CN109502994A - A kind of glass fibre protection type size - Google Patents
A kind of glass fibre protection type size Download PDFInfo
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- CN109502994A CN109502994A CN201811431389.XA CN201811431389A CN109502994A CN 109502994 A CN109502994 A CN 109502994A CN 201811431389 A CN201811431389 A CN 201811431389A CN 109502994 A CN109502994 A CN 109502994A
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- Prior art keywords
- parts
- glass fibre
- protection type
- type size
- fibre protection
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of glass fibre protection type sizes; in terms of the component of parts by weight; the size includes modified bisphenol A epoxide resin, 5-10 parts of silicone oil, 0.1-1.0 parts of antistatic agent, 0.1-0.3 parts of surfactant, 0.5-1.5 parts of coupling agent, 0.1-1.0 parts of emulsifier and the 400-550 parts of deionized waters of 5-9 parts of amine; the epoxy resin lotion is the modified bisphenol A epoxide resin of amine, has good defencive function, convergence, compatibility and impregnability to glass fibre.
Description
Technical field
The present invention relates to glass fibre finishing agent field, in particular to a kind of glass fibre protection type size.
Background technique
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, many kinds of, and advantage is good insulating, heat resistance
By force, corrosion resistance is good, high mechanical strength, but the disadvantage is that property is crisp, wearability is poor.Glass fibre is pyrophillite, quartz sand, lime
Stone, dolomite, bechilite, seven kinds of ores of boromagnesite be raw material through techniques systems such as high temperature melting, wire drawing, doff, woven fabrics caused by,
The diameter of its monofilament is several microns to twenties microns, is equivalent to the 1/20-1/5 of a hairline, every bundle fiber is former
Silk is all made of hundreds of even thousands of monofilament.
In glass fibre production and application process, size plays irreplaceable key effect, is used for reinforcing fiber
Adhesiveness, coating, the resistance to nappiness of beam, keep fiber surface smooth, increase flexibility, wearability, and are easy to wind and wind
When damage reduce.
The manufacturing process of traditional glass fibre, film forming agent generally uses starch and paraffin to form, although this film forming agent
There is preferable convergence, but compatibility is poor, and the processing in later period is also troublesome.
Summary of the invention
The object of the present invention is to provide a kind of glass fibre protection type sizes, have good protection function to glass fibre
Energy, convergence, compatibility and impregnability.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of glass fibre protection type size, in terms of the component of parts by weight, which includes the modified bis-phenol of 5-9 parts of amine
A epoxy resin, 5-10 parts of silicone oil, 0.1-1.0 parts of antistatic agent, 0.1-0.3 parts of surfactant, 0.5-1.5 parts
Coupling agent, 0.1-1.0 parts of emulsifier and 400-550 parts of deionized waters.
Preferably, comprising the following components in parts by weight: 5 parts of bisphenol A epoxide resin of amine modification, it is 5 parts of silicone oil, antistatic
0.1 part of agent, 0.1 part of surfactant, 0.5 part of coupling agent, 0.1 part and 400 parts of deionized water of emulsifier.
Preferably, comprising the following components in parts by weight: 6 parts of bisphenol A epoxide resin of amine modification, it is 6 parts of silicone oil, antistatic
0.3 part of agent, 0.2 part of surfactant, 0.8 part of coupling agent, 0.2 part and 450 parts of deionized water of emulsifier.
Preferably, comprising the following components in parts by weight: 8 parts of bisphenol A epoxide resin of amine modification, it is 8 parts of silicone oil, antistatic
0.5 part of agent, 0.2 part of surfactant, 1.0 parts of coupling agent, 0.5 part and 500 parts of deionized water of emulsifier.
Preferably, comprising the following components in parts by weight: 9 parts of bisphenol A epoxide resin of amine modification, resist quiet by 10 parts of silicone oil
1.0 parts of electric agent, 0.3 part of surfactant, 1.5 parts of coupling agent, 1.0 parts and 550 parts of deionized water of emulsifier.
By adopting the above technical scheme, wherein the modified bisphenol A epoxide resin of amine is good to fiberglass surfacing cementability, collection
Beam is good, and the intensity of fiberglass products can be improved.
Preferably, the silicone oil is dimethyl silicone polymer.
Preferably, the antistatic agent is imidazolinyl quaternary ammonium salt.
Preferably, the coupling agent is zirconium class coupling agent.
Preferably, the surfactant is C12-18 fatty alcohol polyoxy ether.
Preferably, the glass fibre protection type size is prepared using following methods, specific steps include
Following steps:
(1) the modified bisphenol A epoxide resin of amine and silicone oil are diluted with 2 times of water and are stirred 20 minutes；
(2) antistatic agent is dissolved and is stirred with 10 times of 35 DEG C of hot water, when temperature is reduced to 20 DEG C or less, stopped
Stirring；
(3) surfactant and emulsifier are dissolved and is stirred 15 minutes with 5 times of 30 DEG C of water；
(4) the 50% of water quality total amount is added into mixing tube, opens blending tank blender, is first slowly added to coupling agent, stirs 5 points
Clock, stirring to solution are clarified, then surface is added the above-mentioned reagent and water modulated into blending tank again, continues to stir without oil bloom
It mixes 10 minutes.
In conclusion compared with prior art, the invention has the benefit that epoxy resin lotion is modified pair of amine
Phenol A epoxy resin can improve the caking property and convergence of glass fibre, while improve glass fiber product to a certain extent
Intensity；Using silicone oil as film forming agent, it is possible to reduce the generation of glass fibre lousiness increases the anti-fracture ability of glass fibre.
Specific embodiment
As described below is only the preferred embodiment of the present invention, and protection scope is not limited merely to the embodiment, all to belong to
Protection scope of the present invention should belong in technical solution under thinking of the present invention.Simultaneously it should be pointed out that for the art
For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Embodiment 1
A kind of glass fibre protection type size, is made of forming for following parts by weight:
5 parts of epoxy resin lotion, 5 parts of dimethyl silicone polymer, 0.1 part of imidazolinyl quaternary ammonium salt, C12-18 fatty alcohol polyoxy
0.1 part of ether, 0.5 part of zirconium class coupling agent, 0.1 part and 400 parts of deionized water of emulsifier.
Embodiment 2
A kind of glass fibre protection type size, is made of forming for following parts by weight:
6 parts of epoxy resin lotion, 6 parts of dimethyl silicone polymer, 0.3 part of imidazolinyl quaternary ammonium salt, C12-18 fatty alcohol polyoxy
0.2 part of ether, 0.8 part of zirconium class coupling agent, 0.2 part and 450 parts of deionized water of emulsifier.
Embodiment 3
A kind of glass fibre protection type size, is made of forming for following parts by weight:
8 parts of epoxy resin lotion, 8 parts of dimethyl silicone polymer, 0.5 part of imidazolinyl quaternary ammonium salt, C12-18 fatty alcohol polyoxy
0.2 part of ether, 1.0 parts of zirconium class coupling agent, 0.5 part and 500 parts of deionized water of emulsifier.
Embodiment 4
A kind of glass fibre protection type size, is made of forming for following parts by weight: 9 parts of epoxy type epoxy resin lotion,
10 parts of dimethyl silicone polymer, 1.0 parts of imidazolinyl quaternary ammonium salt, 0.3 part of ether of C12-18 fatty alcohol polyoxy, zirconium class coupling agent
1.5 parts, 1.0 parts and 550 parts of deionized water of emulsifier.
The glass fibre protection type size of above-described embodiment 1 to 4 is all made of following methods and is prepared, specific steps packet
Include following steps:
(1) the modified bisphenol A epoxide resin of amine and silicone oil are diluted with 2 times of water and are stirred 20 minutes；
(2) antistatic agent is dissolved and is stirred with 10 times of 35 DEG C of hot water, when temperature is reduced to 20 DEG C or less, stopped
Stirring；
(3) surfactant and emulsifier are dissolved and is stirred 15 minutes with 5 times of 30 DEG C of water；
(4) the 50% of water quality total amount is added into mixing tube, opens blending tank blender, is first slowly added to coupling agent, stirs 5 points
Clock, stirring to solution are clarified, then surface is added the above-mentioned reagent and water modulated into blending tank again, continues to stir without oil bloom
It mixes 10 minutes.
Embodiment 5
A kind of glass fibre protection type size, is made of forming for following parts by weight: 4 parts of epoxy type epoxy resin lotion,
4 parts of dimethyl silicone polymer, 1.5 parts of imidazolinyl quaternary ammonium salt, 0.5 part of ether of C12-18 fatty alcohol polyoxy, zirconium class coupling agent
1.8 parts, 1.5 parts and 600 parts of deionized water of emulsifier.
The glass fibre protection type size is prepared using following methods, specific steps the following steps are included:
(1) the modified bisphenol A epoxide resin of amine and silicone oil are diluted with 2 times of water and are stirred 20 minutes；
(2) antistatic agent is dissolved and is stirred with 10 times of 75 DEG C of hot water, when temperature is reduced to 20 DEG C or less, stopped
Stirring；
(3) surfactant and emulsifier are dissolved and is stirred 15 minutes with 10 times of 40 DEG C of water；
(4) the 60% of water quality total amount is added into mixing tube, opens blending tank blender, is first slowly added to coupling agent, stirs 5 points
Clock, stirring to solution are clarified, then surface is added the above-mentioned reagent and water modulated into blending tank again, continues to stir without oil bloom
It mixes 5 minutes.
Performance test:
By the glass fibre after the size infiltration in embodiment 1-5, after drying box is dried, glass is supported using plying
Fiber yarn tests the breaking strength and surface lousiness of glass fiber yarn, and it is shown that test result is as follows:
Embodiment 1: breaking strength (N/tex) is 0.65, and surface lousiness (radical) is 4-11；
Embodiment 2: breaking strength (N/tex) is 0.60, and surface lousiness (radical) is 3-10；
Embodiment 3: breaking strength (N/tex) is 0.63, and surface lousiness (radical) is 4-10；
Embodiment 4: breaking strength (N/tex) is 0.64, and surface lousiness (radical) is 2-8；
Embodiment 5: breaking strength (N/tex) is 0.4, and surface lousiness (radical) is 9-17.
Claims (10)
1. a kind of glass fibre protection type size, which is characterized in that in terms of the component of parts by weight, which includes 5-9 parts
The modified bisphenol A epoxide resin of amine, 5-10 parts of silicone oil, 0.1-1.0 parts of antistatic agent, 0.1-0.3 parts of surface active
Agent, 0.5-1.5 parts of coupling agent, 0.1-1.0 parts of emulsifier and 400-550 parts of deionized waters.
2. a kind of glass fibre protection type size according to claim 1, which is characterized in that including following parts by weight
Component: 5 parts of bisphenol A epoxide resin of amine modification, 5 parts of silicone oil, 0.1 part of antistatic agent, 0.1 part of surfactant, coupling agent 0.5
Part, 0.1 part and 400 parts of deionized water of emulsifier.
3. a kind of glass fibre protection type size according to claim 2, which is characterized in that including following parts by weight
Component: 6 parts of bisphenol A epoxide resin of amine modification, 6 parts of silicone oil, 0.3 part of antistatic agent, 0.2 part of surfactant, coupling agent 0.8
Part, 0.2 part and 450 parts of deionized water of emulsifier.
4. a kind of glass fibre protection type size according to claim 3, which is characterized in that including following parts by weight
Component: 8 parts of bisphenol A epoxide resin of amine modification, 8 parts of silicone oil, 0.5 part of antistatic agent, 0.2 part of surfactant, coupling agent 1.0
Part, 0.5 part and 500 parts of deionized water of emulsifier.
5. a kind of glass fibre protection type size according to claim 4, which is characterized in that including following parts by weight
Component: 9 parts of bisphenol A epoxide resin of amine modification, 10 parts of silicone oil, 1.0 parts of antistatic agent, 0.3 part of surfactant, coupling agent
1.5 parts, 1.0 parts and 550 parts of deionized water of emulsifier.
6. a kind of glass fibre protection type size according to claim 4, which is characterized in that the silicone oil is poly- diformazan
Radical siloxane.
7. a kind of glass fibre protection type size according to claim 4, which is characterized in that the antistatic agent is miaow
Oxazoline based quaternary ammonium salt.
8. a kind of glass fibre protection type size according to claim 4, which is characterized in that the coupling agent is zirconium class
Coupling agent.
9. a kind of glass fibre protection type size according to claim 4, which is characterized in that the surfactant is
C12-18 fatty alcohol polyoxy ether.
10. a kind of glass fibre protection type size according to claim 4, which is characterized in that the glass fibre
Protection type size is prepared using following methods:
(1) the modified bisphenol A epoxide resin of amine and silicone oil are diluted with 2 times of water and are stirred 20 minutes；
(2) antistatic agent is dissolved and is stirred with 10 times of 35 DEG C of hot water, when temperature is reduced to 20 DEG C or less, stopped
Stirring；
(3) surfactant and emulsifier are dissolved and is stirred 15 minutes with 5 times of 30 DEG C of water；
(4) the 50% of water quality total amount is added into mixing tube, opens blending tank blender, is first slowly added to coupling agent, stirs 5 points
Clock, stirring to solution are clarified, then surface is added the above-mentioned reagent and water modulated into blending tank again, continues to stir without oil bloom
It mixes 10 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811431389.XA CN109502994A (en) | 2018-11-28 | 2018-11-28 | A kind of glass fibre protection type size |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811431389.XA CN109502994A (en) | 2018-11-28 | 2018-11-28 | A kind of glass fibre protection type size |
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| Publication Number | Publication Date |
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| CN109502994A true CN109502994A (en) | 2019-03-22 |
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| CN201811431389.XA Pending CN109502994A (en) | 2018-11-28 | 2018-11-28 | A kind of glass fibre protection type size |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112390541A (en) * | 2020-12-14 | 2021-02-23 | 南通天和树脂有限公司 | High-equivalent-weight epoxy impregnating compound and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63297249A (en) * | 1987-05-29 | 1988-12-05 | Nippon Glass Fiber Co Ltd | Sizing agent for glass fiber |
| CN1923740A (en) * | 2006-09-13 | 2007-03-07 | 中材科技股份有限公司 | Enhancement soakage agent for thin glass fiber bulked yarn |
| CN106186729A (en) * | 2016-06-30 | 2016-12-07 | 武汉鑫友泰光电科技有限公司 | Quartz glass fibre organic silicon type wetting agent and preparation method thereof |
| CN107555814A (en) * | 2017-09-05 | 2018-01-09 | 山东玻纤集团股份有限公司 | One kind insulation pultrusion alkali-free glass fibre yarn size |
| CN108330691A (en) * | 2018-02-12 | 2018-07-27 | 巨石集团有限公司 | A kind of insulator direct roving sizing agent and its preparation method and application |
| CN108892397A (en) * | 2018-09-20 | 2018-11-27 | 黄勇 | A kind of novel glass fiber size |
-
2018
- 2018-11-28 CN CN201811431389.XA patent/CN109502994A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63297249A (en) * | 1987-05-29 | 1988-12-05 | Nippon Glass Fiber Co Ltd | Sizing agent for glass fiber |
| CN1923740A (en) * | 2006-09-13 | 2007-03-07 | 中材科技股份有限公司 | Enhancement soakage agent for thin glass fiber bulked yarn |
| CN106186729A (en) * | 2016-06-30 | 2016-12-07 | 武汉鑫友泰光电科技有限公司 | Quartz glass fibre organic silicon type wetting agent and preparation method thereof |
| CN107555814A (en) * | 2017-09-05 | 2018-01-09 | 山东玻纤集团股份有限公司 | One kind insulation pultrusion alkali-free glass fibre yarn size |
| CN108330691A (en) * | 2018-02-12 | 2018-07-27 | 巨石集团有限公司 | A kind of insulator direct roving sizing agent and its preparation method and application |
| CN108892397A (en) * | 2018-09-20 | 2018-11-27 | 黄勇 | A kind of novel glass fiber size |
Non-Patent Citations (1)
| Title |
|---|
| 姜肇中等: "《玻璃纤维应用技术》", 31 January 2004, 中国石化出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112390541A (en) * | 2020-12-14 | 2021-02-23 | 南通天和树脂有限公司 | High-equivalent-weight epoxy impregnating compound and preparation method thereof |
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Application publication date: 20190322 |