CN109504559A - A kind of photovoltaic module cleaning agent and its preparation method and application - Google Patents
A kind of photovoltaic module cleaning agent and its preparation method and application Download PDFInfo
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- CN109504559A CN109504559A CN201811594421.6A CN201811594421A CN109504559A CN 109504559 A CN109504559 A CN 109504559A CN 201811594421 A CN201811594421 A CN 201811594421A CN 109504559 A CN109504559 A CN 109504559A
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- parts
- adjuvant
- photovoltaic module
- cleaning agent
- agent
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 68
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000002671 adjuvant Substances 0.000 claims abstract description 113
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 82
- 239000000203 mixture Substances 0.000 claims abstract description 67
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 59
- 238000004140 cleaning Methods 0.000 claims abstract description 35
- 239000003292 glue Substances 0.000 claims abstract description 34
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims abstract description 31
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 60
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical group CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 54
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 49
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 claims description 46
- PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 claims description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 22
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 16
- 235000019441 ethanol Nutrition 0.000 claims description 11
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 4
- 239000002798 polar solvent Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 14
- 230000032258 transport Effects 0.000 abstract description 5
- 230000009972 noncorrosive effect Effects 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 28
- 238000000034 method Methods 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- -1 dimethyl butyrate Chemical compound 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- ZNEMGFATAVGQSF-UHFFFAOYSA-N 1-(2-amino-6,7-dihydro-4H-[1,3]thiazolo[4,5-c]pyridin-5-yl)-2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound NC=1SC2=C(CN(CC2)C(CC=2OC(=NN=2)C=2C=NC(=NC=2)NC2CC3=CC=CC=C3C2)=O)N=1 ZNEMGFATAVGQSF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/245—Hydrocarbons cyclic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/241—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/242—Hydrocarbons branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/247—Hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5027—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/22—Electronic devices, e.g. PCBs or semiconductors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of photovoltaic module cleaning agents and its preparation method and application.Photovoltaic module cleaning agent of the invention, by weight, include following components: 60~80 parts of host agent, 10~30 parts of the first adjuvant, 5~20 parts of the second adjuvant, wherein the host agent is the mixture of any one or at least two in the isomer of hexamethylene, n-hexane and n-hexane.Preparation method provided by the invention, simple to operation, cleaning of the photovoltaic module cleaning agent obtained for residue glue in photovoltaic module is not necessarily to high temperature, and cleaning speed is fast, and cleaning effect is thorough, no pollution to the environment non-corrosive to equipment, easily transports.
Description
Technical field
The invention belongs to cleaning agent technical field, it is related to a kind of photovoltaic module cleaning agent and its preparation method and application.
Background technique
Either single glass component or solar double-glass assemblies, in lamination process, inevitable that glue film (EVA or
POE it) overflows, to be polluted to the inside of glass surface, back plate surface and laminating machine.Temperature and pressure in lamination process
Under the action of power, EVA or POE generate cross-linking reaction, form tridimensional network.So the extremely difficult cleaning of these residue glues, component
There is an urgent need to a kind of solvents for factory, carry out cleaning additive to it.
CN106914671A discloses a kind of MWT photovoltaic module extraction welding method, includes the following steps: that (1) is welded
Surface treatment, if there is EVA residual at conductive foil pad, the EVA residue glue that need to will be overflow using electric iron to pad is removed, and is then beaten
Metal foil welding region is ground, metal foil surface oxide layer is removed, increases welding region roughness；(2) tin on, obtained by step 1
Rough face on tin, tin layers overlay area is one round, and round diameter is not less than 5mm, and tin layers high uniformity is consistent, if when upper tin
It was found that bond pad surface has corrosion, then pad, removal corrosion are smeared using soldering-assistant pencil；(3) it welds, lead-out wire is welded on by step
The surface of rapid 2 processing.EVA residue glue is removed using electric iron in the invention, needs high temperature, and processing is time-consuming and laborious, is not suitable for
In the removal and cleaning of photovoltaic module residue glue.
Since residue glue has formed tridimensional network, usual vehicle is difficult to be cleared up, is difficult to clean up with single solvent,
It needs multi-solvents to carry out interworking, could have good cleaning effect, and need higher temperature that can just clean out.But
If cleaning temperature is too high, these solvents are volatile, to worker and equipment, there are certain harm and corrosivity.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of photovoltaic module cleaning agents and preparation method thereof
And purposes, cleaning of the photovoltaic module cleaning agent for residue glue in photovoltaic module are not necessarily to high temperature, cleaning speed is fast, cleaning effect
Thoroughly, non-corrosive to equipment, no pollution to the environment is easily transported.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of photovoltaic module cleaning agent, by weight, the photovoltaic module cleaning agent include following components:
60~80 parts of host agent, such as the parts by weight of host agent are 60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 66 parts, 67
Part, 68 parts, 69 parts, 70 parts, 71 parts, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78 parts, 79 parts, 80 parts etc.；
First 10~30 parts of adjuvant, for example, the first adjuvant parts by weight be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts,
16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts etc.；
Second 5~20 parts of adjuvant, for example, the second adjuvant parts by weight be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts,
12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts etc.；Wherein, the host agent be hexamethylene, n-hexane and
In the isomer of n-hexane any one or at least two mixture.
The present invention in the isomer of hexamethylene, n-hexane and n-hexane any one or at least two mixing
Object is host agent, for being swollen and dissolving the matrix resin of residue glue in residue glue, is added to the first adjuvant to auxiliary agent remaining in residue glue
It is dissolved, is added to the second adjuvant and obstinate residue glue is swollen and is dissolved, by adjusting host agent, the first adjuvant and second
The composition and ratio of adjuvant, three's synergistic effect are not necessarily to high temperature, cleaning speed is fast, clearly for the cleaning of residue glue in photovoltaic module
It is thorough to manage effect, no pollution to the environment non-corrosive to equipment is easily transported.
Host agent of the invention plays main function to cleaning for being swollen and dissolving the matrix resin of residue glue in residue glue.Its
In, the host agent is the mixture of any one or at least two in the isomer of hexamethylene, n-hexane and n-hexane.
Wherein, the isomer of the n-hexane is 2- methylpentane, 3- methylpentane, 2,3- dimethylbutane and to dimethyl butyrate
One of alkane.The mixture typical case but unrestricted group are combined into the mixture of hexamethylene and n-hexane, hexamethylene and 2- first
The mixture of base pentane, the mixture of hexamethylene and 3- methylpentane, hexamethylene and 2, the mixture of 3- dimethylbutane, hexamethylene
Alkane and mixture to dimethylbutane, the mixture of n-hexane and 2- methylpentane, the mixing of n-hexane and 3- methylpentane
Object, n-hexane and 2, the mixture of 3- dimethylbutane, n-hexane and the mixture to dimethylbutane, 2- methylpentane, 3-
The mixture of methylpentane hexamethylene, n-hexane, the mixture of 2- methylpentane, 2,3- dimethylbutane, 2- methylpentane and
To the mixture of dimethylbutane, the mixture of 3- methylpentane, 2,3- dimethylbutane, 3- methylpentane and to dimethyl butyrate
The mixture of alkane, 2,3- dimethylbutanes and the mixture to dimethylbutane, hexamethylene, n-hexane and 2- methylpentane it is mixed
Conjunction object, the mixture of hexamethylene, n-hexane and 3- methylpentane, hexamethylene, n-hexane and 2, the mixture of 3- dimethylbutane,
Hexamethylene, n-hexane and the mixture to dimethylbutane, the mixture of n-hexane and 2- methylpentane, 3- methylpentane, just
The mixture of hexane and 2- methylpentane, 2,3- dimethylbutane, n-hexane and 2- methylpentane, the mixing to dimethylbutane
Object, the mixture of n-hexane and 3- methylpentane, 2,3- dimethylbutane, n-hexane and 3- methylpentane, to dimethylbutane
Mixture, n-hexane and 2,3- dimethylbutane and the mixture etc. to dimethylbutane；The mixture may be four
The mixture of kind, such as the mixture of hexamethylene, n-hexane, 2- methylpentane, 3- methylpentane, hexamethylene, n-hexane, 2,3-
Dimethylbutane and mixture to dimethylbutane, 2- methylpentane, 3- methylpentane, 2,3- dimethylbutane and to diformazan
The mixture of base butane, n-hexane, 3- methylpentane, 2,3- dimethylbutane and to mixture of dimethylbutane etc.；It is described
Mixture can also be five kinds of mixture, such as hexamethylene, n-hexane, 2- methylpentane, 3- methylpentane, 2,3- dimethyl
The mixture of butane, n-hexane, 2- methylpentane, 3- methylpentane, 2,3- dimethylbutane and the mixing to dimethylbutane
Object etc..
The first adjuvant in the present invention has good dissolution to auxiliary agent remaining in residue glue, and first adjuvant is
Intensive polar solvent.Preferably, the intensive polar solvent is any one in ethyl acetate, Ethyl formate and ethyl alcohol or at least two
The mixture of kind.Such as the mixture is the mixture of ethyl acetate, Ethyl formate, the mixture of ethyl acetate, ethyl alcohol, first
The mixture of acetoacetic ester and ethyl alcohol, the mixture of ethyl acetate, Ethyl formate and ethyl alcohol.
The second adjuvant in the present invention is swollen and dissolves to obstinate residue glue, it is preferable that second adjuvant is two
Toluene and/or toluene.
As a preferred solution of the present invention, by weight, the photovoltaic module cleaning agent includes following components:
65~75 parts of host agent, such as the parts by weight of host agent are 65 parts, 66 parts, 67 parts, 68 parts, 69 parts, 70 parts, 71 parts, 72
Part, 73 parts, 74 parts, 75 parts etc..
First 15~25 parts of adjuvant, such as the parts by weight of the first adjuvant are 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts
Deng.
Second 10~15 parts of adjuvant, such as the parts by weight of the second adjuvant are 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts
Deng.
As the preferred preferred embodiment of the present invention, by weight, the photovoltaic module cleaning agent includes following components:
70 parts of host agent
First 20 parts of adjuvant
Second 10 parts of adjuvant.
The second object of the present invention is to provide a kind of preparation method of photovoltaic module cleaning agent described in the first purpose, institute
It states the preparation method comprises the following steps: by weight, 60~80 parts of host agent, 10~30 parts of the first adjuvant and the second of 5~20 parts is auxiliary
Agent is uniformly mixed in closed container, obtains the photovoltaic module cleaning agent.
The third object of the present invention is to provide a kind of purposes of photovoltaic module cleaning agent described in the first purpose, will be described
Photovoltaic module cleaning agent is used for the cleaning of residue glue.
How much the dosage of photovoltaic module cleaning agent can adjust according to the quality of residue glue, it is preferable that the photovoltaic module
The mass ratio of cleaning agent and the residue glue is (1:2)~(1:10)；Least photovoltaic module can be utilized as far as possible within this range
Cleaning agent reaches optimal cleaning effect.
Preferably, EVA and/or POE is contained in the residue glue.
The problems such as not dangerous chemicals of auxiliary agent of the present invention, there is no transportation safeties.Configured photovoltaic module cleaning agent can
It is saved with being placed in glass container or plastic bottle.
Compared with prior art, the invention has the benefit that
(1) photovoltaic module cleaning agent of the invention, penetrating odor is few when processing and is not necessarily to high temperature, and cleaning speed is fast, and 23
DEG C or so 60s under room temperature in can by residue glue clear up thoroughly, it is non-corrosive to equipment without residue glue after processing, to environment
It is pollution-free, easily transport.
(2) preparation method of photovoltaic module cleaning agent of the invention, simple to operation, no pollution to the environment are used for photovoltaic
Cleaning effect is good when component residue glue is cleared up；In addition, the not dangerous chemicals of photovoltaic module cleaning agent of the invention, there is no transport peaces
Congruent problem is easy to transport.
Specific embodiment
The technical scheme of the invention is further explained by means of specific implementation.
Unless specific instructions, various raw materials of the invention are commercially available buys, or is prepared according to the conventional method of this field
It obtains.
Embodiment 1
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is n-hexane, and the first adjuvant is ethyl acetate, and the second adjuvant is dimethylbenzene.
Embodiment 2
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is hexamethylene, and the first adjuvant is the mixture of 15 parts of Ethyl formates and 15 parts of ethyl alcohol, and the second adjuvant is
Toluene.
Embodiment 3
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is the mixture of 30 parts of hexamethylenes and 35 parts of n-hexanes, and the first adjuvant is 10 parts of ethyl acetate and 15
The mixture of part ethyl alcohol, the second adjuvant are the mixture of 5 parts of toluene and 5 parts of dimethylbenzene.
Embodiment 4
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is the mixture of 30 parts of hexamethylenes, 20 parts of n-hexanes and 20 parts of 3- methylpentanes, and the first adjuvant is 15
Part ethyl acetate, the second adjuvant are the mixture of 5 parts of toluene and 10 parts of dimethylbenzene.
Embodiment 5
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent be 20 parts of hexamethylenes, 15 parts of n-hexanes, 15 parts dimethylbutane and 20 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 10 parts of ethyl acetate and 10 parts of Ethyl formates, and the second adjuvant is 10 parts of toluene.
Embodiment 6
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent be 20 parts of hexamethylenes, 15 parts of n-hexanes, 15 parts dimethylbutane and 20 parts of 3- methylpentanes are mixed
Close object, the first adjuvant is the mixture of 2 parts of ethyl acetate, 3 parts of Ethyl formates and 5 parts of ethyl alcohol, the second adjuvant be 10 parts of toluene and
The mixture of 10 parts of dimethylbenzene.
Embodiment 7
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is the mixture of 35 parts of n-hexanes and 40 parts of 3- methylpentanes, the first adjuvant be 5 parts of Ethyl formates and
The mixture of 5 parts of ethyl alcohol, the second adjuvant are the mixture of 10 parts of toluene and 5 parts of dimethylbenzene.
Embodiment 8
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is 75 parts of n-hexanes, and the first adjuvant is the mixture of 10 parts of Ethyl formates and 5 parts of ethyl alcohol, and second is auxiliary
Agent is the mixture of 2 parts of toluene and 8 parts of dimethylbenzene.
Embodiment 9
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is 75 parts to dimethylbutane, and the first adjuvant is 20 parts of ethyl alcohol, and the second adjuvant is 5 parts of dimethylbenzene.
Embodiment 10
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is 25 parts of hexamethylenes, 20 parts of 2- methylpentanes, 15 parts of 2,3- dimethylbutanes and 20 parts to dimethyl
The mixture of butane, the first adjuvant are 10 parts of ethyl acetate, and the second adjuvant is 10 parts of dimethylbenzene.
Embodiment 11
The photovoltaic module cleaning agent of the present embodiment, including host agent, the first adjuvant and the second adjuvant, the specific weight of each component
Part is as shown in table 1.
Wherein, host agent is 40 parts of hexamethylenes and 40 parts of mixtures to dimethylbutane, and the first adjuvant is 10 parts of acetic acid second
The mixture of ester and 5 parts of Ethyl formates, the second adjuvant are 5 parts of dimethylbenzene.
Comparative example 1
The photovoltaic module cleaning agent of this comparative example, only includes host agent, and the host agent is hexamethylene, specific parts by weight such as table 1
It is shown.
Comparative example 2
The photovoltaic module cleaning agent of this comparative example only includes the first adjuvant, and first adjuvant is ethyl acetate, specific weight
It is as shown in table 1 to measure part.
Comparative example 3
The photovoltaic module cleaning agent of this comparative example, only includes the second adjuvant, and second adjuvant is dimethylbenzene, specific weight
Part is as shown in table 1.
Comparative example 4
The photovoltaic module cleaning agent of this comparative example, includes host agent and the first adjuvant, and specific parts by weight are as shown in table 1.
Wherein, host agent is hexamethylene, and the first adjuvant is ethyl acetate.
Comparative example 5
The photovoltaic module cleaning agent of this comparative example, includes the first adjuvant and the second adjuvant, and specific parts by weight are as shown in table 1.
Wherein, the first adjuvant is ethyl acetate, and the second adjuvant is toluene.
Comparative example 6
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent is 10 parts of hexamethylenes, 5 parts of n-hexanes, 5 parts of mixing to dimethylbutane and 10 parts of 3- methylpentanes
Object, the first adjuvant are the mixture of 20 parts of ethyl acetate and 20 parts of Ethyl formates, and the second adjuvant is 30 parts of toluene.
Comparative example 7
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent be 30 parts of hexamethylenes, 20 parts of n-hexanes, 20 parts dimethylbutane and 20 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 2 parts of ethyl acetate and 6 parts of Ethyl formates, and the second adjuvant is 2 parts of toluene.
Comparative example 8
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent be 30 parts of hexamethylenes, 10 parts of n-hexanes, 10 parts dimethylbutane and 20 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 2 parts of ethyl acetate and 3 parts of Ethyl formates, and the second adjuvant is 25 parts of toluene.
Comparative example 9
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent be 30 parts of hexamethylenes, 10 parts of n-hexanes, 10 parts dimethylbutane and 10 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 20 parts of ethyl acetate and 15 parts of Ethyl formates, and the second adjuvant is 5 parts of toluene.
Comparative example 10
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent be 25 parts of hexamethylenes, 15 parts of n-hexanes, 20 parts dimethylbutane and 18 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 10 parts of ethyl acetate and 10 parts of Ethyl formates, and the second adjuvant is 2 parts of toluene.
Comparative example 11
The photovoltaic module cleaning agent of this comparative example includes host agent, the first adjuvant and the second adjuvant, the difference with embodiment 5
It is only that the parts by weight of each component are different, specific parts by weight are as shown in table 1.
Wherein, host agent be 20 parts of hexamethylenes, 10 parts of n-hexanes, 10 parts dimethylbutane and 20 parts of 3- methylpentanes are mixed
Object is closed, the first adjuvant is the mixture of 6 parts of ethyl acetate and 4 parts of Ethyl formates, and the second adjuvant is 30 parts of toluene.
Table 1
Photovoltaic module cleaning agent made from the embodiment of the present invention 1-11 and comparative example 1-11 is used for the cleaning of residue glue,
In, the group of residue glue becomes POE, and the mass ratio of photovoltaic module cleaning agent and residue glue is 1:5, the cleaning effect of photovoltaic module cleaning agent
As shown in table 2.
Table 2
Wherein, " ◎ " indicates cleaning thoroughly, and assembly surface is remained without residue glue after cleaning, and surface is clearly smooth, and "○" indicates
Cleaning effect is general, and assembly surface has a small amount of residual after cleaning, surface blur, and "×" indicates that cleaning effect is poor, cannot thoroughly by
Residue glue is removed；Cleaning temperature is actual temperature when testing at that time, is 23 DEG C.
As can be seen from Table 2, the comparative example 1 of the application, only the cleaning effect comprising host agent component is general, scavenging period
Long, comparative example 2 include the first adjuvant, and cleaning effect is preferable, but the penetrating odor of cleaning agent is too heavy, to human body and environment
It is unfavorable.Comparative example 3 include the second adjuvant, and cleaning is not thorough, and cannot completely remove residue glue, penetrating odor is also very heavy.Comparison
Example 4 include host agent and the first adjuvant, and comparative example 5 comprising the first adjuvant and the second adjuvant comparative example 6-11 each component comprising containing
Amount not in the range of the application limits, cannot all reach the application cleaning speed is fast, cleaning thoroughly, penetrating odor it is minimum
Effect.
Photovoltaic module cleaning agent of the invention is not necessarily to high temperature, and cleaning speed is fast, and cleaning effect is thorough, corrosion-free to equipment
Property, no pollution to the environment, the preparation method of photovoltaic module cleaning agent of the invention is simple to operation, no pollution to the environment, is used for
Cleaning effect is good when photovoltaic module residue glue is cleared up；In addition, the not dangerous chemicals of photovoltaic module cleaning agent of the invention, there is no fortune
Defeated security problems are easy to transport.
Detailed process equipment and process flow of the invention that the present invention is explained by the above embodiments, but the present invention is not
It is confined to above-mentioned detailed process equipment and process flow, that is, does not mean that the present invention must rely on above-mentioned detailed process equipment and work
Skill process could be implemented.It should be clear to those skilled in the art, any improvement in the present invention, to product of the present invention
The equivalence replacement of each raw material and addition, the selection of concrete mode of auxiliary element etc., all fall within protection scope of the present invention and public affairs
Within the scope of opening.
Claims (10)
1. a kind of photovoltaic module cleaning agent, which is characterized in that by weight, the photovoltaic module cleaning agent includes with the following group
Point:
60~80 parts of host agent
First 10~30 parts of adjuvant
Second 5~20 parts of adjuvant,
Wherein, the host agent is any one in the isomer of hexamethylene, n-hexane and n-hexane or at least two
Mixture.
2. photovoltaic module cleaning agent according to claim 1, which is characterized in that the isomer of the n-hexane is 2-
Methylpentane, 3- methylpentane, 2,3- dimethylbutane and in dimethylbutane any one or at least two mixing
Object.
3. photovoltaic module cleaning agent according to claim 1 or 2, which is characterized in that first adjuvant is highly polar molten
Agent.
4. photovoltaic module cleaning agent according to claim 3, which is characterized in that the intensive polar solvent be ethyl acetate,
In Ethyl formate and ethyl alcohol any one or at least two mixture.
5. photovoltaic module cleaning agent described in one of -4 according to claim 1, which is characterized in that second adjuvant is dimethylbenzene
And/or toluene.
6. photovoltaic module cleaning agent described in one of -5 according to claim 1, which is characterized in that by weight, the photovoltaic
Component cleaning agent includes following components:
65~75 parts of host agent
First 15~25 parts of adjuvant
Second 10~15 parts of adjuvant.
7. photovoltaic module cleaning agent described in one of -6 according to claim 1, which is characterized in that by weight, the photovoltaic
Component cleaning agent includes following components:
70 parts of host agent
First 20 parts of adjuvant
Second 10 parts of adjuvant.
8. a kind of preparation method of such as described in any item photovoltaic module cleaning agents of claim 1-7, which is characterized in that the system
Preparation Method are as follows: by weight, 60~80 parts of host agent, 10~30 parts of the first adjuvant and 5~20 parts of the second adjuvant are existed
It is uniformly mixed in closed container, obtains the photovoltaic module cleaning agent.
9. a kind of purposes of such as described in any item photovoltaic module cleaning agents of claim 1-7, which is characterized in that by the photovoltaic
Component cleaning agent is used for the cleaning of photovoltaic module residue glue.
10. purposes according to claim 9, which is characterized in that the quality of the photovoltaic module cleaning agent and the residue glue
Than for (1:2)~(1:10)；
Preferably, EVA and/or POE is contained in the residue glue.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811594421.6A CN109504559B (en) | 2018-12-25 | 2018-12-25 | Photovoltaic module cleaning agent and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811594421.6A CN109504559B (en) | 2018-12-25 | 2018-12-25 | Photovoltaic module cleaning agent and preparation method and application thereof |
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| CN109504559B CN109504559B (en) | 2020-11-13 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111423939A (en) * | 2020-03-06 | 2020-07-17 | 深圳市唯特偶新材料股份有限公司 | Component cleaning agent |
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| CN105296217A (en) * | 2015-10-30 | 2016-02-03 | 深圳市辛骏翔科技有限公司 | Organic cleaning agent |
| CN106398892A (en) * | 2016-08-30 | 2017-02-15 | 乐凯特科技铜陵有限公司 | Circuit board cleaning agent with excellent cleaning performance |
| CN106467872A (en) * | 2015-08-20 | 2017-03-01 | 英属开曼群岛商正特殊材料材料股份有限公司 | Adhesive remover and using this adhesive remover except gluing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106467872A (en) * | 2015-08-20 | 2017-03-01 | 英属开曼群岛商正特殊材料材料股份有限公司 | Adhesive remover and using this adhesive remover except gluing method |
| CN105296217A (en) * | 2015-10-30 | 2016-02-03 | 深圳市辛骏翔科技有限公司 | Organic cleaning agent |
| CN106398892A (en) * | 2016-08-30 | 2017-02-15 | 乐凯特科技铜陵有限公司 | Circuit board cleaning agent with excellent cleaning performance |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111423939A (en) * | 2020-03-06 | 2020-07-17 | 深圳市唯特偶新材料股份有限公司 | Component cleaning agent |
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| CN109504559B (en) | 2020-11-13 |
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