 2003-11-28 2005-07-13 王明正 Fabric with dispelling on surface water and water absorption water on bottom function
CN1837299A (en) * 2005-03-21 2006-09-27 刘景春 Method for preparing nano-structural film with straggling effect for multiple substances and use thereof
CN107237130A (en) * 2017-06-28 2017-10-10 太仓红桥服饰有限公司 A kind of environmentally friendly wool fabric yarn slurry and slashing technique

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1184498A (en) * 1995-03-20 1998-06-10 东陶机器株式会社 Method of photocatalytically making the surface of base material ultrahydrophilic, base material having ultrahydraphilic and photocatalytic surface, and process for producing said material
CN2709487Y (en) * 2003-11-28 2005-07-13 王明正 Fabric with dispelling on surface water and water absorption water on bottom function
CN1837299A (en) * 2005-03-21 2006-09-27 刘景春 Method for preparing nano-structural film with straggling effect for multiple substances and use thereof
CN107237130A (en) * 2017-06-28 2017-10-10 太仓红桥服饰有限公司 A kind of environmentally friendly wool fabric yarn slurry and slashing technique

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114541150A (en) * 2022-04-15 2022-05-27 南通摩登服装有限公司 Antibacterial textile composite fabric and preparation process thereof

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Application publication date: 20190322