CN109504822A - RH refining rotary powder injection device and deoxidation method - Google Patents

RH refining rotary powder injection device and deoxidation method Download PDF

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Publication number
CN109504822A
CN109504822A CN201811480909.6A CN201811480909A CN109504822A CN 109504822 A CN109504822 A CN 109504822A CN 201811480909 A CN201811480909 A CN 201811480909A CN 109504822 A CN109504822 A CN 109504822A
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China
Prior art keywords
injecting powder
rotating
rotating injecting
rifle
vacuum chamber
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CN201811480909.6A
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Chinese (zh)
Inventor
赵亮
廖相巍
张晓光
丁丽华
曹祥
万雪峰
曹东
田勇
孙群
康伟
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Angang Steel Co Ltd
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Angang Steel Co Ltd
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Priority to CN201811480909.6A priority Critical patent/CN109504822A/en
Publication of CN109504822A publication Critical patent/CN109504822A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0037Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a RH refining rotary powder spraying device and a deoxidation method, 1) a rotary powder spraying gun is inserted 400-650mm below the liquid level of molten steel, and rotary powder spraying is started; 2) the rotating speed of the rotary powder gun is 180-230 r/min; the carrier gas flow of the rotary powder spraying device is 30-90Nm3The carrier gas pressure is 0.8-1.2MPa, the powder spraying rate is 0.1-4.5kg/s, and the carrier gas is Ar gas; 3) the blowing time is 10-20min, after blowing, the powder gun is rotated to lift the liquid level of the molten steel, the rotating speed is reduced to be below 5-10r/min, the liquid level of the molten steel is lifted by 300-500mm, the rotation is accelerated for 10-30s again, and the rotating speed is 50-80 r/min.

Description

A kind of RH refining rotating injecting powder device and method of deoxidation
Technical field
The invention belongs to field of steel metallurgy, in particular to a kind of RH refining rotating injecting powder device and method of deoxidation.
Background technique
Currently, RH vacuum chamber injection technology, Refining powders high-pressure rotary is sprayed into vacuum chamber molten bath, Refining powders and molten Chemical element reacts in pond, while generating tiny microbubble and will capture in molten bath there are field trash and floating, and can play net Change the effect that molten steel removes harmful element in steel simultaneously.
Notification number CN101323895B proposes a kind of process for removing impurity from molten steel, and this method passes through Pulvis will be prepared to spray into molten steel, played using element reaction generation micro-bubble in pulvis and molten steel and remove field trash in molten steel Purpose, this method is applied to the techniques such as LF, RH, VD.But after this method is only applied to the refinery practices such as LF, RH, VD, by pulvis Spray into ladle in, conveying gas pressure be 0.01~1.5MPa, belong to the blowing process of normal pressures, although this method using Blowing process, but spray into ladle by normal pressures, pulvis in molten steel as bubble diffuses to surface, in pulvis and molten steel Element generation chemical reaction probability is extremely low, and most pulvis can be diffused into air with bubble, therefore pulvis utilization rate is extremely low.
Notification number CN101440422A proposes a kind of RH vacuum refining top gun powder spraying device and top gun powder spraying method, this method By adjusting top gun position, powder-trace method is improved, production efficiency is improved, saves production cost.But this method passes through top gun By in pulvis blowing to vacuum chamber liquid level, pulvis with the indoor molten steel of vacuum there is no contacting, and element occurs in pulvis and molten steel Chemical reaction probability is extremely low, and most pulvis can be diffused into air, therefore pulvis utilization rate is extremely low, and ideal refining effect is not achieved Fruit.
Notification number CN201210269403.7 proposes a kind of deoxidation modification agent of molten steel, ingredient Al2O3、Al、CaCO3、 NaCO3、BaCO3Composition mixtures are waited, wherein CaCO3Ratio be greater than 60%, this method is by deoxidier during liquid steel refining It puts into ladle, generates valuable gases and fine dispersion particle in molten steel using mixture, promote the quick deoxidation of molten steel.But it should Directly deoxidier is added in molten steel for method, poor for the dynamic conditions control of deoxygenation, and deoxidation pulvis is in molten steel It is inside not easy to spread, so that the utilization rate of pulvis is lower, production cost is higher.
Summary of the invention
For the defect of currently available technology, technical problem to be solved by the invention is to provide a kind of RH to refine rotation spray Powder device and method of deoxidation.
Object of the present invention is to what is realized by following technical solution:
A kind of RH refining rotating injecting powder device, including vacuum chamber, tedge and down-comer with vacuum chamber, tedge Gas source conveyance conduit is promoted equipped with RH, it is characterised in that: it further include rotating injecting powder rifle, the top of the rotating injecting powder rifle and rotation Rotating motor connection, rotating electric machine drive the rotation of rotating injecting powder rifle, rotary joint are equipped with above rotating electric machine, and rotary joint connection is defeated High-pressure air source is delivered to feed bin by feeding storehouse, conveyance conduit, and the filling of Refining powders is completed by conveying feed bin;The rotation Podwer gun connection driving lifting device;The body of a gun of the rotary spray gun is hollow tube, and pipette tips are that inverted T-shaped swivel head is inserted into very Below the liquid steel level and top of down-comer in empty room;It is equipped with injection hole in the two sides of inverted T-shaped swivel head, is used for RH vacuum chamber Spray refining pulvis inside molten steel, the entire rotating injecting powder rifle body of a gun and inverted T-shaped swivel head wrap up refractory material.
The rotating injecting powder rifle rifle total length is 2500-4500mm, inverted T-shaped swivel head length 500-800mm, inverted T-shaped Swivel head diameter is 200-400mm, and blowing bore dia is 6-15mm, and hollow pipe diameter is 80-150mm.
The vacuum chamber diameter is 1500-2500mm, vacuum chamber height 4500-5500mm, rises pipe diameter 500- 800mm, decline pipe diameter are identical as pipe diameter is risen.
Lift gas injection hole is arranged away from the vacuum chamber bottom position 600-900mm in the tedge, and blowing hole number is 8-12, lift gas is argon gas.
Described to dust for deoxidation pulvis, ingredient is Al by weight percentage2O310-35%, Al20-30%, CaCO330-50%, the granularity of deoxidier are 0.06-0.08mm.
A kind of method of deoxidation using RH refining rotating injecting powder device, it is characterised in that include the following steps:
1) 400-650mm under rotating injecting powder rifle insertion liquid steel level, starts rotating injecting powder;2) revolving speed of rotating injecting powder rifle is 180-230r/min;The carrier gas flux 30-90Nm of the rotating injecting powder device3/ h, nebulizer gas pressure 0.8-1.2MPa, dusts Rate is 0.1-4.5kg/s, the use of carrier gas is Ar gas;3) the blowing time is 10-20min, and rotating injecting powder rifle mentions after blowing Liquid steel level out, revolving speed drop to 5-10r/min hereinafter, proposing the above 300-500mm of liquid steel level, spin up 10- again 30s, revolution 50-80r/min.
RH Refining powders can be delivered to inside the molten steel of RH vacuum chamber by the present invention, when working along with RH in vacuum chamber Molten steel circulates, and rotating injecting powder device, which rotates pulvis, to be sprayed into molten steel, and pulvis is sufficiently spread inside molten steel and and steel Element in liquid chemically reacts, and concurrently injected pulvis is integrally recycled by molten steel, is brought into and participates in following inside ladle The molten steel circulatory function of RH itself is utilized in ring concurrently biochemical reaction, the present apparatus, and pulvis is fully used.It is rotated in pulvis Spray into vacuum chamber molten steel during, Refining powders with microbubble by the collective effect of centrifugal force and buoyancy, along helix It is floated to liquid level, under the action of the centrifugal force, bubble makes the better disperse of Refining powders point to pulvis emission direction regional movement Cloth, while forming vortex in molten steel and slowly rising, to increase residence time of the refining solvent in molten steel, improve steel The dynamic conditions that reaction carries out in liquid promotes Al in molten steel2O3It is mingled with and collides, assembles and grow up with fine particle, the gas of disperse It steeps and sufficiently floats with field trash, improve the degree of purity of molten steel and the utilization rate of Refining powders.It can be refined in RH real in production Existing deoxidation operation, to achieve the purpose that cleaning molten steel.
Detailed description of the invention
Fig. 1 is RH refining rotating injecting powder schematic device;
Wherein, 1. conveyance conduit;2. conveying feed bin;3. rotating electric machine;4. vacuum chamber;5. rotating injecting powder rifle;6.RH is promoted Gas source conveyance conduit;7. ladle;8 tedges;9 down-comers;10 rotary joints.
Specific embodiment
It is illustrated combined with specific embodiments below:
Embodiment 1
Embodiment carries out on 180t ladle, for producing carbon aluminium-killed steel, implements the converter tapping temperature of steel grade Degree is 1630 DEG C, phosphorus content 0.06%.
Ladle back cut diameter 3130mm, base diameter 2560mm, internal height 4300mm.Vacuum chamber diameter is 1780mm, vacuum chamber height 6800mm, rise pipe diameter 590mm, and decline pipe diameter is identical as pipe diameter is risen.Lift gas spray For aperture blowing away from vacuum chamber bottom 580mm, being blown hole number is 10.
Rotating injecting powder rifle rifle total length is 7500mm, and inverted T-shaped swivel head length 580mm, stirring-head diameter is 230mm, spray Aperture blowing diameter is 6mm, and hollow pipe diameter is 90mm.
The main component of the deoxidation pulvis used includes Al2O328%, Al22%, CaCO345%.The granularity of deoxidier is 0.07mm。
Deoxygenation step using the liquid steel refining rotary blowing of the device is as follows: 1) RH purifier work after, vacuum chamber Interior molten steel liquid level reaches 1210mm, and rotating injecting powder rifle is connected to work order and is begun to decline by standby position, is inserted under liquid steel level 520mm starts rotating injecting powder.2) revolving speed of the rotating injecting powder rifle described in is set as 185r/min.3) the rotating injecting powder dress described in The carrier gas flux 60Nm set3/ h, nebulizer gas pressure 1.0MPa, rate of dusting are 3.5kg/s, the use of carrier gas are Ar gas.4) described Blowing time of rotating injecting powder device be 12min, rotating injecting powder rifle proposes liquid steel level after blowing, and revolving speed drops to 10r/ Min spins up 20s, revolution 50r/min hereinafter, the proposition above 300mm of liquid steel level again.
Implementing activity oxygen content before steel grade refines is 0.032%, the total oxygen content after the processing of rotary blowing deoxidation step It is 0.0016%, temperature drop is 22 DEG C, and deoxidation effect is obvious.
Embodiment 2
Embodiment carries out on 180t ladle, for producing carbon aluminium-killed steel, implements the converter tapping temperature of steel grade Degree is 1640 DEG C, phosphorus content 0.07%.
Ladle back cut diameter 3120mm, base diameter 2560mm, internal height 4300mm.Vacuum chamber diameter is 1780mm, vacuum chamber height 6850mm, rise pipe diameter 580mm, and decline pipe diameter is identical as pipe diameter is risen.Lift gas spray For aperture blowing away from vacuum chamber bottom 600mm, being blown hole number is 12.
Rotating injecting powder rifle rifle total length is 7120mm, and inverted T-shaped swivel head length 580mm, stirring-head diameter is 230mm, spray Aperture blowing diameter is 7mm, and hollow pipe diameter is 90mm.
The main component of the deoxidation pulvis used includes Al2O323%, Al28%, CaCO346%.The granularity of deoxidier is 0.07mm。
Deoxygenation step using the liquid steel refining rotary blowing of the device is as follows: 1) RH purifier work after, vacuum chamber Interior molten steel liquid level reaches 1200mm, and rotating injecting powder rifle is connected to work order and is begun to decline by standby position, is inserted under liquid steel level 520mm starts rotating injecting powder.2) revolving speed of the rotating injecting powder rifle described in is set as 190r/min.3) the rotating injecting powder dress described in The carrier gas flux 60Nm set3/ h, nebulizer gas pressure 1.5MPa, rate of dusting are 3.3kg/s, the use of carrier gas are Ar gas.4) described Blowing time of rotating injecting powder device be 13min, rotating injecting powder rifle proposes liquid steel level after blowing, and revolving speed drops to 10r/ Min spins up 20s, revolution 50r/min hereinafter, the proposition above 300mm of liquid steel level again.
Implementing activity oxygen content before steel grade refines is 0.038%, the total oxygen content after the processing of rotary blowing deoxidation step It is 0.0014%, temperature drop is 22 DEG C.
Embodiment 3
Embodiment carries out on 180t ladle, for producing carbon aluminium-killed steel, implements the converter tapping temperature of steel grade Degree is 1638 DEG C, phosphorus content 0.07%.
Ladle back cut diameter 3140mm, base diameter 2580mm, internal height 4300mm.Vacuum chamber diameter is 1780mm, vacuum chamber height 7100mm, rise pipe diameter 580mm, and decline pipe diameter is identical as pipe diameter is risen.Lift gas spray For aperture blowing away from vacuum chamber bottom 600mm, being blown hole number is 12.
Rotating injecting powder rifle rifle total length is 7800mm, and inverted T-shaped swivel head length 580mm, stirring-head diameter is 230mm, spray Aperture blowing diameter is 6mm, and hollow pipe diameter is 90mm.
The main component of the deoxidation pulvis used includes Al2O328%, Al26%, CaCO344%.The granularity of deoxidier is 0.075mm。
Deoxygenation step using the liquid steel refining rotary blowing of the device is as follows: 1) RH purifier work after, vacuum chamber Interior molten steel liquid level reaches 1200mm, and rotating injecting powder rifle is connected to work order and is begun to decline by standby position, is inserted under liquid steel level 520mm starts rotating injecting powder.2) revolving speed of the rotating injecting powder rifle described in is set as 195r/min.3) the rotating injecting powder dress described in The carrier gas flux 70Nm set3/ h, nebulizer gas pressure 1.1MPa, rate of dusting are 3.4kg/s, the use of carrier gas are Ar gas.4) described Blowing time of rotating injecting powder device be 13min, rotating injecting powder rifle proposes liquid steel level after blowing, and revolving speed drops to 10r/ Min spins up 20s, revolution 50r/min hereinafter, the proposition above 300mm of liquid steel level again.
Implementing activity oxygen content before steel grade refines is 0.041%, the total oxygen content after the processing of rotary blowing deoxidation step It is 0.0017%, temperature drop is 24 DEG C.
Embodiment 4
Embodiment carries out on 180t ladle, for producing carbon aluminium-killed steel, implements the converter tapping temperature of steel grade Degree is 1646 DEG C, phosphorus content 0.06%.
Ladle back cut diameter 3160mm, base diameter 2580mm, internal height 4300mm.Vacuum chamber diameter is 1780mm, vacuum chamber height 6900mm, rise pipe diameter 600mm, and decline pipe diameter is identical as pipe diameter is risen.Lift gas spray For aperture blowing away from vacuum chamber bottom 610mm, being blown hole number is 12.
Rotating injecting powder rifle rifle total length is 7510mm, and inverted T-shaped swivel head length 580mm, stirring-head diameter is 230mm, spray Aperture blowing diameter is 8mm, and hollow pipe diameter is 90mm.
The main component of the deoxidation pulvis used includes Al2O332%, Al24%, CaCO342%.The granularity of deoxidier is 0.08mm。
Deoxygenation step using the liquid steel refining rotary blowing of the device is as follows: 1) RH purifier work after, vacuum chamber Interior molten steel liquid level reaches 1200mm, and rotating injecting powder rifle is connected to work order and is begun to decline by standby position, is inserted under liquid steel level 520mm starts rotating injecting powder.2) revolving speed of the rotating injecting powder rifle described in is set as 210r/min.3) the rotating injecting powder dress described in The carrier gas flux 70Nm set3/ h, nebulizer gas pressure 1.1MPa, rate of dusting are 3.5kg/s, the use of carrier gas are Ar gas.4) described Blowing time of rotating injecting powder device be 15min, rotating injecting powder rifle proposes liquid steel level after blowing, and revolving speed drops to 10r/ Min spins up 20s, revolution 50r/min hereinafter, the proposition above 300mm of liquid steel level again.
Implementing activity oxygen content before steel grade refines is 0.046%, the total oxygen content after the processing of rotary blowing deoxidation step It is 0.0018%, temperature drop is 26 DEG C.
Comparative example
Carbon aluminium-killed steel is produced using the fixed top gun of RH-KTB vacuum chamber on 180t ladle, implements the converter of steel grade Tapping temperature is 1635 DEG C, phosphorus content 0.06%, and activity oxygen content is 0.042%, and fixed top gun is away from liquid level in vacuum chamber 500mm is blown deoxidier, carrier gas flux 20Nm using carrier gas3/ h, nebulizer gas pressure 1.1MPa, carrier gas Ar.The deoxidation used The main component of pulvis is Al2O332%, Al24%, CaCO342% etc..The granularity of deoxidier is 0.07mm, throughput 70Nm3/ H, nebulizer gas pressure 1.1MPa, rate of dusting are 5.5kg/s, and the processing time is 20min.
Implementing activity oxygen content before steel grade refines is 0.047%, and total oxygen content is 0.0035% after blowing processing, and temperature drop is 30℃。
Liquid steel refining deoxidation is carried out using the method for the present invention, improves the dynamic conditions of deoxidation in molten steel, promotes molten steel Middle Al2O3It is mingled with and collides, assembles and grow up with other fine particles, the bubble of disperse sufficiently floats with field trash, with conventional essence Refining blowing deoxidier is compared, and after treatment total oxygen content reduces by 30%, improves the degree of purity of molten steel, and the processing time shortens 25%, pulvis utilization rate improves 35%.

Claims (6)

1. a kind of RH refines rotating injecting powder device, including vacuum chamber, tedge and down-comer with vacuum chamber, tedge are set There is RH to promote gas source conveyance conduit, it is characterised in that: it further include rotating injecting powder rifle, the top of the rotating injecting powder rifle and rotation Motor connection, rotating electric machine drive the rotation of rotating injecting powder rifle, and rotary joint, rotary joint connection conveying are equipped with above rotating electric machine High-pressure air source is delivered to feed bin by feed bin, conveyance conduit, and the filling of Refining powders is completed by conveying feed bin;The rotation spray Powder rifle connection driving lifting device;The body of a gun of the rotary spray gun is hollow tube, and pipette tips are that inverted T-shaped swivel head is inserted into vacuum Below the indoor liquid steel level and top of down-comer;It is equipped with injection hole in the two sides of inverted T-shaped swivel head, is used for RH vacuum chamber steel Spray refining pulvis inside liquid, the entire rotating injecting powder rifle body of a gun and inverted T-shaped swivel head wrap up refractory material.
2. a kind of RH according to claim 1 refines rotating injecting powder device, it is characterised in that: the rotating injecting powder rifle rifle Total length is 2500-4500mm, and inverted T-shaped swivel head length 500-800mm, inverted T-shaped swivel head diameter is 200-400mm, blowing Bore dia is 6-15mm, and hollow pipe diameter is 80-150mm.
3. a kind of RH according to claim 1 refines rotating injecting powder device, it is characterised in that: the vacuum chamber diameter is 1500-2500mm, vacuum chamber height 4500-5500mm rise pipe diameter 500-800mm, decline pipe diameter and rising pipe diameter It is identical.
4. a kind of RH according to claim 1 refines rotating injecting powder device, it is characterised in that: the tedge is away from vacuum Lift gas injection hole is arranged in the room bottom position 600-900mm, and blowing hole number is 8-12, and lift gas is argon gas.
5. a kind of RH according to claim 1 refines rotating injecting powder device, it is characterised in that: described dusts for deoxidation powder Agent, ingredient are Al by weight percentage2O310-35%, Al20-30%, CaCO330-50%, the granularity of deoxidier are 0.06- 0.08mm。
6. a kind of method of deoxidation using RH refining rotating injecting powder device described in claim 1, it is characterised in that including as follows Step:
1) 400-650mm under rotating injecting powder rifle insertion liquid steel level, starts rotating injecting powder;2) revolving speed of rotating injecting powder rifle is 180- 230r/min;The carrier gas flux 30-90Nm of the rotating injecting powder device3/ h, nebulizer gas pressure 0.8-1.2MPa, rate of dusting It the use of carrier gas is Ar gas for 0.1-4.5kg/s;3) the blowing time is 10-20min, and rotating injecting powder rifle proposes steel after blowing Water level, revolving speed drop to 5-10r/min hereinafter, proposing the above 300-500mm of liquid steel level, spin up 10-30s again, turn Number is 50-80r/min.
CN201811480909.6A 2018-12-05 2018-12-05 RH refining rotary powder injection device and deoxidation method Pending CN109504822A (en)

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Application Number Priority Date Filing Date Title
CN201811480909.6A CN109504822A (en) 2018-12-05 2018-12-05 RH refining rotary powder injection device and deoxidation method

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CN109504822A true CN109504822A (en) 2019-03-22

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101440422A (en) * 2008-12-22 2009-05-27 辽宁科技学院 Top lance power injection apparatus and method for RH vacuum refining
CN107299192A (en) * 2017-04-24 2017-10-27 鞍钢股份有限公司 Refining rotary blowing deoxidation device and deoxidation method
JP2018109213A (en) * 2017-01-05 2018-07-12 新日鐵住金株式会社 Method and apparatus for desulfurizing molten steel
CN209555296U (en) * 2018-12-05 2019-10-29 鞍钢股份有限公司 RH refining rotary powder spraying device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101440422A (en) * 2008-12-22 2009-05-27 辽宁科技学院 Top lance power injection apparatus and method for RH vacuum refining
JP2018109213A (en) * 2017-01-05 2018-07-12 新日鐵住金株式会社 Method and apparatus for desulfurizing molten steel
CN107299192A (en) * 2017-04-24 2017-10-27 鞍钢股份有限公司 Refining rotary blowing deoxidation device and deoxidation method
CN209555296U (en) * 2018-12-05 2019-10-29 鞍钢股份有限公司 RH refining rotary powder spraying device

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