CN109486369A - A kind of environment-friendly water-based vinyl ester resin glass flake plasticine and its preparation process - Google Patents
A kind of environment-friendly water-based vinyl ester resin glass flake plasticine and its preparation process Download PDFInfo
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- CN109486369A CN109486369A CN201811526096.XA CN201811526096A CN109486369A CN 109486369 A CN109486369 A CN 109486369A CN 201811526096 A CN201811526096 A CN 201811526096A CN 109486369 A CN109486369 A CN 109486369A
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- ester resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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Abstract
A kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present invention, the raw material including following weight percent: aqueous vinyl ester resin 45%-56%, glass flake 20%-30%, barium sulfate 7%-15%, Anti-cracking agent 5%-8%, titanium dioxide 1%-2%, sagging inhibitor 1.5%-3%, defoaming agent 0.05-0.1%；Environment-friendly water-based vinyl ester resin glass flake plasticine of the invention; using high performance vinyl ester resin; and foliated glass scale is added wherein; keep the foliated glass scale in coating parallel to each other or overlapping arrangement; form a lot of scale protective barrier; corrosive medium is delayed to reach the time of substrate surface through coating, to substantially prolong the service life of substrate；High temperature resistant, corrosion-resistant, vapour resistant rate is high, can harden under normal temperature conditions, and molding is simple, is easy repairing；Good mechanical performance and have good flame retardant effect.
Description
Technical field:
The invention belongs to aqueous, environmental protective technical field of polymer materials, and in particular to a kind of environment-friendly water-based vinyl ester resin
Glass flake plasticine.
Background technique:
Recently as the anti-corrosion facility closely related with coating, (storage tank, pipeline, tower, chimney, FRP lid, is taken out at tub
Beam hanger, dust collect plant, washer, blower, fertilizer granulation tower, petticoat pipe, grid), (electrolytic cell, desulfurization duct, electricity remove metallurgy industry
Day with fog, absorption tower, head tank, circulating slot, relaying slot, storage tank, pipe-line system, blower, rinse bath), chemical fibre papermaking (hydroformylation liquid system
System, cesspool, neutralization chamber, bleaching tower and liner, wastewater disposal basin), food pharmaceutical (pure water equipment, water treatment facilities, food cans slot,
GMP terrace, consersion unit, neutralization chamber), building industry (movable dwellings, decorated articles, sanitary ware, water treatment facilities, change excrement
Pond, manhole cover, concrete FRP reinforcing rib, building reinforcement, water-proof repairing), electric power energy (flue gas desulfurization device, chimney, wind
Electric equipment, waste pipe, transformer, insulating element (resistance to SF6), pure water device, change (useless) pond, soda acid library FGD), communications and transportation
(subway component, leaf spring, wheel, baffle, steering wheel, vehicle body, sport car shell, integral vacuum toilet, trim panel, seat, trip
Ship, canoe, big fishing vessel, bridge scale protection, FRP bridge, airfield pavement), ocean engineering protect (offshore platform, oil tanker, sea
Bottom pipeline) etc. industry fast development, driven the rapid development of paint industry；The paint industry of early stage is mainly that oiliness applies
Material, oil paint, can be right since its property is stable, have good rust resistance and corrosion resistance effect, be not easy to be flooded profit and oxidation
Matrix plays a very good protection and is widely used；But with the enhancing of people's health consciousness, oil paint is again because of it
It the strong pungent smell of generation and is gradually banned the shortcomings that containing the substance being harmful to the human body.
With the enhancing of environmental consciousness, injury in order to avoid the harmful substance in oil paint to human body is molten with water
The water paint and aqueous vinyl plexiglas flake mortar of agent or decentralized medium are gradually promoted and are used by people；But mesh
The preceding anticorrosive paint and clay used on the market, using temperature generally at 100 DEG C hereinafter, protection the phase be generally 2~3 years, big portion
Divide and is extremely difficult to corrosion-resistant effect in sour, this kind of corrosion of alkali environment.Therefore develop more resistant to high temperature, it is corrosion-resistant and have resistance
The environmental protection coating material of fuel efficiency fruit is current development trend.
Summary of the invention:
Exist for current coating and clay in acid, anti-corrosion is difficult under alkali environment and long-term use temperature is low asks
Topic, the present invention provide a kind of use temperature range that can break through current conventional ethylene base ester plexiglas flake mortar, can
It is used under high temperature, strong corrosive environment, and solidifies avirulent novel environment-friendly water-based vinyl ester resin glass flake plasticine.
The present invention solves scheme used by its technical problem: a kind of environment-friendly water-based vinyl ester resin glass flake glue
Mud, the raw material including following weight percent: aqueous vinyl ester resin 45%~56%, glass flake 20%~30%, sulphur
Sour barium 7%~15%, Anti-cracking agent 5%~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3%, defoaming agent 0.05~
0.1%.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the aqueous vinyl ester resin are bis-phenol
One kind or two of A epoxy methacrylic acid aqueous vinyl ester resin and epoxy novolac methacrylic acid aqueous vinyl ester resin
Kind.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the glass flake are the glass of 20~40 mesh
Glass scale.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the barium sulfate are blanc fixe.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the Anti-cracking agent are talcum powder.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the titanium dioxide are anatase thpe white powder.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the sagging inhibitor are gas phase titanium dioxide
Silicon.
A kind of above-mentioned environment-friendly water-based vinyl ester resin glass flake plasticine, the defoaming agent are silicone oil or propylene glycol.
The present invention also provides a kind of preparation process of environment-friendly water-based vinyl ester resin glass flake plasticine, including it is following
Step: following raw material is weighed: aqueous vinyl ester resin 45%~56%, glass flake 20%~30%, barium sulfate 7%~
15%, Anti-cracking agent 5%~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3% and defoaming agent 0.05~0.1%；First
Aqueous vinyl ester resin total amountBy it with glass flake, barium sulfate, Anti-cracking agent, titanium dioxide and sagging inhibitor
It is added in kneader together, stirs 15min~30min, then defoaming agent and remaining aqueous vinyl ester resin are added again
Kneader stirs 0.5~1.0 hour, after uniform, obtains finished product.
The preparation process of above-mentioned a kind of environment-friendly water-based vinyl ester resin glass flake plasticine, comprising the following steps: claim
Measure following raw material: aqueous vinyl ester resin 45%~56%, barium sulfate 7%~15%, is prevented glass flake 20%~30%
Crackle agent 5%~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3% and defoaming agent 0.05~0.1%；It is first aqueous
Vinyl ester resin total amountIt is pinched with the addition of glass flake, barium sulfate, Anti-cracking agent, titanium dioxide and sagging inhibitor
In conjunction machine, 15min~30min is stirred, kneader, stirring then is added in defoaming agent and remaining aqueous vinyl ester resin again
0.5~1.0 hour, after uniform, obtain finished product.
Beneficial effects of the present invention: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present invention is adopted
With high performance vinyl ester resin, and foliated glass scale is added wherein, put down the foliated glass scale in coating each other
Capable or overlapping arrangement forms a lot of scale protective barrier, and corrosive medium is delayed to reach the time of substrate surface through coating, from
And substantially prolong the service life of substrate；With high temperature resistant, corrosion-resistant；Low abrasivity, low curing shrinkage rate and low linear expansion
Coefficient；Vapour resistant rate is 6~15 times higher than common epoxy resin daub, coating；It can harden under normal temperature conditions, molding letter
It is single, it is easy repairing；Good mechanical performance and have good flame retardant effect.
Specific embodiment:
Below with reference to embodiment, technical scheme of the present invention will be further described.
Embodiment 1: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: glass flake 25%, the precipitated sulfur of bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin 51%, 30 mesh
Sour barium 14.5%, talcum powder 5%, anatase thpe white powder 2%, fumed silica 2.4%, silicone oil 0.1%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and the 34% acids ethylene of bisphenol-A epoxy metering system is then added
Base ester resin stirs 15~30min, then again by 17% bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin and silicon
Kneader is added in oil, stirs 30~60min, stirs evenly and obtain finished product.
Embodiment 2: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: glass flake 20%, the precipitated sulfur of bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin 56%, 32 mesh
Sour barium 13%, talcum powder 7%, anatase thpe white powder 1.8%, fumed silica 2.1%, propylene glycol 0.1%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and the 28% acids ethylene of bisphenol-A epoxy metering system is then added
Base ester resin stirs 15~30min, then again by 28% bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin and third
Kneader is added in glycol, stirs 30~60min, stirs evenly and obtain finished product.
Embodiment 3: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: glass flake 27%, the sulfate precipitate of epoxy novolac methacrylic acid aqueous vinyl ester resin 48%, 25 mesh
Barium 15%, talcum powder 6%, anatase thpe white powder 1.5%, fumed silica 2.4%, silicone oil 0.1%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and 36% epoxy novolac methacrylic acid aqueous vinyl is then added
Ester resin stirs 15~30min, then again adds 12% epoxy novolac methacrylic acid aqueous vinyl ester resin and silicone oil
Enter kneader, stirs 30~60min, stir evenly and obtain finished product.
Embodiment 4: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: glass flake 30%, the sulfate precipitate of epoxy novolac methacrylic acid aqueous vinyl ester resin 45%, 28 mesh
Barium 12.95%, talcum powder 8%, anatase thpe white powder 1%, fumed silica 3%, silicone oil 0.05%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and 30% epoxy novolac methacrylic acid aqueous vinyl is then added
Ester resin stirs 15~30min, then again adds 15% epoxy novolac methacrylic acid aqueous vinyl ester resin and silicone oil
Enter kneader, stirs 30~60min, stir evenly and obtain finished product.
Embodiment 5: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin 54.21%, the glass flake 28% of 20 mesh, precipitating
Barium sulfate 7%, talcum powder 8%, anatase thpe white powder 1.2%, fumed silica 1.5%, propylene glycol 0.09%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and the 36.14% acids second of bisphenol-A epoxy metering system is then added
Alkenyl esters resin stirs 15~30min, then adds 18.07% bisphenol-A epoxy methacrylic acid aqueous vinyl ester tree
Kneader is added in rouge and propylene glycol, stirs 30~60min, stirs evenly and obtain finished product.
Embodiment 6: a kind of environment-friendly water-based vinyl ester resin glass flake plasticine of the present embodiment, including following weight hundred
Divide the raw material of ratio: bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin 34%, the acids ethylene of epoxy novolac metering system
Base ester resin 17%, the glass flake 25% of 27 mesh, blanc fixe 12.4%, talcum powder 7.52%, anatase thpe white powder
2%, fumed silica 2%, silicone oil 0.08%.
Preparation process: more than precise each raw material, by load weighted glass flake, blanc fixe, talcum powder, rutile titania
Type titanium dioxide and fumed silica are added in kneader, and the 34% acids ethylene of bisphenol-A epoxy metering system is then added
Base ester resin stirs 15~30min, then again by 17% epoxy novolac methacrylic acid aqueous vinyl ester resin and silicone oil
Kneader is added, stirs 30~60min, stirs evenly and obtain finished product.
The foregoing is merely the optimal embodiments of the present invention, and for those skilled in the art, the present invention can have
Various modifications and variations.Any modification done within the spirit and principles of the present invention, equivalent replacement etc., should be included in
Within protection scope of the present invention.
Claims (10)
1. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine, which is characterized in that the original including following weight percent
Material: aqueous vinyl ester resin 45%~56%, glass flake 20%~30%, barium sulfate 7%~15%, Anti-cracking agent 5%
~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3%, defoaming agent 0.05~0.1%.
2. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Aqueous vinyl ester resin is that bisphenol-A epoxy methacrylic acid aqueous vinyl ester resin and epoxy novolac metering system are acids
The one or two of vinyl ester resin.
3. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Glass flake is the glass flake of 20~40 mesh.
4. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Barium sulfate is blanc fixe.
5. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Anti-cracking agent is talcum powder.
6. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Titanium dioxide is anatase thpe white powder.
7. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Sagging inhibitor is fumed silica.
8. a kind of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 1, which is characterized in that described
Defoaming agent is silicone oil or propylene glycol.
9. a kind of preparation process of environment-friendly water-based vinyl ester resin glass flake plasticine, which comprises the following steps:
Weigh following raw material: aqueous vinyl ester resin 45%~56%, glass flake 20%~30%, barium sulfate 7%~15%,
Anti-cracking agent 5%~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3% and defoaming agent 0.05~0.1%；First fetch water
Sex ethylene base ester resin total amountBy it with glass flake, barium sulfate, Anti-cracking agent, titanium dioxide and sagging inhibitor
It is added in kneader, stirs 15min~30min, then defoaming agent and remaining aqueous vinyl ester resin are added again and mediated
Machine stirs 0.5~1.0 hour, after uniform, obtains finished product.
10. a kind of preparation process of environment-friendly water-based vinyl ester resin glass flake plasticine according to claim 9, special
Sign is, comprising the following steps: weighs following raw material: aqueous vinyl ester resin 45%~56%, glass flake 20%~
30%, barium sulfate 7%~15%, Anti-cracking agent 5%~8%, titanium dioxide 1%~2%, sagging inhibitor 1.5%~3% and defoaming
Agent 0.05~0.1%；First aqueous vinyl ester resin total amountBy it with glass flake, barium sulfate, Anti-cracking agent, titanium white
Powder and sagging inhibitor are added in kneader together, 15min~30min are stirred, then again by defoaming agent and remaining aqueous ethylene
Kneader is added in base ester resin, stirs 0.5~1.0 hour, after uniform, obtains finished product.
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| CN201811526096.XA CN109486369A (en) | 2018-12-13 | 2018-12-13 | A kind of environment-friendly water-based vinyl ester resin glass flake plasticine and its preparation process |
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| CN201811526096.XA CN109486369A (en) | 2018-12-13 | 2018-12-13 | A kind of environment-friendly water-based vinyl ester resin glass flake plasticine and its preparation process |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110028878A (en) * | 2019-05-21 | 2019-07-19 | 河南省华昌高新技术有限公司 | A kind of fireproof glass flake mortar and preparation method thereof |
| CN110193459A (en) * | 2019-05-05 | 2019-09-03 | 张波 | A kind of compound glass scale anticorrosion technology |
| CN111534200A (en) * | 2020-05-14 | 2020-08-14 | 哈尔滨鑫科纳米科技发展有限公司 | Carbon nano tube reinforced aqueous vinyl ester high-temperature wear-resistant coating and preparation method thereof |
| CN112661439A (en) * | 2020-12-23 | 2021-04-16 | 江苏邦杰防腐保温科技有限公司 | Preparation method of corrosion-resistant mortar |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110193459A (en) * | 2019-05-05 | 2019-09-03 | 张波 | A kind of compound glass scale anticorrosion technology |
| CN110028878A (en) * | 2019-05-21 | 2019-07-19 | 河南省华昌高新技术有限公司 | A kind of fireproof glass flake mortar and preparation method thereof |
| CN111534200A (en) * | 2020-05-14 | 2020-08-14 | 哈尔滨鑫科纳米科技发展有限公司 | Carbon nano tube reinforced aqueous vinyl ester high-temperature wear-resistant coating and preparation method thereof |
| CN112661439A (en) * | 2020-12-23 | 2021-04-16 | 江苏邦杰防腐保温科技有限公司 | Preparation method of corrosion-resistant mortar |
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Application publication date: 20190319 |