CN109490467A - The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process - Google Patents

The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process Download PDF

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Publication number
CN109490467A
CN109490467A CN201710824231.8A CN201710824231A CN109490467A CN 109490467 A CN109490467 A CN 109490467A CN 201710824231 A CN201710824231 A CN 201710824231A CN 109490467 A CN109490467 A CN 109490467A
Authority
CN
China
Prior art keywords
nmp
standard
baking oven
coating process
lithium titanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710824231.8A
Other languages
Chinese (zh)
Inventor
刘金良
高峰
张要枫
程凯
杨小花
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yinlong New Energy Co Ltd
Hebei Yinlong New Energy Co Ltd
Original Assignee
Yinlong New Energy Co Ltd
Hebei Yinlong New Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yinlong New Energy Co Ltd, Hebei Yinlong New Energy Co Ltd filed Critical Yinlong New Energy Co Ltd
Priority to CN201710824231.8A priority Critical patent/CN109490467A/en
Publication of CN109490467A publication Critical patent/CN109490467A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0062General constructional details of gas analysers, e.g. portable test equipment concerning the measuring method, e.g. intermittent, or the display, e.g. digital
    • G01N33/0063General constructional details of gas analysers, e.g. portable test equipment concerning the measuring method, e.g. intermittent, or the display, e.g. digital using a threshold to release an alarm or displaying means

Abstract

The invention discloses the prior-warning devices and method for early warning of NMP concentration over-standard in lithium titanate battery coating process, prior-warning device includes for the coater head of coating sizing-agent, baking oven, detection unit and alarm unit on foil band, the coater head and baking oven are arranged in same level, and the detection unit is arranged in baking oven and connect with the alarm unit being arranged in outside baking oven;When foil band by the coater head complete coating after by the baking oven when, detection unit detect oven interior NMP concentration, when concentration be greater than preset value when, alarm unit alarm, avoid the problem of influencing pole piece caking property because of NMP concentration over-standard.

Description

The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process
Technical field
The invention belongs to lithium ion power battery technology fields, and in particular to NMP concentration in lithium titanate battery coating process Exceeded prior-warning device and method for early warning.
Background technique
N-Methyl pyrrolidone (NMP) is colourless transparent liquid, is one kind using gamma-butyrolacton as raw material, is condensed with methylamine Into liquid, it is widely used in the production of lithium batteries.
In electrode of lithium cell manufacturing process, gaseous state, NMP gas will form after solvent NMP in coating machine slurry is heated Body is toxic, there is the possibility of explosion when having injury to human body, and mixing with air;In addition, the concentration of NMP has pole piece caking property Very big influence, the rate of volatilization of surface pole piece NMP will have a direct impact on the caking property of pole piece, and the pole piece of bad adhesion can not carry out Compacting;And NMP takes away not in time, and NMP excessive concentration also will affect the caking property of coating pole piece inside coater oven;Therefore The monitoring of NMP is not only related to the energy-saving and emission-reduction benefit of battery production enterprise with recycling, and even more concern personnel health and life peace Full cardinal task.
Summary of the invention
The object of the present invention is to provide the prior-warning devices of NMP concentration over-standard in lithium titanate battery coating process, pass through detection The cooperation of unit and alarm unit solves the problems, such as to influence pole piece caking property because of NMP concentration over-standard.
It is a further object of the present invention to provide the method for early warning of NMP concentration over-standard in lithium titanate battery coating process.
The technical scheme adopted by the invention is that:
The prior-warning device of NMP concentration over-standard in lithium titanate battery coating process comprising for being coated with slurry on foil band Coater head, baking oven, detection unit and the alarm unit of material, the coater head and baking oven are arranged in same level, institute Detection unit is stated to be arranged in baking oven and connect with the alarm unit being arranged in outside baking oven;
When foil band by the coater head complete coating after by the baking oven when, detection unit detect oven interior The concentration of NMP, when concentration is greater than preset value, alarm unit alarm.
The features of the present invention also characterized in that
Air outlet is provided on the baking oven.
The detection unit is gas detector, and the gas detector is arranged at air outlet.
The coater head is direct injection coater head.
The alarm unit is tri coloured lantern.
The method for early warning of NMP concentration over-standard in lithium titanate battery coating process, using above-mentioned lithium titanate battery coating process The prior-warning device of middle NMP concentration over-standard, is specifically implemented according to the following steps:
Step 1, foil band is coated by coater head;
Step 2, the foil band after being coated by baking oven to the step 1 toasts, while detection unit is real-time Detect the concentration of oven interior NMP;
Step 3, when the concentration of the NMP of the step 2 detection is greater than secure threshold, alarm unit alarm.
The features of the present invention also characterized in that
The walking speed of coater head is less than or equal to 25m/min in the step 1.
The concentration of oven interior NMP is detected in the step 2 method particularly includes: by exhausting motor by gas in baking oven It is evacuated at air outlet, the concentration of NMP is detected by the way that the gas detector at air outlet is arranged in.
The range of the concentration secure threshold of NMP in the step 3 are as follows: 14%-16%.
The exhausting motor power is 7.5-10kw, frequency 50HZ.
Compared with prior art, in use, passing through the concentration of NMP in detection unit real-time detection baking oven, when concentration is greater than When secure threshold, alarm unit alarm avoids the problem of influencing pole piece caking property because of NMP concentration over-standard.
Detailed description of the invention
Fig. 1 is that the embodiment of the present invention provides the structure of the prior-warning device of NMP concentration over-standard in lithium titanate battery coating process Schematic diagram;
Fig. 2 be the embodiment of the present invention provide lithium titanate battery coating process in NMP concentration over-standard prior-warning device in baking oven Structural schematic diagram.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
The embodiment of the present invention provides the prior-warning device of NMP concentration over-standard in lithium titanate battery coating process, such as Fig. 1-2 institute Show comprising for the coater head 1 of coating sizing-agent, baking oven 2, detection unit 3 and alarm unit 4 on foil band, coating Head 1 and baking oven 2 are arranged in same level, detection unit 3 be arranged in baking oven 2 and with the alarm list that is arranged in outside baking oven 2 Member 4 connects, and coater head 1 is direct injection coater head;In this way, when foil band by coater head 1 complete coating after through baking When case 2, detection unit 3 detects the concentration of 2 inside NMP of baking oven, and when concentration is greater than secure threshold, alarm unit 4 is alarmed.
It is provided with air outlet on baking oven 2, in this way, taking the NMP inside baking oven 2 in time away by air outlet, avoids baking NMP excessive concentration influences the caking property of coating pole piece inside case.
Detection unit 3 is gas detector, gas detector model MicroGAS D9200Ex, gas detector setting At air outlet, in this way, the concentration of NMP can be detected at air outlet.
Alarm unit 4 is tri coloured lantern, in this way, tri coloured lantern flashing reminds operator to pay attention to NMP concentration.
The method for early warning of NMP concentration over-standard in lithium titanate battery coating process, using above-mentioned lithium titanate battery coating process The prior-warning device of middle NMP concentration over-standard, is specifically implemented according to the following steps:
Step 1, foil band is coated by coater head 1, the walking speed of coater head 1 is less than or equal to 25m/min;
Step 2, the foil band after being coated by baking oven 2 to step 1 toasts, while detection unit 3 is examined in real time Survey the concentration of 2 inside NMP of baking oven;Method particularly includes: gas in baking oven 2 is evacuated at air outlet by exhausting motor, by setting The concentration of the gas detector detection NMP at air outlet is set, exhausting motor power is 7.5-10kw, frequency 50HZ;
Step 3, when the concentration of the NMP detected when step 2 is greater than secure threshold, alarm unit 4 is alarmed, the concentration peace of NMP The range of full threshold value are as follows: 14%-16%.
Using the above scheme, compared with prior art, in use, by detection unit real-time detection baking oven NMP it is dense Degree, when concentration is greater than secure threshold, alarm unit alarm, avoiding influences asking for pole piece caking property because of NMP concentration over-standard Topic.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, In the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with scope of protection of the claims Subject to.

Claims (10)

1. the prior-warning device of NMP concentration over-standard in a kind of lithium titanate battery coating process, which is characterized in that it includes in foil The coater head of coating sizing-agent, baking oven, detection unit and alarm unit on material band, the coater head and baking oven are arranged same One horizontal plane, the detection unit are arranged in baking oven and connect with the alarm unit being arranged in outside baking oven;
When foil band after the coater head completes coating by the baking oven when, the detection unit detects oven interior The concentration of NMP, when concentration is greater than secure threshold, alarm unit alarm.
2. the prior-warning device of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 1 In being provided with air outlet on the baking oven.
3. the prior-warning device of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 2 In the detection unit is gas detector, and the gas detector is arranged at air outlet.
4. the prior-warning device of NMP concentration over-standard in lithium titanate battery coating process according to claim 1-3, It is characterized in that, the coater head is direct injection coater head.
5. the prior-warning device of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 4 In the alarm unit is tri coloured lantern.
6. a kind of early warning using NMP concentration over-standard in the described in any item lithium titanate battery coating process of claim 1-5 fills The method for early warning set, which is characterized in that this method is specifically implemented according to the following steps:
Step 1, foil band is coated by coater head;
Step 2, the foil band after being coated by baking oven to the step 1 toasts, while detection unit real-time detection The concentration of oven interior NMP;
Step 3, when the concentration of the NMP of the step 2 detection is greater than secure threshold, alarm unit alarm.
7. the method for early warning of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 6 In the walking speed of coater head is less than or equal to 25m/min in the step 1.
8. the method for early warning of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 7 In the concentration of detection oven interior NMP in the step 2 method particularly includes: be evacuated to gas in baking oven by exhausting motor At air outlet, the concentration of NMP is detected by the way that the gas detector at air outlet is arranged in.
9. the method for early warning of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 8 In the range of the concentration secure threshold of NMP in the step 3 are as follows: 14%-16%.
10. the method for early warning of NMP concentration over-standard, feature exist in lithium titanate battery coating process according to claim 9 In the exhausting motor power is 7.5-10kw, frequency 50HZ.
CN201710824231.8A 2017-09-13 2017-09-13 The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process Pending CN109490467A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710824231.8A CN109490467A (en) 2017-09-13 2017-09-13 The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710824231.8A CN109490467A (en) 2017-09-13 2017-09-13 The prior-warning device and method for early warning of NMP concentration over-standard in lithium titanate battery coating process

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CN109490467A true CN109490467A (en) 2019-03-19

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Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5691867A (en) * 1979-12-27 1981-07-25 Daido Steel Co Ltd Atmosphere controlling process in continuous paint drying and baking oven
JP2007155297A (en) * 2005-12-08 2007-06-21 Hirayama Setsubi Kk Drying method of coating sheet
KR20070092385A (en) * 2006-03-09 2007-09-13 삼성에스디아이 주식회사 Method of drying slurry for electrode of rechargeable battery and apparatus for the same
CN101703995A (en) * 2008-10-24 2010-05-12 汕头市远东轻化装备有限公司 Drying device of coating complex machine
CN102299384A (en) * 2011-07-25 2011-12-28 青岛海霸能源集团有限公司 160AH lithium iron phosphate square battery and production process thereof
JP2012028164A (en) * 2010-07-23 2012-02-09 Ngk Insulators Ltd Drying furnace for electrode coating film for lithium ion battery
CN102489437A (en) * 2011-12-02 2012-06-13 杨峥雄 Energy-saving device and method for drying box of coating compound machine
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CN203267457U (en) * 2013-05-30 2013-11-06 浙江南洋科技股份有限公司 Automatic control device for printing coating drying oven
CN203408853U (en) * 2013-08-15 2014-01-29 湖南深泰虹科技有限公司 Ventilating device of circuit board coating compound machine
CN104285115A (en) * 2012-05-15 2015-01-14 株式会社Lg化学 Automatic intake air flow control device for electrode drying ovens for manufacturing secondary batteries
CN205405820U (en) * 2016-03-14 2016-07-27 深圳市睿华涂布科技有限公司 A solvent strength warning protection device for coating machine
CN105932226A (en) * 2016-05-19 2016-09-07 宁德时代新能源科技股份有限公司 Drying method of battery pole piece
CN106733415A (en) * 2017-01-23 2017-05-31 合肥国轩高科动力能源有限公司 A kind of lithium battery pole piece coating machine
CN106910868A (en) * 2017-04-12 2017-06-30 深圳市斯盛能源股份有限公司 A kind of battery pole piece coating system and method
CN107118599A (en) * 2017-05-17 2017-09-01 河北金力新能源科技股份有限公司 A kind of fire resistant water-based aramid fiber coating lithium ion battery diaphragm and preparation method thereof
CN207318452U (en) * 2017-09-13 2018-05-04 河北银隆新能源有限公司 The prior-warning device of NMP concentration over-standards in lithium titanate battery coating process

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5691867A (en) * 1979-12-27 1981-07-25 Daido Steel Co Ltd Atmosphere controlling process in continuous paint drying and baking oven
JP2007155297A (en) * 2005-12-08 2007-06-21 Hirayama Setsubi Kk Drying method of coating sheet
KR20070092385A (en) * 2006-03-09 2007-09-13 삼성에스디아이 주식회사 Method of drying slurry for electrode of rechargeable battery and apparatus for the same
CN101703995A (en) * 2008-10-24 2010-05-12 汕头市远东轻化装备有限公司 Drying device of coating complex machine
JP2012028164A (en) * 2010-07-23 2012-02-09 Ngk Insulators Ltd Drying furnace for electrode coating film for lithium ion battery
CN102299384A (en) * 2011-07-25 2011-12-28 青岛海霸能源集团有限公司 160AH lithium iron phosphate square battery and production process thereof
CN102489437A (en) * 2011-12-02 2012-06-13 杨峥雄 Energy-saving device and method for drying box of coating compound machine
CN104285115A (en) * 2012-05-15 2015-01-14 株式会社Lg化学 Automatic intake air flow control device for electrode drying ovens for manufacturing secondary batteries
CN203012918U (en) * 2012-11-15 2013-06-19 天津力神电池股份有限公司 Coating machine NMP concentration automatic alarming device
CN203267457U (en) * 2013-05-30 2013-11-06 浙江南洋科技股份有限公司 Automatic control device for printing coating drying oven
CN203408853U (en) * 2013-08-15 2014-01-29 湖南深泰虹科技有限公司 Ventilating device of circuit board coating compound machine
CN205405820U (en) * 2016-03-14 2016-07-27 深圳市睿华涂布科技有限公司 A solvent strength warning protection device for coating machine
CN105932226A (en) * 2016-05-19 2016-09-07 宁德时代新能源科技股份有限公司 Drying method of battery pole piece
CN106733415A (en) * 2017-01-23 2017-05-31 合肥国轩高科动力能源有限公司 A kind of lithium battery pole piece coating machine
CN106910868A (en) * 2017-04-12 2017-06-30 深圳市斯盛能源股份有限公司 A kind of battery pole piece coating system and method
CN107118599A (en) * 2017-05-17 2017-09-01 河北金力新能源科技股份有限公司 A kind of fire resistant water-based aramid fiber coating lithium ion battery diaphragm and preparation method thereof
CN207318452U (en) * 2017-09-13 2018-05-04 河北银隆新能源有限公司 The prior-warning device of NMP concentration over-standards in lithium titanate battery coating process

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